CN113462848A - Vanadium-extracting slag-gathering agent for converter - Google Patents

Vanadium-extracting slag-gathering agent for converter Download PDF

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Publication number
CN113462848A
CN113462848A CN202110689512.3A CN202110689512A CN113462848A CN 113462848 A CN113462848 A CN 113462848A CN 202110689512 A CN202110689512 A CN 202110689512A CN 113462848 A CN113462848 A CN 113462848A
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CN
China
Prior art keywords
parts
converter
vanadium
slag
conglomeration agent
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CN202110689512.3A
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Chinese (zh)
Inventor
杜鸽
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Individual
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Individual
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Priority to CN202110689512.3A priority Critical patent/CN113462848A/en
Publication of CN113462848A publication Critical patent/CN113462848A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/36Processes yielding slags of special composition
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00Obtaining refractory metals
    • C22B34/20Obtaining niobium, tantalum or vanadium
    • C22B34/22Obtaining vanadium

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

The invention discloses a vanadium extraction slag conglomeration agent for a converter, which comprises the following raw materials in parts by weight: 35-55 parts of albite; 10-15 parts of fluorite; 15-25 parts of raw vermiculite; 4-8 parts of chromium metaborate; 5-15 parts of calcium phosphate; 8-12 parts of perlite; 10-15 parts of petalite; 3-8 parts of boric sludge; 3-15 parts of calcium carbonate; 1-5 parts of salt; 1-5 parts of water; the slag conglomeration agent improves the melting point of the vanadium slag, reduces the loss of the vanadium slag in the semi-steel discharging process, improves the recovery rate of the vanadium slag, reduces the smelting cost of vanadium extraction of a converter, improves the economic benefit of vanadium extraction, can reduce the content of iron oxide in the vanadium slag and improve the grade of the vanadium slag after the vanadium slag conglomeration agent is added, reduces the production cost in the production of the rear process, reduces the oxide in the vanadium slag after the vanadium slag conglomeration agent is added, reduces the erosion of the vanadium slag to the converter lining, and prolongs the service life of the converter lining for vanadium extraction.

