CN116832957A - Mineral separation method of lepidolite ore - Google Patents

Mineral separation method of lepidolite ore Download PDF

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CN116832957A
CN116832957A CN202310842595.4A CN202310842595A CN116832957A CN 116832957 A CN116832957 A CN 116832957A CN 202310842595 A CN202310842595 A CN 202310842595A CN 116832957 A CN116832957 A CN 116832957A
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concentrate
tailings
ore
magnetic separation
cyclone
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胡晖
张政军
欧阳霞嫦
周灵芝
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CINF Engineering Corp Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • B03C1/025High gradient magnetic separators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B5/00Washing granular, powdered or lumpy materials; Wet separating
    • B03B5/02Washing granular, powdered or lumpy materials; Wet separating using shaken, pulsated or stirred beds as the principal means of separation
    • B03B5/04Washing granular, powdered or lumpy materials; Wet separating using shaken, pulsated or stirred beds as the principal means of separation on shaking tables
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B7/00Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • B03C1/30Combinations with other devices, not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/018Mixtures of inorganic and organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B04CENTRIFUGAL APPARATUS OR MACHINES FOR CARRYING-OUT PHYSICAL OR CHEMICAL PROCESSES
    • B04CAPPARATUS USING FREE VORTEX FLOW, e.g. CYCLONES
    • B04C9/00Combinations with other devices, e.g. fans, expansion chambers, diffusors, water locks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00Specified effects produced by the flotation agents
    • B03D2201/005Dispersants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00Specified effects produced by the flotation agents
    • B03D2201/02Collectors

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

本发明涉及一种锂云母矿石的选矿方法,包括以下步骤:步骤S1、将矿石破碎,得到入磨物料;步骤S2、将入磨物料进行磨矿分级作业;步骤S3、将步骤S2所得筛下物进行磁选作业,得到铁精矿和磁选尾矿;步骤S4、将磁选尾矿进行布溜和摇床重选作业,得到钽铌锡精矿和重选尾矿、摇床中矿;步骤S5、将重选尾矿进行脱泥旋流器作业后,得到超细长石和旋流器沉砂;步骤S6、将旋流器沉砂给入浮选作业,得到锂云母精矿和浮选尾矿;步骤S7、将浮选尾矿进行高梯度磁选作业,得到长石和高梯度磁选精矿;步骤S8、将高梯度磁选精矿与摇床中矿混合,返回步骤S2。本发明锂云母精矿的回收率和品位可达到73%、2.6%以上,无尾矿产生,综合回收利用价值高。

The invention relates to a method for beneficiating lepidolite ore, which includes the following steps: Step S1, crush the ore to obtain grinding materials; Step S2, carry out grinding and classification operations on the grinding materials; Step S3, sieve the result obtained in Step S2 The material is subjected to magnetic separation operation to obtain iron concentrate and magnetic separation tailings; step S4, the magnetic separation tailings are subjected to cloth slide and shaking table gravity separation operations to obtain tantalum niobium tin concentrate, gravity separation tailings, and shaking table middlings. ; Step S5: After the gravity separation tailings are subjected to a desliming cyclone operation, ultra-fine feldspar and cyclone sand are obtained; Step S6: The cyclone sand is fed into the flotation operation to obtain lepidolite concentrate and Flotation tailings; Step S7, perform high-gradient magnetic separation on the flotation tailings to obtain feldspar and high-gradient magnetic separation concentrate; Step S8, mix the high-gradient magnetic separation concentrate with the shaker middlings, and return to step S2 . The recovery rate and grade of the lepidolite concentrate of the present invention can reach 73% and above 2.6%, no tailings are generated, and the comprehensive recycling value is high.

Description

一种锂云母矿石的选矿方法A kind of mineral processing method for lepidolite ore

技术领域Technical field

本发明涉及一种锂云母矿石的选矿方法,属于矿产综合利用技术领域。The invention relates to a method for beneficiating lepidolite ore and belongs to the technical field of comprehensive utilization of minerals.

背景技术Background technique

随着电池产业、新能源汽车、电子通讯产业的飞速发展,“锂”由于其具有的优异性能使其成为最热门金属。盐湖提锂和矿石提锂技术是获取锂金属的两种常用方法。国内具有开采价值的含锂矿物主要是锂辉石(LiAl[Si2O6],Li2O含量为8.04%)和锂云母(KLi1.5Al1.5(AlSi3O10),Li2O含量为1.23%~5.90%),其中锂云母矿石集中分布在江西宜春。锂云母矿石中除了氧化锂外,还通常伴生有多种有价金属元素,如钽、铌、锡、铁。同时,锂云母矿石中往往存在大量脉石矿物,如长石、石英。综合回收上述有价元素和脉石矿物,实现选厂无尾矿化生产,可以为企业创造更多的经济价值,同时还有利于生态环境保护。With the rapid development of the battery industry, new energy vehicles, and electronic communications industries, "lithium" has become the most popular metal due to its excellent properties. Salt lake lithium extraction and ore lithium extraction technologies are two common methods to obtain lithium metal. The lithium-containing minerals with mining value in China are mainly spodumene (LiAl[Si 2 O 6 ], Li 2 O content is 8.04%) and lepidolite (KLi 1.5 Al 1.5 (AlSi 3 O 10 ), Li 2 O content is 8.04%). 1.23% ~ 5.90%), among which lepidolite ore is concentrated in Yichun, Jiangxi. In addition to lithium oxide, lepidolite ore is usually accompanied by a variety of valuable metal elements, such as tantalum, niobium, tin, and iron. At the same time, there are often a large number of gangue minerals, such as feldspar and quartz, in lepidolite ores. Comprehensive recovery of the above-mentioned valuable elements and gangue minerals to achieve tailing-free mineralization production in the dressing plant can create more economic value for the enterprise and is also beneficial to ecological and environmental protection.

