CN116924519A - Efficient automatic control method and system for immersed ultrafiltration membrane - Google Patents
Efficient automatic control method and system for immersed ultrafiltration membrane Download PDFInfo
- Publication number
- CN116924519A CN116924519A CN202310700376.2A CN202310700376A CN116924519A CN 116924519 A CN116924519 A CN 116924519A CN 202310700376 A CN202310700376 A CN 202310700376A CN 116924519 A CN116924519 A CN 116924519A
- Authority
- CN
- China
- Prior art keywords
- liquid
- cleaning
- valve
- tank
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/18—Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/20—Accessories; Auxiliary operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/22—Controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/008—Control or steering systems not provided for elsewhere in subclass C02F
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/11—Turbidity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/42—Liquid level
Landscapes
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
本发明公开了一种浸没式超滤膜的高效自动控制方法及系统,包括超滤产水控制程序、化学清洗控制程序;超滤产水控制程序控制超滤膜池进水透过超滤膜进行出水;当开启产水泵进行产水时,水透过超滤膜从其内侧进行出水;当进行化学清洗时,根据清洗药剂的种类和清洗方式,会有不同的实施程序,化学清洗能将附着于超滤膜上的无机物和有机物去除,使超滤膜恢复最佳透水性。经本控制方法处理得到的水质水量稳定,超滤膜运行使用寿命长,系统回收率高,运行成本低,自动化程度高。
The invention discloses an efficient automatic control method and system for a submerged ultrafiltration membrane, which includes an ultrafiltration water production control program and a chemical cleaning control program; the ultrafiltration water production control program controls the incoming water of the ultrafiltration membrane pool to pass through the ultrafiltration membrane. When the water production pump is turned on to produce water, water passes through the ultrafiltration membrane and flows out from the inside; when chemical cleaning is performed, there will be different implementation procedures according to the type of cleaning agent and cleaning method. Chemical cleaning can The inorganic and organic substances attached to the ultrafiltration membrane are removed to restore the optimal water permeability of the ultrafiltration membrane. The water quality and quantity treated by this control method are stable, the ultrafiltration membrane has a long service life, the system recovery rate is high, the operating cost is low, and the degree of automation is high.
Description
技术领域Technical field
本发明属于水处理技术领域,特别涉及一种浸没式超滤膜全过程自动控制方法及系统。The invention belongs to the technical field of water treatment, and particularly relates to a full-process automatic control method and system for a submerged ultrafiltration membrane.
背景技术Background technique
超滤是一种能将溶液进行净化和分离的膜分离技术,超滤膜是用于超滤过程中的人工滤膜。一般由高分子材料如PVDF、PP、PS等制成。超滤膜是以超滤膜丝为过滤介质,膜两侧的压力差为驱动力的溶液分离装置。超滤膜只允许溶液中的溶剂(如水分子)、无机盐及溶解性有机物透过,截留溶液中的悬浮物、胶体和微生物等,从而达到净化和分离的目的。目前超滤膜被广泛用于水处理过程,超滤技术在反渗透预处理、饮用水处理、中水回用等领域发挥越来越重要的作用。Ultrafiltration is a membrane separation technology that can purify and separate solutions. Ultrafiltration membrane is an artificial filter membrane used in the ultrafiltration process. Generally made of polymer materials such as PVDF, PP, PS, etc. Ultrafiltration membrane is a solution separation device that uses ultrafiltration membrane wire as the filtration medium and the pressure difference on both sides of the membrane as the driving force. The ultrafiltration membrane only allows the solvent (such as water molecules), inorganic salts and dissolved organic matter in the solution to pass through, and intercepts suspended solids, colloids and microorganisms in the solution, thereby achieving the purpose of purification and separation. Ultrafiltration membranes are currently widely used in water treatment processes, and ultrafiltration technology plays an increasingly important role in reverse osmosis pretreatment, drinking water treatment, reclaimed water reuse and other fields.
超滤膜工艺近年来逐渐得到业内认可推崇,整个系统中包括超滤产水、物理清洗、化学清洗、药液配制、药液中和、废液排放等板块,超滤产水对系统回收率往往有较高要求(等于净产水/总产水),高回收率表示系统运行效率高,运行成本低。由于超滤规模的不断扩大,工作人员对作业条件要求的提高以及对超滤处理高效率的追求,如何实现超滤系统高效、稳定、自动化运行成为亟待解决的问题。但是目前国内在这方面取得的成果还少之又少。The ultrafiltration membrane process has gradually been recognized and respected in the industry in recent years. The entire system includes ultrafiltration water production, physical cleaning, chemical cleaning, liquid preparation, liquid neutralization, waste liquid discharge and other sections. The ultrafiltration water production has an important impact on the system recovery rate. There are often higher requirements (equal to net water production/total water production). A high recovery rate indicates high system operating efficiency and low operating costs. Due to the continuous expansion of the scale of ultrafiltration, the improvement of workers' requirements for operating conditions and the pursuit of high efficiency in ultrafiltration processing, how to achieve efficient, stable and automated operation of the ultrafiltration system has become an urgent problem to be solved. However, there are currently very few results achieved in this regard domestically.
发明内容Contents of the invention
为解决上述中存在的问题,本发明提供了一种能够提高浸没式超滤膜系统的运行安全性及处理效率,并节约运行成本的高效自动控制方法及系统。In order to solve the above problems, the present invention provides an efficient automatic control method and system that can improve the operation safety and processing efficiency of the submerged ultrafiltration membrane system and save operating costs.
为实现上述目标,本发明采用如下的技术解决方案:In order to achieve the above goals, the present invention adopts the following technical solutions:
一种浸没式超滤膜的高效自动控制方法,包括:An efficient automatic control method for submerged ultrafiltration membranes, including:
超滤产水控制程序:超滤膜池进水从进水渠流入,进水渠设置温度计、液位计、浊度仪,分别对进水水质水量进行检测,可通过分析其测量出的进水温度值、液位值和浊度值对膜池产水流量进行相应设定,当温度值低于15℃时,将膜池产水流量下调至设计流量的80%,当高于15℃时,为设计流量,当液位值在2m时,上调膜池产水流量,低于2m时,下调产水流量,当浊度高于5NTU时,下调产水流量,当浊度低于5NTU时上调产水流量。通过PLC控制闸板阀开度从而调节超滤膜池进水流量,超滤膜池内部装有静压液位计,通过静压液位计的测量值判断是否开启产水泵和是否开启进水闸板阀,当膜池液位低于L液位时,进水闸板阀开启,当膜池液位高于H液位时,进水闸板阀关闭,当膜池液位高于L液位时,真空射流器开启,约10-30s关闭,然后产水阀开启,接着产水泵开启,系统开始产水,当膜池液位低于LL液位时,产水泵关闭,产水阀关闭,产水程序结束,当系统正常运行时,产水时间按固定周期设定,一般为20-50分钟,到达设定周期产水停止。LL液位为保护液位,防止超滤膜因干燥造成损伤和防止产水泵空抽造成泵损伤,L液位为超滤产水启动液位,H液位为进水停止液位,防止膜池进水过多造成溢流。Ultrafiltration water production control program: The incoming water of the ultrafiltration membrane pool flows in from the inlet canal. The inlet canal is equipped with a thermometer, liquid level meter, and turbidity meter to detect the quality and quantity of the incoming water respectively. The measured inlet water temperature can be analyzed Value, liquid level value and turbidity value set the membrane tank water flow rate accordingly. When the temperature value is lower than 15℃, the membrane tank water flow rate is reduced to 80% of the design flow rate. When it is higher than 15℃, For the design flow rate, when the liquid level is at 2m, increase the water flow rate of the membrane tank. When it is lower than 2m, adjust the water flow rate down. When the turbidity is higher than 5NTU, adjust the water flow rate down. When the turbidity is lower than 5NTU, increase it. Product water flow. The PLC controls the opening of the gate valve to adjust the inlet flow of the ultrafiltration membrane tank. The ultrafiltration membrane tank is equipped with a static pressure level gauge. The measurement value of the static pressure level gauge is used to determine whether to open the water production pump and whether to open the water inlet gate. Plate valve. When the membrane tank liquid level is lower than the L liquid level, the inlet gate valve opens. When the membrane tank liquid level is higher than the H liquid level, the inlet gate valve closes. When the membrane tank liquid level is higher than the L liquid level, the inlet gate valve closes. , the vacuum jet is turned on and closed for about 10-30 seconds, then the water production valve is opened, and then the water production pump is turned on, and the system begins to produce water. When the membrane tank liquid level is lower than the LL liquid level, the water production pump is closed, the water production valve is closed, and water production begins. At the end of the water program, when the system is running normally, the water production time is set according to a fixed period, usually 20-50 minutes, and the water production stops when the set period is reached. The LL liquid level is a protective liquid level to prevent damage to the ultrafiltration membrane due to drying and to prevent pump damage caused by empty pumping of the produced water pump. The L liquid level is the start liquid level of the ultrafiltration water produced, and the H liquid level is the water inlet stop liquid level to prevent the membrane from being damaged due to drying. Too much water entering the pool causes overflow.
