CN115254893A - A kind of waste soft pack lithium battery directly charged crushing equipment and method - Google Patents

A kind of waste soft pack lithium battery directly charged crushing equipment and method Download PDF

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CN115254893A
CN115254893A CN202210849953.XA CN202210849953A CN115254893A CN 115254893 A CN115254893 A CN 115254893A CN 202210849953 A CN202210849953 A CN 202210849953A CN 115254893 A CN115254893 A CN 115254893A
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crushing
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苑文仪
陈登峰
黄庆
章金宇
徐利军
蒋晨龙
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Shanghai Polytechnic University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • B09B3/35Shredding, crushing or cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B2101/00Type of solid waste
    • B09B2101/15Electronic waste
    • B09B2101/16Batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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Abstract

本发明涉及一种废旧软包锂电池直接带电破碎设备及方法,设备包括送料单元、破碎单元、筛分单元、集液单元、低温烘焙单元、破碎保护系统、集气系统。软包锂电池通过送料单元的裙边挡板输送机进行均匀上料,破碎单元采用双轴对辊破碎机对软包电池进行破碎,筛分单元使用振动筛将破碎过程产生的电池固体物料和破碎废液分离,集液单元收集电池废液,低温烘焙单元将残留在电池固体物料中的废液蒸发出来,破碎保护系统使用液氮作为保护介质防止破碎过程出现燃烧爆炸,集气系统收集破碎过程和烘焙过程中产生的废气。本发明能实现软包锂电池的直接带电破碎,无须对电池进行放电预处理,极大缩短了电池破碎周期,破碎效率高、运行成本低、安全可靠。

Figure 202210849953

The invention relates to a directly charged crushing device and method for waste soft-pack lithium batteries. The device comprises a feeding unit, a crushing unit, a screening unit, a liquid collecting unit, a low-temperature baking unit, a crushing protection system and a gas collecting system. The soft-pack lithium battery is uniformly fed through the skirt baffle conveyor of the feeding unit. The crushing unit uses a dual-shaft roller crusher to crush the soft-pack battery. The screening unit uses a vibrating screen to separate the battery solid materials generated during the crushing process and The crushing waste liquid is separated, the liquid collecting unit collects the battery waste liquid, the low-temperature baking unit evaporates the waste liquid remaining in the solid material of the battery, the crushing protection system uses liquid nitrogen as a protective medium to prevent combustion and explosion during the crushing process, and the gas collecting system collects and crushes Exhaust gases from processes and roasting. The invention can realize the direct charged crushing of the soft-pack lithium battery without discharging pretreatment of the battery, greatly shortens the battery crushing cycle, has high crushing efficiency, low operating cost, and is safe and reliable.

Figure 202210849953

Description

一种废旧软包锂电池直接带电破碎设备及方法A kind of equipment and method for directly charged crushing of waste soft-pack lithium batteries

技术领域technical field

本发明涉及一种带电破碎设备及方法,具体涉及一种不需要对电池进行放电,破碎电池的周期缩短,破碎效率高,运行成本低,便于人员操作,安全可靠的废旧软包锂电池直接带电破碎设备及方法。The invention relates to a charged crushing equipment and method, in particular to a safe and reliable waste soft-packed lithium battery that does not need to be discharged, shortens the cycle of crushing the battery, has high crushing efficiency, low operating cost, is convenient for personnel to operate, and is safe and reliable. Crushing equipment and methods.

背景技术Background technique

软包锂电池是当代移动电子设备所使用电池的主流产品,而且软包锂电池中含有各种有害物质,如果废旧后直接丢弃将会危害环境。所以会回收废弃软包锂电池,取出其中有价值的物质进行再次利用。针对大量的废旧软包电池,需要快速进行处理,而传统的盐水放电工艺,会产生氯气或者氢气、氧气等气体,既不环保,也存在一定的安全性;而物理放电,则存在放电效率低,还有放电过程中的安全性问题。为了提高电池的处理效率,带电破碎是满足当前大批量处理废旧软包电池的刚性需求。Soft-pack lithium batteries are the mainstream products used in contemporary mobile electronic devices, and soft-pack lithium batteries contain various harmful substances. If they are discarded directly after use, they will endanger the environment. Therefore, waste soft-pack lithium batteries will be recycled, and valuable substances will be taken out for reuse. A large number of waste pouch batteries need to be processed quickly, and the traditional salt water discharge process will produce chlorine, hydrogen, oxygen and other gases, which is neither environmentally friendly nor safe; while physical discharge has low discharge efficiency , There are also safety issues during the discharge process. In order to improve the processing efficiency of batteries, live crushing is to meet the current rigid demand for mass processing of waste pouch batteries.

目前的工艺中带电破碎中,电池受到挤压、剪切等物理过程,会使其中正负极片短路,电池中残余的电量急速释放,导致破碎过程中发生放热、起火、爆炸等现象,影响了破碎过程的安全性。In the current process of charged crushing, the battery is subjected to physical processes such as extrusion and shearing, which will short-circuit the positive and negative electrodes, and the residual power in the battery will be released rapidly, resulting in heat release, fire, explosion and other phenomena during the crushing process. It affects the safety of the crushing process.

中国发明专利(CN202110129571.1)提供一种带电破碎设备,将废旧电池放入进料斗内,打开第一气动阀,电池落入进料暂存组件中,第一气动阀闭合,打开第二气动阀,电池落入电池破碎仓中,破碎机对电池进行破碎,破碎后打开第四气动阀,破碎物料落入出料暂存仓,然后关闭第四气动阀,打开第三气动阀,破碎物料进入出料漏斗中。破碎过程中使用氮气作为保护气体,破碎过程中产生气体被抽气扇和排气管道抽到碱液喷淋塔进行处理。该设备采用多个气动阀,虽然一定程度上加强了密封性,但是也大大降低了破碎效率。该设备未考虑破碎过程中电解液的处理问题,破碎过程电解液将积聚破碎装置中,并且破碎后的物料还会残留电解液,该设备却直接将破碎后物料收集起来。而且,该设备没有传感器智能反馈系统,无法检测设备运行状态,无法确保设备长期运行时的安全性。Chinese invention patent (CN202110129571.1) provides a live crushing equipment, put the waste battery into the feeding hopper, open the first pneumatic valve, the battery falls into the feeding temporary storage assembly, close the first pneumatic valve, open the second Pneumatic valve, the battery falls into the battery crushing bin, the crusher crushes the battery, opens the fourth pneumatic valve after crushing, the crushed material falls into the discharge temporary storage bin, then closes the fourth pneumatic valve, opens the third pneumatic valve, and crushes The material enters the discharge hopper. Nitrogen is used as a protective gas during the crushing process, and the gas generated during the crushing process is pumped by the exhaust fan and exhaust pipe to the lye spray tower for treatment. The equipment adopts multiple pneumatic valves, although the sealing performance is enhanced to a certain extent, but the crushing efficiency is also greatly reduced. This equipment does not consider the problem of electrolyte treatment during the crushing process. During the crushing process, the electrolyte will accumulate in the crushing device, and the crushed material will still have electrolyte, but this equipment directly collects the crushed material. Moreover, the device does not have an intelligent sensor feedback system, which cannot detect the operating status of the device, and cannot ensure the safety of the device during long-term operation.

发明内容Contents of the invention

针对上述问题,本发明的主要目的在于提供一种不需要对电池进行放电,破碎电池的周期缩短,破碎效率高,运行成本低,便于人员操作,安全可靠的废旧软包锂电池直接带电破碎设备及方法。In view of the above problems, the main purpose of the present invention is to provide a direct charge crushing equipment for waste soft-packed lithium batteries that does not need to be discharged, shortens the cycle of crushing batteries, has high crushing efficiency, low operating costs, is convenient for personnel to operate, and is safe and reliable. and methods.

本发明是通过下述技术方案来解决上述技术问题的:一种废旧软包锂电池直接带电破碎设备,所述废旧软包锂电池直接带电破碎设备用于破碎废旧软包锂电池,所述废旧软包锂电池直接带电破碎设备包括:送料单元(1)、破碎单元(2)、筛分单元(3)、集液单元(4)、低温烘焙单元(5)、破碎保护系统(6)和集气系统(7)。The present invention solves the above-mentioned technical problems through the following technical solutions: a waste soft-pack lithium battery direct charging crushing equipment, the waste soft-pack lithium battery direct charging crushing equipment is used for crushing waste soft-pack lithium batteries, the waste Soft package lithium battery directly charged crushing equipment includes: feeding unit (1), crushing unit (2), screening unit (3), liquid collection unit (4), low temperature baking unit (5), crushing protection system (6) and Gas collection system (7).

废旧软包锂电池通过送料单元(1)依次进入破碎单元(2)和筛分单元(3),筛分单元(3)中出来的固体进入低温烘焙单元(5),液体进入集液单元(4),气体进入集气系统(7)。The waste soft-packed lithium battery enters the crushing unit (2) and the screening unit (3) sequentially through the feeding unit (1), the solids from the screening unit (3) enter the low-temperature baking unit (5), and the liquid enters the liquid collection unit ( 4), the gas enters the gas collection system (7).

送料单元(1):所述送料单元(1)将软包锂电池送入破碎单元(2)。Feeding unit (1): The feeding unit (1) sends the soft-pack lithium battery into the crushing unit (2).

破碎单元(2):所述破碎单元(2)将送料单元(1)送来的软包锂电池进行破碎。Crushing unit (2): The crushing unit (2) crushes the soft-pack lithium battery sent by the feeding unit (1).

筛分单元(3):所述筛分单元(3)使用振动筛将破碎单元(2)破碎过程产生的电池固体物料和破碎废液分离。Screening unit (3): The screening unit (3) uses a vibrating screen to separate the battery solid material and crushing waste liquid generated during the crushing process of the crushing unit (2).

集液单元(4):所述集液单元(4)位于筛分单元(3)的底部,收集筛分单元(3)中的液体。Liquid collection unit (4): The liquid collection unit (4) is located at the bottom of the screening unit (3), and collects the liquid in the screening unit (3).

低温烘焙单元(5):所述低温烘焙单元(5)位于筛分单元(3)的一侧,收集筛分单元(3)中的固体;所述低温烘焙单元(5)在传送固体物料的同时还烘焙出残留在固体物料中的废液。Low-temperature baking unit (5): the low-temperature baking unit (5) is located on one side of the screening unit (3), and collects solids in the screening unit (3); At the same time, the waste liquid remaining in the solid material is also baked out.

破碎保护系统(6):所述破碎保护系统(6)安装在破碎单元(2)的一侧,保护破碎单元(2)中的物料不会溅出;同时所述破碎保护系统(6)中使用液氮作为保护介质以防止破碎过程出现燃烧爆炸。Crushing protection system (6): The crushing protection system (6) is installed on one side of the crushing unit (2) to protect the materials in the crushing unit (2) from splashing; at the same time, the crushing protection system (6) Use liquid nitrogen as a protective medium to prevent combustion and explosion during the crushing process.

集气系统(7):所述集气系统(7)位于筛分单元(3)的另一侧,收集筛分单元(3)中的气体,集气系统还为破碎过程提供负压排气。Gas collection system (7): The gas collection system (7) is located on the other side of the screening unit (3), collecting the gas in the screening unit (3), and the gas collection system also provides negative pressure exhaust for the crushing process .

在本发明的具体实施例子中,所述送料单元(1)包括送料漏斗(101)、送料漏斗支架(102)、裙边挡板输送带(103)、输送机支架(104);送料漏斗101固定在送料漏斗支架(102)上,送料漏斗支架102横跨在输送带进料端正上方,送料漏斗(101)顶端设置进料口,下端设置出料口;软包锂电池通过送料漏斗(101)落到裙边挡板输送带(103)的进料端块状传送区域中,输送机匀速将软包电池输送到输送机顶部旁的进料漏斗中。In a specific implementation example of the present invention, the feeding unit (1) includes a feeding funnel (101), a feeding funnel support (102), a skirt baffle conveyor belt (103), a conveyor support (104); the feeding funnel 101 It is fixed on the feed funnel support (102), and the feed funnel support 102 is straddled directly above the feeding end of the conveyor belt. ) falls into the bulk transfer area at the feed end of the skirt baffle conveyor belt (103), and the conveyor transports the pouch battery to the feed hopper next to the top of the conveyor at a constant speed.

在本发明的具体实施例子中,所述破碎单元(2)包括进料漏斗(201)、破碎机(202)、破碎机支架(203)、刚性法兰(204)、柔性金属管(205)、维修门(206),所述进料漏斗(201)位于破碎机(202)的上方,进料漏斗(201)侧边设有开口与送料单元(1)的出料端相连;破碎机支架(203)位于破碎机下方,破碎机(202)与破碎机支架(203)之间采用刚性法兰(204)连接;破碎机支架203侧边设有维护的维修门(206),软包锂电池通过进料漏斗(201)进入到所述的破碎机(202)中进行破碎。In a specific implementation example of the present invention, the crushing unit (2) includes a feed hopper (201), a crusher (202), a crusher support (203), a rigid flange (204), a flexible metal pipe (205) , maintenance door (206), described feeding funnel (201) is positioned at the top of crusher (202), and feeding funnel (201) side is provided with opening and is connected with the discharge end of feeding unit (1); Crusher support (203) is located below the crusher, and the rigid flange (204) is used to connect the crusher (202) and the crusher bracket (203); the maintenance door (206) is provided on the side of the crusher bracket 203, and the soft-packed lithium The battery enters the crusher (202) through the feed hopper (201) for crushing.

所述筛分单元(3)位于破碎机支架203内部,其包括筛网(301)、振动电机(302)、弹簧组(303),所述筛分单元(3)位于破碎机支架内部,其包括筛网(301)、振动电机(302)、弹簧组(303),所述筛网(301)的一端通过合页与破碎机支架相连,另一端与弹簧组相连,弹簧组中的弹簧竖直固定在破碎机支架内,振动电机连接在筛网架上为筛网提供振动源,筛分单元将电解液和破碎物料筛分开。在具体的实施过程中筛网(301)的孔径可以为30目,弹簧组中的可以采用弹簧竖直固定在破碎机支架内。The screening unit (3) is located inside the crusher support 203, and it includes a screen (301), a vibrating motor (302), and a spring set (303). The screening unit (3) is located inside the crusher support, and its It includes a screen (301), a vibrating motor (302), and a spring set (303). One end of the screen (301) is connected to the crusher bracket through a hinge, and the other end is connected to the spring set. The springs in the spring set are vertical It is directly fixed in the bracket of the crusher, the vibration motor is connected to the screen frame to provide a vibration source for the screen, and the screening unit screens the electrolyte and the crushed material. In the specific implementation process, the aperture of the screen cloth (301) can be 30 meshes, and the springs in the spring group can be vertically fixed in the crusher support by using springs.

在本发明的具体实施例子中,所述集液单元(4)包括集液器(401)和集液器支架(402),集液器支架(402)位于破碎机支架(203)下方,集液器(401)为漏斗形状固定在集液器支架(402)内,集液器(401)收集筛分单元产生的电解液。In a specific implementation example of the present invention, the liquid collection unit (4) includes a liquid collector (401) and a liquid collector bracket (402), the liquid collector bracket (402) is located under the crusher bracket (203), and the liquid collector The liquid collector (401) is funnel-shaped and fixed in the liquid collector bracket (402), and the liquid collector (401) collects the electrolyte produced by the screening unit.

在本发明的具体实施例子中,所述低温烘焙单元(5)包括烘焙腔体(501)、集气模块(502)、低温加热模块(503)、低温烘焙单元支架(504)、柔性金属管(505),所述烘焙腔体采用柔性金属管与筛分单元连接,其内部有带式输送机输送固体物料,腔体内侧壁均匀布有加热条,腔体顶部等距布置一排集气口,固体物料从筛分单元进入本单元后,输送机缓慢将其运送到出料口,运送过程中,固体物料受到烘焙腔体中低温加热模块的持续烘焙,固体物料中的残留电解液被蒸发,集气模块收集被蒸发的电解液并通过管道传送到集气系统中。In a specific implementation example of the present invention, the low-temperature baking unit (5) includes a baking cavity (501), a gas collection module (502), a low-temperature heating module (503), a low-temperature baking unit bracket (504), a flexible metal tube (505), the baking cavity is connected with the screening unit by a flexible metal pipe, and there is a belt conveyor inside to transport the solid material, the inner wall of the cavity is evenly distributed with heating strips, and a row of gas collection ports are equidistantly arranged on the top of the cavity After the solid material enters the unit from the screening unit, the conveyor slowly transports it to the discharge port. During the transportation, the solid material is continuously baked by the low-temperature heating module in the baking cavity, and the residual electrolyte in the solid material is evaporated. , the gas collection module collects the evaporated electrolyte and sends it to the gas collection system through pipelines.

在本发明的具体实施例子中,所述破碎保护系统(6)为使用液氮作为保护介质以防止破碎过程出现燃烧爆炸的破碎保护系统(6);所述破碎保护系统(6)包括喷淋嘴(601)、液氮传输管(602)、气泵(603)、液氮储存罐(604)温度传感器(605)、氧含量传感器(606)、报警装置(607)、启停控制器(608);所述液氮储存罐位于整个设备侧部,气泵和液氮传输管把储存罐中液氮运送到喷淋嘴中,喷淋嘴位于进料漏斗的顶端侧壁,通过控制气泵可以控制液氮喷淋量;在靠近破碎机入口的进料漏斗侧壁上装有温度传感器和氧含量传感器,温度传感器和氧含量传感器分别检测装置中的温度和氧含量,传感器与报警装置和启停控制器连接。In a specific implementation example of the present invention, the crushing protection system (6) is a crushing protection system (6) that uses liquid nitrogen as a protective medium to prevent combustion and explosion during the crushing process; the crushing protection system (6) includes spraying Nozzle (601), liquid nitrogen transfer pipe (602), air pump (603), liquid nitrogen storage tank (604), temperature sensor (605), oxygen content sensor (606), alarm device (607), start-stop controller (608 ); the liquid nitrogen storage tank is located at the side of the entire device, and the liquid nitrogen in the storage tank is transported to the spray nozzle by the air pump and the liquid nitrogen transfer pipe, and the spray nozzle is located at the top side wall of the feed funnel, which can be controlled by controlling the air pump The amount of liquid nitrogen spraying; a temperature sensor and an oxygen content sensor are installed on the side wall of the feed funnel near the crusher inlet. The temperature sensor and the oxygen content sensor detect the temperature and oxygen content in the device respectively, and the sensor and alarm device and start-stop control device connection.

在本发明的具体实施例子中,所述喷淋嘴采用角度可调节的喷头,喷淋嘴对称分布于进料漏斗顶端内壁上,在破碎机上方形成交叉的液氮低温、无氧保护区域。In a specific implementation example of the present invention, the spray nozzle adopts an angle-adjustable spray head, and the spray nozzle is symmetrically distributed on the inner wall of the top of the feeding funnel, forming a crossed liquid nitrogen low temperature and anaerobic protection area above the crusher.

在本发明的具体实施例子中,所述集气系统(7)包括负压排气口(701)、排气管(702)、气泵(703),所述负压排气口位于筛分单元侧壁上,排气管分别与筛分单元中的负压排气口和低温烘焙单元的集气模块连接,真空泵通过排气管收集整个设备处理软包锂电池过程中产生的废气。In a specific implementation example of the present invention, the gas collection system (7) includes a negative pressure exhaust port (701), an exhaust pipe (702), and an air pump (703), and the negative pressure exhaust port is located in the screening unit On the side wall, the exhaust pipe is respectively connected to the negative pressure exhaust port in the screening unit and the gas collection module of the low-temperature baking unit. The vacuum pump collects the exhaust gas generated during the process of processing the soft-packed lithium battery by the entire equipment through the exhaust pipe.

一种废旧软包锂电池直接带电破碎方法,其特征在于:所述带电破碎方法包括如下步骤:A method for directly charged crushing of waste soft-pack lithium batteries, characterized in that: the charged crushing method includes the following steps:

第一步:将软包锂电池送料到送料单元,裙边挡板输送带将软包锂电池匀速送到破碎单元;The first step: Feed the soft-pack lithium battery to the feeding unit, and the skirt baffle conveyor belt will send the soft-pack lithium battery to the crushing unit at a uniform speed;

第二步,软包电池进入破碎机中进行破碎,破碎过程立体布局的喷淋嘴持续喷出液氮保证破碎过程安全进行;In the second step, the pouch battery enters the crusher for crushing, and the three-dimensional spray nozzles in the crushing process continuously spray liquid nitrogen to ensure the safety of the crushing process;

第三步:破碎后物料进入筛分单元,振动筛将固体物料和电解液筛分开,电解液漏入集液单元中,而固体物料进入低温烘焙单元;Step 3: The crushed material enters the screening unit, the vibrating screen separates the solid material and the electrolyte, the electrolyte leaks into the liquid collection unit, and the solid material enters the low-temperature baking unit;

第四步:固体物料在低温烘焙单元中被传送带缓慢传送到出料口,移动过程中受到腔体内低温持续烘焙,固体物料中的残留废液被蒸发出来,集气模块通过负压吸取这些气体然后通过排气管道传送到集气系统中,最后收集被低温烘焙单元排出的固体物料。Step 4: The solid material is slowly conveyed to the discharge port by the conveyor belt in the low-temperature baking unit. During the moving process, it is continuously baked at low temperature in the cavity, and the residual waste liquid in the solid material is evaporated. The gas collection module absorbs these gases through negative pressure. Then it is sent to the gas collection system through the exhaust pipe, and finally the solid material discharged by the low-temperature roasting unit is collected.

本发明的积极进步效果在于:本发明提供的废旧软包锂电池直接带电破碎设备及方法有如下优点:The positive and progressive effect of the present invention is that the waste soft-pack lithium battery direct charged crushing equipment and method provided by the present invention have the following advantages:

1、本发明送料单元采用裙边挡板输送带,防止电池包堆积,确保均匀送料。1. The feeding unit of the present invention adopts the skirt baffle conveyor belt to prevent the accumulation of battery packs and ensure uniform feeding.

2、本发明采用立体空间布局的液氮喷淋方法,有效避免破碎过程中氧气与活性物质的接触,能够大幅降低破碎过程中设备及电池的温度。2. The present invention adopts the liquid nitrogen spray method in three-dimensional space layout, which can effectively avoid the contact between oxygen and active substances during the crushing process, and can greatly reduce the temperature of equipment and batteries during the crushing process.

3、本发明使用低温烘焙单元将破碎后电池材料中有机废液被充分收集。3. The invention uses a low-temperature baking unit to fully collect the organic waste liquid in the crushed battery material.

4、本发明采用传感器智能化反馈机制,使本装置更加自动化,降低了劳动强度,提升了系统设备的安全性,更具实用性。4. The present invention adopts an intelligent sensor feedback mechanism, which makes the device more automatic, reduces labor intensity, improves the safety of system equipment, and is more practical.

附图说明Description of drawings

图1为本发明的软包锂电池带电破碎设备的整体示意图。Fig. 1 is an overall schematic diagram of the charged crushing equipment for soft-pack lithium batteries of the present invention.

图2为本发明的软包锂电池带电破碎设备的正面立体结构示意图。Fig. 2 is a schematic diagram of the front three-dimensional structure of the charged crushing equipment for the soft-pack lithium battery of the present invention.

图3-1为本发明的软包锂电池带电破碎设备的剖面图。Figure 3-1 is a cross-sectional view of the charged crushing equipment for soft-pack lithium batteries of the present invention.

图3-2为图3-1的局部放大图。Figure 3-2 is a partially enlarged view of Figure 3-1.

图4为本发明的软包锂电池带电破碎设备的的定向结构示意图。Fig. 4 is a schematic diagram of the directional structure of the charged crushing equipment for soft-pack lithium batteries of the present invention.

图5为本发明的软包锂电池带电破碎单元主要连接结构示意图。Fig. 5 is a schematic diagram of the main connection structure of the charged crushing unit of the pouch lithium battery of the present invention.

下面是本发明中标号对应的名称:Below is the name corresponding to the label in the present invention:

图中标号:1—送料单元,2—破碎单元,3—筛分单元,4—集液单元,5—低温烘焙单元,6—破碎保护系统,7—集气系统,101—送料漏斗,102—送料漏斗支架,103—裙边挡板输送带,104—输送机支架,201—进料漏斗,202—破碎机,203—破碎机支架,204—刚性法兰连接,205—柔性金属管,204—维修门,301—筛网,302—振动电机,303—弹簧组,401—集液器,402—集液器支架,501—烘焙腔体,502—集气模块,503—低温加热模块,504—低温烘焙单元支架,505—柔性金属管,601—喷淋嘴,602—液氮传输管,603—气泵,604—液氮储存罐,605—温度传感器,606—氧含量传感器,607—报警装置,608—启停控制器,701—负压排气口,702—排气管,703—真空泵。Numbers in the figure: 1—feeding unit, 2—crushing unit, 3—sieving unit, 4—liquid collection unit, 5—low temperature baking unit, 6—crushing protection system, 7—gas collection system, 101—feeding funnel, 102 —Feeding funnel bracket, 103—skirt baffle conveyor belt, 104—conveyor bracket, 201—feed funnel, 202—crusher, 203—crusher bracket, 204—rigid flange connection, 205—flexible metal pipe, 204—maintenance door, 301—screen, 302—vibration motor, 303—spring set, 401—liquid collector, 402—liquid collector bracket, 501—baking cavity, 502—gas collection module, 503—low temperature heating module , 504—low temperature baking unit bracket, 505—flexible metal pipe, 601—spray nozzle, 602—liquid nitrogen transfer pipe, 603—air pump, 604—liquid nitrogen storage tank, 605—temperature sensor, 606—oxygen content sensor, 607 —alarm device, 608—start-stop controller, 701—negative pressure exhaust port, 702—exhaust pipe, 703—vacuum pump.

具体实施方式Detailed ways

下面结合附图给出本发明较佳实施例,以详细说明本发明的技术方案。The preferred embodiments of the present invention are given below in conjunction with the accompanying drawings to describe the technical solution of the present invention in detail.

图1为本发明的软包锂电池带电破碎设备的整体示意图;图2为本发明的软包锂电池带电破碎设备的正面立体结构示意图;如图1-2所示:本发明提供的废旧软包锂电池直接带电破碎方法及设备,包括送料单元(1)、破碎单元(2)、筛分单元(3)、集液单元(4)、低温烘焙单元(5)、破碎保护系统(6)和集气系统(7)。Fig. 1 is the overall schematic diagram of the charged crushing equipment for soft-packed lithium batteries of the present invention; Fig. 2 is a schematic diagram of the front three-dimensional structure of the charged crushing equipment for soft-packed lithium batteries of the present invention; Lithium-packed battery directly charged crushing method and equipment, including feeding unit (1), crushing unit (2), screening unit (3), liquid collection unit (4), low-temperature baking unit (5), crushing protection system (6) and gas collection system (7).

作为一种优选的技术方案,本发明中的送料单元(1)包括送料漏斗(101)、送料漏斗支架(102)、裙边挡板输送带(103)、输送机支架(104)。软包锂电池通过送料漏斗落到裙边挡板传送带的底部块状传送区域中,输送机匀速将软包电池输送到输送机顶部旁的进料漏斗中。As a preferred technical solution, the feeding unit (1) in the present invention includes a feeding funnel (101), a feeding funnel support (102), a skirt baffle conveyor belt (103), and a conveyor support (104). The soft pack lithium battery falls into the bottom block conveying area of the skirt baffle conveyor belt through the feeding funnel, and the conveyor transports the soft pack battery to the feeding funnel next to the top of the conveyor at a constant speed.

作为一种优选的技术方案,本发明中的破破碎单元(2)包括进料漏斗(201)、破碎机(202)、破碎机支架(203),刚性法兰连接(204)、柔性金属管(205)、维修门(206),在具体的实施过程中,破碎单元采用双轴对辊破碎机对软包电池进行快速破碎,参见图5,进料漏斗位于破碎机入口上方,进料漏斗侧边设有开口与输送机出料端相连。破碎机支架位于破碎机下方,破碎机与支架之间采用刚性法兰连接,柔性金属管将破碎机出料口与下面筛分单元连接。破碎机支架侧边设有维护维修门方便设备的后期维修维护,软包锂电池通过进料漏斗进入到双轴对辊破碎机中进行破碎,破碎后通过柔性金属管进入下一个单元。As a preferred technical solution, the crushing unit (2) in the present invention includes a feed hopper (201), a crusher (202), a crusher support (203), a rigid flange connection (204), a flexible metal pipe (205), maintenance door (206), in the specific implementation process, the crushing unit uses a double-shaft roller crusher to quickly crush the pouch battery, see Figure 5, the feeding funnel is located above the crusher inlet, and the feeding funnel An opening is provided on the side to connect with the discharge end of the conveyor. The crusher bracket is located below the crusher, the crusher and the bracket are connected by a rigid flange, and the flexible metal pipe connects the discharge port of the crusher to the screening unit below. There is a maintenance door on the side of the crusher bracket to facilitate the later maintenance of the equipment. The soft-pack lithium battery enters the double-shaft double-roller crusher through the feeding funnel for crushing, and then enters the next unit through the flexible metal tube.

作为一种优选的技术方案,本发明中的筛分单元(3)位于破碎机支架内部,其包括筛网(301)、振动电机(302)、弹簧组(303),筛网一端通过合页与破碎机支架相连,另一端与弹簧组相连,振动电机连接在筛网架上为筛网提供振动源。As a preferred technical solution, the screening unit (3) in the present invention is located inside the crusher bracket, which includes a screen (301), a vibrating motor (302), a spring set (303), and one end of the screen passes through a hinge It is connected with the bracket of the crusher, and the other end is connected with the spring group, and the vibration motor is connected with the screen frame to provide the vibration source for the screen.

作为一种优选的技术方案,本发明中的集液单元(4)包括集液器(401)和集液器支架(402),集液器支架位于破碎机支架下方,集液器固定在集液器支架上,负责收集筛分单元产生电解液。As a preferred technical solution, the liquid collection unit (4) in the present invention includes a liquid collector (401) and a liquid collector bracket (402), the liquid collector bracket is located below the crusher bracket, and the liquid collector is fixed on the On the liquid device bracket, it is responsible for collecting the electrolyte produced by the screening unit.

作为一种优选的技术方案,本发明中的低温烘焙单元(5)包括烘焙腔体(501)、集气模块(502)、低温加热模块(503)、低温烘焙单元支架(504)、柔性金属管(505),所述烘焙腔体采用柔性金属管与筛分单元连接,其内部有带式输送机输送固体物料,腔体内侧壁均匀布有加热条,腔体顶部等距布置一排集气口。固体物料从筛分单元进入本单元后,输送机缓慢将其运送到出料口,运送过程中,固体物料受到烘焙腔体中低温加热模块的持续烘焙,固体物料中的残留电解液被蒸发,集气模块收集被蒸发的电解液并通过管道传送到集气系统中。As a preferred technical solution, the low-temperature baking unit (5) in the present invention includes a baking cavity (501), a gas collection module (502), a low-temperature heating module (503), a low-temperature baking unit bracket (504), a flexible metal tube (505), the baking cavity is connected with the screening unit by a flexible metal tube, inside which there is a belt conveyor to transport solid materials, the inner wall of the cavity is evenly distributed with heating strips, and a row of collectors is arranged equidistantly on the top of the cavity breath. After the solid material enters the unit from the screening unit, the conveyor slowly transports it to the discharge port. During the transportation, the solid material is continuously baked by the low-temperature heating module in the baking cavity, and the residual electrolyte in the solid material is evaporated. The gas collection module collects the evaporated electrolyte and sends it to the gas collection system through pipelines.

图3-1为本发明的软包锂电池带电破碎设备的剖面图,图3-2为图3-1的局部放大图。图4为本发明的软包锂电池带电破碎设备的定向结构示意图;如上述图所示:本发明中的破碎保护系统(6)包括喷淋嘴(601)、液氮传输管(602)、气泵(603)、液氮储存罐(604)、温度传感器(605)、氧含量传感器(606)、报警装置(607)、启停控制器(608)。液氮储存罐位于整个设备侧部,气泵和液氮传输管把储存罐中液氮运送到喷淋嘴中,喷淋嘴位于进料漏斗的顶端侧壁,通过控制气泵可以控制液氮喷淋量。在进料漏斗内壁距破碎机入口下沿10cm处装有温度传感器和氧含量传感器,温度传感器和氧含量传感器分别检测装置中的温度和氧含量,传感器的数据实时传输到报警装置和启停控制器。所述的传感器、报警装置和启停控制器由单片机控制板联合控制,当传感器检测到异常,报警器和启停控制器就会做出响应。Fig. 3-1 is a cross-sectional view of the charged crushing equipment for soft-pack lithium batteries of the present invention, and Fig. 3-2 is a partial enlarged view of Fig. 3-1. Figure 4 is a schematic diagram of the directional structure of the charged crushing equipment for soft-packed lithium batteries of the present invention; Air pump (603), liquid nitrogen storage tank (604), temperature sensor (605), oxygen content sensor (606), alarm device (607), start-stop controller (608). The liquid nitrogen storage tank is located on the side of the entire equipment. The air pump and liquid nitrogen transfer pipe transport the liquid nitrogen in the storage tank to the spray nozzle. The spray nozzle is located on the top side wall of the feed funnel. The liquid nitrogen spray can be controlled by controlling the air pump quantity. A temperature sensor and an oxygen content sensor are installed on the inner wall of the feed funnel 10cm below the crusher inlet. The temperature sensor and the oxygen content sensor detect the temperature and oxygen content in the device respectively, and the data of the sensor are transmitted to the alarm device and start-stop control in real time. device. The sensor, the alarm device and the start-stop controller are jointly controlled by the single-chip microcomputer control board. When the sensor detects an abnormality, the alarm and the start-stop controller will respond.

本发明中的喷淋嘴采用角度可调节的喷头,角度范围0~180°,喷头孔径3~5mm。四组喷淋嘴对称分布于进料漏斗顶部的侧壁和筛分单元侧壁上,进料漏斗侧壁上的两组喷淋嘴可以在破碎机上方形成交叉的液氮低温、无氧保护区域;筛分单元侧壁上的两组喷淋嘴有两个作用:一是液氮汽化往上运动,有利于破碎机刀具的冷却;二是消除振动筛的不安全因素,确保破碎机输出物料的安全性。The spray nozzle in the present invention adopts a nozzle with an adjustable angle, the angle range is 0-180°, and the aperture of the nozzle is 3-5mm. Four sets of spray nozzles are symmetrically distributed on the side wall at the top of the feed funnel and the side wall of the screening unit. The two sets of spray nozzles on the side wall of the feed funnel can form a cross liquid nitrogen low temperature and anaerobic protection above the crusher. area; the two sets of spray nozzles on the side wall of the screening unit have two functions: one is that the liquid nitrogen vaporizes and moves upwards, which is beneficial to the cooling of the crusher cutter; the other is to eliminate the unsafe factors of the vibrating screen and ensure the output of the crusher. Material safety.

作为一种优选的技术方案,温度和氧含量传感器在检测到温度或者氧含量异常时会发送信号给报警器和启停控制器,报警器报警,若持续时间超过10s则启停控制器停止送料单元和破碎单元的运行,待报警解除后再重新启动。As a preferred technical solution, the temperature and oxygen content sensor will send a signal to the alarm and the start-stop controller when detecting abnormal temperature or oxygen content, the alarm will alarm, and if the duration exceeds 10s, the start-stop controller will stop feeding The operation of the unit and the crushing unit will be restarted after the alarm is released.

作为一种优选的技术方案,集气系统(7)包括负压排气口(701)、排气管(702)、真空泵(703),负压排气口位于破碎机支架靠近破碎机出口的侧壁上,负压排气口与排气管连接,排气管再与真空泵连接。烘焙过程产生气体进入集气系统(7),集气系统还为破碎过程提供负压排气。As a preferred technical solution, the gas collection system (7) includes a negative pressure exhaust port (701), an exhaust pipe (702), and a vacuum pump (703). On the side wall, the negative pressure exhaust port is connected with the exhaust pipe, and the exhaust pipe is connected with the vacuum pump. The gas generated during the roasting process enters the gas collection system (7), and the gas collection system also provides negative pressure exhaust for the crushing process.

本发明中的方法基于装置,带电破碎方法包括如下步骤:The method in the present invention is based on the device, and the charged crushing method includes the following steps:

第一步:将软包锂电池送料到送料单元,裙边挡板输送带将软包锂电池匀速送到破碎单元;The first step: Feed the soft-pack lithium battery to the feeding unit, and the skirt baffle conveyor belt will send the soft-pack lithium battery to the crushing unit at a uniform speed;

第二步,软包电池进入破碎机中进行破碎,破碎过程立体布局的喷淋嘴持续喷出液氮保证破碎过程安全进行;In the second step, the pouch battery enters the crusher for crushing, and the three-dimensional spray nozzles in the crushing process continuously spray liquid nitrogen to ensure the safety of the crushing process;

第三步:破碎后物料进入筛分单元,振动筛将固体物料和电解液筛分开,电解液漏入集液单元中,而固体物料进入低温烘焙单元;Step 3: The crushed material enters the screening unit, the vibrating screen separates the solid material and the electrolyte, the electrolyte leaks into the liquid collection unit, and the solid material enters the low-temperature baking unit;

第四步:固体物料在低温烘焙单元中被传送带缓慢传送到出料口,移动过程中受到腔体内低温持续烘焙,固体物料中的残留废液被蒸发出来,集气模块通过负压吸取这些气体然后通过排气管道传送到集气系统中,最后收集被低温烘焙单元排出的固体物料。Step 4: The solid material is slowly conveyed to the discharge port by the conveyor belt in the low-temperature baking unit. During the moving process, it is continuously baked at low temperature in the cavity, and the residual waste liquid in the solid material is evaporated. The gas collection module absorbs these gases through negative pressure. Then it is sent to the gas collection system through the exhaust pipe, and finally the solid material discharged by the low-temperature roasting unit is collected.

下面是一些具体的运用的例子:Here are some specific examples of usage:

实施例1(以华为8.4英寸平板电脑软包电池为处理对象)Example 1 (taking Huawei 8.4-inch tablet soft-pack battery as the processing object)

将华为废旧8.4英寸平板的6100mAh软包电池放置到送料漏斗(101)中,电池通过裙边挡板输送带(103)以0.4m/s速度均匀送到进料漏斗(201),然后电池落入破碎机(202)中,破碎机上方对称喷淋嘴(601)喷洒液氮为破碎过程提供保护,负压排气口(701)持续抽取气体,温度传感器(605)和氧含量传感器(606)检测破碎过程的温度和氧含量,破碎后物料落到筛网(301)上,通过振动电机(302)初步将固体物料和废液分开,废液落入集液器(401)中进行收集,固体物料随着倾斜的振动筛抖动到低温烘焙单元(5),固体物料通过烘焙腔体中的以0.1m/s速度运行的传送带到最终出料口,传送过程中通过低温加热模块(503)控制烘焙腔体为50℃左右,蒸发出的气体通过集气模块(502)收集起来方便后续集中处理,单个电池通过整个设备时间在1min左右,该设备一个小时可以处理大约62kg的软包电池。Put the 6100mAh pouch battery of Huawei's used 8.4-inch tablet into the feeding funnel (101), and the battery is evenly sent to the feeding funnel (201) at a speed of 0.4m/s through the skirt baffle conveyor belt (103), and then the battery falls into the crusher (202), the symmetrical spray nozzle (601) above the crusher sprays liquid nitrogen to provide protection for the crushing process, the negative pressure exhaust port (701) continuously extracts gas, the temperature sensor (605) and the oxygen content sensor (606 ) to detect the temperature and oxygen content in the crushing process, the crushed material falls on the screen (301), the solid material and the waste liquid are preliminarily separated by the vibrating motor (302), and the waste liquid falls into the liquid collector (401) for collection , the solid material shakes to the low-temperature baking unit (5) with the inclined vibrating screen, and the solid material passes through the conveyor running at a speed of 0.1m/s in the baking cavity to the final discharge port, and passes through the low-temperature heating module (503 ) to control the baking chamber at about 50°C, and the evaporated gas is collected through the gas collection module (502) to facilitate subsequent centralized processing. It takes about 1 minute for a single battery to pass through the entire device, and the device can process about 62kg of pouch batteries in one hour .

实施例2(以小米10.1英寸平板电脑软包电池为处理对象)Embodiment 2 (taking the soft pack battery of Xiaomi 10.1-inch tablet computer as the processing object)

将小米废旧10.1英寸平板的8620mAh软包电池放置到送料漏斗(101)中,电池通过裙边挡板输送带(103)以0.4m/s速度均匀送到进料漏斗(201),然后电池落入破碎机(202)中,破碎机上方对称喷淋嘴(601)喷洒液氮为破碎过程提供保护,负压排气口(701)持续抽取气体,温度传感器(605)和氧含量传感器(606)检测破碎过程的温度和氧含量,破碎后物料落到筛网(301)上,通过振动电机(302)初步将固体物料和废液分开,废液落入集液器(401)中进行收集,固体物料随着倾斜的振动筛抖动到低温烘焙单元(5),固体物料通过烘焙腔体中的以0.1m/s速度运行的传送带到最终出料口,传送过程中通过低温加热模块(503)控制烘焙腔体为50℃左右,蒸发出的气体通过集气模块(502)收集起来方便后续集中处理,单个电池通过整个设备时间在1min左右,该设备一个小时可以处理大约83kg的软包电池。Put the 8620mAh pouch battery of Xiaomi’s waste 10.1-inch tablet into the feeding funnel (101), and the battery is evenly sent to the feeding funnel (201) through the skirt baffle conveyor belt (103) at a speed of 0.4m/s, and then the battery falls into the crusher (202), the symmetrical spray nozzle (601) above the crusher sprays liquid nitrogen to provide protection for the crushing process, the negative pressure exhaust port (701) continuously extracts gas, the temperature sensor (605) and the oxygen content sensor (606 ) to detect the temperature and oxygen content in the crushing process, the crushed material falls on the screen (301), the solid material and the waste liquid are preliminarily separated by the vibrating motor (302), and the waste liquid falls into the liquid collector (401) for collection , the solid material shakes to the low-temperature baking unit (5) with the inclined vibrating screen, and the solid material passes through the conveyor running at a speed of 0.1m/s in the baking cavity to the final discharge port, and passes through the low-temperature heating module (503 ) to control the baking chamber at about 50°C, and the evaporated gas is collected through the gas collection module (502) to facilitate subsequent centralized processing. It takes about 1 minute for a single battery to pass through the entire equipment, and the equipment can process about 83kg of pouch batteries in one hour .

实施例3(以微软13英寸平板电脑软包电池为处理对象)Embodiment 3 (taking Microsoft's 13-inch tablet computer soft pack battery as the processing object)

将微软废旧13英寸平板的50.2Wh软包电池放置到送料漏斗(101)中,电池通过裙边挡板输送带(103)以0.4m/s速度均匀送到进料漏斗(201),然后电池落入破碎机(202)中,破碎机上方对称喷淋嘴(601)喷洒液氮为破碎过程提供保护,负压排气口(701)持续抽取气体,温度传感器(605)和氧含量传感器(606)检测破碎过程的温度和氧含量,破碎后物料落到筛网(301)上,通过振动电机(302)初步将固体物料和废液分开,废液落入集液器(401)中进行收集,固体物料随着倾斜的振动筛抖动到低温烘焙单元(5),固体物料通过烘焙腔体中的以0.1m/s速度运行的传送带到最终出料口,传送过程中通过低温加热模块(503)控制烘焙腔体为50℃左右,蒸发出的气体通过集气模块(502)收集起来方便后续集中处理,单个电池通过整个设备时间在1min左右,该设备一个小时可以处理大约97kg的软包电池。Place the 50.2Wh pouch battery of Microsoft's waste 13-inch tablet into the feeding funnel (101), and the battery is evenly sent to the feeding funnel (201) at a speed of 0.4m/s through the skirt baffle conveyor belt (103), and then the battery Falling into the crusher (202), the symmetrical spray nozzle (601) above the crusher sprays liquid nitrogen to provide protection for the crushing process, the negative pressure exhaust port (701) continuously extracts gas, the temperature sensor (605) and the oxygen content sensor ( 606) Detect the temperature and oxygen content of the crushing process. After crushing, the material falls on the screen (301), and the solid material and waste liquid are initially separated by the vibrating motor (302), and the waste liquid falls into the liquid collector (401) for further processing. Collected, the solid material shakes to the low-temperature baking unit (5) with the inclined vibrating screen, and the solid material passes through the conveyor running at a speed of 0.1m/s in the baking cavity to the final discharge port, and passes through the low-temperature heating module ( 503) Control the temperature of the baking cavity at about 50°C, and the evaporated gas is collected by the gas collection module (502) to facilitate subsequent centralized processing. It takes about 1 minute for a single battery to pass through the entire device, and the device can process about 97kg of soft bags in one hour Battery.

实施例4(以苹果11英寸平板电脑软包电池为处理对象)Embodiment 4 (taking apple's 11-inch tablet computer soft pack battery as processing object)

将苹果废旧11英寸平板的28.65Wh软包电池放置到送料漏斗(101)中,电池通过裙边挡板输送带(103)以0.4m/s速度均匀送到进料漏斗(201),然后电池落入破碎机(202)中,破碎机上方对称喷淋嘴(601)喷洒液氮为破碎过程提供保护,负压排气口(701)持续抽取气体,温度传感器(605)和氧含量传感器(606)检测破碎过程的温度和氧含量,破碎后物料落到筛网(301)上,通过振动电机(302)初步将固体物料和废液分开,废液落入集液器(401)中进行收集,固体物料随着倾斜的振动筛抖动到低温烘焙单元(5),固体物料通过烘焙腔体中的以0.1m/s速度运行的传送带到最终出料口,传送过程中通过低温加热模块(503)控制烘焙腔体为50℃左右,蒸发出的气体通过集气模块(502)收集起来方便后续集中处理,单个电池通过整个设备时间在1min左右,该设备一个小时可以处理大约92kg的软包电池。Put the 28.65Wh pouch battery of Apple’s waste 11-inch tablet into the feeding funnel (101), and the battery is evenly sent to the feeding funnel (201) at a speed of 0.4m/s through the skirt baffle conveyor belt (103), and then the battery Falling into the crusher (202), the symmetrical spray nozzle (601) above the crusher sprays liquid nitrogen to provide protection for the crushing process, the negative pressure exhaust port (701) continuously extracts gas, the temperature sensor (605) and the oxygen content sensor ( 606) Detect the temperature and oxygen content of the crushing process. After crushing, the material falls on the screen (301), and the solid material and waste liquid are initially separated by the vibrating motor (302), and the waste liquid falls into the liquid collector (401) for further processing. Collected, the solid material shakes to the low-temperature baking unit (5) with the inclined vibrating screen, and the solid material passes through the conveyor running at a speed of 0.1m/s in the baking cavity to the final discharge port, and passes through the low-temperature heating module ( 503) Control the temperature of the baking cavity at about 50°C, and the evaporated gas is collected through the gas collection module (502) to facilitate subsequent centralized processing. It takes about 1 minute for a single battery to pass through the entire device, and the device can process about 92kg of soft bags in one hour Battery.

实施例5(以低于4200mAh的各种软包电池混合物为处理对象)Embodiment 5 (with various pouch battery mixtures lower than 4200mAh as processing object)

将混合软包电池放置到送料漏斗(101)中,电池通过裙边挡板输送带(103)以0.4m/s速度均匀送到进料漏斗(201),然后电池落入破碎机(202)中,破碎机上方对称喷淋嘴(601)喷洒液氮为破碎过程提供保护,负压排气口(701)持续抽取气体,温度传感器(605)和氧含量传感器(606)检测破碎过程的温度和氧含量,破碎后物料落到筛网(301)上,通过振动电机(302)初步将固体物料和废液分开,废液落入集液器(401)中进行收集,固体物料随着倾斜的振动筛抖动到低温烘焙单元(5),固体物料通过烘焙腔体中的以0.1m/s速度运行的传送带到最终出料口,传送过程中通过低温加热模块(503)控制烘焙腔体为50℃左右,蒸发出的气体通过集气模块(502)收集起来方便后续集中处理,单个电池通过整个设备时间在1min左右,该设备一个小时可以处理大约126kg的软包电池。Put the mixed pouch battery into the feeding hopper (101), and the battery is evenly sent to the feeding hopper (201) through the skirt baffle conveyor belt (103) at a speed of 0.4m/s, and then the battery falls into the crusher (202) Among them, the symmetrical spray nozzle (601) above the crusher sprays liquid nitrogen to protect the crushing process, the negative pressure exhaust port (701) continuously draws gas, the temperature sensor (605) and the oxygen content sensor (606) detect the temperature of the crushing process and oxygen content, the crushed material falls on the screen (301), and the solid material and waste liquid are initially separated by the vibrating motor (302), and the waste liquid falls into the liquid collector (401) for collection, and the solid material The vibrating screen shakes to the low-temperature baking unit (5), and the solid material is brought to the final discharge port through the conveyor running at a speed of 0.1m/s in the baking cavity. During the transmission process, the low-temperature heating module (503) controls the baking cavity to be At about 50°C, the evaporated gas is collected by the gas collection module (502) for subsequent centralized processing. It takes about 1 minute for a single battery to pass through the entire device, and the device can process about 126kg of pouch batteries in one hour.

实施例1至实施例5实验结果如下表所示:Embodiment 1 to embodiment 5 experimental results are shown in the table below:

Figure BDA0003753081750000121
Figure BDA0003753081750000121

综合上述实施例,本方案采用立体布局液氮保护、负压排气、振动筛筛分、智能传感器反馈和低温烘焙等技术结合的方法,能够很好的实现废旧软包电池的直接带电破碎,破碎效果强、适应性强,整个设备采用自动化设计以及智能反馈系统,极大地提高了破碎效率及安全性。Based on the above-mentioned embodiments, this solution adopts the combination of technologies such as three-dimensional layout liquid nitrogen protection, negative pressure exhaust, vibrating screen screening, intelligent sensor feedback and low-temperature baking, which can well realize the direct charged crushing of waste soft pack batteries. The crushing effect is strong and the adaptability is strong. The whole equipment adopts automatic design and intelligent feedback system, which greatly improves the crushing efficiency and safety.

以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的只是说明本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内,本发明要求保护范围由所附的权利要求书及其等效物界定。The basic principles and main features of the present invention and the advantages of the present invention have been shown and described above. Those skilled in the industry should understand that the present invention is not limited by the above-mentioned embodiments. What are described in the above-mentioned embodiments and the description only illustrate the principle of the present invention. Without departing from the spirit and scope of the present invention, the present invention will also have Various changes and improvements fall within the scope of the claimed invention, which is defined by the appended claims and their equivalents.

Claims (10)

1. The utility model provides a direct electrified crushing equipment of old and useless soft packet of lithium cell, the direct electrified crushing equipment of old and useless soft packet of lithium cell is used for broken old and useless soft packet of lithium cell, its characterized in that: the direct electrified crushing equipment of soft packet of lithium cell of old and useless includes:
the device comprises a feeding unit (1), a crushing unit (2), a screening unit (3), a liquid collecting unit (4), a low-temperature baking unit (5), a crushing protection system (6) and a gas collecting system (7);
the waste soft package lithium battery sequentially enters a crushing unit (2) and a screening unit (3) through a feeding unit (1), solid discharged from the screening unit (3) enters a low-temperature baking unit (5), liquid enters a liquid collecting unit (4), and gas enters a gas collecting system (7);
feeding unit (1): the feeding unit (1) feeds the soft package lithium battery into the crushing unit (2);
crushing unit (2): the crushing unit (2) is used for crushing the soft package lithium battery sent by the feeding unit (1);
a screening unit (3): the screening unit (3) uses a vibrating screen to separate the battery solid materials and the crushed waste liquid generated in the crushing process of the crushing unit (2);
liquid collecting unit (4): the liquid collecting unit (4) is positioned at the bottom of the screening unit (3) and is used for collecting liquid in the screening unit (3);
low temperature baking unit (5): the low-temperature baking unit (5) is positioned at one side of the screening unit (3) and used for collecting solids in the screening unit (3); the low-temperature roasting unit (5) is used for roasting waste liquid remained in the solid material while conveying the solid material;
fragmentation protection system (6): the crushing protection system (6) is arranged on one side of the crushing unit (2) and protects materials in the crushing unit (2) from splashing; meanwhile, liquid nitrogen is used as a protective medium in the crushing protection system (6) to prevent combustion and explosion in the crushing process;
gas collection system (7): the gas collection system (7) is located on the other side of the screening unit (3) and used for collecting gas in the screening unit (3), and the gas collection system also provides negative pressure exhaust for the crushing process.
2. The waste soft-package lithium battery direct-charging crushing equipment according to claim 1, characterized in that: the feeding unit (1) comprises a feeding hopper (101), a feeding hopper bracket (102), a skirt baffle conveying belt (103) and a conveyor bracket (104); the feeding hopper (101) is fixed on a feeding hopper bracket (102), the feeding hopper bracket (102) stretches over the feeding end of the conveying belt, the top end of the feeding hopper (101) is provided with a feeding hole, and the lower end of the feeding hopper is provided with a discharging hole; the soft-package lithium battery falls into a feeding end block-shaped conveying area of the skirt baffle conveying belt (103) through the feeding hopper (101), and the soft-package lithium battery is conveyed into the feeding hopper beside the top of the conveyor at a constant speed by the conveyor.
3. The waste soft-package lithium battery direct charged crushing equipment according to claim 1, characterized in that: the crushing unit (2) comprises a feeding funnel (201), a crusher (202), a crusher support (203), a rigid flange (204), a flexible metal pipe (205) and a maintenance door (206), wherein the feeding funnel (201) is positioned above the crusher (202), and an opening is formed in the side edge of the feeding funnel (201) and connected with the discharge end of the feeding unit (1); the crusher support (203) is positioned below the crusher, and the crusher (202) is connected with the crusher support (203) by a rigid flange (204); breaker support (203) side is equipped with maintenance door (206) of maintaining, and soft packet of lithium cell enters into through feed hopper (201) breaker (202) in carry out the breakage.
4. The waste soft-package lithium battery direct charged crushing equipment according to claim 1, characterized in that: screening unit (3) are located inside breaker support (203), and it includes screen cloth (301), vibrating motor (302), spring assembly (303), the one end of screen cloth (301) is passed through the hinge and is linked to each other with the breaker support, and the other end links to each other with the spring assembly, and the spring in the spring assembly is vertical to be fixed in the breaker support, and vibrating motor connects and provides the vibration source for the screen cloth on the screen frame, and the screening unit is sieved electrolyte and broken material and is separated.
5. The waste soft-package lithium battery direct charged crushing equipment according to claim 1, characterized in that: the liquid collecting unit (4) comprises a liquid collector (401) and a liquid collector support (402), the liquid collector support (402) is located below the crusher support (203), the liquid collector (401) is fixed in the liquid collector support (402) in a funnel shape, and electrolyte generated by the screening unit is collected by the liquid collector (401).
6. The waste soft-package lithium battery direct charged crushing equipment according to claim 1, characterized in that: the low-temperature baking unit (5) comprises a baking cavity (501), a gas collecting module (502), a low-temperature heating module (503), a low-temperature baking unit support (504) and a flexible metal pipe (505), the baking cavity is connected with a screening unit through the flexible metal pipe, a belt conveyor is arranged in the baking cavity to convey solid materials, heating strips are evenly distributed on the inner side wall of the cavity, a row of gas collecting ports are arranged at the top of the cavity at equal intervals, the solid materials are conveyed to a discharge port slowly by the conveyor after entering the baking cavity from the screening unit, in the conveying process, the solid materials are continuously baked by the low-temperature heating module in the baking cavity, residual electrolyte in the solid materials is evaporated, and the gas collecting module collects the evaporated electrolyte and conveys the electrolyte into a gas collecting system through a pipeline.
7. The waste soft-package lithium battery direct charged crushing equipment according to claim 1, characterized in that: the crushing protection system (6) is a crushing protection system (6) which uses liquid nitrogen as a protection medium to prevent combustion and explosion in the crushing process; the crushing protection system (6) comprises a spray nozzle (601), a liquid nitrogen transmission pipe (602), an air pump (603), a liquid nitrogen storage tank (604), a temperature sensor (605), an oxygen content sensor (606), an alarm device (607) and a start-stop controller (608); the liquid nitrogen storage tank is positioned on the side part of the whole device, the air pump and the liquid nitrogen transmission pipe convey the liquid nitrogen in the storage tank to the spray nozzle, the spray nozzle is positioned on the side wall of the top end of the feeding hopper, and the spray amount of the liquid nitrogen can be controlled by controlling the air pump; a temperature sensor and an oxygen content sensor are arranged on the side wall of the feeding hopper close to the inlet of the crusher, the temperature sensor and the oxygen content sensor respectively detect the temperature and the oxygen content in the device, and the sensors are connected with an alarm device and a start-stop controller.
8. The waste soft-package lithium battery direct-charging crushing equipment according to claim 7, characterized in that: the spray nozzles are spray heads with adjustable angles, and are symmetrically distributed on the inner wall of the top end of the feeding hopper, so that crossed liquid nitrogen low-temperature and anaerobic protection areas are formed above the crusher.
9. The waste soft-package lithium battery direct-charging crushing equipment according to claim 1, characterized in that: the gas collection system (7) comprises a negative pressure gas exhaust port (701), an exhaust pipe (702) and an air pump (703), the negative pressure gas exhaust port is located on the side wall of the screening unit, the exhaust pipe is respectively connected with the negative pressure gas exhaust port in the screening unit and the gas collection module of the low-temperature baking unit, and the vacuum pump collects waste gas generated in the process of processing the soft package lithium battery by the whole equipment through the exhaust pipe.
10. A waste soft package lithium battery direct charged crushing method based on the equipment in claims 1-9, which is characterized in that: the charged crushing method comprises the following steps:
the first step is as follows: feeding the soft package lithium batteries to a feeding unit, and conveying the soft package lithium batteries to a crushing unit at a constant speed by a skirt baffle conveyer belt;
secondly, the soft package battery enters a crusher to be crushed, and liquid nitrogen is continuously sprayed out of a spray nozzle in the three-dimensional layout in the crushing process to ensure that the crushing process is safely carried out;
the third step: the crushed materials enter a screening unit, a vibrating screen screens solid materials from electrolyte, the electrolyte leaks into a liquid collecting unit, and the solid materials enter a low-temperature baking unit;
the fourth step: the solid material is slowly conveyed to the discharge port by the conveyor belt in the low-temperature baking unit, the solid material is continuously baked at low temperature in the cavity in the moving process, residual waste liquid in the solid material is evaporated, the gas collection module absorbs the gas through negative pressure and then conveys the gas to the gas collection system through the exhaust pipeline, and finally the solid material discharged by the low-temperature baking unit is collected.
CN202210849953.XA 2022-07-19 2022-07-19 A kind of waste soft pack lithium battery directly charged crushing equipment and method Pending CN115254893A (en)

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Application publication date: 20221101