中国专利申请CN115999780A公开了一种铁锂云母矿石磁浮和提锂的选矿方法,采用“高梯度强磁选预富集-浮选回收-浮选尾矿返回磁选作业”的工艺流程进行铁锂云母的分选回收,磁选作业采用高梯度磁选机经一段或多段强磁选回收铁锂云母并将其与白云母及其他脉石初步分离;将磁选作业获得的磁性产品合并进行浮选,配合高效铁锂云母浮选捕收剂LYP,获得高品质铁锂云母精矿;浮选尾矿返回至高梯度磁选作业,最终实现铁锂云母的高效分选。但是,该方法所示流程只是为了富集铁锂云母,没有考虑其他有用组分的回收;此外,铁锂云母矿具有磁性,才能够用强磁选机富集。中国专利申请CN115739380A公开了一种锂矿石选矿方法,包括以下步骤:1)破碎;2)分级将步骤1)中得到的矿石加入筛网进行分级,得到粗粒矿和细粒矿;3)去钽铌;4)球磨将步骤3)中得到的轻物加入球磨机,进行湿式球磨;5)除铁;6)脱泥;7)预浮选;8)精选锂云母;9)粗扫选锂辉石;10)精选锂辉石。该方法流先去脱泥、除铁后再进行浮选、分级进行浮选,可回收钼铌、锂云母成品,特别适用于富含锂萤石、锂钽铌的锂矿石选矿,但是无法完全做到无尾矿化生产。Chinese patent application CN115999780A discloses a magnetic flotation and lithium extraction method for iron lithium mica ore, using the process flow of "high gradient strong magnetic separation pre-enrichment - flotation recovery - flotation tailings return to magnetic separation operation" for iron and lithium extraction. For the separation and recovery of mica, the magnetic separation operation uses a high gradient magnetic separator to recover lithium mica through one or more stages of strong magnetic separation and initially separate it from muscovite and other gangue; the magnetic products obtained from the magnetic separation operation are combined and floated Select, cooperate with the high-efficiency lepidolite flotation collector LYP to obtain high-quality lepidolite concentrate; the flotation tailings are returned to the high-gradient magnetic separation operation, and finally achieve efficient separation of lepidolite. However, the process shown in this method is only for enriching lepidolite and does not consider the recovery of other useful components; in addition, lepidolite ore is magnetic and can be enriched with a strong magnetic separator. Chinese patent application CN115739380A discloses a lithium ore beneficiation method, which includes the following steps: 1) crushing; 2) classification. Add the ore obtained in step 1) to a screen for classification to obtain coarse-grained ore and fine-grained ore; 3) remove Tantalum and niobium; 4) Ball milling Add the light material obtained in step 3) to the ball mill for wet ball milling; 5) Iron removal; 6) Desliming; 7) Pre-flotation; 8) Lepidolite selection; 9) Rough sweep selection Spodumene; 10) Selected spodumene. This method first deslimes and removes iron and then carries out flotation and classification. It can recover molybdenum niobium and lepidolite finished products. It is especially suitable for beneficiation of lithium ore rich in lithium fluorite and lithium tantalum niobium. However, it cannot completely Achieve tailings-free production.

锂矿石选厂存在着资源浪费、经济指标不理想的现象,这通常是由于设计时工艺流程的制定和设备选择不合理所致。锂云母矿石往往嵌布特征复杂,依靠单一选别技术难以回收全部有用矿物组分,同时,锂云母与长石等硅酸盐矿物的物化性质相近,在碎磨过程中易泥化,恶化选别效果。针对这些现象,如何制定合适的选矿工艺流程,选择高效的选矿设备,以充分回收矿石中的有价组分,实现锂云母矿无尾矿化生产,是一个亟待解决的难题。There is a waste of resources and unsatisfactory economic indicators in lithium ore dressing plants. This is usually due to unreasonable formulation of process flow and unreasonable equipment selection during design. Lepidolite ore often has complex embedded characteristics, and it is difficult to recover all useful mineral components by relying on a single sorting technology. At the same time, lepidolite has similar physical and chemical properties to silicate minerals such as feldspar, so it is easy to muddy during the grinding process, worsening the separation. No effect. In response to these phenomena, how to formulate a suitable mineral processing process and select efficient mineral processing equipment to fully recover the valuable components in the ore and achieve tailings-free production of lepidolite ore is an urgent problem that needs to be solved.

发明内容Contents of the invention

针对现有技术的不足,本发明的目的在于提供一种锂云母矿石的选矿方法,以充分回收矿石中的有价组分,实现锂云母矿无尾矿化生产。In view of the shortcomings of the existing technology, the purpose of the present invention is to provide a lepidolite ore beneficiation method to fully recover the valuable components in the ore and realize tailings-free production of lepidolite ore.

为了解决上述技术问题,本发明的技术方案如下:In order to solve the above technical problems, the technical solutions of the present invention are as follows:

步骤S1、将矿石破碎,得到入磨物料;Step S1: Crush the ore to obtain grinding materials;

步骤S2、将入磨物料进行磨矿分级作业;Step S2: Grinding and classifying the input materials;

步骤S3、将步骤S2所得筛下物进行磁选作业,得到铁精矿和磁选尾矿;Step S3: Perform magnetic separation on the undersize obtained in step S2 to obtain iron concentrate and magnetic separation tailings;

步骤S4、将磁选尾矿进行多次布溜作业和多次摇床重选作业,得到钽铌锡精矿和重选尾矿、摇床中矿;Step S4, subject the magnetic separation tailings to multiple slip operations and multiple shaking table gravity separation operations to obtain tantalum-niobium-tin concentrate, gravity separation tailings, and shaking table middlings;

步骤S5、将重选尾矿进行多段脱泥旋流器作业,得到超细长石和旋流器沉砂;Step S5: Perform multi-stage desliming cyclone operation on the gravity separation tailings to obtain ultra-fine feldspar and cyclone sand;

步骤S6、将旋流器沉砂给入浮选作业,得到锂云母精矿和浮选尾矿;Step S6: Feed the cyclone sand into the flotation operation to obtain lepidolite concentrate and flotation tailings;

步骤S7、将浮选尾矿进行高梯度磁选作业,得到长石和高梯度磁选精矿;Step S7: Perform high-gradient magnetic separation on the flotation tailings to obtain feldspar and high-gradient magnetic separation concentrate;

步骤S8、将高梯度磁选精矿与步骤S4中所得摇床中矿混合,返回步骤S2。Step S8: Mix the high-gradient magnetic separation concentrate with the shaker medium ore obtained in step S4, and return to step S2.