化学清洗控制程序:超滤膜池出水管道装有压力表,其压力表测量值可与静压液位计测量值计算超滤膜跨膜压差,该值反映超滤膜透水性强弱,能够判定超滤膜是否需进行化学清洗,当系统正常运行时,维护性清洗和恢复性清洗频率按固定产水周期设定。跨膜压差值做为超滤膜清洗参考值和保护值,跨膜压差在0-30KPa时表示超滤膜透水性好,跨膜压差在30-60KPa时需进行维护性清洗清洗,跨膜压差在60-80KPa时需进行恢复性清洗,跨膜压差在80KPa及以上时设为保护值,即达到此设定值时,PLC控制系统发出报警信号且停止产水。当进行化学清洗时,根据清洗药剂的种类和清洗方式,会有不同的实施程序,化学清洗能将附着于超滤膜上的无机物和有机物去除,使超滤膜恢复最佳透水性。Chemical cleaning control program: The outlet pipe of the ultrafiltration membrane pool is equipped with a pressure gauge. The measurement value of the pressure gauge can be used with the measurement value of the hydrostatic level gauge to calculate the transmembrane pressure difference of the ultrafiltration membrane. This value reflects the water permeability of the ultrafiltration membrane. It can determine whether the ultrafiltration membrane needs chemical cleaning. When the system is operating normally, the frequency of maintenance cleaning and restorative cleaning is set according to a fixed water production cycle. The transmembrane pressure difference is used as a reference value and protection value for ultrafiltration membrane cleaning. When the transmembrane pressure difference is 0-30KPa, it means that the ultrafiltration membrane has good water permeability. When the transmembrane pressure difference is 30-60KPa, maintenance cleaning is required. Restorative cleaning is required when the transmembrane pressure difference is 60-80KPa. When the transmembrane pressure difference is 80KPa and above, it is set as a protection value. That is, when this set value is reached, the PLC control system sends an alarm signal and stops water production. When performing chemical cleaning, there will be different implementation procedures depending on the type of cleaning agent and cleaning method. Chemical cleaning can remove inorganic and organic substances attached to the ultrafiltration membrane and restore the optimal water permeability of the ultrafiltration membrane.
酸浸泡洗:开启酸清洗进液阀,开启酸清洗出液阀,再开启酸清洗水泵,膜池药液达到LL液位时停止进药,关闭酸清洗水泵,再关闭酸清洗进液阀,开启酸清洗出液阀,酸浸泡达到设定时间后,若该药液重复利用次数未到设定次数,开启药液回流阀,再开启酸液回流阀和酸清洗进液阀,药液回流进入酸清洗水池,待药液回流完成,关闭药液回流阀、酸液回流阀和酸清洗进液阀,酸浸泡程序完成,进入膜池漂洗及管道冲洗程序;若该药液重复利用次数达到设定次数,开启废液排放阀,该药液排入中和池,待排空完成后,再关闭废液排放阀,酸浸泡程序完成,进入膜池漂洗及管道冲洗程序。Acid immersion washing: open the acid cleaning liquid inlet valve, open the acid cleaning liquid outlet valve, and then open the acid cleaning water pump. When the membrane tank liquid reaches the LL level, stop feeding, close the acid cleaning water pump, and then close the acid cleaning liquid inlet valve. Open the acid cleaning outlet valve. After the acid soak reaches the set time, if the number of reuses of the chemical solution has not reached the set number, open the chemical solution return valve, then open the acid solution return valve and acid cleaning inlet valve, and the chemical solution will flow back. Enter the acid cleaning pool, wait for the liquid reflux to be completed, close the liquid reflux valve, acid reflux valve and acid cleaning inlet valve, the acid soaking process is completed, enter the membrane tank rinsing and pipeline flushing process; if the number of times the chemical liquid is reused reaches Set the number of times, open the waste liquid discharge valve, and discharge the liquid into the neutralization tank. After the emptying is completed, close the waste liquid discharge valve. The acid soaking process is completed, and the membrane tank rinsing and pipeline flushing procedures are entered.
或碱浸泡洗:开启碱清洗进液阀,开启碱清洗出液阀,再开启碱清洗水泵,膜池药液达到LL液位时停止进药,关闭碱清洗水泵,再关闭碱清洗进液阀和碱清洗出液阀,碱浸泡达到设定时间后,若该药液重复利用次数未到设定次数,开启药液回流阀,再开启碱液回流阀和碱清洗进液阀,药液回流进入碱清洗水池,待药液回流完成,关闭药液回流阀、碱液回流阀和碱清洗进液阀,碱浸泡程序完成,进入膜池漂洗及管道冲洗程序;若该药液重复利用次数达到设定次数,开启废液排放阀,该药液排入中和池,待排空完成后,再关闭废液排放阀,碱浸泡程序完成,进入膜池漂洗及管道冲洗程序。Or alkali immersion washing: open the alkali cleaning liquid inlet valve, open the alkali cleaning liquid outlet valve, and then open the alkali cleaning water pump. When the membrane tank liquid reaches the LL level, stop feeding, close the alkali cleaning water pump, and then close the alkali cleaning liquid inlet valve. and alkali cleaning liquid outlet valve. After the alkali soaking reaches the set time, if the number of times the chemical liquid is reused has not reached the set number, open the chemical liquid return valve, then open the alkali liquid return valve and alkali cleaning liquid inlet valve, and the chemical liquid will flow back. Enter the alkali cleaning pool. After the liquid reflux is completed, close the liquid reflux valve, alkali reflux valve and alkali cleaning inlet valve. The alkali soaking process is completed, and then enter the membrane tank rinsing and pipeline flushing process; if the chemical liquid is reused for Set the number of times, open the waste liquid discharge valve, and discharge the liquid into the neutralization tank. After the emptying is completed, close the waste liquid discharge valve. The alkali soaking process is completed, and the membrane tank rinsing and pipeline flushing processes are entered.
膜池漂洗及管道冲洗:打开进水闸板阀,当膜池液位达到LL液位时,关闭进水闸板阀,开启清洗循环阀,当清洗为碱洗时,开启碱清洗出液阀,再开启碱清洗水泵,当清洗为酸洗时,开启酸清洗出液阀,再开启酸清洗水泵,膜池内水在膜池、产水管道、药液回流管和进药管之间内循环,对膜池漂洗及管道冲洗,时间约2-10min,然后关闭对应清洗水泵,再关闭清洗循环阀和对应清洗出液阀,开启废液排放阀,漂洗液排入中和池,待膜池排空完成,关闭废液排放阀,此为1次膜池漂洗及管道冲洗过程,然后再重复1次该程序;膜池漂洗及管道冲洗完成后,打开进水闸板阀,当膜池液位达到L液位,膜池进入正常产水状态。Membrane tank rinsing and pipeline flushing: Open the water inlet gate valve. When the membrane tank liquid level reaches the LL level, close the water inlet gate valve and open the cleaning cycle valve. When the cleaning is alkali cleaning, open the alkali cleaning outlet valve, and then Turn on the alkali cleaning water pump. When the cleaning is pickling, open the acid cleaning liquid outlet valve, and then turn on the acid cleaning water pump. The water in the membrane tank will circulate between the membrane tank, water production pipeline, chemical liquid return pipe and chemical inlet pipe. Rinse the membrane tank and flush the pipeline for about 2-10 minutes, then close the corresponding cleaning water pump, then close the cleaning circulation valve and the corresponding cleaning liquid outlet valve, open the waste liquid discharge valve, and discharge the rinse liquid into the neutralization tank until the membrane tank is emptied. After completion, close the waste liquid discharge valve. This is a membrane tank rinsing and pipeline flushing process, and then repeat the process once. After the membrane tank rinsing and pipeline flushing are completed, open the water inlet gate valve. When the membrane tank liquid level reaches L liquid level, the membrane tank enters normal water production state.
膜池漂洗及管道冲洗程序为化学清洗控制程序的附属程序,主要是降低化学清洗药剂在膜池的残留浓度,同时对产水管道、进药管道和药液回流管进行清洗,以保证产水水质。The membrane tank rinsing and pipeline flushing procedures are subsidiary procedures of the chemical cleaning control program. They are mainly to reduce the residual concentration of chemical cleaning agents in the membrane tank, and at the same time clean the water production pipeline, chemical feed pipeline and chemical liquid return pipe to ensure water production. water quality.
进一步的,还包括物理清洗控制程序:超滤膜每产水一定时间进行一次物理清洗,即反洗气洗同时进行,首先超滤膜池进行液位下降过滤,关闭进水闸板阀,膜池继续产水,当膜池液位低于LL液位时,产水泵关闭,产水阀关闭,接着开启反洗阀,再开启反洗泵,同时开启气洗阀,再开启罗茨风机,50-70s关闭反洗泵和罗茨风机,再关闭反洗阀和气洗阀,物理清洗结束,开启进水闸板阀,系统再进入产水状态。达到设定次数物理清洗后,一般设定次数为3-6次,打开废水排放阀,将超滤膜池内反洗废水排入废水排放池,当膜池排空后,关闭废水排放阀,打开进水闸板阀,系统再进入产水程序;Furthermore, it also includes a physical cleaning control program: the ultrafiltration membrane is physically cleaned every time water is produced, that is, backwashing and air washing are performed at the same time. First, the ultrafiltration membrane tank performs liquid level drop filtration, closes the inlet gate valve, and the membrane tank Continue to produce water. When the membrane tank liquid level is lower than the LL level, the produced water pump is closed, the water production valve is closed, then the backwash valve is opened, then the backwash pump is opened, the air wash valve is opened at the same time, and then the Roots blower is opened, 50 -Turn off the backwash pump and Roots blower for 70 seconds, then close the backwash valve and air wash valve. After the physical cleaning is completed, open the water inlet gate valve and the system will enter the water production state again. After reaching the set number of physical cleanings, usually 3-6 times, open the wastewater discharge valve and discharge the backwash wastewater in the ultrafiltration membrane tank into the wastewater discharge tank. When the membrane tank is emptied, close the wastewater discharge valve and open Water inlet gate valve, the system then enters the water production process;
当物理清洗控制程序的反洗废水排空完成后,关闭废水排放阀再启动化学清洗控制程序。When the backwash wastewater of the physical cleaning control program is drained, close the wastewater discharge valve and then start the chemical cleaning control program.
