CN113207901A - Application of acidic electrolyzed water mixed with pesticide for sterilizing and killing insects - Google Patents

Application of acidic electrolyzed water mixed with pesticide for sterilizing and killing insects Download PDF

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Publication number
CN113207901A
CN113207901A CN202110306937.1A CN202110306937A CN113207901A CN 113207901 A CN113207901 A CN 113207901A CN 202110306937 A CN202110306937 A CN 202110306937A CN 113207901 A CN113207901 A CN 113207901A
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electrolyzed water
pesticide
acidic electrolyzed
acidic
sterilizing
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CN202110306937.1A
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Chinese (zh)
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李信
徐军
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34Nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to the technical field of planting, discloses an application of mixing acidic electrolyzed water and pesticide to achieve sterilization and deinsectization, and solves the problem of pesticide residue caused by using a large amount of pesticide in the existing fruit and vegetable planting process. The invention achieves the effect of sterilization and deinsectization by mixing the acidic electrolyzed water and the pesticide, reduces the using amount of the pesticide on one hand, reduces the pesticide residue of fruits and vegetables on the other hand, and improves the quality of the fruits and vegetables.

Description

Application of acidic electrolyzed water mixed with pesticide for sterilizing and killing insects
Technical Field
The invention belongs to the technical field of sterilization and deinsectization, and particularly relates to an application of mixing acidic electrolyzed water and pesticide to achieve sterilization and deinsectization.
Background
In order to achieve the effects of sterilization and deinsectization in the planting process of fruits and vegetables, a large amount of pesticides are used in the cultivation process, for example, in the cultivation process of tremella, penicillium, trichoderma, chitinase (commonly called powdery mildew), rhodotorula and the like are mainly harmful to sporocarp, the most common and serious harm is caused to the chitinase, and the diseased lugs form a layer of powder and the tremella sporocarp is hardened. The fruiting body with serious disease should be removed in time, and then controlled by spraying lime sulfur mixture.
For another example, common pests in the process of cultivating tremella include nematodes, mites, fungus flies, slugs and the like, wherein the nematodes are main pests causing ear rot, and the fungi cannot be nourished and rot due to the fact that fungus bases are invaded. The pesticide can be used for preventing and controlling 0.1-0.2% dipterex sprayed on the auricularia auricula-judae, and can inhibit the propagation of nematodes. Mites are also the main pests of tremella, reproduce very quickly, often eat hypha and ear roots, after the occurrence, 0.5% of dichlorvos is applied to spray an earfield and 1: 800 times of 20% wettable acaricide sulfone can be used for soaking the agaric wood (immediately taken out after soaking) or spraying the agaric wood for control, and 800 times of dimethoate or dipterex can also be used for spraying and killing.
The use of a large amount of pesticide can ensure the yield of fruits and vegetables, but also cause pesticide residues on the fruits and vegetables, thereby affecting the quality of the fruits and vegetables.
Disclosure of Invention
The invention aims to solve the problem of pesticide residue caused by using a large amount of pesticide in the existing fruit and vegetable planting process, and provides the purpose of mixing the acidic electrolyzed water and the pesticide to achieve sterilization and deinsectization.
In order to solve the technical problem, the technical scheme adopted by the invention is as follows:
an application of acidic electrolyzed water and agricultural chemical in sterilizing and killing pests.
The acid electrolyzed water is an acid stock solution with the pH value of 1.5-2.0 and generated by using sodium chloride as electrolyte through electrolysis, the oxidation-reduction potential ORP of the acid stock solution is 900 mv-1200 mv, the mass fraction of sodium in the acid stock solution is less than or equal to 0.01%, and the concentration of chlorine in the acid stock solution is 80-150 mg/L.
The volume ratio of the acidic electrolyzed water to the pesticide is 1: 0.1-0.3.
The pesticide is chlorothalonil, chlorpyrifos, trichlorphon, carbendazim, dichlorvos or dimethoate and other common pesticides.
Compared with the prior art, the invention has the following beneficial effects:
the invention utilizes the acidic electrolyzed water and the pesticide to be mixed together to achieve the sterilization and insecticidal effects in the planting process of fruits and vegetables, compared with the mode of adopting a large amount of pesticide in the prior art, the invention can achieve good sterilization and insecticidal effects, simultaneously reduce the dosage of the pesticide and greatly reduce the residue of the pesticide.
Detailed Description
The present invention will be further described with reference to the following examples, which are intended to illustrate only some, but not all, of the embodiments of the present invention. Based on the embodiments of the present invention, other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
An application of acidic electrolyzed water and agricultural chemical in sterilizing and killing pests.
The acid electrolyzed water is an acid stock solution with the pH value of 1.5-2.0 and generated by using sodium chloride as electrolyte through electrolysis, the oxidation-reduction potential ORP of the acid stock solution is 900 mv-1200 mv, the mass fraction of sodium in the acid stock solution is less than or equal to 0.01%, and the concentration of chlorine in the acid stock solution is 80-150 mg/L.
Preferably, the pH of the acidic electrolyzed water is 1.5 to 1.9. In specific implementation, the acid electrolyzed water can be 1.5, 1.6, 1.7, 1.8, 1.9 and 2.0. The pH of the alkaline electrolyzed water is 12.5, 12.7, 12.8, 13.0, 13.1, 13.2, 13.3, 13.4, 13.5, and the pH of the alkaline electrolyzed water is preferably 13.1-1.35.
