CN116621369A - A system for the production, transmission, distribution and reuse of regenerated water into the heating network - Google Patents
A system for the production, transmission, distribution and reuse of regenerated water into the heating network Download PDFInfo
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- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
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- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
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Abstract
一种热网入网再生水生产、输配及回用系统,包括依次连通的超滤UF单元、两段反渗透RO单元和真空电化学除氧单元,所述超滤UF单元包括相连通的自清洗过滤器和超滤膜,所述两段反渗透RO单元包括依次连通的反渗透低压进水泵一、反渗透低压进水泵二和反渗透膜,所述真空电化学除氧单元包括相连通的真空电化学除氧器和除氧水池,所述除氧池内设置隔绝囊。该系统基于双膜法+真空电化学除氧工艺,对传统的城镇污水厂的出水进行深度处理,使之满足供热管网的入网水质标准,从而实现利用现有的供热管网进行再生水输配,且无需另行敷设再生水管网,从而减少了市政管网的建设。
A system for producing, distributing and reusing regenerated water into the heating network, including an ultrafiltration UF unit, a two-stage reverse osmosis RO unit, and a vacuum electrochemical oxygen removal unit connected in sequence, and the ultrafiltration UF unit includes a connected self-cleaning unit. filter and ultrafiltration membrane, the two-stage reverse osmosis RO unit includes reverse osmosis low-pressure water inlet pump one, reverse osmosis low-pressure water inlet pump two and reverse osmosis membrane connected in sequence, and the vacuum electrochemical deoxygenation unit includes a connected vacuum An electrochemical deaerator and a deaeration pool, wherein an isolation bag is arranged in the deaeration pool. Based on the double-membrane method + vacuum electrochemical deoxidation process, the system performs advanced treatment on the effluent of traditional urban sewage plants to make it meet the water quality standards of the heating pipe network, so as to realize the use of the existing heating pipe network for reclaimed water Transmission and distribution, and there is no need to lay additional reclaimed water pipe network, thus reducing the construction of municipal pipe network.
Description
技术领域technical field
本发明属于污水处理、再生水利用与供热管网融合技术领域,具体涉及一种热网入网再生水生产、输配及回用系统。The invention belongs to the technical field of sewage treatment, reclaimed water utilization and heating pipe network integration, and specifically relates to a system for producing, transporting, distributing and reusing regenerated water into a heating network.
背景技术Background technique
当前,城镇污水处理厂出水水质普遍达到一级A标准甚至更高,已经接近或超过供热管网设计的规范要求。如果将污水厂出水进行适当的深度处理,则城市供暖系统中的热水循环管路可作为再生水回用的管路平台,将供热管网进行合理优化与调配,在非采暖期,可利用现有的供热管网输配再生水,无需敷设新的中水管网,在采暖期,再生水可作为供热管网的补水水源且输送再生水至用户,进行厂外水处理和热量回收之后再利用。At present, the effluent quality of urban sewage treatment plants generally meets the first-class A standard or even higher, which is close to or exceeds the specification requirements for the design of the heating pipe network. If the effluent of the sewage plant is properly treated in depth, the hot water circulation pipeline in the urban heating system can be used as a pipeline platform for reclaimed water reuse, and the heating pipeline network can be rationally optimized and deployed. During the non-heating period, it can be used The existing heating pipe network transmits and distributes regenerated water without laying a new reclaimed water pipe network. During the heating period, regenerated water can be used as a supplementary water source for the heating pipe network and delivered to users for reuse after off-site water treatment and heat recovery .
再生水生产工艺的主要任务是脱盐,目前常用于大规模除盐的方法有离子交换法、电渗析法、反渗透法、电吸附法等。其中,离子交换法一般不单独使用,电吸附法单个模块处理量较小,电渗析法对于出水水质的保证率没有反渗透高。结合经济性和稳定性,采用反渗透工艺更适用于大规模城镇污水处理厂出水的深度处理。由于反渗透系统对于进水水质的要求非常严格,因此不能将水源直接由泵打入,需要采用超滤或微滤进行预处理。The main task of the reclaimed water production process is desalination. At present, the methods commonly used for large-scale desalination include ion exchange, electrodialysis, reverse osmosis, and electrosorption. Among them, the ion exchange method is generally not used alone, the processing capacity of a single module of the electroadsorption method is small, and the guarantee rate of the effluent water quality of the electrodialysis method is not as high as that of reverse osmosis. Combining economy and stability, the reverse osmosis process is more suitable for advanced treatment of large-scale urban sewage treatment plant effluent. Since the reverse osmosis system has very strict requirements on the quality of influent water, the water source cannot be pumped directly, and ultrafiltration or microfiltration is required for pretreatment.