较大的悬浮物、胶体等被截留在超滤膜外侧,当超滤膜外侧杂质累积到一定程度时会影响超滤膜的透水性,可根据水质情况及运行时间设置物理清洗频率,即反洗和气洗同时进行,通过反洗泵将超滤膜出水经过反洗管道送入超滤膜内部,水从超滤膜内部出来,同时曝气风机开启,对超滤膜进行空气擦洗,可以把附着于超滤膜上的部分杂质清洗掉,使超滤膜恢复一定的透水性。Larger suspended solids, colloids, etc. are trapped on the outside of the ultrafiltration membrane. When the impurities on the outside of the ultrafiltration membrane accumulate to a certain extent, it will affect the water permeability of the ultrafiltration membrane. The physical cleaning frequency can be set according to the water quality and operating time, that is, reverse Washing and air washing are performed at the same time. The ultrafiltration membrane effluent is sent into the interior of the ultrafiltration membrane through the backwash pipe through the backwash pump. The water comes out from the inside of the ultrafiltration membrane. At the same time, the aeration fan is turned on to air scrub the ultrafiltration membrane. Some of the impurities attached to the ultrafiltration membrane are washed away to restore a certain degree of water permeability to the ultrafiltration membrane.
进一步的,化学清洗控制程序还包括酸循环洗:开启酸清洗进液阀,开启酸清洗出液阀,再开启酸清洗水泵,膜池药液达到LL液位时,开启清洗循环阀,关闭酸清洗进液阀,开始药液循环洗,酸循环达到设定时间后,关闭酸清洗水泵,再关闭清洗循环阀和酸清洗出液阀,若该药液重复利用次数未到设定次数,开启药液回流阀,再开启酸液回流阀和酸清洗进液阀,药液回流进入酸清洗水池,待药液回流完成,关闭药液回流阀、酸液回流阀和酸清洗进液阀,酸循环程序完成,进入膜池漂洗及管道冲洗程序;若该药液重复利用次数达到设定次数,开启废液排放阀,该药液排入中和池,待排空完成后,再关闭废液排放阀,酸循环程序完成,进入膜池漂洗及管道冲洗程序。Furthermore, the chemical cleaning control program also includes acid cycle cleaning: open the acid cleaning inlet valve, open the acid cleaning outlet valve, and then open the acid cleaning water pump. When the membrane tank liquid reaches the LL level, open the cleaning circulation valve and close the acid. Clean the liquid inlet valve and start chemical liquid circulation washing. After the acid cycle reaches the set time, turn off the acid cleaning water pump, then close the cleaning circulation valve and acid cleaning outlet valve. If the number of times the chemical liquid is reused has not reached the set number, open The chemical liquid reflux valve, then open the acid liquid reflux valve and acid cleaning inlet valve, and the chemical liquid will flow back into the acid cleaning pool. After the chemical liquid reflux is completed, close the chemical liquid reflux valve, acid liquid reflux valve and acid cleaning inlet valve, and the acid will After the cycle program is completed, the membrane tank rinsing and pipeline flushing procedures are entered; if the number of times the chemical liquid is reused reaches the set number, the waste liquid discharge valve is opened and the liquid is discharged into the neutralization tank. After the emptying is completed, the waste liquid is closed. Discharge valve, the acid cycle process is completed, and the membrane tank rinsing and pipeline flushing processes are entered.
碱循环洗:开启碱清洗进液阀,开启碱清洗出液阀,再开启碱清洗水泵,膜池药液达到LL液位时,开启清洗循环阀,关闭碱清洗进液阀,开始药液循环,碱循环达到设定时间后,关闭碱清洗水泵,再关闭清洗循环阀和碱清洗出液阀,若该药液重复利用次数未到设定次数,开启药液回流阀,再开启碱液回流阀和碱清洗进液阀,药液回流进入碱清洗水池,待药液回流完成,关闭药液回流阀、碱液回流阀和碱清洗进液阀,碱循环程序完成,进入膜池漂洗及管道冲洗程序;若该药液重复利用次数达到设定次数,开启废液排放阀,该药液排入中和池,待排空完成后,再关闭废液排放阀,碱循环程序完成,进入膜池漂洗及管道冲洗程序。Alkali cycle cleaning: Open the alkali cleaning liquid inlet valve, open the alkali cleaning liquid outlet valve, and then open the alkali cleaning water pump. When the membrane tank liquid reaches the LL level, open the cleaning cycle valve, close the alkali cleaning liquid inlet valve, and start the liquid circulation. , after the alkali cycle reaches the set time, turn off the alkali cleaning water pump, then close the cleaning cycle valve and the alkali cleaning liquid outlet valve. If the number of reuses of the chemical solution has not reached the set number, open the chemical solution reflux valve, and then open the alkali solution reflux valve and alkali cleaning liquid inlet valve, the chemical liquid refluxes into the alkali cleaning pool. When the chemical liquid reflux is completed, close the chemical liquid reflux valve, alkali liquid reflux valve and alkali cleaning liquid inlet valve. The alkali cycle program is completed, and enters the membrane tank rinsing and pipeline Flushing process; if the number of reuses of the chemical solution reaches the set number, open the waste liquid discharge valve and discharge the chemical liquid into the neutralization tank. After the emptying is completed, close the waste liquid discharge valve and the alkali cycle program is completed and enters the membrane. Pool rinse and pipe flushing procedures.
进一步的,还包括药液配置控制程序:化学清洗药液由药剂原液和超滤产水按一定比例配置而成,药剂原液通过计量泵加入对应化学清洗水池,根据设定流量和所配药剂浓度设置加药时间,化学清洗水池装有碱液液位计、酸液液位计,通过碱液液位计、酸液液位计的测量值判定是否开启补水泵,设定补水液位为2.7m,此液位以下开启补水泵,到达此液位关闭补水泵,化学清洗水池装有碱液温度计、酸液温度计和碱液加热器、酸液加热器,通过温度计的测量值判定是否开启加热器,一般所设化学清洗药剂温度为12-15摄氏度以上,药剂原液罐包括次氯酸钠原液箱、氢氧化钠原液箱、柠檬酸原液箱,药剂原液罐上装有液位计,根据液位测量值可判断是否需补药剂原液,柠檬酸原液箱装有柠檬酸混合搅拌器,可对柠檬酸固体进行搅拌混合,化学清洗液在化学清洗前2h配置,每循环一次药液补充30%药剂原液;以配置酸清洗液为例,开启柠檬酸配药阀,开启柠檬酸计量泵,按设定流量及设定时间往酸清洗池加药,此时开启清洗补水阀,再开启清洗补水泵,往酸清洗池补水,当酸清洗池液位达到补水液位,停止补水,关闭清洗水泵,再关闭清洗补水阀,当柠檬酸原液达到加药时间,关闭柠檬酸计量泵,再关闭柠檬酸配药阀,停止补药,酸清洗液配置完成,当酸液温度计显示温度低于所设温度值时,开启酸液加热器,对所配清洗液进行加热,直至所设温度值。Furthermore, it also includes a chemical liquid configuration control program: the chemical cleaning liquid is composed of the chemical liquid and the ultrafiltration produced water in a certain proportion. The chemical liquid is added to the corresponding chemical cleaning pool through a metering pump, and the chemical cleaning liquid is added according to the set flow rate and the concentration of the prepared chemical. Set the dosing time. The chemical cleaning pool is equipped with an alkali liquid level gauge and an acid liquid level gauge. Use the measured values of the alkali liquid level gauge and acid liquid level gauge to determine whether to turn on the water replenishment pump. Set the water replenishment level to 2.7 m, the water replenishment pump is turned on below this liquid level, and the water replenishment pump is turned off when it reaches this liquid level. The chemical cleaning pool is equipped with an alkali liquid thermometer, an acid liquid thermometer, an alkali liquid heater, and an acid liquid heater. The measurement value of the thermometer is used to determine whether to turn on the heating. The chemical cleaning agent is generally set at a temperature of 12-15 degrees Celsius or above. The agent stock solution tank includes a sodium hypochlorite stock solution tank, a sodium hydroxide stock solution tank, and a citric acid stock solution tank. The agent stock solution tank is equipped with a liquid level gauge. According to the liquid level measurement value, To determine whether it is necessary to replenish the pharmaceutical stock solution, the citric acid stock solution tank is equipped with a citric acid mixing agitator, which can stir and mix the citric acid solid. The chemical cleaning solution is prepared 2 hours before chemical cleaning, and 30% of the pharmaceutical stock solution is replenished in each cycle; Taking the acid cleaning solution as an example, open the citric acid dispensing valve, turn on the citric acid metering pump, add medicine to the acid cleaning pool according to the set flow rate and set time, then open the cleaning and replenishing valve, then open the cleaning and replenishing pump, and add acid to the cleaning tank. When the acid cleaning pool liquid level reaches the water replenishment level, stop replenishing water, close the cleaning water pump, and then close the cleaning water replenishment valve. When the citric acid stock solution reaches the dosing time, close the citric acid metering pump, then close the citric acid dispensing valve, and stop After the tonic and acid cleaning liquid preparation is completed, when the acid liquid thermometer shows that the temperature is lower than the set temperature value, turn on the acid liquid heater to heat the prepared cleaning liquid until the set temperature value.