本发明采用弱磁选-重选-浮选-强磁选的工艺,对锂云母矿石进行选别。在磨矿分级阶段控制分级粒度,可有效降低粒度对后续重选作业的影响;首先通过一段弱磁作业选出铁精矿,然后采用布溜作业和摇床重选作业选出高比重矿物钽铌锡;长石在锂云母矿石中易被磨细,通过旋流器分级可以实现其与片状锂云母的分离,从而得到超细粒级别的长石精矿;通过浮选可分离锂云母与长石;浮选尾矿经过再分级及重选,返回到上级流程中,实现无尾矿化及矿石的综合利用。The present invention adopts the process of weak magnetic separation-gravity separation-flotation-strong magnetic separation to select lepidolite ore. Controlling the classification particle size during the grinding and classification stage can effectively reduce the impact of particle size on subsequent gravity separation operations; first, the iron concentrate is selected through a weak magnetic operation, and then the high specific gravity mineral tantalum is selected using cloth slide operation and shaking table gravity separation operation. Niobium tin; feldspar is easily ground in lepidolite ore, and can be separated from flake lepidolite through cyclone classification, thereby obtaining ultra-fine-grained feldspar concentrate; lepidolite can be separated through flotation and feldspar; the flotation tailings are re-classified and gravity-selected and returned to the upper-level process to achieve tailings-free and comprehensive utilization of ores.

进一步地,步骤S1中采用三段一闭路破碎筛分流程将矿石破碎至粒度小于12mm。将矿石粗碎、中碎,细碎筛分后,达到进入磨机的细度要求。“三段”指矿石需要进行三次破碎,“一闭路”指最后一段细碎机与筛子组成闭路作业,以控制破碎产品粒度。如此,能够提高磨矿能力,便于获得粒度符合要求的入磨物料。进一步地,步骤S2中,磨矿分级作业采用球磨、旋流器、高频细筛的双闭路流程,物料经球磨后进入旋流器,旋流器溢流给入高频细筛,筛上物和旋流器沉砂一起返回球磨。高频筛筛下产品粒度小于0.15mm占60%-80%,高频细筛为十叠层振动筛,筛分效率可达到88%-90%。磨矿分级作业是将矿石破碎至入磨粒度后,将其给入磨矿机进一步粉碎,磨机通常与水力旋流器组成闭路作业,即磨矿后物料进入水力旋流器进行分级,分级后的沉砂(粒度较大)返回磨机继续碎磨,溢流产品(通常测定-0.15mm、-0.074mm、-0.037mm粒级含量)则进入下一步作业。水力旋流器在生产过程中容易出现“跑粗”现象,导致磨矿产品矿物单体解离度不够,影响后续选别作业,因此在旋流器后增加一段高频细筛作业与球磨机组成闭路作业,严格控制溢流产品粒度。Further, in step S1, a three-stage one-closed-circuit crushing and screening process is used to crush the ore to a particle size less than 12 mm. After the ore is coarsely crushed, medium crushed, and finely crushed and screened, it reaches the fineness requirement for entering the mill. "Three stages" means that the ore needs to be crushed three times, and "one closed circuit" means that the final stage of fine crusher and screen form a closed circuit operation to control the particle size of the crushed products. In this way, the grinding capacity can be improved and the grinding materials with the required particle size can be easily obtained. Further, in step S2, the grinding and classification operation adopts a double closed-circuit process of ball mill, cyclone, and high-frequency fine screen. After the material is ball milled, it enters the cyclone, and the overflow of the cyclone is fed to the high-frequency fine screen. The materials and cyclone grit are returned to the ball mill. The product particle size under the high-frequency screen is less than 0.15mm, accounting for 60%-80%. The high-frequency fine screen is a ten-stack vibrating screen, and the screening efficiency can reach 88%-90%. The grinding and classification operation is to crush the ore to the grinding size and then feed it into the grinding mill for further crushing. The grinding mill usually forms a closed-circuit operation with the hydrocyclone, that is, the materials after grinding enter the hydrocyclone for classification. The final sand settling (larger particle size) is returned to the mill to continue grinding, and the overflow product (usually measured with -0.15mm, -0.074mm, -0.037mm particle size content) enters the next step. The hydrocyclone is prone to "coarse" phenomenon during the production process, resulting in insufficient dissociation of mineral monomers in the grinding products, which affects subsequent sorting operations. Therefore, a high-frequency fine screening operation and a ball mill are added after the cyclone. Closed-circuit operation, strictly control overflow product particle size.

进一步地,步骤S3中,磁选作业的磁场强度为0.6-0.85T。磁选作业是基于被分离物料中不同组分的磁性差异,采用不同类型的磁选机将物料中不同磁性组分分离的作业。如此,通过一段弱磁作业选出铁精矿,实现铁精矿的高效分选。同时,能改善难免离子Fe3+对锂云母浮选的影响,有利于提高锂云母精矿品质。Further, in step S3, the magnetic field intensity of the magnetic separation operation is 0.6-0.85T. Magnetic separation is based on the magnetic differences of different components in the material to be separated, and uses different types of magnetic separators to separate different magnetic components in the material. In this way, the iron concentrate is selected through a period of weak magnetic operation to achieve efficient sorting of iron concentrate. At the same time, it can improve the influence of unavoidable ion Fe 3+ on lepidolite flotation, which is beneficial to improving the quality of lepidolite concentrate.

