CN116717354B - Emission treatment system suitable for lean-burn methanol engine and control method - Google Patents

Emission treatment system suitable for lean-burn methanol engine and control method Download PDF

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CN116717354B
CN116717354B CN202311009544.XA CN202311009544A CN116717354B CN 116717354 B CN116717354 B CN 116717354B CN 202311009544 A CN202311009544 A CN 202311009544A CN 116717354 B CN116717354 B CN 116717354B
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methanol
nitrogen
temperature
value
lean
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CN116717354A (en
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李志杰
翟天宇
张晓丽
曾笑笑
张瑜
满恒孝
杨春霞
李童
吴心波
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Weichai Power Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N11/00Monitoring or diagnostic devices for exhaust-gas treatment apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N11/00Monitoring or diagnostic devices for exhaust-gas treatment apparatus
    • F01N11/002Monitoring or diagnostic devices for exhaust-gas treatment apparatus the diagnostic devices measuring or estimating temperature or pressure in, or downstream of the exhaust apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N9/00Electrical control of exhaust gas treating apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D41/00Electrical control of supply of combustible mixture or its constituents
    • F02D41/02Circuit arrangements for generating control signals
    • F02D41/021Introducing corrections for particular conditions exterior to the engine
    • F02D41/0235Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
    • F02D41/024Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to increase temperature of the exhaust gas treating apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D41/00Electrical control of supply of combustible mixture or its constituents
    • F02D41/30Controlling fuel injection
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2560/00Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/02Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
    • F01N2560/026Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting NOx
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2560/00Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/06Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being a temperature sensor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2560/00Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/14Exhaust systems with means for detecting or measuring exhaust gas components or characteristics having more than one sensor of one kind

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

本发明提供一种适用于稀燃甲醇发动机的排放处理系统及控制方法,该系统由增压管路、增压管路控制阀、旁通管路、旁通管路控制阀、至少一个氧化催化器、一个甲醇作为还原剂的选择性还原催化器、至少两个温度传感器和两个氮氧传感器和控制执行系统所组成,由控制执行系统进行智能控制完成废气的排放处理。该系统结构简单、成本低,不使用尿素而是使用甲醇作为还原剂,由此用户不需要频繁加注尿素、正常加注甲醇即可、使用方便,并且甲醇供给方式采用缸内后喷,这就不需要额外的还原剂储罐、喷射系统等。

The invention provides an emission treatment system and a control method suitable for lean-burn methanol engines. The system consists of a booster pipeline, a booster pipeline control valve, a bypass pipeline, a bypass pipeline control valve, and at least one oxidation catalytic converter. It consists of a device, a selective reduction catalytic converter with methanol as the reducing agent, at least two temperature sensors and two nitrogen and oxygen sensors, and a control execution system. The control execution system carries out intelligent control to complete the exhaust gas emission treatment. The system has a simple structure and low cost. It does not use urea but uses methanol as the reducing agent. Therefore, users do not need to frequently add urea and just add methanol normally. It is easy to use and the methanol supply method adopts in-cylinder post-injection. This There is no need for additional reducing agent storage tanks, injection systems, etc.

Description

适用于稀燃甲醇发动机的排放处理系统及控制方法Emission treatment system and control method suitable for lean-burn methanol engines

技术领域Technical field

本发明涉及稀燃甲醇发动机技术领域,更具体地说,涉及一种适用于稀燃甲醇发动机的排放处理系统及控制方法。The present invention relates to the technical field of lean-burn methanol engines, and more specifically, to an emission treatment system and a control method suitable for lean-burn methanol engines.

背景技术Background technique

现有的稀燃甲醇发动机的后处理系统常照搬柴油机的DOC+DPF+urea-SCR+ASC技术路线。DOC通过催化氧化除去发动机排放的未燃烧或未完全燃烧的碳氢化合物或碳氢氧化合物;DPF通过其颗粒捕集功能除去发动机排放的颗粒;urea-SCR使用尿素作为还原剂,通过喷射尿素,先使尿素在较高温度下分解产生氨气,再由氨气与发动机产生的氮氧化物发生反应,将氮氧化物除去(为了能够保证氮氧化物被有效除去,这些氨气必须是过量的);最后ASC通过氧化反应除去urea-SCR中过量的氨气。The existing post-treatment system of lean-burn methanol engines often follows the DOC+DPF+urea-SCR+ASC technical route of diesel engines. DOC removes unburned or incompletely burned hydrocarbons or hydrocarbons emitted by the engine through catalytic oxidation; DPF removes particles emitted by the engine through its particle capture function; urea-SCR uses urea as a reducing agent, by injecting urea, First, urea is decomposed at a higher temperature to produce ammonia, and then the ammonia reacts with the nitrogen oxides produced by the engine to remove the nitrogen oxides (in order to ensure that nitrogen oxides are effectively removed, these ammonia must be in excess ); Finally, ASC removes excess ammonia in urea-SCR through oxidation reaction.

其技术缺陷在于零部件多,系统复杂,成本高等,特别是尿素需要专门的储罐、喷射泵、喷嘴等零部件。并且,发动机用户需要在加注燃料之外经常加注尿素。此外工业研究中发现甲醇与氨气在某些条件下有可能发生反应生成剧毒的氢氰酸,因此存在安全风险。Its technical shortcomings include many parts, complex systems, and high costs. In particular, urea requires special storage tanks, injection pumps, nozzles and other parts. Also, engine users need to frequently add urea in addition to fuel. In addition, industrial research has found that methanol and ammonia may react under certain conditions to form highly toxic hydrocyanic acid, which poses a safety risk.

发明内容Contents of the invention

有鉴于此,为解决上述问题,本发明提供一种适用于稀燃甲醇发动机的排放处理系统及控制方法,技术方案如下:In view of this, in order to solve the above problems, the present invention provides an emission treatment system and a control method suitable for lean-burn methanol engines. The technical solution is as follows:

一种适用于稀燃甲醇发动机的排放处理系统,所述系统包括:增压器旁通系统和后处理系统;An emission treatment system suitable for lean-burn methanol engines, the system includes: a supercharger bypass system and an aftertreatment system;

所述增压器旁通系统包含增压管路、增压管路控制阀、旁通管路、旁通管路控制阀和位于所述旁通管路上的第一氧化催化器;The supercharger bypass system includes a boost pipeline, a boost pipeline control valve, a bypass pipeline, a bypass pipeline control valve and a first oxidation catalytic converter located on the bypass pipeline;

所述后处理系统包含催化器系统和测控执行系统,所述催化器系统包含甲醇作为还原剂的选择性还原催化器和第二氧化催化器,所述测控执行系统包含测量系统和控制执行系统,所述测量系统包含第一温度传感器、第二温度传感器和第一氮氧传感器;其中,The post-treatment system includes a catalytic converter system and a measurement and control execution system. The catalytic converter system includes a selective reduction catalyst with methanol as a reducing agent and a second oxidation catalytic converter. The measurement and control execution system includes a measurement system and a control execution system. The measurement system includes a first temperature sensor, a second temperature sensor and a first nitrogen and oxygen sensor; wherein,

所述第一温度传感器和所述第一氮氧传感器位于所述选择性还原催化器上游,所述第二温度传感器位于所述选择性还原催化器与所述第二氧化催化器之间;The first temperature sensor and the first nitrogen oxygen sensor are located upstream of the selective reduction catalyst, and the second temperature sensor is located between the selective reduction catalyst and the second oxidation catalyst;

所述控制执行系统,用于采集所述第一温度传感器所测的第一温度值,并与预设的特征值进行对比;如果所述第一温度值大于或等于所述特征值,控制所述增压管路控制阀处于开启状态、所述旁通管路控制阀处于关闭状态,以使所述稀燃甲醇发动机所排出的废气通过所述增压管路、并使增压器对所述增压管路中的废气进行增压处理;采集所述第二温度传感器所测的第二温度值和所述第一氮氧传感器所测的第一氮氧浓度值,并根据所述第一温度值、所述第二温度值和所述第一氮氧浓度值计算第一甲醇喷射量;如果所述第一温度值小于所述特征值,控制所述增压管路控制阀处于关闭状态、所述旁通管路控制阀处于开启状态,以使所述稀燃甲醇发动机所排出的废气通过所述旁通管路、并使所述第一氧化催化器对所述旁通管路中的废气进行催化氧化;基于所述第一温度值和预设的升温需求计算第二甲醇喷射量;控制所述稀燃甲醇发动机的燃料喷射系统按照所述第一甲醇喷射量/所述第二甲醇喷射量进行缸内后喷,以使所述选择性还原催化器以甲醇对所述增压器/所述第一氧化催化器所排出废气中的氮氧化物进行催化还原,还使所述第二氧化催化器对所述选择性还原催化器所排出废气进行催化氧化。The control execution system is used to collect the first temperature value measured by the first temperature sensor and compare it with a preset characteristic value; if the first temperature value is greater than or equal to the characteristic value, control the The supercharging pipeline control valve is in an open state, and the bypass pipeline control valve is in a closed state, so that the exhaust gas discharged by the lean-burn methanol engine passes through the supercharging pipeline and allows the supercharger to The exhaust gas in the pressurization pipeline is pressurized; the second temperature value measured by the second temperature sensor and the first nitrogen oxygen concentration value measured by the first nitrogen oxygen sensor are collected, and the A temperature value, the second temperature value and the first nitrogen and oxygen concentration value are used to calculate the first methanol injection amount; if the first temperature value is less than the characteristic value, the booster pipeline control valve is controlled to be closed state, the bypass line control valve is in an open state, so that the exhaust gas discharged from the lean-burn methanol engine passes through the bypass line, and the first oxidation catalytic converter is connected to the bypass line. The exhaust gas in the engine is catalytically oxidized; the second methanol injection amount is calculated based on the first temperature value and the preset heating requirement; and the fuel injection system of the lean-burn methanol engine is controlled according to the first methanol injection amount/the third The dimethanol injection amount is used for in-cylinder post-injection, so that the selective reduction catalytic converter uses methanol to catalytically reduce the nitrogen oxides in the exhaust gas discharged from the supercharger/the first oxidation catalytic converter, and also allows the The second oxidation catalyst catalytically oxidizes the exhaust gas discharged from the selective reduction catalyst.

优选的,在上述排放处理系统中,所述测量系统还包含第二氮氧传感器,所述第二氮氧传感器位于所述选择性还原催化器与所述第二氧化催化器之间;Preferably, in the above emission treatment system, the measurement system further includes a second nitrogen oxygen sensor, the second nitrogen oxygen sensor is located between the selective reduction catalytic converter and the second oxidation catalytic converter;

所述控制执行系统还用于:The control execution system is also used to:

如果所述第一温度值大于或等于所述特征值,经过预设的第一运行时长重新采集所述第一氮氧浓度值、以及采集所述第二氮氧传感器所测的第二氮氧浓度值,并计算所述选择性还原催化器的氮氧转换效率;按照所述氮氧转换效率对所述第一甲醇喷射量进行调整。If the first temperature value is greater than or equal to the characteristic value, the first nitrogen oxygen concentration value and the second nitrogen oxygen concentration value measured by the second nitrogen oxygen sensor are collected again after a preset first running time. concentration value, and calculate the nitrogen-oxygen conversion efficiency of the selective reduction catalytic converter; adjust the first methanol injection amount according to the nitrogen-oxygen conversion efficiency.

