CN118221300A - Oil exploitation wastewater treatment process - Google Patents
Oil exploitation wastewater treatment process Download PDFInfo
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Abstract
本发明涉及高难废水处理技术领域,尤其涉及一种石油开采废水处理工艺。技术问题:该石油开采废水处理工艺主要针对解决现有技术下压裂返排液处理难度大,处理效果欠佳、难长期稳定达标排放与及大规模应用的问题。技术方案:一种石油开采废水处理工艺,其步骤如下:S1:初步油水分离处理;S2:臭氧纳米气浮系统;S3:加药反应系统;S4:生物过滤系统;S5:再次臭氧纳米气浮深度处理;S6:砂碳过滤系统;S7:超滤过滤系统;S8:DTRO过滤系统;S9:电催化氧化系统;S10:MVR蒸发系统;S11:低温刮板蒸发系统;S12:抗污染膜过滤系统。本发明利用臭氧+纳米微细气泡气浮、生物过滤系统、砂碳过滤系统、超滤过滤系统、DTRO过滤系统、电催化氧化系统和抗污染膜过滤系统等工艺可以对废液起到多重净化处理的效果。
The present invention relates to the technical field of high-difficulty wastewater treatment, and in particular to a process for treating wastewater from oil production. Technical problem: The process for treating wastewater from oil production is mainly aimed at solving the problems of great difficulty in treating fracturing flowback fluid under the existing technology, poor treatment effect, difficulty in long-term stable discharge and large-scale application. Technical solution: A process for treating wastewater from oil production, the steps of which are as follows: S1: preliminary oil-water separation treatment; S2: ozone nano-flotation system; S3: dosing reaction system; S4: biological filtration system; S5: ozone nano-flotation deep treatment again; S6: sand carbon filtration system; S7: ultrafiltration filtration system; S8: DTRO filtration system; S9: electrocatalytic oxidation system; S10: MVR evaporation system; S11: low-temperature scraper evaporation system; S12: anti-pollution membrane filtration system. The present invention utilizes processes such as ozone + nano-fine bubble flotation, biological filtration system, sand carbon filtration system, ultrafiltration filtration system, DTRO filtration system, electrocatalytic oxidation system and anti-pollution membrane filtration system to achieve multiple purification effects on wastewater.
Description
技术领域Technical Field
本发明涉及高难废水处理技术领域,尤其涉及一种石油开采废水处理工艺。The invention relates to the technical field of high-difficulty wastewater treatment, and in particular to a process for treating oil production wastewater.
背景技术Background technique
针对现石油开采废水所使用的工艺步骤较为简单,过滤机构较为单一,在对废水进行处理中往往有一定的残余废水需要重新进行过滤处理,浓水处理非常困难,费时费力,不能达到高效稳定处理废水的效果,故而急需一种可以对废水快速进行水油分离和多步骤高效过滤处理的石油开采废水处理工艺,以提升石油开采废水的处理速度,进而满足使用人员高效稳定处理废水及环保的需求。The current process steps for treating oil production wastewater are relatively simple, and the filtering mechanism is relatively single. There is often a certain amount of residual wastewater that needs to be re-filtered during wastewater treatment. The treatment of concentrated water is very difficult, time-consuming and labor-intensive, and cannot achieve the effect of efficient and stable wastewater treatment. Therefore, there is an urgent need for an oil production wastewater treatment process that can quickly separate water from oil and perform multi-step efficient filtering treatment on wastewater, so as to improve the treatment speed of oil production wastewater, and thereby meet the needs of users for efficient and stable wastewater treatment and environmental protection.
发明内容Summary of the invention
针对现有技术的不足,本发明的目的在于提供一种石油开采废水处理工艺,该石油开采废水处理工艺主要针对解决现有技术下压裂返排液处理难度大,处理效果欠佳、难长期稳定达标排放与及大规模应用的问题的技术问题。In view of the shortcomings of the prior art, the purpose of the present invention is to provide a process for treating oil production wastewater, which is mainly aimed at solving the technical problems of the prior art that the treatment of fracturing return fluid is difficult, the treatment effect is poor, it is difficult to achieve long-term stable emission standards and large-scale application.