进一步的,还包括药液中和控制程序:中和池装有pH计和ORP计,可检测其废液酸碱度与氧化还原性,通过其测量值判定是否开启计量泵,当pH值低于设定值6时,开启氢氧化钠加药泵,当pH高于设定值9时,开启酸加药泵,当ORP值高于设定氧化还原电位值400mv时,开启还原剂SBS加药泵,中和池装有管道混合器,可以将药液进行充分混合反应,直到中和池废液达到排放要求,停止加药,中和控制程序完成,进入废液排放控制程序。Furthermore, it also includes a liquid neutralization control program: the neutralization tank is equipped with a pH meter and an ORP meter, which can detect the pH and redox properties of the waste liquid, and determine whether to turn on the metering pump based on its measured values. When the pH value is lower than the set value, When the set value is 6, the sodium hydroxide dosing pump is turned on. When the pH is higher than the set value of 9, the acid dosing pump is turned on. When the ORP value is 400mv higher than the set redox potential value, the reducing agent SBS dosing pump is turned on. , the neutralization tank is equipped with a pipeline mixer, which can fully mix the chemical liquid until the waste liquid in the neutralization tank reaches the discharge requirements, stop dosing, the neutralization control program is completed, and the waste liquid discharge control program is entered.
进一步的,还包括废液排放控制程序:废水池和中和池装有废水池液位计、中和池液位计,通过液位计的测量值判定是否开启中和池排放泵和废水池排放泵,为保证中和池和废水池足够的预留空间,一般液位达到1m时就开启排放泵进行排放。Further, it also includes waste liquid discharge control procedures: the waste pool and neutralization pool are equipped with waste pool level gauges and neutralization pool level gauges. The measurement values of the level gauges are used to determine whether to open the neutralization pool discharge pump and the waste pool. Discharge pump, in order to ensure enough reserved space for the neutralization tank and wastewater pool, the discharge pump is generally turned on for discharge when the liquid level reaches 1m.
进一步的,本自动控制系统化学清洗根据清洗药剂分为酸洗和碱洗,酸洗药剂为盐酸或柠檬酸,主要去除附着于超滤膜上的无机物,碱洗药剂为次氯酸钠和氢氧化钠,主要去除附着于超滤膜上的有机物;根据清洗周期分为维护性清洗和恢复性清洗,维护性清洗周期较短,一般设定为1-30天一次,清洗药剂浓度较低,酸浓度一般为0.1%-0.5%,碱浓度一般为0.1-0.5%,清洗时间较短,一般为20-120分钟,主要维持超滤膜透水性,恢复性清洗周期较长,一般设定为3-12月一次,清洗药剂浓度较高,酸浓度一般为0.5%-2%,碱浓度一般为0.5-2%,清洗时间较长,一般为4-24小时,主要使超滤膜恢复最佳透水性,药剂浓度、清洗周期及时间具体需根据水质而定;根据清洗方式分为浸泡清洗和循环清洗,浸泡清洗为清洗药液对超滤膜进行纯浸泡,清洗药液不透过超滤膜,运行成本较低,循环清洗为清洗药液透过超滤膜再回到膜池,进行内循环,清洗效果较好。Furthermore, the chemical cleaning of this automatic control system is divided into pickling and alkali cleaning according to the cleaning reagents. The pickling reagent is hydrochloric acid or citric acid, which mainly removes inorganic substances attached to the ultrafiltration membrane. The alkali cleaning reagents are sodium hypochlorite and sodium hydroxide. , mainly removes organic matter attached to the ultrafiltration membrane; according to the cleaning cycle, it is divided into maintenance cleaning and restorative cleaning. The maintenance cleaning cycle is shorter and is generally set to once every 1-30 days. The cleaning agent concentration is low and the acid concentration is low. Generally, it is 0.1%-0.5%. The alkali concentration is generally 0.1-0.5%. The cleaning time is short, usually 20-120 minutes. It mainly maintains the water permeability of the ultrafiltration membrane. The restorative cleaning cycle is longer, generally set to 3- Once every 12 months, the cleaning agent concentration is relatively high, the acid concentration is generally 0.5%-2%, the alkali concentration is generally 0.5-2%, and the cleaning time is longer, generally 4-24 hours, mainly to restore the optimal water permeability of the ultrafiltration membrane. The chemical concentration, cleaning cycle and time need to be determined according to the water quality; according to the cleaning method, it is divided into immersion cleaning and cycle cleaning. Immersion cleaning is a pure soaking of the ultrafiltration membrane in the cleaning liquid, and the cleaning liquid does not penetrate the ultrafiltration membrane. , the operating cost is low, and the cyclic cleaning is that the cleaning solution passes through the ultrafiltration membrane and then returns to the membrane tank for internal circulation, and the cleaning effect is better.
进一步的,本自动控制系统化学清洗药剂使用循环重复利用程序,极大程度节约运行成本,每次新配化学清洗药剂可循环重复利用多次,一般设定为2-6次,具体根据现场清洗效果设定。Furthermore, the chemical cleaning agent of this automatic control system uses a recycling and reuse program, which greatly saves operating costs. Each new chemical cleaning agent can be recycled and reused multiple times. It is generally set to 2-6 times, depending on the on-site cleaning. Effect settings.
进一步的,本自动控制系统采用PLC控制技术,采用电缆连接,以计算机为操作终端,可在系统操作界面上查看系统各部分工况,超滤产水、物理清洗、化学清洗、药液配置、药液中和、废液排放等环节的诸多参数可以由操作人员设置;本自动控制系统设有自动控制及手动控制两种模式,自动控制下系统按预设参数自动运行,手动控制下可对各环节进行控制、调整。Furthermore, this automatic control system adopts PLC control technology, uses cable connection, and uses a computer as the operating terminal. The working conditions of each part of the system, including ultrafiltration water production, physical cleaning, chemical cleaning, liquid preparation, etc., can be viewed on the system operation interface. Many parameters of chemical liquid neutralization, waste liquid discharge and other aspects can be set by the operator; this automatic control system has two modes: automatic control and manual control. Under automatic control, the system automatically operates according to preset parameters, and under manual control it can Control and adjust every link.
超滤产水控制程序控制进水并透过超滤膜进行出水,包括进水渠、进水闸板阀、超滤膜池、产水泵、流量计、液位计等;进水渠设置温度计、液位计、浊度仪,超滤膜池进口处设置电动闸板阀,超滤膜池内部装有静压液位计;超滤膜池产水管道装有压力表、浊度仪等。The ultrafiltration water production control program controls the water inlet and outlet through the ultrafiltration membrane, including water inlet channel, water inlet gate valve, ultrafiltration membrane tank, water production pump, flow meter, liquid level meter, etc.; the water inlet channel is equipped with a thermometer and liquid level Gauge and turbidity meter, an electric gate valve is installed at the inlet of the ultrafiltration membrane tank, and a static pressure level gauge is installed inside the ultrafiltration membrane tank; the water production pipeline of the ultrafiltration membrane tank is equipped with a pressure gauge, turbidity meter, etc.
物理清洗控制程序控制超滤膜进行反洗和气洗,包括罗茨风机、反洗水泵等。The physical cleaning control program controls the ultrafiltration membrane to perform backwashing and air washing, including Roots blower, backwash pump, etc.
化学清洗控制程序控制超滤膜进行酸洗、碱洗和药液循环,包括超滤膜池、化学清洗池、清洗水泵、液位计等;超滤膜池连接有酸清洗水泵、碱清洗水泵、药液回流阀;药液回流阀后分别通过酸液回流阀、碱液回流阀连通酸液进药阀、碱液进药阀;超滤膜池产水管道连接有清洗循环管道,并设有清洗循环阀。The chemical cleaning control program controls the ultrafiltration membrane to perform pickling, alkali cleaning and liquid circulation, including ultrafiltration membrane pool, chemical cleaning pool, cleaning water pump, liquid level gauge, etc.; the ultrafiltration membrane pool is connected to an acid cleaning water pump and an alkali cleaning water pump. , liquid medicine reflux valve; after the medicine liquid reflux valve, it is connected to the acid liquid feed valve and alkali liquid feed valve respectively through the acid liquid reflux valve and the alkali liquid reflux valve; the ultrafiltration membrane tank water production pipeline is connected to a cleaning circulation pipe, and is equipped with There is a cleaning cycle valve.
