CN116102158A - A modular microbial fuel cell constructed wetland system - Google Patents

A modular microbial fuel cell constructed wetland system Download PDF

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CN116102158A
CN116102158A CN202310033634.6A CN202310033634A CN116102158A CN 116102158 A CN116102158 A CN 116102158A CN 202310033634 A CN202310033634 A CN 202310033634A CN 116102158 A CN116102158 A CN 116102158A
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fuel cell
microbial fuel
water
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wetland system
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王曦
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EVERISE EMERGING TECHNOLOGY DEVELOPMENT Inc
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Abstract

The invention discloses a modularized microbial fuel cell type constructed wetland system, which relates to the technical field of water pollution control and water treatment and comprises a water inlet channel, a wetland treatment area and a water outlet channel which are sequentially connected, wherein the wetland treatment area comprises a plurality of treatment units which are arranged in parallel, the water inlets of the treatment units are connected with the water inlet channel, the water outlets of the treatment units are connected with the water outlet channel, each treatment unit comprises a plurality of microbial fuel cells which are connected in series, the two ends of each microbial fuel cell are respectively provided with a water inlet and a water outlet, the water inlet side and the water outlet side are respectively provided with electrode leading-out ends with opposite polarities, the water inlets and the water outlets of adjacent microbial fuel cells are detachably connected, and the electrode leading-out ends with opposite polarities of the adjacent microbial fuel cells are detachably connected. The invention can utilize the microbial fuel cell to enhance the organic matter degradation capability and degradation rate of the wetland system, and can ensure the electric energy output of the microbial fuel cell on the basis of solving the blockage problem.

Description

一种模块化微生物燃料电池型人工湿地系统A modular microbial fuel cell constructed wetland system

技术领域technical field

本发明涉及水污染控制与水处理技术领域,特别是涉及一种模块化微生物燃料电池型人工湿地系统。The invention relates to the technical field of water pollution control and water treatment, in particular to a modular microbial fuel cell artificial wetland system.

背景技术Background technique

人工湿地是由湿地植物、填料和微生物群落通过物理、化学和生物的协同作用来去除水中污染物。人工湿地作为一种低成本、低能耗的生态污水处理技术,在污(废)水处理及微污染水体生态修复应用中有着显著的优势,尤其是在近年的海绵城市建设、黑臭水体治理及农村污水处理中得到迅速发展和认可肯定。但是,人工湿地也存在着有机负荷较低、占地面积大、长时间运行易发生堵塞等问题,这些都成为制约人工湿地技术发展的因素。Constructed wetlands are composed of wetland plants, fillers and microbial communities to remove pollutants in water through physical, chemical and biological synergies. As a low-cost, low-energy ecological sewage treatment technology, constructed wetlands have significant advantages in the application of sewage (waste) water treatment and ecological restoration of slightly polluted water bodies, especially in recent years in the construction of sponge cities, the treatment of black and odorous water bodies and Rural sewage treatment has been rapidly developed and recognized. However, constructed wetlands also have problems such as low organic load, large floor area, and easy blockage after long-term operation, which have become factors restricting the development of constructed wetland technology.

在人工湿地长期运行过程中会出现堵塞、短流、基质吸附饱和等现象,使得湿地处理能力下降,面对上述问题,传统解决办法是对湿地进行反冲洗,或者更换填料、植物,但存在操作复杂并且成本高、事后湿地系统恢复期较长、稳定性差等问题。目前研究较多的解决办法还有湿地模块化,通过模块化的可拆卸、局部分离来实现局部更换/冲洗,从而简化操作、降低成本、减小系统稳定性损害。例如,申请公布号为CN105858900A的中国专利公开了一种模块化格栅式组合人工湿地系统,包括依次连接的进水分布区、湿地系统处理区和出水收集区,湿地系统处理区包括多个由格栅式湿地槽串联组合而成的处理单元,每个处理单元均与进水分布区上的一个出水口对应连接,处理单元的出水口则与出水收集区汇总连接,进水分布区的出水面和出水收集区的进水面均设置有穿孔布水隔板。该方案可以在人工湿地局部发生堵塞时进行局部的更换或调整,减少对湿地系统的整体影响,但这也仅能较好解决堵塞问题,却无法有效提高湿地的处理能力、减小占地。During the long-term operation of constructed wetlands, phenomena such as clogging, short flow, and matrix adsorption saturation will occur, which will reduce the wetland treatment capacity. Faced with the above problems, the traditional solution is to backwash the wetlands, or replace fillers and plants, but there are operations Complexity and high cost, long post-event wetland system recovery period, poor stability and other issues. At present, there are more researches on the solution of wetland modularization, which realizes partial replacement/flush through modular detachment and partial separation, so as to simplify operation, reduce cost, and reduce system stability damage. For example, the Chinese patent application publication number CN105858900A discloses a modular grid-type combined constructed wetland system, which includes a sequentially connected water inlet distribution area, wetland system treatment area, and effluent collection area. The wetland system treatment area includes multiple A treatment unit composed of grid-type wetland tanks in series, each treatment unit is connected to a water outlet on the water inlet distribution area, and the water outlet of the treatment unit is connected to the outlet water collection area, and the outlet of the water inlet distribution area Both the water surface and the water inlet surface of the effluent collection area are provided with perforated water distribution partitions. This solution can be partially replaced or adjusted when the constructed wetland is partially blocked, so as to reduce the overall impact on the wetland system, but this can only solve the problem of blockage, but cannot effectively improve the processing capacity of the wetland and reduce the land occupation.