本发明的技术方案为:一种石油开采废水处理工艺,其步骤如下:The technical solution of the present invention is: a process for treating oil production wastewater, the steps of which are as follows:
S1:初步油水分离处理:首先将石油开采过程中产生的废水收集到采出水收集池中,然后将废水引入到纳米气浮分油设备中,利用高度分散的微小气泡作为载体,粘附废水中的悬浮物,特别是油珠,使其浮力增大随气泡升到水面而得以去除,分离出来的石油进入到集油桶中返回油田利用;S1: Preliminary oil-water separation treatment: First, the wastewater generated during the oil extraction process is collected into the produced water collection pool, and then the wastewater is introduced into the nano-gas flotation oil separation equipment. Highly dispersed tiny bubbles are used as carriers to adhere to the suspended matter in the wastewater, especially the oil droplets, so that their buoyancy is increased and they are removed as the bubbles rise to the water surface. The separated oil enters the oil collection barrel and returns to the oil field for use;
S2:深度油水分离及氧化处理:将S1中经过纳米气浮分油处理后的水和压裂液收集池中的压裂液混合后进入臭氧纳米气浮设备中,在臭氧+纳米微细气泡的作用下产生大量的羟基自由基,无选择性快速氧化水体中的各种有机物,迅速使有机物开环断键,快速降解COD等污染指标,还能将污水中的悬浮物和大分子有机物浮出水面,从而分离去除:S2: Deep oil-water separation and oxidation treatment: The water treated by nano-flotation oil separation in S1 is mixed with the fracturing fluid in the fracturing fluid collection pool and then enters the ozone nano-flotation equipment. Under the action of ozone + nano-fine bubbles, a large number of hydroxyl free radicals are generated, which non-selectively and rapidly oxidize various organic matter in the water body, quickly open the ring and break the bonds of organic matter, and quickly degrade pollution indicators such as COD. It can also float suspended matter and macromolecular organic matter in sewage to the surface, thereby separating and removing them:
S21:浮渣处理:将S2中臭氧纳米气浮所产生的浮渣进入到污泥池中进行处理;S21: Scum treatment: The scum produced by ozone nano-flotation in S2 is put into the sludge tank for treatment;
S3:加药反应系统:将S2中臭氧纳米气浮处理后的水引入到加药反应设备中,往加药反应设备中投加PAC、软化剂、PAM等药剂,使其能够和废水进行混合处理;S3: Dosing reaction system: introduce the water treated by ozone nano-flotation in S2 into the dosing reaction equipment, add PAC, softener, PAM and other agents into the dosing reaction equipment, so that it can be mixed with the wastewater for treatment;
S4:生物过滤系统;经过加药反应系统处理后的废水进入到生物过滤设备进行拦截过滤悬浮物,并利用微生物的新陈代谢作用降解有机物:S4: Biological filtration system; the wastewater treated by the dosing reaction system enters the biological filtration equipment to intercept and filter suspended matter, and utilizes the metabolism of microorganisms to degrade organic matter:
S5:废水深度处理:S4中生物过滤设备处理后的清水进入到纳米臭氧气浮设备中,去除难以生物降解的有机物和色度,同时,纳米气浮技术再次被用来分离悬浮物:S5: Advanced wastewater treatment: The clean water treated by the biological filtration equipment in S4 enters the nano-ozone flotation equipment to remove organic matter and color that is difficult to biodegrade. At the same time, nano-flotation technology is used again to separate suspended matter:
S51:污泥处理:将纳米臭氧气浮设备中所产生的浮渣水引入到污泥池中,同时将S4中生物过滤设备中的污泥也引入到污泥池进行处理;S51: Sludge treatment: The scum water produced in the nano-ozone flotation equipment is introduced into the sludge pool, and the sludge in the biological filtration equipment in S4 is also introduced into the sludge pool for treatment;
S6:砂碳过滤系统:经过纳米臭氧气浮设备处理后的清水进入砂碳过滤设备中,使用砂粒拦截悬浮物,利用活性炭的吸附性去除残余的色度及部分有机物;S6: Sand-carbon filtration system: The clean water treated by the nano-ozone flotation equipment enters the sand-carbon filtration equipment, where sand particles are used to intercept suspended matter, and the adsorption of activated carbon is used to remove residual color and some organic matter;
S61:将砂碳过滤设备中的反洗水引入到纳米臭氧气浮设备中重新进行循环处理;S61: introducing the backwash water in the sand carbon filtration device into the nano ozone flotation device for recirculation treatment;
S7:超滤过滤系统:经过砂碳过滤设备中处理后的清水进入到超滤过滤设备中,使用超滤膜对废水进行过滤,能够截留分子量较大的物质,进一步净化水质;S7: Ultrafiltration system: The clean water treated in the sand-carbon filtration equipment enters the ultrafiltration equipment, and the wastewater is filtered using an ultrafiltration membrane, which can intercept substances with larger molecular weight and further purify the water quality;
S71:浓水处理;将超滤过滤设备中处理后的浓水引入到纳米臭氧气浮设备中重新进行循环处理,去除水中的部分无机物和有机物、色度等,S71: Concentrated water treatment: The concentrated water treated in the ultrafiltration equipment is introduced into the nano-ozone flotation equipment for recirculation treatment to remove some inorganic and organic matter, chromaticity, etc. in the water.
