CN117382260A - Non-woven fabric softener and non-woven face towel containing the softener - Google Patents

Non-woven fabric softener and non-woven face towel containing the softener Download PDF

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Publication number
CN117382260A
CN117382260A CN202311328893.8A CN202311328893A CN117382260A CN 117382260 A CN117382260 A CN 117382260A CN 202311328893 A CN202311328893 A CN 202311328893A CN 117382260 A CN117382260 A CN 117382260A
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woven fabric
softener
woven
nonwoven fabric
layer
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徐敏
赵茂龙
张洪良
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Zhejiang Shushi Biotechnology Co ltd
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Zhejiang Shushi Biotechnology Co ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00—Body-drying implements; Toilet paper; Holders therefor
    • A47K10/02—Towels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2432/00—Cleaning articles, e.g. mops or wipes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

The invention discloses a non-woven fabric softener and a face towel non-woven fabric with the same, which comprises a winding core and a non-woven fabric substrate, wherein the non-woven fabric substrate is wound on the winding core, a breakpoint-shaped split line for splitting a non-woven fabric body into two parts is arranged on the non-woven fabric substrate, the non-woven fabric body comprises a first non-woven fabric layer, a graphene non-woven fabric layer and a second non-woven fabric layer which are fixedly connected through hot-press adhesion, the second non-woven fabric layer is arranged on two sides of the first non-woven fabric layer, the graphene non-woven fabric layer is arranged between the first non-woven fabric layer and the second non-woven fabric layer, and the softener is arranged between the first non-woven fabric layer and the second non-woven fabric layer at intervals. The beneficial effects are that: the cleaning agent has the advantages of enhancing cleaning force, being particularly suitable for oily skin, adsorbing dust and grease on the face and keeping clean.

Description

无纺布柔软剂及带有该柔软剂的洗脸巾无纺布Non-woven fabric softener and non-woven face towel containing the softener

技术领域Technical field

本发明涉及无纺布制品技术领域，具体来说，涉及无纺布柔软剂及带有该柔软剂的洗脸巾无纺布。The present invention relates to the technical field of non-woven products, specifically, to a non-woven fabric softener and a non-woven facial towel containing the softener.

背景技术Background technique

目前市面常见的一次性毛巾，大多是都是折叠后压缩成紧密，这种一次性毛巾为一块抗菌无纺布，经折叠、压缩成紧密的小块，可以是方形、圆台形等形状，由于这种一次性毛巾压缩成紧密的小块，体积很小，携带很方便。使用时将它浸入水中，吸水后，无纺布纤维舒展，成为柔软的毛巾，方便使用，虽然无纺布成本较低，但是这种常见的一次性毛巾，出厂时是多大就多大，无法根据需要选择使用大小，总体来说仍然比较浪费，而且常见的一次性毛巾吸水性都不太好，使用时候的清洁力度也不够强，另外尺寸大小为固定的，由于无纺布不具有经纬线的特点，不易于根据自己的需求拆分。Most of the common disposable towels currently on the market are folded and compressed into a tight shape. This kind of disposable towel is a piece of antibacterial non-woven fabric that is folded and compressed into compact pieces, which can be square, truncated, etc., because This disposable towel is compressed into compact pieces, small in size and easy to carry. When using it, immerse it in water. After absorbing water, the non-woven fiber stretches and becomes a soft towel, which is convenient to use. Although the cost of non-woven fabric is low, this common disposable towel is as big as it is when it leaves the factory. It cannot be adjusted according to the size of the towel. You need to choose the size to use. Generally speaking, it is still wasteful. Moreover, the water absorbency of common disposable towels is not very good, and the cleaning strength during use is not strong enough. In addition, the size is fixed, because non-woven fabrics do not have warp and weft lines. Features, not easy to split according to your own needs.

