CN1141285A - 适用在齐格勒-纳塔催化剂制备中使用的二醚 - Google Patents
适用在齐格勒-纳塔催化剂制备中使用的二醚 Download PDFInfo
- Publication number
- CN1141285A CN1141285A CN96105750A CN96105750A CN1141285A CN 1141285 A CN1141285 A CN 1141285A CN 96105750 A CN96105750 A CN 96105750A CN 96105750 A CN96105750 A CN 96105750A CN 1141285 A CN1141285 A CN 1141285A
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- CN
- China
- Prior art keywords
- methoxyl methyl
- fluorenes
- methyl
- indenes
- equal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 22
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 12
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 10
- 150000002367 halogens Chemical class 0.000 claims abstract description 9
- -1 methoxyl methyl Chemical group 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 20
- 239000002585 base Substances 0.000 claims description 17
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 16
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 150000002220 fluorenes Chemical class 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 11
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 10
- 150000002469 indenes Chemical class 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 238000010189 synthetic method Methods 0.000 claims description 6
- XZKPFRIEWDWYDH-UHFFFAOYSA-N 1-(methoxymethyl)-9h-fluorene Chemical class C1C2=CC=CC=C2C2=C1C(COC)=CC=C2 XZKPFRIEWDWYDH-UHFFFAOYSA-N 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- GPTXWRGISTZRIO-UHFFFAOYSA-N chlorquinaldol Chemical compound ClC1=CC(Cl)=C(O)C2=NC(C)=CC=C21 GPTXWRGISTZRIO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- KBPQOHWZZITULV-UHFFFAOYSA-N 1-(1-methoxyethyl)-9h-fluorene Chemical class C1C2=CC=CC=C2C2=C1C(C(C)OC)=CC=C2 KBPQOHWZZITULV-UHFFFAOYSA-N 0.000 claims description 2
- GWZYQIFDRYREJD-UHFFFAOYSA-N 1-cyclopentyl-9H-fluorene Chemical class C1(CCCC1)C1=CC=CC=2C3=CC=CC=C3CC1=2 GWZYQIFDRYREJD-UHFFFAOYSA-N 0.000 claims description 2
- FSLIJWKFJDIQES-UHFFFAOYSA-N CC(C1(C(C(C)=CC=C2)=C2C2=CC=CC=C12)OC)OC Chemical class CC(C1(C(C(C)=CC=C2)=C2C2=CC=CC=C12)OC)OC FSLIJWKFJDIQES-UHFFFAOYSA-N 0.000 claims description 2
- BCBSZQPSTVJFKB-UHFFFAOYSA-N CCOCC1(C(C(C)=CC=C2)=C2C2=CC=CC=C12)OC Chemical class CCOCC1(C(C(C)=CC=C2)=C2C2=CC=CC=C12)OC BCBSZQPSTVJFKB-UHFFFAOYSA-N 0.000 claims description 2
- VTDFVCIYZGVOMP-UHFFFAOYSA-N [O].CC1=CC=CC=2C3=CC=CC=C3CC12 Chemical class [O].CC1=CC=CC=2C3=CC=CC=C3CC12 VTDFVCIYZGVOMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003153 chemical reaction reagent Substances 0.000 claims description 2
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- IAGDDPYFLFGQCX-UHFFFAOYSA-N 1-fluoro-9h-fluorene Chemical class C12=CC=CC=C2CC2=C1C=CC=C2F IAGDDPYFLFGQCX-UHFFFAOYSA-N 0.000 claims 1
- KVUNGQZMTJQBSF-UHFFFAOYSA-N 5,6-dichloro-1-(1-methoxyethyl)-1h-indene Chemical class ClC1=C(Cl)C=C2C(C(C)OC)C=CC2=C1 KVUNGQZMTJQBSF-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 5
- 125000003118 aryl group Chemical group 0.000 abstract description 4
- 229920006395 saturated elastomer Polymers 0.000 abstract description 3
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 3
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 3
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 13
- OQKYEMHWZYHWBL-UHFFFAOYSA-N 9h-fluoren-1-ylmethanol Chemical class C1C2=CC=CC=C2C2=C1C(CO)=CC=C2 OQKYEMHWZYHWBL-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000002902 bimodal effect Effects 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 238000006266 etherification reaction Methods 0.000 description 4
- 229910000104 sodium hydride Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 229910052756 noble gas Inorganic materials 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- DKVSUVZNYVKYRX-UHFFFAOYSA-N 1-(methoxymethyl)-1h-indene Chemical class C1=CC=C2C(COC)C=CC2=C1 DKVSUVZNYVKYRX-UHFFFAOYSA-N 0.000 description 1
- AYAWAOFYRKTFLD-UHFFFAOYSA-N 1-(phenoxymethyl)-1h-indene Chemical class C1=CC2=CC=CC=C2C1COC1=CC=CC=C1 AYAWAOFYRKTFLD-UHFFFAOYSA-N 0.000 description 1
- DNUJVGBNIXGTHC-UHFFFAOYSA-N 3,6-dihydro-2h-oxazine Chemical compound C1NOCC=C1 DNUJVGBNIXGTHC-UHFFFAOYSA-N 0.000 description 1
- PJKWPBGXUWKQPJ-UHFFFAOYSA-N 9h-xanthene-1-sulfonic acid Chemical class O1C2=CC=CC=C2CC2=C1C=CC=C2S(=O)(=O)O PJKWPBGXUWKQPJ-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- UHOIPYIURDGEKJ-UHFFFAOYSA-N O(C)C1(C(=CC2=CC=CC(=C12)C(C)(C)C)C)C(C)OC Chemical class O(C)C1(C(=CC2=CC=CC(=C12)C(C)(C)C)C)C(C)OC UHOIPYIURDGEKJ-UHFFFAOYSA-N 0.000 description 1
- VWOIZFFGWZIVOK-UHFFFAOYSA-N O(C)CC1CCC2=CC=CC(=C12)C1=CC=CC=C1 Chemical compound O(C)CC1CCC2=CC=CC(=C12)C1=CC=CC=C1 VWOIZFFGWZIVOK-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 238000005882 aldol condensation reaction Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- KXDAEFPNCMNJSK-UHFFFAOYSA-N benzene carboxamide Natural products NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- GMNNKZQYNNOQPT-UHFFFAOYSA-N cyclohepta-1,2,4-triene Chemical compound C1CC=C=CC=C1 GMNNKZQYNNOQPT-UHFFFAOYSA-N 0.000 description 1
- 239000005343 cylinder glass Substances 0.000 description 1
- QPJORFLSOJAUNL-UHFFFAOYSA-N dibenzo[a,d][7]annulene Chemical compound C1=CC2=CC=CC=C2CC2=CC=CC=C21 QPJORFLSOJAUNL-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- SHFJWMWCIHQNCP-UHFFFAOYSA-M hydron;tetrabutylazanium;sulfate Chemical compound OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC SHFJWMWCIHQNCP-UHFFFAOYSA-M 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 150000003732 xanthenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/162—Unsaturated ethers containing rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/164—Unsaturated ethers containing six-membered aromatic rings
- C07C43/168—Unsaturated ethers containing six-membered aromatic rings containing six-membered aromatic rings and other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/17—Unsaturated ethers containing halogen
- C07C43/174—Unsaturated ethers containing halogen containing six-membered aromatic rings
- C07C43/1747—Unsaturated ethers containing halogen containing six-membered aromatic rings containing six membered aromatic rings and other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/78—Ring systems having three or more relevant rings
- C07D311/80—Dibenzopyrans; Hydrogenated dibenzopyrans
- C07D311/82—Xanthenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
- C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
- C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
- C07C2603/18—Fluorenes; Hydrogenated fluorenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
- C07C2603/24—Anthracenes; Hydrogenated anthracenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
- C07C2603/28—Phenalenes; Hydrogenated phenalenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Description
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI95A000316 | 1995-02-21 | ||
ITMI950316A IT1274250B (it) | 1995-02-21 | 1995-02-21 | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011451874A Division CN1210243C (zh) | 1995-02-21 | 1996-02-18 | 二醚的合成方法 |
CNB021278466A Division CN1289451C (zh) | 1995-02-21 | 1996-02-18 | 适用在齐格勒-纳塔催化剂制备中使用的二醚 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1141285A true CN1141285A (zh) | 1997-01-29 |
CN1121368C CN1121368C (zh) | 2003-09-17 |
Family
ID=11370615
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011451874A Expired - Fee Related CN1210243C (zh) | 1995-02-21 | 1996-02-18 | 二醚的合成方法 |
CNB021278466A Expired - Fee Related CN1289451C (zh) | 1995-02-21 | 1996-02-18 | 适用在齐格勒-纳塔催化剂制备中使用的二醚 |
CN96105750A Expired - Fee Related CN1121368C (zh) | 1995-02-21 | 1996-02-18 | 适用在齐格勒-纳塔催化剂制备中使用的二醚 |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011451874A Expired - Fee Related CN1210243C (zh) | 1995-02-21 | 1996-02-18 | 二醚的合成方法 |
CNB021278466A Expired - Fee Related CN1289451C (zh) | 1995-02-21 | 1996-02-18 | 适用在齐格勒-纳塔催化剂制备中使用的二醚 |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0728724A1 (zh) |
JP (1) | JP3615861B2 (zh) |
CN (3) | CN1210243C (zh) |
IT (1) | IT1274250B (zh) |
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WO2007076639A1 (fr) | 2006-01-04 | 2007-07-12 | China Petroleum & Chemical Corporation | Composant de catalyseur pour la polymerisation ou la copolymerisation d'olefines, son procede de preparation, catalyseur contenant ledit composant de catalyseur et son utilisation |
WO2007112700A1 (en) | 2006-04-06 | 2007-10-11 | China Petroleum & Chemical Corporation | Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom |
CN100389112C (zh) * | 2004-12-16 | 2008-05-21 | 中国石油化工股份有限公司 | 一类环状缩醛和缩酮化合物及其应用 |
CN101560273B (zh) * | 2009-04-24 | 2011-03-23 | 营口市向阳催化剂有限责任公司 | 烯烃聚合催化剂、制备方法及聚合方法 |
WO2011044760A1 (zh) | 2009-10-16 | 2011-04-21 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及包含其的催化剂 |
WO2011047522A1 (zh) | 2009-10-20 | 2011-04-28 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法 |
CN105384611A (zh) * | 2014-12-03 | 2016-03-09 | 苏州亚培克生物科技有限公司 | 一种齐格勒-纳塔催化剂的给电子体及其制备方法 |
US9499569B2 (en) | 2009-07-15 | 2016-11-22 | China Petroleum & Chemical Corporation | Spherical magnesium halide adduct, a catalyst component and a catalyst for olefin polymerization prepared therefrom |
WO2020078352A1 (zh) | 2018-10-19 | 2020-04-23 | 中国石油化工股份有限公司 | 用于烯烃聚合催化剂组分、催化剂及其应用 |
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US5869418A (en) * | 1994-05-31 | 1999-02-09 | Borealis Holding A/S | Stereospecific catalyst system for polymerization of olefins |
NL1003007C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding. |
NL1003018C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerde indeen. |
NL1003004C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met onderling verschillende groepen gesubstitueerde cyclopentadieen- verbinding. |
NL1003013C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met cyclische groepen gesubstitueerde cyclopentadieenverbinding. |
NL1003008C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerde cyclopentadieen- verbinding. |
US6117811A (en) * | 1996-05-03 | 2000-09-12 | Dsm N.V. | Cyclopentadiene compound substituted with linear groups |
US6124488A (en) * | 1996-05-03 | 2000-09-26 | Dsm N.V. | Cyclopentadiene compound substituted with branched alkyl groups |
NL1003011C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom bevattende groep gesubstitueerde cyclopentadieen- verbinding. |
NL1003017C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Met een heteroatoom-bevattende groep gesubstitueerd fluoreen. |
NL1003016C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Gesubstitueerde pentadieenverbinding. |
FR2771092B1 (fr) * | 1997-11-18 | 1999-12-17 | Rhone Poulenc Rorer Sa | Procede de preparation de derives de la classe des taxoides |
US6436864B1 (en) | 1999-10-06 | 2002-08-20 | Sri International | Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts |
ES2322047T3 (es) | 2002-03-08 | 2009-06-16 | Basell Poliolefine Italia S.R.L. | Proceso para obtener un componente catalizador basado en un dieter. |
CN100338018C (zh) | 2004-10-29 | 2007-09-19 | 中国石油化工股份有限公司 | 一种环戊酯类化合物及其合成方法和应用 |
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US10526427B2 (en) | 2015-12-18 | 2020-01-07 | Japan Polypropylene Corporation | Method for producing solid catalyst component for α-olefin polymerization and method for producing α-olefin polymer using the same |
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JP2018188636A (ja) | 2017-05-10 | 2018-11-29 | 日本ポリプロ株式会社 | プロピレン・エチレン・1−ブテンターポリマー及びその製造方法 |
US20210403691A1 (en) | 2018-11-19 | 2021-12-30 | Sabic Global Technologies B.V. | Food packaging comprising a polymer composition and use of said polymer composition for manufacturing of food packaging |
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CN116041577A (zh) | 2021-10-28 | 2023-05-02 | 中国石油化工股份有限公司 | 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1129147B (de) * | 1959-12-08 | 1962-05-10 | Hoechst Ag | Verfahren zur Herstellung von Dialkylpolyalkylenglykolen |
IT1227260B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
IT1243924B (it) * | 1990-11-20 | 1994-06-28 | Himont Inc | Procedimento per la preparazione di dieteri |
-
1995
- 1995-02-21 IT ITMI950316A patent/IT1274250B/it active IP Right Grant
-
1996
- 1996-02-18 CN CNB011451874A patent/CN1210243C/zh not_active Expired - Fee Related
- 1996-02-18 CN CNB021278466A patent/CN1289451C/zh not_active Expired - Fee Related
- 1996-02-18 CN CN96105750A patent/CN1121368C/zh not_active Expired - Fee Related
- 1996-02-21 JP JP05843996A patent/JP3615861B2/ja not_active Expired - Fee Related
- 1996-02-21 EP EP96102586A patent/EP0728724A1/en not_active Withdrawn
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100389112C (zh) * | 2004-12-16 | 2008-05-21 | 中国石油化工股份有限公司 | 一类环状缩醛和缩酮化合物及其应用 |
WO2007076639A1 (fr) | 2006-01-04 | 2007-07-12 | China Petroleum & Chemical Corporation | Composant de catalyseur pour la polymerisation ou la copolymerisation d'olefines, son procede de preparation, catalyseur contenant ledit composant de catalyseur et son utilisation |
WO2007112700A1 (en) | 2006-04-06 | 2007-10-11 | China Petroleum & Chemical Corporation | Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom |
CN101560273B (zh) * | 2009-04-24 | 2011-03-23 | 营口市向阳催化剂有限责任公司 | 烯烃聚合催化剂、制备方法及聚合方法 |
US9499569B2 (en) | 2009-07-15 | 2016-11-22 | China Petroleum & Chemical Corporation | Spherical magnesium halide adduct, a catalyst component and a catalyst for olefin polymerization prepared therefrom |
US10239969B2 (en) | 2009-07-15 | 2019-03-26 | China Petroleum & Chemical Corporation | Spherical magnesium halide adduct, a catalyst component and a catalyst for olefin polymerization prepared therefrom |
US9243086B2 (en) | 2009-10-16 | 2016-01-26 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and catalyst comprising the same |
US9321857B2 (en) | 2009-10-16 | 2016-04-26 | China Petroleum & Chemical Corporation | Carrier for olefin polymerization catalyst, preparation method and application thereof |
WO2011044760A1 (zh) | 2009-10-16 | 2011-04-21 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及包含其的催化剂 |
WO2011047522A1 (zh) | 2009-10-20 | 2011-04-28 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法 |
CN105384611A (zh) * | 2014-12-03 | 2016-03-09 | 苏州亚培克生物科技有限公司 | 一种齐格勒-纳塔催化剂的给电子体及其制备方法 |
CN105384611B (zh) * | 2014-12-03 | 2019-04-19 | 亚培烯科技(杭州)有限公司 | 一种齐格勒-纳塔催化剂的给电子体及其制备方法 |
WO2020078352A1 (zh) | 2018-10-19 | 2020-04-23 | 中国石油化工股份有限公司 | 用于烯烃聚合催化剂组分、催化剂及其应用 |
US11970510B2 (en) | 2018-10-19 | 2024-04-30 | China Petroleum & Chemical Corporation | Catalyst component and catalyst for olefin polymerization, and application thereof |
Also Published As
Publication number | Publication date |
---|---|
ITMI950316A0 (it) | 1995-02-21 |
JPH08333413A (ja) | 1996-12-17 |
CN1473809A (zh) | 2004-02-11 |
EP0728724A1 (en) | 1996-08-28 |
CN1121368C (zh) | 2003-09-17 |
CN1289451C (zh) | 2006-12-13 |
IT1274250B (it) | 1997-07-15 |
ITMI950316A1 (it) | 1996-08-21 |
JP3615861B2 (ja) | 2005-02-02 |
CN1491929A (zh) | 2004-04-28 |
CN1210243C (zh) | 2005-07-13 |
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