Description

Vanadium-extracting slag-gathering agent for converter
Technical Field
The invention relates to the technical field of slag conglomeration agents, in particular to a vanadium extraction slag conglomeration agent for a converter.
Background
In the process of vanadium extraction in the existing converter, because the composition of molten iron changes unusually, the slag state of vanadium slag after vanadium extraction also changes greatly, sometimes the slag is dry, sometimes the slag is dilute, and when the slag is dry: the metal iron content in the vanadium slag is high, the loss of the metal iron is large in the vanadium extraction process, the vanadium slag is difficult to crush, and the smelting cost is increased for extracting vanadium in a converter; when the slag is diluted: in the semi-steel discharging process, a rotational flow is formed on the liquid surface and inside, vanadium slag is directly rolled into the semi-steel, the more the slag is rolled, the more the vanadium slag is rolled away by one furnace, almost one ton of vanadium slag is lost, the price of each ton of vanadium slag reaches more than one ten thousand yuan, and the lost economic benefit is too large.
Therefore, the invention provides a vanadium extraction slag conglomeration agent for a converter.
Disclosure of Invention
Aiming at the technical defects, the invention aims to provide a vanadium extraction slag conglomeration agent for a converter, and solves the technical problem of great change of slag state of vanadium slag after vanadium extraction in the prior art.
In order to solve the technical problems, the invention adopts the following technical scheme:
the invention provides a vanadium extraction slag conglomeration agent for a converter, which comprises the following raw materials in parts by weight:
35-55 parts of albite;
10-15 parts of fluorite;
15-25 parts of raw vermiculite;
4-8 parts of chromium metaborate;
5-15 parts of calcium phosphate;
8-12 parts of perlite;
10-15 parts of petalite;
3-8 parts of boric sludge;
3-15 parts of calcium carbonate;
1-5 parts of salt;
1-5 parts of water.
Preferably, the feed comprises the following raw materials in parts by weight:
35 parts of albite;
10 parts of fluorite;
15 parts of raw vermiculite;
4 parts of chromium metaborate;
5 parts of calcium phosphate;
8 parts of perlite;
10 parts of petalite;
3 parts of boric sludge;
3 parts of calcium carbonate;
1 part of table salt;
and 1 part of water.
Preferably, the feed comprises the following raw materials in parts by weight:
45 parts of albite;
12.5 parts of fluorite;
20 parts of raw vermiculite;
6 parts of chromium metaborate;
10 parts of calcium phosphate;
10 parts of perlite;
12 parts of petalite;
5.8 parts of boric sludge;
10 parts of calcium carbonate;
3 parts of table salt;
and 3 parts of water.
Preferably, the feed comprises the following raw materials in parts by weight:
55 parts of albite;
15 parts of fluorite;
25 parts of raw vermiculite;
8 parts of chromium metaborate;
15 parts of calcium phosphate;
12 parts of perlite;
15 parts of petalite;
8 parts of boric sludge;
15 parts of calcium carbonate;
5 parts of table salt;
and 5 parts of water.
Preferably, the method also comprises a method for preparing the converter vanadium extraction slag conglomeration agent, and the specific steps are as follows: putting 35-55 parts of albite, 10-15 parts of fluorite, 15-25 parts of raw vermiculite, 4-8 parts of chromium metaborate, 5-15 parts of calcium phosphate, 8-12 parts of perlite, 10-15 parts of petalite, 3-8 parts of boric sludge, 3-15 parts of calcium carbonate and 1-5 parts of salt into a grinding machine for grinding until the particle size is 0.1-0.5 mm, then putting the mixed mixture into a mixer, adding 1-5 parts of water while stirring, and uniformly mixing to obtain the vanadium-extracting slag conglomeration agent for the converter.
Preferably, including being used for the converter to carry vanadium and gathering slag agent sprinkler, sprinkler includes the storage tank, the bottom of storage tank is connected with the conveying pipeline, be fixed with the air pump on the outer wall of storage tank, the end of giving vent to anger of air pump is connected with the outlet duct, the one end of outlet duct extends to the inside of storage tank, the lower extreme of outlet duct sets up towards the discharging pipe of storage tank, and the lower extreme of outlet duct is fixed with the shower nozzle.
Preferably, the top of storage tank articulates there is sealed lid, install adjusting valve on the discharging pipe of storage tank.
Preferably, be fixed with fixed cover on the terminal outer wall of conveying pipeline, the top of fixed cover is fixed with the connecting rod, the upper end of connecting rod is fixed with the lead screw cover, the upper end of lead screw cover is fixed with the uide bushing, be fixed with driving motor on the outer wall of storage tank, driving motor's output is fixed with the lead screw, lead screw cover screw drive is on the lead screw, still be fixed with the guide bar that is parallel to each other with the lead screw on the outer wall of storage tank, the uide bushing slides and cup joints on the guide bar.