发明内容Contents of the invention

(一)解决的技术问题(1) Technical problems solved

针对现有技术的不足，本发明提供了无纺布柔软剂及带有该柔软剂的洗脸巾无纺布，具备密收纳方便与清洁效果好的优点，进而解决了吸水性都不太好，使用时候的清洁力度也不够强，另外尺寸大小为固定的，由于无纺布不具有经纬线的特点，不易于根据自己的需求拆分的问题。In view of the shortcomings of the existing technology, the present invention provides a non-woven fabric softener and a non-woven face towel containing the softener, which have the advantages of convenient compact storage and good cleaning effect, thereby solving the problem of poor water absorption. The cleaning power during use is not strong enough, and the size is fixed. Since non-woven fabrics do not have the characteristics of longitude and latitude, it is not easy to separate according to your own needs.

(二)技术方案(2) Technical solutions

为实现上述具备密收纳方便与清洁效果好的优点，本发明采用的具体技术方案如下：In order to realize the above-mentioned advantages of convenient close storage and good cleaning effect, the specific technical solutions adopted by the present invention are as follows:

无纺布柔软剂及带有该柔软剂的洗脸巾无纺布，包括卷芯与无纺布基材，所述无纺布基材绕卷在卷芯上，所述无纺布基材上设有将无纺布本体一分为二的断点状拆分线，无纺布本体包括通过热压粘合实现固定连接的第一无纺布层、石墨烯无纺布层和第二无纺布层，所述第二无纺布层设置在第一无纺布层的两侧，所述石墨烯无纺布层设置在第一无纺布层与第二无纺布层之间，且之间间隔设置有柔软剂。Non-woven softener and non-woven facial towel with the softener, including a core and a non-woven base material, the non-woven base material is wound on the core, and the non-woven base material is There is a breakpoint-like splitting line that divides the non-woven fabric body into two parts. The non-woven fabric body includes a first non-woven fabric layer, a graphene non-woven fabric layer and a second non-woven fabric layer that are fixedly connected by hot pressure bonding. a woven fabric layer, the second non-woven fabric layer is disposed on both sides of the first non-woven fabric layer, the graphene non-woven fabric layer is disposed between the first non-woven fabric layer and the second non-woven fabric layer, And there are softeners spaced between them.

进一步的，所述无纺布基材表面采用水刺提花或压花工艺形成的凸起结构，增加清洁力度的凸起设于所述第一无纺布层的外侧表面。Furthermore, the surface of the non-woven fabric base material adopts a convex structure formed by spunlace jacquard or embossing process, and the convex structures that increase the cleaning power are provided on the outer surface of the first non-woven fabric layer.

进一步的，所述石墨烯无纺布层具有防霾、抗菌与抑菌的功能，活石墨烯无纺布层的一侧固定有过滤层，过滤层的一侧固定有活性炭无纺布层，活性炭无纺布层的制成方法是将配制完成的浓度为-Wt％的活性炭均匀的喷涂到丙纶无纺布上面，取得活性炭无纺布材料，活性炭无纺布层可以防毒气、甲醛、氨气。Further, the graphene non-woven layer has anti-haze, antibacterial and bacteriostatic functions. A filter layer is fixed on one side of the active graphene non-woven layer, and an activated carbon non-woven layer is fixed on one side of the filter layer. The method of making the activated carbon non-woven fabric layer is to evenly spray the prepared activated carbon with a concentration of -Wt% onto the polypropylene non-woven fabric to obtain the activated carbon non-woven fabric material. The activated carbon non-woven fabric layer can prevent poison gas, formaldehyde, and ammonia. gas.

进一步的，所述柔软剂由以下步骤制成：Further, the softener is made by the following steps:

1按重量份数计，取100～140份混合溶剂、40～60份混合料、20～40份聚乙二醇、30～40份混合氨基酸、2～5份催化剂及2～3缩合剂，首先将混合溶剂、混合料、混合氨基酸混合均匀，预热；1 In terms of parts by weight, take 100 to 140 parts of mixed solvent, 40 to 60 parts of mixture, 20 to 40 parts of polyethylene glycol, 30 to 40 parts of mixed amino acids, 2 to 5 parts of catalyst and 2 to 3 condensing agents. First, mix the mixed solvent, mixed materials, and mixed amino acids evenly and preheat;

