CN114618279A - Emission reduction system and construction method for removing odor and greenhouse gas using sulfur autotrophs - Google Patents

Emission reduction system and construction method for removing odor and greenhouse gas using sulfur autotrophs Download PDF

Info

Publication number
CN114618279A
CN114618279A CN202210381707.6A CN202210381707A CN114618279A CN 114618279 A CN114618279 A CN 114618279A CN 202210381707 A CN202210381707 A CN 202210381707A CN 114618279 A CN114618279 A CN 114618279A
Authority
CN
China
Prior art keywords
bacterial agent
agent pool
pool
sulfur
inspection well
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202210381707.6A
Other languages
Chinese (zh)
Other versions
CN114618279B (en
Inventor
董磊
张欣
陈银广
孙伟迪
范心韵
郑雄
冯雷雨
黄海宁
张学萌
崔贺
马慧婕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongji University
Shanghai Municipal Engineering Design Insitute Group Co Ltd
Original Assignee
Tongji University
Shanghai Municipal Engineering Design Insitute Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongji University, Shanghai Municipal Engineering Design Insitute Group Co Ltd filed Critical Tongji University
Priority to CN202210381707.6A priority Critical patent/CN114618279B/en
Publication of CN114618279A publication Critical patent/CN114618279A/en
Application granted granted Critical
Publication of CN114618279B publication Critical patent/CN114618279B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • B01D53/526Mixtures of hydrogen sulfide and carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/95Specific microorganisms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Treating Waste Gases (AREA)

Abstract

利用硫自养菌去除恶臭和温室气体的减排系统,包括反应池系统、除臭系统及冷凝水排放系统,生物反应池上连接有进水管和进风管;除臭系统设置的除臭箱体内部安装有第一、第二及第三菌剂池;菌剂池上设置菌剂池检查井及含硫恶臭在线监测仪表;除臭箱体还与太阳能尾气排放塔相连通,太阳能尾气排放塔的一侧设置有风力发电机;冷凝水排放系统包括与除臭箱体相连通的冷凝水排放管,冷凝水排放管上设置有冷凝水排放泵和冷凝水排放管检查井;本发明用于净化地下式污水厂散发的含硫恶臭气体,通过采用太阳能无动力抽吸方式,在节能降耗的同时实现二氧化碳固定。

Figure 202210381707

The emission reduction system using sulfur autotrophic bacteria to remove odor and greenhouse gas includes reaction tank system, deodorization system and condensate water discharge system. The biological reaction tank is connected with water inlet pipe and air inlet pipe; the deodorization box set in the deodorization system The first, second and third bacterial agent pools are installed inside; the bacterial agent pool is equipped with inspection wells for bacterial agent pools and on-line monitoring instruments for sulfur-containing odor; the deodorizing box is also connected to the solar exhaust emission tower, and the A wind turbine is arranged on one side; the condensate water discharge system includes a condensate water discharge pipe that communicates with the deodorizing box, and the condensate water discharge pipe is provided with a condensate water discharge pump and a condensate water discharge pipe inspection well; the present invention is used for purifying The sulfur-containing odorous gas emitted by the underground sewage treatment plant can be fixed by using the solar powerless suction method while saving energy and reducing consumption.

Figure 202210381707

Description

利用硫自养菌去除恶臭和温室气体的减排系统及搭建方法Emission reduction system and construction method for removing odor and greenhouse gas by using sulfur autotrophic bacteria

技术领域technical field

本发明涉及污水处理技术领域,特别是涉及一种利用硫自养菌去除恶臭和温室气体的减排系统及搭建方法。The invention relates to the technical field of sewage treatment, in particular to an emission reduction system and a construction method for removing malodor and greenhouse gases by using sulfur autotrophs.

背景技术Background technique

污水处理厂是市政及环保基础设施的重要组成部分,在保护生态环境、节约水资源、改善人们生活质量等方面起着巨大的作用;根据相关部门统计,截至 2020年,全国污水处理厂总数达到15700座。Sewage treatment plants are an important part of municipal and environmental protection infrastructure, and play a huge role in protecting the ecological environment, saving water resources, and improving people's quality of life. According to statistics from relevant departments, as of 2020, the total number of sewage treatment plants nationwide has reached 15,700 seats.

传统的地上污水处理厂在净化污水的同时,所散发的恶臭主要成分如硫化氢、甲硫醇、三甲胺、甲硫醚、二甲二硫、二硫化碳等含硫臭气,这些气体具有强烈刺鼻气味的同时还存在毒性,如果处理不当,会对周边居民及厂区工作人员的生命安全产生严重的威胁,所产生的“邻避效应”使周围地块贬值,投资价值等受到严重影响。While the traditional above-ground sewage treatment plants purify sewage, the main components of the stench are hydrogen sulfide, methyl mercaptan, trimethylamine, methyl sulfide, dimethyl disulfide, carbon disulfide and other sulfur-containing odors. Nose odor is also toxic. If it is not handled properly, it will pose a serious threat to the life safety of surrounding residents and factory workers. The resulting "NIMBY effect" will depreciate the surrounding land and seriously affect the investment value.

同时,我国城镇污水处理厂普遍采用活性污泥法作为主流技术,其中活性污泥中的微生物在降解污水中碳,氮,磷等污染物的同时也会释放大量二氧化碳,根据我国多地污水厂的实地调研测试,生物处理单元可产生10000~36000ppm的温室气体。At the same time, the activated sludge method is generally adopted as the mainstream technology in urban sewage treatment plants in my country. The microorganisms in activated sludge will release a large amount of carbon dioxide while degrading pollutants such as carbon, nitrogen and phosphorus in sewage. According to the field research and testing, the biological treatment unit can produce 10000-36000ppm of greenhouse gases.

而传统地上式生物除臭系统装置需要在池体顶部额外设置恶臭收集盖,以实现对系统的密封;其系统尾部依据规范必须设置15m高的尾气排放烟囱,严重影响厂区的景观美观。传统除臭系统无法实现对温室气体的直接减排。此外,配套的大功率风机、喷淋泵等其他附属设施,其能耗范围在12-37kw·h/万立方米气体,且通常需要24小时运行,消耗大量电能,其间接地增加温室气体的排放。总体,当前现有除臭系统缺乏去除恶臭气体且减排温室气体的系统。The traditional above-ground biological deodorization system requires an additional odor collection cover on the top of the tank to seal the system; the tail of the system must be equipped with a 15m-high exhaust chimney according to the specifications, which seriously affects the landscape of the plant. Traditional deodorization systems cannot achieve direct reductions in greenhouse gas emissions. In addition, the supporting high-power fans, spray pumps and other auxiliary facilities have an energy consumption range of 12-37kw h/10,000 cubic meters of gas, and usually require 24 hours of operation, consuming a large amount of electricity, which indirectly increases greenhouse gas emissions . In general, the current existing deodorization systems lack systems for removing malodorous gases and reducing greenhouse gases.

地下污水处理厂具有占地小,臭气封闭性强,环境友好,能与绿化,景观结合美观性好等优点,已逐渐得到各地政府和周边居民的认可,成为城市水处理工程建设的新方向。地下式水处理构筑物是将水处理设施由露天转移到地下,一般分为三层:地面层、地下一层和地下二层。地面层通常为休闲公园,并设置通风井与出入口,大部分区域与室外空间隔断;地下一层为设备起吊以及巡检空间;地下二层为污水池体层,通常为封闭状态,与地下一层组成箱体。The underground sewage treatment plant has the advantages of small footprint, strong odor sealing, environmental friendliness, and good aesthetics in combination with greening and landscape. It has gradually been recognized by local governments and surrounding residents, and has become a new direction for urban water treatment engineering construction. . The underground water treatment structure is to transfer the water treatment facilities from the open air to the underground. It is generally divided into three layers: the ground layer, the first underground layer and the second underground layer. The ground floor is usually a leisure park, with ventilation shafts and entrances and exits, and most areas are separated from the outdoor space; the first underground floor is the equipment lifting and inspection space; the second underground floor is the sewage pool body layer, which is usually closed and separated from the underground one. The layers make up the box.

现有技术中,公开号为CN111939750A的发明专利,公开了一种除臭菌剂、除臭装置及除臭方法,除臭菌剂的有效成分包括来源于食品中的酵母菌、乳酸菌和醋酸菌;对进入其中的气体进行三级处理,恶臭废气被微生物菌株分解吸收在物体内,在微生物繁殖的同时达到去除恶臭废气的目的,通过三次处理联合除臭,保证了高效性也保证了彻底性;但是不具备在净化恶臭的同时减排温室气体,使恶臭含硫气体通过热压作用形成主动式、零能耗的自然流出的优势。In the prior art, the invention patent with the publication number of CN111939750A discloses a deodorant bacterial agent, a deodorizing device and a deodorizing method. The active ingredients of the deodorizing bacterial agent include yeast, lactic acid bacteria and acetic acid bacteria derived from food. ;Three-stage treatment is performed on the gas entering it, and the odorous waste gas is decomposed and absorbed in the object by microbial strains, and the purpose of removing the odorous waste gas is achieved while the microorganisms multiply, and the combined deodorization through three treatments ensures high efficiency and thoroughness. However, it does not have the advantage of reducing greenhouse gas emissions while purifying the odor, so that the odorous sulfur-containing gas can form an active, zero-energy natural outflow through thermal pressure.

