CN116408995A - Automatic production process method for ultrahigh-speed pultrusion - Google Patents

Automatic production process method for ultrahigh-speed pultrusion Download PDF

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Publication number
CN116408995A
CN116408995A CN202211743412.5A CN202211743412A CN116408995A CN 116408995 A CN116408995 A CN 116408995A CN 202211743412 A CN202211743412 A CN 202211743412A CN 116408995 A CN116408995 A CN 116408995A
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China
Prior art keywords
glass fiber
resin
production process
product
dipping
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Pending
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CN202211743412.5A
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Inventor
史兵振
康红伟
刘晓林
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Shenzhen Langbowan Advanced Materials Co ltd
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Shenzhen Langbowan Advanced Materials Co ltd
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Priority to CN202211743412.5A priority Critical patent/CN116408995A/en
Publication of CN116408995A publication Critical patent/CN116408995A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/521Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement before the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/525Component parts, details or accessories; Auxiliary operations
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/70Wind energy
    • Y02E10/72Wind turbines with rotation axis in wind direction

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The invention provides an ultra-high-speed pultrusion automatic production process method which is characterized by comprising the following steps of: s1, step: the glass fiber yarn group is stably and rapidly unreeled, a plurality of ends of the glass fiber yarn group are continuously wound, and the glass fiber yarn group is put into a single glass fiber tension control device to obtain glass fibers, wherein the continuous length of the glass fibers is more than 5 ten thousand meters; s2, step: placing the glass fiber into a dehumidifying and heating device, uniformly heating the glass fiber to more than 100 ℃ within 60 seconds by a heat source with the temperature not exceeding 120 DEG, dipping the heated glass fiber, dipping the glass fiber by using a plurality of waves, and uniformly dipping the glass fiber within 30 seconds to obtain a fiber dipping structure; s3, step: controlling the temperature of the resin at 40-60 ℃, and supplementing resin into the resin tank all the time in the production process, wherein the resin amount is consistent all the time; s4, step: and curing the glass fiber and the resin by adopting an external mold to obtain the product.