常规的供热管网为闭式系统,如果将再生水输配至用户,整个系统将成为开式系统,空气容易进入管网,导致溶解氧含量上升,进而引发腐蚀。氧腐蚀是最常见也是最严重的腐蚀现象,供热管网对于进水溶解氧有着严格的标准(要求DO≤0.1mg/L),除氧是保证热网正常运行的关键步骤之一。真空电化学除氧集真空、电、化学三种除氧方法于一体,出水水质稳定,综合成本适中,是一种优越的除氧方式,这种除氧方式采用的除氧水储存装置不仅需要保证与空气隔绝,还要使得水箱进水时水箱内不会升压,水箱出水时不会抽空,始终保持常压。大规模工程应用时,采用数量巨大的成品除氧水箱是不现实的,需要设立混凝土结构的除氧水池,考虑到结构梁体的影响,采用柔性隔绝囊更为合适。The conventional heating pipe network is a closed system. If reclaimed water is delivered to users, the whole system will become an open system, and air can easily enter the pipe network, resulting in an increase in dissolved oxygen content, which in turn leads to corrosion. Oxygen corrosion is the most common and serious corrosion phenomenon. The heating pipe network has strict standards for influent dissolved oxygen (requires DO≤0.1mg/L), and oxygen removal is one of the key steps to ensure the normal operation of the heating network. Vacuum electrochemical deaeration integrates vacuum, electricity and chemical deaeration methods. The effluent water quality is stable and the comprehensive cost is moderate. It is a superior deaeration method. The deaeration water storage device used in this deaeration method not only needs It is guaranteed to be isolated from the air, and the pressure in the water tank will not be boosted when the water tank enters the water, and the water tank will not be evacuated when the water is discharged, and the normal pressure is always maintained. For large-scale engineering applications, it is unrealistic to use a large number of finished deaeration water tanks. It is necessary to set up a deaeration tank with a concrete structure. Considering the influence of the structural beam, it is more appropriate to use a flexible insulation bag.
发明内容Contents of the invention
针对上述问题,本发明的目的是提供一种热网入网再生水生产、输配及回用系统,该系统针对当前北方缺水城市污水再生,利用管网投资费用高而集中供热管网却未得到充分利用的现状,基于双膜法+真空电化学除氧工艺,对传统的城镇污水厂的出水进行深度处理,使之满足供热管网的入网水质标准,从而实现利用现有的供热管网进行再生水输配,且无需另行敷设再生水管网,从而减少了市政管网的建设。In view of the above problems, the purpose of the present invention is to provide a system for the production, distribution and reuse of regenerated water entering the heating network. This system is aimed at the regeneration of sewage in water-deficient cities in the north. Based on the current situation that has been fully utilized, based on the double-membrane method + vacuum electrochemical deoxidation process, the effluent of traditional urban sewage plants is subjected to advanced treatment to make it meet the water quality standards of the heating pipe network, so as to realize the utilization of existing heating The pipeline network is used for the transmission and distribution of recycled water, and there is no need to lay additional recycled water pipeline networks, thereby reducing the construction of municipal pipeline networks.