优选的,在上述排放处理系统中,所述控制执行系统还用于:Preferably, in the above emission treatment system, the control execution system is also used for:

对比所述氮氧转换效率与预设的转换效率限值;如果所述氮氧转换效率小于所述转换效率限值,则禁止所述稀燃甲醇发动机后喷、并限速限扭。Compare the nitrogen-to-oxygen conversion efficiency with a preset conversion efficiency limit; if the nitrogen-to-oxygen conversion efficiency is less than the conversion efficiency limit, rear injection of the lean-burn methanol engine is prohibited and the speed and torque are limited.

优选的,所述控制执行系统,还用于:Preferably, the control execution system is also used for:

如果所述第一温度值小于所述特征值,经过预设的第二运行时长重新采集所述第一温度值,并重新与所述特征值进行对比;如果重新对比后所述第一温度值小于所述特征值,则禁止所述稀燃甲醇发动机后喷、并限速限扭。If the first temperature value is less than the characteristic value, the first temperature value is re-collected after the preset second running time, and compared with the characteristic value again; if the first temperature value is re-compared, If it is less than the characteristic value, the lean-burn methanol engine will be prohibited from rear injection, and the speed and torque will be limited.

优选的,所述测量系统包含第三温度传感器,所述第三温度传感器位于所述第二氧化催化器下游;Preferably, the measurement system includes a third temperature sensor located downstream of the second oxidation catalyst;

所述控制执行系统还用于:The control execution system is also used to:

如果所述第一温度值小于所述特征值,经过预设的第三运行时长重新采集所述第二温度值、以及采集所述第三温度传感器所测的第三温度值,并计算温度差值;若所述温度差值大于预设的温度差阈值,则禁止所述稀燃甲醇发动机后喷、并限速限扭。If the first temperature value is less than the characteristic value, the second temperature value and the third temperature value measured by the third temperature sensor are collected again after a preset third running time, and the temperature difference is calculated. value; if the temperature difference is greater than the preset temperature difference threshold, the lean-burn methanol engine is prohibited from rear injection and the speed and torque are limited.

优选的,在上述排放处理系统中,所述控制执行系统还用于:Preferably, in the above emission treatment system, the control execution system is also used for:

对所述第一温度传感器、所述第二温度传感器、所述第三温度传感器、所述第一氮氧传感器和所述第二氮氧传感器进行故障监测;如果所述第一温度传感器、所述第二温度传感器、所述第三温度传感器、所述第一氮氧传感器和所述第二氮氧传感器中的任意传感器出现故障,则禁止所述稀燃甲醇发动机后喷、并限速限扭。Perform fault monitoring on the first temperature sensor, the second temperature sensor, the third temperature sensor, the first nitrogen oxygen sensor and the second nitrogen oxygen sensor; if the first temperature sensor, the If any sensor among the second temperature sensor, the third temperature sensor, the first nitrogen oxygen sensor and the second nitrogen oxygen sensor fails, the lean-burn methanol engine will be prohibited from rear injection and the speed limit will be limited. Twist.

本申请还提供了一种控制方法,所述控制方法应用于适用于稀燃甲醇发动机的排放处理系统中的控制执行系统,所述方法包括:This application also provides a control method, which is applied to a control execution system in an emission treatment system suitable for lean-burn methanol engines. The method includes:

采集第一温度传感器所测的第一温度值,并与预设的特征值进行对比;Collect the first temperature value measured by the first temperature sensor and compare it with a preset characteristic value;

如果所述第一温度值大于或等于所述特征值,控制增压管路控制阀处于开启状态、旁通管路控制阀处于关闭状态,以使所述稀燃甲醇发动机所排出的废气通过增压管路、并使增压器对所述增压管路中的废气进行增压处理;If the first temperature value is greater than or equal to the characteristic value, control the booster pipeline control valve to be in an open state and the bypass pipeline control valve to be in a closed state, so that the exhaust gas discharged from the lean-burn methanol engine passes through the booster pipeline control valve. pressurize the pipeline and allow the supercharger to supercharge the exhaust gas in the supercharged pipeline;

采集第二温度传感器所测的第二温度值和第一氮氧传感器所测的第一氮氧浓度值,并根据所述第一温度值、所述第二温度值和所述第一氮氧浓度值计算第一甲醇喷射量;Collect the second temperature value measured by the second temperature sensor and the first nitrogen oxygen concentration value measured by the first nitrogen oxygen sensor, and use the first temperature value, the second temperature value and the first nitrogen oxygen concentration value to The concentration value calculates the first methanol injection amount;

如果所述第一温度值小于所述特征值,控制所述增压管路控制阀处于关闭状态、所述旁通管路控制阀处于开启状态,以使所述稀燃甲醇发动机所排出的废气通过旁通管路、并使第一氧化催化器对所述旁通管路中的废气进行催化氧化;If the first temperature value is less than the characteristic value, the boost line control valve is controlled to be in a closed state and the bypass line control valve is in an open state, so that the exhaust gas emitted by the lean-burn methanol engine Pass the bypass line and use the first oxidation catalytic converter to catalytically oxidize the exhaust gas in the bypass line;

基于所述第一温度值和预设的升温需求计算第二甲醇喷射量;Calculate the second methanol injection amount based on the first temperature value and the preset heating requirement;

控制所述稀燃甲醇发动机的燃料喷射系统按照所述第一甲醇喷射量/所述第二甲醇喷射量进行缸内后喷,以使选择性还原催化器以甲醇对所述增压器/所述第一氧化催化器所排出废气中的氮氧化物进行催化还原,还使第二氧化催化器对所述选择性还原催化器所排出废气进行催化氧化。The fuel injection system of the lean-burn methanol engine is controlled to perform in-cylinder post-injection according to the first methanol injection amount/the second methanol injection amount, so that the selective reduction catalyst uses methanol to inject the supercharger/the The nitrogen oxides in the exhaust gas discharged from the first oxidation catalytic converter are catalytically reduced, and the second oxidation catalytic converter is also allowed to catalytically oxidize the exhaust gas discharged from the selective reduction catalytic converter.

优选的,在上述控制方法中,所述方法还包括:Preferably, in the above control method, the method further includes:

如果所述第一温度值大于或等于所述特征值,经过预设的第一运行时长重新采集所述第一氮氧浓度值、以及采集第二氮氧传感器所测的第二氮氧浓度值,并计算所述选择性还原催化器的氮氧转换效率;If the first temperature value is greater than or equal to the characteristic value, the first nitrogen oxygen concentration value and the second nitrogen oxygen concentration value measured by the second nitrogen oxygen sensor are collected again after a preset first operating time. , and calculate the nitrogen-oxygen conversion efficiency of the selective reduction catalytic converter;

按照所述氮氧转换效率对所述第一甲醇喷射量进行调整。The first methanol injection amount is adjusted according to the nitrogen-oxygen conversion efficiency.

优选的,在上述控制方法中,所述方法还包括:Preferably, in the above control method, the method further includes:

对比所述氮氧转换效率与预设的转换效率限值;如果所述氮氧转换效率小于所述转换效率限值,则禁止所述稀燃甲醇发动机后喷、并限速限扭。Compare the nitrogen-to-oxygen conversion efficiency with a preset conversion efficiency limit; if the nitrogen-to-oxygen conversion efficiency is less than the conversion efficiency limit, rear injection of the lean-burn methanol engine is prohibited and the speed and torque are limited.

优选的,在上述控制方法中,所述方法还包括:Preferably, in the above control method, the method further includes:

如果所述第一温度值小于所述特征值,经过预设的第二运行时长重新采集所述第一温度值,并重新与所述特征值进行对比;If the first temperature value is less than the characteristic value, re-acquire the first temperature value after a preset second running time, and compare it with the characteristic value again;

如果重新对比后所述第一温度值小于所述特征值,则禁止所述稀燃甲醇发动机后喷、并限速限扭。If the first temperature value is smaller than the characteristic value after re-comparison, the lean-burn methanol engine is prohibited from post-injection and the speed and torque are limited.

相较于现有技术,本发明实现的有益效果为:Compared with the existing technology, the beneficial effects achieved by the present invention are:

本发明提供一种适用于稀燃甲醇发动机的排放处理系统及控制方法,控制执行系统采集第一温度传感器所测的第一温度值,并与预设的特征值进行对比;如果第一温度值大于或等于特征值,控制增压管路控制阀开启、旁通管路控制阀关闭,稀燃甲醇发动机所排出的废气通过增压管路、增压器对增压管路中的废气进行增压处理;采集第二温度传感器所测的第二温度值、第一氮氧传感器所测的第一氮氧浓度值和第二氮氧传感器所测的第二氮氧浓度值,并计算第一甲醇喷射量;如果第一温度值小于特征值,控制增压管路控制阀关闭、旁通管路控制阀开启,稀燃甲醇发动机所排出的废气通过旁通管路、第一氧化催化器对旁通管路中的废气进行催化氧化;基于第一温度值和预设的升温需求计算第二甲醇喷射量;控制稀燃甲醇发动机的燃料喷射系统按照第一甲醇喷射量/第二甲醇喷射量进行缸内后喷,选择性还原催化器以甲醇对增压器/第一氧化催化器所排出废气中的氮氧化物进行催化还原,第二氧化催化器对选择性还原催化器所排出废气进行催化氧化。The invention provides an emission treatment system and a control method suitable for lean-burn methanol engines. The control execution system collects the first temperature value measured by the first temperature sensor and compares it with the preset characteristic value; if the first temperature value Greater than or equal to the characteristic value, the control valve of the supercharging pipeline is opened and the control valve of the bypass pipeline is closed. The exhaust gas emitted by the lean-burn methanol engine increases the exhaust gas in the supercharging pipeline through the supercharging pipeline and the supercharger. pressure processing; collecting the second temperature value measured by the second temperature sensor, the first nitrogen oxygen concentration value measured by the first nitrogen oxygen sensor, and the second nitrogen oxygen concentration value measured by the second nitrogen oxygen sensor, and calculating the first Methanol injection amount; if the first temperature value is less than the characteristic value, the control valve of the booster pipeline is closed and the control valve of the bypass pipeline is opened. The exhaust gas discharged from the lean-burn methanol engine passes through the bypass pipeline and the first oxidation catalytic converter. The exhaust gas in the bypass line is catalytically oxidized; the second methanol injection amount is calculated based on the first temperature value and the preset temperature rise demand; and the fuel injection system of the lean-burn methanol engine is controlled according to the first methanol injection amount/the second methanol injection amount. In-cylinder post-injection is performed, the selective reduction catalytic converter uses methanol to catalytically reduce the nitrogen oxides in the exhaust gas discharged from the supercharger/first oxidation catalytic converter, and the second oxidation catalytic converter catalytically reduces the exhaust gas discharged from the selective reduction catalytic converter. Oxidation.