Description

Automatic production process method for ultrahigh-speed pultrusion
Technical Field
The invention relates to the field, in particular to an ultrahigh-speed pultrusion automatic production process method.
Background
The pultrusion molding of one of the composite material molding processes belongs to the process with simple production steps, high quality stability and higher production efficiency, and more applications in the market mainly adopt thermosetting pultrusion, wherein the general production speed of the pultrusion of epoxy resin is 0.5m/min, and the more 1m/min of the pultrusion of vinyl and unsaturated polyester is, but the latter causes some harm to the environment, and the mechanical property of the resin is poor. There are some processes using photo-setting resin to pull and squeeze, which are mainly applied to the reinforced core product of optical cable in the existing market, but the process is not used at present, and the reason is that the design of the pulling and squeezing process and the mould is similar to the thermal setting pulling and squeezing process, and the light energy and the light intensity of the selected ultraviolet curing mechanism can not meet the requirement of high-speed production.
In order to solve the problems, we develop a process capable of matching with ultra-high-speed pultrusion, which solves the following problems, namely 1, ensuring the sustainability of high-efficiency production, 2, the quality stability of continuous production, 3, the benefit brought by high-speed production, 4, and the superiority of the self-performance of the product.
Disclosure of Invention
The invention aims to provide an automatic production process method for ultrahigh-speed pultrusion.
In order to solve the above background technical problems, the technical scheme of the invention is as follows: an automatic production process method for ultra-high-speed pultrusion is characterized by comprising the following steps:
s1, step: the glass fiber yarn group is stably and rapidly unreeled, a plurality of ends of the glass fiber yarn group are continuously wound, and the glass fiber yarn group is put into a single glass fiber tension control device to obtain glass fibers, wherein the continuous length of the glass fibers is more than 5 ten thousand meters;
s2, step: placing the glass fiber into a dehumidifying and heating device, uniformly heating the glass fiber to more than 100 ℃ within 60 seconds by a heat source with the temperature not exceeding 120 DEG, dipping the heated glass fiber, dipping the glass fiber by using a plurality of waves, and uniformly dipping the glass fiber within 30 seconds to obtain a fiber dipping structure;
s3, step: controlling the temperature of the resin at 40-60 ℃, and supplementing resin into the resin tank all the time in the production process, wherein the resin amount is consistent all the time;
s4, step: and curing the glass fiber and the resin by adopting an external mold to obtain the product.
By adopting the scheme, the glass fiber yarn groups are rapidly unreeled, the knots are avoided when the head and the tail are wound, and the phenomenon of cross and unreeling during unreeling of yarns is avoided; placing the glass fiber yarn clusters into a single glass fiber tension control device, and ensuring the consistency and uniformity of the tension applied to each glass fiber to ensure the consistency of the quality of each glass fiber; the continuous length of the glass fiber is more than 5 ten thousand meters, so that the production continuity of the glass fiber is ensured, and the high-speed production of the glass fiber is ensured; the heating source is limited below 120 degrees, so as to protect the impregnating compound material on the surface of the glass fiber, and meanwhile, the heated glass fiber is impregnated, so that the impregnation efficiency of the glass fiber can be improved at high temperature, the glass fiber is uniformly impregnated within 30 seconds, the quality of an impregnation structure of the glass fiber is ensured, and the stability of a product is improved; the glass fiber is heated and dehumidified, so that the combination speed of the glass fiber and the resin is effectively improved, the dipping speed of the glass fiber is improved, and the overall production process time is shortened; the temperature of the resin is controlled to be 40-60 ℃, and the resin is always supplemented in the production process, so that the glass fiber broken yarn hairiness in the resin is removed by the circulation of the resin, the quality of the product is improved, the defective rate is reduced, and the production benefit is further improved; the extrusion step is not needed in the process of curing outside the die, so that the condition of die blockage is avoided, the damage to the die is reduced, the service life of the die is prolonged, the continuity of high-speed production is ensured, and the enterprise benefit is improved.
Preferably, a plurality of separating rods are arranged in the resin tank in the step S4, the separating rods are vertically arranged, the intervals at the inlets of the separating rods are consistent with the widths of the glass fibers, and the total intervals at the outlets are consistent with the widths of the products. Between each spacer rod, 1-3 glass fibers are allowed to pass through, and the spacer rods use high-hardness smooth metal rods.
By adopting the scheme, the glass fibers are required to be kept parallel to each other when the glass fibers exit the resin tank, and the glass fibers are separated by the separating rod, so that the glass fibers cannot be entangled together, and the glass fibers are kept parallel, thereby achieving the effect of improving the uniform dipping rate of the glass fibers.
Preferably, the curing in the step S5 is performed by irradiation curing with an ultraviolet lamp or by reheating curing in the first ultraviolet curing.
By adopting the scheme, the heat conduction can conduct longer distance according to time, the effective penetration of light can not increase the penetration distance along with the increase of time, and the proper ultraviolet curing machine can be selected according to the size of the pultrusion product, so that the performance of the cured product is improved.
