CN115449897A - HVPE production line for batch gallium nitride wafers and using method thereof - Google Patents

HVPE production line for batch gallium nitride wafers and using method thereof Download PDF

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Publication number
CN115449897A
CN115449897A CN202211042935.7A CN202211042935A CN115449897A CN 115449897 A CN115449897 A CN 115449897A CN 202211042935 A CN202211042935 A CN 202211042935A CN 115449897 A CN115449897 A CN 115449897A
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hvpe
substrate carrier
substrate
production line
gallium nitride
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郑小超
罗晓菊
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Jiate Semiconductor Technology Shanghai Co ltd
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Jiate Semiconductor Technology Shanghai Co ltd
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Priority to CN202211042935.7A priority Critical patent/CN115449897A/en
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    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B25/00Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
    • C30B25/02Epitaxial-layer growth
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45563Gas nozzles
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/52Controlling or regulating the coating process
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/54Apparatus specially adapted for continuous coating
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B25/00Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
    • C30B25/02Epitaxial-layer growth
    • C30B25/14Feed and outlet means for the gases; Modifying the flow of the reactive gases
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B25/00Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
    • C30B25/02Epitaxial-layer growth
    • C30B25/16Controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B29/00Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
    • C30B29/10Inorganic compounds or compositions
    • C30B29/40AIIIBV compounds wherein A is B, Al, Ga, In or Tl and B is N, P, As, Sb or Bi
    • C30B29/403AIII-nitrides
    • C30B29/406Gallium nitride

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

The invention discloses an HVPE production line for batch gallium nitride wafers and a using method thereof, wherein the HVPE production line comprises the following steps: a substrate carrier; the sealed conveying track comprises a synchronous belt used for conveying the substrate carrier and a sealed cavity enclosed outside the synchronous belt; the windows are arranged at the top of the closed cavity at intervals; the horizontal bases are positioned above the sealed cavity at intervals and are intersected with the extending direction of the sealed cavity; the plurality of mechanical arms are connected to the bottoms of the plurality of horizontal bases in a sliding manner; the HVPE machines are communicated with one ends, far away from the closed cavity, of the horizontal bases; and the optical probe is positioned at the tail end of the horizontal base and is in signal connection with the corresponding manipulator. The invention has the advantages that the pollution problem in the substrate conveying process is solved through the sealed conveying track, the growth of a plurality of substrates can be completed at one time through the matching of the synchronous belt and the mechanical arm, and the production efficiency is improved.

Description

HVPE production line for batch gallium nitride wafers and using method thereof
Technical Field
The invention relates to the field of growing a CaN film by hydride epitaxy (HVPE), in particular to an HVPE production line for batching gallium nitride wafers and a using method thereof.
Background
The main principle of HVPE nitride growth is: the method comprises the following steps of taking metal gallium as a III group gallium source, ammonia gas (NH 3) as a V group nitrogen source, hydrogen chloride (HCl) as a reaction gas, carrying the reaction gas by carrier gas (hydrogen or nitrogen), carrying out a chemical reaction with the metal gallium in the reaction gas by a gallium boat to generate gallium chloride (GaCl), carrying the reaction gas by the carrier gas (hydrogen or nitrogen), reacting the reaction gas with the NH3 above a substrate to generate GaN, and depositing on the substrate, wherein the main chemical reaction comprises the following steps:
2HCl(g)+2Ga(l)=2GaCl(g)+H2(g)
GaCl(g)+NH3(g)=GaN(S)+HCl(g)+H2(g)
hydride vapor phase epitaxy equipment is compound growth process equipment and is mainly used for epitaxially growing a layer of thick film or crystal such as GaAs, gaN and the like on the surface of a substrate through hydride gas such as H2, HCl and the like in a high-temperature environment. The existing hydride vapor phase epitaxy equipment is operated by a single substrate one by one, the substrate needs to be manually placed into HVPE for growth, and the substrate is manually taken out after the growth is finished, so that the production efficiency is low.
Chinese utility model patent publication No. CN203007478U discloses multi-cavity step-by-step processing device for vapor phase epitaxy material growth, including one or more process treatment chamber, the process treatment chamber side is equipped with two and more than substep HVPE epitaxial growth chambers, be equipped with one or more than one loading/unloading wafer chamber between process treatment chamber and the substep HVPE epitaxial growth chamber, be equipped with one or more than one linkage transmission structure of transmission effect between process treatment chamber, loading/unloading wafer chamber and the substep HVPE epitaxial growth chamber. The utility model provides a crystal material growth step thermophysics, chemical reaction dynamics and different growth condition deposition rate and reaction chamber shower nozzle velocity of flow control precision match the scheduling problem to high efficiency obtains high-quality GaN substrate in batches, and the device's every reaction chamber internal parameter is different, solves crystal material growth step thermophysics, chemical reaction dynamics and different growth condition deposition rate and reaction chamber shower nozzle velocity of flow control precision match the scheduling problem.
Disclosure of Invention
The invention aims to solve the technical problem that the existing HVPE can not be automatically carried out in batch, and provides an HVPE production line for batch gallium nitride wafers and a using method thereof.
The technical scheme of the invention is as follows: an HVPE production line for bulk gallium nitride wafers, comprising: a substrate carrier; the sealed conveying track comprises a synchronous belt for conveying the substrate carrier and a sealed cavity body enclosed outside the synchronous belt; the windows are arranged at the top of the closed cavity at intervals; the horizontal bases are positioned above the sealed cavity at intervals and are intersected with the extending direction of the sealed cavity; the plurality of mechanical arms are connected to the bottoms of the plurality of horizontal bases in a sliding manner; the HVPE machines are communicated with one ends, far away from the closed cavity, of the horizontal bases; and the optical probe is positioned at the tail end of the horizontal base and is in signal connection with the corresponding manipulator.
The improvement of the proposal is that a plurality of nitrogen nozzles facing the substrate carrier are uniformly distributed in the closed cavity.
The further improvement of the scheme is that the plurality of horizontal bases are internally provided with gate valves.
In the scheme, the periphery of the substrate carrier is provided with positioning holes, and the center of the substrate carrier is provided with a positioning groove.
A further improvement of the scheme is that sealing doors are arranged at two ends of the sealing conveying track.
The use method of the HVPE production line for batch gallium nitride wafers comprises the following steps: placing a plurality of substrates into corresponding substrate carriers, placing the substrate carriers on a synchronous belt, detecting the substrates by an optical probe on a first horizontal base when the first substrate carrier passes through the first horizontal base, sending a starting signal to a mechanical arm, and grabbing and sending the first substrate carrier and the substrates into a first HVPE machine table from a window by the mechanical arm for wafer growth; when the second substrate carrier passes through the second horizontal base, an optical probe on the second horizontal base detects the substrate and sends a starting signal to the mechanical arm, and the mechanical arm grabs and sends the second substrate carrier and the substrate into a second HVPE machine table for wafer growth; and the steps are carried out until the last substrate carrier is grabbed by the mechanical hand and sent to the last HVPE machine for wafer growth, the grown wafer in the substrate carrier is grabbed by the corresponding mechanical hand again and sent to the synchronous belt, and the wafer is received from the tail end of the synchronous belt, so that the wafer growth of the first batch is completed.
The invention has the advantages that the pollution problem in the substrate conveying process is solved through the sealed conveying track, automatic feeding and discharging are realized through the matching of the synchronous belt and the mechanical arm, the growth of a plurality of substrates can be completed at one time, and the production efficiency is improved.
Drawings
FIG. 1 is a schematic view of an HVPE production line for bulk gallium nitride wafers in accordance with the present invention;
FIG. 2 is a schematic view of the sealing conveyor track of FIG. 1;
in the figure, the device comprises a substrate carrier 1, a substrate carrier 11, a positioning hole 12, a positioning groove 2, a synchronous belt 3, a closed cavity 4, a horizontal base 5, a mechanical arm 6, an HVPE machine table 7, a nitrogen nozzle 8, a gate valve 9 and a sealing door.
Detailed Description
The technical solution in the embodiments of the present invention is clearly and completely described below with reference to the accompanying drawings. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments based on the embodiments in the present invention, without any inventive work, will be apparent to those skilled in the art from the following description.
The HVPE internal structure of the invention is the prior art, like the HVPE cavity internal temperature measuring device disclosed by the Chinese utility model patent publication No. CN213148130U, includes: an HVPE cavity and a temperature measuring probe; the method is characterized in that: it still includes: a gate valve mounted at the bottom of the HVPE chamber; the operation cabin is fixedly communicated with the bottom of the door valve; the lifting device is arranged at the bottom of the operation cabin and is used for sequentially passing the temperature measuring probe through the operation cabin and the gate valve and sending the temperature measuring probe into the HVPE cavity; the temperature measuring probe fixing device is fixed at the top of the lifting rod; and the temperature measuring probe is fixed on the temperature measuring probe fixing device.
An HVPE production line for batch production of gallium nitride wafers comprises: a substrate carrier 1; the sealed conveying track comprises a synchronous belt 2 for conveying a substrate carrier and a sealed cavity 3 enclosed outside the synchronous belt; the windows are arranged at the top of the closed cavity at intervals; the horizontal bases 4 are arranged above the sealed cavity at intervals and are intersected with the extending direction of the sealed cavity; the manipulators 5 are connected to the bottoms of the horizontal bases in a sliding manner; the HVPE machines 6 are communicated with one ends of the horizontal bases far away from the closed cavity; and the optical probe is positioned at the tail end of the horizontal base and is in signal connection with the corresponding manipulator.
The closed cavity in the invention is preferably made of transparent material, such as glass or acrylic plate, so that the conveying condition of the substrate carrier can be observed at any time. And sealing doors 9 are arranged at two ends of the sealing conveying track, and when a substrate carrier needs to be put in or taken out, the corresponding sealing doors are opened.
The periphery of the substrate carrier is provided with positioning holes 11, the center of the substrate carrier is provided with a positioning groove 12, the positioning groove is used for bearing a substrate, the positioning holes are used for positioning in HVPE, a telescopic positioning column is arranged in the corresponding HVPE, the positioning column is used for fixing the substrate carrier when extending out, and the substrate carrier can be taken out when retracting.
The sealing conveying track can be designed into a linear type or a square-shaped type, and the square-shaped type is convenient for saving the occupied area.
As a preferred example of the invention, a plurality of nitrogen nozzles 7 facing the substrate carrier are uniformly distributed in the closed cavity, and the nitrogen nozzles can spray nitrogen to the substrate on the closed cavity in the whole conveying process of the substrate carrier, so that the pollution on the substrate can be swept, and the yield of products can be improved. The blown out nitrogen gas can be discharged from the window.
And gate valves 8 are arranged in the horizontal bases, and are closed after the substrate carrier enters the HVPE to isolate the HVPE from the sealed conveying track.
The use method of HVPE production line of batch gallium nitride wafer comprises the following steps: placing a plurality of substrates into corresponding substrate carriers, placing the substrate carriers on a synchronous belt, detecting the substrates by an optical probe on a first horizontal base when the first substrate carrier passes through the first horizontal base, sending a starting signal to a mechanical arm, and grabbing and sending the first substrate carrier and the substrates into a first HVPE machine table from a window by the mechanical arm for wafer growth; when the second substrate carrier passes through the second horizontal base, an optical probe on the second horizontal base detects the substrate and sends a starting signal to the mechanical arm, and the mechanical arm grabs and sends the second substrate carrier and the substrate into a second HVPE machine for wafer growth; and the steps are carried out until the last substrate carrier is grabbed by the mechanical hand and sent to the last HVPE machine for wafer growth, the grown wafer in the substrate carrier is grabbed by the corresponding mechanical hand again and sent to the synchronous belt, and the wafer is received from the tail end of the synchronous belt, so that the wafer growth of the first batch is completed.

Claims (6)

1. HVPE production line of batched gallium nitride wafer, characterized by: the method comprises the following steps: a substrate carrier (1); the sealed conveying track comprises a synchronous belt (2) used for conveying the substrate carrier and a closed cavity (3) enclosed outside the synchronous belt; the windows are arranged at the top of the closed cavity at intervals; the horizontal bases (4) are positioned above the sealed cavity at intervals and are intersected with the extending direction of the sealed cavity; the manipulators (5) are connected to the bottoms of the horizontal bases in a sliding manner; the plurality of HVPE machine tables (6) are communicated with one ends, far away from the closed cavity, of the plurality of horizontal bases; and the optical probe is positioned at the tail end of the horizontal base and is in signal connection with the corresponding manipulator.
2. The HVPE production line for bulk gallium nitride wafers according to claim 1, wherein: and a plurality of nitrogen nozzles (7) facing the substrate carrier are uniformly distributed in the closed cavity.
3. The HVPE production line for bulk gallium nitride wafers according to claim 1, wherein: gate valves (8) are arranged in the horizontal bases.
4. The HVPE production line for bulk gallium nitride wafers according to claim 1, wherein: positioning holes (11) are formed in the periphery of the substrate carrier, and a positioning groove (12) is formed in the center of the substrate carrier.
5. The HVPE production line for bulk gallium nitride wafers according to claim 1, wherein: and sealing doors (9) are arranged at two ends of the sealing conveying track.
6. The use method of HVPE production line for batch gallium nitride wafers according to any one of claims 1-5, wherein: the method comprises the following steps: placing a plurality of substrates into corresponding substrate carriers, placing the substrate carriers on a synchronous belt, detecting the substrates by an optical probe on a first horizontal base when the first substrate carrier passes through the first horizontal base, sending a starting signal to a mechanical arm, and grabbing and sending the first substrate carrier and the substrates into a first HVPE machine table from a window by the mechanical arm for wafer growth; when the second substrate carrier passes through the second horizontal base, an optical probe on the second horizontal base detects the substrate and sends a starting signal to the mechanical arm, and the mechanical arm grabs and sends the second substrate carrier and the substrate into a second HVPE machine table for wafer growth; and the steps are carried out until the last substrate carrier is grabbed by the mechanical hand and sent to the last HVPE machine for wafer growth, the grown wafer in the substrate carrier is grabbed by the corresponding mechanical hand again and sent to the synchronous belt, and the wafer is received from the tail end of the synchronous belt, so that the wafer growth of the first batch is completed.
CN202211042935.7A 2022-08-29 2022-08-29 HVPE production line for batch gallium nitride wafers and using method thereof Pending CN115449897A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030013222A1 (en) * 2001-06-29 2003-01-16 Agnes Trassoudaine Process for producing an epitaxial layer of gallium nitride by the HVPE method
CN102304698A (en) * 2011-09-08 2012-01-04 中国科学院半导体研究所 Device for growing silicon carbide crystal by high-temperature chemical vapor deposition (HTCVD) method
JP2012131692A (en) * 2011-04-28 2012-07-12 Aetech Corp METHOD AND APPARATUS FOR MANUFACTURING GALLIUM NITRIDE (GaN) SELF-SUPPORTING SUBSTRATE
KR101445673B1 (en) * 2013-04-30 2014-10-01 주식회사 이엔에프테크놀로지 Method and Apparatus for growing semiconductor crystal

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030013222A1 (en) * 2001-06-29 2003-01-16 Agnes Trassoudaine Process for producing an epitaxial layer of gallium nitride by the HVPE method
JP2012131692A (en) * 2011-04-28 2012-07-12 Aetech Corp METHOD AND APPARATUS FOR MANUFACTURING GALLIUM NITRIDE (GaN) SELF-SUPPORTING SUBSTRATE
CN102304698A (en) * 2011-09-08 2012-01-04 中国科学院半导体研究所 Device for growing silicon carbide crystal by high-temperature chemical vapor deposition (HTCVD) method
KR101445673B1 (en) * 2013-04-30 2014-10-01 주식회사 이엔에프테크놀로지 Method and Apparatus for growing semiconductor crystal

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
兰虎 等主编: "工业机器人基础", 机械工业出版社, pages: 190 - 191 *

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Application publication date: 20221209