在人工湿地中引入微生物燃料电池技术,构建合理的电池极室,利用湿地中的微生物群落形成电极-微生物电极效应、植物-微生物根际效应、基质-微生物生物膜效应等多种效应。通过产电微生物促进对污染物的降解从而增强人工湿地的去除能力,同时将污染物的有机质能量转化成电能收集起来。例如,申请公布号为CN113540542A的中国专利公开了一种人工湿地微生物电池,包括下流反应器、阳极和空气阴极;下流反应器的内部设置有玻璃纤维棉分隔层,玻璃纤维棉分隔层将下流反应器的内腔分为上腔和下腔两部分;上腔和下腔内均填充有砾石与厌氧污泥;阳极和空气阴极分别设置于下流反应器的底部和顶部;阳极包括第一不锈钢网和第一石墨毡,第一石墨毡设置在第一不锈钢网的外部;空气阴极包括第二不锈钢网和第二石墨毡,第二不锈钢网包裹在第二石墨毡的外部。该方案的目的在于无需种植植物,且设置其支撑作用的砾石,减少污泥堵塞,但实际运行时仍旧会存在堵塞,并仍会存在输出电压和功率低的缺陷。同时堵塞会增大基质内阻,影响电子/质子的传递效率,也会影响产电菌的电能输出,不利于电子/质子的传输,增大了电池的内电阻,影响发电效能。Introduce microbial fuel cell technology in constructed wetlands, build a reasonable battery cell, and use the microbial community in the wetland to form various effects such as electrode-microbe electrode effect, plant-microbe rhizosphere effect, and matrix-microbe biofilm effect. The degradation of pollutants is promoted by electrogenic microorganisms to enhance the removal capacity of constructed wetlands, and at the same time, the organic matter energy of pollutants is converted into electrical energy and collected. For example, the application publication number is that the Chinese patent of CN113540542A discloses a kind of artificial wetland microbial battery, comprises downflow reactor, anode and air cathode; The inner chamber of the reactor is divided into two parts, the upper chamber and the lower chamber; the upper chamber and the lower chamber are filled with gravel and anaerobic sludge; the anode and the air cathode are respectively arranged at the bottom and top of the downflow reactor; the anode includes the first stainless steel A mesh and a first graphite felt, the first graphite felt is arranged outside the first stainless steel mesh; the air cathode includes a second stainless steel mesh and a second graphite felt, and the second stainless steel mesh is wrapped outside the second graphite felt. The purpose of this solution is to not need to plant plants, and set its supporting gravel to reduce sludge clogging, but clogging will still occur during actual operation, and there will still be defects of low output voltage and power. At the same time, blockage will increase the internal resistance of the matrix, affect the transfer efficiency of electrons/protons, and also affect the power output of electrogenic bacteria, which is not conducive to the transfer of electrons/protons, increases the internal resistance of the battery, and affects the power generation efficiency.

目前,上述人工湿地与微生物燃料电池耦合技术的研究多限于微弱电压如何提高和有效输出利用,而对其堵塞问题却无能为力。At present, the research on the coupling technology of the above-mentioned constructed wetlands and microbial fuel cells is mostly limited to how to increase the weak voltage and effectively output and utilize it, but there is nothing to do about its clogging problem.

发明内容Contents of the invention

本发明的目的是提供一种模块化微生物燃料电池型人工湿地系统,以解决上述现有技术存在的问题,通过微生物燃料电池串联组成处理单元,若干处理单元并联组成湿地处理区,能够利用微生物燃料电池增强湿地系统的有机物降解能力和降解速率,同时,能够更换堵塞位置的微生物燃料电池以在解决堵塞问题的基础上保证微生物燃料电池的电能输出。The purpose of the present invention is to provide a modular microbial fuel cell artificial wetland system to solve the problems of the above-mentioned prior art. The microbial fuel cells are connected in series to form treatment units, and several treatment units are connected in parallel to form a wetland treatment area, which can utilize microbial fuel The battery enhances the organic matter degradation capacity and degradation rate of the wetland system. At the same time, the microbial fuel cell at the clogged position can be replaced to ensure the electrical energy output of the microbial fuel cell on the basis of solving the clogging problem.

为实现上述目的,本发明提供了如下方案:To achieve the above object, the present invention provides the following scheme:

本发明提供一种模块化微生物燃料电池型人工湿地系统,包括顺次连接的进水渠、湿地处理区和出水渠,所述湿地处理区包括并联设置的若干处理单元,所述处理单元的进水口连接所述进水渠,所述处理单元的出水口连接所述出水渠,每个所述处理单元包括若干串联连接的微生物燃料电池,所述微生物燃料电池的两端分别设置有进水口和出水口,并在进水口侧和出水口侧分别设置有极性相反的电极引出端,相邻所述微生物燃料电池的进水口和出水口可拆卸连接,且相邻所述微生物燃料电池的极性相反的电极引出端可拆卸连接。The present invention provides a modular microbial fuel cell constructed wetland system, which includes sequentially connected water inlet channels, wetland treatment areas and outlet channels. The wetland treatment area includes several processing units arranged in parallel, and the water inlets of the processing units Connect the water inlet channel, the water outlet of the treatment unit is connected to the water outlet channel, each of the treatment units includes a number of microbial fuel cells connected in series, and the two ends of the microbial fuel cell are respectively provided with a water inlet and a water outlet , and the electrode leads with opposite polarities are respectively arranged on the water inlet side and the water outlet side, the water inlet and the water outlet of the adjacent microbial fuel cells are detachably connected, and the polarities of the adjacent microbial fuel cells are opposite The electrode leads are detachably connected.

优选地,所述微生物燃料电池根据连接部的不同分为A型模块、B型模块和C型模块,所述A型模块的两端分别设置有第一连接部,所述B型模块的两端分别设置有第二连接部,所述C型模块的两端分别设置有第一连接部和第三连接部,所述第一连接部与所述第二连接部连接,所述第三连接部与所述进水渠或所述出水渠连接。Preferably, the microbial fuel cell is divided into A-type modules, B-type modules and C-type modules according to different connection parts, the two ends of the A-type module are respectively provided with first connection parts, and the two ends of the B-type module The two ends of the C-shaped module are respectively provided with a second connection part, and the two ends of the C-shaped module are respectively provided with a first connection part and a third connection part, and the first connection part is connected with the second connection part, and the third connection part is connected with the second connection part. The part is connected with the water inlet channel or the water outlet channel.