The ORP value of the acidic electrolyzed water is 900 mv-1200 mv, and the ORP value of the acidic electrolyzed water can be selected from 900mv, 1000mv, 1100mv, 1150mv, 1185mv and 1200mv during the specific production and use process. The ORP value of the preferable acidic electrolyzed water is 1185-1200 mv, and in the range, the ORP value is better for sterilizing and killing insects, and meanwhile, the growth of plants can be promoted.
The effective chlorine concentration of the acidic electrolyzed water can reach 80-150 mg/L, for example, the effective chlorine concentration is 80, 90, 95, 100, 110, 115, 121, 130, 133, 140, 145 and 150 mg/L. Preferably, in order to improve the sterilization and disinsection effects, the effective chlorine concentration is 100-150 mg/L.
The pH value, oxidation-reduction potential and effective chlorine concentration of the acidic electrolyzed water are different from those of the acidic electrolyzed water in the prior art, and the acidic electrolyzed water in the prior art cannot reach the physicochemical indexes of the pH value, ORP value and effective chlorine concentration of the acidic electrolyzed water in the invention.
The volume ratio of the acidic electrolyzed water to the pesticide is 1: 0.1-0.3. In the process of mixing the acidic electrolyzed water and the pesticide, the proportion of the acidic electrolyzed water and the pesticide can be properly adjusted according to the occurrence condition of the pest, so as to achieve the best effect, for example, when the pest is serious, the dosage of the pesticide can be properly increased, and when the pest is light, the dosage of the pesticide can be properly reduced, which is clear and obvious for a person skilled in the art, and is not described herein again.
The pesticide is chlorothalonil, chlorpyrifos, trichlorphon, carbendazim, dichlorvos or dimethoate and other common pesticides.
The following tests were carried out on common fruits and vegetables as follows
Example one
Taking sterilization and disinsection in the process of tremella cultivation as an example
Log sterilizing and insect killing effect table
Figure 336865DEST_PATH_IMAGE002
Sterilization and disinsection effect table in inoculation/spawn running stage in tremella management
Infectious conditions Electrolytic water sterilization and disinsection mode and dilution ratio Result of sterilization and disinsection
Ear hallInfection with nematodes before inoculation Diluting acidic electrolyzed water and Dimethoate with water (the volume ratio of acidic electrolyzed water mixed Dimethoate to water is 1: 3.5) Spraying to the auditorium with the volume ratio of the acidic electrolyzed water to the dimethoate being 1:0.15 No nematodes were detected
Infection with cotton rot fungus before auricular inoculation And mites Diluting the acidic electrolyzed water and lime sulphur with water (the acidic electrolyzed water is mixed with lime sulphur and then mixed with water by volume) Ratio of 1: 6.5) spraying to the auricular, wherein the volume ratio of the acidic electrolyzed water to the lime sulphur is 1:0.25 No cotton rot fungi and mites were detected Class I
Schizophyllum commune infection before auricular inoculation And slugs Adding trichlorfon into the acidic electrolyzed water, diluting the acidic electrolyzed water with water (the acidic electrolyzed water is mixed with the trichlorfon and then diluted with the volume of the water) Ratio of 1: 4) spraying to the auricular, wherein the volume ratio of the acidic electrolyzed water to the trichlorfon is 1:0.3 Schizophyllum commune and Slim were not detected A kind of big slug
Infection of coriolus versicolor and wood before auricular inoculation Mildew, nematode and fungus cord Adding the dichlorvos into the acidic electrolyzed water and diluting the acidic electrolyzed water with water (mixing the acidic electrolyzed water with the dichlorvos and then diluting the mixture with the water volume Ratio of 1: 3.5) spraying to the auditorium, wherein the volume ratio of the acidic electrolyzed water to the dichlorvos is 1:0.15 No Coriolus versicolor, Trichoderma, Nematode and fungal rope
Infecting with cotton rot fungus before auricular inoculation, Trichoderma, nematode, mite, bactrocera, Slug Diluting acidic electrolyzed water with Dimethoate and water (the volume of Dimethoate mixed with acidic electrolyzed water and water)Ratio of 1: 5) to Spraying in an auditorium with the volume ratio of the acidic electrolyzed water to the dimethoate being 1.0.1 No cotton rot fungus or wood is detected Mold, nematode, acarid, bactrocera, and slug
Feeling before ear infection after auricular inoculation Dyeing and weaving shell mould (known as powdery mildew) Diluting the acidic electrolyzed water with lime sulphur agent (after mixing the acidic electrolyzed water with lime sulphur agent, mixing with the acidic electrolyzed water with lime sulphur agent The volume ratio of the water is 1: 17), the spraying is carried out on the auricular hall, and the volume ratio of the acidic electrolyzed water to the lime sulphur is 1:0.3 No evidence of Chaetomium
According to the table, the acidic electrolyzed water and the pesticide are mixed to thoroughly kill infectious mixed bacteria and pests in the vegetable cultivation process, so that the normal growth of the tremella can be guaranteed.
Example two
Figure DEST_PATH_IMAGE003
As can be seen from the above table, the acidic electrolyzed water of the present invention can be widely applied to the prevention and treatment of insect pests of fruit trees.
The following comparative tests were carried out using pakchoi
Figure DEST_PATH_IMAGE005
The comparison shows that the pesticide residue can be greatly reduced when the acidic electrolyzed water is added into the pesticide and then the pesticide is used for sterilization and disinsection operation of vegetables and fruits.
In the above comparative test, the detection apparatus mainly includes a gas chromatograph, and the detection limit of the method is 0.0003.
In conclusion, after the acidic electrolyzed water is mixed with the pesticide, the effects of sterilizing and killing insects can be achieved, the using amount of the pesticide can be reduced, pesticide residues are greatly reduced, and the quality of fruits and vegetables is improved.