Preferably, the cooling of the cured product adopts a forced cooling mode.
Through adopting above-mentioned scheme, forced cooling can accelerate cooling speed, shortens production time, improves production efficiency.
Preferably, the continuous production speed of the product is 5-10 m/min, the continuous production speed of the product is traction by a crawler-type traction machine, and the continuous production speed of the product is more than 10m/min, and the continuous production speed of the product is directly traction by traction wheels.
By adopting the scheme, the stability of the winding speed is ensured, the sizes of the produced products are further unified, and the production quality is ensured.
Preferably, the step S1 uses a dual reel-up device for fast unreeling.
By adopting the scheme, under the high-speed pultrusion condition, the speed reduction and the speed acceleration of the equipment are not beneficial to the stability of the product. The double winding device is also required to be provided with an automatic feeding auxiliary mechanism and an automatic unwinding auxiliary mechanism, so that the efficiency of changing the rolls can be effectively improved, meanwhile, because the speed of thermal curing is slower, the ultra-high-speed pultrusion speed is 10 times or more than that of thermal curing, and the double winding device is highly automatic in mechanism assistance, can save a great amount of time in winding and unwinding steps, and improves the production efficiency.
Preferably, the step S5 is followed by the steps of:
s6, step: the product is packaged after passing through the detection mechanism.
By adopting the scheme, the product passes through the detection mechanism, defective products in the product can be detected, and the yield of the produced product is improved.
Compared with the prior art, the ultrahigh-speed pultrusion automatic production process method provided by the invention has the following advantages:
1. the glass fiber yarn is rapidly unreeled, the head and the tail are wound with waists, the knotting is avoided, and the phenomenon that the yarns are scattered during the cross and unreeling process is avoided; placing the glass fiber yarn clusters into a single glass fiber tension control device, and ensuring the consistency and uniformity of the tension applied to each glass fiber to ensure the consistency of the quality of each glass fiber; the continuous length of the glass fiber is more than 5 ten thousand meters, so that the production continuity of the glass fiber is ensured, and the high-speed production of the glass fiber is ensured.
2. The heating source is limited below 120 degrees, so as to protect the impregnating compound material on the surface of the glass fiber, and meanwhile, the heated glass fiber is impregnated, so that the impregnation efficiency of the glass fiber can be improved at high temperature, the glass fiber is uniformly impregnated within 30 seconds, the quality of an impregnation structure of the glass fiber is ensured, and the stability of a product is improved; the glass fiber is heated and dehumidified, so that the combination speed of the glass fiber and the resin is effectively improved, the dipping speed of the glass fiber is improved, and the whole production process time is shortened.
3. The temperature of the resin is controlled to be 40-60 ℃, and the resin is always supplemented in the production process, so that the glass fiber broken yarn hairiness in the resin is removed by the circulation of the resin, the quality of the product is improved, the defective rate is reduced, and the production benefit is further improved; the extrusion step is not needed in the process of curing outside the die, so that the condition of die blockage is avoided, the damage to the die is reduced, the service life of the die is prolonged, the continuity of high-speed production is ensured, and the enterprise benefit is improved.
Detailed Description
Examples
Example 1
Example one product was a glass fiber reinforced board 100mm wide and 5mm thick, at a production rate of 8m/min. The humidity is controlled between 40% and 70%. The resin is a photo-curable resin.
Glass fiber size HMG 920HT-2400, 400 x 8 reels, 400 glass fibers are required for the product, and 8 reels of yarn are required for each glass fiber to be placed in order to ensure continuous production.
The glass fiber is applied with tension, the applied tension value is 5N, and the tension value is controlled within +/-2N of the design value.
The glass fiber tension was measured once every 24 hours, and the glass fiber tensioner was adjusted once.
The dehumidification temperature is controlled between 120 and 130 ℃ and the heating time is 60s.
The glass fiber is extruded in a resin tank for 5 times, the length of the resin tank is designed to be 2m, and the dipping time is 15s.
Four sets of dies were used with thickness dimensions of 5.3mm, 5.2mm, 5.1mm and 5mm, respectively.
The light curing is carried out by adopting 365nm wave band, the illumination intensity is 30J/cm 2 The effective irradiation time was 0.5s.
The forced cooling process is selected, and the product is blown by using 20m/s air flow, wherein the air flow is stable at 30-40 ℃ for 2min.
The crawler-type traction machine is used for traction, and the winding machine adopts a standby structure.
Example 2
The second product of the embodiment is a glass fiber reinforced board with the width of 10mm and the thickness of 2mm, and the production speed is 40m/min. The humidity is controlled between 40% and 70%. The resin is a photo-curable resin.
Glass fiber size HMG 920HT-600, number of reels 50 x 8, product requires 50 glass fibers, in order to guarantee continuous production, 8 reels of yarn placement per glass fiber are required.
The glass fiber is applied with tension, the applied tension value is 5N, and the tension value is controlled within +/-2N of the design value.
The glass fiber tension was measured every 12 hours and the glass fiber tensioner was adjusted.
The dehumidification temperature is controlled between 120 and 130 ℃ and the heating time is 30s.
The glass fiber is extruded in a resin tank for 8 times, the length of the resin tank is designed to be 4m, and the dipping time is 6s.