药液配制控制程序控制清洗药液用量和浓度,包括药剂原液罐、计量泵、流量计、化学清洗池、化学清洗泵、补水泵、液位计等。The chemical liquid preparation control program controls the dosage and concentration of the cleaning liquid, including chemical liquid tanks, metering pumps, flow meters, chemical cleaning pools, chemical cleaning pumps, water replenishment pumps, liquid level gauges, etc.
药液中和控制程序控制中和池废液的酸碱度和氧化还原性,包括中和池、pH计、ORP计、药剂原液罐、计量泵等;药剂原液罐包括次氯酸钠原液箱、氢氧化钠原液箱、柠檬酸原液箱,药剂原液罐上装有液位计;柠檬酸原液箱装有柠檬酸混合搅拌器;中和池装有管道混合器。The liquid neutralization control program controls the pH and redox properties of the waste liquid in the neutralization tank, including the neutralization tank, pH meter, ORP meter, pharmaceutical stock solution tank, metering pump, etc.; the pharmaceutical stock liquid tank includes a sodium hypochlorite stock solution tank and a sodium hydroxide stock solution. Box, citric acid stock solution tank, the pharmaceutical stock solution tank is equipped with a liquid level gauge; the citric acid stock solution tank is equipped with a citric acid mixing agitator; the neutralization tank is equipped with a pipeline mixer.
废液排放控制程序控制废水池和中和池的液体排放,包括中和池液位计、中和池排放泵、废水池液位计、废水池排放泵等。The waste liquid discharge control program controls the liquid discharge from the waste pool and neutralization pool, including neutralization pool level gauge, neutralization pool discharge pump, waste pool level gauge, waste pool discharge pump, etc.
本发明所提供的一种浸没式超滤膜高效自动控制方法,其主要的优点在于:The main advantages of the high-efficiency automatic control method for immersed ultrafiltration membranes provided by the present invention are:
第一,提供的自动控制方法以满足实际工程应用为目的,是在长期的实际应用过程中对各环节进行修改完善,最终得到的具有全系统一键式操作、各环节有自动及手动两档可选、具体参数可随时调整等鲜明优点的浸没式超滤膜全程高效自动化控制系统。First, the automatic control method provided is designed to meet actual engineering applications. Each link is modified and improved during the long-term practical application process. The final result is a one-button operation for the entire system, and each link has automatic and manual gears. It is a fully efficient automated control system for immersed ultrafiltration membranes that has the distinct advantages of being optional and specific parameters can be adjusted at any time.
第二,经本系统处理得到的水量回收率高,水质稳定,超滤膜运行使用寿命长,化学清洗药剂循环重复利用率高,系统运行成本大大降低低,且该系统自动化程度高,能够提高浸没式超滤膜系统的处理效率和安全性、节省人力。Second, the water recovery rate processed by this system is high, the water quality is stable, the ultrafiltration membrane has a long service life, the chemical cleaning agent has a high recycling rate, the system operating cost is greatly reduced, and the system is highly automated and can improve The immersed ultrafiltration membrane system has high processing efficiency, safety and labor saving.
第三,本系统全程对超滤膜运行跨膜压差实时检测,并设有临界报警装置,能及时有效的对超滤膜进行物理及化学清洗,以保证其最佳透水性,能有效延长超滤膜的使用寿命。Third, this system detects the transmembrane pressure difference in real time during the entire operation of the ultrafiltration membrane, and is equipped with a critical alarm device. It can perform physical and chemical cleaning of the ultrafiltration membrane in a timely and effective manner to ensure its optimal water permeability and effectively prolong the life of the ultrafiltration membrane. The service life of ultrafiltration membrane.
第四,本系统化学清洗药液采用循环重复利用程序,系统产水回收率高,运行成本低。Fourth, the chemical cleaning liquid in this system adopts a recycling and reuse procedure, which results in a high system water recovery rate and low operating costs.
附图说明Description of the drawings
图1为本发明的浸没式超滤膜的高效自动控制方法工艺流程图一。Figure 1 is a process flow chart 1 of the efficient automatic control method of the immersed ultrafiltration membrane of the present invention.
图2为本发明的浸没式超滤膜的高效自动控制方法工艺流程图二。Figure 2 is the second process flow chart of the efficient automatic control method of the immersed ultrafiltration membrane of the present invention.
图3为本发明的浸没式超滤膜的高效自动控制方法化学清洗工艺流程图。Figure 3 is a flow chart of the chemical cleaning process of the high-efficiency automatic control method of the immersed ultrafiltration membrane of the present invention.
图4为本发明的浸没式超滤膜的高效自动控制方法废液排放工艺流程图。Figure 4 is a flow chart of the waste liquid discharge process of the high-efficiency automatic control method of the immersed ultrafiltration membrane of the present invention.
图中,1-温度计,2-液位计,3-进水浊度仪,4-出水浊度仪,5-反洗泵,6-清洗补水泵,7-进水闸板阀,8-进气阀,9-清洗进药阀,10-静压液位计,11-真空射流器,12-压力表,13-反洗阀,14-清洗循环阀,15-产水阀,16-超滤产水泵,17-药液回流阀,18-废水排放阀,19-废液排放阀,20-次氯酸钠原药液位计,21-次氯酸钠原液箱,22-氢氧化钠原药液位计,23-氢氧化钠原液箱,24-柠檬酸原药液位计,25-柠檬酸原液箱,26-柠檬酸混合搅拌器,27-碱液补水阀,28-氢氧化钠配药阀,29-碱液液位计,30-碱液温度计,31-碱液加热器,32-碱液排空阀,33-碱清洗进液阀,34-碱液回流阀,35-碱清洗水泵,36-次氯酸钠计量泵,37-碱液混合阀,38-碱清洗出液阀,39-氢氧化钠中和阀,40-柠檬酸配药阀,41-酸液补水阀,42-酸液液位计,43-酸液温度计,44-酸液加热器,45-酸液排空阀,46-酸液中和阀,47-酸清洗进液阀,48-酸液回流阀,49-酸清洗水泵,50-氢氧化钠计量泵,51-酸液混合阀,52-酸清洗出液阀,53-柠檬酸计量泵,54-PH计,55-中和池液位计,56-ORP计,57-中和池排放泵,58-废水池液位计,59-废水池排放泵。In the picture, 1-thermometer, 2-liquid level gauge, 3-inlet water turbidity meter, 4-outlet water turbidity meter, 5-backwash pump, 6-cleaning water pump, 7-inlet gate valve, 8-inlet Air valve, 9-cleaning medicine inlet valve, 10-static liquid level gauge, 11-vacuum ejector, 12-pressure gauge, 13-backwash valve, 14-cleaning cycle valve, 15-water production valve, 16-super Filter product water pump, 17-chemical liquid return valve, 18-waste water discharge valve, 19-waste liquid discharge valve, 20-sodium hypochlorite original drug liquid level gauge, 21-sodium hypochlorite original liquid level meter, 22-sodium hydroxide original drug liquid level gauge, 23-Sodium hydroxide original solution tank, 24-Citric acid original drug liquid level gauge, 25-Citric acid original solution tank, 26-Citric acid mixing stirrer, 27-Alkali liquid replenishment valve, 28-Sodium hydroxide dispensing valve, 29- Alkali liquid level gauge, 30-lye thermometer, 31-lye heater, 32-lye drain valve, 33-alkali cleaning inlet valve, 34-lye return valve, 35-alkali cleaning water pump, 36- Sodium hypochlorite metering pump, 37-alkali mixing valve, 38-alkali cleaning outlet valve, 39-sodium hydroxide neutralization valve, 40-citric acid dispensing valve, 41-acid replenishing valve, 42-acid level gauge, 43-acid thermometer, 44-acid heater, 45-acid drain valve, 46-acid neutralization valve, 47-acid cleaning inlet valve, 48-acid reflux valve, 49-acid cleaning water pump, 50-sodium hydroxide metering pump, 51-acid mixing valve, 52-acid cleaning outlet valve, 53-citric acid metering pump, 54-PH meter, 55-neutralization tank level meter, 56-ORP meter, 57 -Neutralization pool discharge pump, 58-Wastewater pool liquid level gauge, 59-Wastewater pool discharge pump.
具体实施方式Detailed ways
为了便于本领域技术人员的理解,下面结合实施例与附图对本发明作进一步的说明。In order to facilitate the understanding of those skilled in the art, the present invention will be further described below in conjunction with the embodiments and drawings.