2待预热结束后，加入缩合剂，氮气保护，升温，搅拌，加入催化剂，搅拌反应，静置，冷却，过滤，烘干，收集干燥物；2. After preheating is completed, add the condensing agent, protect with nitrogen, raise the temperature, stir, add the catalyst, stir the reaction, let stand, cool, filter, dry, and collect the dry matter;

3将干燥物、复合料、N-羟基琥珀酰亚胺及二氯甲烷按质量比4:3～6:0.5:15～18放入反应器，升温，搅拌,冷却，静置；3. Put the dry matter, composite material, N-hydroxysuccinimide and methylene chloride into the reactor in a mass ratio of 4:3~6:0.5:15~18, heat up, stir, cool and let stand;

4待静置结束后，冷冻干燥，收集冷冻干燥物，按重量份数计，取100～100份水、45～50份冷冻干燥物、7～10份柠檬酸、3～5份烷基三甲基季铵、0.5～1.2份三钛酸钠，混合均，即得无纺布柔软剂。4. After standing, freeze-dry and collect the freeze-dried product. In terms of parts by weight, take 100 to 100 parts of water, 45 to 50 parts of freeze-dried product, 7 to 10 parts of citric acid, and 3 to 5 parts of alkyl trisulfide. Methyl quaternary ammonium and 0.5 to 1.2 parts of sodium trititanate are mixed to obtain a non-woven fabric softener.

所述步骤1中混合溶剂为氯仿、二氯甲烷及丁二酸按体积比1:1:1～3混合而成。The mixed solvent in step 1 is chloroform, methylene chloride and succinic acid mixed in a volume ratio of 1:1:1-3.

所述步骤1中混合料为将马来酸酐、丁二酸酐按质量比9:2～5混合而成。The mixture in step 1 is made by mixing maleic anhydride and succinic anhydride in a mass ratio of 9:2-5.

所述步骤1中混合氨基酸为丝氨酸、酪氨酸按质量比3:2～5混合而成。The mixed amino acids in step 1 are serine and tyrosine mixed in a mass ratio of 3:2 to 5.

所述催化剂为五氧化二磷、三氧化二铝中的任意一种。The catalyst is either phosphorus pentoxide or aluminum oxide.

所述缩合剂为1-乙基-(3-二甲基氨基丙基)碳酰二亚胺盐酸盐。The condensation agent is 1-ethyl-(3-dimethylaminopropyl)carbodiimide hydrochloride.

所述步骤1中复合料为将偶氮二异丁氰、乙烯基三乙氧基硅烷按质量比1:10～20混合而成。The composite material in step 1 is made by mixing azobisisobutyl cyanide and vinyltriethoxysilane in a mass ratio of 1:10 to 20.

(三)有益效果(3) Beneficial effects

与现有技术相比，本发明提供了无纺布柔软剂及带有该柔软剂的洗脸巾无纺布，具备以下有益效果：Compared with the existing technology, the present invention provides a non-woven softener and a non-woven facial towel containing the softener, which have the following beneficial effects:

通过设置有第一无纺布层、石墨烯无纺布层和第二无纺布层，第二无纺布层设置在第一无纺布层的两侧，石墨烯无纺布层设置在第一无纺布层与第二无纺布层之间，且之间间隔设置有柔软剂石墨烯无纺布层具有防霾、抗菌与抑菌的功能，活石墨烯无纺布层的一侧固定有过滤层，过滤层的一侧固定有活性炭无纺布层，活性炭无纺布层的制成方法是将配制完成的浓度为-Wt％的活性炭均匀的喷涂到丙纶无纺布上面，取得活性炭无纺布材料，活性炭无纺布层可以防毒气、甲醛、氨气。设于中间的活性炭无纺布层可以增强清洁力度，特别适用于油性皮肤，可以吸附脸上的灰尘和油脂，保持清爽干净。By providing a first non-woven fabric layer, a graphene non-woven fabric layer and a second non-woven fabric layer, the second non-woven fabric layer is provided on both sides of the first non-woven fabric layer, and the graphene non-woven fabric layer is provided on There is a softener between the first non-woven fabric layer and the second non-woven fabric layer, and the graphene non-woven fabric layer has anti-haze, antibacterial and bacteriostatic functions. One of the living graphene non-woven fabric layers A filter layer is fixed on one side, and an activated carbon non-woven fabric layer is fixed on one side of the filter layer. The activated carbon non-woven fabric layer is made by spraying the prepared activated carbon with a concentration of -Wt% evenly onto the polypropylene non-woven fabric. Obtain activated carbon non-woven material. The activated carbon non-woven layer can prevent poison gas, formaldehyde and ammonia. The activated carbon non-woven layer in the middle can enhance cleaning power and is especially suitable for oily skin. It can absorb dust and grease on the face to keep it fresh and clean.