Four sets of dies were used with thickness dimensions of 2.3mm, 1.9mm, 2mm and 2mm, respectively.
The light curing is carried out by adopting 365nm wave band, and the illumination intensity is 50J/cm 2 The effective irradiation time was 0.1s.
The forced cooling process is selected, 30m/s air flow is used for blowing the product, and the air flow is stable at 30-40 ℃ for 1min.
The traction force is used for direct traction, and the winding machine adopts a standby structure.
Example 3
The third product of the embodiment is a glass fiber reinforced board with the width of 100mm and the thickness of 5mm, and the production speed is 8m/min. The humidity is controlled between 40% and 70%. The resin is a dual cure system resin in which a photo-setting and a thermosetting resin are combined.
Glass fiber size HMG 920HT-2400, 400 x 8 reels, 400 glass fibers are required for the product, and 8 reels of yarn are required for each glass fiber to be placed in order to ensure continuous production.
The glass fiber is applied with tension, the applied tension value is 5N, and the tension value is controlled within +/-2N of the design value.
The glass fiber tension was measured once every 24 hours, and the glass fiber tensioner was adjusted once.
The dehumidification temperature is controlled between 120 and 130 ℃ and the heating time is 60s.
The glass fiber is extruded in a resin tank for 5 times, the length of the resin tank is designed to be 2m, and the dipping time is 15s.
Four sets of dies were used with thickness dimensions of 5.3mm, 5.2mm, 5.1mm and 5mm, respectively.
The light curing is carried out by adopting 365nm wave band, the illumination intensity is 30J/cm 2 The effective irradiation time was 0.5s.
The heat curing is carried out by adopting a contact conduction mode, the heating is stable at 160-180 ℃, and the heating length is 32m.
The forced cooling process is selected, and the product is blown by using 20m/s air flow, wherein the air flow is stable at 30-40 ℃ for 2min.
The crawler-type traction machine is used for traction, and the winding machine adopts a standby structure.
Example 4
The fourth product of the embodiment is a glass fiber reinforced board with the width of 10mm and the thickness of 2mm, and the production speed is 40m/min. The humidity is controlled between 40% and 70%. The resin is a dual cure system resin in which a photo-setting and a thermosetting resin are combined.
Glass fiber size HMG 920HT-600, number of reels 50 x 8, product requires 50 glass fibers, in order to guarantee continuous production, 8 reels of yarn placement per glass fiber are required.
The glass fiber is applied with tension, the applied tension value is 5N, and the tension value is controlled within +/-2N of the design value.
The glass fiber tension was measured every 12 hours and the glass fiber tensioner was adjusted.
The dehumidification temperature is controlled between 120 and 130 ℃ and the heating time is 30s.
The glass fiber is extruded in a resin tank for 8 times, the length of the resin tank is designed to be 4m, and the dipping time is 6s.
Four sets of dies were used with thickness dimensions of 2.3mm, 1.9mm, 2mm and 2mm, respectively.
The light curing is carried out by adopting 365nm wave band, and the illumination intensity is 50J/cm 2 The effective irradiation time was 0.1s.
The heat curing selection mode is a whole-roll heating mode, the whole-roll product is placed in a constant-temperature heating room after being produced, the temperature in the room is set to be 80-90 ℃, and the heating time is 12 hours.
The forced cooling process is selected, 30m/s air flow is used for blowing the product, and the air flow is stable at 30-40 ℃ for 1min.
The traction force is used for direct traction, and the winding machine adopts a standby structure.
In the description of the present application, furthermore, the terms "first," "second," and the like are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more features. In the description of the embodiments of the present application, the meaning of "a plurality" is two or more, unless explicitly defined otherwise.
In the description of the present application, it should be noted that, unless explicitly specified and limited otherwise, the terms "connected," "connected," and "connected" are to be construed broadly, and may be either fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium. The specific meaning of the terms in this application will be understood by those of ordinary skill in the art in a specific context. Furthermore, in the description of the present application, unless otherwise indicated, the meaning of "a plurality" is two or more.
In the description of embodiments of the present application, it is to be understood that in embodiments of the present application, unless explicitly specified and defined otherwise, a first feature "above" or "below" a second feature may include both the first and second features being in direct contact, or may include both the first and second features not being in direct contact but being in contact by another feature therebetween. Moreover, a first feature being "above," "over" and "on" a second feature includes the first feature being directly above and obliquely above the second feature, or simply indicating that the first feature is higher in level than the second feature. The first feature being "under", "below" and "beneath" the second feature includes the first feature being directly above and obliquely above the second feature, or simply indicating that the first feature is less level than the second feature.
In the description of the present specification, reference is made to the description of the terms "one embodiment," "some embodiments," "illustrative embodiments," "examples," "specific examples," or "some examples," etc., meaning that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present application. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
While embodiments of the present application have been shown and described, it will be understood by those of ordinary skill in the art that: many changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the application, the scope of which is defined by the claims and their equivalents.