现有技术中,公开号为CN111111425A的发明专利,公开了一种多反应段组合式臭气处理装置及处理方法,生物除硫反应段的顶部连通生物除氮反应段的底部;生物除氮反应段的顶部连通生物除碳反应段的底部;生物除碳反应段的上部连通深度净化段的底部,深度净化段的顶部设有设出气口;利用多反应段、多菌种组合,对恶臭气体处理更加彻底,处理效果稳定;但是其内部菌群无法利用CO2作为碳源,从而减少温室气体的产生。In the prior art, the invention patent with publication number CN111111425A discloses a multi-reaction section combined odor treatment device and treatment method. The top of the biological sulfur removal reaction section is connected to the bottom of the biological nitrogen removal reaction section; the biological nitrogen removal reaction The top of the section is connected to the bottom of the biological carbon removal reaction section; the upper part of the biological carbon removal reaction section is connected to the bottom of the deep purification section, and the top of the deep purification section is provided with an air outlet; the combination of multiple reaction sections and multiple bacterial species is used to eliminate odorous gas. The treatment is more thorough and the treatment effect is stable; however, its internal flora cannot use CO 2 as a carbon source, thereby reducing the production of greenhouse gases.

发明内容SUMMARY OF THE INVENTION

本发明目的就是针对现有技术中的不足,提供一种利用硫自养菌去除恶臭和温室气体的减排系统及搭建方法,能够在净化恶臭的同时减排温室气体,并利用太阳能尾气排放塔吸收太阳能产生的热量,使恶臭含硫气体通过热压作用形成主动式、零能耗的自然流出;为实现以上目的,本发明通过以下技术方案予以实现:The purpose of the present invention is to aim at the deficiencies in the prior art, to provide an emission reduction system and a construction method for removing malodor and greenhouse gases by using sulfur autotrophic bacteria, which can reduce greenhouse gases while purifying malodor, and utilize a solar exhaust emission tower Absorb the heat generated by solar energy, so that the odorous sulfur-containing gas forms an active, zero-energy-consumption natural outflow through hot pressing; in order to achieve the above purpose, the present invention is achieved through the following technical solutions:

一种利用硫自养菌去除恶臭和温室气体的减排系统,包括反应池系统、除臭系统和冷凝水排放系统,所述反应池系统通过进风管与所述除臭系统连接,所述除臭系统通过冷凝水排放泵与所述冷凝水排放系统连接,所述反应池系统包括生物反应池,所述生物反应池一侧上方连接有进水管,所述生物反应池另一侧连接于进风管的进风口;An emission reduction system utilizing sulfur autotrophic bacteria to remove odor and greenhouse gases, comprising a reaction tank system, a deodorization system and a condensed water discharge system, the reaction tank system is connected with the deodorization system through an air inlet pipe, and the The deodorization system is connected to the condensed water discharge system through a condensed water discharge pump, the reaction tank system includes a biological reaction tank, a water inlet pipe is connected above one side of the biological reaction tank, and the other side of the biological reaction tank is connected to the air inlet of the air inlet pipe;

所述除臭系统包括除臭箱体,所述除臭箱体底部与进风管的出风口相连接,所述除臭箱体包括第一菌剂池、第二菌剂池和第三菌剂池;所述第一菌剂池、第二菌剂池和第三菌剂池依次分别连接,所述第三菌剂池与太阳能尾气排放塔相连通;The deodorizing system includes a deodorizing box, the bottom of the deodorizing box is connected to the air outlet of the air inlet pipe, and the deodorizing box includes a first bacterial agent pool, a second bacterial agent pool and a third bacterial agent pool. agent pool; the first bacteria agent pool, the second bacteria agent pool and the third bacteria agent pool are respectively connected in turn, and the third bacteria agent pool is communicated with the solar exhaust gas discharge tower;

所述冷凝水排放系统包括冷凝水排放管,所述冷凝水排放管与除臭箱体相连通,所述冷凝水排放管与除臭箱体连通处设置有集水坑,所述冷凝水排放管上设置有冷凝水排放泵和冷凝水排放管检查井,所述第一菌剂池、第二菌剂池和第三菌剂池分别通过联通机构与所述除臭箱体底部表面连接。The condensed water discharge system includes a condensed water discharge pipe, the condensed water discharge pipe is communicated with the deodorization box body, and a sump is provided at the connection between the condensed water discharge pipe and the deodorization box body, and the condensed water discharge pipe is A condensed water discharge pump and a condensed water discharge pipe inspection well are arranged on the pipe, and the first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool are respectively connected with the bottom surface of the deodorizing box through a communication mechanism.

所述第一菌剂池、第二菌剂池及第三菌剂池在除臭箱体内部依次排列,所述第一菌剂池与所述进风管的出风口连接,所述第一菌剂池上设置第一菌剂池检查井及第一含硫恶臭在线监测仪表;所述第二菌剂池上设置第二菌剂池检查井及第二含硫恶臭在线监测仪表;所述第三菌剂池上设置第三菌剂池检查井及第三含硫恶臭在线监测仪表,所述第一菌剂池检查井、第二菌剂池检查井及第三菌剂池检查井均垂直设置在第一菌剂池、第二菌剂池及第三菌剂池的上端中心位置,所述所述第一菌剂池检查井、第二菌剂池检查井和第三菌剂池检查井内分别设置有井部密封装置,所述井部密封装置包括密封盖和密封联动机构,所述密封盖与密封联动机构通过操作杆连接。The first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool are arranged in sequence inside the deodorizing box, the first bacterial agent pool is connected to the air outlet of the air inlet pipe, and the first bacterial agent pool is connected to the air outlet of the air inlet pipe. A first bacterial agent tank inspection well and a first sulfur-containing odor online monitoring instrument are arranged on the bacterial agent tank; a second bacterial agent tank inspection well and a second sulfur-containing malodor online monitoring instrument are set on the second bacterial agent tank; the third The third bacterial agent tank inspection well and the third sulfur-containing odor online monitoring instrument are set on the bacterial agent tank. The first bacterial agent tank inspection well, the second bacterial agent tank inspection well and the third bacterial agent tank inspection well are vertically arranged on the The center position of the upper end of the first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool, the inspection wells of the first bacterial agent pool, the second bacterial agent pool inspection well and the third bacterial agent pool inspection well are respectively A well sealing device is provided, the well sealing device includes a sealing cover and a sealing linkage mechanism, and the sealing cover and the sealing linkage mechanism are connected by an operating rod.

所述密封联动机构包括联动盖板,所述联动盖板包括左盖板和右盖板,所述左盖板与所述右盖板转动连接于盖板座上,所述盖板座周圈设置有盖板槽,所述左盖板和所述右盖板边沿处嵌于所述盖板座周圈的盖板槽内。The sealing linkage mechanism includes a linkage cover plate, the linkage cover plate includes a left cover plate and a right cover plate, the left cover plate and the right cover plate are rotatably connected to the cover plate seat, and the cover plate seat has a peripheral ring. A cover plate groove is provided, and the edges of the left cover plate and the right cover plate are embedded in the cover plate grooves on the periphery of the cover plate seat.

所述第一菌剂池投放的微生物菌剂包括55%-65%含量的氧化亚铁硫杆菌和35%-45%含量的氧化硫硫杆菌,所述第二菌剂池投放的微生物菌剂包括55%-65%含量的那不勒斯硫杆菌和35%-45%含量的诺维卢斯硫杆菌,所述第三菌剂池投放的微生物菌剂包括50%-70%含量的排硫硫杆菌和30%-50%含量的硫碱微生物。The microbial inoculants put in the first bacterial agent pool include Thiobacillus ferrooxidans with a content of 55%-65% and Thiobacillus ferrooxidans with a content of 35%-45%, and the microbial inoculants put in the second bacterial agent pool Including 55%-65% content of Thiobacillus Naples and 35%-45% content of Thiobacillus novelius, the microbial inoculum put in the third bacterial agent pool includes 50%-70% content of Thiobacillus thiophane and 30%-50% content of sulfur-alkali microorganisms.

所述联通机构包括DN50电动蝶阀和阀体控制单元,所述阀体控制单元控制所述DN50电动蝶阀运行。The communication mechanism includes a DN50 electric butterfly valve and a valve body control unit, and the valve body control unit controls the operation of the DN50 electric butterfly valve.

