CN114477349A - Multi-section ammonia nitrogen recovery equipment and recovery system thereof - Google Patents

Multi-section ammonia nitrogen recovery equipment and recovery system thereof Download PDF

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Publication number
CN114477349A
CN114477349A CN202111598198.4A CN202111598198A CN114477349A CN 114477349 A CN114477349 A CN 114477349A CN 202111598198 A CN202111598198 A CN 202111598198A CN 114477349 A CN114477349 A CN 114477349A
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China
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ammonia nitrogen
groove
wastewater
module
value
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单孟洋
沈晓光
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Honglei Mechanical Equipment Nantong Co ltd
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Honglei Mechanical Equipment Nantong Co ltd
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Priority to CN202111598198.4A priority Critical patent/CN114477349A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)

Abstract

The invention discloses a multi-section ammonia nitrogen recovery device and a recovery system thereof, which comprise an ammonia nitrogen recovery device and an ammonia nitrogen recovery system, the ammonia nitrogen recovery device comprises a stripping tower, the lower end of the stripping tower is fixedly provided with a bracket, the inner side of the bracket is fixedly provided with a motor, a motor shaft is fixedly arranged on the inner side of the motor, a lifting groove is arranged on the inner side of the motor shaft, the inner side of the lifting groove is axially and movably connected with a lifting piston, the periphery of the upper end of the lifting piston is fixedly connected with air injection fan blades, an air pump is fixedly arranged on the inner side of the bracket and is connected with a pipeline at the bottom of the lifting groove, a control box is fixedly arranged on the inner side of the bracket, a resistance groove is fixedly arranged on the right side of the stripping tower, a resistance block is movably connected on the inner side of the resistance groove, the conductive liquid is arranged on the inner side of the resistance groove, and the high-efficiency recovery function is conveniently and efficiently realized.

Description

Multi-section ammonia nitrogen recovery equipment and recovery system thereof
Technical Field
The invention is applied to the background of wastewater treatment and is named multi-section ammonia nitrogen recovery equipment and a recovery system thereof.
Background
The ammonia nitrogen refers to nitrogen existing in the form of free ammonia (NH3) and ammonium ions (NH4+) in water, the nitrogen content of animal organic matters is generally higher than that of plant organic matters, meanwhile, nitrogen-containing organic matters in human and animal feces are unstable and are easy to decompose into ammonia, therefore, when the content of the ammonia nitrogen in the water is increased, the compound nitrogen existing in the form of ammonia or ammonium ions is referred to as ammonia hydrate, namely non-ionic ammonia, wherein the natural surface water body and underground water body mainly contain nitrate nitrogen (NO3), and the ammonia nitrogen of the nitrogen water body existing in the form of free ammonia (NH3) and ammonium ions (NH4+) is referred to as ammonia hydrate, the non-ionic ammonia is a main factor causing aquatic organism toxicity, the ammonium ions are relatively basically non-toxic, the concentration of the non-ionic ammonia nitrogen is less than or equal to 1 mg/L, the ammonia nitrogen is a nutrient in the water body, and can cause the water eutrophication phenomenon and is a main oxygen-consuming pollutant in the water body, the method has the advantages of simple process, stable treatment effect, low capital cost and operation cost, and the air stripping method is a method for stripping free ammonia nitrogen from the waste water by utilizing the gas separation law (Henry law) through different gas partial pressures, and has the specific principle that the air stripping is used under the alkaline condition by utilizing the difference between the actual concentration and the equilibrium concentration of volatile substances such as the ammonia nitrogen and the like contained in the waste water, and the ammonia concentration in the gas phase is changed because the gas is continuously discharged in the air stripping process, so that the actual concentration is always smaller than the equilibrium concentration under the condition, and finally the ammonia dissolved in the waste water passes through the gas-liquid interface, NH3-N in the wastewater is removed, and air is often used as a carrier. Ammonia stripping is a mass transfer process, the driving force comes from the difference between the partial pressure of ammonia in the air and the balanced partial pressure equivalent to the concentration of ammonia in the waste water, the partial pressure of gas components in the liquid surface and the concentration in the liquid accord with the Henry's theorem, namely, a direct proportion relation, the practicability is strong, however, the PH value and the temperature of the waste water need to be accurately adjusted when ammonia nitrogen is treated by utilizing a stripping method, when the experimental PH value is 11, the removal rate of ammonia nitrogen in the waste water is the highest, and the temperature control of the PH value and the waste water by the existing stripping device is not comprehensive enough, so that the concentration of the ammonia nitrogen in the effluent is high, therefore, a multi-section ammonia nitrogen recovery device and a recovery system thereof are necessary to be provided, and the effect of high-efficiency recovery can be achieved.