Claims (4)

1. An application of acidic electrolyzed water and agricultural chemical in sterilizing and killing pests.
2. The use of the acidic electrolyzed water according to claim 1 for sterilizing and killing insects by mixing with pesticides, wherein the acidic electrolyzed water is an acidic stock solution with a pH value of 1.5-2.0, which is generated by electrolyzing sodium chloride serving as an electrolyte, the oxidation-reduction potential ORP of the acidic stock solution is 900 mv-1200 mv, the mass fraction of sodium in the acidic stock solution is less than or equal to 0.01%, and the concentration of chlorine in the acidic stock solution is 80-150 mg/L.
3. The use of the acidic electrolyzed water and the pesticide according to claim 1 or 2 for sterilizing and killing insects, wherein the volume ratio of the acidic electrolyzed water to the pesticide is 1: 0.1-0.3.
4. The use of the acidic electrolyzed water as defined in claim 1 for sterilizing and killing insects by mixing with a pesticide, wherein the pesticide is chlorothalonil, chlorpyrifos, dichlorvos, carbendazim, dichlorvos or dimethoate.
CN202110306937.1A 2021-03-23 2021-03-23 Application of acidic electrolyzed water mixed with pesticide for sterilizing and killing insects Withdrawn CN113207901A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114431225A (en) * 2022-01-29 2022-05-06 四川建元天地环保科技有限公司 Method for realizing weeding by matching acid electrolyzed water with herbicide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114431225A (en) * 2022-01-29 2022-05-06 四川建元天地环保科技有限公司 Method for realizing weeding by matching acid electrolyzed water with herbicide

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Application publication date: 20210806