附图说明Description of the drawings

为了更清楚地说明本发明实施例或现有技术中的技术方案，下面将对实施例中所需要使用的附图作简单地介绍，显而易见地，下面描述中的附图仅仅是本发明的一些实施例，对于本领域普通技术人员来讲，在不付出创造性劳动的前提下，还可以根据这些附图获得其他的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the drawings needed to be used in the embodiments will be briefly introduced below. Obviously, the drawings in the following description are only some of the drawings of the present invention. Embodiments, for those of ordinary skill in the art, other drawings can also be obtained based on these drawings without exerting creative efforts.

图1是本发明的结构示意图；Figure 1 is a schematic structural diagram of the present invention;

图2是本发明中无纺布基材2的结构示意图；Figure 2 is a schematic structural diagram of the non-woven fabric base material 2 in the present invention;

图3是本发明中柔软剂7的连接示意图；Figure 3 is a schematic diagram of the connection of the softener 7 in the present invention;

图4是中第一无纺布层4的结构示意图。Figure 4 is a schematic structural diagram of the first non-woven fabric layer 4.

图中：卷芯1、无纺布基材2、断点状拆分线3、第一无纺布层4、活石墨烯无纺布层5、第二无纺布层6、柔软剂7、过滤层8、活性炭无纺布层9。In the picture: core 1, non-woven fabric base material 2, breakpoint split line 3, first non-woven fabric layer 4, active graphene non-woven fabric layer 5, second non-woven fabric layer 6, softener 7 , filter layer 8, activated carbon non-woven fabric layer 9.

具体实施方式Detailed ways

为进一步说明各实施例，本发明提供有附图，这些附图为本发明揭露内容的一部分，其主要用以说明实施例，并可配合说明书的相关描述来解释实施例的运作原理，配合参考这些内容，本领域普通技术人员应能理解其他可能的实施方式以及本发明的优点，图中的组件并未按比例绘制，而类似的组件符号通常用来表示类似的组件。In order to further explain each embodiment, the present invention provides drawings. These drawings are part of the disclosure of the present invention. They are mainly used to illustrate the embodiments and can be used with the relevant descriptions in the specification to explain the operating principles of the embodiments. For reference From this, those of ordinary skill in the art will be able to understand other possible implementations and advantages of the present invention. The components in the figures are not drawn to scale, and similar component symbols are generally used to represent similar components.

根据本发明的实施例，提供了无纺布柔软剂及带有该柔软剂的洗脸巾无纺布。According to embodiments of the present invention, a nonwoven fabric softener and a face towel nonwoven fabric containing the softener are provided.

