CN115571980A - A UASB reactor for treating high-concentration papermaking wastewater - Google Patents

A UASB reactor for treating high-concentration papermaking wastewater Download PDF

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CN115571980A
CN115571980A CN202211285492.4A CN202211285492A CN115571980A CN 115571980 A CN115571980 A CN 115571980A CN 202211285492 A CN202211285492 A CN 202211285492A CN 115571980 A CN115571980 A CN 115571980A
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reactor
papermaking wastewater
treating high
water
uasb
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王文鹏
王森
于政达
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Qingdao University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2846Anaerobic digestion processes using upflow anaerobic sludge blanket [UASB] reactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/26Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
    • C02F2103/28Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention discloses a UASB reactor for treating high-concentration papermaking wastewater, which comprises a tank body, a water distribution system, a three-phase separator, a biogas collection system and an external circulation system. Upper-layer sewage in the reactor is shunted along the central axis of the reactor through a water outlet of the circulating pipeline, and granular sludge in a reaction layer is impacted, so that the sewage and the granular sludge are fully mixed, the uniform water temperature in the reactor is facilitated, and the contact area of the sewage and the granular sludge is increased; circulation pipeline water inlet position can inhale come-up hollow granule mud, can guarantee again can not inhale full granule mud circulating pump in, destroy granule mud structure through the circulating pump, again through inside the circulation pipeline delivery port rush into the reactor, promote new and old granule mud to replace the growth, guaranteed that whole reactor's good has operation and efficient treatment.

Description

一种用于处理高浓度造纸废水的UASB反应器A UASB reactor for treating high-concentration papermaking wastewater

技术领域technical field

本发明涉及UASB反应器技术领域,特别涉及一种用于处理高浓度造纸废水的UASB反应器。The invention relates to the technical field of UASB reactors, in particular to a UASB reactor for treating high-concentration papermaking wastewater.

背景技术Background technique

制浆造纸废水属于高浓度有机废水,国家对其排放标准要求较为严格。造纸废水成复杂,主要特点为色度较高、COD较高,包含多种其他化学物质。目前,处理造纸废水的技术主要有物理法、化学法、物理化学法、生物法、膜技术和光催化法等。而在众多的处理方法中,厌氧生物处理技术因为具有能耗低、工作负荷高及二次污染小等优点,已成为造纸废水的首选预处理方法。Pulping and papermaking wastewater is a high-concentration organic wastewater, and the country has stricter requirements on its discharge standards. The composition of papermaking wastewater is complex, the main features are high chroma, high COD, and contains a variety of other chemical substances. At present, the technologies for treating papermaking wastewater mainly include physical methods, chemical methods, physicochemical methods, biological methods, membrane technology and photocatalytic methods. Among many treatment methods, anaerobic biological treatment technology has become the preferred pretreatment method for papermaking wastewater because of its advantages of low energy consumption, high workload and low secondary pollution.

本发明基于高浓度有机物废水进入反应层,污水无法和反应层内颗粒污泥充分接触反应,从而导致反应缓慢,去除效率低,水温不均匀,并且在三相分离器上方漂浮中空颗粒污泥等问题,构建了一种厌氧外部循环系统,从而达到强化污染物去除、控制水温恒定、促进新老颗粒污泥更替生长等目的,显著提高了去除效率,为缓解后续生化反应工作负荷提供保障。The present invention is based on the fact that high-concentration organic waste water enters the reaction layer, and the sewage cannot fully contact and react with the granular sludge in the reaction layer, resulting in slow reaction, low removal efficiency, uneven water temperature, and floating hollow granular sludge above the three-phase separator, etc. To solve the problem, an anaerobic external circulation system was constructed to achieve the purpose of strengthening the removal of pollutants, controlling the constant water temperature, and promoting the replacement and growth of new and old granular sludge, which significantly improved the removal efficiency and provided a guarantee for alleviating the workload of subsequent biochemical reactions.

发明内容Contents of the invention

本发明的目的是为了克服传统UASB厌氧反应器污水与微生物接触不充分,反应器内部水温不均匀,中空颗粒污泥上浮等问题,提供一种用于处理高浓度造纸废水的UASB反应器。The purpose of the present invention is to provide a UASB reactor for treating high-concentration papermaking wastewater in order to overcome the problems of insufficient contact between sewage and microorganisms in traditional UASB anaerobic reactors, uneven water temperature inside the reactor, and floating of hollow particle sludge.

本发明根据UASB厌氧反应器外部循环带动反应器内部水流流动,冲击反应层颗粒污泥,克服传统UASB污水和微生物接触不充分的缺点,对反应器内部水温进行均化,对中空污泥进行破坏,促进新老颗粒污泥更替生长,提高了厌氧反应效率。其具体方案是:一种用于处理高浓度造纸废水的UASB外循环系统,其特征在于:该系统包括罐体(1)、进水口(3)、布水器(4)、通孔(5)、循环管路出水口(7)、循环泵(6)、循环管路进水口(8)、出水口(9)、沼气收集管(14)、沼气收集器(12)、出气口(11)、溢流堰(13)、温度计探头(2)、三相分离器(15)、温度计探头(16)、流量计(17)、止回阀(18),进水口和出水口分别设置在反应器的下端和上端,循环管路系统各部由管道进行连接。According to the external circulation of the UASB anaerobic reactor, the water flow inside the reactor is driven to impact the granular sludge in the reaction layer, so as to overcome the shortcomings of insufficient contact between the traditional UASB sewage and microorganisms, homogenize the water temperature inside the reactor, and carry out the hollow sludge treatment. Destruction, promote the replacement growth of new and old granular sludge, and improve the efficiency of anaerobic reaction. The specific solution is: a UASB external circulation system for treating high-concentration papermaking wastewater, which is characterized in that: the system includes a tank body (1), a water inlet (3), a water distributor (4), a through hole (5 ), circulation pipeline water outlet (7), circulation pump (6), circulation pipeline water inlet (8), water outlet (9), biogas collection pipe (14), biogas collector (12), gas outlet (11 ), overflow weir (13), thermometer probe (2), three-phase separator (15), thermometer probe (16), flow meter (17), check valve (18), water inlet and outlet are respectively set in The lower end and upper end of the reactor, and each part of the circulation piping system are connected by pipes.

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:所述布水器(4)铺设在反应器底部,所述通孔(5)密布在布水器(4)上。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water distributor (4) is laid on the bottom of the reactor, and the through holes (5) are densely covered in the water distributor (4) up.

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:进水口(3)与布水器(4)连接,位于反应器主体(1)底部。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water inlet (3) is connected to the water distributor (4) and is located at the bottom of the reactor main body (1).

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:循环管路进水口(8)位于三相分离器(15)上方。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water inlet (8) of the circulation pipeline is located above the three-phase separator (15).

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:循环管路出水口(7)位于布水器(4)上方。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water outlet (7) of the circulation pipeline is located above the water distributor (4).

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:所述三相分离器(15)截面的性状为三角形,顶角角度在50°~60°之间,其顶角处开有沼气收集管(14),所述沼气收集管(14)与沼气收集器(12)连接,所述所述止回阀(18)位于沼气收集管(14)中段。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the shape of the section of the three-phase separator (15) is triangular, and the vertex angle is between 50° and 60° There is a biogas collection pipe (14) at the top corner, the biogas collection pipe (14) is connected to the biogas collector (12), and the check valve (18) is located in the middle section of the biogas collection pipe (14).

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:所述弯头(10)位于沼气收集器(12)内,并与沼气收集管(14)链接。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the elbow (10) is located in the biogas collector (12) and connected with the biogas collection pipe (14).

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:所述循环泵(6)为螺旋泵,其与循环管路出水口(7)、流量计(18)和循环管路进水口(8)连接。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the circulation pump (6) is a screw pump, which is connected with the circulation pipeline outlet (7), flow meter (18 ) to the water inlet (8) of the circulation line.

优选的,所述的一种用于处理高浓度造纸废水的UASB反应器,其特征在于:所述温度计探头-1(2)、温度计探头-2(16)分别位于反应器1/3、2/3处。Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the thermometer probe-1 (2) and the thermometer probe-2 (16) are respectively located in the reactor 1/3, 2 /3 places.

附图说明Description of drawings

图1是本发明的总体结构示意图,图中标号:1:UASB反应器主体;2:温度计探头-1;3:进水口;4:布水器;5:通孔;6:循环泵;7:循环管路出水口;8:循环管路进水口;9:出水口;10:弯头;11:出气口;12:沼气收集器;13:溢流堰;14:沼气收集管;15:三相分离器;16:温度计探头-2;17:流量计;18:止回阀。Fig. 1 is a schematic diagram of the overall structure of the present invention, the number in the figure: 1: UASB reactor main body; 2: thermometer probe-1; 3: water inlet; 4: water distributor; 5: through hole; 6: circulating pump; 7 : circulation pipeline water outlet; 8: circulation pipeline water inlet; 9: water outlet; 10: elbow; 11: gas outlet; 12: biogas collector; 13: overflow weir; 14: biogas collection pipe; 15: Three-phase separator; 16: thermometer probe-2; 17: flow meter; 18: check valve.

图2是循环泵开启前后COD去除效率。Figure 2 is the COD removal efficiency before and after the circulation pump is turned on.

图3循环泵开启前后温度变化。Figure 3 Temperature change before and after the circulation pump is turned on.

具体实施方式detailed description

为实现本发明实施例的目的、技术方案和优点,下面将结合以下实施例,对本发明进一步说明。显然,所描述的实施例是本发明的一部分实施例,而不是全部的实施例。基于所描述的本发明的实施例,本领域普通技术人员在无需创造性劳动的前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to achieve the objectives, technical solutions and advantages of the embodiments of the present invention, the present invention will be further described below in conjunction with the following embodiments. Apparently, the described embodiments are some, not all, embodiments of the present invention. Based on the described embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

本发明提出的是一种用于处理高浓度造纸废水的UASB反应器,包括如下步骤:What the present invention proposes is a kind of UASB reactor for the treatment of high-concentration papermaking wastewater, comprising the following steps:

(1)构建储水系统,并与UASB进水口连接;(1) Build a water storage system and connect it to the UASB water inlet;

(2)构建UASB系统,采用有机玻璃材质制作配件并组装;(2) Construct the UASB system, use plexiglass to make accessories and assemble them;

(2)准备足量的厌氧颗粒污泥;(2) Prepare a sufficient amount of anaerobic granular sludge;

(3)填充厌氧颗粒污泥;(3) Filling with anaerobic granular sludge;

(4)从造纸厂取废水,进行微生物驯化,开始进水,驯化一周;(4) Take wastewater from the paper mill, carry out microbial domestication, start water intake, and domesticate for a week;

(6)正式运行。(6) Formal operation.

以下结合具体实例,对本发明进行详细说明。The present invention will be described in detail below in conjunction with specific examples.

实施例一:造纸产业园污水厂原水,COD 4500 mg/L、水温20℃;UASB水力停留时间:13.5 h。Example 1: Raw water from sewage plant in paper industry park, COD 4500 mg/L, water temperature 20°C; UASB hydraulic retention time: 13.5 h.

每天固定两个时间段,采集系统内的进水水样、出水水样,使用标准方法进行测定COD的浓度(TU-1810, PUXI, China),使用数显温度计(TDM-280)进行水温测定。所用的所有试剂均为分析级试剂,分析一式两份,经过20天水温和COD数据监测,发现在开启循环泵以后,COD去除效率较开启循环泵前提高10%左右;反应器内部水温更加稳定,变化幅度较小。Set two time periods every day to collect the influent and effluent water samples in the system, use the standard method to measure the COD concentration (TU-1810, PUXI, China), and use the digital display thermometer (TDM-280) to measure the water temperature . All reagents used are analytical grade reagents, analyzed in duplicate, after 20 days of water temperature and COD data monitoring, it is found that after the circulation pump is turned on, the COD removal efficiency is about 10% higher than before the circulation pump is turned on; the water temperature inside the reactor is more stable, The change is small.

Claims (9)

1. The utility model provides a UASB extrinsic cycle system for handling high concentration papermaking waste water which characterized in that: the system comprises a tank body (1), a water inlet (3), a water distributor (4), a through hole (5), a circulating pipeline water outlet (7), a circulating pump (6), a circulating pipeline water inlet (8), a water outlet (9), a methane collecting pipe (14), a methane collector (12), a gas outlet (11), an overflow weir (13), a thermometer probe (2), a three-phase separator (15), a thermometer probe (16), a flowmeter (17) and a check valve (18), wherein the water inlet and the water outlet are respectively arranged at the lower end and the upper end of a reactor, and all parts of a circulating pipeline system are connected by pipelines.
2. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water distributor (4) is laid at the bottom of the reactor, and the through holes (5) are densely distributed on the water distributor (4).
3. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water inlet (3) is connected with the water distributor (4) and is positioned at the bottom of the reactor main body (1).
4. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water inlet (8) of the circulating pipeline is positioned above the three-phase separator (15).
5. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the water outlet (7) of the circulating pipeline is positioned above the water distributor (4).
6. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the section of the three-phase separator (15) is triangular, the angle of a vertex angle is 50-60 degrees, a biogas collecting pipe (14) is arranged at the vertex angle, the biogas collecting pipe (14) is connected with a biogas collector (12), and the check valve (18) is positioned at the middle section of the biogas collecting pipe (14).
7. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the elbow (10) is positioned in the biogas collector (12) and is connected with the biogas collecting pipe (14).
8. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the circulating pump (6) is a screw pump and is connected with the circulating pipeline water outlet (7), the flowmeter (18) and the circulating pipeline water inlet (8).
9. Preferably, the UASB reactor for treating high-concentration papermaking wastewater is characterized in that: the thermometer probe-1 (2) and the thermometer probe-2 (16) are respectively positioned at 1/3 and 2/3 of the reactor.
CN202211285492.4A 2022-10-20 2022-10-20 A UASB reactor for treating high-concentration papermaking wastewater Pending CN115571980A (en)

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