S8:DTRO过滤系统;经过S7中超滤过滤设备所产生的清水进入到DTRO过滤设备中,利用DTRO膜元件高抗污染、高截留率和超高耐压性的特点,分离去除渗滤液中的绝大部分可溶性盐分、小分子有机物等,对膜系统浓水做减量化处理。在高压力下,渗滤液透过DTRO膜系统变成纯净的产水;S8: DTRO filtration system; the clean water produced by the ultrafiltration filtration equipment in S7 enters the DTRO filtration equipment, and the DTRO membrane elements are used to separate and remove most of the soluble salts, small molecular organic matter, etc. in the leachate, and the concentrated water of the membrane system is reduced. Under high pressure, the leachate passes through the DTRO membrane system and becomes pure produced water;
S81:清洗水处理;DTRO过滤设备中处理的清洗水引入到纳米臭氧气浮设备中重新进行循环处理;S81: Washing water treatment: the washing water treated in the DTRO filtration equipment is introduced into the nano-ozone flotation equipment for recirculation treatment;
S9:电催化氧化系统;DTRO过滤设备中处理后的浓水进入到电催化氧化设备中,采用高频脉冲电絮凝法,利用电化学原理,借助外加电源作用产生电化学反应,把电能转化为化学能,在特定的电离设备流程中,对废水中的有机或无机污染物质进行氧化及还原反应,进而凝聚、将污染物从水体中分离,对乳化油、大分子有机物、微生物、重金属离子、氟离子、浊度和部分有色类物质具有良好的去除效果,能去除大部分COD,并将其转化为低毒性或无害的物质;S9: Electrocatalytic oxidation system; The concentrated water treated in the DTRO filtration equipment enters the electrocatalytic oxidation equipment, and adopts high-frequency pulse electrocoagulation method, using electrochemical principles, with the help of external power supply to produce electrochemical reactions, converting electrical energy into chemical energy. In a specific ionization equipment process, the organic or inorganic pollutants in the wastewater are oxidized and reduced, and then condensed and separated from the water body. It has a good removal effect on emulsified oil, macromolecular organic matter, microorganisms, heavy metal ions, fluoride ions, turbidity and some colored substances, and can remove most COD and convert it into low-toxic or harmless substances;
S91:DTRO过滤设备中处理后的淡水进入到抗污染膜过滤设备中进行处理;S91: The fresh water treated in the DTRO filtration equipment enters the anti-pollution membrane filtration equipment for treatment;
S10:MVR蒸发系统:经过电催化氧化设备中的废水进入到MVR蒸发设备中,将废水加热至沸腾,使水分蒸发并冷凝回收,而污染物则留在浓缩液中,即母液,蒸发剩余结晶盐可以进行委外处理;S10: MVR evaporation system: The wastewater from the electrocatalytic oxidation device enters the MVR evaporation device, where the wastewater is heated to boiling, the water evaporates and condenses for recovery, while the pollutants remain in the concentrated liquid, i.e. the mother liquor. The remaining crystallized salt from evaporation can be outsourced for treatment;
S11:低温刮板蒸发系统:蒸发处理后剩余的母液可以进入到低温刮板蒸发设备中,蒸发剩余结晶盐可以进行委外处理,而S10中MVR蒸发设备以及低温刮板蒸发设备的冷凝水可以一同进入到抗污染膜过滤设备中进行处理;S11: Low-temperature scraper evaporation system: The mother liquor remaining after evaporation can enter the low-temperature scraper evaporation equipment, and the remaining crystallized salt can be outsourced for treatment. The condensed water of the MVR evaporation equipment and the low-temperature scraper evaporation equipment in S10 can enter the anti-pollution membrane filtration equipment for treatment together;
S12:抗污染膜过滤系统:抗污染膜过滤设备中处理后的淡水可以进行回用或排放,而浓水重新进入到DTRO过滤设备中进行循环处理。S12: Anti-pollution membrane filtration system: The fresh water treated in the anti-pollution membrane filtration equipment can be reused or discharged, and the concentrated water re-enters the DTRO filtration equipment for circulation treatment.
本发明的有益效果:本发明采用纳米气浮分油以及纳米臭氧气浮等工艺能够快速分离悬浮物和油滴,降解部分COD,而利用生物过滤系统、砂碳过滤系统、超滤过滤系统、DTRO过滤系统、电催化氧化系统和抗污染膜过滤系统等工艺可以对废液起到多重过滤净化处理的效果,能够大大提升废水的处理速度,进一步使石油开采废水可以快速高效进行处理,便于后期回收再利用或排放。Beneficial effects of the present invention: The present invention adopts nano-flotation oil separation and nano-ozone flotation processes to quickly separate suspended matter and oil droplets and degrade part of COD, and utilizes biological filtration system, sand carbon filtration system, ultrafiltration filtration system, DTRO filtration system, electrocatalytic oxidation system and anti-pollution membrane filtration system to achieve multiple filtration and purification effects on waste liquid, which can greatly improve the treatment speed of wastewater, further enable oil production wastewater to be quickly and efficiently treated, and facilitate later recycling and reuse or discharge.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1展现的为本发明的石油开采废水处理工艺流程图。FIG. 1 shows a process flow chart of oil production wastewater treatment according to the present invention.