现结合附图和具体实施方式对本发明进一步说明，如图1-4所示，根据本发明实施例的无纺布柔软剂及带有该柔软剂的洗脸巾无纺布，包括卷芯1与无纺布基材2，所述无纺布基材2绕卷在卷芯1上，所述无纺布基材2上设有将无纺布本体一分为二的断点状拆分线3，无纺布本体包括通过热压粘合实现固定连接的第一无纺布层4、石墨烯无纺布层5和第二无纺布层6，所述第二无纺布层6设置在第一无纺布层4的两侧，所述活石墨烯无纺布层5设置在第一无纺布层4与第二无纺布层6之间，且之间间隔设置有柔软剂7。The present invention will now be further described with reference to the accompanying drawings and specific embodiments. As shown in Figures 1-4, the non-woven softener according to the embodiment of the present invention and the non-woven face towel with the softener include a core 1 and a Non-woven fabric base material 2. The non-woven fabric base material 2 is wound on the winding core 1. The non-woven fabric base material 2 is provided with a breakpoint-shaped splitting line that divides the non-woven fabric body into two. 3. The non-woven fabric body includes a first non-woven fabric layer 4, a graphene non-woven fabric layer 5 and a second non-woven fabric layer 6 that are fixedly connected by thermal pressure bonding. The second non-woven fabric layer 6 is provided On both sides of the first non-woven fabric layer 4, the active graphene non-woven fabric layer 5 is disposed between the first non-woven fabric layer 4 and the second non-woven fabric layer 6, with a softener spaced between them. 7.

在一个实施例中，所述无纺布基材2表面采用水刺提花或压花工艺形成的凸起结构，增加清洁力度的凸起设于所述第一无纺布层4的外侧表面。In one embodiment, the surface of the non-woven fabric base material 2 adopts a convex structure formed by a spunlace jacquard or embossing process, and the convex structures to increase cleaning power are provided on the outer surface of the first non-woven fabric layer 4 .

在一个实施例中，所述石墨烯无纺布层5具有防霾、抗菌与抑菌的功能，石墨烯无纺布层5的一侧固定有过滤层8，过滤层8的一侧固定有活性炭无纺布层9，活性炭无纺布层9的制成方法是将配制完成的浓度为5-15Wt％的活性炭均匀的喷涂到丙纶无纺布上面，取得活性炭无纺布材料，活性炭无纺布层9可以防毒气、甲醛、氨气。In one embodiment, the graphene non-woven fabric layer 5 has anti-haze, antibacterial and bacteriostatic functions. A filter layer 8 is fixed on one side of the graphene non-woven layer 5, and a filter layer 8 is fixed on one side of the filter layer 8. The activated carbon non-woven fabric layer 9 is made by spraying the prepared activated carbon with a concentration of 5-15wt% evenly onto the polypropylene non-woven fabric to obtain the activated carbon non-woven fabric material. The cloth layer 9 can prevent poison gas, formaldehyde, and ammonia.

在一个实施例中，所述柔软剂7由以下步骤制成：In one embodiment, the softener 7 is made by the following steps:

1按重量份数计，取100～140份混合溶剂、40～60份混合料、20～40份聚乙二醇、30～40份混合氨基酸、2～5份催化剂及2～3缩合剂，首先将混合溶剂、混合料、混合氨基酸混合均匀，预热；1 In terms of parts by weight, take 100 to 140 parts of mixed solvent, 40 to 60 parts of mixture, 20 to 40 parts of polyethylene glycol, 30 to 40 parts of mixed amino acids, 2 to 5 parts of catalyst and 2 to 3 condensing agents. First, mix the mixed solvent, mixed materials, and mixed amino acids evenly and preheat;

2待预热结束后，加入缩合剂，氮气保护，升温，搅拌，加入催化剂，搅拌反应，静置，冷却，过滤，烘干，收集干燥物；2. After preheating is completed, add the condensing agent, protect with nitrogen, raise the temperature, stir, add the catalyst, stir the reaction, let stand, cool, filter, dry, and collect the dry matter;

3将干燥物、复合料、N-羟基琥珀酰亚胺及二氯甲烷按质量比4:3～6:0.5:15～18放入反应器，升温，搅拌,冷却，静置；3. Put the dry matter, composite material, N-hydroxysuccinimide and methylene chloride into the reactor in a mass ratio of 4:3~6:0.5:15~18, heat up, stir, cool and let stand;

4待静置结束后，冷冻干燥，收集冷冻干燥物，按重量份数计，取100～100份水、45～50份冷冻干燥物、7～10份柠檬酸、3～5份烷基三甲基季铵、0.5～1.2份三钛酸钠，混合均，即得无纺布柔软剂。4. After standing, freeze-dry and collect the freeze-dried product. In terms of parts by weight, take 100 to 100 parts of water, 45 to 50 parts of freeze-dried product, 7 to 10 parts of citric acid, and 3 to 5 parts of alkyl trisulfide. Methyl quaternary ammonium and 0.5 to 1.2 parts of sodium trititanate are mixed to obtain a non-woven fabric softener.