进一步地,步骤S4中,采用2次布溜作业和2次摇床重选作业且均采用一段粗选、一段扫选流程。将布溜粗选尾矿给入布溜扫选作业,布溜粗选和扫选精矿混合后进入摇床作业,将摇床粗选中矿给入摇床扫选作业,摇床粗选和扫选精矿混合,即为钽铌锡精矿;布溜扫选尾矿、摇床粗选和扫选尾矿作为重选尾矿后续进行脱泥旋流器作业。如此,经过两段布溜作业和两段摇床作业,基本可回收原矿中的钽铌锡精矿。Further, in step S4, two cloth-sliding operations and two shaker re-selection operations are used, and both use one stage of rough selection and one stage of sweeping selection. The tailings from the rough separation of the Buliu are fed into the Sweeping operation of the Buliu. The roughing concentrates from the Buliu and the sweeping concentrates are mixed and then enter the shaking table operation. The roughing ore from the shaking table is fed into the sweeping operation of the shaking table. The roughing and sweeping operation of the shaking table is carried out. The scavenging concentrate is mixed to form tantalum-niobium-tin concentrate; the Buliu scavenging tailings, shaking table roughing and scavenging tailings are used as gravity separation tailings for subsequent desliming cyclone operations. In this way, after two stages of cloth slide operation and two stages of shaking table operation, the tantalum niobium tin concentrate in the raw ore can basically be recovered.

布溜作业是一种重选工艺,利用矿物之间的密度差异,将比重不同的矿物进行分离的技术,适用于细粒矿物的选别。将物料给入布溜设备,布溜呈阶梯布置,在分选过程中,轻颗粒被水流带走,重颗粒吸附在布溜的毛毯上,经过一段时间后使用高压水枪将毛毯清洗干净,完成一次循环作业。本发明中布溜设备全程实现自动化控制。摇床作业也是一种重选工艺,利用矿物之间的密度和粒度差异,使用摇床设备将比重不同的矿物进行分离的技术,适用于细粒矿物分选。具体为,物料经给矿槽流入摇床面上,在水流和床面振动作用下发生松散、分层。分层后,上层轻矿物沿床面的横向倾斜向下运动,成为尾矿。位于下层的重矿物受床面不对称往复运动的推动,纵向移动到传动端对面,成为精矿。矿粒群由于其密度和粒度差异在摇床面上呈扇形分带。Clothing operation is a gravity separation process that uses the density difference between minerals to separate minerals with different specific gravity. It is suitable for the separation of fine-grained minerals. Feed the material into the cloth slide equipment. The cloth slide is arranged in a ladder. During the sorting process, the light particles are taken away by the water flow, and the heavy particles are adsorbed on the blanket of the cloth slide. After a period of time, use a high-pressure water gun to clean the blanket. Complete A cycle operation. In the present invention, the whole process of the cloth and sliding equipment is realized with automatic control. Shaking table operation is also a gravity separation process. It uses the density and particle size differences between minerals to separate minerals with different specific gravity using shaking table equipment. It is suitable for fine-grained mineral sorting. Specifically, the material flows into the shaking table through the feeding trough, and is loosened and stratified under the action of water flow and bed surface vibration. After stratification, the upper light minerals move downward along the lateral slope of the bed surface and become tailings. The heavy minerals located in the lower layer are driven by the asymmetric reciprocating motion of the bed surface and move longitudinally to the opposite side of the transmission end to become concentrate. Ore particles are divided into fan-shaped zones on the shaking table due to differences in density and particle size.

进一步地,步骤S5中,进行2段脱泥旋流器作业,2段旋流器形成闭路作业,第一段旋流器溢流给入第二段旋流器,第二段旋流器溢流经斜板浓密机和压滤机两段脱水作业得到超细长石。第二段旋流器沉砂返回第一段旋流器,第一段旋流器沉砂后续进行浮选作业。通过预先分离出超细长石,不仅有效降低浮选药剂成本,而且减小浮选机和搅拌槽等设备规格,节约了水资源。Further, in step S5, a 2-stage desliming cyclone operation is performed. The 2-stage cyclone forms a closed-circuit operation. The overflow of the first-stage cyclone is fed into the second-stage cyclone, and the second-stage cyclone overflows. Ultra-fine feldspar is obtained by flowing through the two stages of dehydration operations of the inclined plate thickener and the filter press. The sand settled in the second stage cyclone returns to the first stage cyclone, and the sand settled in the first stage cyclone is followed by flotation operation. By pre-separating ultra-fine feldspar, it not only effectively reduces the cost of flotation reagents, but also reduces the specifications of equipment such as flotation machines and stirring tanks, saving water resources.

所述超细长石是粒度为10μm或15μm或20μm的长石粉产品,主要用于生产油漆、塑料、橡胶等产品的填充剂。The ultra-fine feldspar is a feldspar powder product with a particle size of 10 μm or 15 μm or 20 μm, which is mainly used to produce fillers for paints, plastics, rubber and other products.

进一步地,步骤S6中,浮选作业在pH为7-10的环境下进行,粗选矿浆质量浓度为25%-35%,浮选药剂含有捕收剂、活化剂和分散剂,其中捕收剂、活化剂和分散剂粗选段用量分别为200-400g/t原矿,100-300g/t原矿,150-300g/t原矿。进一步地,所述捕收剂含有十二胺、油酸、氧化石蜡皂、磷酸三丁酯中的至少一种。捕收剂可选择性地吸附于锂云母矿物表面,导致矿化泡沫的形成,并促使其作为泡沫产品被刮出。Further, in step S6, the flotation operation is carried out in an environment with a pH of 7-10, the roughing slurry mass concentration is 25%-35%, and the flotation agent contains a collector, an activator and a dispersant, wherein the collector The dosage of agent, activator and dispersant in the rough selection section is 200-400g/t raw ore, 100-300g/t raw ore and 150-300g/t raw ore respectively. Further, the collector contains at least one of dodecylamine, oleic acid, oxidized paraffin soap, and tributyl phosphate. The collector can selectively adsorb on the surface of lepidolite mineral, leading to the formation of mineralized foam and prompting it to be scraped out as a foam product.