优选地,所述第一连接部包括卡板、分布在所述卡板上的第一孔洞以及设置在所述卡板中部的导电插头,所述第二连接部包括与所述卡板配合的卡槽、分布在所述卡槽上的第二孔洞以及设置在所述卡槽中部的导电插盒,所述导电插头与所述导电插盒分别连接不同电极,且所述导电插头与所述导电插盒能够在所述卡板与所述卡槽插接连接后实现连接。Preferably, the first connecting part includes a card board, first holes distributed on the card board, and a conductive plug arranged in the middle of the card board, and the second connecting part includes a The card slot, the second hole distributed on the card slot, and the conductive box arranged in the middle of the card slot, the conductive plug and the conductive box are respectively connected to different electrodes, and the conductive plug and the The conductive plug box can be connected after the card board is plugged and connected to the card slot.

优选地,所述卡槽包括位于两侧的滑槽和位于底部的限位槽,所述卡板的两侧分别设置有与所述滑槽对应的第一插接部,所述卡板的底部设置有与所述限位槽对应的第二插接部。Preferably, the card slot includes a chute on both sides and a limit slot on the bottom, the two sides of the card board are respectively provided with first insertion parts corresponding to the chute, and the card board The bottom is provided with a second insertion part corresponding to the limiting groove.

优选地,所述第一插接部沿插接方向依次布置有若干滚轮,所述滑槽的一面与所述滚轮对应位置设置有滑道。Preferably, a plurality of rollers are arranged sequentially along the insertion direction of the first plug-in part, and a slideway is provided on one side of the sliding groove corresponding to the rollers.

优选地,所述滑槽的另一面以及所述限位槽的另一面均设置有橡胶垫,所述滚轮进入所述滑道后将所述第一插接部的背面贴合在所述橡胶垫上。Preferably, the other side of the chute and the other side of the limiting groove are provided with rubber pads, and after the roller enters the slideway, the back surface of the first insertion part is attached to the rubber pad. Pad.

优选地,所述第三连接部包括固定环,所述进水渠处和所述出水渠处设置有导杆,所述固定环向下运动能够套入所述导杆。Preferably, the third connecting portion includes a fixing ring, guide rods are provided at the water inlet channel and the water outlet channel, and the fixing ring can be inserted into the guide rods by moving downward.

优选地,所述第三连接部包括与所述微生物燃料电池内部连通的开口朝下的承插孔,所述进水渠和所述出水渠均连接有竖直朝上的通水管,所述通水管上设置有开关阀门,所述承插孔向下套入所述通水管实现连通。Preferably, the third connecting portion includes a downwardly facing socket hole communicating with the inside of the microbial fuel cell, and the water inlet channel and the water outlet channel are connected with vertically upward water pipes, and the water channel A switch valve is arranged on the water pipe, and the socket hole is inserted downward into the water pipe to realize communication.

优选地,所述微生物燃料电池包括填料床和湿地植物,填料床包括自下而上设置的承托层、中层基质层、上层基质层,所述中层基质层的底部敷设有阳极材料,所述上层基质层的顶部敷设有阴极材料,所述阴极材料和所述阳极材料分别连接有不同的电极引出端,所述上层基质层中栽种有湿地植物。Preferably, the microbial fuel cell includes a packing bed and wetland plants, the packing bed includes a support layer arranged from bottom to top, a middle matrix layer, and an upper matrix layer, the bottom of the middle matrix layer is laid with an anode material, the A cathode material is laid on the top of the upper matrix layer, and the cathode material and the anode material are respectively connected to different electrode leads, and wetland plants are planted in the upper matrix layer.

优选地,所述承托层厚20cm,基质选用粒径φ16~30mm的砾石、碎石;所述中层基质层厚35cm,基质选用粒径φ4~15mm的砾石、沸石;所述上层基质层厚15cm,基质选用粒径较小的粗砂或土壤;所述湿地植物选用芦苇、菖蒲、美人蕉;所述阴极材料和所述阳极材料采用活性炭层或者石墨毯。Preferably, the supporting layer is 20 cm thick, and the matrix is gravel and gravel with a particle size of φ16 to 30 mm; the middle matrix layer is 35 cm thick, and the matrix is gravel and zeolite with a particle size of φ4 to 15 mm; the upper matrix layer is thick The substrate is coarse sand or soil with a small particle size; the wetland plants are reeds, calamus, and canna; the cathode material and the anode material are activated carbon layers or graphite blankets.

本发明相对于现有技术取得了以下技术效果:Compared with the prior art, the present invention has achieved the following technical effects:

(1)本发明通过微生物燃料电池串联组成处理单元,若干处理单元并联组成湿地处理区,能够利用微生物燃料电池增强湿地系统的有机物降解能力和降解速率,同时,能够更换堵塞位置的微生物燃料电池以在解决堵塞问题的基础上保证微生物燃料电池的电能输出;因此,本发明既能解决湿地堵塞问题,又能提高湿地处理能力,还能将有机质转化为电能输出利用;(1) In the present invention, microbial fuel cells are connected in series to form processing units, and several processing units are connected in parallel to form a wetland treatment area. Microbial fuel cells can be used to enhance the organic matter degradation capacity and degradation rate of the wetland system. At the same time, the microbial fuel cells at the blocked position can be replaced to On the basis of solving the blockage problem, the electric energy output of the microbial fuel cell is guaranteed; therefore, the present invention can not only solve the wetland blockage problem, but also improve the wetland treatment capacity, and can also convert organic matter into electric energy output and utilization;

(2)本发明将微生物燃料电池划分为A型模块、B型模块和C型模块,能够利用各模块所设置的连接部的不同实现各模块之间以及模块与进水渠、出水渠之间的便捷连接,方便的将出现堵塞的微生物燃料电池进行取出和更换;(2) The present invention divides the microbial fuel cell into A-type modules, B-type modules and C-type modules, and can utilize the difference of the connection parts that each module is provided with to realize the connection between each module and between the modules and the water inlet and the water outlet. Convenient connection, easy to take out and replace the clogged microbial fuel cell;