在本发明中,整个排放处理系统由增压管路、增压管路控制阀、旁通管路、旁通管路控制阀、至少一个氧化催化器、一个甲醇作为还原剂的选择性还原催化器、至少两个温度传感器和两个氮氧传感器和控制执行系统所组成,由控制执行系统进行智能控制完成废气的排放处理。控制执行系统可以集成于发动机控制单元中。该系统结构简单、成本低,不使用尿素而是使用甲醇作为还原剂,由此用户不需要频繁加注尿素、正常加注甲醇即可、使用方便,并且甲醇供给方式采用缸内后喷,这就不需要额外的还原剂储罐、喷射系统等。In the present invention, the entire emission treatment system consists of a booster pipeline, a booster pipeline control valve, a bypass pipeline, a bypass pipeline control valve, at least one oxidation catalyst, and a selective reduction catalytic converter with methanol as the reducing agent. It consists of a sensor, at least two temperature sensors, two nitrogen and oxygen sensors and a control execution system. The control execution system carries out intelligent control to complete the exhaust gas emission treatment. The control execution system can be integrated into the engine control unit. The system has a simple structure and low cost. It does not use urea but uses methanol as the reducing agent. Therefore, users do not need to frequently add urea and can just add methanol normally. It is easy to use and the methanol supply method adopts post-injection in the cylinder. This There is no need for additional reducing agent storage tanks, injection systems, etc.

附图说明Description of the drawings

为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据提供的附图获得其他的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings in the following description are only These are embodiments of the present invention. For those of ordinary skill in the art, other drawings can be obtained based on the provided drawings without exerting creative efforts.

图1为本发明实施例提供的一种适用于稀燃甲醇发动机的排放处理系统的结构示意图;Figure 1 is a schematic structural diagram of an emission treatment system suitable for lean-burn methanol engines provided by an embodiment of the present invention;

图2为本发明实施例提供的与图1所示排放处理系统相匹配的稀燃甲醇发动机的布置结构;Figure 2 is a layout structure of a lean-burn methanol engine matching the emission treatment system shown in Figure 1 provided by an embodiment of the present invention;

图3为本发明实施例提供的一种控制方法的方法流程图。Figure 3 is a method flow chart of a control method provided by an embodiment of the present invention.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of the present invention.

为方便理解本发明,以下首先对本发明涉及的相关概念进行说明:In order to facilitate understanding of the present invention, the relevant concepts involved in the present invention are first described below:

(1)稀燃甲醇发动机:也可称之为稀薄燃烧的甲醇发动机。即使用甲醇作为燃料、空气与燃料比例高于化学计量比的内燃机。由于甲醇的物理化学性质及燃烧特性,稀薄燃烧的甲醇发动机具有区别于柴油发动机(也是稀薄燃烧)的一些独特性质:(1) Lean-burn methanol engine: It can also be called a lean-burn methanol engine. That is, an internal combustion engine that uses methanol as fuel and the ratio of air to fuel is higher than the stoichiometric ratio. Due to the physical and chemical properties and combustion characteristics of methanol, lean-burn methanol engines have some unique properties that are different from diesel engines (which are also lean-burn):

1)排气温度特性:甲醇挥发性较柴油更高,与空气混合更充分,因此在常用工况下甲醇发动机排气温度较柴油发动机更高一些。但另一方面,由于甲醇热值较低,冷启动和升温较慢,此时缸内燃烧状态差,会排放出大量未燃的甲醇,以及甲醛等不完全燃烧产物。1) Exhaust temperature characteristics: Methanol is more volatile than diesel and mixes more fully with air. Therefore, the exhaust temperature of methanol engines is higher than that of diesel engines under common operating conditions. But on the other hand, due to the low calorific value of methanol, cold start and slow temperature rise, the combustion state in the cylinder is poor at this time, and a large amount of unburned methanol, as well as incomplete combustion products such as formaldehyde will be emitted.

2)排放物特性:2) Emission characteristics:

A.甲醇发动机排放物中含有较高浓度的甲醇和甲醛(冷启动时更甚)等碳氢氧化合物,其对人体大多有害。目前,国家环保部门已对道路用甲醇发动机的甲醇、甲醛排放水平提出管控要求。A. Methanol engine emissions contain relatively high concentrations of methanol and formaldehyde (more so during cold starts) and other carbon, hydrogen and oxygen compounds, which are mostly harmful to the human body. At present, the national environmental protection department has put forward control requirements for methanol and formaldehyde emission levels of methanol engines used on roads.

B.甲醇比柴油更易气化,相比于柴油液滴来说与空气混合更均匀,燃烧更加充分,因此颗粒物排放水平较低。B. Methanol is easier to vaporize than diesel, mixes more evenly with air than diesel droplets, and burns more completely, so the level of particulate matter emissions is lower.

C.由于采用稀薄燃烧,发动机内氧气过量,在高温、富氧条件下,发动机内氮气与氧气结合,生成大量氮氧化物,其中主要是一氧化氮,而二氧化氮较少。C. Due to the lean combustion, there is an excess of oxygen in the engine. Under high temperature and oxygen-rich conditions, nitrogen and oxygen in the engine combine to generate a large amount of nitrogen oxides, mainly nitric oxide and less nitrogen dioxide.

D.还有其他如一氧化碳、碳氢化合物等与柴油发动机类似的排放污染物。D. There are other pollutants such as carbon monoxide and hydrocarbons that are similar to diesel engines.

(2)后处理催化单元:通过催化剂,使发动机排气中的污染物、氧气和外加反应剂(可选)彼此发生反应,最终转化为无害的水、氮气、二氧化碳等物质。特定催化剂对特定反应的催化效率彼此不同,但均受温度影响较大,一般都有一定的温度区间能够令其发挥较高活性;如果低于活性区间,催化剂的转化效率不足;如果高于活性区间,不仅转化效率不足,长期使用还可能导致催化剂性能永久性下降。此外,随着排放法规愈发加严,现代发动机的后处理系统通常是多个催化单元的多级组合和系统集成控制。(2) Post-treatment catalytic unit: Through the catalyst, the pollutants, oxygen and external reactants (optional) in the engine exhaust react with each other, and are eventually converted into harmless water, nitrogen, carbon dioxide and other substances. The catalytic efficiency of specific catalysts for specific reactions is different from each other, but they are all greatly affected by temperature. Generally, there is a certain temperature range in which they can exert higher activity; if it is lower than the activity range, the conversion efficiency of the catalyst is insufficient; if it is higher than the activity interval, not only is the conversion efficiency insufficient, but long-term use may also lead to a permanent decline in catalyst performance. In addition, as emission regulations become increasingly stringent, the after-treatment system of modern engines is usually a multi-stage combination and system integration control of multiple catalytic units.

以下简单介绍了柴油、天然气发动机常用的几种后处理催化单元,及其在稀燃甲醇发动机上应用的可行性:The following is a brief introduction to several post-treatment catalytic units commonly used in diesel and natural gas engines, and their feasibility of application in lean-burn methanol engines:

1)三元催化器(TWC,Three-Way Catalyst),可通过其内部的贵金属促进三元催化反应,将排气中有害的一氧化碳、碳氢氧化合物、氮氧化物等,转化为无害的水、氮气和二氧化碳。三元催化器对甲醇、甲醛也有较好的处理能力,在当量燃烧的甲醇发动机有应用前景。但是稀燃甲醇发动机排气污染物比例与当量燃烧甲醇发动机不同,氮氧化物含量更高,TWC对其并不适用。1) Three-Way Catalyst (TWC, Three-Way Catalyst) can promote the three-way catalytic reaction through the precious metals inside it, converting harmful carbon monoxide, carbon hydroxides, nitrogen oxides, etc. in the exhaust into harmless water, nitrogen and carbon dioxide. The three-way catalytic converter also has good processing capabilities for methanol and formaldehyde, and has application prospects in equivalent combustion methanol engines. However, the ratio of exhaust pollutants of lean-burn methanol engines is different from that of equivalent-burning methanol engines. The nitrogen oxide content is higher, and TWC is not applicable to it.

2)氧化催化器(OC,Oxidation Catalyst),例如给柴油发动机后处理使用的DOC(Diesel Oxidation Catalyst),其原理是氧化型贵金属催化剂可以使将尾气中的一氧化碳、碳氢化合物、碳氢氧化合物等被氧气氧化为无害的水和二氧化碳。氧化催化剂对甲醇、甲醛有净化作用,可用于稀燃甲醇发动机。但是稀燃甲醇发动机在低温工况的未燃甲醇和不完全燃烧产物较多,直接使用DOC处理会使得这些排放物氧化释放的热量耗散,造成更大的能量损失。2) Oxidation Catalyst (OC, Oxidation Catalyst), such as DOC (Diesel Oxidation Catalyst) used for diesel engine after-treatment. The principle is that the oxidation precious metal catalyst can convert carbon monoxide, hydrocarbons, and carbon hydroxide compounds in the exhaust gas. etc. are oxidized by oxygen into harmless water and carbon dioxide. The oxidation catalyst has a purifying effect on methanol and formaldehyde and can be used in lean-burn methanol engines. However, lean-burn methanol engines have more unburned methanol and incomplete combustion products under low-temperature conditions. Direct use of DOC treatment will dissipate the heat released by the oxidation of these emissions, resulting in greater energy loss.

3)选择性还原催化器(SCR,Selected Catalyst Reduction)和氨逃逸催化器(ASC,Ammonia Slip Catalyst)。SCR的原理是通过催化剂,令还原剂(可以来自燃料,也可以额外注入)在催化剂的作用下与排气中的氮氧化物反应,最终转化为无害的水和氮气(可能还包括二氧化碳)。SCR可以通过还原剂的通入量控制,对反应程度进行灵活控制,因此也适用于氮氧排放高的稀燃甲醇发动机。SCR可以按照不同的还原剂区分,例如H2-SCR(氢气作为还原剂)、NH3-SCR(氨气作为还原剂)、Urea-SCR(尿素作为还原剂,先热分解生成氨气,再与氮氧化物反应)、HC-SCR(发动机的烃类燃料如汽油、柴油、天然气等直接作为还原剂)等。氨逃逸催化器(ASC,Ammonia Slip Catalyst),仅用于匹配NH3-SCR和Urea-SCR,由于这类SCR一般使用过量的还原剂,通过贵金属催化氧化,把SCR中剩余的过量氨气转化为无害的水和氮气。目前这方面柴油发动机应用最广泛的是Urea-SCR+ASC。3) Selected Catalyst Reduction (SCR) and Ammonia Slip Catalyst (ASC). The principle of SCR is to use a catalyst to allow the reducing agent (which can come from the fuel or be additionally injected) to react with the nitrogen oxides in the exhaust, eventually converting it into harmless water and nitrogen (and possibly carbon dioxide). . SCR can flexibly control the degree of reaction by controlling the amount of reductant introduced, so it is also suitable for lean-burn methanol engines with high nitrogen and oxygen emissions. SCR can be distinguished according to different reducing agents, such as H 2 -SCR (hydrogen is used as the reducing agent), NH 3 -SCR (ammonia is used as the reducing agent), Urea-SCR (urea is used as the reducing agent, which is first thermally decomposed to generate ammonia, and then Reacts with nitrogen oxides), HC-SCR (engine hydrocarbon fuels such as gasoline, diesel, natural gas, etc. directly serve as reducing agents), etc. Ammonia slip catalyst (ASC, Ammonia Slip Catalyst) is only used to match NH 3 -SCR and Urea-SCR. Since this type of SCR generally uses an excess of reducing agent, it converts the excess ammonia remaining in the SCR through precious metal catalytic oxidation. For harmless water and nitrogen. At present, the most widely used diesel engine in this regard is Urea-SCR+ASC.