Disclosure of Invention
The invention aims to provide multi-section ammonia nitrogen recovery equipment and a recovery system thereof, which aim to solve the problems in the background technology.
In order to solve the technical problems, the invention provides the following technical scheme: a multi-section ammonia nitrogen recovery device and a recovery system thereof comprise an ammonia nitrogen recovery device, wherein the ammonia nitrogen recovery device comprises a blow-off tower, a support is fixedly arranged at the lower end of the blow-off tower, a motor is fixedly arranged on the inner side of the support, a motor shaft is fixedly arranged on the inner side of the motor, a lifting groove is arranged on the inner side of the motor shaft, a lifting piston is movably connected with the inner side of the lifting groove in the axial direction, air jet fan blades are fixedly connected with the periphery of the upper end of the lifting piston, an air pump is fixedly arranged on the inner side of the support and connected with a pipeline at the bottom of the lifting groove, a control box is fixedly arranged on the inner side of the support, a resistance groove is fixedly arranged on the right side of the blow-off tower, a resistance block is movably connected with the inner side of the resistance groove, conductive liquid is arranged on the inner side of the resistance groove, a double-section air cylinder is fixedly arranged on the upper end of the resistance groove, the lower shaft end of the double-section cylinder is fixedly connected with the resistance block, the upper end of the resistance block is electrically connected with the power supply, the lower end of the resistance groove is fixedly provided with the contact block, the inner side of the blow-off tower is fixedly provided with the heating ring, the contact block is electrically connected with the heating ring, and the double-section cylinder is electrically connected with the control box.
In one embodiment, the inboard fixed mounting who blows the tower has ammonia nitrogen tester, be provided with the ooff valve in the inboard pipeline of lift piston, the ooff valve is connected with the control box electricity, the upper end of lift piston is provided with detects the groove, the inboard upper end fixed mounting who blows the tower has storage cabin, the lower extreme of storage cabin is provided with the conduction groove, the inboard swing joint in conduction groove has the conduction piston, the lower extreme fixed mounting in storage cabin has the camera, the upper end in lift groove is provided with the response groove, the inboard swing joint in response groove has the response piston, the upper end in response groove is connected with the left end pipeline in conduction groove.
In one embodiment, a temporary storage box is fixedly installed at the left end of the storage cabin, a lower end pipeline of the temporary storage box is connected with a flow limiting box, the inner side of the flow limiting box is movably connected with a flow limiting block, and the lower end of the flow limiting box is connected with a left end pipeline of the conduction groove.
In one embodiment, an adjusting cabin is fixedly mounted at the upper end of the right side of the stripping tower, an adjusting wheel is connected to an inner side bearing of the adjusting cabin, a servo motor is fixedly mounted at the front end of the adjusting cabin, the shaft end of the servo motor is fixedly connected with the center of the adjusting wheel, the servo motor is electrically connected with a control box, and a water level detector is fixedly mounted at the bottom of the stripping tower.
In one embodiment, the ammonia nitrogen recovery system comprises a preliminary adjusting module and a reset adjusting module, wherein the preliminary adjusting module comprises an ammonia nitrogen detecting module, an analysis judging module and a temperature adjusting module, the reset adjusting module comprises an acid-base detecting module, an acid-base judging module and a calculation adding module, the preliminary adjusting module and the reset adjusting module are respectively in infinite electric connection, the preliminary adjusting module is used for automatically adjusting the temperature of a stripping material, and the reset adjusting module is used for re-allocating the pH value to ensure the dissociation rate of the ammonia nitrogen when the dissociation rate of the ammonia nitrogen is greatly reduced;
the ammonia nitrogen detection module is in signal connection with an ammonia nitrogen tester, the temperature regulation module is in signal connection with the control box, the acid-base detection module is in signal connection with the camera, the calculation adding module is in signal connection with the control box, and the calculation adding module is in signal connection with the water level detector.
In one embodiment, the operation of the ammonia nitrogen recovery system comprises the following steps:
s1, detecting the concentration of ammonia nitrogen in the wastewater in real time through an ammonia nitrogen tester;
s2, analyzing the change of the ammonia nitrogen concentration in the wastewater at each time point along with the time, and judging whether the removal efficiency is reduced or not and how much the removal efficiency is reduced;
s3, automatically adjusting the temperature of the wastewater in the stripping tower according to the change of the ammonia nitrogen dissociation rate, thereby reducing the reduction of the dissociation rate as much as possible;
s4, when the dissociation rate of ammonia nitrogen cannot be effectively ensured by adjusting the temperature, stopping blowing off to detect the pH value of the wastewater;
s5, calculating the amount of the quicklime required to be added to reach PH11 according to the detected pH value, adding and readjusting the pH value;
and S6, repeating the steps S1-S5 to realize the high-efficiency recovery of ammonia nitrogen.