The invention has the beneficial effects that:
1. the slag conglomeration agent can improve the melting point of the vanadium slag, reduce the loss of the vanadium slag in the semisteel tapping process, improve the recovery rate of the vanadium slag, reduce the smelting cost of vanadium extraction in a converter and improve the economic benefit of vanadium extraction.
2. After the vanadium slag conglomeration agent is added, the iron oxide content in the vanadium slag can be reduced, the grade of the vanadium slag is improved, and the production cost is reduced by the production of the subsequent process.
3. After the vanadium slag conglomeration agent is added, the oxide in the vanadium slag is reduced, the corrosion of the vanadium slag to the converter lining is reduced, and the service life of the converter vanadium extraction lining is prolonged.
4. After the slag conglomeration agent is added into the converter vanadium extracting furnace, the oxidizability of vanadium slag is greatly reduced, the turnover in the semisteel tank is greatly reduced in the semisteel discharging process, the semisteel is prevented from overflowing from the tank in the semisteel discharging process, and the occurrence of safety and environmental protection accidents is reduced.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the drawings without creative efforts.
Fig. 1 is a schematic structural diagram of a spraying device for vanadium extraction and slag conglomeration agent of a converter provided by the embodiment of the invention.
Description of reference numerals:
1. a material storage tank; 2. a sealing cover; 3. an air pump; 4. an air outlet pipe; 5. a spray head; 6. adjusting the valve; 7. a delivery pipe; 8. a guide bar; 9. a drive motor; 10. a screw rod; 11. a screw rod sleeve; 12. a guide sleeve; 13. a connecting rod; 14. and (4) fixing sleeves.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As shown in figure 1, the invention provides a vanadium extraction slag conglomeration agent for a converter, which comprises the following raw materials in parts by weight:
35-55 parts of albite;
10-15 parts of fluorite;
15-25 parts of raw vermiculite;
4-8 parts of chromium metaborate;
5-15 parts of calcium phosphate;
8-12 parts of perlite;
10-15 parts of petalite;
3-8 parts of boric sludge;
3-15 parts of calcium carbonate;
1-5 parts of salt;
1-5 parts of water.
The invention provides a vanadium extraction slag conglomeration agent for a converter, which comprises the following raw materials in parts by weight:
35 parts of albite;
10 parts of fluorite;
15 parts of raw vermiculite;
4 parts of chromium metaborate;
5 parts of calcium phosphate;
8 parts of perlite;
10 parts of petalite;
3 parts of boric sludge;
3 parts of calcium carbonate;
1 part of table salt;
and 1 part of water.
Embodiment 2, the invention provides a vanadium extraction slag conglomeration agent for a converter, which comprises the following raw materials in parts by weight:
45 parts of albite;
12.5 parts of fluorite;
20 parts of raw vermiculite;
6 parts of chromium metaborate;
10 parts of calcium phosphate;
10 parts of perlite;
12 parts of petalite;
5.8 parts of boric sludge;
10 parts of calcium carbonate;
3 parts of table salt;
and 3 parts of water.
Embodiment 3, the invention provides a vanadium extraction slag conglomeration agent for a converter, which comprises the following raw materials in parts by weight:
55 parts of albite;
15 parts of fluorite;
25 parts of raw vermiculite;
8 parts of chromium metaborate;
15 parts of calcium phosphate;
12 parts of perlite;
15 parts of petalite;
8 parts of boric sludge;
15 parts of calcium carbonate;
5 parts of table salt;
and 5 parts of water.
In one embodiment of the invention, the method for preparing the converter vanadium extraction slag conglomeration agent further comprises the following specific steps: putting 35-55 parts of albite, 10-15 parts of fluorite, 15-25 parts of raw vermiculite, 4-8 parts of chromium metaborate, 5-15 parts of calcium phosphate, 8-12 parts of perlite, 10-15 parts of petalite, 3-8 parts of boric sludge, 3-15 parts of calcium carbonate and 1-5 parts of salt into a grinding machine for grinding until the particle size is 0.1-0.5 mm, then putting the mixed mixture into a mixer, adding 1-5 parts of water while stirring, and uniformly mixing to obtain the vanadium-extracting slag conglomeration agent for the converter.