但是,稀燃甲醇发动机使用Urea-SCR+ASC有一些不利因素,首先是尿素喷射需要单独布置尿素储罐、喷射系统等,用户使用时除了到甲醇站加注甲醇燃料,还要前往加油站或服务站加注尿素,成本高且使用不便。此外,一定条件下排气中未燃的甲醇甲醛等与尿素分解产生氨气可能发生氨氧化反应,生成剧毒的氢氰酸,反而有害人体健康。However, there are some disadvantages to using Urea-SCR+ASC in lean-burn methanol engines. The first is that urea injection requires a separate urea storage tank, injection system, etc. When using it, in addition to going to a methanol station to refill methanol fuel, users also have to go to a gas station or Urea is added at service stations, which is costly and inconvenient to use. In addition, under certain conditions, unburned methanol, formaldehyde, etc. in the exhaust may decompose with urea to produce ammonia gas, which may undergo an ammonia oxidation reaction to generate highly toxic hydrocyanic acid, which is harmful to human health.

甲醇也可以直接作为SCR反应的还原剂,即使用MeOH-SCR但是这种催化方式的活性温度窗口较Urea-SCR更窄,针对温度变化较大的发动机运行情况,后处理系统需要进行系统性的优化,本发明正是以此为核心进行系统性的设计及优化。Methanol can also be directly used as the reducing agent for the SCR reaction. Even if MeOH-SCR is used, the activity temperature window of this catalytic method is narrower than that of Urea-SCR. For engine operation conditions with large temperature changes, the post-processing system needs to be systematically modified. Optimization, the present invention takes this as the core to carry out systematic design and optimization.

4)颗粒捕集器(Particulate Filter),典型的例如柴油机使用的颗粒捕集器(DPF,Diesel Particulate Filter)。对于甲醇发动机而言,由于燃烧充分、颗粒物排放少,按照现行的法规限值,尚不需要颗粒捕集器。4) Particle trap (Particulate Filter), typically such as the particle trap (DPF, Diesel Particulate Filter) used in diesel engines. For methanol engines, due to sufficient combustion and low particulate matter emissions, particulate traps are not yet required according to current regulatory limits.

(3)燃料缸内后喷:指在一个发动机运行周期内,在燃料主喷(用于正常燃烧、输出动力)时间之后,再进行一次或多次喷射。此时由于发动机不处在燃烧冲程,后喷的燃料在缸内燃烧比例较少,大多直接从发动机排出。这种方式是为了满足某些特殊需求,例如后处理快速升温,或者在不增加喷嘴的情况下使燃料直接进入后处理中参与某些化学反应。这两种情况本发明均有涉及。(3) Post-injection in the fuel cylinder: refers to one or more injections after the main fuel injection (used for normal combustion and power output) during an engine operating cycle. At this time, because the engine is not in the combustion stroke, a small proportion of the post-injected fuel is burned in the cylinder, and most of it is discharged directly from the engine. This method is to meet certain special needs, such as rapid heating of the aftertreatment, or allowing fuel to directly enter the aftertreatment to participate in certain chemical reactions without adding a nozzle. Both cases are covered by the present invention.

在本申请的发明创造过程中,发明人经过研究发现:During the invention creation process of this application, the inventor discovered through research:

现有的稀燃甲醇发动机的后处理系统常照搬柴油机的DOC+DPF+urea-SCR+ASC技术路线,或者只省去DPF(即使用DOC+urea-SCR+ASC技术路线)。这类技术路线存在如下技术缺陷:The existing after-treatment systems of lean-burn methanol engines often copy the DOC+DPF+urea-SCR+ASC technical route of diesel engines, or only omit the DPF (that is, use the DOC+urea-SCR+ASC technical route). This type of technical route has the following technical flaws:

1)低温工况下未燃甲醇直接被DOC催化氧化,热量损失大;2)SCR需要引入尿素作为反应剂,因此产品中需匹配储罐、喷射系统等,成本高且使用不方便;3)应用到甲醇发动机上,SCR和ASC还可能有剧毒的氢氰酸等物质生成;4)有部分技术中虽然采用了甲醇-SCR避免了上述的各种问题,但需要布置额外的甲醇输送管路和甲醇喷嘴,对于为了除氮氧而喷射的过量甲醇如何处理也未详细说明,并且仍无法低温下甲醇-SCR活性不足的问题。1) Under low-temperature conditions, unburned methanol is directly catalytically oxidized by DOC, resulting in large heat loss; 2) SCR requires the introduction of urea as a reactant, so the product needs to be equipped with storage tanks, injection systems, etc., which is costly and inconvenient to use; 3) When applied to methanol engines, SCR and ASC may also generate highly toxic hydrocyanic acid and other substances; 4) Although some technologies use methanol-SCR to avoid the above-mentioned problems, additional methanol delivery pipes need to be arranged Road and methanol nozzle, there is no detailed explanation on how to deal with the excess methanol injected to remove nitrogen and oxygen, and the problem of insufficient methanol-SCR activity at low temperatures is still not solved.

由此可知当前技术的缺点在于热量损失大、所需零部件多、成本高、有剧毒排放物风险,或者缺乏系统性、全面性等。It can be seen that the shortcomings of current technology include large heat loss, many required parts, high cost, risk of highly toxic emissions, or lack of systematicness and comprehensiveness.

基于此,在本发明实施例中提出了一种适用于稀燃甲醇发动机的排放处理系统,能够有效在不同排气温度下高效地净化甲醇发动机尾气中的氮氧化物、一氧化碳、甲醇、甲醛等污染物且不引入新的有毒物质,并且使用甲醇燃料直接作为反应剂,热量利用率高,无需尿素等额外的反应剂,能够节约空间和成本。Based on this, in the embodiment of the present invention, an emission treatment system suitable for lean-burn methanol engines is proposed, which can effectively purify nitrogen oxides, carbon monoxide, methanol, formaldehyde, etc. in the exhaust of methanol engines at different exhaust temperatures. It eliminates pollutants without introducing new toxic substances, and uses methanol fuel directly as the reactant. It has high heat utilization rate and does not require additional reactants such as urea, which can save space and cost.

为使本发明的上述目的、特征和优点能够更加明显易懂,下面结合附图和具体实施方式对本发明作进一步详细的说明。In order to make the above objects, features and advantages of the present invention more obvious and understandable, the present invention will be described in further detail below with reference to the accompanying drawings and specific embodiments.

本发明实施例提供的适用于稀燃甲醇发动机的排放处理系统包括增压器旁通系统和后处理系统,后处理系统包含催化器系统和测控执行系统,测控执行系统包含测量系统和控制执行系统。The emission treatment system suitable for lean-burn methanol engines provided by the embodiment of the present invention includes a supercharger bypass system and a post-processing system. The post-processing system includes a catalytic converter system and a measurement and control execution system. The measurement and control execution system includes a measurement system and a control execution system. .

参考图1,图1为本发明实施例提供的一种适用于稀燃甲醇发动机的排放处理系统的结构示意图,该排放处理系统中增压器旁通系统包含增压管路1、增压管路控制阀2、旁通管路3、旁通管路控制阀4和位于旁通管路3上的第一氧化催化器5(即图1中位于旁通管路3上的OC),催化器系统包含甲醇作为还原剂的选择性还原催化器6(即图1中的MeOH-SCR)和第二氧化催化器7(即图1中位于MeOH-SCR下游的OC),测量系统包含位于选择性还原催化器6上游的第一温度传感器8、位于选择性还原催化器6与第二氧化催化器7之间第二温度传感器9、位于第二氧化催化器7下游的第三温度传感器10、位于选择性还原催化器6上游的第一氮氧传感器11和位于选择性还原催化器6与第二氧化催化器7之间的第二氮氧传感器12。Referring to Figure 1, Figure 1 is a schematic structural diagram of an emission treatment system suitable for lean-burn methanol engines provided by an embodiment of the present invention. The supercharger bypass system in the emission treatment system includes a supercharger pipeline 1, a supercharger pipe path control valve 2, bypass line 3, bypass line control valve 4 and the first oxidation catalytic converter 5 located on the bypass line 3 (that is, the OC located on the bypass line 3 in Figure 1), the catalytic The system includes a selective reduction catalyst 6 with methanol as the reducing agent (i.e., MeOH-SCR in Figure 1) and a second oxidation catalyst 7 (i.e., OC located downstream of MeOH-SCR in Figure 1). The measurement system includes a selective reduction catalyst located at The first temperature sensor 8 upstream of the selective reduction catalytic converter 6, the second temperature sensor 9 located between the selective reduction catalytic converter 6 and the second oxidation catalytic converter 7, the third temperature sensor 10 located downstream of the second oxidation catalytic converter 7, The first nitrogen oxygen sensor 11 is located upstream of the selective reduction catalyst 6 and the second nitrogen oxygen sensor 12 is located between the selective reduction catalyst 6 and the second oxidation catalyst 7 .