如图1~4所示,其为本浸没式超滤膜的高效自动控制方法及系统的主要工艺流程图。该工艺路线为:As shown in Figures 1 to 4, they are the main process flow charts of the efficient automatic control method and system of this immersed ultrafiltration membrane. The process route is:
Ⅰ超滤产水控制程序ⅠUltrafiltration water production control program
超滤膜池进水从进水渠流入,进水渠设置温度计1、液位计2、进水浊度仪3、出水浊度仪4,分别对进水水质水量进行检测,可通过分析其测量出的进水温度值、液位值和浊度值对膜池产水流量进行相应设定,当温度值低于15℃时,将膜池产水流量下调至设计流量的80%,当高于15℃时,为设计流量,当液位值在2m时,上调膜池产水流量,低于2m时,下调产水流量,当浊度高于5NTU时,下调产水流量,当浊度低于5NTU时上调产水流量。超滤膜池进口处设置电动闸板阀7,通过PLC自动控制闸板阀开度从而调节超滤膜池进水流量,超滤膜池内部装有静压液位计10,通过静压液位计10的测量值判断是否开启产水泵16和是否开启进水闸板阀7,当膜池液位低于L液位时,进水闸板阀7开启,当膜池液位高于H液位时,进水闸板阀7关闭,当膜池液位高于L液位时,真空射流器11开启,约10-30s关闭,然后产水阀15开启,接着产水泵16开启,系统开始产水,当膜池液位低于LL液位时,产水泵16关闭,产水阀15关闭,产水程序结束,当正常运行时,产水时间按固定周期设定,一般为20-50分钟,到达设定周期产水停止。The incoming water of the ultrafiltration membrane pool flows in from the inlet canal. The inlet canal is equipped with a thermometer 1, a liquid level meter 2, an inlet water turbidity meter 3, and an outlet water turbidity meter 4. The quality and quantity of the incoming water are tested respectively, and the measured values can be measured by analyzing them. The inlet water temperature, liquid level and turbidity values are used to set the membrane tank water flow rate accordingly. When the temperature value is lower than 15°C, the membrane tank water flow rate is reduced to 80% of the design flow rate. When it is higher than At 15℃, it is the design flow rate. When the liquid level is 2m, increase the water flow rate of the membrane tank. When it is lower than 2m, adjust the water flow rate downward. When the turbidity is higher than 5NTU, adjust the water flow rate downward. When the turbidity is low, Increase the water production flow rate at 5NTU. An electric gate valve 7 is installed at the inlet of the ultrafiltration membrane tank. The opening of the gate valve is automatically controlled by PLC to adjust the inlet water flow of the ultrafiltration membrane tank. A hydrostatic liquid level gauge 10 is installed inside the ultrafiltration membrane tank. Through the static pressure liquid The measurement value of the level meter 10 determines whether to open the produced water pump 16 and whether to open the water inlet gate valve 7. When the membrane tank liquid level is lower than the L level, the water inlet gate valve 7 is opened. When the membrane tank liquid level is higher than the H liquid level, the water inlet gate valve 7 is opened. When the water inlet gate valve 7 is closed, when the membrane tank liquid level is higher than the L level, the vacuum ejector 11 is opened and closed for about 10-30 seconds, then the water production valve 15 is opened, and then the water production pump 16 is opened, and the system starts to produce water. , when the membrane tank liquid level is lower than the LL liquid level, the water production pump 16 is closed, the water production valve 15 is closed, and the water production program ends. During normal operation, the water production time is set according to a fixed period, usually 20-50 minutes. Water production stops when the set cycle is reached.
Ⅱ物理清洗控制程序ⅡPhysical cleaning control program
超滤膜每产水一定时间进行一次物理清洗,一般为20-50分钟,即反洗气洗同时进行,首先超滤膜池进行液位下降过滤,关闭进水闸板阀7,膜池继续产水,当膜池液位低于LL液位时,产水泵16关闭,产水阀15关闭,接着开启反洗阀13,再开启反洗泵5,同时开启气洗阀8,再开启罗茨风机,约60s关闭反洗泵5和罗茨风机,再关闭反洗阀13和气洗阀8,物理清洗结束,开启进水闸板阀7,系统再进入产水状态,每进行若干次物理清洗后,具体需根据水质而定,一般为3-6次,超滤膜池内反洗废水需进行排空,即打开废水排放阀18,排入废水排放池,当膜池排空后,关闭废水排放阀18,打开进水闸板阀7,系统再进入产水程序。The ultrafiltration membrane is physically cleaned every time water is produced, usually 20-50 minutes, that is, backwashing and air washing are performed at the same time. First, the ultrafiltration membrane tank is filtered with the liquid level falling, and the water inlet gate valve 7 is closed. The membrane tank continues to produce water. Water, when the liquid level of the membrane tank is lower than the LL level, the produced water pump 16 is closed, the produced water valve 15 is closed, then the backwash valve 13 is opened, then the backwash pump 5 is opened, and the air wash valve 8 is opened at the same time, and then the roots are opened fan, turn off the backwash pump 5 and the Roots blower for about 60 seconds, then close the backwash valve 13 and the air wash valve 8. After the physical cleaning is completed, open the water inlet gate valve 7, and the system will enter the water production state again. After each physical cleaning, The specific time depends on the water quality, usually 3-6 times. The backwash wastewater in the ultrafiltration membrane tank needs to be emptied, that is, open the wastewater discharge valve 18 and discharge it into the wastewater discharge tank. When the membrane tank is emptied, close the wastewater discharge. Valve 18, open the water inlet gate valve 7, and then the system enters the water production process.
Ⅲ化学清洗控制程序ⅢChemical cleaning control program
超滤膜池出水管道装有压力表12,其压力表12测量值可与静压液位计10测量值计算超滤膜跨膜压差,该值反映超滤膜透水性强弱,能够判定超滤膜是否需进行化学清洗,根据现场调试,可设定维护性清洗和恢复性清洗的固定周期,跨膜压差值做为超滤膜清洗参考值和保护值。当进行化学清洗时,根据清洗药剂的种类和清洗方式,会有不同的实施程序,以下分别说明:The outlet pipe of the ultrafiltration membrane pool is equipped with a pressure gauge 12. The measurement value of the pressure gauge 12 can be used with the measurement value of the hydrostatic level gauge 10 to calculate the transmembrane pressure difference of the ultrafiltration membrane. This value reflects the water permeability of the ultrafiltration membrane and can be used to determine Whether the ultrafiltration membrane needs chemical cleaning, according to on-site debugging, the fixed cycle of maintenance cleaning and restorative cleaning can be set, and the transmembrane pressure difference value is used as the ultrafiltration membrane cleaning reference value and protection value. When performing chemical cleaning, there will be different implementation procedures depending on the type of cleaning agent and cleaning method, which are explained below:
①酸浸泡洗:反洗废水排空完成后,关闭废水排放阀18,开启酸清洗进液阀47,开启酸清洗出液阀52,再开启酸清洗水泵49,膜池药液达到LL液位时停止进药,关闭酸清洗水泵49,再关闭酸清洗进液阀47和酸清洗出液阀52,酸浸泡达到设定时间后,若该药液重复利用次数未到设定次数,开启药液回流阀17,再开启酸液回流阀48和酸清洗进液阀47,药液回流进入酸清洗水池,待药液回流完成,关闭阀门药液回流阀17、酸液回流阀48和酸清洗进液阀47,酸浸泡程序完成,进入膜池漂洗及管道冲洗程序;若该药液重复利用次数达到设定次数,开启排放阀19,该药液排入中和池,待排空完成后,再关闭排放阀19,酸浸泡程序完成,进入膜池漂洗及管道冲洗程序。① Acid soaking: After the backwash wastewater is drained, close the wastewater discharge valve 18, open the acid cleaning inlet valve 47, open the acid cleaning outlet valve 52, and then open the acid cleaning water pump 49. The membrane tank solution reaches the LL level. Stop feeding, turn off the acid cleaning water pump 49, then close the acid cleaning liquid inlet valve 47 and the acid cleaning liquid outlet valve 52. After the acid soaking reaches the set time, if the number of times the chemical liquid is reused has not reached the set number, open the chemical solution. Liquid reflux valve 17, then open the acid liquid reflux valve 48 and acid cleaning liquid inlet valve 47. The chemical liquid will flow back into the acid cleaning pool. When the chemical liquid reflux is completed, close the valves, the chemical liquid reflux valve 17, the acid liquid reflux valve 48 and the acid cleaning tank. Inlet valve 47, after the acid soaking process is completed, enter the membrane tank rinsing and pipeline flushing process; if the number of reuses of the chemical solution reaches the set number, open the discharge valve 19, and the chemical solution will be discharged into the neutralization tank until the emptying is completed. , then close the discharge valve 19, the acid soaking procedure is completed, and the membrane tank rinsing and pipeline flushing procedures are entered.
②酸循环洗:反洗废水排空完成后,关闭废水排放阀18,开启酸清洗进液阀47,开启酸清洗出液阀52,再开启酸清洗水泵49,膜池药液达到LL液位时,开启循环阀14,关闭酸清洗进液阀47,开始药液循环洗,酸循环达到设定时间后,关闭酸清洗水泵49,再关闭循环阀14和酸清洗出液阀52,若该药液重复利用次数未到设定次数,开启药液回流阀17,再开启酸液回流阀48和酸清洗进液阀47,药液回流进入酸清洗水池,待药液回流完成,关闭药液回流阀17、酸液回流阀48和酸清洗进液阀47,酸循环程序完成,进入膜池漂洗及管道冲洗程序;若该药液重复利用次数达到设定次数,开启排放阀19,该药液排入中和池,待排空完成后,再关闭排放阀19,酸循环程序完成,进入膜池漂洗及管道冲洗程序。② Acid cycle washing: After the backwash wastewater is drained, close the wastewater discharge valve 18, open the acid cleaning inlet valve 47, open the acid cleaning outlet valve 52, and then open the acid cleaning water pump 49. The membrane tank solution reaches the LL level. When If the number of reuses of the chemical solution has not reached the set number, open the chemical solution return valve 17, then open the acid solution return valve 48 and the acid cleaning liquid inlet valve 47. The chemical solution will flow back into the acid cleaning pool. When the chemical solution reflux is completed, close the chemical solution. Return valve 17, acid return valve 48 and acid cleaning liquid inlet valve 47, the acid cycle program is completed, and the membrane tank rinsing and pipeline flushing program is entered; if the number of reuses of the chemical solution reaches the set number, the discharge valve 19 is opened, and the chemical solution is The liquid is discharged into the neutralization tank. After the emptying is completed, the discharge valve 19 is closed, the acid cycle program is completed, and the membrane tank rinsing and pipeline flushing procedures are entered.
