CN115947501A - A kind of strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water - Google Patents

A kind of strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water Download PDF

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CN115947501A
CN115947501A CN202310102315.6A CN202310102315A CN115947501A CN 115947501 A CN115947501 A CN 115947501A CN 202310102315 A CN202310102315 A CN 202310102315A CN 115947501 A CN115947501 A CN 115947501A
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ultrafiltration membrane
flocculation
circulation
water
enters
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巩福栋
吴军
陈汪洋
桂祖晟
徐培豪
叶丹
李宾
金家明
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Ruikun Engineering Consulting Hangzhou Co ltd
Zhejiang Qianjiang Water Supply Co ltd
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Ruikun Engineering Consulting Hangzhou Co ltd
Zhejiang Qianjiang Water Supply Co ltd
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Abstract

本发明涉及一种自然流水的强絮凝超滤膜净水处理方法,其特征在于采用以下步骤:S1、将自然流水、絮凝剂加入环流絮凝箱,所述环流絮凝箱底部设有排泥管,中部设有一个导流筒,所述导流筒中设有一个提升搅拌器;环流絮凝箱中部设置絮凝液出液管;自然流水与絮凝剂在环流絮凝箱内充分混合后形成絮凝液;S2、所述絮凝液经过增压泵提压后进入自清洗过滤器,然后从超滤膜净化器顶部进入超滤膜净化器,过滤后所得净水从超滤膜净化器中部的净水管流出;超滤膜前形成的浓缩液进入超滤膜净化器底部的回流管;所述回流管连接环流絮凝箱,所述浓缩液通过回流管进入环流絮凝箱中。本发明具有工艺流程短、抗污堵能力强、运行简单可靠等有益效果。

Figure 202310102315

The present invention relates to a natural flowing water strong flocculation ultrafiltration membrane water purification treatment method, which is characterized in that the following steps are adopted: S1, adding natural flowing water and flocculant into a circulation flocculation box, the bottom of the circulation flocculation box is provided with a mud discharge pipe, There is a guide tube in the middle, and a lifting agitator is arranged in the guide tube; the flocculation liquid outlet pipe is set in the middle of the circulation flocculation box; the natural flowing water and the flocculant are fully mixed in the circulation flocculation box to form a flocculation liquid; S2, The flocculant enters the self-cleaning filter after being boosted by the booster pump, and then enters the ultrafiltration membrane purifier from the top of the ultrafiltration membrane purifier, and the purified water obtained after filtration flows out from the water purification pipe in the middle of the ultrafiltration membrane purifier; The concentrated liquid formed before the ultrafiltration membrane enters the return pipe at the bottom of the ultrafiltration membrane purifier; the return pipe is connected to the circulation flocculation box, and the concentrated liquid enters the circulation flocculation box through the return pipe. The invention has the beneficial effects of short technological process, strong anti-fouling ability, simple and reliable operation, and the like.

Figure 202310102315

Description

一种自然流水的强絮凝超滤膜净水处理方法A kind of strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water

技术领域technical field

本发明涉及净水处理技术领域,特别涉及一种自然流水强絮凝超滤膜净水处理方法。The invention relates to the technical field of water purification treatment, in particular to a water purification treatment method of natural flowing water strong flocculation ultrafiltration membrane.

背景技术Background technique

《生活饮用水卫生标准(GB5749-2022)》于2022年3月发布,2023年4月1日执行。该标准删除了小型集中式和分散式供水部分水质指标及限值的暂行规定,意味着城乡供水水质要求同质化。对小型集中式和分散式供水水质提出了更高的要求。小型集中式和分散式供水主要分布于农村、牧区、矿区以及远离城镇市政管网配套的工厂,往往自然条件上具有水源水质差、季节性变化大的特点,管理上又缺乏专业管理人员。使得传统的混凝、沉淀、砂滤工艺难以稳定达标。超滤膜处理净水处理方法具有净水出水浊度低,水质较好的优点从而引起重视。但常规的全流量超滤膜净水工艺对原水的预处理要求较高,否则膜孔易堵塞影响正常使用。错流过滤能解决膜孔堵塞问题,但能耗高,运行费用大也使得其难以推广使用。自清洗过滤器是一种利用滤网直接拦截液体中的杂质,漂浮物,颗粒物等,同时降低水的浊度,减少污垢,同时保障后面设备正常工作及使用寿命的精密设备,它具有可自动排污的特点。The Hygienic Standard for Drinking Water (GB5749-2022) was released in March 2022 and will be implemented on April 1, 2023. The standard deletes the provisional provisions on water quality indicators and limit values for small-scale centralized and decentralized water supply, which means that the water quality requirements for urban and rural water supply are homogeneous. Higher requirements are put forward for the water quality of small centralized and decentralized water supply. Small-scale centralized and decentralized water supply is mainly distributed in rural areas, pastoral areas, mining areas, and factories far away from urban municipal pipe networks. Natural conditions often have the characteristics of poor water quality and large seasonal changes, and there is a lack of professional management personnel in management. It makes it difficult for the traditional coagulation, sedimentation, and sand filtration processes to meet the standards stably. The water purification treatment method of ultrafiltration membrane treatment has the advantages of low turbidity of purified water effluent and good water quality, which has attracted attention. However, the conventional full-flow ultrafiltration membrane water purification process requires high pretreatment of raw water, otherwise the membrane pores are easily blocked and affect normal use. Cross-flow filtration can solve the problem of membrane pore clogging, but its high energy consumption and high operating costs also make it difficult to promote its use. The self-cleaning filter is a precision device that uses the filter to directly intercept impurities, floating objects, particles, etc. in the liquid, while reducing the turbidity of the water, reducing dirt, and at the same time ensuring the normal operation and service life of the subsequent equipment. It has automatic The characteristics of sewage.

发明内容Contents of the invention

本发明要解决的技术问题是,提供一种具有工艺流程短、抗污堵能力强、运行简单可靠的超滤膜净水工艺。The technical problem to be solved by the present invention is to provide an ultrafiltration membrane water purification process with short process flow, strong anti-fouling ability, and simple and reliable operation.

为解决上述技术问题,本发明采用以下技术方案,一种自然流水的强絮凝超滤膜净水处理方法,其特征在于采用以下步骤:In order to solve the above-mentioned technical problems, the present invention adopts the following technical scheme, a kind of strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water, it is characterized in that adopting following steps:

S1、将自然流水、絮凝剂加入环流絮凝箱,所述环流絮凝箱底部设有排泥管,中部设有一个导流筒,所述导流筒中设有一个提升搅拌器;环流絮凝箱中部设置絮凝液出液管;自然流水与絮凝剂在环流絮凝箱内充分混合后形成絮凝液;S1. Add natural flowing water and flocculant into the circulation flocculation box, the bottom of the circulation flocculation box is provided with a mud discharge pipe, and a guide tube is provided in the middle, and a lifting agitator is provided in the guide tube; the middle part of the circulation flocculation box is set Flocculant liquid outlet pipe; natural flowing water and flocculant are fully mixed in the circulation flocculation box to form flocculant liquid;

S2、所述絮凝液经过增压泵提压后进入自清洗过滤器,然后从超滤膜净化器顶部进入超滤膜净化器,过滤后所得净水从超滤膜净化器中部的净水管流出;超滤膜前形成的浓缩液进入超滤膜净化器底部的回流管;所述回流管连接环流絮凝箱,所述浓缩液通过回流管进入环流絮凝箱中。S2. The flocculated liquid enters the self-cleaning filter after being pressurized by the booster pump, and then enters the ultrafiltration membrane purifier from the top of the ultrafiltration membrane purifier, and the purified water obtained after filtration passes through the water purification pipe in the middle of the ultrafiltration membrane purifier Outflow; the concentrated solution formed before the ultrafiltration membrane enters the return pipe at the bottom of the ultrafiltration membrane purifier; the return pipe is connected to the circulation flocculation box, and the concentrated solution enters the circulation flocculation box through the return pipe.

进一步,所述自清洗过滤器底部设有清洗液排放管,所述清洗液排放管连接环流絮凝箱,自清洗过滤器产生的含有较大絮凝颗粒的浊液通过清洗液排放管进入环流絮凝箱或直接外排。Further, a cleaning liquid discharge pipe is provided at the bottom of the self-cleaning filter, and the cleaning liquid discharge pipe is connected to a circulation flocculation box, and the turbid liquid containing larger flocculation particles generated by the self-cleaning filter enters the circulation flocculation box through the cleaning liquid discharge pipe or directly out.

所述絮凝液在经过增压泵提压时添加消毒剂。A disinfectant is added to the flocculant when it is pressurized by a booster pump.

所述超滤膜为陶瓷超滤膜或碳化硅超滤膜或PTFE超滤膜或PVDF超滤膜。The ultrafiltration membrane is a ceramic ultrafiltration membrane, a silicon carbide ultrafiltration membrane, a PTFE ultrafiltration membrane or a PVDF ultrafiltration membrane.

本发明在超滤膜净化器前端设置自清洗过滤器,截留颗粒较大的絮凝体浊液回流至循环絮凝箱,强化了絮凝效果,且利用了浊液中的消毒剂做预氧化处理。In the present invention, a self-cleaning filter is arranged at the front end of the ultrafiltration membrane purifier, and the turbid liquid of flocs with larger particles is retained to flow back to the circulating flocculation box, thereby strengthening the flocculation effect, and utilizing the disinfectant in the turbid liquid for pre-oxidation treatment.

本发明采用增压泵在为絮凝液增压的同时添加消毒剂,确保水体消毒的同时,减缓了膜表面污染,延长使用寿命。The invention adopts a booster pump to add disinfectant while boosting the flocculation liquid, so as to ensure the disinfection of the water body, slow down the pollution of the membrane surface and prolong the service life.

如图1、图2、图3所示,本发明首先将自然流水、絮凝剂加入到环流絮凝箱1,在提升搅拌器4的作用下形成混合液,且该混合液在环流絮凝箱内形成环流。自清洗过滤器6产生的含有较大絮凝颗粒的浊液回流到环流絮凝箱1内与自然流水、絮凝剂混合不断循环搅拌,形成粗大颗粒体从底部排泥管7排出,部分较轻的漂浮物从上部排渣管8排出。絮凝液在增压泵5抽吸下从中部出水管9抽送经自清洗过滤器6至超滤膜净化器10。As shown in Fig. 1, Fig. 2 and Fig. 3, the present invention firstly adds natural flowing water and flocculant into the circulation flocculation tank 1, and forms a mixed liquid under the action of the lifting agitator 4, and the mixed liquid is formed in the circulation flocculation tank circulation. The turbid liquid containing larger flocculation particles produced by the self-cleaning filter 6 flows back into the circulating flocculation tank 1 to mix with natural flowing water and flocculant and continuously circulates and stirs to form coarse particles and discharge them from the mud discharge pipe 7 at the bottom, and some of the lighter ones float The waste is discharged from the upper slag discharge pipe 8. The flocculation liquid is pumped from the central outlet pipe 9 to the ultrafiltration membrane purifier 10 through the self-cleaning filter 6 under the suction of the booster pump 5 .

细微颗粒的絮凝体与消毒剂混合后从超滤膜净化器10顶部进入超滤膜净化通道11。经过滤后的净水从净水管12流出,被超滤膜截留的浓缩液沿膜表面冲刷,汇聚于回流管13,回流至环流絮凝箱1。After the flocs of fine particles are mixed with the disinfectant, they enter the ultrafiltration membrane purification channel 11 from the top of the ultrafiltration membrane purifier 10 . The filtered clean water flows out from the clean water pipe 12, and the concentrated liquid intercepted by the ultrafiltration membrane washes along the surface of the membrane, gathers in the return pipe 13, and returns to the circulation flocculation tank 1.

本发明在膜净化器前端加入消毒液,利用消毒液的强氧化能力和回流形成的错流对膜表面的冲刷作用,减缓了超滤膜表面的结垢和污堵问题。The invention adds disinfectant to the front end of the membrane purifier, utilizes the strong oxidizing ability of the disinfectant and the scouring effect of the cross-flow formed by backflow on the surface of the membrane, and slows down the problem of fouling and fouling on the surface of the ultrafiltration membrane.

将超滤膜截留产生的浓缩液回流至环流絮凝箱1,可以充分利用细小的、未被完全反应和吸附的絮凝剂,提供絮凝核,促使快速絮凝。将自清洗过滤器6产生的大颗粒絮凝体回流至环流絮凝箱可以促使矾花下沉至排泥管7排放,强化了膜前端的预处理效果,提升了膜净化效率。Returning the concentrated solution produced by the interception of the ultrafiltration membrane to the circulation flocculation box 1 can make full use of the fine, incompletely reacted and adsorbed flocculants to provide flocculation nuclei and promote rapid flocculation. Returning the large-particle flocs produced by the self-cleaning filter 6 to the circulation flocculation box can promote the alum flowers to sink to the sludge discharge pipe 7 for discharge, which strengthens the pretreatment effect at the front end of the membrane and improves the membrane purification efficiency.

本发明采用简单易操作的自清洗过滤器替代了复杂的传统砂滤预处理,简化了系统控制。The invention adopts a simple and easy-to-operate self-cleaning filter to replace the complex traditional sand filter pretreatment and simplifies system control.

综上所述,本发明具有本发明具有工艺流程短、抗污堵能力强、运行简单可靠等有等有益效果。In summary, the present invention has the beneficial effects of short process flow, strong anti-fouling ability, simple and reliable operation, and the like.

附图说明Description of drawings

图1为本发明工艺流程示意图。Fig. 1 is a schematic diagram of the process flow of the present invention.

图2为环流絮凝箱结构示意图。Figure 2 is a schematic diagram of the structure of the circulating flocculation box.

图3为超滤膜净化器结构示意图。Fig. 3 is a schematic structural diagram of an ultrafiltration membrane purifier.

实施方式Implementation

结合附图对本发明做进一步说明,下面结合实施例对本发明作进一步详述:The present invention will be further described in conjunction with accompanying drawing, and the present invention will be described in further detail below in conjunction with embodiment:

实施例1:为某农村供水系统,取水水源为河道水,原水浊度5~200NTU,日供水量100m3/d,处理按5.0m3/hr。供水水质要求达到《生活饮用水卫生标准(GB5749-2022)》标准。如图1、图2、图3所示净水步骤如下:河道水作为原水(自然流水)以5.0m3/h流量,自然流进环流絮凝箱,原水、絮凝剂、回流浓缩液(流量:1.00m3/h)进入环流絮凝罐1,在里面混合均匀。进水管2将混合液引导至导流筒3底部,在提升搅拌器4的作用下,混合液在环流絮凝箱内形成环流,原水、絮凝剂、回流浓缩液、自清洗排放液不断循环搅拌,形成的粗大颗粒体从底部排泥管7排出,部分较轻的漂浮物从上部排渣管8排出,絮凝液在增压泵5抽吸下从中部出水管9((流量:7.00m3/h))抽送,经自清洗过滤器6至超滤膜净化器10。增压泵5抽吸过程中将消毒剂混匀于絮凝液中。自清洗过滤器6连续将截留大颗粒排放回环流絮凝箱1(流量:1.00m3/h),絮凝液与消毒剂混合后从超滤膜净化器10顶部,进入超滤膜净化通道11。所述超滤膜采用陶瓷膜,净水在压力作用下透过陶瓷膜从净水管12流出(流量:5.00m3/h)。被膜截留的浓缩液沿膜表面冲刷,汇聚于回流管13,回流至环流絮凝器1(流量:1.00m3/h)。经过净化后的出水,其浊度为1NTU以下,达到《生活饮用水卫生标准(GB5749-2022)》的要求。Example 1: It is a rural water supply system, the water source is river water, the raw water turbidity is 5~200NTU, the daily water supply is 100m3/d, and the treatment is 5.0m3/hr. The quality of water supply shall meet the standard of "Drinking Water Hygienic Standard (GB5749-2022)". As shown in Figure 1, Figure 2, and Figure 3, the water purification steps are as follows: the river water is used as raw water (natural flow water) at a flow rate of 5.0m3/h, and naturally flows into the circulation flocculation tank, and the raw water, flocculant, and return concentrate (flow rate: 1.00 m3/h) into the circulation flocculation tank 1 and mix evenly inside. The water inlet pipe 2 guides the mixed liquid to the bottom of the diversion tube 3, and under the action of the lifting agitator 4, the mixed liquid forms a circulation in the circulation flocculation tank, and the raw water, flocculant, reflux concentrate, and self-cleaning discharge liquid are continuously circulated and stirred. The formed coarse particles are discharged from the bottom mud discharge pipe 7, and part of the lighter floating matter is discharged from the upper slag discharge pipe 8, and the floc is sucked by the booster pump 5 from the middle outlet pipe 9 (flow: 7.00m3/h )) pumping, through the self-cleaning filter 6 to the ultrafiltration membrane purifier 10. During the suction process of the booster pump 5, the disinfectant is mixed evenly in the flocculation liquid. The self-cleaning filter 6 continuously discharges the intercepted large particles back to the circulation flocculation tank 1 (flow rate: 1.00m3/h). After the flocculation liquid is mixed with the disinfectant, it enters the ultrafiltration membrane purification channel 11 from the top of the ultrafiltration membrane purifier 10 . The ultrafiltration membrane adopts a ceramic membrane, and the purified water flows out from the water purification pipe 12 through the ceramic membrane under pressure (flow rate: 5.00m3/h). The concentrated liquid retained by the membrane washes along the membrane surface, gathers in the return pipe 13, and returns to the loop flocculator 1 (flow rate: 1.00m3/h). After purification, the turbidity of the effluent water is below 1NTU, meeting the requirements of the Sanitary Standard for Drinking Water (GB5749-2022).

Claims (4)

1.一种自然流水的强絮凝超滤膜净水处理方法,其特征在于采用以下步骤:1. a strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water, characterized in that the following steps are adopted: S1、将自然流水、絮凝剂加入环流絮凝箱,所述环流絮凝箱底部设有排泥管,中部设有一个导流筒,所述导流筒中设有一个提升搅拌器;环流絮凝箱中部设置絮凝液出液管;自然流水与絮凝剂在环流絮凝箱内充分混合后形成絮凝液;S1. Add natural flowing water and flocculant into the circulation flocculation box, the bottom of the circulation flocculation box is provided with a mud discharge pipe, and a guide tube is provided in the middle, and a lifting agitator is provided in the guide tube; the middle part of the circulation flocculation box is set Flocculant liquid outlet pipe; natural flowing water and flocculant are fully mixed in the circulation flocculation box to form flocculant liquid; S2、所述絮凝液经过增压泵提压后进入自清洗过滤器,然后从超滤膜净化器顶部进入超滤膜净化器,过滤后所得净水从超滤膜净化器中部的净水管流出;超滤膜前形成的浓缩液进入超滤膜净化器底部的回流管;所述回流管连接环流絮凝箱,所述浓缩液通过回流管进入环流絮凝箱中。S2. The flocculated liquid enters the self-cleaning filter after being pressurized by the booster pump, and then enters the ultrafiltration membrane purifier from the top of the ultrafiltration membrane purifier, and the purified water obtained after filtration passes through the water purification pipe in the middle of the ultrafiltration membrane purifier Outflow; the concentrated solution formed before the ultrafiltration membrane enters the return pipe at the bottom of the ultrafiltration membrane purifier; the return pipe is connected to the circulation flocculation box, and the concentrated solution enters the circulation flocculation box through the return pipe. 2.根据权利要求1所述自然流水的强絮凝超滤膜净水处理方法,其特征在于:所述自清洗过滤器底部设有清洗液排放管,所述清洗液排放管连接环流絮凝箱,自清洗过滤器产生的含有较大絮凝颗粒的浊液通过清洗液排放管进入环流絮凝箱或直接外排。2. The strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water according to claim 1, characterized in that: the bottom of the self-cleaning filter is provided with a cleaning liquid discharge pipe, and the cleaning liquid discharge pipe is connected to a circulation flocculation box, The turbid liquid containing larger flocculated particles generated by the self-cleaning filter enters the circulation flocculation tank through the cleaning liquid discharge pipe or is directly discharged outside. 3.根据权利要求1所述自然流水的强絮凝超滤膜净水处理方法,其特征在于:所述絮凝液在经过增压泵提压时添加消毒剂。3. The natural flowing water strong flocculation ultrafiltration membrane water purification treatment method according to claim 1, characterized in that a disinfectant is added to the flocculation liquid when it is boosted by a booster pump. 4.根据权利要求1所述自然流水的强絮凝超滤膜净水处理方法,其特征在于:所述超滤膜为陶瓷超滤膜或碳化硅超滤膜或PTFE超滤膜或PVDF超滤膜。4. according to claim 1, the strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water is characterized in that: the ultrafiltration membrane is a ceramic ultrafiltration membrane or a silicon carbide ultrafiltration membrane or a PTFE ultrafiltration membrane or a PVDF ultrafiltration membrane membrane.
CN202310102315.6A 2023-02-13 2023-02-13 A kind of strong flocculation ultrafiltration membrane water purification treatment method of natural flowing water Pending CN115947501A (en)

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