如图1所示,适用于稀燃甲醇发动机的排放处理系统还包含控制执行系统13,甲醇燃料箱A、稀燃甲醇发动机B、进气道喷射C、缸内直喷D、废气再循环系统(Exhaust GasRecirculation ,EGR)E、发动机控制单元(ECU)F。需要说明的是,图1中3~13为本发明新增的硬件结构,而1~2、以及A~F则可以组成一台常规的、不带后处理的甲醇发动机,此外,图1中虚线所示的废气再循环系统E为可选结构。参见图2,图2为本发明实施例提供的与图1所示排放处理系统相匹配的稀燃甲醇发动机的布置结构,其中,甲醇动力系统包括排放处理系统和其它内容,排放处理系统包括增压器旁通系统和后处理系统,增压器旁通系统包含增压管路1、增压管路控制阀2、旁通管路3、旁通管路控制阀4和第一氧化催化器5,后处理系统包含催化器系统和测控执行系统,催化器系统包含选择性还原催化器6和第二氧化催化器7,测控执行系统包含测量系统和控制执行系统13,测量系统包含第一温度传感器8、第二温度传感器9、第三温度传感器10、第一氮氧传感器11和第二氮氧传感器12,其它内容包含甲醇燃料箱A、稀燃甲醇发动机B、进气道喷射C、缸内直喷D、废气再循环系统E、发动机控制单元F,控制执行系统13可以包含于发动机控制单元F中(即控制执行系统13可以集成于发动机控制单元F中)。As shown in Figure 1, the emission treatment system suitable for lean-burn methanol engines also includes a control execution system 13, methanol fuel tank A, lean-burn methanol engine B, port injection C, in-cylinder direct injection D, and exhaust gas recirculation system (Exhaust GasRecirculation, EGR) E. Engine control unit (ECU) F. It should be noted that 3 to 13 in Figure 1 are new hardware structures of the present invention, while 1 to 2 and A to F can form a conventional methanol engine without post-processing. In addition, in Figure 1 The exhaust gas recirculation system E shown in dotted lines is an optional structure. Referring to Figure 2, Figure 2 is an arrangement structure of a lean-burn methanol engine matching the emission treatment system shown in Figure 1 provided by an embodiment of the present invention. The methanol power system includes an emission treatment system and other contents. The emission treatment system includes an additional Pressure bypass system and after-treatment system, the supercharger bypass system includes booster pipeline 1, booster pipeline control valve 2, bypass pipeline 3, bypass pipeline control valve 4 and the first oxidation catalytic converter 5. The post-treatment system includes a catalytic converter system and a measurement and control execution system. The catalytic converter system includes a selective reduction catalytic converter 6 and a second oxidation catalytic converter 7. The measurement and control execution system includes a measurement system and a control execution system 13. The measurement system includes the first temperature Sensor 8, second temperature sensor 9, third temperature sensor 10, first nitrogen oxygen sensor 11 and second nitrogen oxygen sensor 12. Other contents include methanol fuel tank A, lean methanol engine B, port injection C, cylinder Internal direct injection D, exhaust gas recirculation system E, engine control unit F, the control execution system 13 may be included in the engine control unit F (that is, the control execution system 13 may be integrated into the engine control unit F).

基于图1所示的本发明的结构,空气通过进气管进入稀燃甲醇发动机B,甲醇燃料由甲醇燃料箱A通过燃料输送管以进气道喷射C或缸内直喷D的方式输入稀燃甲醇发动机B中,燃烧并对外做功;然后稀燃甲醇发动机B燃烧产生的废气则流出,可使用废气再循环系统E使部分废气回流进入进气管中,也可不使用;最后废气经过增压器旁通系统和后处理系统被净化,最终排放到大气中。Based on the structure of the present invention shown in Figure 1, air enters the lean-burn methanol engine B through the intake pipe, and the methanol fuel is input into the lean-burn engine from the methanol fuel tank A through the fuel delivery pipe in the form of intake port injection C or in-cylinder direct injection D. In methanol engine B, it burns and performs external work; then the exhaust gas produced by the combustion of lean-burn methanol engine B flows out. The exhaust gas recirculation system E can be used to return part of the exhaust gas into the intake pipe, or it can not be used; finally, the exhaust gas passes next to the supercharger The purification system and after-treatment system are purified and finally discharged into the atmosphere.

具体的,控制执行系统13执行如下过程:Specifically, the control execution system 13 executes the following process:

采集第一温度传感器8所测的第一温度值,并与预设的特征值进行对比;Collect the first temperature value measured by the first temperature sensor 8 and compare it with the preset characteristic value;

如果第一温度值大于或等于特征值,控制增压管路控制阀2处于开启状态、旁通管路控制阀4处于关闭状态,以使稀燃甲醇发动机B所排出的废气通过增压管路1、并使增压器对增压管路1中的废气进行增压处理;采集第二温度传感器9所测的第二温度值和第一氮氧传感器11所测的第一氮氧浓度值,并根据第一温度值、第二温度值和第一氮氧浓度值计算第一甲醇喷射量;If the first temperature value is greater than or equal to the characteristic value, control the booster pipeline control valve 2 to be in an open state and the bypass pipeline control valve 4 to be in a closed state, so that the exhaust gas discharged by the lean-burn methanol engine B passes through the booster pipeline. 1. Let the supercharger supercharge the exhaust gas in the supercharging pipeline 1; collect the second temperature value measured by the second temperature sensor 9 and the first nitrogen oxygen concentration value measured by the first nitrogen oxygen sensor 11 , and calculate the first methanol injection amount according to the first temperature value, the second temperature value and the first nitrogen oxygen concentration value;

如果第一温度值小于特征值,控制增压管路控制阀2处于关闭状态、旁通管路控制阀4处于开启状态,以使稀燃甲醇发动机B所排出的废气通过旁通管路3、并使第一氧化催化器5对旁通管路3中的废气进行催化氧化;基于第一温度值和预设的升温需求计算第二甲醇喷射量;If the first temperature value is less than the characteristic value, control the boost line control valve 2 to be in a closed state and the bypass line control valve 4 to be in an open state, so that the exhaust gas discharged by the lean-burn methanol engine B passes through the bypass line 3, And make the first oxidation catalytic converter 5 catalytically oxidize the exhaust gas in the bypass line 3; calculate the second methanol injection amount based on the first temperature value and the preset temperature rise demand;

控制稀燃甲醇发动机B的燃料喷射系统按照第一甲醇喷射量/第二甲醇喷射量进行缸内后喷,以使选择性还原催化器6以甲醇对增压器/第一氧化催化器5所排出废气中的氮氧化物进行催化还原,还使第二氧化催化器7对选择性还原催化器6所排出废气进行催化氧化。The fuel injection system of the lean-burn methanol engine B is controlled to perform in-cylinder post-injection according to the first methanol injection amount/the second methanol injection amount, so that the selective reduction catalyst 6 uses methanol to inject the supercharger/first oxidation catalyst 5 The nitrogen oxides in the exhaust gas are catalytically reduced, and the second oxidation catalyst 7 is also allowed to catalytically oxidize the exhaust gas exhausted from the selective reduction catalyst 6 .

也就是说,针对选择性还原催化器6上游的第一温度传感器8所测的温度(即第一温度值)可以设置一特征值T(可根据不同的发动机用途、催化剂性能等具体设置),控制执行系统13对比第一温度值与特征值T。需要说明的是,该特征值T为催化活性限值。That is to say, a characteristic value T can be set for the temperature measured by the first temperature sensor 8 upstream of the selective reduction catalytic converter 6 (i.e., the first temperature value) (which can be specifically set according to different engine uses, catalyst performance, etc.), The control execution system 13 compares the first temperature value with the characteristic value T. It should be noted that this characteristic value T is the catalytic activity limit.

当第一温度值大于或等于特征值T时,认为稀燃甲醇发动机B在较高的负荷下运行,此时排温足够高,各催化器可以以很高的效率工作。控制执行系统13控制增压管路控制阀2保持开启、旁通管路控制阀4保持关闭,使稀燃甲醇发动机B所排出的废气通过增压管路1、而不通过旁通管路3,此时可使增压器正常工作,保障发动机的增压性能。When the first temperature value is greater than or equal to the characteristic value T, it is considered that the lean-burn methanol engine B is running at a higher load. At this time, the exhaust temperature is high enough and each catalytic converter can work at a high efficiency. The control execution system 13 controls the booster pipeline control valve 2 to remain open and the bypass pipeline control valve 4 to remain closed, so that the exhaust gas discharged from the lean-burn methanol engine B passes through the booster pipeline 1 instead of the bypass pipeline 3 , at this time, the supercharger can work normally and ensure the supercharging performance of the engine.

废气则继续通入选择性还原催化器6中,根据选择性还原催化器6上下游温度传感器和上游氮氧浓度传感器测量的值(即第一温度值、第二温度传感器9所测的第二温度值、第一氮氧传感器11所测的第一氮氧浓度值)计算此时所需甲醇还原剂的量(即第一甲醇喷射量),并控制稀燃甲醇发动机B的燃料喷射系统(进气道喷射C或缸内直喷D)通过缸内后喷提供对应数量的甲醇,从而实现甲醇对氮氧化物的催化还原,生成无害的水、二氧化碳和氮气。需要说明的是,根据选择性还原催化器6上下游温度传感器和上游氮氧浓度传感器测量的值计算第一甲醇喷射量的过程,为行业内成熟的实现方案,在此不再赘述,举例来说,第一甲醇喷射量=第一氮氧浓度值×发动机排气流量×甲醇分子量×甲醇/氮氧化物理论分子比/(空气分子量×转化效率),其中,发动机排气流量=发动机进气流量+发动机燃料消耗量,发动机进气流量和发动机燃料消耗量为实时监控值、甲醇分子量、甲醇/氮氧化物理论分子比、空气分子量为固定值,转化效率为预设值、且与第一温度值和第二温度值的平均值相对应。The exhaust gas continues to pass into the selective reduction catalytic converter 6. According to the values measured by the upstream and downstream temperature sensors of the selective reduction catalytic converter 6 and the upstream nitrogen and oxygen concentration sensor (i.e., the first temperature value, the second temperature value measured by the second temperature sensor 9 temperature value, the first nitrogen oxygen concentration value measured by the first nitrogen oxygen sensor 11) to calculate the amount of methanol reducing agent required at this time (i.e., the first methanol injection amount), and control the fuel injection system of the lean-burn methanol engine B ( Port injection C or in-cylinder direct injection D) provides a corresponding amount of methanol through in-cylinder post-injection, thereby achieving the catalytic reduction of nitrogen oxides by methanol and generating harmless water, carbon dioxide and nitrogen. It should be noted that the process of calculating the first methanol injection amount based on the values measured by the upstream and downstream temperature sensors and the upstream nitrogen and oxygen concentration sensor of the selective reduction catalytic converter 6 is a mature implementation solution in the industry and will not be described in detail here. For example, Say, the first methanol injection amount = the first nitrogen and oxygen concentration value × engine exhaust flow × methanol molecular weight × methanol/nitrogen oxide theoretical molecular ratio / (air molecular weight × conversion efficiency), where engine exhaust flow = engine intake air Flow + engine fuel consumption, engine air intake flow and engine fuel consumption are real-time monitoring values, methanol molecular weight, methanol/nitrogen oxide theoretical molecular ratio, air molecular weight are fixed values, conversion efficiency is a preset value, and is consistent with the first The temperature value corresponds to the average value of the second temperature value.

然后,废气再流经第二氧化催化器7,废气中含有的过量甲醇、甲醛、一氧化碳等被催化氧化为无害的水和二氧化碳,至此实现了对甲醇发动机尾气的高效净化处理。Then, the exhaust gas flows through the second oxidation catalytic converter 7, and excess methanol, formaldehyde, carbon monoxide, etc. contained in the exhaust gas are catalytically oxidized into harmless water and carbon dioxide. At this point, efficient purification of methanol engine exhaust gas is achieved.