In one embodiment, the ammonia nitrogen detection module, the analysis and judgment module and the temperature adjustment module in the steps S1-S3 are as follows:
s31, detecting the ammonia nitrogen concentration Y in the wastewater in real time through an ammonia nitrogen tester;
s32, setting the reduction speed of the ammonia nitrogen concentration as V when the PH value in the wastewater is 11Combination of Chinese herbsAccording to the ammonia nitrogen concentration Y in the wastewater measured in real time, the reduction speed V of the ammonia nitrogen concentration in the wastewater in real time can be calculatedFruit of Chinese wolfberryWhen V isFruit of Chinese wolfberry<90%VCombination of Chinese herbsWhen the temperature is regulated, the control box gives a signal to control the double-section air cylinder to extend out of the first section of stroke so as to raise the heating temperature of the heating ring, and after the regulation is finished, V is regulatedFruit of Chinese wolfberryAgain less than 90% VCombination of Chinese herbsAnd when the temperature is higher than the preset temperature, the double-section cylinder is controlled to extend out of the second section of stroke to raise the heating temperature again.
In one embodiment, the manner of the acid-base detection module and the acid-base determination module in S4 is as follows:
s41, when the heating temperature of the heating ring is 35 ℃ at most and VFruit of Chinese wolfberry<90%VCombination of Chinese herbsWhen the wastewater is treated, a signal is sent to the control box to control the switch valve to be closed, so that the blowing-off is stopped, and the pH value of the wastewater is detected;
s42, the purple litmus is dripped into the detection groove, the camera is used for shooting the color change of the wastewater in the detection groove, the acid-base judgment module is used for judging the acid-base property of the wastewater at the moment according to the characteristics that the purple litmus is changed into red when meeting acid and is changed into blue when meeting alkali, and the color depth is compared with the standard pH color depth, so that the pH value L of the wastewater at the moment is obtained.
In one embodiment, the manner of calculating the adding module in S5 is as follows:
s51, in order to reach the qualified pH value of the wastewater, the pH value to be increased is U, and the formula is shown as follows;
U=11-L
s52, adding the pH value of each unit of liquid to be raised when the stripping tower is fullThe amount of the added quicklime is R, the water level height when the bin is full is M through a water level detector, the water level height detected when the pH value needs to be adjusted is N, and the amount of the added quicklime actually needed is RFruit of Chinese wolfberryThe formula is as follows:
Rfruit of Chinese wolfberry=UR(N/M)
According to the calculated quantity R of the quicklime required to be addedFruit of Chinese wolfberryAnd the servo motor drives the adjusting wheel to rotate the amount of the quicklime falling for a circle, and the number of turns required to be rotated by the servo motor is calculated, so that the pH value of the wastewater in the stripping tower is adjusted to a proper value, and the dissociation rate of ammonia nitrogen in the wastewater is ensured.
Compared with the prior art, the invention has the following beneficial effects: according to the invention, by arranging the ammonia nitrogen recovery device and the ammonia nitrogen recovery system, the temperature can be automatically adjusted according to the detected reduction speed of the ammonia nitrogen concentration in the wastewater so as to ensure the dissociation rate of the ammonia nitrogen, and the pH value in the wastewater is readjusted when the temperature is adjusted to the maximum value and the dissociation rate cannot be ensured, so that the ammonia nitrogen dissociation rate is ensured, and the recovery efficiency of the ammonia nitrogen is greatly improved.
Drawings
The technical solution and other advantages of the present application will become apparent from the detailed description of the embodiments of the present application with reference to the accompanying drawings.
In the drawings:
FIG. 1 is a schematic view of the overall structure of the present invention;
FIG. 2 is a schematic front elevational view in general section of the present invention;
FIG. 3 is an enlarged schematic view of area A of the present invention;
FIG. 4 is an enlarged schematic view of area B of the present invention;
FIG. 5 is an enlarged schematic view of region C of the present invention;
FIG. 6 is a schematic diagram of the overall system architecture of the present invention;
in the figure: 1. a stripping tower; 2. a regulation cabin; 3. a support; 4. an air pump; 5. a motor; 6. a control box; 7. a motor shaft; 8. a lift piston; 9. an on-off valve; 10. a lifting groove; 11. a jet fan blade; 12. an induction tank; 13. an induction piston; 14. a detection tank; 15. an adjustment wheel; 16. a servo motor; 17. a heating ring; 18. a storage compartment; 19. a camera; 20. a conduction groove; 21. conducting the piston; 22. a temporary storage box; 23. a flow-limiting box; 24. a flow limiting block; 25. a resistance slot; 26. a resistance block; 27. a contact block; 28. two sections of cylinders.