③碱浸泡洗:反洗废水排空完成后,关闭废水排放阀18,开启碱清洗进液阀33,开启碱清洗出液阀38,再开启碱清洗水泵35,膜池药液达到LL液位时停止进药,关闭碱清洗水泵35,再关闭碱清洗进液阀33和碱清洗出液阀38,碱浸泡达到设定时间后,若该药液重复利用次数未到设定次数,开启药液回流阀17,再开启碱液回流阀34和碱清洗进液阀33,药液回流进入碱清洗水池,待药液回流完成,关闭药液回流阀17、碱液回流阀34和碱清洗进液阀33,碱浸泡程序完成,进入漂洗程序;若该药液重复利用次数达到设定次数,开启排放阀19,该药液排入中和池,待排空完成后,再关闭排放阀19,碱浸泡程序完成,进入膜池漂洗及管道冲洗程序。③Alkali soaking wash: After the backwash wastewater is drained, close the wastewater discharge valve 18, open the alkali cleaning inlet valve 33, open the alkali cleaning outlet valve 38, and then open the alkali cleaning water pump 35, until the membrane tank liquid reaches the LL level Stop feeding the medicine, close the alkali cleaning water pump 35, and then close the alkali cleaning inlet valve 33 and the alkali cleaning outlet valve 38. After the alkali soaking reaches the set time, if the number of times the chemical liquid is reused has not reached the set number, open the medicine. Liquid reflux valve 17, then open the alkali liquid reflux valve 34 and alkali cleaning liquid inlet valve 33, and the chemical liquid will flow back into the alkali cleaning pool. After the liquid reflux is completed, close the chemical liquid reflux valve 17, alkali liquid reflux valve 34 and alkali cleaning inlet valve. Liquid valve 33, the alkali soaking process is completed, and the rinsing process is entered; if the number of times the chemical liquid is reused reaches the set number, the discharge valve 19 is opened, and the chemical liquid is discharged into the neutralization tank. After the emptying is completed, the discharge valve 19 is closed. , the alkali soaking procedure is completed, and the membrane tank rinsing and pipeline flushing procedures are entered.
④碱循环洗:反洗废水排空完成后,关闭废水排放阀18,开启碱清洗进液阀33,开启碱清洗出液阀38,再开启碱清洗水泵35,膜池药液达到LL液位时,开启循环阀14,关闭碱清洗进液阀33,开始药液循环,碱循环达到设定时间后,关闭碱清洗水泵35,再关闭循环阀14和碱清洗出液阀38,若该药液重复利用次数未到设定次数,开启药液回流阀17,再开启碱液回流阀34和碱清洗进液阀33,药液回流进入碱清洗水池,待药液回流完成,关闭阀门药液回流阀17、碱液回流阀34和碱清洗进液阀33,碱循环程序完成,进入漂洗程序;若该药液重复利用次数达到设定次数,开启排放阀19,该药液排入中和池,待排空完成后,再关闭排放阀19,碱循环程序完成,进入膜池漂洗及管道冲洗程序。④Alkali cycle washing: After the backwash wastewater is drained, close the wastewater discharge valve 18, open the alkali cleaning inlet valve 33, open the alkali cleaning outlet valve 38, and then open the alkali cleaning water pump 35, until the membrane tank liquid reaches the LL level When, open the circulation valve 14, close the alkali cleaning liquid inlet valve 33, and start the liquid circulation. After the alkali circulation reaches the set time, close the alkali cleaning water pump 35, then close the circulation valve 14 and the alkali cleaning liquid outlet valve 38. If the drug If the number of liquid reuses has not reached the set number, open the liquid medicine return valve 17, then open the alkali liquid return valve 34 and the alkali cleaning liquid inlet valve 33. The medicine liquid will flow back into the alkali cleaning pool. When the medicine liquid reflux is completed, close the valve medicine liquid. Return valve 17, alkali liquid return valve 34 and alkali cleaning liquid inlet valve 33, the alkali cycle program is completed and the rinsing program is entered; if the number of times the chemical liquid is reused reaches the set number, the discharge valve 19 is opened, and the chemical liquid is discharged into the neutralizer After the emptying is completed, the discharge valve 19 is closed, the alkali circulation program is completed, and the membrane tank rinsing and pipeline flushing procedures are entered.
膜池漂洗及管道冲洗:打开进水闸板阀7,当膜池液位达到LL液位时,关闭进水闸板阀7,开启循环阀14,开启碱清洗出液阀38(碱清洗后)或酸清洗出液阀52(酸清洗后),再开启碱清洗水泵35(碱清洗后)或酸清洗水泵49(酸清洗后),膜池内水在膜池、产水管道、药液回流管和进药管之间内循环,对膜池漂洗及管道冲洗,时间约2-10min,然后关闭对应清洗水泵,再关闭循环阀和对应清洗进出液阀,开启排放阀19,废液排入中和池,待膜池排空完成,关闭排放阀19,重复以上操作1次,进行2次膜池漂洗及管道冲洗过程;膜池漂洗及管道冲洗完成后,打开进水闸板阀7,当膜池液位达到L液位,膜池进入超滤产水程序。Membrane tank rinsing and pipeline flushing: Open the inlet gate valve 7. When the membrane tank liquid level reaches the LL level, close the inlet gate valve 7, open the circulation valve 14, and open the alkali cleaning outlet valve 38 (after alkali cleaning) or Acid clean the liquid outlet valve 52 (after acid cleaning), and then open the alkali cleaning water pump 35 (after alkali cleaning) or the acid cleaning water pump 49 (after acid cleaning). The water in the membrane tank will circulate in the membrane tank, water production pipeline, chemical liquid return pipe and Internal circulation between the inlet pipes, rinsing the membrane pool and pipelines, the time is about 2-10 minutes, then close the corresponding cleaning water pump, then close the circulation valve and the corresponding cleaning inlet and outlet valve, open the discharge valve 19, and discharge the waste liquid into the neutralizer After the membrane tank is emptied, close the discharge valve 19, repeat the above operation once, and perform the membrane tank rinsing and pipeline flushing process twice; after the membrane tank rinsing and pipeline flushing are completed, open the water inlet gate valve 7, when the membrane tank When the liquid level reaches the L level, the membrane tank enters the ultrafiltration water production process.
膜池漂洗及管道冲洗程序为化学清洗控制程序的附属程序,主要是降低化学清洗药剂在膜池的残留浓度,同时对产水管道、进药管道和药液回流管进行清洗,以保证产水水质。The membrane tank rinsing and pipeline flushing procedures are subsidiary procedures of the chemical cleaning control program. They are mainly to reduce the residual concentration of chemical cleaning agents in the membrane tank, and at the same time clean the water production pipeline, chemical feed pipeline and chemical liquid return pipe to ensure water production. water quality.
Ⅳ药液配置控制程序ⅣMedicine liquid configuration control program
化学清洗药液由药剂原液和超滤产水按一定比例配置而成,药剂原液通过计量泵加入化学清洗水池,计量泵包括:次氯酸钠计量泵36,氢氧化钠计量泵50或柠檬酸计量泵53。The chemical cleaning solution is composed of the original chemical solution and the ultrafiltration produced water in a certain proportion. The original chemical solution is added to the chemical cleaning pool through a metering pump. The metering pumps include: sodium hypochlorite metering pump 36, sodium hydroxide metering pump 50 or citric acid metering pump 53 .
