CN115228298A - Rolled membrane system and gas-liquid two-phase cleaning method thereof - Google Patents

Rolled membrane system and gas-liquid two-phase cleaning method thereof Download PDF

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CN115228298A
CN115228298A CN202210850930.0A CN202210850930A CN115228298A CN 115228298 A CN115228298 A CN 115228298A CN 202210850930 A CN202210850930 A CN 202210850930A CN 115228298 A CN115228298 A CN 115228298A
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washing
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water
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stage
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孙凯
黎泽华
刘牡
林晓峰
苏英强
段梦缘
朱希坤
韩慧铭
张立言
肖聪
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Greentech Environment Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

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Abstract

本发明涉及一种卷式膜系统及其气液两相清洗方法,属于水处理技术领域。该系统包括进水单元、多段卷式膜单元、液相清洗单元、气相清洗单元及用于控制各单元的控制系统;多段卷式膜单元包括一段、二段或三段卷式膜单元;液相清洗单元、气相清洗单元的出口管路分别通过支路连接各段卷式膜单元的进水端和/或末端用于实现对各段卷式膜单元的正向和/或反向的水洗和/或气洗,且各支路上设有正向进水阀、正向排水阀、反向进水阀与反向排水阀;控制系统控制各阀门的开关。该系统及方法不仅清洗效率高,减少清洗频次及延长清洗周期,而且能够针对于对最前端膜元件进行有效清洗,有利于保护膜元件的使用寿命。

Figure 202210850930

The invention relates to a roll-type membrane system and a gas-liquid two-phase cleaning method thereof, belonging to the technical field of water treatment. The system includes a water inlet unit, a multi-section rolled membrane unit, a liquid phase cleaning unit, a gas phase cleaning unit and a control system for controlling each unit; the multi-section rolled membrane unit includes a one-stage, two-stage or three-stage roll-type membrane unit; liquid The outlet pipelines of the phase cleaning unit and the gas phase cleaning unit are respectively connected to the water inlet and/or end of each section of the rolled membrane unit through a branch, so as to realize the forward and/or reverse water washing of each section of the rolled membrane unit And/or air washing, and each branch is provided with a forward water inlet valve, a forward drain valve, a reverse water inlet valve and a reverse drain valve; the control system controls the switch of each valve. The system and method not only have high cleaning efficiency, reduce the cleaning frequency and prolong the cleaning period, but also can effectively clean the front-end membrane element, which is beneficial to protect the service life of the membrane element.

Figure 202210850930

Description

卷式膜系统及其气液两相清洗方法Rolled membrane system and gas-liquid two-phase cleaning method

技术领域technical field

本发明涉及对卷式膜的清洗方法,属于水处理技术领域,具体地涉及一种卷式膜系统及其气液两相清洗方法。The invention relates to a cleaning method for a roll-type membrane, belongs to the technical field of water treatment, and in particular relates to a roll-type membrane system and a gas-liquid two-phase cleaning method thereof.

背景技术Background technique

膜分离工艺技术由于具有处理效率高、工艺流程短、易控制、使用灵活、膜分离水厂占地面积少,生产可实行自动化等特点,卷式膜特别是反渗透和纳滤可以有效去除水中的细菌病毒、无机离子和有机小分子物质等,从而获得以往传统处理工艺从未达到的、稳定可靠的洁净水质,使得卷式膜技术广泛应用于地表水处理、海水淡化、苦咸水淡化、电子及制药工业中超纯水的制造、电厂锅炉给水及制冷机循环用水的生产、以及各种废水的处理及再生回用等。其应用前景广阔,市场潜力很大。因此,卷式膜膜分离的研究和应用逐渐成为给水领域的热点,它被称为当今获得优质饮用水的重要技术之一,被称誉为“21世纪的水处理技术,是替代传统工艺的最佳选择。Membrane separation technology has the characteristics of high treatment efficiency, short process flow, easy control, flexible use, small footprint of membrane separation water plants, and automation of production. Rolled membranes, especially reverse osmosis and nanofiltration, can effectively remove water. In order to obtain stable and reliable clean water quality that has never been achieved by traditional treatment processes in the past, rolled membrane technology is widely used in surface water treatment, seawater desalination, brackish water desalination, The manufacture of ultrapure water in the electronics and pharmaceutical industries, the production of boiler feed water in power plants and the production of circulating water for refrigerators, as well as the treatment and regeneration of various waste water, etc. It has broad application prospects and great market potential. Therefore, the research and application of roll membrane separation has gradually become a hot spot in the field of water supply. It is known as one of the important technologies for obtaining high-quality drinking water today, and is known as "water treatment technology in the 21st century. It is the best alternative to traditional processes." best choice.

卷式膜的膜污染和劣化始终是制约该技术发展的瓶颈之一。在卷式膜膜系统运行过程中,卷式膜膜表面会由于原水中悬浮物、胶状物、有机物、微生物等污染物质的存在及膜分离过程中对难溶物质的浓缩而产生的沉积,进而形成对膜元件的污染。这些污染中最常见的是碳酸钙沉淀、硫酸钙沉淀、金属(铁、锰、铜、镍、铝等)氧化物沉淀、硅沉积物、无机或有机沉积混合物、NOM天然有机物质、合成有机物(如:阻垢剂/分散剂,阳离子聚合电解质)、微生物(藻类、霉菌、真菌)等污染。根据上述污染物种类,膜污染可总结为由以下过程引起:(1)无机物的沉积;(2)有机分子的吸附;(3)颗粒物的沉积;(4)微生物的黏附及生长。膜污染最终造成的结果是:在正常压力下,卷式膜产水量降至正常值的85%以下,或出水导电率增加15%以上,卷式膜各段间压差增加明显。膜污染给系统带来的危害根据污染程度不同危害程度也不同,在污染较轻时,系统整体运行变化不明显,对出水等影响不是很大,轻度污染在线清洗便可;而重度污染则对系统影响甚大,不仅造成进水压力显著上升系统能耗明显增加,还会严重影响系统的产水量、产水水质;严重时会导致无法通过清洗来恢复膜的过滤性能从而使膜元件提前报废,极大地增加了卷式膜系统的使用成本。Membrane fouling and deterioration of rolled membranes has always been one of the bottlenecks restricting the development of this technology. During the operation of the roll membrane system, the surface of the roll membrane will be deposited due to the presence of pollutants such as suspended solids, colloids, organic matter, microorganisms and other pollutants in the raw water and the concentration of insoluble substances during the membrane separation process. In turn, contamination of the membrane element is formed. The most common of these contaminations are calcium carbonate precipitation, calcium sulfate precipitation, metal (iron, manganese, copper, nickel, aluminum, etc.) oxide precipitation, silicon deposits, inorganic or organic sediment mixtures, NOM natural organic matter, synthetic organic matter ( Such as: scale inhibitor/dispersant, cationic polyelectrolyte), microorganism (algae, mold, fungus) and other pollution. According to the types of pollutants mentioned above, membrane fouling can be summarized as caused by the following processes: (1) deposition of inorganic substances; (2) adsorption of organic molecules; (3) deposition of particulate matter; (4) adhesion and growth of microorganisms. The final result of membrane fouling is: under normal pressure, the water output of the rolled membrane drops below 85% of the normal value, or the effluent conductivity increases by more than 15%, and the pressure difference between the sections of the rolled membrane increases significantly. The harm caused by membrane pollution to the system varies according to the degree of pollution. When the pollution is relatively light, the overall operation of the system does not change significantly, and the impact on the effluent is not very large. The mild pollution can be cleaned online; It has a great impact on the system, not only causing a significant increase in the water inlet pressure, and a significant increase in the energy consumption of the system, but also seriously affecting the water production volume and water quality of the system; in severe cases, it will lead to the inability to restore the membrane filtration performance through cleaning, thus causing the membrane elements to be scrapped in advance , which greatly increases the use cost of the roll membrane system.

目前已有的卷式膜过滤系统抗污染方法,主要包括增加超滤等预处理设备、倒向卷式膜、闭路循环卷式膜及卷式膜清洗/冲洗技术等,这些技术如增加超滤等预处理设备、倒向卷式膜、闭路循环卷式膜成本比较高,而普通膜清洗/冲洗技术对高污染水源效果有限,频繁清洗运行繁琐且运行成本也比较高。卷式膜的污染种类众多,但这些污染出现的位置不同,根据污染种类分析,胶体、金属氧化物、有机物生物污染、腐蚀损坏最易于出现在系统的最前端膜元件(第一段前端),而矿物垢、聚合硅沉淀和阻垢剂污染容易出现在末段、最末端膜元件。特别是在第一段前端的膜污染时候,由于一段和二段相连,传统的冲洗方式会造成第一段前端的污染物被冲洗进入一段末端甚至第二段膜元件的现象,严重影响了清洗效果。且传统方式采用了过多的化学清洗也会影响卷式膜元件的使用寿命或者脱盐率。The existing anti-fouling methods for roll membrane filtration systems mainly include adding pretreatment equipment such as ultrafiltration, reverse roll membrane, closed loop membrane membrane, and roll membrane cleaning/rinsing technology, etc. These technologies, such as adding ultrafiltration The cost of other pretreatment equipment, reverse roll membrane, and closed-circuit roll membrane is relatively high, while ordinary membrane cleaning/flushing technology has limited effect on highly polluted water sources, and frequent cleaning operations are cumbersome and operating costs are relatively high. There are many types of fouling of rolled membranes, but the locations of these fouling are different. According to the analysis of fouling types, colloids, metal oxides, organic biological fouling, and corrosion damage are most likely to appear in the front-end membrane element of the system (front-end of the first section), However, mineral scale, polymeric silicon precipitation and scale inhibitor fouling are likely to appear in the final and final membrane elements. Especially when the membrane at the front end of the first stage is fouled, since the first stage and the second stage are connected, the traditional flushing method will cause the pollutants at the front end of the first stage to be washed into the end of the first stage or even the second stage membrane element, which seriously affects the cleaning. Effect. In addition, excessive chemical cleaning is used in the traditional method, which will also affect the service life or the salt rejection rate of the coiled membrane element.

发明内容SUMMARY OF THE INVENTION

为解决上述技术问题,本发明公开了一种卷式膜系统及其气液两相清洗方法。该系统及方法不仅清洗效率高,减少清洗频次及延长清洗周期,而且能够针对于对最前端膜元件进行有效清洗,保护膜元件的使用寿命。In order to solve the above technical problems, the present invention discloses a roll-type membrane system and a gas-liquid two-phase cleaning method thereof. The system and method not only have high cleaning efficiency, reduce the cleaning frequency and prolong the cleaning period, but also can effectively clean the front-end membrane element and protect the service life of the membrane element.

为实现上述技术目的,本发明公开了一种卷式膜系统,它包括进水单元、多段卷式膜单元、液相清洗单元、气相清洗单元及用于控制各单元的控制系统;所述多段卷式膜单元包括一段、二段或三段的卷式反渗透膜、卷式纳滤膜或卷式超/微滤膜中任意一种;In order to achieve the above technical purpose, the present invention discloses a roll-type membrane system, which includes a water inlet unit, a multi-stage roll-type membrane unit, a liquid-phase cleaning unit, a gas-phase cleaning unit and a control system for controlling each unit; The roll-type membrane unit includes any one of one-stage, two-stage or three-stage roll-type reverse osmosis membrane, roll-type nanofiltration membrane or roll-type ultra/microfiltration membrane;

所述液相清洗单元、气相清洗单元的出口管路分别通过支路连接各段卷式膜单元的进水端和/或末端用于实现对各段卷式膜单元的正向和/或反向的水洗和/或气洗,且各支路上设有正向进水阀、正向排水阀、反向进水阀与反向排水阀;所述控制系统控制各阀门的开关和泵的启停;The outlet pipelines of the liquid-phase cleaning unit and the gas-phase cleaning unit are respectively connected to the water inlet and/or end of each section of the roll-type membrane unit through a branch, so as to realize the forward and/or reverse direction of each section of the roll-type membrane unit. Water washing and/or air washing in the forward direction, and each branch is provided with a forward water inlet valve, a forward drain valve, a reverse water inlet valve and a reverse drain valve; the control system controls the opening and closing of each valve and the start of the pump. stop;

各段卷式膜单元的末端还连接三条子路,一条子路用于排出浓水,一条子路用于排出产水,余下一条子路用于排出清洗排水。The ends of each section of the coiled membrane unit are also connected with three sub-circuits, one is used to discharge concentrated water, one is used to discharge product water, and the remaining one is used to discharge cleaning and drainage.

进一步地,反向水洗的进水压≤0.3MPa,优选≤0.2MPa,进一步优选≤0.06MPa。Further, the water inlet pressure of the reverse water washing is ≤0.3MPa, preferably ≤0.2MPa, more preferably ≤0.06MPa.

进一步地,气洗的进气压≤0.1MPa,优选≤0.08MPa。Further, the inlet pressure of the air scrubbing is less than or equal to 0.1 MPa, preferably less than or equal to 0.08 MPa.

进一步地,所述气相清洗单元包括依次连接的空压罐、调压阀与气洗阀。Further, the gas phase cleaning unit includes an air pressure tank, a pressure regulating valve and an air washing valve which are connected in sequence.

进一步地,所述液相清洗单元包括依次连接的加药装置、清洗泵和清洗过滤装置。Further, the liquid-phase cleaning unit includes a dosing device, a cleaning pump and a cleaning and filtering device connected in sequence.

进一步地,所述多段卷式膜单元包括一段卷式膜单元、二段卷式膜单元,其中,一段卷式膜单元上设有正向和/或反向气洗和/或水洗管路,所述二段卷式膜单元上设有正向气洗和/或水洗管路;所述卷式膜单元可以是卷式反渗透膜、卷式纳滤膜或者卷式超/微滤膜;Further, the multi-stage roll-type membrane unit includes a one-stage roll-type membrane unit and a two-stage roll-type membrane unit, wherein the one-stage roll-type membrane unit is provided with forward and/or reverse air washing and/or water washing pipelines, The two-stage roll-type membrane unit is provided with a forward air washing and/or water washing pipeline; the roll-type membrane unit can be a roll-type reverse osmosis membrane, a roll-type nanofiltration membrane or a roll-type ultra/microfiltration membrane;

所述清洗过滤装置、气洗阀的出口管路连接三条支路,第一条支路为一段正洗进水管路,第二条支路为二段正洗进水管路,第三条支路为一段反洗进水管路;The outlet pipelines of the cleaning and filtering device and the air washing valve are connected with three branches, the first branch is a positive washing water inlet pipeline, the second branch is a second positive washing water inlet pipeline, and the third branch It is a backwash water inlet pipeline;

所述一段正洗进水管路连接所述一段卷式膜单元上设置的一段正洗进水阀,所述一段正洗进水阀连通一段卷式膜单元进水端,一段卷式膜单元末端连接一段正洗排水阀;The first section of the positive washing water inlet pipeline is connected to a section of the forward washing water inlet valve set on the first section of the rolled membrane unit. Connect a section of positive wash drain valve;

所述二段正洗进水管路连接所述二段卷式膜单元上设置的二段正洗进水阀,所述二段正洗进水阀连通二段卷式膜单元进水端,二段卷式膜单元末端连接二段正洗排水阀;The second-stage positive-washing water inlet pipeline is connected to the second-stage positive-washing water inlet valve set on the second-stage roll-type membrane unit, and the second-stage positive-washing water inlet valve is connected to the water inlet end of the second-stage roll-type membrane unit; The end of the segmented membrane unit is connected to the second-stage positive washing drain valve;

所述一段反洗进水管路连接一段卷式膜单元上设置的一段反洗进水阀,所述一段反洗进水阀连通一段卷式膜单元末端,所述一段卷式膜单元进水端连接一段反洗排水阀;The first section of the backwash inlet pipeline is connected to a section of the backwash inlet valve set on the first section of the roll-type membrane unit, the section of the backwash inlet valve is connected to the end of the first section of the roll-type membrane unit, and the first section of the roll-type membrane unit is connected to the water inlet end. Connect a backwash drain valve;

所述一段正洗排水阀、二段正洗排水阀与一段反洗排水阀均通向清洗排水。The first-stage forward washing drain valve, the second-stage forward-washing drain valve and the first-stage backwashing drain valve all lead to cleaning drainage.

进一步地,所述气洗的气体为空气,所述水洗为采用外加水或卷式膜产水或浓水清洗,还可以向外加水中加入药剂,所述药剂包括杀菌剂、表面活性剂、酸性清洗剂、碱性清洗剂、中性清洗剂、络合物清洗剂中任意一种,只有当采用本发明设计的气液清洗模式对系统的压力降改善不佳的极少情况才会采用加药剂的化学清洗。Further, the gas of the air washing is air, and the water washing is to use externally added water or rolled membrane to produce water or concentrated water for cleaning, and can also add a medicament to the externally added water, and the medicament includes a bactericide, a surfactant, an acid Any one of cleaning agent, alkaline cleaning agent, neutral cleaning agent and complex cleaning agent, only when the gas-liquid cleaning mode designed in the present invention is used to improve the pressure drop of the system is very rare. Chemical cleaning of agents.

本发明的目的之二是公开一种上述系统对卷式膜气液两相清洗方法,清洗模式包括一段卷式膜单元正向水洗和/或气洗、一段卷式膜单元反向水洗和/或气洗、二段卷式膜单元正向水洗和/或气洗,或者任意形式的组合。The second purpose of the present invention is to disclose a gas-liquid two-phase cleaning method for the above-mentioned system to the roll-type membrane unit. Or air washing, forward water washing and/or air washing of two-stage wound membrane unit, or any combination.

进一步地,所述清洗模式为一段卷式膜单元正向水洗和/或气洗+一段卷式膜单元反向水洗和/或气洗+二段卷式膜单元正向水洗和/或气洗。Further, the cleaning mode is forward washing and/or air washing of one-stage coiled membrane unit + reverse washing and/or air washing of one-stage coiled membrane unit + forward washing and/or air washing of two-stage coiled membrane unit .

进一步地,当一段卷式膜单元、二段卷式膜单元的压力降持续在0.15MPa以上时,控制系统关闭进水单元的各泵和阀门,开启气相清洗单元和液相清洗单元的各泵和阀门,且一段反洗进水阀、一段反洗排水阀开启,一段气液反向冲洗30~120s;一段正洗进水阀、一段正洗排水阀开启,一段气液正向冲洗30~120s;二段正洗进水阀、二段正洗排水阀开启,二段水正向冲洗30~150s;且每间隔48h重复上述操作一次至一段卷式膜单元的压力降为0.01~0.10MPa,二段卷式膜单元的压力降为0.01~0.10MPa。优选的,一段气液反向冲洗50~80s,一段气液正向冲洗50~80s,二段水正向冲洗100~150s,优选每间隔48h重复上述操作一次至一段卷式膜单元的压力降为0.05~0.08MPa,二段卷式膜单元的压力降为0.01~0.02MPa。Further, when the pressure drop of the one-stage coiled membrane unit and the second-stage coiled membrane unit continues to be above 0.15MPa, the control system closes each pump and valve of the water inlet unit, and opens each pump of the gas phase cleaning unit and the liquid phase cleaning unit. and valve, and a backwash inlet valve and a backwash drain valve are opened, and a gas-liquid reverse flush is performed for 30 to 120 s; 120s; the second-stage positive washing water inlet valve and the second-stage positive washing drain valve are opened, and the second-stage water is flushing forward for 30-150s; and repeat the above operation once every 48h until the pressure drop of the first-stage coiled membrane unit is 0.01-0.10MPa , the pressure drop of the two-stage roll membrane unit is 0.01-0.10MPa. Preferably, the first stage of gas-liquid reverse flushing is performed for 50-80s, the first-stage gas-liquid forward flushing is performed for 50-80s, and the second-stage water forward flushing is performed for 100-150s. It is 0.05~0.08MPa, and the pressure drop of the two-stage roll membrane unit is 0.01~0.02MPa.

进一步地,上述的清洗方法适用于进水10000吨/天,卷式膜产水7500吨/天的水过滤系统。Further, the above cleaning method is suitable for a water filtration system with an influent water of 10,000 tons/day and a roll-type membrane water output of 7,500 tons/day.

本发明实施例提供的技术方案与现有技术相比具有如下优点:Compared with the prior art, the technical solutions provided by the embodiments of the present invention have the following advantages:

1、本发明设计的清洗方法采用气液两相清洗效率高,且可对各段卷式膜单元单独清洗或同时清洗,有利于减少清洗频次及延长清洗周期。1. The cleaning method designed in the present invention adopts gas-liquid two-phase cleaning with high efficiency, and can clean each section of the membrane unit individually or at the same time, which is beneficial to reduce the cleaning frequency and prolong the cleaning period.

2、本发明设计的清洗方法能够实现对第一段卷式膜单元中各污染物的精准清洗,避免污染物污染后续卷式膜单元,进而保护膜元件的使用寿命。2. The cleaning method designed in the present invention can realize precise cleaning of the pollutants in the first-stage roll-up membrane unit, avoid contamination of subsequent roll-up membrane units by pollutants, and thus protect the service life of the membrane elements.

3、本发明设计的清洗方法主要采用气液这种物理清洗模式,只有当该模式对系统的压力降改善不佳的极少情况下才会采用外加药剂进行化学清洗,故有利于延缓膜的化学清洗次数,最终实现保护膜元件的技术目的。3. The cleaning method designed by the present invention mainly adopts the physical cleaning mode of gas-liquid. Only when the pressure drop of the system is not improved well by this mode, the chemical cleaning will be carried out with external agents, so it is beneficial to delay the membrane degradation. The number of chemical cleanings, and finally achieve the technical purpose of protecting the membrane element.

附图说明Description of drawings

此处的附图被并入说明书中并构成本说明书的一部分,示出了符合本发明的实施例,并与说明书一起用于解释本发明的原理。The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the invention and together with the description serve to explain the principles of the invention.

为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,对于本领域普通技术人员而言,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following briefly introduces the accompanying drawings that need to be used in the description of the embodiments or the prior art. In other words, on the premise of no creative labor, other drawings can also be obtained from these drawings.

图1为本发明实施例设计的膜系统结构示意图;1 is a schematic structural diagram of a membrane system designed in an embodiment of the present invention;

图2为图1中卷式膜系统的连接关系示意图。FIG. 2 is a schematic diagram of the connection relationship of the rolled membrane system in FIG. 1 .

其中,上述附图中各编号如下:Wherein, each number in the above-mentioned accompanying drawing is as follows:

100、进水单元;100. Water inlet unit;

101、供水泵;102、进水加药设备;103、保安过滤器;104、增压泵;105、进水阀;101, water supply pump; 102, water dosing equipment; 103, security filter; 104, booster pump; 105, water inlet valve;

200、一段卷式膜单元;200-1、一段卷式膜单元进水端;200-2、一段卷式膜单元末端;200, a section of roll-type membrane unit; 200-1, the water inlet end of a section of roll-type membrane unit; 200-2, the end of a section of roll-type membrane unit;

201、一段卷式膜元件;202、一段正洗进水管路;203、一段正洗进水阀;204、一段正洗排水阀;205、一段反洗进水管路;206、一段反洗进水阀;207、一段反洗排水阀;208、一段产水阀;209、一段浓水阀;201, a section of coiled membrane element; 202, a section of positive washing water inlet pipeline; 203, a section of positive washing water inlet valve; 204, a section of positive washing drain valve; 205, a section of backwash water inlet pipeline; valve; 207, a backwash drain valve; 208, a water production valve; 209, a concentrated water valve;

300、二段卷式膜单元;300-1、二段卷式膜单元进水端;300-2、二段卷式膜单元末端;300, two-stage roll-type membrane unit; 300-1, the water inlet end of the two-stage roll-type membrane unit; 300-2, the end of the two-stage roll-type membrane unit;

301、二段卷式膜元件;302、二段正洗进水管路;303、二段正洗进水阀;304、二段正洗排水阀;305、二段产水阀;306、二段浓水阀;301, two-stage coiled membrane element; 302, two-stage positive washing water inlet pipeline; 303, two-stage positive washing water inlet valve; 304, two-stage positive washing drain valve; 305, two-stage water production valve; 306, two-stage Concentrated water valve;

400、液相清洗单元;401、加药装置;402、清洗泵;403、清洗过滤装置;400, liquid phase cleaning unit; 401, dosing device; 402, cleaning pump; 403, cleaning filter device;

500、气相清洗单元;501、调压阀;502、气洗阀;503、空压罐。500, gas phase cleaning unit; 501, pressure regulating valve; 502, gas washing valve; 503, air pressure tank.

具体实施方式Detailed ways

为了能够更清楚地理解本发明的上述目的、特征和优点,下面将对本发明的方案进行进一步描述。需要说明的是,在不冲突的情况下,本发明的实施例及实施例中的特征可以相互组合。In order to more clearly understand the above objects, features and advantages of the present invention, the solution of the present invention will be further described below. It should be noted that the embodiments of the present invention and the features in the embodiments may be combined with each other under the condition of no conflict.

本发明针对卷式膜系统运行过程中,卷式膜表面由于原水中悬浮物、胶状物、有机物、微生物等污染物质的存在及膜分离过程中对难溶物质的浓缩而产生的沉积,进而形成对膜元件的污染,现有技术冲洗或清洗方式存在对高污染水源效果有限、频繁清洗运行繁琐,及最前端膜元件的污染物在普通正向冲洗时清洗物流至末端膜元件导致污染清洗效果不理想等技术问题,为解决上述技术问题,本发明公开了一种卷式膜系统及其气液两相清洗方法。The present invention is aimed at the deposition on the surface of the rolled membrane due to the presence of pollutants such as suspended solids, colloids, organic matter, microorganisms and other pollutants in the raw water and the concentration of insoluble substances during the membrane separation process during the operation of the rolled membrane system. Forming pollution to membrane elements, the prior art flushing or cleaning methods have limited effects on highly polluted water sources, frequent cleaning operations are cumbersome, and pollutants from the front-end membrane elements are cleaned to the end membrane elements during ordinary forward flushing, resulting in pollution cleaning. In order to solve the technical problems such as unsatisfactory effects, the present invention discloses a roll-type membrane system and a gas-liquid two-phase cleaning method thereof.

在下面的描述中阐述了很多具体细节以便于充分理解本发明,但本发明还可以采用其他不同于在此描述的方式来实施;显然,说明书中的实施例只是本发明的一部分实施例,而不是全部的实施例。Many specific details are set forth in the following description to facilitate a full understanding of the present invention, but the present invention can also be implemented in other ways different from those described herein; obviously, the embodiments in the description are only a part of the embodiments of the present invention, and Not all examples.

实施例1Example 1

本实施例公开了一种卷式膜系统,结合图1可知,所述系统包括进水单元100、一段卷式膜单元200、二段卷式膜单元300、液相清洗单元400、气相清洗单元500及用于控制各单元的控制系统;且附图1中未体现出控制系统,但其实际上是存在的,本发明优选控制系统为PLC控制系统,相关控制设备为本领域常用,在此不作赘述。This embodiment discloses a roll-type membrane system. Referring to FIG. 1 , the system includes a water inlet unit 100 , a one-stage roll-type membrane unit 200 , a second-stage roll-type membrane unit 300 , a liquid-phase cleaning unit 400 , and a gas-phase cleaning unit 500 and the control system for controlling each unit; and the control system is not shown in the accompanying drawing 1, but it actually exists, the preferred control system of the present invention is a PLC control system, and the relevant control equipment is commonly used in this field. I won't go into details.

如图1所示,所述液相清洗单元400包括依次连接的加药装置401、清洗泵402和清洗过滤装置403,所述气相清洗单元500包括依次连接的空压罐503、调压阀502与气洗阀501,所述清洗过滤装置403、气洗阀503的出口管路连接三条支路,第一条支路为一段正洗进水管路202,第二条支路为二段正洗进水管路302,第三条支路为一段反洗进水管路205;As shown in FIG. 1 , the liquid phase cleaning unit 400 includes a dosing device 401 , a cleaning pump 402 and a cleaning filter device 403 connected in sequence, and the gas phase cleaning unit 500 includes an air pressure tank 503 and a pressure regulating valve 502 connected in sequence With the air wash valve 501, the cleaning and filtering device 403, and the outlet pipeline of the air wash valve 503 are connected to three branches, the first branch is a first-stage positive washing water inlet pipeline 202, and the second branch is a second-stage positive washing The water inlet pipeline 302, the third branch is a backwash water inlet pipeline 205;

所述一段正洗进水管路202连接所述一段卷式膜单元200上设置的一段正洗进水阀203,所述一段正洗进水阀203连通一段卷式膜单元进水端200-1,一段卷式膜单元末端200-2连接一段正洗排水阀204;The first section of the positive washing water inlet pipeline 202 is connected to the first section of the positive washing water inlet valve 203 provided on the first section of the rolled membrane unit 200, and the first section of the positive washing water inlet valve 203 is connected to the first section of the rolled membrane unit water inlet 200-1 , the end 200-2 of a section of rolled membrane unit is connected to a section of positive washing drain valve 204;

所述二段正洗进水管路302连接所述二段卷式膜单元300上设置的二段正洗进水阀303,所述二段正洗进水阀303连通二段卷式膜单元进水端300-1,二段卷式膜单元末端300-2连接二段正洗排水阀304;The second-stage positive washing water inlet pipeline 302 is connected to the second-stage positive washing water inlet valve 303 provided on the second-stage rolling membrane unit 300, and the second-stage positive washing water inlet valve 303 is connected to the second-stage rolling membrane unit inlet. The water end 300-1, the end 300-2 of the second-stage rolled membrane unit is connected to the second-stage positive washing drain valve 304;

所述一段反洗进水管路205连接一段卷式膜单元200上设置的一段反洗进水阀206,所述一段反洗进水阀206连通一段卷式膜单元末端200-2,所述一段卷式膜单元进水端200-1连接一段反洗排水阀207;The one-stage backwash water inlet pipeline 205 is connected to the one-stage backwash water inlet valve 206 provided on the one-stage roll-type membrane unit 200, and the one-stage backwash water inlet valve 206 is connected to the end 200-2 of the one-stage roll-type membrane unit. The water inlet end 200-1 of the rolled membrane unit is connected to a backwash drain valve 207;

所述一段正洗排水阀204、二段正洗排水阀304与一段反洗排水阀207均通向清洗排水端。The first-stage forward-washing drain valve 204, the second-stage forward-washing drain valve 304 and the first-stage backwashing drain valve 207 all lead to the cleaning and draining end.

各段卷式膜单元的末端还连接三条子路,一条子路用于排出浓水,一条子路用于排出产水,余下一条子路用于排出清洗排水。The ends of each section of the coiled membrane unit are also connected with three sub-circuits, one is used to discharge concentrated water, one is used to discharge product water, and the remaining one is used to discharge cleaning and drainage.

本实施例优选一段卷式膜单元末端200-2还分别连接一段产水阀208、一段浓水阀209;二段卷式膜单元末端300-2还分别连接二段产水阀305、二段浓水阀306。In this embodiment, preferably, the end 200-2 of the first-stage coiled membrane unit is further connected to a first-stage water production valve 208 and a first-stage concentrated water valve 209; Concentrate valve 306.

首先,一段卷式膜单元200与二段卷式膜单元300之间是串联关系,而一段卷式膜单元200内各一段卷式膜元件201之间,二段卷式膜单元300内各二段卷式膜元件301之间均采用多组并联的连接方式,这使得控制液相清洗单元400及气相清洗单元500可实现对各段的独立气液清洗从而避免最前端膜元件的清洗物流至末端时引起污染末端膜器件的技术问题,其中,气洗的气体为空气,控制气洗的进气压≤0.1MPa,优选≤0.08MPa。First, there is a series relationship between the one-stage roll-type membrane unit 200 and the second-stage roll-type membrane unit 300, and between each one-stage roll-type membrane element 201 in the one-stage roll-type membrane unit 200, each two-stage roll-type membrane unit 300 has two The multi-group parallel connection mode is adopted between the segmented membrane elements 301, which enables the control of the liquid-phase cleaning unit 400 and the gas-phase cleaning unit 500 to realize independent gas-liquid cleaning of each section, so as to avoid the cleaning flow of the front-end membrane element. The technical problem of contamination of the terminal membrane device is caused at the end, wherein the gas for the air wash is air, and the inlet pressure of the control air wash is ≤ 0.1MPa, preferably ≤ 0.08MPa.

与此同时,对于一段卷式膜单元200中各膜件污染比较严重的时候,如前述一段卷式膜单元200出现的受胶体、金属氧化物、有机物生物污染等现象,还可选择对一段卷式膜单元200进行反向气液清洗,但反向冲洗存在冲裂膜元件或者破坏密封粘结面的风险,故本实施例一方面控制反洗管路上反冲洗进水压≤0.3MPa,优选≤0.2MPa。At the same time, when the contamination of each membrane element in the one-stage roll-type membrane unit 200 is relatively serious, such as the above-mentioned phenomena such as biological contamination by colloids, metal oxides, and organic substances in the one-stage roll-type membrane unit 200, it is also possible to select the one-stage roll-type membrane unit 200. The type membrane unit 200 is cleaned by reverse gas-liquid cleaning, but there is a risk of cracking the membrane element or damaging the sealing and bonding surface in reverse flushing. ≤0.2MPa.

由于二段卷式膜单元的膜元件污染情况可得到合理控制,本发明可选择不对二段卷式膜单元进行反向冲洗的设计,但二段卷式膜单元反向冲洗的相关设计也在本发明保护范围内。Since the contamination of the membrane elements of the two-stage roll-up membrane unit can be reasonably controlled, the present invention can choose not to carry out the design of backwashing the two-stage roll-up membrane unit, but the related design of the backwashing of the two-stage roll-up membrane unit is also within the protection scope of the present invention.

本发明主要采用气液正向或反向物理清洗模式,只有当该模式对系统的压力降改善不佳的极少情况下才会采用外加药剂对膜元件进行化学清洗,所述药剂包括杀菌剂、表面活性剂、酸性清洗剂、碱性清洗剂、中性清洗剂、络合物清洗剂中任意一种。结合图1可知,本发明设计的进水单元还包括相互连接的供水泵101、进水加药设备102、保安过滤器103、增压泵104和进水阀105。The present invention mainly adopts the gas-liquid forward or reverse physical cleaning mode, and only when the mode does not improve the pressure drop of the system poorly, will the membrane element be chemically cleaned with an external agent, and the agent includes a bactericide , any one of surfactants, acidic cleaning agents, alkaline cleaning agents, neutral cleaning agents and complex cleaning agents. 1 , the water inlet unit designed by the present invention further includes a water supply pump 101 , an inlet water dosing device 102 , a security filter 103 , a booster pump 104 and a water inlet valve 105 , which are connected to each other.

综上所述,本发明设计的膜系统可以实现对卷式膜元件的多模式清洗,如一段卷式膜单元正向水洗、气洗或水洗+气洗、一段卷式膜单元反向水洗、气洗或水洗+气洗、二段卷式膜单元正向水洗、气洗或水洗+气洗,及一段卷式膜单元与二段卷式膜单元同时正向水洗、气洗或水洗+气洗等。且可以在产水正常进行或者停止产水的情况下根据各渗透单元的实际压力降采用上述模式灵活清洗。To sum up, the membrane system designed in the present invention can realize multi-mode cleaning of the coiled membrane elements, such as forward water washing, air washing or water washing + air washing, reverse water washing of the first-stage coiled membrane unit, Air washing or water washing + air washing, two-stage coiled membrane unit forward water washing, air washing or water washing + air washing, and one-stage coiled membrane unit and two-stage coiled membrane unit at the same time forward water washing, air washing or water washing + air washing wash etc. And the above mode can be flexibly cleaned according to the actual pressure drop of each permeation unit under the condition of normal water production or stop water production.

实施例2Example 2

本实施例选择对进水10000吨/天,反渗透产水7500吨/天的中水回用处理系统进行清洗,其中,该中水回用处理系统的进水水质与出水水质要求如下表1与表2;This embodiment chooses to clean the reclaimed water reuse treatment system with 10,000 tons/day of influent water and 7,500 tons/day of reverse osmosis production water, wherein the requirements for the influent water quality and effluent water quality of the reclaimed water reuse treatment system are as follows in Table 1 with Table 2;

表1中水回用处理系统设计进水水质参数Table 1 Influent water quality parameters of the design of the water reuse treatment system

序号serial number 指标index 单位unit 平均值average value 11 CODCOD mg/Lmg/L ≤30≤30 22 BODBOD mg/Lmg/L ≤6≤6 33 氨氮Ammonia nitrogen mg/Lmg/L ≤1.5≤1.5 44 TNTN mg/Lmg/L ≤15≤15 55 TPTP mg/Lmg/L ≤0.3≤0.3 66 pHpH 6~96 to 9 77 SSSS mg/Lmg/L ≤10≤10 88 溶解性总固体total dissolved solids mg/Lmg/L ≤1000≤1000 99 硫酸盐Sulfate mg/Lmg/L ≤200≤200 1010 总硬度total hardness mg/Lmg/L ≤400≤400 1111 氯化物chloride mg/Lmg/L ≤200≤200 1212 碱度Alkalinity mg/Lmg/L ≤400≤400

表2中水回用处理系统设计产水水质参数Table 2 Design water quality parameters of water reuse treatment system

指标index 数据data 脱盐率Desalination rate 97%(三年)97% (three years) PHPH 6.5~9.06.5~9.0 浊度Turbidity <1<1 CODCOD <2(锰法)<2 (manganese method) 游离氯free chlorine <0.1mg/L<0.1mg/L

所述过滤系统采用如图2所示的两套反渗透系统,单套设计进水水量208.4m3/h,产水水量156.3m3/h,设计运行通量17.3LMH,一级两段方式,第一段采用36支6芯膜壳,第二段采用18支6芯膜壳,单套共安装324支BW30FR-400/34i型RO膜元件,两套共648支RO膜元件。原系统的维护清洗采用传统的正向水冲洗方式。The filtration system adopts two sets of reverse osmosis systems as shown in Fig. 2, the designed influent water volume of a single set is 208.4m 3 /h, the permeate water volume is 156.3m 3 /h, the designed operating flux is 17.3LMH, and the one-stage two-stage method , the first section adopts 36 6-core membrane shells, and the second section adopts 18 6-core membrane shells. A total of 324 BW30FR-400/34i RO membrane elements are installed in a single set, and two sets of 648 RO membrane elements are installed. The maintenance and cleaning of the original system adopts the traditional forward water flushing method.

上述中水回用处理系统的原反渗透系统建成投运后不到2个月反渗透膜元件出现污染堵塞,特别是1#RO一段和2#RO一段压力降高居不下,如高于0.15MPa,传统的维护清洗的正向水冲洗方式对一段和二段的冲洗效果有限,且压力上升后经过化学清洗后也仅能维持约15天运行稳定,不但清洗化学清洗药剂费用较高,而且清洗费时需要经常安排人员清洗,还由于清洗时RO系统需要停运,导致整个系统运行效率低下。The original reverse osmosis system of the above-mentioned reclaimed water reuse treatment system was completed and put into operation less than 2 months after the reverse osmosis membrane element was polluted and blocked, especially the pressure drop of the 1#RO section and the 2#RO section remained high, such as higher than 0.15MPa , the traditional positive water flushing method of maintenance cleaning has limited flushing effect on the first and second stages, and after the pressure rises, after chemical cleaning, it can only maintain stable operation for about 15 days, not only the cleaning chemical cleaning agent cost is high, but also cleaning It takes time and needs to arrange personnel to clean frequently, and because the RO system needs to be shut down during cleaning, the operation efficiency of the entire system is low.

其中,采用本实施例1设计的清洗装置分别对上述二级卷式膜系统进行清洗处理,得到如下表3,且表3给出了具体清洗方法。Wherein, using the cleaning device designed in Example 1 to perform cleaning treatment on the above-mentioned two-stage rolled membrane system respectively, the following Table 3 is obtained, and Table 3 presents the specific cleaning method.

表3各清洗方法的运行参数及运行效果列表Table 3 List of operating parameters and operating effects of each cleaning method

Figure BDA0003753436250000101
Figure BDA0003753436250000101

结合表3可知,原系统的运行方式为“过滤→水冲洗→过滤”周期性循环运行,其中水冲洗仅为对第一和第二两段同时进行正向水冲洗,压力高时进行CIP化学清洗;系统优化改造后的运行方式为“过滤→气液两相冲洗→过滤”周期性循环运行,其中气液两相冲洗包括第一段反向气液两相冲洗、第一段正向气液两相冲洗和第二段正向水冲洗;从表3可以看出,对原系统进行了气液两相清洗改造后,明显提高了每次冲洗的效果,延长了CIP化学清洗周期及提高了化学清洗效果,彻底解决了原传统膜系统的膜污染问题。Combining with Table 3, it can be seen that the operation mode of the original system is "filtering→water flushing→filtering" periodic cycle operation, in which the water flushing only performs forward water flushing for the first and second sections at the same time, and CIP chemical is performed when the pressure is high. Cleaning; after the system is optimized and transformed, the operation mode is "filtering → gas-liquid two-phase flushing → filtering" periodic cycle operation, in which the gas-liquid two-phase flushing includes the first stage reverse gas-liquid two-phase flushing, the first stage forward gas-liquid two-phase flushing Liquid two-phase flushing and second-stage forward water flushing; as can be seen from Table 3, after the gas-liquid two-phase cleaning transformation was carried out on the original system, the effect of each flushing was significantly improved, the CIP chemical cleaning cycle was prolonged, and the The chemical cleaning effect is improved, and the membrane fouling problem of the original traditional membrane system is completely solved.

除了上述实施例2列举的清洗模式,对于其他类型污染状况,还可采用其他的清洗模式。如一段卷式膜单元膜压力降较快达到清洗要求(0.15MPa)状况,可以采用单独进行一段气液两相清洗模式:“一段卷式膜单元反向水洗+气洗→一段卷式膜单元正向水洗+气洗”方式;如一段卷式膜单元膜压力降较快达到清洗要求(0.15MPa)状况,可以采用单独二段气液两相清洗模式:“二段卷式膜单元正向水洗+气洗方式”;如一段卷式膜单元和二段卷式膜单元的压力降均达到清洗要求(0.15MPa)状况时,可采用和实施例2类似的“一段卷式膜单元反向水洗+气洗→一段卷式膜单元正向水洗+气洗→二段卷式膜单元正向水洗+气洗”相结合的清洗模式;如膜压力降较高状况(0.2MPa),可以采用将清洗水中添加化学药剂,通过气液两相强化化学清洗方式进一步提高清洗效果:“一段卷式膜单元反向药洗+气洗→一段卷式膜单元正向药洗+气洗→二段卷式膜单元正向药洗+气洗”相结合的清洗模式。In addition to the cleaning modes listed in Embodiment 2 above, other cleaning modes may also be used for other types of contamination conditions. If the membrane pressure drop of a first-stage coiled membrane unit reaches the cleaning requirement (0.15MPa) quickly, a separate gas-liquid two-phase cleaning mode can be used: "a first-stage coiled membrane unit reverse water washing + air washing → a first-stage coiled membrane unit Forward water washing + air washing" method; if the pressure drop of the first-stage coiled membrane unit is faster to meet the cleaning requirements (0.15MPa), a separate second-stage gas-liquid two-phase cleaning mode can be used: "The second-stage coiled membrane unit forward Water washing + air washing method”; if the pressure drop of the one-stage coiled membrane unit and the second-stage coiled membrane unit both meet the cleaning requirements (0.15MPa), the “one-stage coiled membrane unit reversed” similar to Example 2 can be used. Water washing + air washing → one-stage coiled membrane unit forward water washing + air washing → two-stage coiled membrane unit forward water washing + air washing” combined cleaning mode; if the membrane pressure drop is high (0.2MPa), you can use the cleaning mode Chemicals are added to the cleaning water, and the cleaning effect is further improved by the gas-liquid two-phase enhanced chemical cleaning method: "One-stage coiled membrane unit reverse drug washing + air washing → one-stage coiled membrane unit forward drug washing + air washing → second stage The coiled membrane unit is a cleaning mode that combines forward chemical washing + air washing.

综上所述,该系统及方法不仅清洗效率高,减少清洗频次及延长清洗周期,而且能够针对于对最前端膜元件进行有效清洗,保护膜元件的使用寿命。To sum up, the system and method not only have high cleaning efficiency, reduce cleaning frequency and prolong cleaning cycle, but also can effectively clean the front-end membrane element and protect the service life of the membrane element.

需要说明的是,在本文中,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that, herein, the terms "comprising", "comprising" or any other variation thereof are intended to encompass non-exclusive inclusion, such that a process, method, article or device comprising a series of elements includes not only those elements, It also includes other elements not expressly listed or inherent to such a process, method, article or apparatus. Without further limitation, an element qualified by the phrase "comprising a..." does not preclude the presence of additional identical elements in a process, method, article or apparatus that includes the element.

以上所述仅是本发明的具体实施方式,使本领域技术人员能够理解或实现本发明。对这些实施例的多种修改对本领域的技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。因此,本发明将不会被限制于本文所述的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above descriptions are only specific embodiments of the present invention, so that those skilled in the art can understand or implement the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments described herein, but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (10)

1. A spiral-wound membrane system is characterized by comprising a water inlet unit, a multi-section spiral-wound membrane unit, a liquid phase cleaning unit, a gas phase cleaning unit and a control system for controlling each unit; the multi-section rolled membrane unit comprises one section, two sections or three sections of rolled reverse osmosis membranes, rolled nanofiltration membranes or rolled ultra/microfiltration membranes;
the outlet pipelines of the liquid phase cleaning unit and the gas phase cleaning unit are respectively connected with the water inlet end and/or the tail end of each section of the roll-type membrane unit through branches for realizing forward and/or reverse water washing and/or gas washing of each section of the roll-type membrane unit, and each branch is provided with a forward water inlet valve, a forward water discharge valve, a reverse water inlet valve and a reverse water discharge valve; the control system controls the opening and closing of each valve and the starting and stopping of each pump;
the tail end of each section of the roll-type membrane unit is also connected with three sub-paths, one sub-path is used for discharging concentrated water, one sub-path is used for discharging produced water, and the other sub-path is used for discharging cleaning and discharging water.
2. Membrane system according to claim 1, characterized in that the water inlet pressure of the reverse water wash is ≤ 0.3MPa.
3. The rolled membrane system of claim 1 wherein the inlet gas pressure of the gas wash is ≤ 0.1MPa.
4. The membrane system according to any one of claims 1 to 3, characterized in that the gas phase washing unit comprises a pneumatic tank, a pressure regulating valve and a gas washing valve connected in series.
5. The membrane system of claim 4, wherein the liquid phase washing unit comprises a dosing device, a washing pump and a washing filtration device connected in sequence.
6. The rolled membrane system of claim 5, characterized in that the multi-sectional rolled membrane unit comprises a one-section rolled membrane unit and a two-section rolled membrane unit, wherein a forward and/or reverse air washing and/or water washing pipeline is arranged on the one-section rolled membrane unit, and a forward air washing and/or water washing pipeline is arranged on the two-section rolled membrane unit;
the outlet pipelines of the cleaning and filtering device and the gas washing valve are connected with three branches, wherein the first branch is a section of forward washing water inlet pipeline, the second branch is a section of forward washing water inlet pipeline, and the third branch is a section of backwashing water inlet pipeline;
the first section of forward washing water inlet pipeline is connected with a first section of forward washing water inlet valve arranged on the first section of spiral membrane unit, the first section of forward washing water inlet valve is communicated with the water inlet end of the first section of spiral membrane unit, and the tail end of the first section of spiral membrane unit is connected with a first section of forward washing drain valve;
the second-stage forward washing water inlet pipeline is connected with a second-stage forward washing water inlet valve arranged on the second-stage spiral-wound membrane unit, the second-stage forward washing water inlet valve is communicated with the water inlet end of the second-stage spiral-wound membrane unit, and the tail end of the second-stage spiral-wound membrane unit is connected with a second-stage forward washing drain valve;
the first section of backwashing water inlet pipeline is connected with a first section of backwashing water inlet valve arranged on the first section of spiral membrane unit, the first section of backwashing water inlet valve is communicated with the tail end of the first section of spiral membrane unit, and the water inlet end of the first section of spiral membrane unit is connected with a first section of backwashing water outlet valve;
and the first section of forward washing drain valve, the second section of forward washing drain valve and the first section of backwashing drain valve are communicated with cleaning drain water.
7. The rolled membrane system of claim 1 or 2 or 3 or 5 or 6, wherein the gas of the gas washing is air, the water washing is cleaning by using external water or water produced by the rolled membrane or concentrated water, and a medicament can be added into the external water, and the medicament comprises any one of a bactericide, a surfactant, an acidic cleaning agent, an alkaline cleaning agent, a neutral cleaning agent and a complex cleaning agent.
8. A method for cleaning gas-liquid two-phase of a rolled membrane by the system of any one of claims 1 to 7, which is characterized in that: the cleaning mode comprises forward water washing and/or air washing of the first-stage roll type membrane unit, reverse water washing and/or air washing of the first-stage roll type membrane unit, forward water washing and/or air washing of the second-stage roll type membrane unit, or any combination.
9. The method of claim 8, wherein: the cleaning mode is forward water washing and/or gas washing of the first-section spiral membrane unit, reverse water washing and/or gas washing of the first-section spiral membrane unit and forward water washing and/or gas washing of the second-section spiral membrane unit.
10. The method of claim 9, wherein: when the pressure drop of the first-section spiral membrane unit and the second-section spiral membrane unit is continuously over 0.15MPa, the control system closes each pump and each valve of the water inlet unit, opens each pump and each valve of the gas-phase cleaning unit and the liquid-phase cleaning unit, opens the first-section backwashing water inlet valve and the first-section backwashing drainage valve, and flushes the first-section gas-liquid reverse direction for 30-120 s; a first-stage forward washing water inlet valve and a first-stage forward washing water outlet valve are opened, and a first-stage gas-liquid forward washing is carried out for 30-120 s; a second-stage forward washing water inlet valve and a second-stage forward washing water outlet valve are opened, and the second-stage water is washed forward for 30-150 seconds; and repeating the operation once every 48h until the pressure drop of the first section of the roll-type membrane unit is 0.01-0.10 MPa, and the pressure drop of the second section of the roll-type membrane unit is 0.01-0.10 MPa.
CN202210850930.0A 2022-07-19 2022-07-19 Rolled membrane system and gas-liquid two-phase cleaning method thereof Pending CN115228298A (en)

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