进一步地,所述活化剂为氯化铝溶液,活化剂能选择性活化锂云母,促进捕收剂在该矿物表面的吸附,并扩大其与长石表面的可浮性差异。Further, the activator is an aluminum chloride solution, which can selectively activate lepidolite, promote the adsorption of the collector on the mineral surface, and expand the difference in floatability between it and the feldspar surface.

进一步地,所述分散剂为六偏磷酸钠溶液,分散剂可通过吸附在细泥矿物表面,改变矿物表面电性,抑制细泥与矿物之间的静电吸附作用,从而减少夹带上浮量。Furthermore, the dispersant is sodium hexametaphosphate solution. The dispersant can be adsorbed on the surface of fine mud minerals, change the electrical properties of the mineral surface, and inhibit the electrostatic adsorption between the fine mud and minerals, thereby reducing the amount of entrained floating matter.

在一些实施例中,步骤S6中,浮选作业包括以下步骤:将粗选泡沫给入精选一作业,精选一泡沫给入精选二作业,精选二泡沫脱水后得到锂云母精矿产品,两段精选作业尾矿循序返回上级作业,将浮选尾矿给入扫选一作业,扫选一尾矿给入扫选二作业,两段扫选所得泡沫循序返回上级作业;扫选二尾矿后续进行高梯度磁选作业。如此,提高了锂云母精矿的回收效果,实现锂云母精矿的高效回收。进一步地,步骤S7中,高梯度磁选作业磁场强度为1-2T。以便于充分回收长石产品。高梯度磁选尾矿过滤后得到陶瓷级长石产品。使用高梯度磁选机进行高梯度磁选作业,高梯度磁选机是一种用于弱磁性矿物选别的强磁选机,可以分离一般磁选机难以分选的磁性极弱的细粒物料,降低分选粒度下限。In some embodiments, in step S6, the flotation operation includes the following steps: feeding the rough selection foam into the first selection operation, feeding the first selection foam into the second selection operation, and obtaining lepidolite concentrate after dehydration of the second selection foam. Products, the tailings from the two stages of beneficiation operations are returned to the upper-level operation in sequence, the flotation tailings are fed into the first sweeping operation, the tailings from the first sweeping operation are fed into the second sweeping operation, and the foam obtained from the two stages of sweeping is returned to the superior operation in sequence; sweeping operation The second tailings will be selected for subsequent high-gradient magnetic separation operations. In this way, the recovery effect of lepidolite concentrate is improved and efficient recovery of lepidolite concentrate is achieved. Further, in step S7, the magnetic field intensity of the high gradient magnetic separation operation is 1-2T. To facilitate full recovery of feldspar products. Ceramic grade feldspar products are obtained after filtration of high gradient magnetic separation tailings. High gradient magnetic separator is used for high gradient magnetic separation operation. High gradient magnetic separator is a strong magnetic separator used for the separation of weak magnetic minerals. It can separate extremely weak magnetic fine particles that are difficult to be separated by ordinary magnetic separators. material, lower the lower limit of sorting particle size.

进一步地,步骤S4中摇床中矿与步骤S8中的高梯度磁选精矿流向一致,在一些实施例中,步骤S8中,将高梯度磁选精矿与步骤S4中所得摇床中矿混合,进行旋流器分级作业,分级沉砂给入步骤S2,分级溢流经浓缩后矿浆质量浓度为10%-20%,分级溢流进行布溜作业,布溜精矿给入步骤S4,布溜尾矿给入步骤S5。布溜作业采用一粗一扫,布溜粗选尾矿流入布溜扫选,布溜扫选尾矿给入步骤S5的斜板浓密机,得到超细长石产品;布溜扫选精矿和布溜粗选精矿给入步骤S4摇床粗选作业。如此,不仅能够充分回收钽铌锡金属,而且实现了无尾矿化生产的目的。Further, in step S4, the flow direction of the shaker medium ore is consistent with that of the high gradient magnetic separation concentrate in step S8. In some embodiments, in step S8, the high gradient magnetic separation concentrate is the same as the flow direction of the shaker medium ore obtained in step S4. Mix, carry out cyclone classification operation, graded sand settling is fed to step S2, the graded overflow is concentrated and the slurry mass concentration is 10%-20%, graded overflow is used for cloth flow operation, and cloth flow concentrate is fed to step S4, The cloth tailings are fed into step S5. The cloth-sliding operation adopts one roughing and one sweep. The tailings from the rough selection in the cloth-sliding flow flow into the cloth-sliding and sweeping process, and the tailings from the cloth-sliding and sweeping process are fed into the inclined plate thickener in step S5 to obtain ultra-fine feldspar products; the cloth-sliding and sweeping concentrates The roughing concentrate of the cloth slide is fed into the shaking table roughing operation in step S4. In this way, not only can tantalum, niobium and tin metals be fully recovered, but the purpose of tailings-free production can also be achieved.

与现有技术相比,本发明的有益效果如下:Compared with the prior art, the beneficial effects of the present invention are as follows:

(1)本发明可获得合格的铁精矿、钽铌锡精矿、超细长石精矿、锂云母精矿及陶瓷级长石精矿,主要回收矿物锂云母精矿的回收率和品位可达到73%、2.6%以上,无尾矿产生,综合回收利用价值高。(1) The present invention can obtain qualified iron concentrate, tantalum niobium tin concentrate, ultra-fine feldspar concentrate, lepidolite concentrate and ceramic grade feldspar concentrate, and the recovery rate and grade of the main recovered mineral lepidolite concentrate It can reach more than 73% and 2.6%, no tailings are generated, and the comprehensive recycling value is high.

(2)本发明通过旋流器和高频细筛严格控制磨矿粒度,通过分级和重选预先分离出铁精矿、钽铌锡精矿及超细长石,一方面可有效降低浮选药剂成本,减小浮选机和搅拌槽等设备规格,另一方面可改善难免离子Fe3+对锂云母浮选的影响,有利于提高锂云母精矿品质。(2) The present invention strictly controls the grinding particle size through cyclones and high-frequency fine screens, and pre-separates iron concentrate, tantalum-niobium-tin concentrate and ultra-fine feldspar through classification and gravity separation. On the one hand, it can effectively reduce flotation It can reduce the cost of chemicals and reduce the specifications of equipment such as flotation machines and stirring tanks. On the other hand, it can improve the influence of unavoidable ion Fe 3+ on lepidolite flotation, which is beneficial to improving the quality of lepidolite concentrate.

(3)本发明采用布溜和摇床重选的方式,对细粒矿物适应性强,分离效率高。(3) The present invention adopts cloth slide and shaking table gravity separation, which has strong adaptability to fine-grained minerals and high separation efficiency.

(4)本发明对扫选尾矿进行一段高梯度磁选,进一步回收其中的弱磁性铁和钽铌,同时保证长石品质。(4) The present invention performs a stage of high-gradient magnetic separation on the scavenging tailings to further recover the weakly magnetic iron and tantalum niobium while ensuring the quality of the feldspar.

(5)选矿回水利用率高,水资源得到节约,经济和环境效益明显。(5) The mineral processing return water utilization rate is high, water resources are saved, and the economic and environmental benefits are obvious.

附图说明Description of the drawings

图1是本发明实施例1中的工艺流程图。Figure 1 is a process flow diagram in Embodiment 1 of the present invention.

具体实施方式Detailed ways

以下将结合实施例来详细说明本发明。需要说明的是,在不冲突的情况下,本发明中的实施例及实施例中的特征可以相互组合。The present invention will be described in detail below with reference to examples. It should be noted that, as long as there is no conflict, the embodiments and features in the embodiments of the present invention can be combined with each other.

实施例1Example 1

本实例中原矿为江西宜春地区某锂云母矿石,其中Li2O含量0.42%,其它化学成分主要包括SiO2含量68.52%、Al2O3含量18.73%、K2O含量3.83%、Na2O含量3.6%、MgO含量0.18%、Fe2O3含量0.64%。原矿中Li2O主要赋存在锂云母中,矿石中主要矿物为钾长石、纳长石、石英、云母、方解石,及少量的黄铁矿、萤石、独居石、赤铁矿、锆石、黄玉等。In this example, the raw ore is a lepidolite ore in the Yichun area of Jiangxi Province, with a Li 2 O content of 0.42%. Other chemical components mainly include SiO 2 content of 68.52%, Al 2 O 3 content of 18.73%, K 2 O content of 3.83%, and Na 2 O The content is 3.6%, the MgO content is 0.18%, and the Fe 2 O 3 content is 0.64%. Li 2 O in the raw ore mainly occurs in lepidolite. The main minerals in the ore are potassium feldspar, nanofeldspar, quartz, mica, calcite, and a small amount of pyrite, fluorite, monazite, hematite, and zircon. , Topaz, etc.

一种锂云母矿石的选矿方法,其工艺流程参见图1,具体包括以下步骤:A method for beneficiating lepidolite ore, the process flow of which is shown in Figure 1, which specifically includes the following steps:

步骤S1、采用三段一闭路破碎筛分流程将矿石破碎,得到预定细度的入磨物料。Step S1: Use a three-stage one-closed-circuit crushing and screening process to crush the ore to obtain grinding materials with a predetermined fineness.

步骤S2、将步骤S1得到的筛下矿石进行磨矿分级作业,磨矿细度为-0.15mm占70%。Step S2: Grind and classify the ore under the sieve obtained in Step S1. The grinding fineness is -0.15mm accounting for 70%.

步骤S3、将步骤S2所得筛下物进行弱磁选作业,磁场强度为0.8T,磁选精矿经斜板浓密机和带式过滤机两段脱水后得到铁精矿产品。Step S3: Perform weak magnetic separation on the undersized material obtained in Step S2. The magnetic field strength is 0.8T. The magnetic separation concentrate is dehydrated in two stages, the inclined plate thickener and the belt filter, to obtain an iron concentrate product.

步骤S4、将步骤S3所得弱磁尾矿先后进行2次布溜作业和2次摇床重选作业,将布溜粗选尾矿给入布溜扫选作业,布溜粗选和扫选精矿混合后进入摇床作业,将摇床粗选中矿给入摇床扫选作业,摇床粗选和扫选精矿混合,即为钽铌锡精矿。Step S4: The weak magnetic tailings obtained in step S3 are subjected to 2 cloth slide operations and 2 shaking table gravity selection operations, and the cloth slide roughing tailings are fed into the cloth slide sweeping operation, and the cloth slide roughing and sweeping fine selection operations are carried out. After the ore is mixed, it enters the shaking table operation, and the shaker roughing ore is fed into the shaking table sweeping operation. The shaking table roughing and sweeping concentrates are mixed to form tantalum niobium tin concentrate.

步骤S5、将步骤S4布溜和摇床尾矿混合,进行2段脱泥旋流器闭路作业,得到的溢流产品即为超细长石。Step S5: Mix the cloth from step S4 with the shaker tailings, and perform a two-stage desliming cyclone closed-circuit operation. The overflow product obtained is ultrafine feldspar.

步骤S6、将步骤S5所得旋流器沉砂进行浮选作业,其中粗选矿浆质量浓度为30%,矿浆pH值为8,浮选药剂为捕收剂、活化剂和分散剂,其用量分别为350g/t原矿,100g/t原矿,250g/t原矿,采用一粗二精二扫的闭路流程,将粗选泡沫给入精选一作业,精选一泡沫给入精选二作业,精选二泡沫脱水后得到锂云母精矿产品;两段精选作业尾矿循序返回上级作业,将粗选尾矿给入扫选一作业,扫选一尾矿给入扫选二作业,两段扫选所得泡沫循序返回上级作业。Step S6: Carry out flotation operation using the cyclone sand sedimentation obtained in Step S5, in which the mass concentration of roughing slurry is 30%, the pH value of slurry is 8, and the flotation reagents are collectors, activators and dispersants, and their dosages are respectively For 350g/t raw ore, 100g/t raw ore, 250g/t raw ore, a closed-circuit process of one coarse, two fines and two sweeps is adopted. The coarse foam is fed into the first selection operation, the foam from the first selection is fed into the second selection operation, and the fine foam is fed into the second selection operation. Lepidolite concentrate product is obtained after the second selection foam is dehydrated; the tailings of the two stages of selection operation are returned to the upper level operation in sequence, and the rough selection tailings are fed into the first sweeping operation, and the tailings of the first sweeping operation are fed into the second sweeping operation. The bubbles obtained by scanning are returned to the upper level operation in sequence.