在实际应用中,还可以辅以选择性还原催化器6上下游氮氧浓度传感器测量的值对选择性还原催化器6对除氮氧化物的效果进行监控和闭环。具体的,经过预设的第一运行时长重新采集第一氮氧浓度值、以及采集第二氮氧传感器12所测的第二氮氧浓度值,并以此计算选择性还原催化器6的氮氧转换效率,氮氧转换效率=(第一氮氧浓度值-第二氮氧浓度值) /第一氮氧浓度值;按照氮氧转换效率对第一甲醇喷射量进行调整。需要说明的是,按照氮氧转换效率对第一甲醇喷射量的调整方式,为行业内成熟的技术,在此不再赘述。In practical applications, the value measured by nitrogen and oxygen concentration sensors upstream and downstream of the selective reduction catalytic converter 6 can also be supplemented to monitor and close the loop on the effect of the selective reduction catalytic converter 6 on removing nitrogen oxides. Specifically, the first nitrogen and oxygen concentration value is re-collected after the preset first operating time, and the second nitrogen and oxygen concentration value measured by the second nitrogen and oxygen sensor 12 is collected, and the nitrogen of the selective reduction catalytic converter 6 is calculated based on this. Oxygen conversion efficiency, nitrogen-oxygen conversion efficiency = (first nitrogen-oxygen concentration value - second nitrogen-oxygen concentration value) / first nitrogen-oxygen concentration value; the first methanol injection amount is adjusted according to the nitrogen-oxygen conversion efficiency. It should be noted that the method of adjusting the first methanol injection amount according to the nitrogen-oxygen conversion efficiency is a mature technology in the industry and will not be described again here.

在此基础上,控制执行系统13还可以通过氮氧转换效率来监测系统故障。具体来说,对比氮氧转换效率与预设的转换效率限值;如果氮氧转换效率小于转换效率限值,则认为转换效率低,可能为喷射量错误或催化剂失败,此时禁止稀燃甲醇发动机后喷、并限速限扭,以防止发生事故,并报出警告,提示用户发动机或后处理有故障,需进行维修。当然,如果氮氧转换效率大于或等于转换效率限值,则继续监测。On this basis, the control execution system 13 can also monitor system faults through nitrogen-oxygen conversion efficiency. Specifically, compare the nitrogen-to-oxygen conversion efficiency with the preset conversion efficiency limit; if the nitrogen-to-oxygen conversion efficiency is less than the conversion efficiency limit, it is considered that the conversion efficiency is low, possibly due to an incorrect injection amount or catalyst failure, and lean methanol is prohibited at this time. The engine sprays after the engine and limits the speed and torque to prevent accidents, and issues a warning to remind the user that the engine or aftertreatment is faulty and requires repair. Of course, if the nitrogen-oxygen conversion efficiency is greater than or equal to the conversion efficiency limit, continue monitoring.

当第一温度值小于特征值T时,认为此时稀燃甲醇发动机B的排温不足以让各催化器有效发挥活性,此时应当令后处理快速升温。一方面,控制执行系统13控制增压管路控制阀2保持关闭、旁通管路控制阀4保持开启,使稀燃甲醇发动机B所排出的废气通过旁通管路3和第一氧化催化器5、而不通过增压管路1,这是因为此时增压器会导致排气温度下降,在需要提升排温的情况下应避免再降排温的情况;另一方面,此时也应开启燃料缸内后喷,借助旁通管路3中的第一氧化催化器5,使后喷的未在缸内燃烧的甲醇在第一氧化催化器5上迅速氧化放热,提高后处理温度。当然,在此过程中,如果当前的第一温度值等于或大于特征值T,则结束该过程,控制执行系统13执行以上“第一温度值大于或等于特征值”条件下的控制方案。When the first temperature value is less than the characteristic value T, it is considered that the exhaust temperature of the lean-burn methanol engine B is not sufficient for each catalytic converter to effectively activate, and the after-treatment should be rapidly heated at this time. On the one hand, the control execution system 13 controls the supercharging pipeline control valve 2 to remain closed and the bypass pipeline control valve 4 to remain open, so that the exhaust gas discharged from the lean-burn methanol engine B passes through the bypass pipeline 3 and the first oxidation catalytic converter. 5. Do not pass through the booster pipeline 1. This is because the supercharger will cause the exhaust temperature to drop at this time. If the exhaust temperature needs to be increased, it should be avoided to lower the exhaust temperature again. On the other hand, this is also The post-injection in the fuel cylinder should be turned on, and with the help of the first oxidation catalytic converter 5 in the bypass line 3, the post-injected methanol that is not burned in the cylinder can be quickly oxidized and exothermic on the first oxidation catalytic converter 5 to improve aftertreatment. temperature. Of course, during this process, if the current first temperature value is equal to or greater than the characteristic value T, the process ends, and the control execution system 13 executes the control plan under the above condition of "the first temperature value is greater than or equal to the characteristic value".

废气则继续通入选择性还原催化器6中,控制执行系统13基于第一温度值和预设的升温需求(即作为升温目标的目标温度值)计算此时所需甲醇还原剂的量(即第二甲醇喷射量),并控制稀燃甲醇发动机B的燃料喷射系统(进气道喷射C或缸内直喷D)通过缸内后喷提供对应数量的甲醇,从而实现甲醇对氮氧化物的催化还原,生成无害的水、二氧化碳和氮气。需要说明的是,基于第一温度和目标温度计算第二甲醇喷射量的过程,为行业内成熟的实现方案,在此不再赘述,举例来说,第二甲醇喷射量=选择性还原催化器6的热容×(目标温度值—温度值)/(甲醇热值×甲醇催化氧化热效率),其中,甲醇热值为固定值、而选择性还原催化器6的热容和甲醇催化氧化热效率可以通过简单且成熟的实验获取。The exhaust gas continues to flow into the selective reduction catalyst 6, and the control execution system 13 calculates the amount of methanol reducing agent required at this time (i.e., based on the first temperature value and the preset temperature rising demand (i.e., the target temperature value as the temperature rising target)). second methanol injection amount), and controls the fuel injection system (port injection C or in-cylinder direct injection D) of lean-burn methanol engine B to provide a corresponding amount of methanol through in-cylinder post-injection, thereby achieving the reduction of nitrogen oxides by methanol. Catalytic reduction produces harmless water, carbon dioxide and nitrogen. It should be noted that the process of calculating the second methanol injection amount based on the first temperature and the target temperature is a mature implementation solution in the industry, and will not be repeated here. For example, the second methanol injection amount = selective reduction catalyst 6 heat capacity Obtained through simple and proven experiments.

然后,废气再流经第二氧化催化器7,废气中含有的过量甲醇、甲醛、一氧化碳等被催化氧化为无害的水和二氧化碳,至此实现了对甲醇发动机尾气的高效净化处理。Then, the exhaust gas flows through the second oxidation catalytic converter 7, and excess methanol, formaldehyde, carbon monoxide, etc. contained in the exhaust gas are catalytically oxidized into harmless water and carbon dioxide. At this point, efficient purification of methanol engine exhaust gas is achieved.

在此基础上,控制执行系统13还可以通过第一温度值来监测系统故障。具体来说,经过预设的第二运行时长重新采集第一温度值,并重新与特征值进行对比;如果重新对比后第一温度值小于特征值,则认为后处理温升效率低,可能为喷射量错误或催化剂失败,此时禁止稀燃甲醇发动机后喷、并限速限扭,以防止发生事故,并报出警告,提示用户发动机或后处理有故障,需进行维修。当然,如果重新对比后第一温度值大于或等于特征值,则继续监测。On this basis, the control execution system 13 can also monitor system faults through the first temperature value. Specifically, the first temperature value is re-collected after the preset second running time, and compared with the characteristic value again; if the first temperature value is smaller than the characteristic value after re-comparison, it is considered that the post-processing temperature rise efficiency is low, which may be If the injection amount is wrong or the catalyst fails, the lean-burn methanol engine will be prohibited from post-injection and limited speed and torque to prevent accidents. A warning will be issued to remind the user that the engine or after-treatment is faulty and requires repair. Of course, if the first temperature value is greater than or equal to the characteristic value after re-comparison, monitoring will continue.

另外,控制执行系统13还可以通过第二温度值和第三温度传感器10所测的第三温度值来监测系统故障。具体来说,经过预设的第三运行时长重新采集第二温度值、以及采集第三温度传感器10所测的第三温度值,并计算温度差值(温度差值=第二温度值—第三温度值);若温度差值大于预设的温度差阈值,则认为第二氧化催化器7及其所在管路存在故障(一般可能是管路存在漏气、或者催化功能严重下降),此时禁止稀燃甲醇发动机后喷、并限速限扭。当然,如果温度差值小于或等于温度差值,则继续监测。In addition, the control execution system 13 can also monitor system faults through the second temperature value and the third temperature value measured by the third temperature sensor 10 . Specifically, the second temperature value is re-collected after the preset third running time, and the third temperature value measured by the third temperature sensor 10 is collected, and the temperature difference is calculated (temperature difference=second temperature value-th three temperature values); if the temperature difference is greater than the preset temperature difference threshold, it is considered that there is a fault in the second oxidation catalytic converter 7 and the pipeline in which it is located (generally, there may be air leakage in the pipeline, or the catalytic function is severely reduced), and this During this period, rear injection of lean-burn methanol engines is prohibited, and speed and torque limits are imposed. Of course, if the temperature difference is less than or equal to the temperature difference, continue monitoring.

另外,实际应用中,控制执行系统13还可以对传感器进行可信性判断,以此来监测系统故障。具体来说,对第一温度传感器8、第二温度传感器9、第三温度传感器10、第一氮氧传感器11和第二氮氧传感器12进行故障监测,也就是说,对第一温度值、第二温度值、第一氮氧浓度值和第二氮氧浓度值分别与其各自对应的安全可信上限、安全可信上限进行对比,以第一温度传感器8举例来说,如果采集的第一温度值大于其对应的安全可信上限、或者小于其对应的安全可信上限,则认为第一温度传感器8故障;如果第一温度传感器8、第二温度传感器9、第三温度传感器10、第一氮氧传感器11和第二氮氧传感器12中的任意传感器出现故障,则禁止稀燃甲醇发动机后喷、并限速限扭,以防止发生事故,并报出警告,提示用户发动机或后处理有故障,需进行维修。In addition, in practical applications, the control execution system 13 can also judge the credibility of the sensor to monitor system faults. Specifically, fault monitoring is performed on the first temperature sensor 8, the second temperature sensor 9, the third temperature sensor 10, the first nitrogen oxygen sensor 11 and the second nitrogen oxygen sensor 12, that is to say, the first temperature value, The second temperature value, the first nitrogen oxygen concentration value and the second nitrogen oxygen concentration value are respectively compared with their corresponding safe and trusted upper limits and safe and trusted upper limits. Taking the first temperature sensor 8 as an example, if the first collected If the temperature value is greater than its corresponding safe and trusted upper limit, or less than its corresponding safe and trusted upper limit, the first temperature sensor 8 is considered to be faulty; if the first temperature sensor 8, the second temperature sensor 9, the third temperature sensor 10, and the If any sensor in the first nitrogen oxygen sensor 11 and the second nitrogen oxygen sensor 12 fails, the rear injection of the lean-burn methanol engine will be prohibited and the speed and torque will be limited to prevent accidents, and a warning will be issued to remind the user of the engine or aftertreatment. It is faulty and needs to be repaired.