具体实施方式Detailed ways
下面结合附图和实施例对本发明进一步地进行说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.
请参阅图1,本发明提供一种实施例:一种石油开采废水处理工艺,其步骤如下:Please refer to FIG1 , the present invention provides an embodiment: a process for treating oil production wastewater, the steps of which are as follows:
S1:初步油水分离处理:首先将石油开采过程中产生的废水收集到采出水收集池中,然后将废水引入到纳米气浮分油设备中,利用高度分散的微小气泡作为载体,粘附废水中的悬浮物,特别是油珠,使其浮力增大随气泡升到水面而得以去除,分离出来的石油进入到集油桶中返回油田利用;S1: Preliminary oil-water separation treatment: First, the wastewater generated during the oil extraction process is collected into the produced water collection pool, and then the wastewater is introduced into the nano-gas flotation oil separation equipment. Highly dispersed tiny bubbles are used as carriers to adhere to the suspended matter in the wastewater, especially the oil droplets, so that their buoyancy is increased and they are removed as the bubbles rise to the water surface. The separated oil enters the oil collection barrel and returns to the oil field for use;
S2:深度油水分离及氧化处理:将S1中经过纳米气浮分油处理后的水和压裂液收集池中的压裂液混合后进入臭氧纳米气浮设备中,在臭氧+纳米微细气泡的作用下产生大量的羟基自由基,无选择性的快速氧化水体中的各种有机物,迅速使有机物开环断键,快速降解COD等污染指标,还能将污水中的悬浮物和大分子有机物浮选至水面,从而分离去除;S2: Deep oil-water separation and oxidation treatment: The water treated by nano-flotation oil separation in S1 is mixed with the fracturing fluid in the fracturing fluid collection pool and then enters the ozone nano-flotation equipment. Under the action of ozone + nano-fine bubbles, a large number of hydroxyl free radicals are generated, which non-selectively and rapidly oxidize various organic matter in the water body, quickly open the ring and break the bonds of organic matter, and quickly degrade pollution indicators such as COD. It can also float suspended matter and macromolecular organic matter in sewage to the water surface, thereby separating and removing them;
S21:浮渣处理:将S2中臭氧纳米气浮所产生的浮渣进入到污泥池中进行处理;S21: Scum treatment: The scum produced by ozone nano-flotation in S2 is put into the sludge tank for treatment;
S3:加药反应系统:将S2中臭氧纳米气浮处理后的水引入到加药反应设备中,往加药反应设备中投加PAC、软化剂、PAM等药剂,使其能够和废水进行混合处理;S3: Dosing reaction system: introduce the water treated by ozone nano-flotation in S2 into the dosing reaction equipment, add PAC, softener, PAM and other agents into the dosing reaction equipment, so that it can be mixed with the wastewater for treatment;
S4:生物过滤系统;经过加药反应系统处理后的废水进入到生物过滤设备进行拦截过滤悬浮物,并利用微生物的新陈代谢作用降解有机物:S4: Biological filtration system; the wastewater treated by the dosing reaction system enters the biological filtration equipment to intercept and filter suspended matter, and utilizes the metabolism of microorganisms to degrade organic matter:
S5:废水深度处理:S4中生物过滤设备处理后的清水进入到纳米臭氧气浮设备中,去除难以生物降解的有机物和色度,同时,纳米气浮技术再次被用来分离悬浮物:S5: Advanced wastewater treatment: The clean water treated by the biological filtration equipment in S4 enters the nano-ozone flotation equipment to remove organic matter and color that is difficult to biodegrade. At the same time, nano-flotation technology is used again to separate suspended matter:
S51:污泥处理:将纳米臭氧气浮设备中所产生的浮渣水引入到污泥池中,同时将S4中生物过滤设备中的污泥也引入到污泥池进行处理;S51: Sludge treatment: The scum water produced in the nano-ozone flotation equipment is introduced into the sludge pool, and the sludge in the biological filtration equipment in S4 is also introduced into the sludge pool for treatment;
S6:砂碳过滤系统:经过纳米臭氧气浮设备处理后的清水进入砂碳过滤设备中,使用砂粒拦截悬浮物,利用活性炭的吸附性去除残余的色度及部分有机物;S6: Sand-carbon filtration system: The clean water treated by the nano-ozone flotation equipment enters the sand-carbon filtration equipment, where sand particles are used to intercept suspended matter, and the adsorption of activated carbon is used to remove residual color and some organic matter;
S61:将砂碳过滤设备中的反洗水引入到纳米臭氧气浮设备中重新进行循环处理;S61: introducing the backwash water in the sand carbon filtration device into the nano ozone flotation device for recirculation treatment;
