CN115625816A - A kind of dimensionally stable reinforced flame-retardant PET and its preparation method - Google Patents
A kind of dimensionally stable reinforced flame-retardant PET and its preparation method Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/06—Conditioning or physical treatment of the material to be shaped by drying
- B29B13/065—Conditioning or physical treatment of the material to be shaped by drying of powder or pellets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/10—Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0026—Flame proofing or flame retarding agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
- B29K2105/165—Hollow fillers, e.g. microballoons or expanded particles
- B29K2105/167—Nanotubes
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Abstract
Description
技术领域technical field
本发明涉及一种增强阻燃PET,特别是涉及一种尺寸稳定的增强阻燃PET,本发明还涉及一种增强阻燃PET的制备方法,特别涉及一种尺寸稳定的增强阻燃PET的制备方法,属于增强阻燃PET技术领域。The present invention relates to a reinforced flame-retardant PET, in particular to a dimensionally stable reinforced flame-retardant PET, the invention also relates to a method for preparing a reinforced flame-retardant PET, in particular to a dimensionally stable reinforced flame-retardant PET preparation The method belongs to the technical field of enhanced flame-retardant PET.
背景技术Background technique
PET塑料,简称PET或PETP,中文意思是:聚对苯二甲酸类塑料,主要包括聚对苯二甲酸乙二酯PET和聚对苯二甲酸丁二酯PBT,聚对苯二甲酸乙二醇酯又俗称涤纶树脂,它是对苯二甲酸与乙二醇的缩聚物,与PBT一起统称为热塑性聚酯,或饱和聚酯。PET plastic, referred to as PET or PETP, Chinese means: polyethylene terephthalate plastics, mainly including polyethylene terephthalate PET and polybutylene terephthalate PBT, polyethylene terephthalate Ester is also commonly known as polyester resin, which is a condensation polymer of terephthalic acid and ethylene glycol, and together with PBT is collectively referred to as thermoplastic polyester, or saturated polyester.
现有技术中在进行PET塑料加工生产的过程中需要对其进行冷水降温处理,然后在进行烘干去除表面水分,最后再进行烘干处理,而在进行冷水降温处理的时候并不能高效全部的进行降温处理,另外还需要单独的水泵来进行单独的供水处理,其次切割需要单独的切割设备进行切割,而且在进行烘干的时候烘干还需要单独的烘干振动结构并不便捷,为此设计一种尺寸稳定的增强阻燃PET及其制备方法来解决上述问题。In the prior art, during the processing and production of PET plastics, it is necessary to perform cold water cooling treatment, then dry to remove surface moisture, and finally perform drying treatment, but the cold water cooling treatment cannot efficiently and completely For cooling treatment, a separate water pump is required for separate water supply treatment, and secondly, cutting requires a separate cutting equipment for cutting, and it is not convenient to dry with a separate drying vibration structure during drying. A dimensionally stable reinforced flame-retardant PET and its preparation method are designed to solve the above problems.
发明内容Contents of the invention
本发明的主要目的是为了提供一种尺寸稳定的增强阻燃PET及其制备方法,通过称取PET90-110重量份、PC树脂15-20重量份、玻璃纤维0-10重量份、阻燃剂10-15重量份、改性碳纳米管0.3-1.0重量份、改性剂5-10重量份、成核剂0.3-1重量份搅拌混合通过双螺旋杆挤出机挤出,挤出后进入至内水冷筒内,然后启动双头电机调节第一输出转杆带动调节齿轮旋转,通过调节齿轮调节外齿轮环带动内水冷筒旋转,通过双头电机的运动进一步带动第一锥齿轮运动,通过第一锥齿轮调节第二锥齿轮运动,通过第二锥齿轮调节调节盘运动,通过调节盘调节铰接杆运动,通过铰接杆调节活塞在活塞筒内上下运动,通过活塞的运动打开第二单向阀将水池中的水通过进液口进入至活塞筒内,通过压动活塞打开第一限位弹簧将冷水导入至导入水管内,冷水通过导入水管进入至密封外环内,通过密封外环进入至内水冷筒内,然后通过内水冷筒配合喷头喷出进行对挤出的拉丝后的原料降温处理,通过第三锥齿轮调节第一垂杆带动切割刀运动,通过切割刀调节旋转进行对通过内水冷筒的原料条进行切割成粒,切割成粒后的原料落入至振动过滤板上,带动振动过滤板的振动,同步启动烘干风机和侧加热板进行加热烘干处理制备成增强阻燃PET。The main purpose of the present invention is to provide a dimensionally stable reinforced flame-retardant PET and its preparation method, by weighing 90-110 parts by weight of PET, 15-20 parts by weight of PC resin, 0-10 parts by weight of glass fiber, flame retardant 10-15 parts by weight, 0.3-1.0 parts by weight of modified carbon nanotubes, 5-10 parts by weight of modifier, 0.3-1 parts by weight of nucleating agent, stirring and mixing, extruding through a twin-screw extruder, and entering into the inner water-cooling cylinder, then start the double-headed motor to adjust the first output rotating rod to drive the adjustment gear to rotate, adjust the outer gear ring to drive the inner water-cooling cylinder to rotate through the adjustment gear, and further drive the first bevel gear to move through the movement of the double-headed motor. The movement of the second bevel gear is adjusted by the first bevel gear, the movement of the adjustment disc is adjusted by the second bevel gear, the movement of the hinge rod is adjusted by the adjustment disc, the movement of the piston up and down in the piston barrel is adjusted by the hinge rod, and the second one-way is opened by the movement of the piston. The valve enters the water in the pool into the piston barrel through the liquid inlet, and the first limit spring is opened by pressing the piston to introduce the cold water into the water pipe. The cold water enters into the sealing outer ring through the water pipe and enters through the sealing outer into the inner water-cooling cylinder, and then through the inner water-cooling cylinder and the spray nozzle to cool down the extruded and drawn raw materials, adjust the first vertical rod through the third bevel gear to drive the movement of the cutting knife, and adjust the rotation of the cutting knife to pass through The raw material strips of the inner water cooling cylinder are cut into granules, and the cut granulated raw materials fall onto the vibrating filter plate, which drives the vibration of the vibrating filter plate, and simultaneously starts the drying fan and the side heating plate for heating and drying to prepare a reinforced resistance Burn PET.
本发明的目的可以通过采用如下技术方案达到:The purpose of the present invention can be achieved by adopting the following technical solutions:
一种尺寸稳定的增强阻燃PET,包括以下重量份原料:A dimensionally stable reinforced flame-retardant PET, comprising the following raw materials in parts by weight:
PET90-110重量份、PC树脂15-20重量份、玻璃纤维0-10重量份、阻燃剂10-15重量份、改性碳纳米管0.3-1.0重量份、改性剂5-10重量份、成核剂0.3-1重量份。PET90-110 parts by weight, PC resin 15-20 parts by weight, glass fiber 0-10 parts by weight, flame retardant 10-15 parts by weight, modified carbon nanotubes 0.3-1.0 parts by weight, modifier 5-10 parts by weight , 0.3-1 parts by weight of nucleating agent.
优选的,该制备方法包括如下使用设备,该使用设备包括外套筒,所述外套筒的内顶部与内底部处通过连接轴承安装有旋转喷洒筒组件,所述外套筒的一侧顶部处通过电机架安装有双头电机组件,该双头电机组件的一输出端与所述旋转喷洒筒组件通过齿轮盘组件相互配合,双头电机组件的另一输出端通过锥齿轮组件驱动有调节盘组件,所述调节盘组件下方设有可被所述调节盘组件驱动的活塞筒组件,该活塞筒组件的输入端通过导入管组件与旋转喷洒筒组件连通,所述锥齿轮组件还驱动有切割刀组件,所述外套筒的侧底部处安装有L型侧架,且所述L型侧架的底部安装有烘干仓,所述烘干仓的内底部处设有振动过滤网组件,所述烘干仓的内中部处安装有烘干风机。Preferably, the preparation method includes the use of equipment as follows, the use equipment includes an outer sleeve, the inner top and inner bottom of the outer sleeve are installed with a rotating spraying cylinder assembly through a connecting bearing, and the top of one side of the outer sleeve is A double-headed motor assembly is installed through the motor frame, and one output end of the double-headed motor assembly cooperates with the rotating spray cylinder assembly through a gear plate assembly, and the other output end of the double-headed motor assembly is driven and adjusted by a bevel gear assembly. Disc assembly, below the adjustment disc assembly, there is a piston cylinder assembly that can be driven by the adjustment disk assembly, the input end of the piston cylinder assembly communicates with the rotating spray cylinder assembly through the introduction pipe assembly, and the bevel gear assembly also drives As for the cutter assembly, an L-shaped side frame is installed at the side bottom of the outer sleeve, and a drying bin is installed at the bottom of the L-shaped side frame, and a vibrating filter assembly is arranged at the inner bottom of the drying bin , a drying fan is installed at the inner middle of the drying bin.
优选的,旋转喷洒筒组件包括内水冷筒和喷头,所述外套筒的内壁上方和下方通过连接轴承安装有内水冷筒,且所述内水冷筒的内部等间距连通有喷头。Preferably, the rotating spray cylinder assembly includes an inner water cooling cylinder and a spray head, an internal water cooling cylinder is installed above and below the inner wall of the outer sleeve through connecting bearings, and the inside of the internal water cooling cylinder is connected with spray heads at equal intervals.
优选的,双头电机组件包括双头电机、第一输出转杆和下转轴,所述电机架安装有双头电机,所述双头电机的顶输出端安装有第一输出转杆,所述双头电机的底输出端安装有下转轴,所述第一输出转杆的顶部处安装有齿轮盘组件。Preferably, the double-head motor assembly includes a double-head motor, a first output shaft and a lower shaft, the motor frame is equipped with a double-head motor, and the top output end of the double-head motor is equipped with a first output shaft. A lower rotating shaft is installed at the bottom output end of the double-headed motor, and a gear plate assembly is installed at the top of the first output rotating rod.
优选的,齿轮盘组件包括调节齿轮和外齿轮环,所述内水冷筒的外侧顶部处安装有外齿轮环,所述第一输出转杆的顶部处安装有调节齿轮,且所述调节齿轮部分位于所述外套筒的内侧且与所述外齿轮环相互啮合。Preferably, the gear plate assembly includes an adjustment gear and an external gear ring, the outer top of the inner water cooling cylinder is installed with the outer gear ring, the top of the first output shaft is installed with an adjustment gear, and the adjustment gear part It is located inside the outer sleeve and meshes with the outer gear ring.
优选的,锥齿轮组件包括第一锥齿轮、第二锥齿轮和第三锥齿轮,所述下转轴的底部安装有第一锥齿轮,所述第一锥齿轮的外侧啮合有第二锥齿轮,且所述第二锥齿轮的底部啮合有第三锥齿轮,所述第三锥齿轮的底中部处安装有切割刀组件。Preferably, the bevel gear assembly includes a first bevel gear, a second bevel gear and a third bevel gear, the bottom of the lower shaft is equipped with a first bevel gear, and the outside of the first bevel gear is meshed with a second bevel gear, And the bottom of the second bevel gear is meshed with a third bevel gear, and a cutting knife assembly is installed at the middle of the bottom of the third bevel gear.
优选的,所述调节盘组件包括调节盘、铰接杆和连接横杆,所述第二锥齿轮的一侧中部处安装有连接横杆,该连接横杆的另一端安装有调节盘,所述调节盘的边部处铰接有铰接杆,所述铰接杆的底部铰接有活塞筒组件。Preferably, the adjustment disc assembly includes an adjustment disc, a hinged rod and a connecting cross bar, a connecting cross bar is installed at the middle of one side of the second bevel gear, and an adjusting disc is installed at the other end of the connecting cross bar. A hinged rod is hinged at the edge of the adjusting disc, and a piston barrel assembly is hinged at the bottom of the hinged rod.
优选的,活塞筒组件包括活塞、活塞筒、第二限位弹簧、第一单向阀、第一限位弹簧和第二单向阀,所述活塞筒的底部两侧分别开设有进液口和出液口,其中进液口内置有第二单向阀,且第二单向阀与活塞筒之间设有第二限位弹簧,其中出液口内置有第一单向阀,且第一单向阀与活塞筒之间设有第一限位弹簧,所述活塞筒的内部设有可在所述活塞筒内滑动的活塞,所述铰接杆的底部与所述活塞的顶中部处铰接,所述出液口通过导入管组件与所述内水冷筒连通。Preferably, the piston barrel assembly includes a piston, a piston barrel, a second limit spring, a first one-way valve, a first limit spring and a second one-way valve, and liquid inlets are respectively opened on both sides of the bottom of the piston barrel and a liquid outlet, wherein a second one-way valve is built in the liquid inlet, and a second limit spring is provided between the second one-way valve and the piston barrel, and a first one-way valve is built in the liquid outlet, and the second A first limit spring is arranged between a one-way valve and the piston barrel, and a piston that can slide in the piston barrel is arranged inside the piston barrel, and the bottom of the hinge rod and the top middle of the piston The liquid outlet is hinged, and the liquid outlet communicates with the inner water cooling cylinder through the inlet pipe assembly.
优选的,所述导入管组件包括导入水管和密封外环,所述出液口的底部连通有导入水管,所述导入水管的另一端贯穿外套筒连通有密封外环,且所述密封外环插入至所述内水冷筒的内部并与所述内水冷筒连通;Preferably, the inlet pipe assembly includes an inlet water pipe and a sealed outer ring, the bottom of the liquid outlet is connected to an inlet water pipe, the other end of the inlet water pipe passes through the outer sleeve and communicates with a sealed outer ring, and the sealed outer ring The ring is inserted into the interior of the inner water-cooling cylinder and communicates with the inner water-cooling cylinder;
切割刀组件包括第一垂杆和切割刀,所述第三锥齿轮的底中部处安装有第一垂杆,且所述第一垂杆的底部等间距设有三组切割刀;The cutting knife assembly includes a first vertical rod and a cutting knife, a first vertical rod is installed at the bottom middle of the third bevel gear, and three sets of cutting knives are arranged at equal intervals at the bottom of the first vertical rod;
所述外套筒的侧中部处安装有L型支撑架,且L型支撑架通过轴承安装有第一垂杆和连接横杆;An L-shaped support frame is installed at the side middle part of the outer sleeve, and the L-shaped support frame is equipped with a first vertical bar and a connecting cross bar through a bearing;
振动过滤网组件包括振动过滤板、振动弹簧和内支撑环,所述烘干仓的内底部处安装有内支撑环,所述内支撑环的顶部处安装有振动弹簧,所述振动弹簧的顶部处安装有振动过滤板;The vibrating filter screen assembly includes a vibrating filter plate, a vibrating spring and an inner support ring, an inner support ring is installed at the inner bottom of the drying bin, a vibrating spring is installed at the top of the inner support ring, and the top of the vibrating spring A vibrating filter plate is installed at the place;
所述烘干仓的内壁安装有侧加热板,且所述烘干仓的外侧中部处安装有电加热器,该电加热器电性连接侧加热板。A side heating plate is installed on the inner wall of the drying bin, and an electric heater is installed at the outer middle of the drying bin, and the electric heater is electrically connected to the side heating plate.
一种尺寸稳定的增强阻燃PET制备方法,包括如下步骤:A method for preparing a dimensionally stable reinforced flame-retardant PET, comprising the steps of:
步骤一:通过称取PET90-110重量份、PC树脂15-20重量份、玻璃纤维0-10重量份、阻燃剂10-15重量份、改性碳纳米管0.3-1.0重量份、改性剂5-10重量份、成核剂0.3-1重量份搅拌混合通过双螺旋杆挤出机挤出;Step 1: By weighing 90-110 parts by weight of PET, 15-20 parts by weight of PC resin, 0-10 parts by weight of glass fiber, 10-15 parts by weight of flame retardant, 0.3-1.0 parts by weight of modified carbon nanotubes, modified 5-10 parts by weight of agent and 0.3-1 part by weight of nucleating agent are stirred and mixed and extruded through a twin-screw extruder;
步骤二:挤出后进入至内水冷筒内,然后启动双头电机调节第一输出转杆带动调节齿轮旋转,通过调节齿轮调节外齿轮环带动内水冷筒旋转;Step 2: After extruding, enter the inner water cooling cylinder, then start the double-headed motor to adjust the first output shaft to drive the adjustment gear to rotate, and adjust the outer gear ring through the adjustment gear to drive the inner water cooling cylinder to rotate;
步骤三:通过双头电机的运动进一步带动第一锥齿轮运动,通过第一锥齿轮调节第二锥齿轮运动,通过第二锥齿轮调节调节盘运动;Step 3: The movement of the double-head motor further drives the movement of the first bevel gear, the movement of the second bevel gear is adjusted through the first bevel gear, and the movement of the adjustment disc is adjusted through the second bevel gear;
步骤四:通过调节盘调节铰接杆运动,通过铰接杆调节活塞在活塞筒内上下运动;Step 4: Adjust the movement of the articulated rod through the adjusting disc, and adjust the movement of the piston up and down in the piston cylinder through the articulated rod;
步骤五:通过活塞的运动打开第二单向阀将水池中的水通过进液口进入至活塞筒内,通过压动活塞打开第一限位弹簧将冷水导入至导入水管内;Step 5: Open the second one-way valve through the movement of the piston to allow the water in the pool to enter the piston cylinder through the liquid inlet, and open the first limit spring by pressing the piston to introduce cold water into the water inlet pipe;
步骤六:冷水通过导入水管进入至密封外环内,通过密封外环进入至内水冷筒内,然后通过内水冷筒配合喷头喷出进行对挤出的拉丝后的原料降温处理;Step 6: Cold water enters the sealed outer ring through the water pipe, enters the inner water-cooled cylinder through the sealed outer ring, and then sprays out through the inner water-cooled cylinder with the nozzle to cool down the extruded and drawn raw materials;
步骤七:通过第三锥齿轮调节第一垂杆带动切割刀运动,通过切割刀调节旋转进行对通过内水冷筒的原料条进行切割成粒;Step 7: Adjust the first vertical rod through the third bevel gear to drive the movement of the cutting knife, and adjust the rotation of the cutting knife to cut the raw material strips passing through the inner water cooling cylinder into granules;
步骤八:切割成粒后的原料落入至振动过滤板上,带动振动过滤板的振动,同步启动烘干风机和侧加热板进行加热烘干处理制备成增强阻燃PET。Step 8: The cut and granulated raw materials fall onto the vibrating filter plate, which drives the vibration of the vibrating filter plate, and synchronously starts the drying fan and side heating plate for heating and drying treatment to prepare reinforced flame-retardant PET.
本发明的有益技术效果:Beneficial technical effect of the present invention:
本发明提供的一种尺寸稳定的增强阻燃PET及其制备方法,通过称取PET90-110重量份、PC树脂15-20重量份、玻璃纤维0-10重量份、阻燃剂10-15重量份、改性碳纳米管0.3-1.0重量份、改性剂5-10重量份、成核剂0.3-1重量份搅拌混合通过双螺旋杆挤出机挤出,挤出后进入至内水冷筒内,然后启动双头电机调节第一输出转杆带动调节齿轮旋转,通过调节齿轮调节外齿轮环带动内水冷筒旋转,通过双头电机的运动进一步带动第一锥齿轮运动,通过第一锥齿轮调节第二锥齿轮运动,通过第二锥齿轮调节调节盘运动,通过调节盘调节铰接杆运动,通过铰接杆调节活塞在活塞筒内上下运动,通过活塞的运动打开第二单向阀将水池中的水通过进液口进入至活塞筒内,通过压动活塞打开第一限位弹簧将冷水导入至导入水管内,冷水通过导入水管进入至密封外环内,通过密封外环进入至内水冷筒内,然后通过内水冷筒配合喷头喷出进行对挤出的拉丝后的原料降温处理,通过第三锥齿轮调节第一垂杆带动切割刀运动,通过切割刀调节旋转进行对通过内水冷筒的原料条进行切割成粒,切割成粒后的原料落入至振动过滤板上,带动振动过滤板的振动,同步启动烘干风机和侧加热板进行加热烘干处理制备成增强阻燃PET。The invention provides a dimensionally stable reinforced flame-retardant PET and its preparation method, by weighing 90-110 parts by weight of PET, 15-20 parts by weight of PC resin, 0-10 parts by weight of glass fiber, and 10-15 parts by weight of flame retardant 0.3-1.0 parts by weight of modified carbon nanotubes, 5-10 parts by weight of modifiers, and 0.3-1 parts by weight of nucleating agents are stirred and mixed and extruded through a twin-screw extruder, and then enter into the inner water cooling cylinder Then start the double-head motor to adjust the first output shaft to drive the adjustment gear to rotate, adjust the outer gear ring through the adjustment gear to drive the inner water-cooled cylinder to rotate, the movement of the double-head motor further drives the first bevel gear to move, and the first bevel gear Adjust the movement of the second bevel gear, adjust the movement of the adjustment disc through the second bevel gear, adjust the movement of the hinge rod through the adjustment disc, adjust the movement of the piston up and down in the piston cylinder through the hinge rod, and open the second one-way valve through the movement of the piston. The water enters into the piston barrel through the liquid inlet, and the first limit spring is opened by pressing the piston to introduce cold water into the water pipe. The cold water enters the sealed outer ring through the water pipe, and enters the inner water cooling cylinder through the sealed outer ring. Then, the extruded wire-drawn raw material is cooled through the inner water cooling cylinder and the spray nozzle, and the first vertical rod is adjusted through the third bevel gear to drive the cutting knife to move, and the cutting knife is adjusted to rotate through the inner water cooling cylinder. The raw material strips are cut into granules, and the granulated raw materials fall onto the vibrating filter plate, which drives the vibration of the vibrating filter plate, and simultaneously starts the drying fan and the side heating plate for heating and drying to prepare enhanced flame-retardant PET.
附图说明Description of drawings
图1为按照本发明的一种尺寸稳定的增强阻燃PET及其制备方法的一优选实施例的装置整体结构示意图;Fig. 1 is according to a kind of dimensionally stable reinforced flame-retardant PET of the present invention and the device overall structure schematic diagram of a preferred embodiment of preparation method thereof;
图2为按照本发明的一种尺寸稳定的增强阻燃PET及其制备方法的一优选实施例的振动烘干组件结构示意图;Fig. 2 is a schematic structural view of a vibration drying assembly according to a preferred embodiment of a dimensionally stable reinforced flame-retardant PET and a preparation method thereof of the present invention;
图3为按照本发明的一种尺寸稳定的增强阻燃PET及其制备方法的一优选实施例的切割组件、水冷组件、抽水组件和锥齿轮联动组件组合结构示意图;Fig. 3 is a schematic diagram of the combined structure of a cutting assembly, a water cooling assembly, a pumping assembly and a bevel gear linkage assembly according to a preferred embodiment of a dimensionally stable reinforced flame-retardant PET and a preparation method thereof of the present invention;
图4为按照本发明的一种尺寸稳定的增强阻燃PET及其制备方法的一优选实施例的a处结构放大图;Fig. 4 is according to a kind of size-stable reinforced flame-retardant PET of the present invention and a preferred embodiment of preparation method thereof the enlarged view of the structure at place a;
图5为按照本发明的一种尺寸稳定的增强阻燃PET及其制备方法的一优选实施例的b处结构放大图;Figure 5 is an enlarged view of the structure at b of a preferred embodiment of a dimensionally stable reinforced flame-retardant PET and a preparation method thereof according to the present invention;
图6为按照本发明的一种尺寸稳定的增强阻燃PET及其制备方法的一优选实施例的c处结构放大图。Fig. 6 is an enlarged view of the structure at point c of a preferred embodiment of a dimensionally stable reinforced flame-retardant PET and its preparation method according to the present invention.
图中:1-外套筒,2-L型侧架,3-烘干仓,4-侧加热板,5-振动过滤板,6-振动弹簧,7-烘干风机,8-第一垂杆,9-切割刀,10-调节齿轮,11-内水冷筒,12-喷头,13-调节盘,14-活塞,15-活塞筒,16-L型支撑架,17-密封外环,18-内支撑环,19-第一锥齿轮,20-第二锥齿轮,21-第三锥齿轮,22-铰接杆,23-第一输出转杆,24-双头电机,25-电机架,26-连接轴承,27-第一单向阀,28-第二单向阀,29-第二限位弹簧,30-第一限位弹簧,31-导入水管,32-外齿轮环。In the figure: 1-outer sleeve, 2-L-shaped side frame, 3-drying chamber, 4-side heating plate, 5-vibrating filter plate, 6-vibrating spring, 7-drying fan, 8-first vertical Rod, 9-cutting knife, 10-adjusting gear, 11-inner water cooling cylinder, 12-nozzle, 13-adjusting disc, 14-piston, 15-piston barrel, 16-L-shaped support frame, 17-seal outer ring, 18 -inner support ring, 19-first bevel gear, 20-second bevel gear, 21-third bevel gear, 22-hinged rod, 23-first output rotating rod, 24-double-head motor, 25-motor frame, 26-connecting bearing, 27-the first one-way valve, 28-the second one-way valve, 29-the second limit spring, 30-the first limit spring, 31-import water pipe, 32-external gear ring.
具体实施方式Detailed ways
为使本领域技术人员更加清楚和明确本发明的技术方案,下面结合实施例及附图对本发明作进一步详细的描述,但本发明的实施方式不限于此。In order to make the technical solutions of the present invention clearer and clearer to those skilled in the art, the present invention will be further described in detail below in conjunction with the examples and accompanying drawings, but the embodiments of the present invention are not limited thereto.
如图1-图6所示,本实施例提供的一种尺寸稳定的增强阻燃PET,包括以下重量份原料:As shown in Figures 1-6, a dimensionally stable reinforced flame-retardant PET provided in this embodiment includes the following raw materials in parts by weight:
PET90-110重量份、PC树脂15-20重量份、玻璃纤维0-10重量份、阻燃剂10-15重量份、改性碳纳米管0.3-1.0重量份、改性剂5-10重量份、成核剂0.3-1重量份。PET90-110 parts by weight, PC resin 15-20 parts by weight, glass fiber 0-10 parts by weight, flame retardant 10-15 parts by weight, modified carbon nanotubes 0.3-1.0 parts by weight, modifier 5-10 parts by weight , 0.3-1 parts by weight of nucleating agent.
在本实施例中,该制备方法包括如下使用设备,该使用设备包括外套筒1,外套筒1的内顶部与内底部处通过连接轴承26安装有旋转喷洒筒组件,外套筒1的一侧顶部处通过电机架25安装有双头电机组件,该双头电机组件的一输出端与旋转喷洒筒组件通过齿轮盘组件相互配合,双头电机组件的另一输出端通过锥齿轮组件驱动有调节盘组件,调节盘组件下方设有可被调节盘组件驱动的活塞筒组件,该活塞筒组件的输入端通过导入管组件与旋转喷洒筒组件连通,锥齿轮组件还驱动有切割刀组件,外套筒1的侧底部处安装有L型侧架2,且L型侧架2的底部安装有烘干仓3,烘干仓3的内底部处设有振动过滤网组件,烘干仓3的内中部处安装有烘干风机7。In this embodiment, the preparation method includes the use of equipment as follows, the use equipment includes an
通过称取PET90-110重量份、PC树脂15-20重量份、玻璃纤维0-10重量份、阻燃剂10-15重量份、改性碳纳米管0.3-1.0重量份、改性剂5-10重量份、成核剂0.3-1重量份搅拌混合通过双螺旋杆挤出机挤出,挤出后进入至内水冷筒11内,然后启动双头电机24调节第一输出转杆23带动调节齿轮10旋转,通过调节齿轮10调节外齿轮环32带动内水冷筒11旋转,通过双头电机24的运动进一步带动第一锥齿轮19运动,通过第一锥齿轮19调节第二锥齿轮20运动,通过第二锥齿轮20调节调节盘13运动,通过调节盘13调节铰接杆22运动,通过铰接杆22调节活塞14在活塞筒15内上下运动,通过活塞14的运动打开第二单向阀28将水池中的水通过进液口进入至活塞筒15内,通过压动活塞14打开第一限位弹簧30将冷水导入至导入水管31内,冷水通过导入水管31进入至密封外环17内,通过密封外环17进入至内水冷筒11内,然后通过内水冷筒11配合喷头12喷出进行对挤出的拉丝后的原料降温处理,通过第三锥齿轮21调节第一垂杆8带动切割刀9运动,通过切割刀9调节旋转进行对通过内水冷筒11的原料条进行切割成粒,切割成粒后的原料落入至振动过滤板5上,带动振动过滤板5的振动,同步启动烘干风机7和侧加热板4进行加热烘干处理制备成增强阻燃PET。By weighing PET90-110 parts by weight, PC resin 15-20 parts by weight, glass fiber 0-10 parts by weight, flame retardant 10-15 parts by weight, modified carbon nanotubes 0.3-1.0 parts by weight, modifier 5- 10 parts by weight and 0.3-1 parts by weight of nucleating agent are stirred and mixed and extruded through a twin-screw extruder. The
在本实施例中,旋转喷洒筒组件包括内水冷筒11和喷头12,外套筒1的内壁上方和下方通过连接轴承26安装有内水冷筒11,且内水冷筒11的内部等间距连通有喷头12。In this embodiment, the rotating spray cylinder assembly includes an inner
在本实施例中,双头电机组件包括双头电机24、第一输出转杆23和下转轴,电机架25安装有双头电机24,双头电机24的顶输出端安装有第一输出转杆23,双头电机24的底输出端安装有下转轴,第一输出转杆23的顶部处安装有齿轮盘组件。In this embodiment, the double-head motor assembly includes a double-
在本实施例中,齿轮盘组件包括调节齿轮10和外齿轮环32,内水冷筒11的外侧顶部处安装有外齿轮环32,第一输出转杆23的顶部处安装有调节齿轮10,且调节齿轮10部分位于外套筒1的内侧且与外齿轮环32相互啮合。In this embodiment, the gear plate assembly includes an
在本实施例中,锥齿轮组件包括第一锥齿轮19、第二锥齿轮20和第三锥齿轮21,下转轴的底部安装有第一锥齿轮19,第一锥齿轮19的外侧啮合有第二锥齿轮20,且第二锥齿轮20的底部啮合有第三锥齿轮21,第三锥齿轮21的底中部处安装有切割刀组件。In this embodiment, the bevel gear assembly includes a
在本实施例中,调节盘组件包括调节盘13、铰接杆22和连接横杆,第二锥齿轮20的一侧中部处安装有连接横杆,该连接横杆的另一端安装有调节盘13,调节盘13的边部处铰接有铰接杆22,铰接杆22的底部铰接有活塞筒组件。In this embodiment, the adjusting disc assembly includes an
在本实施例中,活塞筒组件包括活塞14、活塞筒15、第二限位弹簧29、第一单向阀27、第一限位弹簧30和第二单向阀28,活塞筒15的底部两侧分别开设有进液口和出液口,其中进液口内置有第二单向阀28,且第二单向阀28与活塞筒15之间设有第二限位弹簧29,其中出液口内置有第一单向阀27,且第一单向阀27与活塞筒15之间设有第一限位弹簧30,活塞筒15的内部设有可在活塞筒15内滑动的活塞14,铰接杆22的底部与活塞14的顶中部处铰接,出液口通过导入管组件与内水冷筒11连通。In this embodiment, the piston barrel assembly includes the
在本实施例中,导入管组件包括导入水管31和密封外环17,出液口的底部连通有导入水管31,导入水管31的另一端贯穿外套筒1连通有密封外环17,且密封外环17插入至内水冷筒11的内部并与内水冷筒11连通;In this embodiment, the inlet pipe assembly includes an
切割刀组件包括第一垂杆8和切割刀9,第三锥齿轮21的底中部处安装有第一垂杆8,且第一垂杆8的底部等间距设有三组切割刀9;The cutting knife assembly comprises a first
外套筒1的侧中部处安装有L型支撑架16,且L型支撑架16通过轴承安装有第一垂杆8和连接横杆;An L-shaped
振动过滤网组件包括振动过滤板5、振动弹簧6和内支撑环18,烘干仓3的内底部处安装有内支撑环18,内支撑环18的顶部处安装有振动弹簧6,振动弹簧6的顶部处安装有振动过滤板5;The vibrating filter screen assembly comprises a vibrating
烘干仓3的内壁安装有侧加热板4,且烘干仓3的外侧中部处安装有电加热器,该电加热器电性连接侧加热板4。A
一种尺寸稳定的增强阻燃PET制备方法,包括如下步骤:A method for preparing a dimensionally stable reinforced flame-retardant PET, comprising the steps of:
步骤一:通过称取PET90-110重量份、PC树脂15-20重量份、玻璃纤维0-10重量份、阻燃剂10-15重量份、改性碳纳米管0.3-1.0重量份、改性剂5-10重量份、成核剂0.3-1重量份搅拌混合通过双螺旋杆挤出机挤出;Step 1: By weighing 90-110 parts by weight of PET, 15-20 parts by weight of PC resin, 0-10 parts by weight of glass fiber, 10-15 parts by weight of flame retardant, 0.3-1.0 parts by weight of modified carbon nanotubes, modified 5-10 parts by weight of agent and 0.3-1 part by weight of nucleating agent are stirred and mixed and extruded through a twin-screw extruder;
步骤二:挤出后进入至内水冷筒11内,然后启动双头电机24调节第一输出转杆23带动调节齿轮10旋转,通过调节齿轮10调节外齿轮环32带动内水冷筒11旋转;Step 2: After extruding, enter the inner
步骤三:通过双头电机24的运动进一步带动第一锥齿轮19运动,通过第一锥齿轮19调节第二锥齿轮20运动,通过第二锥齿轮20调节调节盘13运动;Step 3: the movement of the
步骤四:通过调节盘13调节铰接杆22运动,通过铰接杆22调节活塞14在活塞筒15内上下运动;Step 4: adjust the movement of the
步骤五:通过活塞14的运动打开第二单向阀28将水池中的水通过进液口进入至活塞筒15内,通过压动活塞14打开第一限位弹簧30将冷水导入至导入水管31内;Step 5: Open the second one-
步骤六:冷水通过导入水管31进入至密封外环17内,通过密封外环17进入至内水冷筒11内,然后通过内水冷筒11配合喷头12喷出进行对挤出的拉丝后的原料降温处理;Step 6: Cold water enters into the sealed
步骤七:通过第三锥齿轮21调节第一垂杆8带动切割刀9运动,通过切割刀9调节旋转进行对通过内水冷筒11的原料条进行切割成粒;Step 7: Adjust the first
步骤八:切割成粒后的原料落入至振动过滤板5上,带动振动过滤板5的振动,同步启动烘干风机7和侧加热板4进行加热烘干处理制备成增强阻燃PET。Step 8: The cut and granulated raw materials fall onto the vibrating
以上,仅为本发明进一步的实施例,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明所公开的范围内,根据本发明的技术方案及其构思加以等同替换或改变,都属于本发明的保护范围。The above are only further embodiments of the present invention, but the scope of protection of the present invention is not limited thereto. Any person familiar with the technical field shall, within the scope disclosed by the present invention, make further improvements according to the technical scheme of the present invention and its design. Equivalent replacements or changes all belong to the protection scope of the present invention.
Claims (10)
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