如上构思,本发明的技术方案是:一种热网入网再生水生产、输配及回用系统,其特征在于:包括依次连通的超滤UF单元、两段反渗透RO单元和真空电化学除氧单元,所述超滤UF单元包括相连通的自清洗过滤器和超滤膜,所述两段反渗透RO单元包括依次连通的反渗透低压进水泵一、反渗透低压进水泵二和反渗透膜,所述真空电化学除氧单元包括相连通的真空电化学除氧器和除氧水池,所述除氧池内设置隔绝囊。As conceived above, the technical solution of the present invention is: a system for the production, distribution and reuse of regenerated water entering the heating network, which is characterized in that it includes sequentially connected ultrafiltration UF units, two-stage reverse osmosis RO units and vacuum electrochemical oxygen removal unit, the ultrafiltration UF unit includes a connected self-cleaning filter and an ultrafiltration membrane, and the two-stage reverse osmosis RO unit includes reverse osmosis low-pressure inlet pump one, reverse osmosis low-pressure inlet pump two and reverse osmosis membrane connected in sequence , the vacuum electrochemical deoxygenation unit includes a connected vacuum electrochemical deaerator and an oxygen removal pool, and an isolation bag is arranged in the oxygen removal pool.
优选地,所述自清洗过滤器的出口连通排水沟,进口连接提升泵。Preferably, the outlet of the self-cleaning filter is connected to a drain, and the inlet is connected to a lift pump.
优选地,所述超滤膜的出口连接反洗废水池。Preferably, the outlet of the ultrafiltration membrane is connected to a backwash wastewater tank.
优选地,所述反渗透低压进水泵一和反渗透低压进水泵二之间安装保安过滤器。Preferably, a security filter is installed between the first reverse osmosis low-pressure water inlet pump and the second reverse osmosis low-pressure water inlet pump.
优选地,所述反渗透膜的出口连接浓水池。Preferably, the outlet of the reverse osmosis membrane is connected to a concentrated water tank.
优选地,所述真空电化学除氧器进水溶解氧≤12mg/L,出水溶解氧≤0.1mg/L。Preferably, the dissolved oxygen in the vacuum electrochemical deaerator is less than or equal to 12 mg/L, and the dissolved oxygen in the outlet water is less than or equal to 0.1 mg/L.
优选地,所述除氧水池的顶部设置排气管路与隔绝囊排气口相连,所述管路通室外。Preferably, an exhaust pipeline is provided on the top of the oxygen-removing pool to connect with the exhaust port of the isolation bag, and the pipeline leads to the outside.
本发明具有以下优点和积极效果:The present invention has the following advantages and positive effects:
1、本发明采用反渗透(RO)工艺对城镇污水处理厂经过常规工艺处理后的出水进行脱盐,其脱盐率可以维持在95~98%之间,出水电导率≤100us/cm,出水总硬度≤20mg/L,出水氯离子≤10mg/L,可以达到大部分再生水用户的水质需求;1. The present invention adopts the reverse osmosis (RO) process to desalinate the effluent of urban sewage treatment plants after conventional process treatment, the desalination rate can be maintained between 95% and 98%, the conductivity of the effluent is ≤100us/cm, and the total hardness of the effluent ≤20mg/L, effluent chlorine ion ≤10mg/L, which can meet the water quality requirements of most reclaimed water users;
2、本发明利用真空电化学工艺对出水进行除氧,满足供热管网对溶解氧的要求,DO≤0.1mg/L,设置除氧水池,隔绝除氧水与外界空气接触,满足储存量的要求;2. The present invention uses a vacuum electrochemical process to deoxygenate the outlet water to meet the requirements of the heating pipe network for dissolved oxygen, DO≤0.1mg/L, and set up a deoxygenation pool to isolate the deoxygenated water from contact with the outside air and meet the storage capacity requirements;
3、本发明采用柔性隔绝囊作为防止二次溶氧的措施,在除氧水池的顶部设置排气管路与隔绝囊排气口相连,该管路通室外,所述隔绝囊内为空气,囊外为水,当液位下降,除氧水池压力下降,空气从管道进入囊内,使除氧水池保持常压状态,同时与空气隔绝,从而可有效地解决了输配再生水过程中的管网腐蚀问题。3. The present invention adopts a flexible isolation bag as a measure to prevent secondary dissolved oxygen. An exhaust pipeline is arranged on the top of the deoxygenation pool to be connected to the exhaust port of the isolation bag. The pipeline leads to the outside, and the inside of the isolation bag is air. The outside of the capsule is water. When the liquid level drops, the pressure of the deoxygenated water pool drops, and the air enters the capsule from the pipeline, so that the deoxygenated water pool maintains a normal pressure state and is isolated from the air at the same time, thus effectively solving the pipeline problem in the process of transporting and distributing regenerated water. Mesh corrosion problem.
4、本发明将将污水厂出水进行适当的深度处理作为再生水作为供热管网的补水水源且输送再生水至用户,进行厂外水处理和热量回收之后再利用,可提升城市再生水回用率,使得市政供热管网得到充分利用,对实现水资源可持续循环利用具有重要意义。4. In the present invention, the effluent from the sewage plant will be properly treated as regenerated water as the replenishment water source of the heating pipe network, and the regenerated water will be transported to the user, and then reused after the off-site water treatment and heat recovery, which can increase the reuse rate of urban regenerated water. It is of great significance to realize the sustainable recycling of water resources to make full use of the municipal heating pipe network.
附图说明Description of drawings
图1是本发明的示意图。Figure 1 is a schematic diagram of the present invention.
具体实施方式Detailed ways
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.
如图1所示,本发明提供一种热网入网再生水生产、输配及回用系统,包括依次连通的超滤UF单元、两段反渗透RO单元和真空电化学除氧单元,所述超滤UF单元包括相连通的自清洗过滤器和超滤膜,所述两段反渗透RO单元包括依次连通的反渗透低压进水泵一、反渗透低压进水泵二和反渗透膜,所述真空电化学除氧单元包括依次连通的真空电化学除氧器和除氧水池+隔绝囊。As shown in Figure 1, the present invention provides a system for the production, distribution and reuse of regenerated water entering the heating network, which includes an ultrafiltration UF unit, a two-stage reverse osmosis RO unit, and a vacuum electrochemical oxygen removal unit connected in sequence. The filter UF unit includes a connected self-cleaning filter and an ultrafiltration membrane. The two-stage reverse osmosis RO unit includes a reverse osmosis low-pressure inlet pump one, a reverse osmosis low-pressure inlet pump two and a reverse osmosis membrane connected in sequence. The chemical deaeration unit includes a vacuum electrochemical deaerator and a deaeration water pool + isolation bag connected in sequence.
优选地,所述自清洗过滤器的出口连通排水沟,进口连接提升泵。Preferably, the outlet of the self-cleaning filter is connected to a drain, and the inlet is connected to a lift pump.
优选地,所述超滤膜的出口连接反洗废水池。Preferably, the outlet of the ultrafiltration membrane is connected to a backwash wastewater tank.
优选地,所述反渗透低压进水泵一和反渗透低压进水泵二之间安装保安过滤器。Preferably, a security filter is installed between the first reverse osmosis low-pressure water inlet pump and the second reverse osmosis low-pressure water inlet pump.
优选地,所述反渗透膜的出口连接浓水池。Preferably, the outlet of the reverse osmosis membrane is connected to a concentrated water tank.
优选地,所述真空电化学除氧器进水溶解氧≤12mg/L,出水溶解氧≤0.1mg/L。Preferably, the dissolved oxygen in the vacuum electrochemical deaerator is less than or equal to 12 mg/L, and the dissolved oxygen in the outlet water is less than or equal to 0.1 mg/L.
优选地,所述除氧水池的顶部设置排气管路与隔绝囊排气口相连,所述管路通室外。Preferably, an exhaust pipeline is provided on the top of the oxygen-removing pool to connect with the exhaust port of the isolation bag, and the pipeline leads to the outside.