In a specific embodiment of the invention, the spraying device comprises a storage tank 1, the bottom of the storage tank 1 is connected with a material conveying pipe 7, an air pump 3 is fixed on the outer wall of the storage tank 1, the air outlet end of the air pump 3 is connected with an air outlet pipe 4, one end of the air outlet pipe 4 extends into the storage tank 1, the lower end of the air outlet pipe 4 faces a material discharging pipe of the storage tank 1, a nozzle 5 is fixed at the lower end of the air outlet pipe 4, and the air pump 3 is operated, so that the slag conglomeration agent can be added into the converter more quickly, and the problem of blockage of the slag conglomeration agent in the storage tank 1 is effectively avoided.
In one embodiment of the present invention, a sealing cover 2 is hinged to the top of the storage tank 1, and a discharge pipe of the storage tank 1 is provided with an adjusting valve 6, so as to adjust the flow rate.
In a specific embodiment of the invention, a fixed sleeve 14 is fixed on the outer wall of the tail end of the conveying pipe 7, a connecting rod 13 is fixed on the top of the fixed sleeve 14, a screw rod sleeve 11 is fixed on the upper end of the connecting rod 13, a guide sleeve 12 is fixed on the upper end of the screw rod sleeve 11, a driving motor 9 is fixed on the outer wall of the storage tank 1, a screw rod 10 is fixed on the output end of the driving motor 9, the screw rod sleeve 11 is spirally driven on the screw rod 10, a guide rod 8 parallel to the screw rod 10 is further fixed on the outer wall of the storage tank 1, the guide sleeve 12 is slidably sleeved on the guide rod 8, and the driving motor 9 is operated to drive the screw rod sleeve 11 to move left and right, so that the position of the conveying pipe 7 can be adjusted, and slag conglomeration agent is conveniently and uniformly sprayed in the converter.
Economic benefits of using slag accretion agents
After the slag conglomeration agent is added, the original vanadium slag loss is reduced to below 2 percent from 5 percent, and 2 percent is taken as a calculation basis for calculation:
the vanadium slag is produced by 20 ten thousand tons every year.
Then: 20 x (5-2)% =0.6 (ten thousand tons)
The price of the vanadium slag is calculated by ten thousand yuan
0.6 × 10000=6000 (ten thousand yuan)
After the slag conglomeration agent is added, the oxidability of the vanadium slag is greatly reduced, so that the degree of the vanadium slag corroding the furnace lining of the vanadium extraction converter is greatly reduced, and the service life of the furnace lining of the vanadium extraction converter can be prolonged.
The generated benefits are as follows:
after the slag conglomeration agent is added, the V2O3 grade of the vanadium slag can be improved by (1-1.5)% (the data is from a steel-climbing converter experiment), so that the quality of the vanadium slag is improved, and the corresponding cost is reduced for further purifying the V2O 3.
The addition cost of the slag conglomeration agent is 1.5-2 Kg per ton of steel, the price of the slag conglomeration agent is calculated by 3000 yuan/ton, and the cost is calculated according to 600 ten thousand tons of molten iron produced per year.
Then: 2 x 3=6 (yuan)/ton iron
600 × 6=3600 (ten thousand yuan)/year
6000-.
After vanadium slag enters a steelmaking process, because the vanadium slag belongs to meta-acid slag, the consumption of lime is required to be increased in the steelmaking process to adjust the alkalinity, so that the steelmaking cost is increased, sometimes, after the vanadium slag enters the steelmaking process in a large amount, the control is not good in the steelmaking process, the large spraying of a steelmaking converter is very easy to cause larger economic loss to steelmaking.
After the converter vanadium extraction blowing is finished, the slag conglomeration agent is added into the converter and is directly contacted with the vanadium slag to react, the reaction is very quick in a high-temperature state, the reaction is carried out for 4-5 minutes in the process of semi-steel tapping, and the effect of vanadium slag polymerization can be completely achieved
After the slag conglomeration agent is added, in the process of discharging semisteel, the semisteel tank is not overturned, so that the temperature loss caused by overturning in the semisteel discharging process is reduced, meanwhile, the problem that the semisteel overflows from the tank due to overturning of the semisteel, equipment facilities are burnt out is avoided, the occurrence of safety accidents of multiple persons is avoided, and after the overturning of the semisteel is inhibited, the environment-friendly problem that smoke dust overflows due to overturning of the semisteel is reduced.
It will be apparent to those skilled in the art that various changes and modifications may be made in the present invention without departing from the spirit and scope of the invention. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include such modifications and variations.