Detailed Description
The following disclosure provides many different embodiments or examples for implementing different features of the application. In order to simplify the disclosure of the present application, specific example components and arrangements are described below. Of course, they are merely examples and are not intended to limit the present application. Moreover, the present application may repeat reference numerals and/or letters in the various examples, such repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed. In addition, examples of various specific processes and materials are provided herein, but one of ordinary skill in the art may recognize applications of other processes and/or use of other materials.
Referring to fig. 1-6, the present invention provides the following technical solutions: a multi-section ammonia nitrogen recovery device and a recovery system thereof comprise an ammonia nitrogen recovery device which comprises a blowing tower 1, wherein a bracket 3 is fixedly arranged at the lower end of the blowing tower 1, a motor 5 is fixedly arranged at the inner side of the bracket 3, a motor shaft 7 is fixedly arranged at the inner side of the motor 5, a lifting groove 10 is arranged at the inner side of the motor shaft 7, a lifting piston 8 is axially and movably connected with the inner side of the lifting groove 10, jet fan blades 11 are fixedly connected with the periphery of the upper end of the lifting piston 8, an air pump 4 is fixedly arranged at the inner side of the bracket 3, the air pump 4 is connected with a pipeline at the bottom of the lifting groove 10, a control box 6 is fixedly arranged at the inner side of the bracket 3, a resistance groove 25 is fixedly arranged at the right side of the blowing tower 1, a resistance block 26 is movably connected with the inner side of the resistance groove 25, conductive liquid is arranged at the inner side of the resistance groove 25, a double-section cylinder 28 is fixedly arranged at the upper end of the resistance groove 25, and the lower shaft end of the double-section cylinder 28 is fixedly connected with the resistance block 26, the upper end of the resistance block 26 is electrically connected with a power supply, the lower end of the resistance slot 25 is fixedly provided with a contact block 27, the inner side of the air stripping tower 1 is fixedly provided with a heating ring 17, the contact block 27 is electrically connected with the heating ring 17, the two-section cylinder 28 is electrically connected with the control box 6, the wastewater with the PH value adjusted to 11 is injected into the air stripping tower 1, air is injected into the jet fan blades 11 through a pipeline between the motor shaft 7 and the lifting piston 8 by the air pump 4 and is jetted out, the motor shaft 7 is driven by the motor 5 to rotate so as to drive the lifting piston 8 and the jet fan blades 11 to rotate and improve the air stripping effect, a resistance is formed between the resistance block 26 and the contact block 27 through the conductive liquid in the inner side of the resistance slot 25, the resistance block 26 is positioned at the upper end of the inner side of the resistance slot 25 when the two-section cylinder 28 is not in an extending state, the resistance between the resistance block 26 and the contact block 27 is larger, at the moment, the current obtained by the heating ring 17 through the contact block 27 is smaller, the heating temperature of the heating ring 17 is at the lowest level, when the first section of stroke of the double-section cylinder 28 is controlled to extend through the control box 6, the resistance block 26 is pushed to move to the middle position of the resistance groove 25, the resistance between the resistance block 26 and the contact block 27 is reduced at the moment, the current obtained by the heating ring 17 is increased, the heating temperature of the heating ring 17 is at the second level at the moment, when the second section of stroke of the double-section cylinder 28 is controlled to extend through the control box 6, the resistance block 26 is pushed to move to the bottom of the resistance groove 25, the resistance block 26 is directly contacted with the contact block 27 at the moment, the current obtained by the heating ring 17 is the largest, the heating temperature is at the highest level, and therefore, the dissociation rate of ammonia nitrogen is adjusted by controlling the heating temperature of the wastewater according to actual conditions, and energy consumption is reduced;
an ammonia nitrogen tester 29 is fixedly installed on the inner side of the stripping tower 1, a switch valve 9 is arranged in a pipeline on the inner side of the lifting piston 8, the switch valve 9 is electrically connected with the control box 6, a detection groove 14 is arranged on the upper end of the lifting piston 8, a storage cabin 18 is fixedly installed on the upper end of the inner side of the stripping tower 1, a conduction groove 20 is arranged on the lower end of the storage cabin 18, a conduction piston 21 is movably connected with the inner side of the conduction groove 20, a camera 19 is fixedly installed on the lower end of the storage cabin 18, an induction groove 12 is arranged on the upper end of the lifting groove 10, an induction piston 13 is movably connected with the inner side of the induction groove 12, the upper end of the induction groove 12 is connected with a pipeline on the left end of the conduction groove 20, the switch valve 9 is controlled to be closed through the control box 6, gas pumped in by the air pump 4 is blocked by the switch valve 9, the air pressure on the bottom of the lifting groove 10 is increased to push the lifting piston 8 to move upwards, when the air injection fan blades 11 are pushed out of the waste level by the lifting piston 8, the induction piston 13 is upwards extruded by the lifting piston 8, oil in the induction groove 12 is extruded by the induction piston 13 under the stress, the oil enters the left end of the conduction groove 20 through a pipeline, the conduction piston 21 moves towards the right side under the pressure of the oil, so that a hole in the conduction piston 21 is communicated with an outlet pipeline of the storage cabin 18, purple litmus stored in the storage cabin 18 falls down from an outlet and is dripped into the detection groove 14 with a small amount of waste water, the purple litmus reacts with the waste water, and the color of liquid in the detection groove 14 is shot through the camera 19, so that the function of automatically detecting the pH value of the waste water is completed;
the left end of the storage chamber 18 is fixedly provided with a temporary storage tank 22, the lower end of the temporary storage tank 22 is connected with a flow limiting tank 23 through a pipeline, the inner side of the flow limiting tank 23 is movably connected with a flow limiting block 24, the lower end of the flow limiting tank 23 is connected with the left end pipeline of the conduction groove 20, when the induction piston 13 is pressed down, oil in the induction groove 12 is extruded to generate pressure, the oil flows to the temporary storage tank 22 and the conduction groove 20 through the pipeline, when the oil flows to the temporary storage tank 22, the flow entering the temporary storage tank 22 is small under the influence of the flow limiting block 24 in the flow limiting tank 23, most of the oil extruded by the induction piston 13 enters the conduction groove 20, when the induction piston 13 stops moving, the oil in the conduction groove 20 is pressed into the temporary storage tank 22 under the elastic force of a spring on the right side of the conduction piston 21, so that a hole on the conduction piston 21 and the storage chamber 18 are automatically closed after a period of communication, and a large amount of purple litmus is prevented from flowing out, influence the detection effect;
an adjusting cabin 2 is fixedly installed at the upper end of the right side of the stripping tower 1, an inner side bearing of the adjusting cabin 2 is connected with an adjusting wheel 15, a servo motor 16 is fixedly installed at the front end of the adjusting cabin 2, the shaft end of the servo motor 16 is fixedly connected with the center of the adjusting wheel 15, the servo motor 16 is electrically connected with a control box 6, a water level detector is fixedly installed at the bottom of the stripping tower 1, quicklime is placed inside the adjusting cabin 2, the servo motor 16 drives the adjusting wheel 15 to rotate clockwise to put equivalent quicklime into the stripping tower 1 so as to adjust the pH value of wastewater, blades around the adjusting wheel 15 are divided into six equivalent areas, the number of rotating circles of the adjusting wheel 15 is controlled through the servo motor 16, the adding amount of the quicklime is controlled finely, and the dissociation rate of ammonia nitrogen in the wastewater is ensured;
the ammonia nitrogen recovery system comprises a preliminary adjusting module and a reset adjusting module, wherein the preliminary adjusting module comprises an ammonia nitrogen detecting module, an analysis judging module and a temperature adjusting module, the reset adjusting module comprises an acid-base detecting module, an acid-base judging module and a calculating adding module, the preliminary adjusting module and the reset adjusting module are respectively in infinite electric connection, the preliminary adjusting module is used for automatically adjusting the temperature of a blow-off material, the reset adjusting module is used for re-allocating the pH value to ensure the dissociation rate of the ammonia nitrogen when the dissociation rate of the ammonia nitrogen is greatly reduced, the ammonia nitrogen detecting module is used for detecting the concentration of the ammonia nitrogen in the waste water in real time, the analysis judging module is used for judging whether the dissociation rate is reduced according to the speed of reducing the concentration of the ammonia nitrogen in the waste water, the temperature adjusting module is used for automatically adjusting the temperature according to the speed of reducing the concentration of the ammonia nitrogen to ensure the dissociation rate of the ammonia nitrogen, the acid-base detection module is used for detecting the pH value of the wastewater through purple litmus, the acid-base judgment module is used for judging the specific pH value through the color of the mixed purple litmus and wastewater, and the calculation and addition module is used for calculating the amount of quicklime required to be added when the wastewater reaches the proper pH value through the detected pH value;
the ammonia nitrogen detection module is in signal connection with an ammonia nitrogen tester 29, the temperature regulation module is in signal connection with the control box 6, the acid-base detection module is in signal connection with the camera 19, the calculation addition module is in signal connection with the control box 6, and the calculation addition module is in signal connection with the water level detector;
the operation of the ammonia nitrogen recovery system comprises the following steps:
s1, detecting the concentration of ammonia nitrogen in the wastewater in real time through an ammonia nitrogen tester 29;
s2, analyzing the change of the ammonia nitrogen concentration in the wastewater at each time point along with the time, and judging whether the removal efficiency is reduced or not and how much the removal efficiency is reduced;
s3, automatically adjusting the temperature of the wastewater in the stripping tower 1 according to the change of the ammonia nitrogen dissociation rate, thereby reducing the decrease of the dissociation rate as much as possible;
s4, when the dissociation rate of ammonia nitrogen cannot be effectively ensured by adjusting the temperature, stopping blowing off to detect the pH value of the wastewater;
s5, calculating the amount of the quicklime required to be added to reach PH11 according to the detected pH value, adding and readjusting the pH value;
s6, repeating the steps S1-S5 to realize the high-efficiency recovery of ammonia nitrogen;
the ammonia nitrogen detection module, the analysis and judgment module and the temperature regulation module in the manners of S1-S3 are as follows:
s31, detecting the ammonia nitrogen concentration Y in the wastewater in real time through an ammonia nitrogen tester;
s32, setting the reduction speed of the ammonia nitrogen concentration as V when the PH value in the wastewater is 11Combination of Chinese herbsAccording to the ammonia nitrogen concentration Y in the wastewater measured in real time, the reduction speed V of the ammonia nitrogen concentration in the wastewater in real time can be calculatedFruit of Chinese wolfberryWhen V isFruit of Chinese wolfberry<90%VCombination of Chinese herbsWhen the temperature is raised, the signal is given to the control box 6 to control the double-section air cylinder 28 to extend out of the first section of stroke, so that the heating temperature of the heating ring 17 is raised, and after the regulation is finished, V is adjustedFruit of Chinese wolfberryAgain less than 90% VCombination of Chinese herbsWhen the temperature is higher than the preset temperature, the double-section air cylinder 28 is controlled to extend out of the second section of stroke to raise the heating temperature again;
the heating temperature of the heating ring 17 is set to 3 grades, the lowest is 20 ℃, the next is 30 ℃, the highest is 35 ℃, when the PH value of the wastewater is 11, the temperature of the wastewater has little influence on the dissociation rate of ammonia nitrogen, when the PH value of the wastewater is reduced, the lower the temperature is, the lower the dissociation rate of ammonia nitrogen is, so that the wastewater with the proper PH value is put into the blow-off tower 1 in an initial state, the heating temperature of the wastewater is 20 ℃, the energy consumption is reduced as much as possible under the condition of not influencing the dissociation rate, but along with the blow-off, the PH value of the wastewater can be continuously reduced, the dissociation rate of ammonia nitrogen can be ensured by increasing the temperature, and the purpose of high efficiency and energy saving can be achieved;
the acid-base detection module and the acid-base judgment module in the S4 are in the following modes:
s41, when the heating temperature of the heating ring 17 is 35 ℃ at most and VFruit of Chinese wolfberry<90%VCombination of Chinese herbsWhen the wastewater is treated, a signal is sent to the control box 6 to control the switch valve 9 to be closed, so that the blowing-off is stopped, and the pH value of the wastewater is detected;
s42, dripping purple litmus into the detection tank 14, shooting the color change of the wastewater in the detection tank 14 by using the camera 19, judging the pH value of the wastewater at the moment by using the acid-base judgment module according to the characteristics that the purple litmus changes into red when encountering acid and changes into blue when encountering alkali, and comparing the color depth with the color depth of a standard pH value so as to obtain the pH value L of the wastewater at the moment;
the manner of calculating the addition module in S5 is as follows:
s51, in order to reach the qualified pH value of the wastewater, the pH value to be increased is U, and the formula is shown as follows;
U=11-L
s52, setting the amount of quicklime required to be added every time a PH value of a unit is raised to be R when the stripping tower 1 is full, measuring the water level height when the stripping tower is full through a water level detector to be M, and measuring the water level height when the pH value is required to be adjusted to be N, wherein the amount of the quicklime actually required to be added is RFruit of Chinese wolfberryThe formula is as follows:
Rfruit of Chinese wolfberry=UR(N/M)
According to the calculated quantity R of the quicklime required to be addedFruit of Chinese wolfberryAnd the servo motor 16 drives the adjusting wheel 15 to rotate the amount of the quicklime falling for a circle, and the number of turns required to rotate by the servo motor 16 is calculated, so that the pH value of the wastewater in the stripping tower 1 is adjusted to a proper value, and the dissociation rate of ammonia nitrogen in the wastewater is ensured.
In the description of the present application, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; may be mechanically connected, may be electrically connected or may be in communication with each other; may be directly connected, may be internal to the two elements or may be in an interactive relationship with the two elements. The above terms are understood in the present application by those of ordinary skill in the art as appropriate.
The above detailed description is provided for a cleaning device provided in the embodiments of the present application, and the principle and the implementation of the present application are explained in the present application by applying specific examples, and the description of the above embodiments is only used to help understanding the technical solution and the core idea of the present application; those of ordinary skill in the art will understand that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; such modifications or substitutions do not depart from the spirit and scope of the present disclosure as defined by the appended claims.

Claims (9)

1. The utility model provides a multistage formula ammonia nitrogen recovery plant, contains ammonia nitrogen recovery unit, its characterized in that: the ammonia nitrogen recovery device comprises a stripping tower (1), wherein a support (3) is fixedly mounted at the lower end of the stripping tower (1), a motor (5) is fixedly mounted on the inner side of the support (3), a motor shaft (7) is fixedly mounted on the inner side of the motor (5), a lifting groove (10) is formed in the inner side of the motor shaft (7), a lifting piston (8) is movably connected to the inner side of the lifting groove (10) in the axial direction, jet fan blades (11) are fixedly connected to the periphery of the upper end of the lifting piston (8), an air pump (4) is fixedly mounted on the inner side of the support (3), the air pump (4) is connected with a pipeline at the bottom of the lifting groove (10), a control box (6) is fixedly mounted on the inner side of the support (3), a resistance groove (25) is fixedly mounted on the right side of the stripping tower (1), and a resistance block (26) is movably connected to the inner side of the resistance groove (25), the inboard of resistance groove (25) sets up conducting liquid, the upper end fixed mounting of resistance groove (25) has two section cylinders (28), the lower axle head and the resistance piece (26) fixed connection of two section cylinders (28), the upper end electricity of resistance piece (26) is connected with the power, the lower extreme fixed mounting of resistance groove (25) has contact piece (27), the inboard fixed mounting of blow-off tower (1) has heating ring (17), contact piece (27) are connected with heating ring (17) electricity, two section cylinders (28) are connected with control box (6) electricity.
2. The multi-stage ammonia nitrogen recovery device of claim 1, which is characterized in that: the utility model discloses a take-off device, including blowing tower (1), lift piston (8), be provided with ooff valve (9) in the inboard pipeline of lift piston (8), ooff valve (9) are connected with control box (6) electricity, the upper end of lift piston (8) is provided with detects groove (14), the inboard upper end fixed mounting of blowing tower (1) has storage cabin (18), the lower extreme of storage cabin (18) is provided with conduction-through groove (20), the inboard swing joint of conduction-through groove (20) has conduction-through piston (21), the lower extreme fixed mounting of storage cabin (18) has camera (19), the upper end of lift groove (10) is provided with response groove (12), the inboard swing joint of response groove (12) has response piston (13), the upper end of response groove (12) is connected with the left end pipeline of conduction-through groove (20).
3. The multi-stage ammonia nitrogen recovery device of claim 2, which is characterized in that: the left end fixed mounting of storage cabin (18) has temporary storage case (22), the lower extreme pipe connection of temporary storage case (22) has current-limiting case (23), the inboard swing joint current-limiting piece (24) of current-limiting case (23), the lower extreme of current-limiting case (23) is connected with the left end pipe connection of conduction groove (20).
4. The multi-stage ammonia nitrogen recovery device of claim 2 or 3, wherein: blow off the right side upper end fixed mounting of tower (1) and have regulation cabin (2), the inboard bearing of regulation cabin (2) is connected with regulating wheel (15), the front end fixed mounting who adjusts cabin (2) has servo motor (16), the axle head of servo motor (16) and the central fixed connection of regulating wheel (15), servo motor (16) are connected with control box (6) electricity, the bottom fixed mounting of blowing off tower (1) has the water level detection appearance.
5. The utility model provides a multistage formula ammonia nitrogen recovery system, contains ammonia nitrogen recovery system, its characterized in that: the ammonia nitrogen recovery system comprises a preliminary adjusting module and a resetting adjusting module, wherein the preliminary adjusting module comprises an ammonia nitrogen detecting module, an analysis judging module and a temperature adjusting module, the resetting adjusting module comprises an acid-base detecting module, an acid-base judging module and a calculation adding module, the preliminary adjusting module and the resetting adjusting module are respectively in infinite electric connection, the preliminary adjusting module is used for automatically adjusting the temperature of a stripping material, and the resetting adjusting module is used for re-allocating the pH value to ensure the dissociation rate of the ammonia nitrogen when the dissociation rate of the ammonia nitrogen is greatly reduced;
the ammonia nitrogen detection module is in signal connection with an ammonia nitrogen tester (29), the temperature regulation module is in signal connection with the control box (6), the acid-base detection module is in signal connection with the camera (19), the calculation adding module is in signal connection with the control box (6), and the calculation adding module is in signal connection with the water level detector.
6. The multi-stage ammonia nitrogen recovery system of claim 5, wherein: the operation of the ammonia nitrogen recovery system comprises the following steps:
s1, detecting the concentration of ammonia nitrogen in the wastewater in real time through an ammonia nitrogen tester (29);
s2, analyzing the change of the ammonia nitrogen concentration in the wastewater at each time point along with the time, and judging whether the removal efficiency is reduced or not and how much the removal efficiency is reduced;
s3, automatically adjusting the temperature of the wastewater in the stripping tower (1) according to the change of the ammonia nitrogen dissociation rate, thereby reducing the decrease of the dissociation rate as much as possible;
s4, when the dissociation rate of ammonia nitrogen cannot be effectively ensured by adjusting the temperature, stopping blowing off to detect the pH value of the wastewater;
s5, calculating the amount of the quicklime required to be added to reach PH11 according to the detected pH value, adding and readjusting the pH value;
and S6, repeating the steps S1-S5 to realize the high-efficiency recovery of ammonia nitrogen.
7. The multi-stage ammonia nitrogen recovery system of claim 6, wherein: the ammonia nitrogen detection module, the analysis and judgment module and the temperature regulation module in the manners of S1-S3 are as follows:
s31, detecting the ammonia nitrogen concentration Y in the wastewater in real time through an ammonia nitrogen tester;
s32, setting the reduction speed of the ammonia nitrogen concentration as V when the PH value in the wastewater is 11Combination of Chinese herbsAccording to the ammonia nitrogen concentration Y in the wastewater measured in real time, the reduction speed V of the ammonia nitrogen concentration in the wastewater in real time can be calculatedFruit of Chinese wolfberryWhen V isFruit of Chinese wolfberry<90%VCombination of Chinese herbsAt the same time, through giving the control box(6) The signal controls the double-section cylinder (28) to extend out of the first section of stroke so as to raise the heating temperature of the heating ring (17), and after the regulation is finished, VFruit of Chinese wolfberryAgain less than 90% VCombination of Chinese herbsAnd meanwhile, the double-section air cylinder (28) is also controlled to extend out of the second section of stroke to raise the heating temperature again.
8. The multi-stage ammonia nitrogen recovery system of claim 7, wherein: the acid-base detection module and the acid-base judgment module in the S4 are in the following modes:
s41, when the heating temperature of the heating ring (17) is 35 ℃ at most and VFruit of Chinese wolfberry<90%VCombination of Chinese herbsWhen the wastewater is treated, a signal is sent to the control box (6) to control the switch valve (9) to be closed, so that the blowing-off is stopped, and the pH value of the wastewater is detected;
s42, the purple litmus is dripped into the detection groove (14), the camera (19) is used for shooting the color change of the wastewater in the detection groove (14), the acid-base judgment module is used for judging the acid-base property of the wastewater at the moment according to the characteristics that the purple litmus changes into red when meeting acid and changes into blue when meeting alkali, and the color depth is compared with the color depth of a standard PH value, so that the PH value L of the wastewater at the moment is obtained.
9. The multi-stage ammonia nitrogen recovery system of claim 8, wherein: the manner of calculating the addition module in S5 is as follows:
s51, in order to reach the qualified pH value of the wastewater, the pH value to be increased is U, and the formula is shown as follows;
U=11-L
s52, setting the amount of quicklime needed to be added every time a PH value of a unit is raised to be R when the stripping tower (1) is full, measuring the water level height when the stripping tower is full through a water level detector to be M, and measuring the water level height when the pH value needs to be adjusted to be N, wherein the amount of the quicklime actually needed to be added is RFruit of Chinese wolfberryThe formula is as follows:
Rfruit of Chinese wolfberry=UR(N/M)
According to the calculated quantity R of the quicklime required to be addedFruit of Chinese wolfberryAnd the servo motor (16) drives the adjusting wheel (15) to rotate for a circle to fall down the raw stoneThe amount of ash calculates and obtains the number of turns of required rotation of servo motor (16), thereby ensuring that the pH value of the wastewater in the stripping tower (1) is adjusted to a proper value, and ensuring the dissociation rate of ammonia nitrogen in the wastewater.
CN202111598198.4A 2021-12-24 2021-12-24 Multi-section ammonia nitrogen recovery equipment and recovery system thereof Pending CN114477349A (en)

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