(3)本发明利用卡槽和卡板的配合实现相邻的微生物燃料电池的插接连接,并且,卡槽包括位于两侧的滑槽和位于底部的限位槽,在卡板和卡槽插接连接后还能够在底部和两侧形成半包围结构,将第一孔洞和第二孔洞在半包围结构内连通,保证连接的密封性,实现水流顺利按照微生物燃料电池的串联顺序进行流动,保证湿地系统的处理效果;(3) The present invention utilizes the cooperation of the card slot and the card board to realize the plug-in connection of adjacent microbial fuel cells, and the card slot includes slide grooves on both sides and a limiting groove at the bottom. After the plug-in connection, a semi-enclosed structure can be formed on the bottom and both sides, and the first hole and the second hole are connected in the semi-enclosed structure to ensure the sealing of the connection and realize the smooth flow of water in accordance with the serial sequence of the microbial fuel cell. Ensure the treatment effect of the wetland system;

(4)本发明在安装卡板和卡槽时,能够利用滚轮和滑道的配合,实现卡板和卡槽装配和拆卸的定位准确、快速、省力,并采用垂直装卸连接方式更易于微生物燃料电池的取出和安装;另外,在滑槽内设置有橡胶垫,在安装卡板与卡槽后能够利用滚轮将卡板的第一插接部贴合在橡胶垫上,形成相对封闭的半包围结构的连通空间,进一步的提高相邻微生物燃料电池连通的密封性。(4) The present invention can utilize the cooperation of the roller and the slideway when installing the clamping plate and the clamping groove to realize accurate, fast and labor-saving positioning of the clamping plate and the clamping groove assembly and disassembly, and adopt the vertical loading and unloading connection mode to facilitate microbial fuel Take out and install the battery; in addition, a rubber pad is provided in the chute, and after installing the card board and the card slot, the first insertion part of the card board can be attached to the rubber pad by using rollers to form a relatively closed semi-enclosed structure The communication space further improves the sealing performance of the communication between adjacent microbial fuel cells.

附图说明Description of drawings

为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the following will briefly introduce the accompanying drawings required in the embodiments. Obviously, the accompanying drawings in the following description are only some of the present invention. Embodiments, for those of ordinary skill in the art, other drawings can also be obtained based on these drawings without any creative effort.

图1为本发明人工湿地系统平面布置图;Fig. 1 is the plane layout diagram of the constructed wetland system of the present invention;

图2为本发明微生物燃料电池结构图;Fig. 2 is the structural diagram of microbial fuel cell of the present invention;

图3为本发明A型模块结构示意图;Fig. 3 is a schematic diagram of the structure of the A-type module of the present invention;

图4为本发明B型模块结构示意图;Fig. 4 is a schematic diagram of the B-type module structure of the present invention;

图5为本发明C型模块结构示意图;Fig. 5 is a schematic structural diagram of a C-type module of the present invention;

图6为本发明A型模块和B型模块组合俯视图;Fig. 6 is a combined top view of the A-type module and the B-type module of the present invention;

图7为图6的正视图;Fig. 7 is the front view of Fig. 6;

图8为本发明C型模块与进水渠/出水渠连接示意图;Figure 8 is a schematic diagram of the connection between the C-type module and the water inlet/outlet of the present invention;

图9为本发明处理单元具体布置方式示意图;Fig. 9 is a schematic diagram of the specific layout of the processing unit of the present invention;

其中,1、进水渠;11、导杆;12、通水管;2、处理单元;21、A型模块;211、第一连接部;2111、滚轮;2112、导电插头;2113、第一孔洞;22、B型模块;221、第二连接部;2211、滑道;2212、导电插盒;2213、第二孔洞;2214、滑槽;2215、限位槽;2216、橡胶垫;23、C型模块;231、第三连接部;2311、承插孔;2312、固定环;3、出水渠;4、湿地处理区;5、阴极材料;6、阳极材料;7、上层基质层;8、中层基质层;9、承托层;10、湿地植物。Among them, 1. water inlet; 11. guide rod; 12. water pipe; 2. processing unit; 21. A-type module; 211. first connecting part; 2111. roller; 2112. conductive plug; 22, B-type module; 221, second connection part; 2211, slideway; 2212, conductive box; 2213, second hole; 2214, chute; 2215, limit groove; 2216, rubber pad; 23, C type Module; 231, third connection part; 2311, socket hole; 2312, fixed ring; 3, outlet channel; 4, wetland treatment area; 5, cathode material; 6, anode material; 7, upper matrix layer; 8, middle layer Substratum layer; 9. Supporting layer; 10. Wetland plants.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.

本发明的目的是提供一种模块化微生物燃料电池型人工湿地系统,以解决现有技术存在的问题,通过微生物燃料电池串联组成处理单元,若干处理单元并联组成湿地处理区,能够利用微生物燃料电池增强湿地系统的有机物降解能力和降解速率,同时,能够更换堵塞位置的微生物燃料电池以在解决堵塞问题的基础上保证微生物燃料电池的电能输出。The purpose of the present invention is to provide a modular microbial fuel cell constructed wetland system to solve the problems existing in the prior art. Microbial fuel cells are connected in series to form treatment units, and several treatment units are connected in parallel to form a wetland treatment area, which can utilize microbial fuel cells Enhance the organic matter degradation capacity and degradation rate of the wetland system. At the same time, the microbial fuel cell at the clogged position can be replaced to ensure the electrical energy output of the microbial fuel cell on the basis of solving the clogging problem.

为使本发明的上述目的、特征和优点能够更加明显易懂,下面结合附图和具体实施方式对本发明作进一步详细的说明。In order to make the above objects, features and advantages of the present invention more comprehensible, the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.

如图1~9所示,本发明提供一种模块化微生物燃料电池型人工湿地系统,包括顺次连接的进水渠1、湿地处理区4和出水渠3,各区域通过围挡围制形成,进水渠1用于汇集待处理的废水或污水并分布到湿地处理区4,出水渠3将湿地处理区4流出的经过处理后的水流汇集后流出。湿地处理区4包括并联设置的若干处理单元2,处理单元2的进水口连接进水渠1,处理单元2的出水口连接出水渠3。每个处理单元2包括若干串联连接的微生物燃料电池,微生物燃料电池能够利用微生物将有机物中的化学能直接转化成电能输出,由于微生物会消耗有机物,在一定程度上能够提升系统降解能力,即降低堵塞的概率。微生物燃料电池的两端分别设置有进水口和出水口,并在进水口侧和出水口侧分别设置有极性相反的电极引出端,相邻微生物燃料电池的进水口和出水口可拆卸连接,实现被处理水的流动通道。相邻微生物燃料电池的极性相反的电极引出端可拆卸连接,实现各微生物燃料电池的串联,可以提高输出电压/电流,保证电能的输出利用。同时,不同的处理单元2之间采用并联的方式,可以根据需求,改变串并联组合的方式,实现串并联组合的多样性,能满足外接电路对电压、电流的不同需求,适应性更广泛。本发明通过微生物燃料电池串联组成处理单元2,若干处理单元2并联组成湿地处理区4,能够利用微生物燃料电池增强湿地系统的有机物降解能力和降解速率,同时,当系统发生堵塞时,只需局部更换发生堵塞的微生物燃料电池,避免了传统人工湿地系统的整体更换,降低了运维成本。另外,通过对堵塞位置更换微生物燃料电池,能够避免堵塞引起的电子/质子传输不畅及内电阻增大,有利于电能的持续输出。因此,本发明既能解决湿地堵塞问题,又能提高湿地处理能力,还能将有机质转化为电能输出利用。As shown in Figures 1 to 9, the present invention provides a modular microbial fuel cell constructed wetland system, which includes sequentially connected water inlet canal 1, wetland treatment area 4 and water outlet canal 3, each area is formed by enclosure, The water inlet channel 1 is used to collect waste water or sewage to be treated and distribute it to the wetland treatment area 4 , and the water outlet channel 3 collects the treated water flowing out of the wetland treatment area 4 and then flows out. The wetland treatment area 4 includes several treatment units 2 arranged in parallel. Each processing unit 2 includes several microbial fuel cells connected in series. Microbial fuel cells can use microorganisms to directly convert chemical energy in organic matter into electrical energy output. Since microorganisms consume organic matter, it can improve the degradation capacity of the system to a certain extent, that is, reduce probability of blockage. The two ends of the microbial fuel cell are respectively provided with a water inlet and a water outlet, and electrode leads with opposite polarities are respectively arranged on the water inlet side and the water outlet side, and the water inlet and water outlet of adjacent microbial fuel cells are detachably connected. Realize the flow channel of the treated water. The lead ends of electrodes with opposite polarities of adjacent microbial fuel cells are detachably connected to realize the series connection of microbial fuel cells, which can increase the output voltage/current and ensure the output and utilization of electric energy. At the same time, different processing units 2 are connected in parallel, and the way of series-parallel combination can be changed according to requirements to realize the diversity of series-parallel combination, which can meet the different requirements of external circuits for voltage and current, and has wider adaptability. In the present invention, microbial fuel cells are connected in series to form a processing unit 2, and several processing units 2 are connected in parallel to form a wetland treatment area 4. The microbial fuel cells can be used to enhance the organic matter degradation capacity and degradation rate of the wetland system. At the same time, when the system is blocked, only local Replacement of clogged microbial fuel cells avoids the overall replacement of traditional constructed wetland systems and reduces operation and maintenance costs. In addition, by replacing the microbial fuel cell at the clogged position, the poor electron/proton transmission and internal resistance increase caused by the clogging can be avoided, which is conducive to the continuous output of electric energy. Therefore, the invention can not only solve the wetland blockage problem, but also improve the wetland treatment capacity, and can also convert organic matter into electric energy for output and utilization.

如图3~5所示,微生物燃料电池根据连接部的不同可以分为A型模块21、B型模块22和C型模块23,A型模块21的两端分别设置有第一连接部211,B型模块22的两端分别设置有第二连接部221,C型模块23的两端分别设置有第一连接部211和第三连接部231。第一连接部211与第二连接部221连接,实现A型模块21和B型模块22的连接,或实现C型模块23和B型模块22的连接。第三连接部231与进水渠1连接,实现C型模块23与进水渠1的连接,或第三连接部231与出水渠3连接,实现C型模块23与出水渠3的连接。从而通过上述的设置方式,可以形成CBABC到CBABA...ABC任意形式串联组合成一个处理单元2。如图9所示,可以组合成为由进水渠1经过CBABABC形式的处理单元2后到达出水渠3的结构形式。As shown in Figures 3 to 5, microbial fuel cells can be divided into A-type modules 21, B-type modules 22, and C-type modules 23 according to different connection parts. The two ends of the A-type module 21 are respectively provided with first connection parts 211, Both ends of the B-type module 22 are respectively provided with a second connection portion 221 , and both ends of the C-type module 23 are respectively provided with a first connection portion 211 and a third connection portion 231 . The first connection part 211 is connected to the second connection part 221 to realize the connection between the A-type module 21 and the B-type module 22 , or realize the connection between the C-type module 23 and the B-type module 22 . The third connecting part 231 is connected to the water inlet 1 to realize the connection between the C-shaped module 23 and the water inlet 1 , or the third connecting part 231 is connected to the outlet 3 to realize the connection between the C-shaped module 23 and the outlet 3 . Therefore, through the above-mentioned setting method, any form of CBABC to CBABA...ABC can be combined in series to form a processing unit 2 . As shown in FIG. 9 , it can be combined into a structural form in which the water inlet channel 1 passes through the CBABABC processing unit 2 and then reaches the water outlet channel 3 .

如图3~7所示,第一连接部211可以包括卡板、分布在卡板上的第一孔洞2113以及设置在卡板中部的导电插头2112,第一孔洞2113根据所设置的位置和水流方向的不同可以作为进水口也可以作为出水口。第二连接部221包括与卡板配合的卡槽、分布在卡槽上的第二孔洞2213以及设置在卡槽中部的导电插盒2212,第二孔洞2213根据所设置的位置和水流方向的不同可以作为进水口也可以作为出水口。导电插头2112可以作为阴极或阳极,导电插盒2212也可以作为阴极或阳极,并且,相互连接的导电插头2112和导电插盒2212具有相反的电极,以在插接连接后实现电路串联连通。导电插头2112可以竖向从上向下插入导电插盒2212实现导通,从而能够在卡板与卡槽插接连接后同步实现连接。As shown in Figures 3-7, the first connecting part 211 may include a card board, first holes 2113 distributed on the card board, and a conductive plug 2112 arranged in the middle of the card board, and the first holes 2113 are arranged according to the set position and water flow. The difference in direction can be used as water inlet or water outlet. The second connecting part 221 includes a card slot matched with the card board, second holes 2213 distributed on the card slot, and a conductive box 2212 arranged in the middle of the card slot. The second hole 2213 is different according to the location and the direction of water flow. Can be used as water inlet or water outlet. The conductive plug 2112 can be used as a cathode or an anode, and the conductive plug box 2212 can also be used as a cathode or an anode, and the interconnected conductive plug 2112 and conductive plug box 2212 have opposite electrodes, so as to realize circuit series connection after the plug connection. The conductive plug 2112 can be vertically inserted into the conductive socket 2212 from top to bottom to achieve conduction, so that the connection can be realized synchronously after the card board and the card slot are plugged and connected.

卡槽可以包括位于两侧的滑槽2214和位于底部的限位槽2215,即卡槽整体形成U型结构(参考图4所示)。卡板的两侧分别设置有与滑槽2214对应的第一插接部,卡板的底部设置有与限位槽2215对应的第二插接部。在卡板与卡槽插接时,卡板由上向下通过卡槽U型结构的开口插入卡槽中,两侧的滑槽2214起到侧方的限位和导向,底部的限位槽2215起到向下方向的限位,在卡入到位后防止继续移动,保证不同的微生物燃料电池连接位置的准确性,另外,可以快速定位,也便于安装和拆卸,同时为导电插头2112和导电插盒2212的对正提供了方便。在卡板和卡槽插接连接后还能够在底部和两侧形成半包围结构,将第一孔洞2113和第二孔洞2213在半包围结构内连通,保证连接的密封性,实现水流顺利按照微生物燃料电池的串联顺序进行流动,保证湿地系统的处理效果。The card slot may include sliding slots 2214 on both sides and a limiting slot 2215 on the bottom, that is, the card slot forms a U-shaped structure as a whole (refer to FIG. 4 ). Both sides of the clamping board are respectively provided with first insertion parts corresponding to the sliding slots 2214 , and the bottom of the clamping board is provided with a second insertion part corresponding to the limiting groove 2215 . When the card board is inserted into the card slot, the card board is inserted into the card slot from top to bottom through the opening of the U-shaped structure of the card slot. 2215 acts as a limit position in the downward direction, and prevents further movement after being snapped into place, ensuring the accuracy of the connection positions of different microbial fuel cells. In addition, it can be positioned quickly and is easy to install and disassemble. It is also a conductive plug 2112 and a conductive The alignment of the insert box 2212 provides convenience. After the card board and the card slot are plugged and connected, a semi-enclosed structure can be formed on the bottom and both sides, and the first hole 2113 and the second hole 2213 are connected in the semi-enclosed structure to ensure the tightness of the connection and realize the smooth flow of water according to the microorganisms. The flow of fuel cells in series sequence ensures the treatment effect of the wetland system.

第一插接部沿插接方向依次布置有若干滚轮2111,滚轮2111的滚动方向与第一插接部的插接方向一致,在滑槽2214的一面与滚轮2111对应位置设置有滑道2211,滚轮2111可以在滑道2211内滚动,可以进一步约束卡板与卡槽的相对位置,同时通过设置滚轮2111可以提高插入和拔出过程的容易程度,实现卡板和卡槽装配和拆卸的定位准确、快速、省力,并采用垂直装卸连接方式,更进一步提高卡板与卡槽安装拆卸时的便利程度。A plurality of rollers 2111 are sequentially arranged along the insertion direction of the first socket part, and the rolling direction of the rollers 2111 is consistent with the socket connection direction of the first socket part, and a slideway 2211 is provided on one side of the chute 2214 corresponding to the rollers 2111, The roller 2111 can roll in the slideway 2211, which can further constrain the relative position of the card board and the card slot. At the same time, by setting the roller 2111, the ease of insertion and extraction process can be improved, and the positioning of the card board and the card slot can be assembled and disassembled accurately. , fast, labor-saving, and adopts the vertical loading and unloading connection method, which further improves the convenience of the installation and disassembly of the card board and the card slot.

如图6~7所示,滑槽2214的另一面以及限位槽2215的另一面均设置有橡胶垫2216,滚轮2111进入滑道2211后能够将第一插接部的背面贴合在橡胶垫2216上,形成相对封闭的半包围结构的连通空间,进一步的提高相邻微生物燃料电池连通的密封性。As shown in Figures 6-7, the other side of the chute 2214 and the other side of the limiting groove 2215 are provided with a rubber pad 2216, after the roller 2111 enters the slideway 2211, the back of the first insertion part can be attached to the rubber pad 2216, a relatively closed semi-enclosed communication space is formed to further improve the sealing of the communication between adjacent microbial fuel cells.

如图8所示,第三连接部231可以包括固定环2312,进水渠1处和出水渠3处设置有导杆11,在安装C型模块23时,从上向下插入,此时,固定环2312向下运动能够套入导杆11,即通过导杆11和固定环2312的配合,能够实现C型模块23的顺利定位安装。As shown in Figure 8, the third connecting part 231 may include a fixing ring 2312, guide rods 11 are provided at the water inlet channel 1 and the water outlet channel 3, when installing the C-shaped module 23, insert it from top to bottom, at this time, fix The downward movement of the ring 2312 can be inserted into the guide rod 11 , that is, through the cooperation of the guide rod 11 and the fixing ring 2312 , the smooth positioning and installation of the C-shaped module 23 can be realized.

如图5和图8所示,第三连接部231包括与微生物燃料电池内部连通的开口朝下的承插孔2311,承插孔2311根据连接在进水渠1还是出水渠3上确定是作为进水孔还是出水孔。进水渠1和出水渠3均连接有竖直朝上的通水管12,承插孔2311向下套入通水管12实现连通,可以在承插孔2311处设置有橡胶止水圈,即能够在插入通水管12后实现管壁的密封。通水管12上设置有开关阀门,在需要拆卸C型模块23时,可以先关闭该开关阀门,取出C型模块23进行更换或冲洗后在重新安装后再打开开关阀门。由于各处理单元2并联设置,且处理单元2相对独立运行,因此,在取出堵塞微生物燃料电池进行更换/冲洗时,只需要关闭对应处理单元2的开关阀门,无需系统整体停水,因此并不影响其它处理单元2的正常运行,实现了更换填料不停止系统运行的效果。As shown in FIGS. 5 and 8 , the third connecting portion 231 includes a socket hole 2311 with the opening facing down that communicates with the microbial fuel cell. The water hole is the water hole. Both the water inlet channel 1 and the water outlet channel 3 are connected with a vertically upward water pipe 12, and the socket hole 2311 is inserted downward into the water pipe 12 to realize communication. After the water pipe 12 is inserted, the sealing of the pipe wall is realized. The water pipe 12 is provided with an on-off valve. When the C-type module 23 needs to be dismantled, the on-off valve can be closed earlier, and the C-type module 23 is taken out for replacement or flushing, and then the on-off valve is opened after reinstallation. Since the processing units 2 are arranged in parallel and the processing units 2 operate relatively independently, when taking out the blocked microbial fuel cell for replacement/rinsing, it is only necessary to close the switch valve of the corresponding processing unit 2 without shutting off the water in the whole system, so it is not necessary It affects the normal operation of other processing units 2, and realizes the effect that the replacement of packing does not stop the operation of the system.

如图2所示,微生物燃料电池包括填料床和湿地植物10,填料床包括自下而上设置的承托层9、中层基质层8、上层基质层7,中层基质层8的底部敷设有阳极材料6,上层基质层7的顶部敷设有阴极材料5,阴极材料5和阳极材料6分别连接有不同的电极引出端(可以是导电插头2112也可以是导电插盒2212),上层基质层7中栽种有湿地植物10。As shown in Figure 2, the microbial fuel cell includes a packing bed and wetland plants 10, and the packing bed includes a support layer 9, a middle matrix layer 8, and an upper matrix layer 7 arranged from bottom to top, and the bottom of the middle matrix layer 8 is provided with an anode Material 6, the top of the upper matrix layer 7 is laid with a cathode material 5, the cathode material 5 and the anode material 6 are respectively connected to different electrode leads (which can be a conductive plug 2112 or a conductive plug box 2212), in the upper matrix layer 7 Wetland plants 10 are planted.

微生物燃料电池作为模块化湿地槽,其尺寸长×宽×高可以设计为1.5m×0.8m×1.0m,材质采用具有一定抗拉强度的ABS或聚氯乙烯等材料。承托层9厚20cm,基质选用粒径φ16~30mm的砾石、碎石等材料;中层基质层8厚35cm,基质选用粒径φ4~15mm的砾石、沸石等材料;上层基质层7厚15cm,基质选用粒径较小的粗砂或土壤等材料;湿地植物10选用芦苇、菖蒲、美人蕉等。可以在上层基质层7顶部敷设活性炭层或者石墨毯等导电材料作为阴极材料5,在中层基质层8底部敷设活性炭层或者石墨毯等导电材料作为阳极材料6。As a modular wetland tank, the microbial fuel cell can be designed as 1.5m x 0.8m x 1.0m in length x width x height, and the material is made of ABS or polyvinyl chloride with a certain tensile strength. The supporting layer 9 is 20cm thick, and the matrix is made of gravel and gravel with a particle size of φ16-30mm; the middle matrix layer 8 is 35cm thick, and the matrix is made of gravel and zeolite with a particle size of φ4-15mm; the upper matrix layer 7 is 15cm thick, Materials such as coarse sand or soil with a small particle size are selected as the substrate; reeds, calamus, canna, etc. are selected as the wetland plants 10 . A conductive material such as an activated carbon layer or a graphite blanket can be laid on the top of the upper matrix layer 7 as the cathode material 5, and a conductive material such as an activated carbon layer or a graphite blanket can be laid on the bottom of the middle matrix layer 8 as the anode material 6.

每个微生物燃料电池形成一个模块化的湿地,废水流经该湿地时,在基质层的截留过滤吸附等物理作用,和附着在基质、根系表面微生物群的生物降解,以及湿地植物10的吸收、根际效应作用下得到净化。湿地下层厌氧区构成微生物燃料电池的阳极室,附着在阳极材料6上的产电菌氧化降解废水中有机物产生电子和质子,电子经阳极材料6和外接导线连接至另一模块阴极材料5,质子随废水上流至阴极材料5。湿地上层在空气复氧、植物根系泌氧作用下形成好氧区构成微生物燃料电池的阴极室,质子在氧气参与下发生电极反应变成水。上述过程,既实现了污水净化,又形成了微生物燃料电池。通过本发明的模块化装置,一方面,阴/阳极两室的氧化还原电位差形成了电压,实现了电能输出。另一方面,微生物燃料电池内部电子加速流通有助于有机物电子的供给,增强了湿地系统的有机物降解能力和降解速率。Each microbial fuel cell forms a modular wetland. When wastewater flows through the wetland, physical effects such as interception, filtration, and adsorption in the substrate layer, biodegradation of the microbial population attached to the surface of the substrate and root system, and absorption of wetland plants 10, Purified under the effect of rhizosphere effect. The wet subterranean anaerobic zone constitutes the anode chamber of the microbial fuel cell, and the electrogenic bacteria attached to the anode material 6 oxidize and degrade the organic matter in the waste water to generate electrons and protons, and the electrons are connected to the cathode material 5 of another module through the anode material 6 and external wires, The protons flow up to the cathode material 5 with the wastewater. The upper layer of the wetland forms an aerobic zone under the action of air reoxygenation and plant root oxygen secretion to form the cathode chamber of the microbial fuel cell, and the protons undergo an electrode reaction with the participation of oxygen to become water. The above process not only realizes the purification of sewage, but also forms a microbial fuel cell. Through the modularized device of the present invention, on the one hand, the oxidation-reduction potential difference between the cathode and anode chambers forms a voltage to realize electric energy output. On the other hand, the accelerated circulation of electrons in the microbial fuel cell is helpful to the supply of organic matter electrons, which enhances the degradation capacity and rate of organic matter in the wetland system.

综上,本发明通过模块化和微生物燃料电池的有机结合,相互强化了防堵塞、污染物降解、电能输出的能力,使之各方面能力较未结合时得到显著提高。To sum up, the present invention, through the organic combination of modularization and microbial fuel cells, mutually strengthens the abilities of anti-clogging, pollutant degradation, and electric energy output, so that the abilities of all aspects are significantly improved compared with those without the combination.

本发明中应用了具体个例对本发明的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本发明的方法及其核心思想;同时,对于本领域的一般技术人员,依据本发明的思想,在具体实施方式及应用范围上均会有改变之处。综上所述,本说明书内容不应理解为对本发明的限制。In the present invention, specific examples have been used to illustrate the principle and implementation of the present invention. The description of the above embodiments is only used to help understand the method and core idea of the present invention; meanwhile, for those of ordinary skill in the art, according to the present invention The idea of the invention will have changes in the specific implementation and scope of application. In summary, the contents of this specification should not be construed as limiting the present invention.

Claims (10)

1. A modular microbial fuel cell type constructed wetland system, which is characterized in that: including the inlet canal, wetland treatment district and the water outlet canal of connecting in order, the wetland treatment district is including a plurality of processing units of parallelly connected setting, processing unit's water inlet is connected the inlet canal, processing unit's delivery port is connected the water outlet canal, every processing unit includes a plurality of microbiological fuel cells of series connection, microbiological fuel cell's both ends are provided with water inlet and delivery port respectively to be provided with the electrode extraction end opposite in polarity respectively at water inlet side and delivery port side, adjacent microbiological fuel cell's water inlet and delivery port can dismantle the connection, and adjacent microbiological fuel cell's electrode extraction end opposite in polarity can dismantle the connection.
2. The modular microbial fuel cell constructed wetland system according to claim 1, wherein: the microbial fuel cell is divided into an A-type module, a B-type module and a C-type module according to the difference of the connecting parts, wherein the two ends of the A-type module are respectively provided with a first connecting part, the two ends of the B-type module are respectively provided with a second connecting part, the two ends of the C-type module are respectively provided with a first connecting part and a third connecting part, the first connecting part is connected with the second connecting part, and the third connecting part is connected with the water inlet channel or the water outlet channel.
3. The modular microbial fuel cell constructed wetland system according to claim 2, wherein: the first connecting portion comprises a clamping plate, first holes distributed on the clamping plate and a conductive plug arranged in the middle of the clamping plate, the second connecting portion comprises a clamping groove matched with the clamping plate, second holes distributed on the clamping groove and a conductive plug box arranged in the middle of the clamping groove, the conductive plug and the conductive plug box are respectively connected with different electrodes, and the conductive plug box can be connected after the clamping plate is connected with the clamping groove in a plugging mode.
4. A modular microbial fuel cell constructed wetland system according to claim 3, wherein: the clamping groove comprises sliding grooves on two sides and a limiting groove on the bottom, the two sides of the clamping plate are respectively provided with a first inserting part corresponding to the sliding grooves, and the bottom of the clamping plate is provided with a second inserting part corresponding to the limiting groove.
5. The modular microbial fuel cell constructed wetland system according to claim 4, wherein: the first inserting portion is provided with a plurality of rollers in sequence along the inserting direction, and a slide way is arranged at a position corresponding to one surface of the sliding groove and the rollers.
6. The modular microbial fuel cell constructed wetland system according to claim 5, wherein: the other face of the chute and the other face of the limiting groove are both provided with rubber pads, and the back face of the first inserting part is attached to the rubber pads after the rollers enter the chute.
7. The modular microbial fuel cell constructed wetland system according to any one of claims 2 to 6, wherein: the third connecting part comprises a fixed ring, guide rods are arranged at the water inlet canal and the water outlet canal, and the fixed ring can be sleeved into the guide rods by downward movement.
8. The modular microbial fuel cell constructed wetland system according to claim 7, wherein: the third connecting portion comprises a socket hole with a downward opening communicated with the interior of the microbial fuel cell, the water inlet channel and the water outlet channel are both connected with a vertical upward water pipe, a switch valve is arranged on the water pipe, and the socket hole is sleeved into the water pipe downwards to realize communication.
9. The modular microbial fuel cell constructed wetland system according to claim 1, wherein: the microbial fuel cell comprises a packed bed and wetland plants, wherein the packed bed comprises a supporting layer, a middle substrate layer and an upper substrate layer which are arranged from bottom to top, anode materials are laid at the bottom of the middle substrate layer, cathode materials are laid at the top of the upper substrate layer, the cathode materials and the anode materials are respectively connected with different electrode leading-out ends, and the wetland plants are planted in the upper substrate layer.
10. The modular microbial fuel cell constructed wetland system according to claim 9, wherein: the thickness of the bearing layer is 20cm, and the substrate is gravel with the particle diameter phi of 16-30 mm; the thickness of the middle layer matrix layer is 35cm, and the matrix adopts gravel and zeolite with the particle diameter phi of 4-15 mm; the thickness of the upper substrate layer is 15cm, and coarse sand or soil with smaller particle size is selected as the substrate; the wetland plants are reed, calamus and canna; the cathode material and the anode material adopt an active carbon layer or a graphite blanket.
CN202310033634.6A 2023-01-10 2023-01-10 A modular microbial fuel cell constructed wetland system Pending CN116102158A (en)

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CN112823141A (en) * 2018-06-28 2021-05-18 水循环有限责任公司 Scalable continuous flow microbial fuel cell
CN217684588U (en) * 2022-07-13 2022-10-28 中山市优谦照明电器有限公司 Wall lamp light-emitting module
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CN105858900A (en) * 2016-05-18 2016-08-17 东南大学 Modularized grid-type combined artificial wetland system
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