Garbage furnace and coal-fired furnace flue gas parallel treatment device and method
Technical Field
The invention relates to the technical field of power station boilers and industrial boilers, in particular to a device and a method for treating flue gas of a garbage furnace and a coal-fired furnace in parallel.
Background
The clearing and transporting amount of Chinese domestic garbage and the production amount of industrial garbage rise year by year, the garbage has great harm to the environment, mainly manifested by land encroachment, atmosphere pollution, soil and water body pollution, and the caused harm is difficult to recover, the treatment principle of Chinese domestic garbage solid waste is reduction, resource utilization and harmlessness, for the parts with heat values in the domestic garbage and part of industrial garbage, such as paper, wood, plastics, textile waste, waste rubber leather and the like, the resource utilization of the waste can be realized while the problem of solid waste disposal is solved by adopting incineration technology; the solid waste incineration treatment has two modes, one mode uses a single incineration device, and the other mode adopts a co-firing technology, namely various power station boilers or industrial kilns are used for mixing and incinerating the waste and the solid waste;
at present, the prior art is mostly applied to producing building materials by coupling a coal-fired boiler with solid waste power generation and cooperatively processing solid waste by a cement kiln, and because the chlorine content in household garbage and combustible industrial garbage is generally high, the cement production has strict limitation on the chlorine content in raw materials, and the coal-fired boiler is mostly applied in the co-firing treatment of the combustible garbage solid waste;
in view of the higher chlorine content in the domestic garbage and the combustible industrial garbage, the flue gas treatment is a great technical difficulty no matter the domestic garbage and the combustible industrial garbage are separately incinerated or co-fired: when the single incineration is adopted, if a flue gas treatment system matched with incineration equipment is completely built, the original investment of the newly built incinerator is further improved, and the construction period is prolonged; when a coal-fired boiler is adopted for co-firing, the combustion temperature level is high, the corrosion hazard of chlorine is obvious, the comprehensive resource utilization of ash slag generated by coal combustion is not facilitated (particularly for a fluidized bed boiler), in addition, the slag and coking are easily caused by alkali metal in garbage, the solid waste mixed combustion amount of the coal-fired boiler is limited by the factors, and the coal-fired boiler is usually close to an industrial garbage generating enterprise, so that the development of a technical process for organically combining an independent combustion technology and the coal-fired boiler is of great significance for the disposal of solid waste of garbage, particularly combustible industrial garbage.
Disclosure of Invention
The invention aims to provide a device and a method for treating flue gas of a garbage furnace and a coal-fired furnace in parallel, which atomize Na2CO3 solution into a flue of a solid waste furnace, realize high-efficiency removal of acid gases such as HCl in the flue gas, and avoid corrosion to downstream flues and equipment.
The above purpose is realized by the following technical scheme:
a garbage furnace and coal-fired furnace flue gas parallel processing device comprises: solid waste furnace, the flue gas mouth and the separator of solid waste furnace are connected, the hot ash mouth of separator is connected with returning charge ware, external bed respectively, the flue gas mouth and the afterbody flue of separator are connected, afterbody flue export is connected with coal-fired furnace, desulfurizing tower respectively, afterbody flue in install atomizer, sprayer respectively, the atomizer respectively with lye tank, gas tank connection, lye tank pass through the conveyer and be connected with the soda ash bin, lye tank be connected with the soft water tank, the sprayer respectively with the active carbon storehouse gas tank connection, the gas tank connection air compressor machine.
The garbage furnace and coal-fired furnace flue gas parallel processing device, the material returning device and the external bed are respectively connected with the material returning port of the solid waste furnace, the desulfurizing tower is connected with the dust remover, and the dust remover is connected with the chimney.
A garbage furnace and coal-fired furnace flue gas parallel processing device and a processing method thereof comprise the following steps:
firstly, solid waste is incinerated in a solid waste furnace, generated flue gas enters a separator through a flue gas port arranged in the solid waste furnace, the flue gas is separated from large-particle fly ash, the separator is additionally provided with a hot ash port and a flue gas port, the separated fly ash enters a material returning device and an external bed through the hot ash port respectively, a high-temperature heating surface is arranged in the material returning device, hot ash exchanges heat with steam in the material returning device to improve the steam temperature and further improve the boiler efficiency, the material returning device is connected with an outlet of the external bed and is provided with a material returning port, and the hot ash returns to the solid waste furnace through the material returning port after staying for a certain time in the material returning device and the external bed for secondary combustion and material circulation;
the flue gas primarily purified by the separator enters a tail flue from a flue gas port, and an outlet of the tail flue and an outlet of the coal-fired furnace are both connected to an inlet of a desulfurizing tower, namely, the flue gas generated by the solid waste furnace and the coal-fired furnace enters the desulfurizing tower for desulfurizing and purifying, then enters a dust remover connected with the desulfurizing tower for dedusting and purifying, and finally is discharged into the atmosphere from a chimney;
the soda ash bin is connected with an alkali liquor tank through a conveyor, namely, waste soda ash in the soda ash bin is conveyed into an alkali liquor tank by the conveyor, the alkali liquor tank is simultaneously provided with a soft water inlet and an alkali liquor outlet, the soft water inlet is connected with the soft water tank, namely, soft water enters the alkali liquor tank to dissolve the waste soda ash to form alkali liquor, the alkali liquor outlet is connected with an alkali liquor channel of a sprayer, the sprayer is additionally provided with a high-pressure gas channel to be connected with a gas storage tank, compressed air from an air compressor is stored in the gas storage tank, namely, the compressed air breaks and atomizes the soda ash solution into small liquid drops in the sprayer, the gas storage tank is also connected with an injector inlet simultaneously with the activated carbon bin, namely, the compressed air is utilized to realize the injection of activated carbon particles;
the sprayer and the sprayer outlet are positioned in the tail flue, the sprayer outlet sprays out the atomized droplets of the soda ash solution, the HCl acid components generated by burning solid wastes in the flue gas are removed by using the soda ash solution, the activated carbon particles are sprayed out of the sprayer outlet to adsorb dioxin in the flue gas, and the dioxin is physically adsorbed by using the larger specific surface area of the activated carbon;
the flue gas is deacidified and detoxified and then is converged with the flue gas generated by the coal-fired furnace, and then further flue gas purification is completed through a desulfurizing tower and a dust remover matched with the coal-fired furnace, and finally the flue gas is emptied.
Has the advantages that:
1. the invention relates to a device for treating flue gas of a garbage furnace and a coal-fired furnace in parallel, which can atomize Na2CO3 solution to be sprayed into a flue of a solid waste furnace, realizes the high-efficiency removal of acid gases such as HCl in the flue gas, avoids the corrosion to a downstream flue and equipment, simultaneously sprays activated carbon particles into the flue, realizes the high-efficiency removal of dioxin in the flue gas, ensures that the emission of the dioxin reaches the standard, is incorporated into a flue gas purification system of the coal-fired boiler after dechlorination and detoxification of the flue gas, does not need related purification equipment of the solid waste furnace, reduces the original investment, shortens the construction period, and avoids influencing the comprehensive utilization of conventional ash residues of the coal-fired boiler.
According to the invention, the activated carbon particles are sprayed into the flue of the solid waste furnace, so that the dioxin in the flue gas can be efficiently removed, the toxicity in the flue gas is reduced, and the emission of the dioxin is ensured to reach the standard.
The flue gas is dechlorinated and detoxified and then is merged into a flue gas purification system of the coal-fired boiler, the original flue gas purification equipment of the coal-fired boiler can be utilized, the new construction of related equipment for a solid waste boiler is not needed, the original investment is reduced, the construction period is shortened, and meanwhile, the flue gas generated by solid waste incineration can be prevented from influencing the utilization of conventional ash generated by the coal-fired boiler.
The invention is not limited by the combination of the furnace types in the embodiment, and can also be applied to the combination of various solid waste incinerators and coal-fired boilers, and the application range is wider.
Description of the drawings:
FIG. 1 is a schematic structural diagram of the present invention.
Wherein: 1. the system comprises a solid waste furnace, 2, a separator, 3, a material returning device, 4, an external bed, 5, a tail flue, 6, a soft water tank, 7, an alkali liquor tank, 8, a conveyor, 9, a soda ash bin, 10, an air compressor, 11 air storage tanks, 12 sprayers, 13 coal-fired furnaces, 14 desulfurizing towers, 15 dust collectors, 16 chimneys, 17 activated carbon bins and 18 sprayers.
The specific implementation mode is as follows:
example 1:
a garbage furnace and coal-fired furnace flue gas parallel processing device comprises: solid waste furnace 1, the flue gas mouth and the separator 2 of solid waste furnace are connected, the hot grey mouth of separator is connected with returning glassware 3, external bed 4 respectively, the flue gas mouth and the afterbody flue 5 of separator are connected, the afterbody flue export is connected with coal-fired furnace 13, desulfurizing tower 14 respectively, the afterbody flue in install atomizer 12, sprayer 18 respectively, the atomizer be connected with lye tank 7, gas holder 11 respectively, lye tank pass through conveyer 8 and be connected with soda storehouse 9, lye tank and soft water tank 6 be connected, the sprayer respectively with activated carbon storehouse 17 the gas tank connection, gas tank connection air compressor machine 10.
Example 2:
according to the device for treating the flue gas of the garbage furnace and the coal-fired furnace in parallel in the embodiment 1, the material returning device and the external bed are respectively connected with the material returning port of the solid waste furnace, the desulfurizing tower is connected with the dust remover 15, and the dust remover is connected with the chimney 16.
Example 3:
the treatment method of the device for treating the flue gas of the garbage furnace and the coal-fired furnace in parallel according to the embodiment 1 or 2 comprises the following steps:
firstly, solid waste is incinerated in a solid waste furnace, generated flue gas enters a separator through a flue gas port arranged in the solid waste furnace, the flue gas is separated from large-particle fly ash, the separator is additionally provided with a hot ash port and a flue gas port, the separated fly ash enters a material returning device and an external bed through the hot ash port respectively, a high-temperature heating surface is arranged in the material returning device, hot ash exchanges heat with steam in the material returning device to improve the steam temperature and further improve the boiler efficiency, the material returning device is connected with an outlet of the external bed and is provided with a material returning port, and the hot ash returns to the solid waste furnace through the material returning port after staying for a certain time in the material returning device and the external bed for secondary combustion and material circulation;
the flue gas primarily purified by the separator enters a tail flue from a flue gas port, and an outlet of the tail flue and an outlet of the coal-fired furnace are both connected to an inlet of a desulfurizing tower, namely, the flue gas generated by the solid waste furnace and the coal-fired furnace enters the desulfurizing tower for desulfurizing and purifying, then enters a dust remover connected with the desulfurizing tower for dedusting and purifying, and finally is discharged into the atmosphere from a chimney;
the soda ash bin is connected with an alkali liquor tank through a conveyor, namely, waste soda ash (the main component is sodium carbonate) in the soda ash bin is conveyed into the alkali liquor tank by the conveyor, the alkali liquor tank is simultaneously provided with a soft water inlet and an alkali liquor outlet, the soft water inlet is connected with the soft water tank, namely, soft water enters the alkali liquor tank to dissolve the waste soda ash to form alkali liquor, the alkali liquor outlet is connected with an alkali liquor channel of a sprayer, the sprayer is additionally provided with a high-pressure air channel to be connected with an air storage tank, the air storage tank stores compressed air from an air compressor, namely, the compressed air breaks and atomizes the soda solution into small liquid drops in the sprayer, the air storage tank is also connected with an injector inlet simultaneously with the activated carbon bin, namely, the compressed air is utilized to realize the injection of activated carbon particles;
the sprayer and the sprayer outlet are positioned in the tail flue, the sprayer outlet sprays out the atomized liquid drops of the soda ash liquid, the acid components such as HCl generated by burning solid wastes in the flue gas are removed by using the soda ash liquid, and the main reaction equation is as follows:
the active carbon particles sprayed out of the outlet of the ejector adsorb dioxin in the flue gas, and the main principle is that the active carbon has a larger specific surface area to realize stronger physical adsorption of the dioxin;
deacidifying and detoxifying the flue gas, then converging the flue gas with the flue gas generated by the coal-fired furnace, then completing further flue gas purification through a desulfurizing tower and a dust remover matched with the coal-fired furnace, and finally emptying;
the alkali liquor tank, the sprayer and a passage through which the alkali liquor flows are made of corrosion-resistant materials;
the method can also adopt another treatment method, and the tail flue is directly connected to the inlet of the desulfurizing tower through the flue;
or, a dust remover is additionally arranged in the middle section of the flue connected between the tail flue and the desulfurizing tower, part of fly ash is returned to the activated carbon bin after being separated, and then the fly ash and fresh activated carbon are sprayed into the tail flue from an injector, so that the adsorption efficiency of the activated carbon and the deacidification efficiency of Na2CO3 are improved through circulation, and the material consumption of system operation can also be reduced. The dust remover can be any one of a bag-type dust remover, an electric dust remover and a cyclone separation dust remover;
the system can be further provided with related metering equipment to realize the online adjustment and fine control of the quality of the dissolved soda ash, the flow rate of the liquid flowing out and the feeding amount of the active carbon;
in the embodiment of the application, the solid waste furnace is a circulating fluidized bed boiler, and the coal-fired furnace is a pulverized coal boiler, but the structure can be applied to the combination of various solid waste incinerators and coal-fired boilers, such as a grate solid waste furnace + pulverized coal boiler, a rotary kiln solid waste incinerator + circulating fluidized bed boiler, a bubbling bed solid waste furnace + pulverized coal boiler and the like, and has a wide application range.