本发明将北方某城镇污水处理厂经过常规工艺处理后的出水经过进水提升泵提升后进入本系统,经过自清洗过滤器净化之后进入超滤膜,超滤膜产生的废水排入反洗废水池,随后随厂区废水排走,超滤产水一部分用于化学清洗用水,另一部分依次经过反渗透低压水泵一、保安过滤器、反渗透高压进水泵二进入后续的反渗透膜,反渗透膜产生的浓水排入浓水池,随后随厂区废水排走或者进行浓水深度处理,产生的再生水则进入真空电化学除氧单元的真空电化学除氧器进行除氧,经过除氧器除氧后的除氧水输配至除氧水池+隔绝囊,作为防止真空系统二次溶氧的措施,使储水与大气隔绝,同时始终保持常压状态。所述除氧水池为真空电化学除氧器在大规模工程应用时,结合污水处理厂的土建形式建设的混凝土结构,其内设置柔性隔绝囊。In the present invention, the effluent from a certain urban sewage treatment plant in the north is lifted by a water inflow lift pump and then enters the system after being treated by a conventional process. After being purified by a self-cleaning filter, it enters the ultrafiltration membrane, and the wastewater generated by the ultrafiltration membrane is discharged into the backwash wastewater. pool, and then drained away with the wastewater in the factory area. Part of the ultrafiltration water is used for chemical cleaning water, and the other part passes through the reverse osmosis low-pressure water pump 1, security filter, and reverse osmosis high-pressure inlet pump 2 in turn to enter the subsequent reverse osmosis membrane, and the reverse osmosis membrane The concentrated water produced is discharged into the concentrated water pool, and then discharged with the wastewater in the factory area or subjected to advanced treatment of the concentrated water, and the regenerated water enters the vacuum electrochemical deaerator of the vacuum electrochemical deaeration unit for deaeration, and deaeration through the deaerator The final deoxygenated water is transported to the deoxygenated water pool + isolation bag, as a measure to prevent secondary dissolved oxygen in the vacuum system, so that the stored water is isolated from the atmosphere, and at the same time maintains a normal pressure state. The deaeration pool is a concrete structure constructed in combination with the civil engineering form of a sewage treatment plant when the vacuum electrochemical deaerator is used in a large-scale project, and a flexible isolation bag is arranged inside it.
本发明将城镇污水处理厂出水出水经过双膜法(超滤膜和反渗透膜)和真空电化学除氧器进行深度处理之后,即可满足供热管网入网的水质标准,同时又可满足特定再生水用户对水质的需要,进入供热管网,双膜法产水的pH值约为3~5,工程运行中投加氢氧化钠调节pH值至9,储罐原药浓度为30%。In the present invention, after the effluent of urban sewage treatment plant is subjected to advanced treatment by double-membrane method (ultrafiltration membrane and reverse osmosis membrane) and vacuum electrochemical deaerator, it can meet the water quality standard of the heating pipe network and at the same time meet the Specific reclaimed water users need for water quality, enter the heating pipe network, the pH value of the double-membrane method is about 3 to 5, add sodium hydroxide to adjust the pH value to 9 during the project operation, and the concentration of the original drug in the storage tank is 30% .
在采暖季,再生水可代替自来水对供热管网进行补水。同时,也可以利用供热管网输送再生水至用户。输配再生水管道的回水温度(20℃-50℃)与再生水出水温度(15℃左右)存在较大温差,为实现管网系统的热平衡及避免热源损失,充分考虑热网水力和再生水输配特性,采暖期经过厂外水处理系统+热源回收系统处理后可再利用。在非采暖期,利用闲置的供热管网可输配再生水给其他用户,用于工业、景观、洗车、冲厕等。During the heating season, recycled water can replace tap water to replenish the heating pipe network. At the same time, the heating pipe network can also be used to transport reclaimed water to users. There is a large temperature difference between the return water temperature (20°C-50°C) and the reclaimed water outlet temperature (about 15°C) of the reclaimed water pipeline for transmission and distribution. In order to achieve the heat balance of the pipe network system and avoid the loss of heat sources, fully consider the hydraulic power of the heating network and the reclaimed water transmission and distribution Features, during the heating period, it can be reused after being treated by the off-site water treatment system + heat source recovery system. During the non-heating period, the idle heating pipe network can be used to transport and distribute recycled water to other users for industry, landscaping, car washing, toilet flushing, etc.
最后应说明的是:以上实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明实施例技术方案的精神和范围。Finally, it should be noted that: the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: it can still be Modifications are made to the technical solutions described in the foregoing embodiments, or equivalent replacements are made to some of the technical features; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the spirit and scope of the technical solutions of the embodiments of the present invention.
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