由此可见,本发明中基于以甲醇作为还原剂的SCR,通过稀燃甲醇发动机缸内后喷实现对发动机排放的氮氧化物的控制,再通过氧化催化处理过量的甲醇、甲醛、一氧化碳等其他污染物,实现了对甲醇发动机的高效低成本排放控制;通过增压器管路旁通结合氧化催化器的方式,实现了稀燃甲醇发动机低温工作时后处理的快速升温,使其温度尽快达到催化剂具有高转化效率的活性窗口。由此,本发明具有如下优势:It can be seen that the present invention is based on SCR using methanol as the reducing agent, and controls the nitrogen oxides emitted by the engine through post-injection in the lean-burn methanol engine cylinder, and then processes excess methanol, formaldehyde, carbon monoxide and other substances through oxidation catalysis. pollutants, achieving high-efficiency and low-cost emission control of methanol engines; through the supercharger pipeline bypass combined with the oxidation catalytic converter, the post-processing temperature of the lean-burn methanol engine is quickly heated when the engine is operating at low temperature, so that the temperature reaches the Catalysts have an active window with high conversion efficiency. Therefore, the present invention has the following advantages:

1)本发明提出了以缸内后喷甲醇作为还原剂的选择性催化还原方法,代替传统的尿素SCR净化氮氧化物,再配合氧化催化器处理过量甲醇、甲醛、一氧化碳等污染物,同时避免了甲醇氨氧化生成剧毒的氢氰酸的可能,从而实现了对稀燃甲醇发动机排放污染物的高效处理。并且相比于传统技术路线,不需要引入额外的反应剂,降低了系统复杂度,节约了零部件,降低了成本。1) The present invention proposes a selective catalytic reduction method using in-cylinder post-injection methanol as the reducing agent to replace the traditional urea SCR to purify nitrogen oxides, and then cooperate with an oxidation catalytic converter to treat excess methanol, formaldehyde, carbon monoxide and other pollutants, while avoiding It eliminates the possibility of ammonia oxidation of methanol to generate highly toxic hydrocyanic acid, thereby achieving efficient treatment of pollutants emitted by lean-burn methanol engines. And compared with the traditional technical route, there is no need to introduce additional reactants, which reduces system complexity, saves parts, and reduces costs.

2)针对甲醇发动机低温时排放污染物多、升温较慢的问题,本发明提出以缸内后喷甲醇+增压器管路旁通+前置催化氧化器的方式,令甲醇在氧化催化剂的作用下快速氧化放热,从而实现了后处理的快速升温,有利于使体系温度尽快进入催化剂的活性窗口,解决了现有方案中甲醇发动机低温工作时排放物难以控制的难题。2) In order to solve the problem of methanol engines emitting a lot of pollutants and slowing down the temperature rise at low temperatures, the present invention proposes the method of post-injection of methanol in the cylinder + supercharger pipeline bypass + pre-catalytic oxidizer, so that the methanol can be emitted in the oxidation catalyst. Rapid oxidation releases heat under the action, thereby achieving rapid temperature rise of the post-processing, which is conducive to bringing the system temperature into the activity window of the catalyst as soon as possible, solving the problem of difficult emission control when the methanol engine operates at low temperature in the existing solution.

3)本发明还提供了上述硬件系统的控制策略,不仅通过阀及后喷模式的切换实现了快速升温、高效催化,还针对体系可能具有的故障模式集成了识别、报警的功能。3) The present invention also provides a control strategy for the above hardware system, which not only achieves rapid temperature rise and efficient catalysis through switching of valves and post-injection modes, but also integrates identification and alarm functions for possible failure modes of the system.

综上,本发明提出的适用于稀燃甲醇发动机的排放处理系统,具有节约空间、节约成本、适用性广、高效净化、控制策略完善等优势。In summary, the emission treatment system proposed by the present invention and suitable for lean-burn methanol engines has the advantages of space saving, cost saving, wide applicability, efficient purification, and perfect control strategy.

可选的,基于本申请上述实施例提供的适用于稀燃甲醇发动机的排放处理系统,在本发明另一实施例中还提供了一种控制方法,该控制方法应用于其中的控制执行系统,参考图3,图3为本发明实施例提供的一种控制方法的方法流程图,包括如下步骤:Optionally, based on the emission treatment system suitable for lean-burn methanol engines provided in the above embodiments of the present application, another embodiment of the present invention also provides a control method, which is applied to the control execution system therein, Referring to Figure 3, Figure 3 is a method flow chart of a control method provided by an embodiment of the present invention, including the following steps:

S10,采集第一温度传感器所测的第一温度值,并与预设的特征值进行对比。S10: Collect the first temperature value measured by the first temperature sensor and compare it with a preset characteristic value.

S20,如果第一温度值大于或等于特征值,控制增压管路控制阀处于开启状态、旁通管路控制阀处于关闭状态,以使稀燃甲醇发动机所排出的废气通过增压管路、并使增压器对增压管路中的废气进行增压处理。S20, if the first temperature value is greater than or equal to the characteristic value, control the booster pipeline control valve to be in an open state and the bypass pipeline control valve to be in a closed state, so that the exhaust gas discharged from the lean-burn methanol engine passes through the booster pipeline, And the supercharger is used to supercharge the exhaust gas in the supercharging pipeline.

S30,采集第二温度传感器所测的第二温度值和第一氮氧传感器所测的第一氮氧浓度值,并根据第一温度值、第二温度值和第一氮氧浓度值计算第一甲醇喷射量。S30: Collect the second temperature value measured by the second temperature sensor and the first nitrogen oxygen concentration value measured by the first nitrogen oxygen sensor, and calculate the second temperature value based on the first temperature value, the second temperature value and the first nitrogen oxygen concentration value. One methanol injection volume.

S40,如果第一温度值小于特征值,控制增压管路控制阀处于关闭状态、旁通管路控制阀处于开启状态,以使稀燃甲醇发动机所排出的废气通过旁通管路、并使第一氧化催化器对旁通管路中的废气进行催化氧化。S40, if the first temperature value is less than the characteristic value, control the supercharging pipeline control valve to be in a closed state and the bypass pipeline control valve to be in an open state, so that the exhaust gas discharged by the lean-burn methanol engine passes through the bypass pipeline, and the bypass pipeline control valve is opened. The first oxidation catalytic converter catalytically oxidizes the exhaust gas in the bypass line.

S50,基于第一温度值和预设的升温需求计算第二甲醇喷射量。S50: Calculate the second methanol injection amount based on the first temperature value and the preset heating requirement.

S60,控制稀燃甲醇发动机的燃料喷射系统按照第一甲醇喷射量/第二甲醇喷射量进行缸内后喷,以使选择性还原催化器以甲醇对增压器/第一氧化催化器所排出废气中的氮氧化物进行催化还原,还使第二氧化催化器对选择性还原催化器所排出废气进行催化氧化。S60, control the fuel injection system of the lean-burn methanol engine to perform in-cylinder post-injection according to the first methanol injection amount/the second methanol injection amount, so that the selective reduction catalytic converter uses methanol to discharge the gas from the supercharger/first oxidation catalytic converter. The nitrogen oxides in the exhaust gas are catalytically reduced, and the second oxidation catalytic converter is also allowed to catalytically oxidize the exhaust gas discharged from the selective reduction catalytic converter.

可选的,在本发明另一实施例中,上述控制方法还包括如下步骤:Optionally, in another embodiment of the present invention, the above control method further includes the following steps:

如果第一温度值大于或等于特征值,经过预设的第一运行时长重新采集第一氮氧浓度值、以及采集第二氮氧传感器所测的第二氮氧浓度值,并计算选择性还原催化器的氮氧转换效率。If the first temperature value is greater than or equal to the characteristic value, the first nitrogen and oxygen concentration value is re-collected after the preset first running time, and the second nitrogen and oxygen concentration value measured by the second nitrogen and oxygen sensor is collected, and the selective reduction is calculated Nitrogen-oxygen conversion efficiency of the catalytic converter.

按照氮氧转换效率对第一甲醇喷射量进行调整。The first methanol injection amount is adjusted according to the nitrogen-oxygen conversion efficiency.

可选的,在本发明另一实施例中,上述控制方法还包括如下步骤:Optionally, in another embodiment of the present invention, the above control method further includes the following steps:

对比氮氧转换效率与预设的转换效率限值;如果氮氧转换效率小于转换效率限值,则禁止稀燃甲醇发动机后喷、并限速限扭。Compare the nitrogen-to-oxygen conversion efficiency with the preset conversion efficiency limit; if the nitrogen-to-oxygen conversion efficiency is less than the conversion efficiency limit, the lean-burn methanol engine will be prohibited from rear injection and the speed and torque will be limited.

可选的,在本发明另一实施例中,上述控制方法还包括如下步骤:Optionally, in another embodiment of the present invention, the above control method further includes the following steps:

如果第一温度值小于特征值,经过预设的第二运行时长重新采集第一温度值,并重新与特征值进行对比。If the first temperature value is smaller than the characteristic value, the first temperature value is re-collected after a preset second running time, and compared with the characteristic value again.

如果重新对比后第一温度值小于特征值,则禁止稀燃甲醇发动机后喷、并限速限扭。If the first temperature value is smaller than the characteristic value after re-comparison, the lean-burn methanol engine is prohibited from post-injection and the speed and torque are limited.

可选的,在本发明另一实施例中,上述控制方法还包括如下步骤:Optionally, in another embodiment of the present invention, the above control method further includes the following steps:

如果第一温度值小于特征值,经过预设的第三运行时长重新采集第二温度值、以及采集第三温度传感器所测的第三温度值,并计算温度差值;If the first temperature value is less than the characteristic value, re-acquire the second temperature value after the preset third running time, collect the third temperature value measured by the third temperature sensor, and calculate the temperature difference;

若温度差值大于预设的温度差阈值,则禁止稀燃甲醇发动机后喷、并限速限扭。If the temperature difference is greater than the preset temperature difference threshold, the lean-burn methanol engine is prohibited from rear injection and the speed and torque are limited.

可选的,在本发明另一实施例中,上述控制方法还包括如下步骤:Optionally, in another embodiment of the present invention, the above control method further includes the following steps:

对第一温度传感器、第二温度传感器、第三温度传感器、第一氮氧传感器和第二氮氧传感器进行故障监测。Perform fault monitoring on the first temperature sensor, the second temperature sensor, the third temperature sensor, the first nitrogen oxygen sensor and the second nitrogen oxygen sensor.

如果第一温度传感器、第二温度传感器、第三温度传感器、第一氮氧传感器和第二氮氧传感器中的任意传感器出现故障,则禁止稀燃甲醇发动机后喷、并限速限扭。If any sensor among the first temperature sensor, the second temperature sensor, the third temperature sensor, the first nitrogen oxygen sensor and the second nitrogen oxygen sensor fails, the rear injection of the lean-burn methanol engine is prohibited and the speed and torque are limited.

需要说明的是,本发明实施例中各步骤的细化执行过程可以参见上述适用于稀燃甲醇发动机的排放处理系统的对应说明处,在此不再赘述。It should be noted that the detailed execution process of each step in the embodiment of the present invention can be found in the corresponding description of the above-mentioned emission treatment system suitable for lean-burn methanol engines, and will not be described again here.