所述步骤1中混合溶剂为氯仿、二氯甲烷及丁二酸按体积比1:1:1～3混合而成。The mixed solvent in step 1 is chloroform, methylene chloride and succinic acid mixed in a volume ratio of 1:1:1-3.

所述步骤1中混合料为将马来酸酐、丁二酸酐按质量比9:2～5混合而成。The mixture in step 1 is made by mixing maleic anhydride and succinic anhydride in a mass ratio of 9:2-5.

所述步骤1中混合氨基酸为丝氨酸、酪氨酸按质量比3:2～5混合而成。The mixed amino acids in step 1 are serine and tyrosine mixed in a mass ratio of 3:2 to 5.

所述催化剂为五氧化二磷、三氧化二铝中的任意一种。The catalyst is either phosphorus pentoxide or aluminum oxide.

所述缩合剂为1-乙基-(3-二甲基氨基丙基)碳酰二亚胺盐酸盐。The condensation agent is 1-ethyl-(3-dimethylaminopropyl)carbodiimide hydrochloride.

所述步骤1中复合料为将偶氮二异丁氰、乙烯基三乙氧基硅烷按质量比1:10～20混合而成。The composite material in step 1 is made by mixing azobisisobutyl cyanide and vinyltriethoxysilane in a mass ratio of 1:10 to 20.

在本发明中，除非另有明确的规定和限定，术语“安装”、“设置”、“连接”、“固定”、“旋接”等术语应做广义理解，例如，可以是固定连接，也可以是可拆卸连接，或成一体；可以是机械连接，也可以是电连接；可以是直接相连，也可以通过中间媒介间接相连，可以是两个元件内部的连通或两个元件的相互作用关系，除非另有明确的限定，对于本领域的普通技术人员而言，可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, unless otherwise expressly stipulated and limited, the terms "installation", "setting", "connection", "fixing", "screwing" and other terms should be understood in a broad sense. For example, it can be a fixed connection or a fixed connection. It can be detachably connected or integrated; it can be mechanically connected or electrically connected; it can be directly connected or indirectly connected through an intermediate medium; it can be the internal connection of two elements or the interaction between two elements. , unless otherwise explicitly limited, those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention according to specific circumstances.

以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention and are not intended to limit the present invention. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention shall be included in the present invention. within the scope of protection.

Claims (10)

1. The non-woven fabric softener and the face towel non-woven fabric with the softener are characterized in that: including rolling up core (1) and non-woven fabrics substrate (2), non-woven fabrics substrate (2) are rolled up on rolling up core (1), be equipped with on non-woven fabrics substrate (2) with non-woven fabrics body one divide into breakpoint form split line (3) of two, the non-woven fabrics body is including realizing fixed connection's first non-woven fabrics layer (4), graphite alkene non-woven fabrics layer (5) and second non-woven fabrics layer (6) through the hot briquetting, second non-woven fabrics layer (6) set up in the both sides of first non-woven fabrics layer (4), graphite alkene non-woven fabrics layer (5) set up between first non-woven fabrics layer (4) and second non-woven fabrics layer (6), and the interval is provided with softener (7) between.
2. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 1, wherein: the surface of the non-woven fabric base material (2) adopts a raised structure formed by a water jet jacquard or embossing process, and the protrusions for increasing the cleaning force are arranged on the outer side surface of the first non-woven fabric layer (4).
3. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 1, wherein: the graphene non-woven fabric layer (5) has the functions of haze prevention, antibiosis and bacteriostasis, a filter layer (8) is fixed on one side of the graphene non-woven fabric layer (5), an activated carbon non-woven fabric layer (9) is fixed on one side of the filter layer (8), the preparation method of the activated carbon non-woven fabric layer (9) is to uniformly spray the prepared activated carbon with the concentration of (5) - (15) Wt% onto the polypropylene non-woven fabric to obtain an activated carbon non-woven fabric material, and the activated carbon non-woven fabric layer (9) can prevent toxic gases, formaldehyde and ammonia.
4. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 1, wherein: the softener (7) is prepared by the following steps:
step one, taking 100 to 140 parts of mixed solvent, 40 to 60 parts of mixture, 20 to 40 parts of polyethylene glycol, 30 to 40 parts of mixed amino acid, 2 to 5 parts of catalyst and 2 to 3 condensing agents according to parts by weight, uniformly mixing the mixed solvent, the mixture and the mixed amino acid, and preheating;
after the preheating is finished, adding a condensing agent, protecting with nitrogen, heating, stirring, adding a catalyst, stirring for reaction, standing, cooling, filtering, drying, and collecting a dried product;
step three, putting the dried product, the composite material, the N-hydroxysuccinimide and the methylene dichloride into a reactor according to the mass ratio of 4:3-6:0.5:15-18, heating, stirring, cooling and standing;
and fourthly, after standing, freeze-drying, collecting freeze-dried substances, and mixing 100-100 parts of water, 45-50 parts of freeze-dried substances, 7-10 parts of citric acid, 3-5 parts of alkyl trimethyl quaternary ammonium and 0.5-1.2 parts of sodium tri-titanate according to parts by weight to obtain the non-woven fabric softener.
5. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 4, wherein: the mixed solvent in the step 1 is formed by mixing chloroform, dichloromethane and succinic acid according to the volume ratio of 1:1:1-3.
6. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 4, wherein: the mixture in the step 1 is prepared by mixing maleic anhydride and succinic anhydride according to a mass ratio of 9:2-5.
7. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 4, wherein: the mixed amino acid in the step 1 is formed by mixing serine and tyrosine according to the mass ratio of 3:2-5.
8. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 4, wherein: the catalyst is any one of phosphorus pentoxide and aluminum oxide.
9. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 4, wherein: the condensing agent is 1-ethyl- (3-dimethylaminopropyl) carbodiimide hydrochloride.
10. The nonwoven fabric softener and the face towel nonwoven fabric with the softener according to claim 4, wherein: the composite material in the step 1 is prepared by mixing azodiisobutyl cyanide and vinyl triethoxysilane according to the mass ratio of 1:10-20.
CN202311328893.8A 2023-10-15 2023-10-15 Non-woven fabric softener and non-woven face towel containing the softener Pending CN117382260A (en)

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Publication number Priority date Publication date Assignee Title
CN211222313U (en) * 2019-06-21 2020-08-11 广州俊麒无纺布企业有限公司 Disposable non-woven fabric face washing towel
CN112575580A (en) * 2020-12-28 2021-03-30 成都峻筠秀科技有限公司 Preparation method of non-woven fabric softener
CN212994593U (en) * 2020-07-15 2021-04-20 田金澄 Activated carbon graphene mask
CN217310058U (en) * 2022-04-21 2022-08-30 浙江舒氏生物科技有限公司 Disposable non-woven washing towel with cutting line
CN217622550U (en) * 2022-04-25 2022-10-21 杭州杭纺科技有限公司 Efficient face-cleaning diamond grain non-woven fabric face washing towel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN211222313U (en) * 2019-06-21 2020-08-11 广州俊麒无纺布企业有限公司 Disposable non-woven fabric face washing towel
CN212994593U (en) * 2020-07-15 2021-04-20 田金澄 Activated carbon graphene mask
CN112575580A (en) * 2020-12-28 2021-03-30 成都峻筠秀科技有限公司 Preparation method of non-woven fabric softener
CN217310058U (en) * 2022-04-21 2022-08-30 浙江舒氏生物科技有限公司 Disposable non-woven washing towel with cutting line
CN217622550U (en) * 2022-04-25 2022-10-21 杭州杭纺科技有限公司 Efficient face-cleaning diamond grain non-woven fabric face washing towel

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