S7:超滤过滤系统:经过砂碳过滤设备中处理后的清水进入到超滤过滤设备中,使用超滤膜对废水进行过滤,能够截留分子量较大的物质,进一步净化水质;S7: Ultrafiltration system: The clean water treated in the sand-carbon filtration equipment enters the ultrafiltration equipment, and the wastewater is filtered using an ultrafiltration membrane, which can intercept substances with larger molecular weight and further purify the water quality;
S71:浓水处理;将超滤过滤设备中处理后的浓水引入到纳米臭氧气浮设备中重新进行循环处理,去除水中的部分无机物和有机物、色度等:S71: Concentrated water treatment: The concentrated water treated in the ultrafiltration equipment is introduced into the nano-ozone flotation equipment for recirculation treatment to remove some inorganic and organic matter, chromaticity, etc. in the water:
S8:DTRO过滤系统;经过S7中超滤过滤设备所产生的清水进入到DTRO过滤设备中,利用DTRO膜元件高抗污染、高截留率和超高耐压性的特点,分离去除渗滤液中的绝大部分可溶性盐分、小分子有机物等,对膜系统浓水做减量化处理。在高压力下,渗滤液透过DTRO膜系统变成纯净的产水;S8: DTRO filtration system; the clean water produced by the ultrafiltration filtration equipment in S7 enters the DTRO filtration equipment, and the DTRO membrane elements are used to separate and remove most of the soluble salts, small molecular organic matter, etc. in the leachate, and the concentrated water of the membrane system is reduced. Under high pressure, the leachate passes through the DTRO membrane system and becomes pure produced water;
S81:清洗水处理;DTRO过滤设备中处理的清洗水引入到纳米臭氧气浮设备中重新进行循环处理;S81: Washing water treatment: the washing water treated in the DTRO filtration equipment is introduced into the nano-ozone flotation equipment for recirculation treatment;
S9:电催化氧化系统;DTRO过滤设备中处理后的浓水进入到电催化氧化设备中,采用高频脉冲电絮凝法,利用电化学原理,借助外加电源作用产生电化学反应,把电能转化为化学能,在特定的电离设备流程中,对废水中的有机或无机污染物质进行氧化及还原反应,进而凝聚、将污染物从水体中分离,对乳化油、大分子有机物、微生物、重金属离子、氟离子、浊度和部分有色类物质具有良好的去除效果,能去除大部分COD,并将其转化为低毒性或无害的物质;S9: Electrocatalytic oxidation system; The concentrated water treated in the DTRO filtration equipment enters the electrocatalytic oxidation equipment, and adopts high-frequency pulse electrocoagulation method, using electrochemical principles, with the help of external power supply to produce electrochemical reactions, converting electrical energy into chemical energy. In a specific ionization equipment process, the organic or inorganic pollutants in the wastewater are oxidized and reduced, and then condensed and separated from the water body. It has a good removal effect on emulsified oil, macromolecular organic matter, microorganisms, heavy metal ions, fluoride ions, turbidity and some colored substances, and can remove most COD and convert it into low-toxic or harmless substances;
S91:DTRO过滤设备中处理后的淡水进入到抗污染膜过滤设备中进行处理;S91: The fresh water treated in the DTRO filtration equipment enters the anti-pollution membrane filtration equipment for treatment;
S10:MVR蒸发系统:经过电催化氧化设备中的废水进入到MVR蒸发设备中,将废水加热至沸腾,使水分蒸发并冷凝回收,而污染物则留在浓缩液中,即母液,蒸发剩余结晶盐可以进行委外处理;S10: MVR evaporation system: The wastewater from the electrocatalytic oxidation device enters the MVR evaporation device, where the wastewater is heated to boiling, the water evaporates and condenses for recovery, while the pollutants remain in the concentrated liquid, i.e. the mother liquor. The remaining crystallized salt from evaporation can be outsourced for treatment;
S11:低温刮板蒸发系统:蒸发处理后剩余的母液可以进入到低温刮板蒸发设备中,蒸发剩余结晶盐可以进行委外处理,而S10中MVR蒸发设备以及低温刮板蒸发设备的冷凝水可以一同进入到抗污染膜过滤设备中进行处理;S11: Low-temperature scraper evaporation system: The mother liquor remaining after evaporation can enter the low-temperature scraper evaporation equipment, and the remaining crystallized salt can be outsourced for treatment. The condensed water of the MVR evaporation equipment and the low-temperature scraper evaporation equipment in S10 can enter the anti-pollution membrane filtration equipment for treatment together;
S12:抗污染膜过滤系统:抗污染膜过滤设备中处理后的淡水可以进行回用或排放,而浓水重新进入到DTRO过滤设备中进行循环处理。S12: Anti-pollution membrane filtration system: The fresh water treated in the anti-pollution membrane filtration equipment can be reused or discharged, and the concentrated water re-enters the DTRO filtration equipment for circulation treatment.
作为优选,S3中首先对石油开采废水进行详细的水质分析,包括pH值、悬浮物(SS)、浊度、油含量、化学需氧量(COD)、生物需氧量(BOD)等指标,通过小试或中试,确定在不同水质条件下PAC、软化剂和PAM的最佳投加量。As a preferred method, S3 first conducts a detailed water quality analysis of the oil production wastewater, including indicators such as pH value, suspended solids (SS), turbidity, oil content, chemical oxygen demand (COD), biological oxygen demand (BOD), etc., and determines the optimal dosage of PAC, softener and PAM under different water quality conditions through small or pilot tests.
作为优选,S4中的生物过滤设备通常由多个生物滤池组成,每个滤池内部填充有生物填料,为微生物提供生长环境。Preferably, the biological filtration equipment in S4 is usually composed of a plurality of biological filter tanks, each of which is filled with biological fillers to provide a growth environment for microorganisms.
作为优选,S51中污泥池中的污泥利用压滤机进行处理,最后将污泥进行委外处理。Preferably, the sludge in the sludge tank in S51 is treated by a filter press, and finally the sludge is outsourced for treatment.
作为优选,S6的砂碳过滤设备中砂层处于过滤罐体的上层,用于初步过滤和截留较大颗粒的悬浮物,活性炭层处于砂层下方,用于吸附有机物、色度和其他污染物。Preferably, in the sand-carbon filtration equipment of S6, the sand layer is located in the upper layer of the filter tank body for preliminary filtration and interception of larger particles of suspended solids, and the activated carbon layer is located below the sand layer for adsorbing organic matter, color and other pollutants.
作为优选,S6中还具有反冲洗系统,其包括反冲洗管道、泵和阀门,用于定期反冲洗过滤介质,去除截留的污染物,恢复过滤性能。Preferably, S6 also has a backwashing system, which includes a backwashing pipeline, a pump and a valve, and is used to regularly backwash the filter medium to remove trapped pollutants and restore the filtering performance.
作为优选,S8中DTRO膜具有高抗污染和高倍浓缩的特性,是专用于污水处理的特殊膜元件,处理油田废水时,可以不依赖预处理,因其内部结构为开放式流道设计,可高效处理含胶体、悬浮物等较多的废水水质。As a preferred choice, the DTRO membrane in S8 has the characteristics of high pollution resistance and high concentration. It is a special membrane element dedicated to sewage treatment. When treating oilfield wastewater, it does not need to rely on pretreatment. Because its internal structure is an open flow channel design, it can efficiently treat wastewater containing more colloids, suspended solids, etc.
作为优选,S9中电催化氧化利用电化学原理,借助外加电源作用产生电化学反应,把电能转化为化学能,在特定的电离设备流程中,对废水中的有机或无机污染物质进行氧化及还原反应,Preferably, the electrocatalytic oxidation in S9 utilizes electrochemical principles to generate electrochemical reactions with the help of an external power source, converting electrical energy into chemical energy, and oxidizing and reducing organic or inorganic pollutants in the wastewater in a specific ionization equipment process.
作为优选,废水中可能存在的PH值、杂质和污染物可能会影响电催化氧化的效果,因此需要对废水进行适当的预处理。Preferably, the pH value, impurities and pollutants that may exist in the wastewater may affect the effect of electrocatalytic oxidation, so the wastewater needs to be properly pretreated.
使用本发明的石油开采废水处理工艺时,其步骤如下:When using the oil production wastewater treatment process of the present invention, the steps are as follows:
S1:初步油水分离处理:首先将石油开采过程中产生的废水收集到采出水收集池中,然后将废水引入到纳米气浮分油设备中,利用高度分散的微小气泡作为载体,粘附废水中的悬浮物,特别是油滴,使其随气泡升到水面而去除,分离出来的石油进入到集油桶中返回油田;S1: Preliminary oil-water separation treatment: First, the wastewater generated during the oil extraction process is collected in the produced water collection pool, and then the wastewater is introduced into the nano-flotation oil separation equipment. Highly dispersed tiny bubbles are used as carriers to adhere to the suspended matter in the wastewater, especially the oil droplets, so that they rise to the water surface with the bubbles and are removed. The separated oil enters the oil collection barrel and returns to the oil field;
S2:深度油水分离及氧化处理:将S1中经过纳米气浮分油处理后的水和压裂液收集池中的压裂液混合后进入臭氧纳米气浮设备中,在臭氧+纳米微细气泡的作用下产生大量的羟基自由基,无选择性快速的氧化水体中的各种有机物,迅速使有机物开环断键,快速降解COD等污染指标,还能将污水中的悬浮物和大分子有机物浮选至水面,从而分离去除;S2: Deep oil-water separation and oxidation treatment: The water treated by nano-flotation oil separation in S1 is mixed with the fracturing fluid in the fracturing fluid collection pool and then enters the ozone nano-flotation equipment. Under the action of ozone + nano-fine bubbles, a large number of hydroxyl free radicals are generated, which non-selectively and rapidly oxidize various organic matter in the water body, quickly open the ring and break the bonds of organic matter, and quickly degrade pollution indicators such as COD. It can also float suspended matter and macromolecular organic matter in sewage to the water surface, thereby separating and removing them;
S21:浮渣处理:将S2中臭氧纳米气浮所产生的浮渣进入到污泥池中进行处理;S21: Scum treatment: The scum produced by ozone nano-flotation in S2 is put into the sludge tank for treatment;
S3:加药反应系统:将S2中臭氧纳米气浮处理后的水引入到加药反应设备中,往加药反应设备中投加PAC、软化剂、PAM等药剂,使其能够和废水进行混合处理;S3: Dosing reaction system: introduce the water treated by ozone nano-flotation in S2 into the dosing reaction equipment, add PAC, softener, PAM and other agents into the dosing reaction equipment, so that it can be mixed with the wastewater for treatment;
S4:生物过滤系统;经过加药反应系统处理后的废水进入到生物过滤设备进行拦截过滤悬浮物,并利用微生物的新陈代谢作用降解有机物:S4: Biological filtration system; the wastewater treated by the dosing reaction system enters the biological filtration equipment to intercept and filter suspended matter, and utilizes the metabolism of microorganisms to degrade organic matter:
S5:废水深度处理:S4中生物过滤设备处理后的清水进入到纳米臭氧气浮设备中,去除难以生物降解的有机物和色度,同时,纳米气浮技术再次被用来分离悬浮物:S5: Advanced wastewater treatment: The clean water treated by the biological filtration equipment in S4 enters the nano-ozone flotation equipment to remove organic matter and color that is difficult to biodegrade. At the same time, nano-flotation technology is used again to separate suspended matter:
S51:污泥处理:将纳米臭氧气浮设备中所产生的浮渣水引入到污泥池中,同时将S4中生物过滤设备中的污泥也引入到污泥池进行处理;S51: Sludge treatment: The scum water produced in the nano-ozone flotation equipment is introduced into the sludge pool, and the sludge in the biological filtration equipment in S4 is also introduced into the sludge pool for treatment;
S6:砂碳过滤系统:经过纳米臭氧气浮设备处理后的清水进入砂碳过滤设备中,使用砂粒拦截悬浮物,利用活性炭的吸附性去除残余的色度及部分有机物;S6: Sand-carbon filtration system: The clean water treated by the nano-ozone flotation equipment enters the sand-carbon filtration equipment, where sand particles are used to intercept suspended matter, and the adsorption of activated carbon is used to remove residual color and some organic matter;
S61:将砂碳过滤设备中的反洗水引入到纳米臭氧气浮设备中重新进行循环处理;S61: introducing the backwash water in the sand carbon filtration device into the nano ozone flotation device for recirculation treatment;
S7:超滤过滤系统:经过砂碳过滤设备中处理后的清水进入到超滤过滤设备中,使用超滤膜对废水进行过滤,能够截留分子量较大的物质,进一步净化水质;S7: Ultrafiltration system: The clean water treated in the sand-carbon filtration equipment enters the ultrafiltration equipment, and the wastewater is filtered using an ultrafiltration membrane, which can intercept substances with larger molecular weight and further purify the water quality;
S71:浓水处理;将超滤过滤设备中处理后的浓水引入到纳米臭氧气浮设备中重新进行循环处理,去除水中的部分无机物和有机物、色度等:S71: Concentrated water treatment: The concentrated water treated in the ultrafiltration equipment is introduced into the nano-ozone flotation equipment for recirculation treatment to remove some inorganic and organic matter, chromaticity, etc. in the water:
S8:DTRO过滤系统;经过S7中超滤过滤设备所产生的清水进入到DTRO过滤设备中,利用DTRO膜元件高抗污染、高截留率和超高耐压性的特点,分离去除渗滤液中的绝大部分可溶性盐分、小分子有机物等,对膜系统浓水做减量化处理。在高压力下,渗滤液透过DTRO膜系统变成纯净的产水;S8: DTRO filtration system; the clean water produced by the ultrafiltration filtration equipment in S7 enters the DTRO filtration equipment, and the DTRO membrane elements are used to separate and remove most of the soluble salts, small molecular organic matter, etc. in the leachate, and the concentrated water of the membrane system is reduced. Under high pressure, the leachate passes through the DTRO membrane system and becomes pure produced water;
S81:清洗水处理;DTRO过滤设备中处理的清洗水引入到纳米臭氧气浮设备中重新进行循环处理;S81: Washing water treatment: the washing water treated in the DTRO filtration equipment is introduced into the nano-ozone flotation equipment for recirculation treatment;