以上对本发明所提供的一种适用于稀燃甲醇发动机的排放处理系统及控制方法进行了详细介绍,本文中应用了具体个例对本发明的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本发明的方法及其核心思想;同时,对于本领域的一般技术人员,依据本发明的思想,在具体实施方式及应用范围上均会有改变之处,综上所述,本说明书内容不应理解为对本发明的限制。The above is a detailed introduction to an emission treatment system and control method suitable for lean-burn methanol engines provided by the present invention. Specific examples are used in this article to illustrate the principles and implementation modes of the present invention. The description of the above embodiments is only It is used to help understand the method and its core idea of the present invention; at the same time, for those of ordinary skill in the field, there will be changes in the specific implementation and application scope according to the idea of the present invention. In summary, this The content of the description should not be construed as limiting the invention.

需要说明的是,本说明书中的各个实施例均采用递进的方式描述,每个实施例重点说明的都是与其他实施例的不同之处,各个实施例之间相同相似的部分互相参见即可。对于实施例公开的装置而言,由于其与实施例公开的方法相对应,所以描述的比较简单,相关之处参见方法部分说明即可。It should be noted that each embodiment in this specification is described in a progressive manner. Each embodiment focuses on its differences from other embodiments. The same and similar parts between the various embodiments are referred to each other. Can. As for the device disclosed in the embodiment, since it corresponds to the method disclosed in the embodiment, the description is relatively simple. For relevant details, please refer to the description in the method section.

还需要说明的是,在本文中,诸如第一和第二等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。而且,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备所固有的要素,或者是还包括为这些过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should also be noted that in this article, relational terms such as first and second are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply that these entities or operations There is no such actual relationship or sequence between them. Furthermore, the terms "comprises," "comprises," or any other variation thereof are intended to cover a non-exclusive inclusion such that a list of elements inherent in, or otherwise included in, a process, method, article, or apparatus includes , elements inherent in a method, article or device. Without further limitation, an element defined by the statement "comprises a..." does not exclude the presence of additional identical elements in a process, method, article, or apparatus that includes the stated element.

对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。因此,本发明将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above description of the disclosed embodiments enables those skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be practiced in other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (10)

1. An emission treatment system suitable for use with a lean burn methanol engine, the system comprising: a supercharger bypass system and an aftertreatment system;
the booster bypass system comprises a booster pipeline, a booster pipeline control valve, a bypass pipeline control valve and a first oxidation catalyst positioned on the bypass pipeline;
the aftertreatment system comprises a catalyst system and a measurement and control execution system, wherein the catalyst system comprises a selective reduction catalyst and a second oxidation catalyst which take methanol as a reducing agent, the measurement and control execution system comprises a measurement system and a control execution system, and the measurement system comprises a first temperature sensor, a second temperature sensor and a first nitrogen-oxygen sensor; wherein,
The first temperature sensor and the first nitrogen-oxygen sensor are located upstream of the selective reduction catalyst, and the second temperature sensor is located between the selective reduction catalyst and the second oxidation catalyst;
the control execution system is used for collecting a first temperature value measured by the first temperature sensor and comparing the first temperature value with a preset characteristic value; if the first temperature value is greater than or equal to the characteristic value, controlling the supercharging pipeline control valve to be in an open state and the bypass pipeline control valve to be in a closed state, so that waste gas discharged by the lean-burn methanol engine passes through the supercharging pipeline and the supercharger carries out supercharging treatment on the waste gas in the supercharging pipeline; collecting a second temperature value measured by the second temperature sensor and a first nitrogen-oxygen concentration value measured by the first nitrogen-oxygen sensor, and calculating a first methanol injection amount according to the first temperature value, the second temperature value and the first nitrogen-oxygen concentration value; if the first temperature value is smaller than the characteristic value, controlling the pressurizing pipeline control valve to be in a closed state and the bypass pipeline control valve to be in an open state, so that the exhaust gas discharged by the lean-burn methanol engine passes through the bypass pipeline and the first oxidation catalyst carries out catalytic oxidation on the exhaust gas in the bypass pipeline; calculating a second methanol injection amount based on the first temperature value and a preset heating requirement; and controlling a fuel injection system of the lean-burn methanol engine to perform in-cylinder post injection according to the first methanol injection amount/the second methanol injection amount, so that the selective reduction catalyst performs catalytic reduction on nitrogen oxides in exhaust gas discharged by the supercharger/the first oxidation catalyst by methanol, and further performs catalytic oxidation on the exhaust gas discharged by the selective reduction catalyst by the second oxidation catalyst.
2. The system of claim 1, wherein the measurement system further comprises a second nitrogen-oxygen sensor located between the selective reduction catalyst and the second oxidation catalyst;
the control execution system is further configured to:
if the first temperature value is greater than or equal to the characteristic value, the first nitrogen-oxygen concentration value is acquired again through a preset first operation time period, the second nitrogen-oxygen concentration value measured by the second nitrogen-oxygen sensor is acquired, and the nitrogen-oxygen conversion efficiency of the selective reduction catalyst is calculated; and adjusting the injection quantity of the first methanol according to the nitrogen-oxygen conversion efficiency.
3. The system of claim 2, wherein the control execution system is further configured to:
comparing the nitrogen-oxygen conversion efficiency with a preset conversion efficiency limit value; and if the nitrogen-oxygen conversion efficiency is smaller than the conversion efficiency limit value, prohibiting the lean-burn methanol engine from post-injection, and limiting the speed and the torque.
4. The system of claim 1, wherein the control execution system is further configured to:
if the first temperature value is smaller than the characteristic value, the first temperature value is acquired again through a preset second operation duration, and the first temperature value is compared with the characteristic value again; and if the first temperature value is smaller than the characteristic value after re-comparison, prohibiting the lean-burn methanol engine from post-injection and limiting the speed and the torque.
5. The system of claim 2, wherein the measurement system further comprises a third temperature sensor located downstream of the second oxidation catalyst;
the control execution system is further configured to:
if the first temperature value is smaller than the characteristic value, the second temperature value is acquired again through a preset third operation time period, a third temperature value measured by the third temperature sensor is acquired, and a temperature difference value is calculated; and if the temperature difference is larger than a preset temperature difference threshold, prohibiting the lean-burn methanol engine from post-injection, and limiting the speed and the torque.
6. The system of claim 5, wherein the control execution system is further configured to:
performing fault monitoring on the first temperature sensor, the second temperature sensor, the third temperature sensor, the first nitrogen-oxygen sensor and the second nitrogen-oxygen sensor; and if any one of the first temperature sensor, the second temperature sensor, the third temperature sensor, the first nitrogen-oxygen sensor and the second nitrogen-oxygen sensor fails, the lean-burn methanol engine is forbidden to post-spray and limit the speed and the torque.
7. A control method, characterized in that the control method is applied to a control execution system in an emission treatment system adapted to a lean-burn methanol engine, the method comprising:
collecting a first temperature value measured by a first temperature sensor, and comparing the first temperature value with a preset characteristic value;
if the first temperature value is greater than or equal to the characteristic value, controlling a supercharging pipeline control valve to be in an open state and a bypass pipeline control valve to be in a closed state, so that waste gas discharged by the lean-burn methanol engine passes through a supercharging pipeline and a supercharger carries out supercharging treatment on the waste gas in the supercharging pipeline;
collecting a second temperature value measured by a second temperature sensor and a first nitrogen-oxygen concentration value measured by a first nitrogen-oxygen sensor, and calculating a first methanol injection amount according to the first temperature value, the second temperature value and the first nitrogen-oxygen concentration value;
if the first temperature value is smaller than the characteristic value, controlling the supercharging pipeline control valve to be in a closed state and the bypass pipeline control valve to be in an open state, so that waste gas discharged by the lean-burn methanol engine passes through a bypass pipeline, and enabling a first oxidation catalyst to catalyze and oxidize the waste gas in the bypass pipeline;
Calculating a second methanol injection amount based on the first temperature value and a preset heating requirement;
and controlling a fuel injection system of the lean-burn methanol engine to perform in-cylinder post injection according to the first methanol injection amount/the second methanol injection amount, so that the selective reduction catalyst performs catalytic reduction on nitrogen oxides in exhaust gas discharged by the supercharger/the first oxidation catalyst by methanol, and further performs catalytic oxidation on the exhaust gas discharged by the selective reduction catalyst by the second oxidation catalyst.
8. The method of claim 7, wherein the method further comprises:
if the first temperature value is greater than or equal to the characteristic value, the first nitrogen-oxygen concentration value is acquired again through a preset first operation time period, the second nitrogen-oxygen concentration value measured by a second nitrogen-oxygen sensor is acquired, and the nitrogen-oxygen conversion efficiency of the selective reduction catalyst is calculated;
and adjusting the injection quantity of the first methanol according to the nitrogen-oxygen conversion efficiency.
9. The method of claim 8, wherein the method further comprises:
comparing the nitrogen-oxygen conversion efficiency with a preset conversion efficiency limit value; and if the nitrogen-oxygen conversion efficiency is smaller than the conversion efficiency limit value, prohibiting the lean-burn methanol engine from post-injection, and limiting the speed and the torque.
10. The method of claim 7, wherein the method further comprises:
if the first temperature value is smaller than the characteristic value, the first temperature value is acquired again through a preset second operation duration, and the first temperature value is compared with the characteristic value again;
and if the first temperature value is smaller than the characteristic value after re-comparison, prohibiting the lean-burn methanol engine from post-injection and limiting the speed and the torque.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105179112A (en) * 2015-10-10 2015-12-23 天津大学 System and method for reducing NOx and particles in emitted pollutants of diesel engine
CN109184858A (en) * 2018-09-27 2019-01-11 潍柴动力股份有限公司 A kind of exhaust treatment system and method
CN109707495A (en) * 2018-12-19 2019-05-03 浙江大学 Diesel engine vent gas after-treatment system and processing method based on high chromium-stainless steel
CN110761874A (en) * 2018-07-26 2020-02-07 罗伯特·博世有限公司 Vehicle exhaust gas treatment system and exhaust gas treatment method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101684531B1 (en) * 2015-03-30 2016-12-08 현대자동차 주식회사 METHOD OF CALCULATING NOx MASS ABSORBED IN LEAN NOx TRAP OF EXHAUST PURIFICATION DEVICE AND EXHAUST PURIFICATION DEVICE
US11053828B2 (en) * 2015-11-11 2021-07-06 Tula Technology, Inc. Separately determining firing density and pumping density during firing density transitions for a lean-burn internal combustion engine

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105179112A (en) * 2015-10-10 2015-12-23 天津大学 System and method for reducing NOx and particles in emitted pollutants of diesel engine
CN110761874A (en) * 2018-07-26 2020-02-07 罗伯特·博世有限公司 Vehicle exhaust gas treatment system and exhaust gas treatment method
CN109184858A (en) * 2018-09-27 2019-01-11 潍柴动力股份有限公司 A kind of exhaust treatment system and method
CN109707495A (en) * 2018-12-19 2019-05-03 浙江大学 Diesel engine vent gas after-treatment system and processing method based on high chromium-stainless steel

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