所述左盖板与所述右盖板为半圆形结构,所述左盖板和所述右盖板扇形边沿处分别设置有下凸起,所述下凸起与所述盖板槽镶嵌连接。The left cover plate and the right cover plate are semi-circular structures, and lower protrusions are respectively provided at the fan-shaped edges of the left cover plate and the right cover plate, and the lower protrusions are inlaid with the cover plate grooves. connect.

所述太阳能尾气排放塔的塔体长度需不小于15m,以形成主动式、零能耗的自然抽风强化设备。The length of the tower body of the solar exhaust emission tower needs to be not less than 15m, so as to form an active and zero energy consumption natural drafting and strengthening equipment.

所述除臭箱体的底部由第一菌剂池下端向第三菌剂池下端倾斜形成斜坡,所述斜坡斜率为0.1%-2%。The bottom of the deodorizing box is inclined from the lower end of the first bacterial agent pool to the lower end of the third bacterial agent pool to form a slope, and the slope of the slope is 0.1%-2%.

所述太阳能尾气排放塔的上端四周均贴覆有平板式太阳能集热器,所述太阳能尾气排放塔的内部设置有隔热板及电阻丝,所述太阳能尾气排放塔的一侧设置有风力发电机;所述风力发电机与电阻丝相连接,所述风力发电机的内部安装有蓄电池。The upper end of the solar exhaust emission tower is covered with flat-plate solar collectors, the interior of the solar exhaust emission tower is provided with a heat insulation board and a resistance wire, and one side of the solar exhaust emission tower is provided with wind power generation The wind generator is connected with a resistance wire, and a battery is installed inside the wind generator.

所述的减排系统的搭建方法,包括以下步骤:The construction method of the emission reduction system includes the following steps:

S1、将反应池系统中的生物反应池建造于地下二层中,利用进风管与设计在地下二层中的除臭系统内的除臭箱体进行连通;S1. The biological reaction tank in the reaction tank system is built in the second underground layer, and the air inlet pipe is used to communicate with the deodorizing box in the deodorizing system designed in the second underground layer;

S2、在除臭箱体内部顺次设置第一菌剂池、第二菌剂池及第三菌剂池,并在第一菌剂池、第二菌剂池及第三菌剂池的左侧分别设置第一含硫恶臭在线监测仪表、第二含硫恶臭在线监测仪表及第三含硫恶臭在线监测仪表;S2. The first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool are set up in sequence inside the deodorizing box, and the left side of the first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool are arranged in sequence. The first sulfur-containing odor online monitoring instrument, the second sulfur-containing odor online monitoring instrument and the third sulfur-containing odor online monitoring instrument are respectively set on the side;

S3、在第一菌剂池、第二菌剂池及第三菌剂池的上端垂直分别设置第一菌剂池检查井、第二菌剂池检查井及第三菌剂池检查井,并将第一菌剂池检查井、第二菌剂检查井及第三菌剂检查井的入口设置在地下一层的操作层,将第一菌剂池分别投放55%-65%含量的氧化亚铁硫杆菌和35%-45%含量的氧化硫硫杆菌,将第二菌剂池内分别投放55%-65%含量的那不勒斯硫杆菌和35%-45%含量的诺维卢斯硫杆菌,将第三菌剂池内分别投放50%-70%含量的排硫硫杆菌和30%-50%含量的硫碱微生物,通过三级菌剂池能以CO2作为碳源,使恶臭中的H2S氧化为硫酸,还能利用曝气池中产生的O2通过化学反应使含硫恶臭中的H2S转化为单质硫,降低H2S在各级处理单元中的浓度以及CO2的排放量;S3. The first bacterial agent tank inspection well, the second bacterial agent tank inspection well, and the third bacterial agent tank inspection well are vertically arranged at the upper ends of the first bacterial agent pool, the second bacterial agent pool, and the third bacterial agent pool, respectively, and The entrances of the first bacterial agent pool inspection well, the second bacterial agent inspection well and the third bacterial agent inspection well are set on the operation layer of the first underground layer, and the first bacterial agent pool is respectively put into 55%-65% content of suboxide. Thiobacillus ferricum and Thiobacillus thiooxidans with a content of 35%-45%, put 55%-65% Thiobacillus Naples and Thiobacillus novelus with a content of 35%-45% in the second bacterial agent pool respectively, 50%-70% content of Thiobacillus thiobacillus and 30%-50% content of sulfur-alkali microorganisms are put into the third bacterial agent pool respectively. Through the third-level bacterial agent pool, CO2 can be used as a carbon source, so that H2 in the stench can be eliminated. S is oxidized to sulfuric acid, and the O 2 generated in the aeration tank can also be used to convert the H 2 S in the sulfur-containing odor into elemental sulfur through chemical reaction, reducing the concentration of H 2 S in the treatment units at all levels and the emission of CO 2 quantity;

S4、将太阳能尾气排放塔的底端与除臭箱体连通后,使太阳能尾气排放塔穿过地下一层的操作层到达地面层,将净化过的无味气体通过太阳能尾气排放塔排放,在地面层外露的太阳能尾气排放塔的塔体四周贴附平板式太阳能集热器,并在塔体一侧安装风力发电机;S4. After connecting the bottom end of the solar exhaust gas discharge tower with the deodorization box, make the solar exhaust gas discharge tower pass through the operation layer of the first basement to the ground layer, and discharge the purified odorless gas through the solar exhaust gas discharge tower. Flat-plate solar collectors are attached around the tower body of the exposed solar exhaust emission tower, and a wind turbine is installed on one side of the tower body;

S5、将除臭箱体的底部设计为自左向右斜率为0.1%-2%的斜坡,在除臭箱体右端末尾处设置集水坑,通过设置有冷凝水排放泵的冷凝水排放管将冷凝水排放至污水管网;冷凝水排放管检查井设置在地下二层,并在地下一层预留冷凝水排放管检查井检查口。S5. Design the bottom of the deodorizing box as a slope with a slope of 0.1%-2% from left to right, set a sump at the end of the right end of the deodorizing box, and pass the condensed water discharge pipe provided with the condensed water discharge pump. The condensed water is discharged to the sewage pipe network; the inspection well for the condensed water discharge pipe is set on the second underground floor, and the inspection well for the condensed water discharge pipe is reserved on the first underground floor.

本发明的有益效果:Beneficial effects of the present invention:

1、本发明用于净化地下式污水厂散发的含硫恶臭气体,通过采用太阳能无动力抽吸方式,利用太阳能和风能实现整个除臭系统的运行,提升系统能源自给率,间接减排温室气体;三级设置的菌剂池内的硫自养菌可利用CO2作为碳源,直接减少30%-50%温室气体的产生;在节能降耗的同时实现二氧化碳固定;1. The present invention is used to purify the sulfur-containing malodorous gas emitted by the underground sewage plant. By adopting the solar powerless suction method, the entire deodorizing system can be operated by using solar energy and wind energy, thereby improving the energy self-sufficiency rate of the system and indirectly reducing greenhouse gas emissions. ; The sulfur autotrophic bacteria in the three-level bacterial agent pool can use CO 2 as a carbon source to directly reduce the generation of greenhouse gases by 30%-50%; realize carbon dioxide fixation while saving energy and reducing consumption;

2、本发明除臭效果显著,通过采用三级硫自养菌微生物菌剂池,使得单位体积内净化含硫恶臭的菌种数量多,种类丰富,除臭效率显著提高,能有效缓解邻避效应;2. The deodorizing effect of the present invention is remarkable. By adopting the tertiary sulfur autotrophic bacteria microbial inoculum pool, the number of bacteria that can purify sulfur-containing malodors per unit volume is large, the variety is rich, the deodorizing efficiency is significantly improved, and the NIMBY can be effectively alleviated. effect;

3、本发明封闭性强,对环境友好且占地小,与水景、绿化相结合性好,在保证美观的同时,充分提升土地利用率以及周边地块价值;3. The present invention has strong sealing, is environmentally friendly, occupies a small area, and has good integration with water features and greening. While ensuring the beauty, the land utilization rate and the value of the surrounding plots are fully improved;

4、本发明利用地下式污水厂自身优势,水温即使在冬天也能达到12度以上,无需采取额外的保温措施,这满足了微生物的适宜温度;负压的装置以及较短的送风管道,能有效减少系统中水汽的损耗,湿度常年可维持在20~30%,以提高微生物的活性。4. The present invention utilizes the advantages of the underground sewage plant, and the water temperature can reach above 12 degrees even in winter, without taking additional thermal insulation measures, which satisfies the suitable temperature of microorganisms; the negative pressure device and the short air supply pipeline, It can effectively reduce the loss of water vapor in the system, and the humidity can be maintained at 20-30% all year round to improve the activity of microorganisms.