Claims (8)

1. The vanadium extraction slag conglomeration agent for the converter is characterized by comprising the following raw materials in parts by weight:
35-55 parts of albite;
10-15 parts of fluorite;
15-25 parts of raw vermiculite;
4-8 parts of chromium metaborate;
5-15 parts of calcium phosphate;
8-12 parts of perlite;
10-15 parts of petalite;
3-8 parts of boric sludge;
3-15 parts of calcium carbonate;
1-5 parts of salt;
1-5 parts of water.
2. The vanadium extraction slag conglomeration agent for the converter as claimed in claim 1, which comprises the following raw materials in parts by weight:
35 parts of albite;
10 parts of fluorite;
15 parts of raw vermiculite;
4 parts of chromium metaborate;
5 parts of calcium phosphate;
8 parts of perlite;
10 parts of petalite;
3 parts of boric sludge;
3 parts of calcium carbonate;
1 part of table salt;
and 1 part of water.
3. The vanadium extraction slag conglomeration agent for the converter as claimed in claim 1, which comprises the following raw materials in parts by weight:
45 parts of albite;
12.5 parts of fluorite;
20 parts of raw vermiculite;
6 parts of chromium metaborate;
10 parts of calcium phosphate;
10 parts of perlite;
12 parts of petalite;
5.8 parts of boric sludge;
10 parts of calcium carbonate;
3 parts of table salt;
and 3 parts of water.
4. The vanadium extraction slag conglomeration agent for the converter as claimed in claim 1, which comprises the following raw materials in parts by weight:
55 parts of albite;
15 parts of fluorite;
25 parts of raw vermiculite;
8 parts of chromium metaborate;
15 parts of calcium phosphate;
12 parts of perlite;
15 parts of petalite;
8 parts of boric sludge;
15 parts of calcium carbonate;
5 parts of table salt;
and 5 parts of water.
5. The converter vanadium extraction slag conglomeration agent according to claim 1, further comprising a method for preparing the converter vanadium extraction slag conglomeration agent, and the specific steps are as follows: putting 35-55 parts of albite, 10-15 parts of fluorite, 15-25 parts of raw vermiculite, 4-8 parts of chromium metaborate, 5-15 parts of calcium phosphate, 8-12 parts of perlite, 10-15 parts of petalite, 3-8 parts of boric sludge, 3-15 parts of calcium carbonate and 1-5 parts of salt into a grinding machine for grinding until the particle size is 0.1-0.5 mm, then putting the mixed mixture into a mixer, adding 1-5 parts of water while stirring, and uniformly mixing to obtain the vanadium-extracting slag conglomeration agent for the converter.
6. The converter vanadium extraction slag conglomeration agent according to claim 1, which comprises a spraying device for converter vanadium extraction slag conglomeration agent, wherein the spraying device comprises a storage tank (1), the bottom of the storage tank (1) is connected with a material conveying pipe (7), an air pump (3) is fixed on the outer wall of the storage tank (1), an air outlet end of the air pump (3) is connected with an air outlet pipe (4), one end of the air outlet pipe (4) extends to the inside of the storage tank (1), the lower end of the air outlet pipe (4) faces a discharge pipe of the storage tank (1), and a spray head (5) is fixed at the lower end of the air outlet pipe (4).
7. The converter vanadium extraction slag conglomeration agent according to claim 6, wherein a sealing cover (2) is hinged to the top of the storage tank (1), and a regulating valve (6) is mounted on a discharge pipe of the storage tank (1).
8. The vanadium-extracting slag conglomeration agent for the converter as claimed in claim 6, wherein a fixed sleeve (14) is fixed on the outer wall of the tail end of the conveying pipe (7), a connecting rod (13) is fixed on the top of the fixed sleeve (14), a screw rod sleeve (11) is fixed on the upper end of the connecting rod (13), a guide sleeve (12) is fixed on the upper end of the screw rod sleeve (11), a driving motor (9) is fixed on the outer wall of the storage tank (1), a screw rod (10) is fixed on the output end of the driving motor (9), the screw rod sleeve (11) is in screw transmission on the screw rod (10), a guide rod (8) parallel to the screw rod (10) is further fixed on the outer wall of the storage tank (1), and the guide sleeve (12) is slidably sleeved on the guide rod (8).
CN202110689512.3A 2021-06-22 2021-06-22 Vanadium-extracting slag-gathering agent for converter Pending CN113462848A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110689512.3A CN113462848A (en) 2021-06-22 2021-06-22 Vanadium-extracting slag-gathering agent for converter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110689512.3A CN113462848A (en) 2021-06-22 2021-06-22 Vanadium-extracting slag-gathering agent for converter

Publications (1)

Publication Number Publication Date
CN113462848A true CN113462848A (en) 2021-10-01

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU404380A1 (en) * 1972-04-24 1978-01-25 Чусовский Государственный Металлургический Завод Charge for making agglomerate used for extracting vanadium
CN102586516A (en) * 2012-03-30 2012-07-18 德清县力拓炉料有限公司 Method for preparing slag conglomeration agent for iron steel
CN104818366A (en) * 2015-04-29 2015-08-05 江苏大学 Ladle slag conglomeration agent prepared by boric sludge
CN104928496A (en) * 2015-07-20 2015-09-23 万燕杰 Smelting copper slag accretion agent and preparing method thereof
CN109971921A (en) * 2019-04-26 2019-07-05 南京伊顿派克重工机械有限公司 Slag conglomeration agent sprinkling system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU404380A1 (en) * 1972-04-24 1978-01-25 Чусовский Государственный Металлургический Завод Charge for making agglomerate used for extracting vanadium
CN102586516A (en) * 2012-03-30 2012-07-18 德清县力拓炉料有限公司 Method for preparing slag conglomeration agent for iron steel
CN104818366A (en) * 2015-04-29 2015-08-05 江苏大学 Ladle slag conglomeration agent prepared by boric sludge
CN104928496A (en) * 2015-07-20 2015-09-23 万燕杰 Smelting copper slag accretion agent and preparing method thereof
CN109971921A (en) * 2019-04-26 2019-07-05 南京伊顿派克重工机械有限公司 Slag conglomeration agent sprinkling system

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Application publication date: 20211001