步骤S7、上述扫选尾矿再进行一段高梯度磁选作业,磁场强度为1.5T,磁选尾矿即为陶瓷级长石产品。Step S7: The above-mentioned scavenging tailings are then subjected to a high-gradient magnetic separation operation with a magnetic field strength of 1.5T. The magnetic separation tailings are ceramic-grade feldspar products.

步骤S8、将上述高梯度磁选精矿与步骤S4所得摇床中矿混合,进行一道旋流器分级作业,分级沉砂给入步骤S2的旋流器分级再磨作业;分级溢流质量浓度为15%,经浓缩后进入布溜重选作业;所述布溜重选采用一粗一扫,布溜尾矿经斜板浓密机和压滤机后混入超细长石产品,布溜精矿给入步骤S4的摇床粗选作业。Step S8: Mix the above-mentioned high gradient magnetic separation concentrate with the shaker medium ore obtained in step S4, perform a cyclone classification operation, and feed the classified sand into the cyclone classification and regrinding operation of step S2; classify the overflow mass concentration It is 15%, and then enters the cloth-liu gravity selection operation after concentration; the cloth-liu gravity selection adopts one coarse and one sweep. The ore is fed into the shaking table roughing operation of step S4.

其中步骤S6中,所述捕收剂含有十二胺、油酸、氧化石蜡皂,其中十二胺的质量与油酸和氧化石蜡皂的总质量之比为1:4,捕收剂的配置过程为先将十二胺溶于磷酸三丁酯,加入油酸与氧化石蜡皂,然后加入氢氧化钠溶液与醇溶液进行加温搅拌。In step S6, the collector contains dodecylamine, oleic acid, and oxidized paraffin soap. The ratio of the mass of dodecylamine to the total mass of oleic acid and oxidized paraffin soap is 1:4. The configuration of the collector The process is to first dissolve dodecamine in tributyl phosphate, add oleic acid and oxidized paraffin soap, then add sodium hydroxide solution and alcohol solution and heat and stir.

步骤S6中,活化剂为氯化铝溶液,分散剂为六偏磷酸钠溶液。In step S6, the activator is aluminum chloride solution, and the dispersant is sodium hexametaphosphate solution.

该矿石在上述工艺流程分选下,最终可得到含Li2O 2.6%,回收率73%的锂云母精矿,以及质量合格的铁精矿(TFe=55%)、钽铌锡精矿(Ta2O5回收率34.2%,Nb2O5回收率22.5%,锡回收率33.8%)、超细长石(产率18%)、陶瓷级长石产品(产率69%),充分回收了原矿的价值矿物组分,达到了选矿厂无尾矿化生产的目的。Under the above-mentioned process flow, the ore can finally be separated into lepidolite concentrate containing 2.6% Li 2 O and a recovery rate of 73%, as well as qualified iron ore concentrate (TFe=55%), tantalum-niobium-tin concentrate ( Ta 2 O 5 recovery rate 34.2%, Nb 2 O 5 recovery rate 22.5%, tin recovery rate 33.8%), ultra-fine feldspar (yield 18%), ceramic grade feldspar products (yield 69%), fully recovered The valuable mineral components of the raw ore are removed, and the purpose of tailing-free production of the mineral processing plant is achieved.

实施例2Example 2

本实施例与实施例1的不同之处在于,在步骤S4中,通过在布溜扫选后增加一组旋流器和高频细筛分级作业,进一步回收筛上物中的钽铌矿物,钽铌回收率提升,而且可增加长石的白度,使其作为高白度长石产品进行出售。The difference between this embodiment and Embodiment 1 is that in step S4, a set of cyclones and high-frequency fine screen classification operations are added after the cloth slide is swept to further recover the tantalum and niobium minerals in the sieve supernatant, The recovery rate of tantalum and niobium is increased, and the whiteness of feldspar can be increased, allowing it to be sold as a high-whiteness feldspar product.

实施例3Example 3

本实施例与实施例1的不同之处在于,步骤S6中,粗选矿浆质量浓度为35%,矿浆pH值为10,捕收剂、活化剂和分散剂粗选段用量分别为250g/t原矿,200g/t原矿,200g/t原矿,可得到含Li2O2.3%,回收率75%的锂云母精矿,陶瓷级长石产率则略有降低。The difference between this embodiment and Example 1 is that in step S6, the mass concentration of the roughing slurry is 35%, the pH value of the slurry is 10, and the amounts of collector, activator and dispersant in the roughing section are 250g/t raw ore respectively. , 200g/t raw ore, 200g/t raw ore can obtain lepidolite concentrate containing Li 2 O2.3% and a recovery rate of 75%, while the yield of ceramic grade feldspar is slightly reduced.

实施例4Example 4

本实施例与实施例1的不同之处在于,步骤S6中,粗选矿浆质量浓度为25%,矿浆pH值为7,捕收剂、活化剂和分散剂粗选段用量分别为300g/t原矿,100g/t原矿,300g/t原矿,可得到含Li2O2.7%,回收率70%的锂云母精矿,陶瓷级长石产率则略有增大。The difference between this embodiment and Example 1 is that in step S6, the mass concentration of the roughing slurry is 25%, the pH value of the slurry is 7, and the amounts of collector, activator and dispersant in the roughing section are 300g/t raw ore respectively. , 100g/t raw ore, 300g/t raw ore, lepidolite concentrate containing Li 2 O2.7% and recovery rate of 70% can be obtained, and the yield of ceramic grade feldspar is slightly increased.

实施例5Example 5

本实施例与实施例1的不同之处在于,取消步骤S8中的分级再重选作业,将高梯度磁选尾矿与步骤S4所得摇床中矿直接给入步骤S2旋流器分级再磨作业,钽铌锡的回收率略有降低,超细长石产率增大,锂云母精矿Li2O回收率下降2%。The difference between this embodiment and Embodiment 1 is that the classification and gravity separation operations in step S8 are cancelled, and the high gradient magnetic separation tailings and the shaker middlings obtained in step S4 are directly fed to the cyclone in step S2 for classification and regrinding. During the operation, the recovery rate of tantalum, niobium and tin decreased slightly, the yield of ultra-slender feldspar increased, and the recovery rate of Li 2 O of lepidolite concentrate decreased by 2%.

对比例1Comparative example 1

与实施例1的不同之处在于,删除步骤S2中高频细筛作业,会出现跑粗现象,锂云母等矿物未能充分单体解离,浮选锂云母精矿品位和回收率均出现下降,分别为2.1%,65%,而铁精矿品位下降,长石精矿产率则略有增大。The difference from Example 1 is that deleting the high-frequency fine screening operation in step S2 will cause the phenomenon of coarsening. Minerals such as lepidolite cannot be fully dissociated into monomers, and the grade and recovery rate of flotation lepidolite concentrate will decrease. , 2.1% and 65% respectively, while the iron concentrate grade decreased and the feldspar concentrate yield increased slightly.

对比例2Comparative example 2

与实施例1的不同之处在于,步骤S6中,不添加活化剂,锂云母精矿品位(2.6%)基本不变,而回收率出现明显下降,为64%,长石中SiO2含量增多,品质下降。The difference from Example 1 is that in step S6, no activator is added, the lepidolite concentrate grade (2.6%) remains basically unchanged, while the recovery rate drops significantly to 64%, and the SiO 2 content in the feldspar increases. , the quality deteriorates.

上述实施例阐明的内容应当理解为这些实施例仅用于更清楚地说明本发明,而不用于限制本发明的范围,在阅读了本发明之后,本领域技术人员对本发明的各种等价形式的修改均落入本申请所附权利要求所限定的范围。The content illustrated in the above embodiments should be understood that these embodiments are only used to illustrate the present invention more clearly, and are not used to limit the scope of the present invention. After reading the present invention, those skilled in the art will be familiar with various equivalent forms of the present invention. All modifications fall within the scope defined by the appended claims of this application.

Claims (10)

1. The mineral separation method of the lepidolite ore is characterized by comprising the following steps of:
s1, crushing ores to obtain grinding materials;
s2, carrying out ore grinding classification operation on the materials to be ground;
s3, carrying out magnetic separation operation on the undersize obtained in the step S2 to obtain iron concentrate and magnetic separation tailings;
s4, carrying out multiple slip distribution operations and multiple shaking table gravity separation operations on the magnetic separation tailings to obtain tantalum-niobium-tin concentrate, gravity separation tailings and shaking table middlings;
s5, performing multistage desliming cyclone operation on the gravity tailings to obtain superfine feldspar and cyclone sand setting;
s6, feeding the cyclone sand setting into flotation operation to obtain lepidolite concentrate and flotation tailings;
s7, performing high-gradient magnetic separation operation on the flotation tailings to obtain feldspar and high-gradient magnetic separation concentrate;
and S8, mixing the high-gradient magnetic concentrate with the middlings of the cradle obtained in the step S4, and returning to the step S2.
2. The beneficiation process according to claim 1, wherein in step S1, the ore is crushed to a particle size of less than 12mm using a three-stage one-pass closed-circuit crushing and screening process.
3. The beneficiation method according to claim 1, wherein in the step S2, materials enter a cyclone after ball milling, the cyclone overflows and is fed into a high-frequency fine screen, and oversize materials and cyclone sand setting are returned to ball milling together; the granularity of the product under the high-frequency sieve is less than 0.15mm and accounts for 60-80 percent.
4. The beneficiation process according to claim 1, wherein in step S3, the magnetic field strength of the magnetic separation operation is 0.6-0.85T.
5. The beneficiation method according to claim 1, wherein in step S4, 2 operations of distributing and reselecting the cradle are adopted, and a roughing process and a scavenging process are adopted.
6. The beneficiation method according to claim 1, wherein in the step S5, 2 stages of desliming cyclones are closed-circuit operation, the overflow of the first stage of cyclones is fed into the second stage of cyclones, and the overflow of the second stage of cyclones is subjected to two stages of dewatering operation through an inclined plate thickener and a filter press.
7. The beneficiation method according to claim 1, wherein in the step S6, flotation operation is performed under the environment of pH 7-10, the mass concentration of rougher pulp is 25% -35%, and the flotation reagent comprises a collector, an activator and a dispersing agent, wherein the rougher stage of the collector, the activator and the dispersing agent is respectively used for 200-400g/t of raw ore, 100-300g/t of raw ore and 150-300g/t of raw ore.
8. The beneficiation process according to claim 7, wherein the activator is an aluminum chloride solution; the dispersing agent is sodium hexametaphosphate solution; the collector contains at least one of dodecyl amine, oleic acid, oxidized paraffin soap and tributyl phosphate.
9. The beneficiation method according to claim 1, wherein in step S7, the magnetic field strength of the high gradient magnetic separation operation is 1-2T.
10. The beneficiation method according to any one of claims 1 to 9, wherein in step S8, high gradient magnetic concentrate is mixed with the shaking middlings obtained in step S4, cyclone classification operation is performed, classified sand setting is performed in step S2, the mass concentration of the concentrated ore pulp after classification overflow is 10% -20%, classification overflow is performed in a distributing operation, distributing concentrate is performed in step S4, and distributing tailings are performed in step S5.
CN202310842595.4A 2023-07-11 2023-07-11 Mineral separation method of lepidolite ore Pending CN116832957A (en)

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CN119793680A (en) * 2025-01-20 2025-04-11 宜丰永洲锂业科技有限公司 A process for improving the recovery rate of lithium mica from lithium-containing china clay ore
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