5、本发明利用绿色清洁能源增大了除臭系统的能源自给率,地下式箱体占地小且能实现除臭系统内保温、保湿,以提高微生物液体菌剂的活性与除臭效率。5. The present invention utilizes green and clean energy to increase the energy self-sufficiency rate of the deodorizing system, and the underground box occupies a small area and can achieve thermal insulation and moisturizing in the deodorizing system, so as to improve the activity and deodorizing efficiency of the microbial liquid inoculum.

附图说明Description of drawings

图1为本发明硫自养菌减排温室气体系统的结构示意图;Fig. 1 is the structural schematic diagram of the sulfur autotrophic bacteria emission reduction greenhouse gas system of the present invention;

图2为本发明太阳能尾气排放塔与平板太阳能集热器的安装示意图;Fig. 2 is the installation schematic diagram of the solar exhaust emission tower and the flat-plate solar collector of the present invention;

图3为本发明第二菌剂池检查井内部结构原理示意图;Fig. 3 is the schematic diagram of the internal structure principle of the second bacterial agent pool inspection well of the present invention;

图4为本发明井部密封装置结构原理示意图。FIG. 4 is a schematic diagram of the structural principle of the well sealing device of the present invention.

图中:1、生物反应池;2、进风管;3、第一菌剂池检查井;4、第一菌剂池; 5、第二菌剂池检查井;6、第二菌剂池;7、第三菌剂池检查井;8、第三菌剂池; 9、第一含硫恶臭在线监测仪表;10、第二含硫恶臭在线监测仪表;11、第三含硫恶臭在线监测仪表;12、太阳能尾气排放塔;13、电阻丝;14、平板太阳能集热器;15、风力发电机;16、冷凝水排放泵;17、冷凝水排放管;18、冷凝水排放管检查井;19、进水管;20、DN50电动蝶阀,21、井部密封装置,22、密封盖,23、密封联动机构,24、操作杆,25、联动盖板,26、左盖板,27、右盖板, 28、盖板座。In the figure: 1. Biological reaction tank; 2. Air inlet pipe; 3. Inspection well of the first bacterial agent tank; 4. The first bacterial agent tank; 5. Inspection well of the second bacterial agent tank; 6. The second bacterial agent tank 7. Inspection well of the third bacterial agent tank; 8. The third bacterial agent tank; 9. The first online monitoring instrument for sulfur-containing odor; 10. The second online monitoring instrument for sulfur-containing odor; 11. The third online monitoring for sulfur-containing odor Instrument; 12. Solar exhaust gas discharge tower; 13. Resistance wire; 14. Flat panel solar collector; 15. Wind turbine; 16. Condensate discharge pump; 17. Condensate discharge pipe; 18. Inspection well for condensate discharge pipe ;19, water inlet pipe; 20, DN50 electric butterfly valve, 21, well sealing device, 22, sealing cover, 23, sealing linkage, 24, operating lever, 25, linkage cover, 26, left cover, 27, right Cover, 28. Cover seat.

具体实施方式Detailed ways

下面,结合附图以及具体实施方式,对本发明做进一步描述:Below, in conjunction with accompanying drawing and specific embodiment, the present invention is further described:

为使本发明的目的、技术方案及优点更加清楚、明确,以下参照附图并举实施例对本发明作进一步说明。In order to make the objectives, technical solutions and advantages of the present invention clearer and clearer, the present invention will be further described below with reference to the accompanying drawings and examples.

实施例1:Example 1:

如图1至图2所示,一种利用硫自养菌去除恶臭和温室气体的减排系统,包括反应池系统、除臭系统及冷凝水排放系统,其中反应池系统包括生物反应池1,生物反应池1上连接有进水管19和进风管2;进水管19用于进水,进风管2用于将生物反应池1上方的恶臭气体引导至除臭系统中。As shown in Figures 1 to 2, an emission reduction system using sulfur autotrophic bacteria to remove odor and greenhouse gases includes a reaction tank system, a deodorization system and a condensed water discharge system, wherein the reaction tank system includes a biological reaction tank 1, The biological reaction tank 1 is connected with a water inlet pipe 19 and an air inlet pipe 2; the water inlet pipe 19 is used for water inlet, and the air inlet pipe 2 is used to guide the malodorous gas above the biological reaction tank 1 to the deodorization system.

除臭系统包括除臭箱体,除臭箱体与进风管2的另一端相连接,除臭箱体的内部设置有第一菌剂池4、第二菌剂池6及第三菌剂池8,并且第一菌剂池4、第二菌剂池6及第三菌剂池8在除臭箱体内部依次排列,除臭箱体的底部为斜率 0.1%-2%的斜坡,通过自然流淌流入至集水坑内。The deodorizing system includes a deodorizing box, the deodorizing box is connected to the other end of the air inlet pipe 2, and the inside of the deodorizing box is provided with a first bacterial agent pool 4, a second bacterial agent pool 6 and a third bacterial agent Pool 8, and the first bacterial agent pool 4, the second bacterial agent pool 6 and the third bacterial agent pool 8 are arranged in sequence inside the deodorizing box, and the bottom of the deodorizing box is a slope with a slope of 0.1%-2%. It flows naturally into the sump.

第一菌剂池4、第二菌剂池6及第三菌剂池8均通过DN50电动蝶阀20与除臭箱体连通;第一菌剂池4上设置第一菌剂池检查井3及第一含硫恶臭在线监测仪表9;第二菌剂池6上设置第二菌剂池检查井5及第二含硫恶臭在线监测仪表10;第三菌剂池8上设置第三菌剂池检查井7及第三含硫恶臭在线监测仪表 11,3组含硫恶臭在线监测仪表能够分别在线监测3个菌剂池内含硫恶臭气体的浓度,所述所述第一菌剂池检查井3、第二菌剂池检查井5和第三菌剂池检查井 7内分别设置有井部密封装置21,所述井部密封装置21包括密封盖22和密封联动机构23,所述密封盖22与密封联动机构23通过操作杆24连接,所述密封联动机构23包括联动盖板25,所述联动盖板25包括左盖板26和右盖板27,所述左盖板26与所述右盖板27转动连接于盖板座28上,所述盖板座28周圈设置有盖板槽,所述左盖板26和所述右盖板27边沿处嵌于所述盖板座28周圈的盖板槽内。The first bacterial agent pool 4, the second bacterial agent pool 6 and the third bacterial agent pool 8 are all communicated with the deodorizing box body through a DN50 electric butterfly valve 20; the first bacterial agent pool 4 is provided with a first bacterial agent pool inspection well 3 and The first sulfur-containing malodor online monitoring instrument 9; the second bacterial agent tank 6 is provided with a second bacterial agent tank inspection well 5 and the second sulfur-containing malodor online monitoring instrument 10; The third bacterial agent tank 8 is provided with a third bacterial agent tank The inspection well 7 and the third sulfur-containing odor online monitoring instrument 11, three groups of sulfur-containing odor online monitoring instruments can respectively monitor the concentration of sulfur-containing odor gas in the three bacterial agent pools online. The first bacterial agent tank inspection well 3 , the second microbial agent pool inspection well 5 and the third microbial agent tank inspection well 7 are respectively provided with a well sealing device 21, the well sealing device 21 includes a sealing cover 22 and a sealing linkage mechanism 23, the sealing cover 22 It is connected with the sealing linkage mechanism 23 through the operating rod 24. The sealing linkage mechanism 23 includes a linkage cover plate 25. The linkage cover plate 25 includes a left cover plate 26 and a right cover plate 27. The left cover plate 26 is connected to the right cover plate 26. The cover plate 27 is rotatably connected to the cover plate seat 28. The cover plate seat 28 is provided with a cover plate groove on the circumference. The edges of the left cover plate 26 and the right cover plate 27 are embedded in the cover plate seat 28. in the cover plate groove of the ring.

第一菌剂池检查井3、第二菌剂检查井5及第三菌剂检查井7均垂直设置在第一菌剂池4、第二菌剂池6及第三菌剂池8的上端中心位置,工作人员能够通过3组菌剂池检查井分别对各自的菌剂池进行硫自养菌的投加和菌剂池的检修工作。第一菌剂池4投放的微生物菌剂包括55%-65%含量的氧化亚铁硫杆菌 (Thiobacillus ferrooxidans)和35%-45%含量的氧化硫硫杆菌(Thiobacillus ferrooxidans);第二菌剂池6投放的微生物菌剂包括55%-65%含量的那不勒斯硫杆菌(Thiobacillus neapolitanus)和35%-45%含量的诺维卢斯硫杆菌(Thiobacillus novellus);第三菌剂池8投放的微生物菌剂包括50%-70%含量的排硫硫杆菌(Thiobacillus thioparus)和30%-50%含量的硫碱微生物(Thioalkalimicrobium cyclicum)。本发明中,第一菌剂池4,第二菌剂池6,第三菌剂池8所采用的菌群均来自实验室培养的纯菌。The first bacterial agent pool inspection well 3, the second bacterial agent inspection well 5 and the third bacterial agent inspection well 7 are vertically arranged on the upper ends of the first bacterial agent pool 4, the second bacterial agent pool 6 and the third bacterial agent pool 8 At the central location, the staff can add sulfur autotrophic bacteria and overhaul the microbial ponds through the three groups of microbial pond inspection wells. The microbial inoculants put in the first inoculant pool 4 include Thiobacillus ferrooxidans with a content of 55%-65% and Thiobacillus ferrooxidans with a content of 35%-45%; the second inoculum pool 6. The microbial inoculants put in include Thiobacillus neapolitanus with a content of 55%-65% and Thiobacillus novellus with a content of 35%-45%; the microbial bacteria put in the third bacterial agent pool 8 The agents include 50%-70% content of Thiobacillus thioparus and 30%-50% content of Thioalkalimicrobium cyclicum. In the present invention, the bacteria groups used in the first bacterial agent pool 4, the second bacterial agent pool 6 and the third bacterial agent pool 8 are all pure bacteria cultivated in the laboratory.