Claims (7)

1. An automatic production process method for ultra-high-speed pultrusion is characterized by comprising the following steps:
s1, step: the glass fiber yarn group is stably and rapidly unreeled, a plurality of ends of the glass fiber yarn group are continuously wound, and the glass fiber yarn group is put into a single glass fiber tension control device to obtain glass fibers, wherein the continuous length of the glass fibers is more than 5 ten thousand meters;
s2, step: placing the glass fiber into a dehumidifying and heating device, uniformly heating the glass fiber to more than 100 ℃ within 60 seconds by a heat source with the temperature not exceeding 120 DEG, dipping the heated glass fiber, dipping the glass fiber by using a plurality of waves, and uniformly dipping the glass fiber within 30 seconds to obtain a fiber dipping structure;
s3, step: controlling the temperature of the resin at 40-60 ℃, and supplementing resin into the resin tank all the time in the production process, wherein the resin amount is consistent all the time;
s4, step: and curing the glass fiber and the resin by adopting an external mold to obtain the product.
2. The ultra-high speed pultrusion automated production process of claim 1, wherein: and (4) a plurality of separation rods are arranged in the resin tank in the step (S4), the separation rods are vertically arranged, the intervals at the inlets of the separation rods are consistent with the widths of the glass fibers, and the total intervals at the outlets are consistent with the widths of the products. Between each spacer rod, 1-3 glass fibers are allowed to pass through, and the spacer rods use high-hardness smooth metal rods.
3. The ultra-high speed pultrusion automated production process of claim 1, wherein: and the curing in the step S5 adopts ultraviolet lamp irradiation curing or ultraviolet curing and reheating curing.
4. The ultra-high speed pultrusion automated production process of claim 1, wherein: and cooling the cured product by adopting a forced cooling mode.
5. The ultra-high speed pultrusion automated production process of claim 1, wherein: the continuous production speed of the product is 5-10 m/min, the continuous production speed of the product is more than 10m/min, and the continuous production speed of the product is directly pulled by a traction wheel.
6. The ultra-high speed pultrusion automated production process of claim 1, wherein: and in the step S1, a double-winding machine device is adopted for quick unwinding.
7. The ultra-high speed pultrusion automated production process of claim 1, wherein: the step S5 comprises the following steps:
s6, step: product passing detection mechanism after that, proceeding and (5) packaging.
CN202211743412.5A 2022-12-30 2022-12-30 Automatic production process method for ultrahigh-speed pultrusion Pending CN116408995A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202211743412.5A CN116408995A (en) 2022-12-30 2022-12-30 Automatic production process method for ultrahigh-speed pultrusion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211743412.5A CN116408995A (en) 2022-12-30 2022-12-30 Automatic production process method for ultrahigh-speed pultrusion

Publications (1)

Publication Number Publication Date
CN116408995A true CN116408995A (en) 2023-07-11

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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