S9:电催化氧化系统;DTRO过滤设备中处理后的浓水进入到电催化氧化设备中,采用高频脉冲电絮凝法,利用电化学原理,借助外加电源作用产生电化学反应,把电能转化为化学能,在特定的电离设备流程中,对废水中的有机或无机污染物质进行氧化及还原反应,进而凝聚、将污染物从水体中分离,对乳化油、大分子有机物、微生物、重金属离子、氟离子、浊度和部分有色类物质具有良好的去除效果,能去除大部分COD,并将其转化为低毒性或无害的物质;废水中可能存在的PH值、杂质和污染物会影响电催化氧化的效果,因此需要对废水进行适当的预处理;S9: Electrocatalytic oxidation system; The concentrated water treated in the DTRO filtration equipment enters the electrocatalytic oxidation equipment, and adopts high-frequency pulse electrocoagulation method, using electrochemical principles, with the help of external power supply to produce electrochemical reactions, converting electrical energy into chemical energy. In the specific ionization equipment process, the organic or inorganic pollutants in the wastewater are oxidized and reduced, and then condensed and separated from the water body. It has a good removal effect on emulsified oil, macromolecular organic matter, microorganisms, heavy metal ions, fluoride ions, turbidity and some colored substances, and can remove most COD and convert it into low-toxic or harmless substances; the pH value, impurities and pollutants that may exist in the wastewater will affect the effect of electrocatalytic oxidation, so the wastewater needs to be properly pretreated;
S91:DTRO过滤设备中处理后的淡水进入到抗污染膜过滤设备中进行处理;S91: The fresh water treated in the DTRO filtration equipment enters the anti-pollution membrane filtration equipment for treatment;
S10:MVR蒸发系统:经过电催化氧化设备中的废水进入到MVR蒸发设备中,将废水加热至沸腾,使水分蒸发并冷凝回收,而污染物则留在浓缩液中,即母液,蒸发剩余结晶盐可以进行委外处理;S10: MVR evaporation system: The wastewater from the electrocatalytic oxidation device enters the MVR evaporation device, where the wastewater is heated to boiling, the water evaporates and condenses for recovery, while the pollutants remain in the concentrated liquid, i.e. the mother liquor. The remaining crystallized salt from evaporation can be outsourced for treatment;
S11:低温刮板蒸发系统:蒸发处理后剩余的母液可以进入到低温刮板蒸发设备中,蒸发剩余结晶盐可以进行委外处理,而S10中MVR蒸发设备以及低温刮板蒸发设备的冷凝水可以一同进入到抗污染膜过滤设备中进行处理;S11: Low-temperature scraper evaporation system: The mother liquor remaining after evaporation can enter the low-temperature scraper evaporation equipment, and the remaining crystallized salt can be outsourced for treatment. The condensed water of the MVR evaporation equipment and the low-temperature scraper evaporation equipment in S10 can enter the anti-pollution membrane filtration equipment for treatment together;
S12:抗污染膜过滤系统:抗污染膜过滤设备中处理后的淡水可以进行回用或排放,而浓水重新进入到DTRO过滤设备中进行循环处理。S12: Anti-pollution membrane filtration system: The fresh water treated in the anti-pollution membrane filtration equipment can be reused or discharged, and the concentrated water re-enters the DTRO filtration equipment for circulation treatment.
通过上述步骤,利用纳米气浮分油以及纳米臭氧气浮等工艺能够可快速分离悬浮物和油珠,降解部分有机物,而利用生物过滤系统、砂碳过滤系统、超滤过滤系统、DTRO过滤系统、电催化氧化系统和抗污染膜过滤系统等工艺可以对废液起到多重过滤净化处理的效果,能够大大提升废水的处理速度,进一步使石油开采废水可以快速高效进行处理,便于后期回收再利用或排放,以解决现有技术下处理方法较为单一,在对废水进行过滤处理中往往有一定的残余浓水,处理非常困难,效率低,费用高,稳定性差等技术难题,进而满足使用人员高效稳定处理废水及环保的需求。Through the above steps, the use of nano-flotation oil separation and nano-ozone flotation processes can quickly separate suspended matter and oil droplets and degrade some organic matter, while the use of biological filtration system, sand carbon filtration system, ultrafiltration filtration system, DTRO filtration system, electrocatalytic oxidation system and anti-pollution membrane filtration system can achieve multiple filtration and purification effects on waste liquid, which can greatly improve the treatment speed of wastewater, further enable oil production wastewater to be treated quickly and efficiently, and facilitate later recycling and reuse or discharge, so as to solve the technical problems that the treatment method under the existing technology is relatively single, there is often a certain amount of residual concentrated water in the filtration treatment of wastewater, the treatment is very difficult, the efficiency is low, the cost is high, the stability is poor, etc., thereby meeting the needs of users for efficient and stable treatment of wastewater and environmental protection.
上面结合附图对本发明的实施方式作了详细说明,但是本发明并不限于上述实施方式,在本领域技术人员所具备的知识范围内,还可以在不脱离本发明宗旨的前提下做出各种变化。The embodiments of the present invention are described in detail above with reference to the accompanying drawings, but the present invention is not limited to the above embodiments, and various changes can be made within the knowledge scope of those skilled in the art without departing from the spirit of the present invention.
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