除臭箱体还与太阳能尾气排放塔12相连通,太阳能尾气排放塔12的塔体长度需不小于15m,以形成主动式、零能耗的自然抽风强化设备,本发明由于设置除臭系统,故将太阳能尾气排放塔12的高度设置为15m高,并将塔体大部分设置在地下,地上的太阳能尾气排放塔12的塔体四周贴覆平板式太阳能集热器14,平板式太阳能集热器14与太阳能尾气排放塔12之间的夹角控制在30-60度为宜,在晴天时,形成主动式、零能耗的自然抽风强化设备,通过吸收太阳辐射产生的热量形成温差,从而使恶臭气体通过热压作用形成的拔风效应自然流出;太阳能尾气排放塔12的内部设置有隔热板及电阻丝13,隔热板作为保温材料以提高热转化率;太阳能尾气排放塔12的一侧设置有风力发电机15,其内部装有蓄电池以作为应对紧急工况和存储多余电量,并且风力发电机15与电阻丝13相连接,通过风力发电产生的电能使太阳能尾气排放塔12内的电阻丝13产生热量,并保证在阴雨天气时除臭系统的正常运行。The deodorizing box is also communicated with the solar exhaust gas discharge tower 12. The length of the solar exhaust gas discharge tower 12 needs to be no less than 15m, so as to form an active and zero-energy-consumption natural drafting and strengthening equipment. Therefore, the height of the solar exhaust emission tower 12 is set to a height of 15m, and most of the tower body is set underground. The angle between the device 14 and the solar exhaust emission tower 12 is preferably controlled at 30-60 degrees. On sunny days, an active, zero-energy-consumption natural ventilation strengthening device is formed, and a temperature difference is formed by absorbing the heat generated by the solar radiation, thereby The odorous gas flows out naturally through the wind-pulling effect formed by hot pressing; the interior of the solar exhaust gas discharge tower 12 is provided with a thermal insulation board and a resistance wire 13, and the thermal insulation board is used as a thermal insulation material to improve the heat conversion rate; One side is provided with a wind power generator 15, which is equipped with a battery inside to deal with emergency conditions and store excess power, and the wind power generator 15 is connected with the resistance wire 13, and the power generated by wind power generation makes the solar exhaust gas discharge tower 12. The resistance wire 13 generates heat and ensures the normal operation of the deodorizing system in rainy weather.

冷凝水排放系统包括冷凝水排放管17,冷凝水排放管17先与除臭箱体相连通,其次与除臭箱体17连通处设置集水坑,冷凝水排放管17上还设置有冷凝水排放泵16和冷凝水排放管检查井18;冷凝水排放系统用于收集恶臭经过除臭系统时所产生的冷凝水,冷凝水除臭箱体底部0.1%-2%的斜坡通过DN50电动球阀的启闭流入集水坑,利用冷凝水排放泵16进入污水管网。工作人员可以在地下一层通过冷凝水排放管检查井18对其进行检修维护。The condensed water discharge system includes a condensed water discharge pipe 17. The condensed water discharge pipe 17 is firstly communicated with the deodorizing box body, and then a sump is set at the place where it communicates with the deodorizing box body 17. The condensed water discharge pipe 17 is also provided with condensed water. The discharge pump 16 and the condensate discharge pipe inspection well 18; the condensate discharge system is used to collect the condensate generated when the odor passes through the deodorization system, and the 0.1%-2% slope at the bottom of the condensate deodorization box passes through the DN50 electric ball valve. Open and close into the sump, and use the condensate discharge pump 16 to enter the sewage pipe network. The staff can inspect and maintain it through the inspection well 18 of the condensate discharge pipe on the ground floor.

太阳能尾气排放塔12是利用热压作用提高除臭箱体内的自然通风速率,通过吸收太阳辐射的热能引起拔风效应,从而使恶臭气体自然流出;太阳能尾气排放塔12四周贴覆太阳能平板集热器14,在晴天时能够形成主动式零能耗的自然抽风强化设备,内部设置绝热板作为保温材料,内部的电阻丝13产热起到热传导作用,将太阳能尾气排放塔12产生的热能传入除臭箱体内,保证抽风效率。The solar exhaust emission tower 12 uses thermal pressure to increase the natural ventilation rate in the deodorizing box, and causes a wind pulling effect by absorbing the heat energy of solar radiation, so that the odorous gas flows out naturally; the solar exhaust emission tower 12 is covered with solar panels around the heat collection The device 14 can form an active and zero-energy-consumption natural ventilation strengthening device in sunny days. A thermal insulation board is set inside as a thermal insulation material, and the internal resistance wire 13 generates heat to play a heat conduction role, and the thermal energy generated by the solar exhaust emission tower 12 is introduced. In the deodorant box, the ventilation efficiency is guaranteed.

风力发电机15通过叶片的转动可以将风能转换为电能对箱体内电阻丝13 进行加热,可在热能拔风效应低下时,通过电阻丝13产热以确保除臭系统的正常运行,其内部蓄电池可储存风力发电机多余的电能,可用于阴雨天气或紧急情况下供电使用,保障紧急工况下继续正常运行。上述装置相对于设置24小时常开的除臭风机大大减少了除臭系统中能源的消耗,提升绿色低碳能源使用率,实现除臭装置零动力。The wind generator 15 can convert wind energy into electrical energy to heat the resistance wire 13 in the box through the rotation of the blades, and can generate heat through the resistance wire 13 to ensure the normal operation of the deodorization system when the thermal energy pulling effect is low to ensure the normal operation of the deodorization system. It can store the excess electric energy of the wind turbine, which can be used for power supply in rainy weather or emergency situations to ensure normal operation under emergency conditions. Compared with the deodorant fan that is normally on for 24 hours, the above device greatly reduces the energy consumption in the deodorization system, improves the utilization rate of green and low-carbon energy, and realizes the zero power of the deodorization device.

实施例2:Example 2:

利用硫自养菌去除恶臭和温室气体的减排系统的搭建方法,包括以下步骤:The construction method of the emission reduction system using sulfur autotrophic bacteria to remove odor and greenhouse gas includes the following steps:

S1、将反应池系统中的生物反应池1建造于地下二层中,利用进风管2与设计在地下二层中的除臭系统内的除臭箱体进行连通;S1, the biological reaction tank 1 in the reaction tank system is built in the second underground layer, and the air inlet pipe 2 is used to communicate with the deodorizing box in the deodorizing system designed in the second underground layer;

S2、在除臭箱体内部顺次设置第一菌剂池4、第二菌剂池6及第三菌剂池8,并在第一菌剂池4、第二菌剂池6及第三菌剂池8的左侧设置第一含硫恶臭在线监测仪表9、第二含硫恶臭在线监测仪表10及第三含硫恶臭在线监测仪表11;S2, the first bacterial agent pool 4, the second bacterial agent pool 6 and the third bacterial agent pool 8 are sequentially arranged inside the deodorizing box, and the first bacterial agent pool 4, the second bacterial agent pool 6 and the third bacterial agent pool 8 are arranged in sequence. The left side of the bacterial agent tank 8 is provided with a first sulfur-containing odor online monitoring instrument 9, a second sulfur-containing odor online monitoring instrument 10, and a third sulfur-containing odor online monitoring instrument 11;

S3、在第一菌剂池4、第二菌剂池6及第三菌剂池8的上端垂直设置第一菌剂池检查井3、第二菌剂池检查井5及第三菌剂池检查井7,并将第一菌剂池检查井3、第二菌剂池检查井5及第三菌剂池检查井7的入口设置在地下一层的操作层;S3, vertically set the first bacterial agent pool inspection well 3, the second bacterial agent pool inspection well 5 and the third bacterial agent pool at the upper ends of the first bacterial agent pool 4, the second bacterial agent pool 6 and the third bacterial agent pool 8 Inspection well 7, and the entrances of the first bacterial agent pool inspection well 3, the second bacterial agent pool inspection well 5 and the third bacterial agent pool inspection well 7 are arranged in the operation layer of the first underground layer;

S4、将太阳能尾气排放塔12的底端与除臭箱体连通后,使太阳能尾气排放塔12穿过地下一层的操作层到达地面层,在地面层外露的太阳能尾气排放塔12 的塔体四周贴附平板式太阳能集热器14,并在塔体一侧安装风力发电机15;S4. After connecting the bottom end of the solar exhaust emission tower 12 with the deodorizing box, the solar exhaust emission tower 12 is made to pass through the operation layer of the first basement to the ground layer, and the tower body of the solar exhaust emission tower 12 is exposed on the ground layer. A flat-plate solar collector 14 is attached around, and a wind generator 15 is installed on one side of the tower body;

S5、将除臭箱体的底部设计为自左向右斜率为0.1%-2%的斜坡,在除臭箱体右端末尾处设置集水坑,通过设置有冷凝水排放泵16的冷凝水排放管17将冷凝水排放至污水管网;冷凝水排放管检查井18设置在地下二层,并在地下一层预留冷凝水排放管检查井检查口。S5. Design the bottom of the deodorizing box as a slope with a slope of 0.1%-2% from left to right, set a sump at the end of the right end of the deodorizing box, and discharge the condensed water through the condensed water discharge pump 16. The pipe 17 discharges the condensed water to the sewage pipe network; the condensed water discharge pipe inspection well 18 is arranged on the second underground floor, and a condensed water discharge pipe inspection well inspection port is reserved on the underground first floor.

第一菌剂池:氧化亚铁硫杆菌和氧化硫硫杆菌通过在地下一层的第一菌剂池检查井3投加进入,其目的主要负责净化刚进入除臭系统内的高浓度H2S气体,而第一含硫恶臭在线监测仪表9能准确显示第一菌剂池3中含硫恶臭的浓度。The first bacterial agent pool: Thiobacillus ferrooxidans and Thiobacillus thiooxidans are added through the inspection well 3 of the first bacterial agent pool on the basement floor, and their purpose is mainly responsible for purifying the high-concentration H2 that has just entered the deodorization system S gas, and the first sulfur-containing odor online monitoring instrument 9 can accurately display the concentration of sulfur-containing odor in the first bacterial agent pool 3 .

第二菌剂池:那不勒斯硫杆菌和诺维卢斯硫杆菌通过在地下一层的第二菌剂池检查井5投加进入,主要负责净化经过第二菌剂池6中的高浓度H2S气体,第二含硫恶臭在线监测仪表10能准确显示第二菌剂池6中含硫恶臭的浓度。The second bacterial agent pool: Thiobacillus napleus and Thiobacillus novelos are added through the inspection well 5 of the second bacterial agent pool on the basement floor, which is mainly responsible for purifying the high-concentration H 2 passing through the second bacterial agent pool 6 S gas, the second sulfur-containing odor online monitoring instrument 10 can accurately display the concentration of sulfur-containing odor in the second bacterial agent pool 6 .

第三菌剂池:排硫硫杆菌和硫碱微生物通过在地下一层的第三菌剂池检查井7投加进入,主要处理经过第一、二菌剂池中的低浓度H2S气体,第三含硫恶臭在线监测仪表11能准确显示第三菌剂池8中含硫恶臭的浓度。The third bacterial agent tank: Thiobacillus thiobacillus and sulfur-alkali microorganisms are added through the inspection well 7 of the third bacterial agent tank on the basement floor, and the low-concentration H 2 S gas in the first and second bacterial agent tanks is mainly treated. , the third sulfur-containing odor online monitoring instrument 11 can accurately display the concentration of sulfur-containing odor in the third bacterial agent pool 8 .

本发明可使恶臭顺次经过第一菌剂池4、第二菌剂池6到第三菌剂池8,再经第三菌剂池8净化过的无味气体通过太阳能尾气排放塔12排放至大气中;由于含硫恶臭主要成分为硫化氢,通常未处理前的H2S浓度的范围可达10-1000 ppm,而容易被忽视的CO2浓度则可达8000-20000ppm,通过本发明所净化的恶臭硫化氢浓度最终可达0.03ppm,且能减少40-60%原有CO2的排放量。The present invention can make the stench pass through the first bacterial agent pool 4, the second bacterial agent pool 6 to the third bacterial agent pool 8 in sequence, and the odorless gas purified by the third bacterial agent pool 8 is discharged through the solar exhaust gas discharge tower 12 to In the atmosphere; because the main component of sulfur-containing odor is hydrogen sulfide, the concentration of H 2 S before treatment is usually in the range of 10-1000 ppm, and the concentration of CO 2 that is easily neglected can reach 8,000-20,000 ppm. The purified odorous hydrogen sulfide concentration can finally reach 0.03ppm, and it can reduce the original CO2 emission by 40-60%.

本发明在其尾端设置太阳能尾气排放塔12,通过吸收太阳能产生的热量,使恶臭含硫气体通过热压作用形成主动式、零能耗地自然流出。此外,三级菌剂池中,微生物液体菌剂既能以CO2作为碳源使恶臭中的H2S氧化为硫酸,还能利用曝气池中产生的O2通过化学反应使含硫恶臭中的H2S转化为单质硫,降低 H2S在各级处理单元中的浓度以及CO2的排放量。In the present invention, a solar exhaust gas discharge tower 12 is arranged at the tail end, and by absorbing the heat generated by the solar energy, the odorous sulfur-containing gas is formed to flow out naturally with zero energy consumption through hot pressing. In addition, in the tertiary inoculum tank, the microbial liquid inoculum can not only use CO 2 as a carbon source to oxidize H 2 S in the odor to sulfuric acid, but also use the O 2 generated in the aeration tank to make the sulfur-containing odor through chemical reaction. The H 2 S in the system is converted into elemental sulfur, which reduces the concentration of H 2 S in the treatment units at all levels and the emission of CO 2 .

本发明通过取消传统除臭风机,发明一种利用硫自养菌去除地下式污水厂恶臭气体的同时,减排了温室气体的排放,采用太阳能无动力抽吸方式,在节能降耗的基础上符合要求;采用清洁能源实现对含硫恶臭气体的净化并实现CO2的固定,做到节能降耗,保证除臭效率。By eliminating the traditional deodorizing fan, the present invention uses sulfur autotrophic bacteria to remove odorous gas from an underground sewage plant, and at the same time reduces the emission of greenhouse gases, adopts the solar powerless suction method, and saves energy and reduces consumption on the basis of Meet the requirements; use clean energy to purify sulfur-containing malodorous gas and achieve CO 2 fixation, so as to save energy and reduce consumption and ensure deodorization efficiency.

对本领域的技术人员来说,可根据以上描述的技术方案以及构思,做出其它各种相应的改变以及形变,而所有的这些改变以及形变都应该属于本发明权利要求的保护范围之内。For those skilled in the art, various other corresponding changes and deformations can be made according to the technical solutions and concepts described above, and all these changes and deformations should fall within the protection scope of the claims of the present invention.

Claims (10)

