CN115962470A - CO treatment incinerator system - Google Patents
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Abstract
Description
技术领域technical field
本发明属于废气处理技术领域,具体涉及一种CO治理焚烧炉系统。The invention belongs to the technical field of waste gas treatment, and in particular relates to a CO treatment incinerator system.
背景技术Background technique
因工艺生产需要,还原钛生产窑炉出口烟气中含CO浓度1~7%,NOx含量为70~100mg/Nm3,出于节能减碳的要求,需要将烟气中的CO浓度降低至300mg/m3以下,同时NOx≤50mg/Nm3,而现有技术中的CO处理系统无法满足上述要求。Due to the needs of process production, the CO concentration in the flue gas at the outlet of the reduction titanium production kiln is 1-7%, and the NOx content is 70-100mg/Nm 3 . In order to meet the requirements of energy saving and carbon reduction, the CO concentration in the flue gas needs to be reduced to 300mg/m 3 or less, and NOx ≤ 50mg/Nm 3 , while the CO treatment system in the prior art cannot meet the above requirements.
发明内容Contents of the invention
本发明的目的就在于为解决现有技术的不足而提供一种CO治理焚烧炉系统。The purpose of the present invention is to provide a CO treatment incinerator system to solve the deficiencies of the prior art.
本发明的目的是以下述技术方案实现的:The purpose of the present invention is achieved with the following technical solutions:
一种CO治理焚烧炉系统,包括焚烧炉、燃烧器、SNCR脱硝系统和控制器;A CO treatment incinerator system, including an incinerator, a burner, an SNCR denitrification system and a controller;
所述燃烧器为4个,呈四角切圆布置于所述焚烧炉的进口端的四周;所述燃烧器上设有烟气进气口、补气进气口以及补气调节阀、烟气助燃风进风口以及烟气助燃风调节阀、补气助燃风进风口以及补气助燃风调节阀;There are 4 burners, which are arranged around the inlet end of the incinerator in a four-corner tangential circle; the burners are provided with a flue gas inlet, a supplementary air intake, a supplementary gas regulating valve, and a flue gas combustion-supporting valve. Air inlet and flue gas combustion-supporting air regulating valve, gas-supplementing combustion-supporting air inlet and gas-supplementing combustion-supporting air regulating valve;
所述SNCR脱硝系统设于所述焚烧炉内的进口端和出口端之间;The SNCR denitrification system is located between the inlet and outlet of the incinerator;
所述焚烧炉的出口端设有温度传感器,用于检测焚烧后出口的烟气温度;The outlet end of the incinerator is provided with a temperature sensor for detecting the flue gas temperature at the outlet after incineration;
所述控制器与所述温度传感器、所述补气调节阀、所述烟气助燃风调节阀、所述补气助燃风调节阀电连接,用于接收所述温度传感器检测的出口烟气温度,当所述出口烟气温度小于设定阈值时,控制增大所述补气调节阀和所述补气助燃风调节阀的开度、或/和、增大所述烟气助燃风调节阀的开度;当所述出口烟气温度大于设定阈值时,控制减小所述补气调节阀和所述补气助燃风调节阀的开度、或/和、减小所述烟气助燃风调节阀的开度。The controller is electrically connected with the temperature sensor, the air supply regulating valve, the flue gas combustion-supporting air regulating valve, and the supplementary air combustion-supporting air regulating valve, and is used to receive the outlet flue gas temperature detected by the temperature sensor , when the temperature of the flue gas at the outlet is lower than the set threshold, control to increase the opening degrees of the supplementary air regulating valve and the supplementary air combustion air regulating valve, or/and increase the flue gas combustion supporting air regulating valve When the outlet flue gas temperature is greater than the set threshold, control the opening of the supplementary air regulating valve and the supplementary air combustion air regulating valve, or/and reduce the combustion of the flue gas The opening of the air regulating valve.
优选的,所述焚烧炉为立式焚烧炉;所述焚烧炉的纵截面为方形。Preferably, the incinerator is a vertical incinerator; the longitudinal section of the incinerator is square.
优选的,所述焚烧炉炉体采用内衬浇注料和保温棉的结构。Preferably, the body of the incinerator adopts a structure of lining castable and insulation cotton.
优选的,所述焚烧炉内还设有多个温度传感器。Preferably, multiple temperature sensors are also provided in the incinerator.
优选的,所述焚烧炉的出口端还设有烟气氧含量检测仪。Preferably, the outlet end of the incinerator is also equipped with a flue gas oxygen content detector.
优选的,所述补气为天然气。Preferably, the supplementary gas is natural gas.
优选的,所述燃烧器为低氮燃烧器。Preferably, the burner is a low nitrogen burner.
优选的,所述焚烧炉的出口端连接余热锅炉。Preferably, the outlet end of the incinerator is connected to a waste heat boiler.
优选的,所述设定阈值为850~900℃。Preferably, the set threshold is 850-900°C.
优选的,所述烟气在所述立式焚烧炉内的停留时间为1.5~2.5S。Preferably, the residence time of the flue gas in the vertical incinerator is 1.5-2.5S.
本申请通过设置四角切圆燃烧器,可保证烟气中CO及颗粒物中固定碳的快速、充分燃烧,减少CO和NOx的生成,设置SNCR(选择性非催化还原)脱硝系统,可有效脱硝,去除烟气中的氮氧化物,通过控制器,根据出口烟气温度自动调节补气和补气助燃风的通入量或烟气助燃风的通入量,进一步确保了烟气燃烧充分,燃烧后的烟气中的CO和NOx含量符合要求。In this application, by setting the four-corner tangential burner, it can ensure the rapid and full combustion of CO in the flue gas and the fixed carbon in the particulate matter, reduce the generation of CO and NOx, and set the SNCR (selective non-catalytic reduction) denitrification system, which can effectively denitrify, Remove the nitrogen oxides in the flue gas, through the controller, according to the temperature of the outlet flue gas, it can automatically adjust the intake of supplementary air and combustion-supporting air or the intake of flue gas combustion-supporting air, which further ensures that the flue gas is fully combusted and the combustion The CO and NOx contents in the flue gas meet the requirements.
附图说明Description of drawings
图1是本发明提供的CO治理焚烧炉系统的结构示意图;Fig. 1 is the structural representation of the CO treatment incinerator system provided by the present invention;
图2是四角切圆燃烧器的布置示意图;Fig. 2 is a schematic diagram of the layout of the four-corner tangential burner;
图3是焚烧炉内热力场图;Fig. 3 is the thermodynamic field diagram in the incinerator;
其中,1-焚烧炉;2-燃烧器;3-SNCR脱硝系统;5-温度传感器;6-烟气氧含量检测仪;7-余热锅炉。Among them, 1-incinerator; 2-burner; 3-SNCR denitrification system; 5-temperature sensor; 6-flue gas oxygen content detector; 7-waste heat boiler.
具体实施方式Detailed ways
本发明提供了一种CO治理焚烧炉系统,如图1~2所示,包括焚烧炉1、燃烧器2、SNCR脱硝系统3和控制器。The present invention provides a CO treatment incinerator system, as shown in Figures 1-2, including an
燃烧器为4个,呈四角切圆布置于焚烧炉的进口端的四周,可通过螺栓固接在炉墙上,4个燃烧器安装时形成一定的切圆。燃烧器优选采用低氮燃烧器,可减少氮氧化物产量。There are 4 burners, which are arranged around the inlet end of the incinerator in a four-corner tangent circle, and can be fixed on the furnace wall through bolts. When the 4 burners are installed, they form a certain tangent circle. The burner is preferably a low-nitrogen burner, which can reduce the output of nitrogen oxides.
燃烧器上设有烟气进气口、补气进气口以及补气调节阀、烟气助燃风进风口以及烟气助燃风调节阀、补气助燃风进风口以及补气助燃风调节阀。补气优选为天然气。为了将烟气中的CO燃尽,需要补燃一部分天然气,和烟气一起作为燃料燃烧。本申请设置单独的烟气进气口和补气进气口,以及相应的助燃风进风口,并配置相应的调节阀,烟气和补气可分开加入,可以根据燃烧所需,调整补气(天然气)和烟气的配比。补气和烟气助燃风也通过不同的进口进入焚烧炉,这样更有益于各自燃料的空燃比配比。The burner is provided with a flue gas inlet, a supplementary air intake, a supplementary gas regulating valve, a flue gas combustion-supporting air intake, a flue gas combustion-supporting air regulating valve, a gas-combustion-supporting air intake, and a gas-combustion-supporting air regulating valve. The make-up gas is preferably natural gas. In order to burn out the CO in the flue gas, a part of natural gas needs to be reburned and burned together with the flue gas as fuel. This application sets up separate flue gas inlets and supplementary air inlets, as well as corresponding combustion air inlets, and is equipped with corresponding regulating valves. The flue gas and supplementary air can be added separately, and the supplementary air can be adjusted according to the needs of combustion. (natural gas) and flue gas ratio. Supplementary air and flue gas combustion-supporting air also enter the incinerator through different inlets, which is more beneficial to the air-fuel ratio of the respective fuels.
使用时,先采用天然气先把炉膛温度提升,达到烟气中的CO可以燃烧的温度,然后才通入烟气,烟气和天然气可通过气体分配器从四个燃烧器共同进入焚烧炉内,在炉内形成一定直径的虚拟切圆,旋转向上快速流动,在短时间内,使废气中的CO反应完全,减少尾气中的CO含量。而且,由于设置了4个燃烧器,可以分散燃烧,降低燃烧温度,从而也降低NOx的生成。When in use, first use natural gas to raise the temperature of the furnace to reach the temperature where CO in the flue gas can burn, and then pass in the flue gas. The flue gas and natural gas can enter the incinerator from the four burners through the gas distributor. A virtual tangential circle with a certain diameter is formed in the furnace, and it rotates and flows upward quickly. In a short time, the CO in the exhaust gas is completely reacted and the CO content in the exhaust gas is reduced. Moreover, since four burners are installed, the combustion can be distributed and the combustion temperature can be reduced, thereby reducing the generation of NOx.
SNCR(选择性非催化还原)脱硝系统3设于焚烧炉内的进口端和出口端之间。SNCR是一种不用催化剂,在850~1100℃范围内还原NOx的方法,因此,SNCR(选择性非催化还原)脱硝系统3位于焚烧炉内850~1100℃范围区域,使用时喷入还原剂氨,该还原剂迅速热分解成NH3,并与燃烧后的烟气中的NOx进行SNCR反应生成N2和H2O,从而达到脱硝的目的,确保烟气中的NOx达到排放标准。The SNCR (Selective Non-Catalytic Reduction)
焚烧炉1的出口端连接余热锅炉7,经过燃烧、脱硝处理后的烟气仍具有一定的温度,将其输送至余热锅炉对余热进行回收利用。The outlet end of the
在焚烧炉的出口端还设有温度传感器5,用于检测焚烧后出口的烟气温度,控制温度为850~900℃,当烟气温度过低时,说明烟气未充分燃烧,将导致烟气中CO含量较高,当烟气温度过高时,说明烟气过分燃烧,能耗过高,且存在NOx含量增多的缺陷。There is also a temperature sensor 5 at the outlet of the incinerator, which is used to detect the temperature of the flue gas at the outlet after incineration. The temperature is controlled at 850-900°C. The CO content in the gas is relatively high. When the flue gas temperature is too high, it means that the flue gas is over-combusted, the energy consumption is too high, and there is a defect that the NOx content increases.
控制器与温度传感器、补气调节阀、烟气助燃风调节阀、补气助燃风调节阀电连接,用于接收温度传感器检测的出口烟气温度,当出口烟气温度小于设定阈值时,控制增大补气调节阀和补气助燃风调节阀的开度、或/和、增大烟气助燃风调节阀的开度,提高天然气的供气量,从而提高烟气温度,使烟气燃烧完全,降低烟气中的CO含量;当出口烟气温度大于设定阈值时,控制减小补气调节阀和补气助燃风调节阀的开度、或/和、减小烟气助燃风调节阀的开度,降低烟气中的NOx含量,且减少能耗。The controller is electrically connected with the temperature sensor, the air supply regulating valve, the flue gas combustion-supporting air regulating valve, and the air supply combustion-supporting air regulating valve, and is used to receive the outlet flue gas temperature detected by the temperature sensor. When the outlet flue gas temperature is lower than the set threshold, Control and increase the opening of the air supply regulating valve and the air supply combustion air regulating valve, or/and increase the opening of the flue gas combustion air regulating valve to increase the gas supply of natural gas, thereby increasing the temperature of the flue gas and making the flue gas Combustion is complete, reduce the CO content in the flue gas; when the outlet flue gas temperature is greater than the set threshold, control to reduce the opening of the air supply regulating valve and the air supply combustion air regulating valve, or/and reduce the combustion air of the flue gas Adjust the opening of the valve to reduce the NOx content in the flue gas and reduce energy consumption.
本申请设置四角切圆燃烧器,邻角加热着火,整体组织燃烧,对空气和燃料的分配均匀性要求低,单只燃烧器喷嘴是否处于最佳工况对整体燃烧影响小,后期混合强,有利于燃尽,炉膛周向和高度方向热负荷均匀,如图3所示。本申请燃料(烟气和天然气)随空气(助燃风)在炉膛内一起向上运动,燃烧的各个阶段均在悬浮状态下进行,燃料燃烧速度快、燃烧效率高,在炉内燃尽所需的时间短。由于设置了多个燃烧器,焚烧炉负荷调节范围大,可在20~110%负荷范围内调整,运行稳定,操作简单。This application is equipped with a four-corner tangential burner, adjacent corners are heated and ignited, and the overall organization is combusted. The requirements for the uniformity of air and fuel distribution are low. Whether a single burner nozzle is in the best working condition has little impact on the overall combustion. It is conducive to burnout, and the heat load in the circumferential and height directions of the furnace is uniform, as shown in Figure 3. The fuel (flue gas and natural gas) of this application moves upward together with the air (combustion-supporting air) in the furnace, and each stage of combustion is carried out in a suspended state. short. Due to the arrangement of multiple burners, the load adjustment range of the incinerator is large, and can be adjusted within the range of 20% to 110% load, with stable operation and simple operation.
因此,本申请通过设置四角切圆燃烧器,可保证烟气中CO及颗粒物中固定碳的快速、充分燃烧,减少CO和NOx的生成,设置SNCR(选择性非催化还原)脱硝系统,可有效脱硝,去除烟气中的氮氧化物,通过控制器,根据出口烟气温度自动调节补气和补气助燃风的通入量或烟气助燃风的通入量,进一步确保了烟气燃烧充分,燃烧后的烟气中的CO和NOx含量符合要求。通过本申请提供的焚烧炉系统,烟气中的CO浓度降低至300mg/m3以下,最低可降低至150~160mg/m3,同时NOx达到35mg/Nm3以下,最低可降低至20mg/Nm3,符合要求。Therefore, by setting the four-corner tangential burner, the present application can ensure the rapid and full combustion of CO in the flue gas and the fixed carbon in the particulate matter, reduce the generation of CO and NOx, and set the SNCR (selective non-catalytic reduction) denitrification system, which can effectively Denitrification, removal of nitrogen oxides in the flue gas, through the controller, according to the outlet flue gas temperature, automatically adjust the intake of supplementary air and combustion-supporting air or the intake of flue gas combustion-supporting air, further ensuring that the flue gas is fully combusted , the CO and NOx contents in the flue gas after combustion meet the requirements. Through the incinerator system provided by this application, the CO concentration in the flue gas can be reduced to below 300mg/m 3 , the lowest can be reduced to 150-160mg/m 3 , and the NOx can be reduced to below 35mg/Nm 3 , the lowest can be reduced to 20mg/Nm 3 , meet the requirements.
优选的,控制器,焚烧炉控制、燃烧器系统控制、SNCR脱硝系统控制可整合进DCS系统中,进行统一控制,可在DCS上监控系统设备。Preferably, the controller, incinerator control, burner system control, and SNCR denitrification system control can be integrated into the DCS system for unified control, and the system equipment can be monitored on the DCS.
优选的,焚烧炉为立式焚烧炉,采用立式布置,占地面积小,可充分利用现场空间,而且立式炉体较长,可延长烟气在焚烧炉内的停留时间,停留时间控制为1.5~2.5S,使CO充分燃尽。焚烧炉的纵截面为方形,方形设计既美观,又满足燃烧需要。Preferably, the incinerator is a vertical incinerator, which adopts a vertical layout, occupies a small area, and can make full use of the site space, and the vertical furnace body is longer, which can prolong the residence time of the flue gas in the incinerator, and the residence time control 1.5 ~ 2.5S, so that CO is fully burned. The longitudinal section of the incinerator is square, and the square design is not only beautiful, but also meets the needs of combustion.
优选的,焚烧炉炉体采用内衬浇注料和保温棉的结构,可以有效保护炉体结构,确保炉内温度,保证CO在焚烧炉内燃烧,并减少热损失。Preferably, the incinerator body is lined with castables and insulation cotton, which can effectively protect the structure of the furnace body, ensure the temperature in the furnace, ensure that CO burns in the incinerator, and reduce heat loss.
优选的,焚烧炉的出口端还设有烟气氧含量检测仪6,用于检测焚烧后烟气中的氧含量,烟气中的氧含量一定程度上也可反映烟气燃烧状况,可根据氧含量及时对燃烧状况进行调整。为了确保测量的精确性,烟气氧含量检测仪可以设置为多个。Preferably, the outlet end of the incinerator is also equipped with a flue gas oxygen content detector 6, which is used to detect the oxygen content in the flue gas after incineration. The oxygen content in the flue gas can also reflect the flue gas combustion state to a certain extent. The oxygen content is adjusted in time to the combustion status. In order to ensure the accuracy of measurement, there can be more than one flue gas oxygen content detector.
如本领域技术人员可以理解的,焚烧炉上还布置有温度测点、氧量测点、CEMS系统(烟气自动监控系统)CO浓度测点,NOx测点等,这样可以直观的反应和监控焚烧炉炉内燃烧状况,以便及时的对燃烧状况进行调整,从而确保燃烧产物含量达到设计要求。As those skilled in the art can understand, the incinerator is also equipped with temperature measuring points, oxygen measuring points, CEMS system (flue gas automatic monitoring system) CO concentration measuring points, NOx measuring points, etc., so that it can be intuitively reacted and monitored The combustion conditions in the incinerator can be adjusted in time to ensure that the content of combustion products meets the design requirements.
尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。While preferred embodiments of the invention have been described, additional changes and modifications to these embodiments can be made by those skilled in the art once the basic inventive concept is appreciated. Therefore, it is intended that the appended claims be construed to cover the preferred embodiment as well as all changes and modifications which fall within the scope of the invention. Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalent technologies, the present invention also intends to include these modifications and variations.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109838795A (en) * | 2019-02-28 | 2019-06-04 | 北京航化节能环保技术有限公司 | A kind of incinerator and method for realizing high nitrogenous exhaust gas, waste liquid nitrogen oxides minimizing discharge |
| CN111578296A (en) * | 2020-04-17 | 2020-08-25 | 江联重工集团股份有限公司 | NO control for blast furnace gas boilerXMethod of generation |
| CN211424419U (en) * | 2019-10-29 | 2020-09-04 | 河南佰利联新材料有限公司 | Tail gas combustion equipment |
| CN216844697U (en) * | 2022-03-15 | 2022-06-28 | 中国铁建重工集团股份有限公司 | Movable garbage incineration device |
| CN114963208A (en) * | 2022-06-20 | 2022-08-30 | 河南佰利联新材料有限公司 | CO waste gas treatment system |
| CN219063478U (en) * | 2023-01-06 | 2023-05-23 | 河南佰利联新材料有限公司 | CO treatment incinerator system |
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| CN109838795A (en) * | 2019-02-28 | 2019-06-04 | 北京航化节能环保技术有限公司 | A kind of incinerator and method for realizing high nitrogenous exhaust gas, waste liquid nitrogen oxides minimizing discharge |
| CN211424419U (en) * | 2019-10-29 | 2020-09-04 | 河南佰利联新材料有限公司 | Tail gas combustion equipment |
| CN111578296A (en) * | 2020-04-17 | 2020-08-25 | 江联重工集团股份有限公司 | NO control for blast furnace gas boilerXMethod of generation |
| CN216844697U (en) * | 2022-03-15 | 2022-06-28 | 中国铁建重工集团股份有限公司 | Movable garbage incineration device |
| CN114963208A (en) * | 2022-06-20 | 2022-08-30 | 河南佰利联新材料有限公司 | CO waste gas treatment system |
| CN219063478U (en) * | 2023-01-06 | 2023-05-23 | 河南佰利联新材料有限公司 | CO treatment incinerator system |
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