根据设定流量和所配药剂浓度设置加药时间,化学清洗水池装有液位计29、42,通过液位计29、42的测量值判定是否开启补水泵6,化学清洗水池装有温度计30、43和加热器31、44,通过温度计的测量值判定是否开启加热器,一般所设化学清洗药剂温度为12-15摄氏度以上,药剂原液罐21、23、25装有液位计20、22、24,根据液位测量值可判断是否需补药剂原液,当液位低于1m时需进行补药,原液罐25装有搅拌机26,可对柠檬酸固体进行搅拌混合,化学清洗液配置时间一般在化学清洗前2h,每循环一次药液需补充30%药剂原液;以配置酸清洗液为例,开启阀门40,开启柠檬酸计量泵53,按设定流量及设定时间往酸清洗池加药,此时开启清洗补水阀41,再开启清洗补水泵6,往酸清洗池补水,设定补水液位为2.7m,当酸清洗池液位达到此液位,停止补水,关闭清洗水泵6,再关闭清洗补水阀41,当柠檬酸原液达到加药时间,关闭柠檬酸计量泵53,再关闭阀门40,停止补药,酸清洗液配置完成,当温度计43显示温度低于所设温度值时,开启加热器44,对所配清洗液进行加热,直至所设温度值。The dosing time is set according to the set flow rate and the concentration of the prepared agent. The chemical cleaning pool is equipped with liquid level gauges 29 and 42. It is determined whether to open the water replenishing pump 6 based on the measured values of the liquid level gauges 29 and 42. The chemical cleaning pool is equipped with a thermometer 30. , 43 and heaters 31, 44. Use the measurement value of the thermometer to determine whether to turn on the heater. Generally, the temperature of the chemical cleaning agent is set to be above 12-15 degrees Celsius. The agent liquid tanks 21, 23, and 25 are equipped with liquid level gauges 20 and 22. , 24. According to the liquid level measurement value, it can be judged whether the liquid level needs to be replenished. When the liquid level is lower than 1m, the liquid level needs to be replenished. The liquid tank 25 is equipped with a mixer 26, which can stir and mix the citric acid solid. The chemical cleaning liquid configuration time is generally 2 hours before chemical cleaning, 30% of the chemical solution needs to be replenished for each cycle; taking the acid cleaning solution as an example, open the valve 40, turn on the citric acid metering pump 53, and add water to the acid cleaning pool according to the set flow rate and set time. medicine, at this time open the cleaning water replenishment valve 41, then open the cleaning water replenishment pump 6, replenish water to the acid cleaning pool, set the replenishment liquid level to 2.7m, when the acid cleaning pool liquid level reaches this level, stop water replenishment, and close the cleaning water pump 6 , then close the cleaning and replenishing valve 41. When the citric acid stock solution reaches the dosing time, close the citric acid metering pump 53, then close the valve 40 to stop dosing. The acid cleaning solution configuration is completed. When the thermometer 43 shows that the temperature is lower than the set temperature value , turn on the heater 44 to heat the cleaning fluid until the set temperature value.
Ⅴ药液中和控制程序ⅤMedicinal liquid neutralization control procedure
中和池装有PH计54和ORP计56,可检测其废液酸碱度与氧化还原性,通过其测量值判定是否开启计量泵,当PH值低于设定值时,开启碱加药泵,当PH高于设定值时,开启酸加药泵,当ORP值高于一定氧化还原电位值时,开启还原剂加药泵,中和池装有管道混合器,可以将药液进行充分混合反应,直到中和池废液达到排放要求,停止加药,中和控制程序完成,进入废液排放控制程序。The neutralization tank is equipped with a PH meter 54 and an ORP meter 56, which can detect the pH and redox properties of the waste liquid, and use the measured values to determine whether to turn on the metering pump. When the pH value is lower than the set value, the alkali dosing pump is turned on. When the pH is higher than the set value, the acid dosing pump is turned on. When the ORP value is higher than a certain redox potential value, the reducing agent dosing pump is turned on. The neutralization tank is equipped with a pipeline mixer to fully mix the liquid. React until the waste liquid in the neutralization tank reaches the discharge requirements, stop dosing, the neutralization control program is completed, and the waste liquid discharge control program is entered.
Ⅵ废液排放控制程序ⅥWaste liquid discharge control procedures
废水池和中和池装有废水池液位计58和中和池液位计55,通过液位计的测量值判定是否开启中和池排放泵57和废液池排放泵59,为保证中和池和废水池足够的预留空间,一般液位达到较低值时就开启排放泵进行排放。The wastewater pool and the neutralization pool are equipped with a wastewater pool liquid level gauge 58 and a neutralization pool liquid level gauge 55. The measurement values of the liquid level gauges are used to determine whether to turn on the neutralization pool discharge pump 57 and the waste liquid pool discharge pump 59. In order to ensure neutralization Sufficient reserved space should be reserved for pools and wastewater pools. Generally, when the liquid level reaches a lower value, the discharge pump will be turned on for discharge.
经本系统处理得到的水量回收率高,水质稳定,超滤膜运行使用寿命长,化学清洗药剂循环重复利用率高,系统运行成本大大降低低,且该系统自动化程度高,能够提高浸没式超滤膜系统的处理效率和安全性、节省人力。The water treated by this system has a high recovery rate, stable water quality, long service life of the ultrafiltration membrane, high recycling rate of chemical cleaning agents, greatly reduced system operating costs, and the system has a high degree of automation, which can improve the immersion ultrafiltration process. The processing efficiency and safety of the membrane filter system save manpower.
以上所述仅为本发明之较佳实施例而已,并非以此限制本发明的实施范围,凡熟悉此项技术者,运用本发明的原则及技术特征,所做的各种变更及装饰,皆应涵盖于本权利要求书所界定的保护范畴之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the scope of the present invention. Anyone familiar with this technology can make various changes and decorations by applying the principles and technical features of the present invention. should be covered by the scope of protection defined by this claim.
Claims (9)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310700376.2A CN116924519A (en) | 2023-06-14 | 2023-06-14 | Efficient automatic control method and system for immersed ultrafiltration membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310700376.2A CN116924519A (en) | 2023-06-14 | 2023-06-14 | Efficient automatic control method and system for immersed ultrafiltration membrane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116924519A true CN116924519A (en) | 2023-10-24 |
Family
ID=88378105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310700376.2A Pending CN116924519A (en) | 2023-06-14 | 2023-06-14 | Efficient automatic control method and system for immersed ultrafiltration membrane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116924519A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103949163A (en) * | 2014-04-25 | 2014-07-30 | 山西太钢不锈钢股份有限公司 | Method for cleaning immersed ultrafiltration membrane in wastewater reuse |
| CN104098155A (en) * | 2014-07-03 | 2014-10-15 | 大庆兰德石油科技有限公司 | Deep treatment device for oil-containing and polymer-containing sewage adopting carbon compound composite film |
| CN111533249A (en) * | 2020-04-27 | 2020-08-14 | 上海华高汇元工程服务有限公司 | MBR-based water production automatic control system |
| CN114699923A (en) * | 2022-05-06 | 2022-07-05 | 江苏道科环境科技有限公司 | Method for recycling chemical cleaning liquid medicine of immersed ultrafiltration membrane |
-
2023
- 2023-06-14 CN CN202310700376.2A patent/CN116924519A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103949163A (en) * | 2014-04-25 | 2014-07-30 | 山西太钢不锈钢股份有限公司 | Method for cleaning immersed ultrafiltration membrane in wastewater reuse |
| CN104098155A (en) * | 2014-07-03 | 2014-10-15 | 大庆兰德石油科技有限公司 | Deep treatment device for oil-containing and polymer-containing sewage adopting carbon compound composite film |
| CN111533249A (en) * | 2020-04-27 | 2020-08-14 | 上海华高汇元工程服务有限公司 | MBR-based water production automatic control system |
| CN114699923A (en) * | 2022-05-06 | 2022-07-05 | 江苏道科环境科技有限公司 | Method for recycling chemical cleaning liquid medicine of immersed ultrafiltration membrane |
Non-Patent Citations (2)
| Title |
|---|
| 朱平华 主编: "《化工原理实验》", 31 December 2018, 南京大学出版社, pages: 127 * |
| 邵刚 编著: "《膜法水处理技术》", 30 June 1992, 冶金工业出版社, pages: 155 - 156 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113233581B (en) | Immersed MBR membrane pool device and method for sewage treatment using the same | |
| CN113041844A (en) | Reverse osmosis automatic cleaning device and method | |
| CN109336222A (en) | Immersion gravity stream ceramic membrane microkinetic ultrafiltration system sewage disposal device and method | |
| CN107899427A (en) | A kind of MBR membrane stacks on-line cleaning system and cleaning method | |
| CN114212927B (en) | Device and method for recycling slice wastewater | |
| CN216630355U (en) | Reverse osmosis membrane cleaning device | |
| CN107349793A (en) | A kind of system and method that can carry out offline chemical cleaning to MBR film group devices online | |
| CN207511908U (en) | A kind of MBR film process equipment of intelligent movable type | |
| CN211800068U (en) | Intelligent management system for running environment of ultrafiltration membrane component | |
| CN214862570U (en) | Reverse osmosis self-cleaning device | |
| CN116924519A (en) | Efficient automatic control method and system for immersed ultrafiltration membrane | |
| CN211770852U (en) | Advanced treatment device for kitchen wastewater | |
| CN202822955U (en) | Ceramic filter cleaning device | |
| CN113548754A (en) | Double-membrane treatment system for circulating cooling water treatment | |
| CN210506015U (en) | Semiconductor material grinding wastewater sludge treatment system | |
| CN112354370A (en) | Ceramic membrane chemical cleaning waste liquid treatment process | |
| CN110803746A (en) | A cleaning method and device for continuous electrodeionization membrane stack | |
| CN220900042U (en) | Efficient sewage cleaning treatment device | |
| CN217202314U (en) | A kind of ultrafiltration membrane cleaning waste liquid recovery and treatment system | |
| CN216825678U (en) | Pollution-resistant high-pressure reverse osmosis device | |
| CN217016116U (en) | Membrane module automatic cleaning system of marine MBR domestic sewage treatment device | |
| CN215996229U (en) | Membrane belt cleaning device | |
| CN209210442U (en) | A kind of immersion gravity stream ceramic membrane microkinetic ultrafiltration system sewage disposal device | |
| CN118579897A (en) | An electrodialysis process pretreatment test device and process | |
| CN114699923A (en) | Method for recycling chemical cleaning liquid medicine of immersed ultrafiltration membrane |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |