CN1150060C - 一种吸附剂用于脱除气体中的羰基金属化合物 - Google Patents
一种吸附剂用于脱除气体中的羰基金属化合物 Download PDFInfo
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- CN1150060C CN1150060C CNB991052560A CN99105256A CN1150060C CN 1150060 C CN1150060 C CN 1150060C CN B991052560 A CNB991052560 A CN B991052560A CN 99105256 A CN99105256 A CN 99105256A CN 1150060 C CN1150060 C CN 1150060C
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- Prior art keywords
- adsorbent
- gas
- carrier
- purposes
- oxide
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- 239000003463 adsorbent Substances 0.000 title claims abstract description 48
- -1 carbonyl metal compound Chemical class 0.000 title claims abstract description 6
- 239000011651 chromium Substances 0.000 claims description 22
- 229910052804 chromium Inorganic materials 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 238000010521 absorption reaction Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 abstract description 15
- 238000000034 method Methods 0.000 abstract description 14
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract description 10
- 229910052742 iron Inorganic materials 0.000 abstract description 10
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- 239000007789 gas Substances 0.000 abstract 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 238000001179 sorption measurement Methods 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 229910003158 γ-Al2O3 Inorganic materials 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 32
- 230000000694 effects Effects 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000003891 oxalate salts Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
Abstract
Description
编号 | 活性组份 | Fe(%) | Ni(ppm) |
实施例1 | Cr2O3 | 1.71 | 423 |
对比例1 | CuO | 1.20 | 69.1 |
对比例2 | PbO | 0.67 | 30.3 |
对比例3 | ZnO | 0.98 | 25.2 |
对比例4 | KOH | 0.82 | 678.0 |
编号 | Cr2O3 | Fe(%) | Ni(ppm) |
实施例2 | 0.60 | 0.256 | 321 |
实施例3 | 1.14 | 0.624 | 438 |
实施例4 | 2.36 | 0.962 | 514 |
实施例5 | 3.41 | 0.986 | 521 |
实施例6 | 11.34 | 0.723 | 322 |
实施例7 | 19.12 | 0.694 | 297 |
编号 | 添加组分 | Fe(%) | Ni(ppm) |
实施例8 | ZnO | 1.92 | 723 |
对比例5 | CuO | 1.43 | 512 |
对比例6 | La2O3 | 1.90 | 300 |
编号 | ZnO(%) | Fe(%) | Ni(ppm) |
实施例9 | 1.10 | 0.566 | 472 |
实施例10 | 3.28 | 1.93 | 372 |
实施例11 | 5.48 | 1.83 | 698 |
实施例12 | 10.95 | 0.962 | 514 |
实施例13 | 19.16 | 0.714 | 486 |
编号 | 焙烧温度℃ | Fe(%) | Ni(ppm) |
实施例14 | 200 | 0.64 | 243 |
实施例15 | 300 | 0.98 | 312 |
实施例16 | 400 | 1.94 | 720 |
实施例17 | 500 | 1.89 | 715 |
实施例18 | 550 | 0.87 | 518 |
实施例19 | 600 | 0.52 | 321 |
编号 | 反应温度℃ | QXJ-01 | K306 | ||
Fe(%) | Ni(ppm) | Fe(%) | Ni(ppm) | ||
实施例20 | 30 | 0.97 | 401 | 0.86 | <25 |
实施例21 | 50 | 1.92 | 723 | 1.17 | <25 |
实施例22 | 80 | 2.85 | 926 | 2.51 | 622 |
编号 | 反应空速h-1 | QXJ-01 | K306 | ||
Fe(%) | Ni(ppm) | Fe(%) | Ni(ppm) | ||
实施例23 | 1000 | 3.17 | 1100 | 2.29 | 89 |
实施例24 | 3000 | 1.92 | 723 | 1.17 | <25 |
实施例25 | 5000 | 0.68 | 314 | 0.50 | <25 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB991052560A CN1150060C (zh) | 1999-04-29 | 1999-04-29 | 一种吸附剂用于脱除气体中的羰基金属化合物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB991052560A CN1150060C (zh) | 1999-04-29 | 1999-04-29 | 一种吸附剂用于脱除气体中的羰基金属化合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1272395A CN1272395A (zh) | 2000-11-08 |
CN1150060C true CN1150060C (zh) | 2004-05-19 |
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CNB991052560A Expired - Fee Related CN1150060C (zh) | 1999-04-29 | 1999-04-29 | 一种吸附剂用于脱除气体中的羰基金属化合物 |
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CN (1) | CN1150060C (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101516768B (zh) * | 2006-09-27 | 2012-02-15 | 国际壳牌研究有限公司 | 用于从合成气物流中除去羰基金属的方法 |
CN102218295A (zh) * | 2010-04-15 | 2011-10-19 | 中国石油化工股份有限公司 | 脱除合成气中羰基铁和羰基镍的脱除剂及其制备方法 |
CN110876935B (zh) * | 2018-09-06 | 2023-06-30 | 中国石油化工股份有限公司 | 甲醇合成催化剂保护剂及其制备方法 |
CN112705157B (zh) * | 2019-10-24 | 2023-06-06 | 中国石油化工股份有限公司 | 用于脱除Fe(CO)5和/或Ni(CO)4的净化剂及其制备方法和应用 |
-
1999
- 1999-04-29 CN CNB991052560A patent/CN1150060C/zh not_active Expired - Fee Related
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CN1272395A (zh) | 2000-11-08 |
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