1.一种利用硫自养菌去除恶臭和温室气体的减排系统,包括反应池系统、除臭系统和冷凝水排放系统,其特征在于,所述反应池系统通过进风管与所述除臭系统连接,所述除臭系统通过冷凝水排放泵与所述冷凝水排放系统连接,所述反应池系统包括生物反应池,所述生物反应池一侧上方连接有进水管,所述生物反应池另一侧连接于进风管的进风口;1. a kind of emission reduction system utilizing sulfur autotrophic bacteria to remove malodor and greenhouse gas, comprising reaction tank system, deodorization system and condensed water discharge system, it is characterized in that, described reaction tank system is by air inlet pipe and described remover. The odor system is connected, the deodorization system is connected to the condensate discharge system through a condensate discharge pump, the reaction tank system includes a biological reaction tank, and a water inlet pipe is connected above one side of the biological reaction tank, and the biological reaction tank The other side of the pool is connected to the air inlet of the air inlet pipe; 所述除臭系统包括除臭箱体,所述除臭箱体底部与进风管的出风口相连接,所述除臭箱体包括第一菌剂池、第二菌剂池和第三菌剂池;所述第一菌剂池、第二菌剂池和第三菌剂池依次分别连接,所述第三菌剂池与太阳能尾气排放塔相连通;The deodorizing system includes a deodorizing box, the bottom of the deodorizing box is connected to the air outlet of the air inlet pipe, and the deodorizing box includes a first bacterial agent pool, a second bacterial agent pool and a third bacterial agent pool. agent pool; the first bacteria agent pool, the second bacteria agent pool and the third bacteria agent pool are respectively connected in turn, and the third bacteria agent pool is communicated with the solar exhaust gas discharge tower; 所述冷凝水排放系统包括冷凝水排放管,所述冷凝水排放管与除臭箱体相连通,所述冷凝水排放管与除臭箱体连通处设置有集水坑,所述冷凝水排放管上设置有冷凝水排放泵和冷凝水排放管检查井,所述第一菌剂池、第二菌剂池和第三菌剂池分别通过联通机构与所述除臭箱体底部表面连接。The condensed water discharge system includes a condensed water discharge pipe, the condensed water discharge pipe is communicated with the deodorization box body, and a sump is provided at the connection between the condensed water discharge pipe and the deodorization box body, and the condensed water discharge pipe is A condensed water discharge pump and a condensed water discharge pipe inspection well are arranged on the pipe, and the first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool are respectively connected with the bottom surface of the deodorizing box through a communication mechanism. 2.根据权利要求1所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述第一菌剂池、第二菌剂池及第三菌剂池在除臭箱体内部依次排列,所述第一菌剂池与所述进风管的出风口连接,所述第一菌剂池上设置第一菌剂池检查井及第一含硫恶臭在线监测仪表;所述第二菌剂池上设置第二菌剂池检查井及第二含硫恶臭在线监测仪表;所述第三菌剂池上设置第三菌剂池检查井及第三含硫恶臭在线监测仪表,所述第一菌剂池检查井、第二菌剂池检查井及第三菌剂池检查井均垂直设置在第一菌剂池、第二菌剂池及第三菌剂池的上端中心位置,所述所述第一菌剂池检查井、第二菌剂池检查井和第三菌剂池检查井内分别设置有井部密封装置,所述井部密封装置包括密封盖和密封联动机构,所述密封盖与密封联动机构通过操作杆连接。2. a kind of emission reduction system utilizing sulfur autotrophic bacteria to remove malodor and greenhouse gas according to claim 1, is characterized in that, described first bacterial agent pool, second bacterial agent pool and third bacterial agent pool are in The inside of the deodorizing box is arranged in sequence, the first bacterial agent tank is connected to the air outlet of the air inlet pipe, and the first bacterial agent tank inspection well and the first sulfur-containing odor online monitoring instrument are arranged on the first bacterial agent tank The second bacterial agent pool inspection well and the second sulfur-containing odor online monitoring instrument are set on the second bacterial agent pool; the third bacterial agent pool inspection well and the third sulfur-containing malodor online monitoring instrument are set on the third bacterial agent pool The first bacterial agent pool inspection well, the second bacterial agent pool inspection well and the third bacterial agent pool inspection well are vertically arranged in the upper center of the first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool Position, the said first bacterial agent pool inspection well, the second bacterial agent pool inspection well and the third bacterial agent pool inspection well are respectively provided with well sealing devices, and the well sealing devices include a sealing cover and a sealing linkage mechanism , the sealing cover is connected with the sealing linkage mechanism through an operating rod. 3.根据权利要求2所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述密封联动机构包括联动盖板,所述联动盖板包括左盖板和右盖板,所述左盖板与所述右盖板转动连接于盖板座上,所述盖板座周圈设置有盖板槽,所述左盖板和所述右盖板边沿处嵌于所述盖板座周圈的盖板槽内。3. a kind of emission reduction system utilizing sulfur autotrophic bacteria to remove malodor and greenhouse gas according to claim 2, is characterized in that, described seal linkage mechanism comprises linkage cover plate, and described linkage cover plate comprises left cover plate and The right cover plate, the left cover plate and the right cover plate are rotatably connected to the cover plate seat, the periphery of the cover plate seat is provided with a cover plate groove, and the edges of the left cover plate and the right cover plate are embedded in the cover plate groove on the circumference of the cover plate seat. 4.根据权利要求2所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述第一菌剂池投放的微生物菌剂包括55%-65%含量的氧化亚铁硫杆菌和35%-45%含量的氧化硫硫杆菌,所述第二菌剂池投放的微生物菌剂包括55%-65%含量的那不勒斯硫杆菌和35%-45%含量的诺维卢斯硫杆菌,所述第三菌剂池投放的微生物菌剂包括50%-70%含量的排硫硫杆菌和30%-50%含量的硫碱微生物。4. a kind of emission reduction system utilizing sulfur autotrophic bacteria to remove malodor and greenhouse gas according to claim 2, it is characterized in that, the microbial inoculum put in described first inoculum agent pool comprises 55%-65% content of microbial inoculum. Thiobacillus ferrooxidans and Thiobacillus ferrooxidans with a content of 35%-45%, and the microbial inoculants put in the second bacterial agent pool include Thiobacillus napolita with a content of 55%-65% and Thiobacillus napolita with a content of 35%-45%. Thiobacillus villus, the microbial inoculum put in the third inoculant pool includes Thiobacillus thiophane with a content of 50%-70% and a sulfur-alkali microorganism with a content of 30%-50%. 5.根据权利要求1所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述联通机构包括DN50电动蝶阀和阀体控制单元,所述阀体控制单元控制所述DN50电动蝶阀运行。5. The emission reduction system according to claim 1, wherein the communication mechanism comprises a DN50 electric butterfly valve and a valve body control unit, wherein the valve body control unit Control the operation of the DN50 electric butterfly valve. 6.根据权利要求3所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述左盖板与所述右盖板为半圆形结构,所述左盖板和所述右盖板扇形边沿处分别设置有下凸起,所述下凸起与所述盖板槽镶嵌连接。6 . The emission reduction system for removing odor and greenhouse gases using sulfur autotrophic bacteria according to claim 3 , wherein the left cover plate and the right cover plate are semicircular structures, and the left cover The cover plate and the fan-shaped edge of the right cover plate are respectively provided with lower protrusions, and the lower protrusions are inlaid and connected with the cover plate groove. 7.根据权利要求1所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述太阳能尾气排放塔的塔体长度需不小于15m,以形成主动式、零能耗的自然抽风强化设备。7. a kind of emission reduction system utilizing sulfur autotrophic bacteria to remove malodor and greenhouse gas according to claim 1, is characterized in that, the tower body length of described solar exhaust gas discharge tower needs to be not less than 15m, to form active, Zero energy consumption of natural ventilation to strengthen equipment. 8.根据权利要求1所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述除臭箱体的底部由第一菌剂池下端向第三菌剂池下端倾斜形成斜坡,所述斜坡斜率为0.1%-2%。8. a kind of emission reduction system utilizing sulfur autotrophic bacteria to remove malodor and greenhouse gas according to claim 1, it is characterized in that, the bottom of described deodorizing box is from the lower end of the first bacterial agent pool to the third bacterial agent The lower end of the pool is inclined to form a slope, and the slope of the slope is 0.1%-2%. 9.根据权利要求1所述的一种利用硫自养菌去除恶臭和温室气体的减排系统,其特征在于,所述太阳能尾气排放塔的上端四周均贴覆有平板式太阳能集热器,所述太阳能尾气排放塔的内部设置有隔热板及电阻丝,所述太阳能尾气排放塔的一侧设置有风力发电机;所述风力发电机与电阻丝相连接,所述风力发电机的内部安装有蓄电池。9. a kind of emission reduction system utilizing sulfur autotrophic bacteria to remove malodor and greenhouse gas according to claim 1, is characterized in that, the upper end of described solar exhaust gas discharge tower is covered with flat plate solar collectors all around, The interior of the solar exhaust emission tower is provided with a heat insulation board and a resistance wire, and a wind generator is arranged on one side of the solar exhaust emission tower; the wind generator is connected with the resistance wire, and the interior of the wind generator is A battery is installed. 10.如权利要求1-9任一项所述的减排系统的搭建方法,其特征在于,包括以下步骤:10. The construction method of the emission reduction system according to any one of claims 1-9, characterized in that, comprising the following steps: S1、将反应池系统中的生物反应池建造于地下二层中,利用进风管与设计在地下二层中的除臭系统内的除臭箱体进行连通;S1. The biological reaction tank in the reaction tank system is built in the second underground layer, and the air inlet pipe is used to communicate with the deodorizing box in the deodorizing system designed in the second underground layer; S2、在除臭箱体内部顺次设置第一菌剂池、第二菌剂池及第三菌剂池,并在第一菌剂池、第二菌剂池及第三菌剂池的左侧分别设置第一含硫恶臭在线监测仪表、第二含硫恶臭在线监测仪表及第三含硫恶臭在线监测仪表;S2. The first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool are set up in sequence inside the deodorizing box, and the left side of the first bacterial agent pool, the second bacterial agent pool and the third bacterial agent pool are arranged in sequence. The first sulfur-containing odor online monitoring instrument, the second sulfur-containing odor online monitoring instrument and the third sulfur-containing odor online monitoring instrument are respectively set on the side; S3、在第一菌剂池、第二菌剂池及第三菌剂池的上端垂直分别设置第一菌剂池检查井、第二菌剂池检查井及第三菌剂池检查井,并将第一菌剂池检查井、第二菌剂检查井及第三菌剂检查井的入口设置在地下一层的操作层,将第一菌剂池分别投放55%-65%含量的氧化亚铁硫杆菌和35%-45%含量的氧化硫硫杆菌,将第二菌剂池内分别投放55%-65%含量的那不勒斯硫杆菌和35%-45%含量的诺维卢斯硫杆菌,将第三菌剂池内分别投放50%-70%含量的排硫硫杆菌和30%-50%含量的硫碱微生物,通过三级菌剂池能以CO2作为碳源,使恶臭中的H2S氧化为硫酸,还能利用曝气池中产生的O2通过化学反应使含硫恶臭中的H2S转化为单质硫,降低H2S在各级处理单元中的浓度以及CO2的排放量;S3. The first bacterial agent tank inspection well, the second bacterial agent tank inspection well, and the third bacterial agent tank inspection well are vertically arranged at the upper ends of the first bacterial agent pool, the second bacterial agent pool, and the third bacterial agent pool, respectively, and The entrances of the first bacterial agent pool inspection well, the second bacterial agent inspection well and the third bacterial agent inspection well are set on the operation layer of the first underground layer, and the first bacterial agent pool is respectively put into 55%-65% content of suboxide. Thiobacillus ferricum and Thiobacillus thiooxidans with a content of 35%-45%, put 55%-65% Thiobacillus Naples and Thiobacillus novelus with a content of 35%-45% in the second bacterial agent pool respectively, 50%-70% content of Thiobacillus thiobacillus and 30%-50% content of sulfur-alkali microorganisms are put into the third bacterial agent pool respectively. Through the third-level bacterial agent pool, CO2 can be used as a carbon source, so that H2 in the stench can be eliminated. S is oxidized to sulfuric acid, and the O 2 generated in the aeration tank can also be used to convert the H 2 S in the sulfur-containing odor into elemental sulfur through chemical reaction, reducing the concentration of H 2 S in the treatment units at all levels and the emission of CO 2 quantity; S4、将太阳能尾气排放塔的底端与除臭箱体连通后,使太阳能尾气排放塔穿过地下一层的操作层到达地面层,将净化过的无味气体通过太阳能尾气排放塔排放,在地面层外露的太阳能尾气排放塔的塔体四周贴附平板式太阳能集热器,并在塔体一侧安装风力发电机;S4. After connecting the bottom end of the solar exhaust gas discharge tower with the deodorization box, make the solar exhaust gas discharge tower pass through the operation layer of the first basement to the ground layer, and discharge the purified odorless gas through the solar exhaust gas discharge tower. Flat-plate solar collectors are attached around the tower body of the exposed solar exhaust emission tower, and a wind turbine is installed on one side of the tower body; S5、将除臭箱体的底部设计为自左向右斜率为0.1%-2%的斜坡,在除臭箱体右端末尾处设置集水坑,通过设置有冷凝水排放泵的冷凝水排放管将冷凝水排放至污水管网;冷凝水排放管检查井设置在地下二层,并在地下一层预留冷凝水排放管检查井检查口。S5. Design the bottom of the deodorizing box as a slope with a slope of 0.1%-2% from left to right, set a sump at the end of the right end of the deodorizing box, and pass the condensed water discharge pipe provided with the condensed water discharge pump. The condensed water is discharged to the sewage pipe network; the inspection well for the condensed water discharge pipe is set on the second underground floor, and the inspection well for the condensed water discharge pipe is reserved on the first underground floor.
CN202210381707.6A 2022-04-12 2022-04-12 Emission reduction system for removing stink and greenhouse gas by using sulfur autotrophic bacteria and building method Active CN114618279B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210381707.6A CN114618279B (en) 2022-04-12 2022-04-12 Emission reduction system for removing stink and greenhouse gas by using sulfur autotrophic bacteria and building method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210381707.6A CN114618279B (en) 2022-04-12 2022-04-12 Emission reduction system for removing stink and greenhouse gas by using sulfur autotrophic bacteria and building method

Publications (2)

Publication Number Publication Date
CN114618279A true CN114618279A (en) 2022-06-14
CN114618279B CN114618279B (en) 2023-02-21

Family

ID=81905097

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210381707.6A Active CN114618279B (en) 2022-04-12 2022-04-12 Emission reduction system for removing stink and greenhouse gas by using sulfur autotrophic bacteria and building method

Country Status (1)

Country Link
CN (1) CN114618279B (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1157756A (en) * 1997-08-11 1999-03-02 Clean Kasei:Kk Biologically deodorizing method and device therefor
JP2002119826A (en) * 2000-10-17 2002-04-23 Ebara Corp Method of deodorizing malodorous gas and device for the same
CN201546384U (en) * 2009-09-28 2010-08-11 河南科达节能环保有限公司 Solar hot-pressing ventilation roof and solar hot-pressing ventilation building
CN106635210A (en) * 2016-11-17 2017-05-10 南京工业大学 Method for removing hydrogen sulfide in biogas by using Acidithiobacillus caldus
CN210286880U (en) * 2019-06-12 2020-04-10 中国市政工程西北设计研究院有限公司 Underground sewage plant ventilation aeration system capable of reducing operation energy consumption
CN211462719U (en) * 2019-07-22 2020-09-11 中国电建集团华东勘测设计研究院有限公司 Multistage biological deodorization system based on odor concentration automatic adjustment
CN211470940U (en) * 2019-08-01 2020-09-11 中国电建集团华东勘测设计研究院有限公司 Sewage treatment plant microorganism high-efficiency deodorization system based on temperature regulation
CN212663210U (en) * 2020-04-20 2021-03-09 中国市政工程中南设计研究总院有限公司 Bury formula sewage treatment plant combination deodorizing device

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1157756A (en) * 1997-08-11 1999-03-02 Clean Kasei:Kk Biologically deodorizing method and device therefor
JP2002119826A (en) * 2000-10-17 2002-04-23 Ebara Corp Method of deodorizing malodorous gas and device for the same
CN201546384U (en) * 2009-09-28 2010-08-11 河南科达节能环保有限公司 Solar hot-pressing ventilation roof and solar hot-pressing ventilation building
CN106635210A (en) * 2016-11-17 2017-05-10 南京工业大学 Method for removing hydrogen sulfide in biogas by using Acidithiobacillus caldus
CN210286880U (en) * 2019-06-12 2020-04-10 中国市政工程西北设计研究院有限公司 Underground sewage plant ventilation aeration system capable of reducing operation energy consumption
CN211462719U (en) * 2019-07-22 2020-09-11 中国电建集团华东勘测设计研究院有限公司 Multistage biological deodorization system based on odor concentration automatic adjustment
CN211470940U (en) * 2019-08-01 2020-09-11 中国电建集团华东勘测设计研究院有限公司 Sewage treatment plant microorganism high-efficiency deodorization system based on temperature regulation
CN212663210U (en) * 2020-04-20 2021-03-09 中国市政工程中南设计研究总院有限公司 Bury formula sewage treatment plant combination deodorizing device

Also Published As

Publication number Publication date
CN114618279B (en) 2023-02-21

Similar Documents

Publication Publication Date Title
CN2870960Y (en) Marsh-gas desulfurizer
CN202569951U (en) Device for performing biological deodorization and waste gas treatment on sewage
CN106178930B (en) A kind of life assemblage deodorization technique and its device
CN108079763A (en) Life in the countryside and aquaculture wastewater processing anaerobic pond sealing deodorizing lid and its processing method
CN204247069U (en) Microorganism filter bed associating deodoration system
CN210286880U (en) Underground sewage plant ventilation aeration system capable of reducing operation energy consumption
CN114618279B (en) Emission reduction system for removing stink and greenhouse gas by using sulfur autotrophic bacteria and building method
CN206273334U (en) A kind of sewage plant process stink collection and cleaning treatment system
CN211384519U (en) Make gas circulating water odor treatment system
CN205925430U (en) Little biological filter deodorizing device
CN201644098U (en) Activated carbon deodorization device
CN202803110U (en) Portable stench biodegradation device
CN201534058U (en) Device utilizing biological soil to filter and deodorize
CN107737517A (en) Method of eliminating malodours from gases and device based on microorganism
CN103657397A (en) Biological treatment method and device for waste gas produced by printing and dyeing wastewater
CN219376444U (en) Solar deodorizing umbrella device for sewage plant
CN219518382U (en) Sewage station deodorizing device
CN203329621U (en) Low wind-resistance mixed filter material bio-deodorizing device
CN216171223U (en) Novel waste gas deodorization device combining chemical washing tower and biological filter
CN1830835A (en) Biological deodorization method and device for reclaimed water system
CN207221687U (en) A kind of reinforced biological soil deodoration system
CN204251466U (en) Sewage work's odor purification and aeration association system
CN113144819A (en) Solar deodorization floating ball for water treatment
CN209238658U (en) A kind of air quantity self-balancing type odor collection system
CN222342495U (en) Waste water treatment waste gas collecting and treating device

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant