CN112875785A - Deep treatment system and method for wet desulphurization wastewater of coal-fired boiler - Google Patents
Deep treatment system and method for wet desulphurization wastewater of coal-fired boiler Download PDFInfo
- Publication number
- CN112875785A CN112875785A CN202110093040.5A CN202110093040A CN112875785A CN 112875785 A CN112875785 A CN 112875785A CN 202110093040 A CN202110093040 A CN 202110093040A CN 112875785 A CN112875785 A CN 112875785A
- Authority
- CN
- China
- Prior art keywords
- wastewater
- coal
- fired boiler
- desulfurization
- wet desulphurization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 83
- 238000000034 method Methods 0.000 title claims abstract description 46
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 73
- 230000023556 desulfurization Effects 0.000 claims abstract description 73
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 54
- 238000001704 evaporation Methods 0.000 claims abstract description 50
- 230000008020 evaporation Effects 0.000 claims abstract description 50
- 239000000428 dust Substances 0.000 claims abstract description 24
- 239000007921 spray Substances 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims abstract description 19
- 239000003546 flue gas Substances 0.000 claims abstract description 16
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000001556 precipitation Methods 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims description 14
- 238000009833 condensation Methods 0.000 claims description 13
- 230000005494 condensation Effects 0.000 claims description 13
- 239000000498 cooling water Substances 0.000 claims description 13
- 238000004065 wastewater treatment Methods 0.000 claims description 11
- 239000002562 thickening agent Substances 0.000 claims description 9
- 238000001694 spray drying Methods 0.000 claims description 7
- 230000003009 desulfurizing effect Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 238000007701 flash-distillation Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 24
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 description 14
- 239000003814 drug Substances 0.000 description 6
- 229910052602 gypsum Inorganic materials 0.000 description 5
- 239000010440 gypsum Substances 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- 239000000779 smoke Substances 0.000 description 5
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000013589 supplement Substances 0.000 description 4
- 239000002918 waste heat Substances 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- -1 chlorine ions Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005713 exacerbation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000003895 groundwater pollution Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/06—Flash evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/16—Evaporating by spraying
- B01D1/18—Evaporating by spraying to obtain dry solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/26—Multiple-effect evaporating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/048—Purification of waste water by evaporation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/16—Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
Abstract
The invention provides a system and a method for advanced treatment of wet desulphurization wastewater of a coal-fired boiler. The advanced treatment system and method for the wet desulphurization wastewater of the coal-fired boiler comprise: step A: carrying out flash evaporation concentration on the desulfurization wastewater from the coal-fired boiler to form a desulfurization wastewater concentrated solution; and B: the concentrated solution of the desulfurization wastewater enters a spray dryer for evaporation and drying, dust and water vapor generated in the evaporation and drying process are introduced into a flue before electric precipitation along with flue gas, chloride ions, other solid particles and metal elements are captured by electric precipitation, and the evaporated water vapor enters a desulfurization tower. The invention also provides a system for advanced treatment of the wet desulphurization wastewater of the coal-fired boiler, which adopts the advanced treatment method for the wet desulphurization wastewater of the coal-fired boiler. The invention realizes energy reutilization, improves the utilization rate of energy, has no external steam input in the whole evaporation process, and realizes low energy consumption.
Description
Technical Field
The invention relates to the field of coal-fired power generation, in particular to a system and a method for treating wet desulphurization wastewater of a coal-fired boiler, and especially relates to a system and a method for deeply treating the wet desulphurization wastewater of the coal-fired boiler.
Background
In order to prevent the desulfurization equipment from being corroded and ensure the quality of gypsum during the operation of the coal-fired boiler, a certain amount of desulfurization wastewater needs to be discharged from the desulfurization absorption tower.
The traditional desulfurization wastewater treatment process usually adopts oxidation, neutralization, precipitation, flocculation and clarificationA cleaning process, wherein sodium hypochlorite preoxidation, Ca (OH) are arranged in a matching way2Neutralizing, organic sulfur, FeClSO4 flocculating, coagulant aid precipitating, sodium sulfite reducing and the like, and discharging or using the treated desulfurization wastewater to dry ash (slag) humidifying and ash field spraying dust settling after reaching DL/T997-2006 Water quality control index of limestone-gypsum wet desulfurization wastewater of thermal power plants.
In the year 2015, 4 months, a water pollution prevention and control action plan (abbreviated as 'ten items of water') is issued by the state institute, and the national water environment quality is improved in stages by 2020, the severely polluted water body is greatly reduced, the drinking water safety guarantee level is continuously improved, and the groundwater pollution exacerbation trend is preliminarily restrained; the development of circulation is required to be promoted, and the advanced treatment and recycling of the wastewater are encouraged; the method has the advantages that a prospective technology is researched and developed, scientific and technological resources are integrated, and the technologies of advanced wastewater treatment, industrial high-salinity wastewater desalination and the like in key industries are quickened to research and develop; and (4) prohibiting the desulfurization wastewater of the coal-fired power plant from being discharged. DL/T5046-: desulfurization waste water should be handled the retrieval and utilization, when zero release requires, should carry out advanced treatment to desulfurization waste water.
The existing advanced treatment technology for desulfurization wastewater of coal-fired power plants mainly comprises pretreatment softening technology, concentration and decrement technology, evaporative crystallization technology and the like of desulfurization wastewater, and the concentration and decrement technology comprises membrane method concentration (RO, FO, ED and the like) and thermal method concentration (concentration by utilizing steam, flue waste heat and the like). The comparison of the advanced treatment performance of the conventional desulfurization wastewater is shown in Table 1
TABLE 1 analysis of the Performance of the conventional desulfurization waste Water advanced treatment
From the conventional desulfurization wastewater advanced treatment, it can be known that: the existing desulfurization wastewater treatment needs adding a medicament for pollution softening, and high-salt mud cakes are generated, so that the treatment process is complex and the cost is high.
In summary, the following problems exist in the prior art: the existing desulfurization wastewater treatment needs adding a medicament for pollution softening, and high-salt mud cakes are generated, so that the treatment process is complex and the cost is high.
Disclosure of Invention
The invention provides a system and a method for advanced treatment of wet desulphurization wastewater of a coal-fired boiler, which aim to solve the problems that the desulphurization wastewater treatment needs adding a medicament for pollution softening, high-salt mud cakes are generated, the treatment process is complex and the cost is high.
Therefore, the invention provides a system and a method for advanced treatment of wet desulphurization wastewater of a coal-fired boiler, wherein the system and the method for advanced treatment of wet desulphurization wastewater of the coal-fired boiler comprise the following steps:
step A: carrying out flash evaporation concentration on the desulfurization wastewater from the coal-fired boiler to form a desulfurization wastewater concentrated solution;
and B: the concentrated solution of the desulfurization wastewater enters a spray dryer for evaporation and drying, dust and water vapor generated in the evaporation and drying process are introduced into a flue before electric precipitation along with flue gas, chloride ions, other solid particles and metal elements are captured by electric precipitation, and the evaporated water vapor enters a desulfurization tower.
Furthermore, in the step A, the desulfurization wastewater does not need a pretreatment system, and the heat of the low-temperature economizer is directly utilized to preheat the desulfurization wastewater.
Further, in the step A, triple-effect flash evaporation concentration is adopted for flash evaporation concentration.
Further, in the step A, the liquid level, the concentration and the temperature in the container are adjusted by controlling the operation of the pump and the valve, so that the flash evaporation concentration of the desulfurization wastewater is realized.
Further, in step B, the number of spray dryers is two, and the two spray dryers are arranged in parallel.
The advanced treatment system for the wet desulphurization wastewater of the coal-fired boiler adopts the advanced treatment method for the wet desulphurization wastewater of the coal-fired boiler, and comprises the following steps: a flash concentration system and a spray drying system connected to each other.
Further, the flash concentration system comprises: in series: first effect flash vessel, two effect flash vessel, three effect flash vessel, thickener and dredge pump, the concentrated system of flash distillation still includes: a cooling water return pipeline connected with the thickener and a condensation water tank connected with the cooling water return pipeline.
Further, a heat exchanger is arranged between the cooling water return pipeline and the condensation water tank.
Further, the spray drying system comprises: the spray dryer and the electric dust removal front flue connected with the spray dryer are connected, and the electric dust removal front flue is connected with the desulfurizing tower.
Further, the number of the spray dryers is two, and the two spray dryers are arranged in parallel.
Because the technologies of low-temperature flash evaporation, calcium sulfate crystal seeds, high-speed circulation and the like are adopted, the salts in the desulfurization wastewater mainly exist in the forms of sulfate, chloride, sulfite, carbonate and gypsum, and the salts can not cause scaling in the evaporation process. The whole system can not be scaled.
The waste heat at the tail part of the flue is used for heating the desulfurization waste water, so that the comprehensive utilization of preheating is realized, and the energy is saved and the consumption is reduced. The desulfurization waste water is heated by using the heat of the low-temperature economizer by adopting a triple-effect flash evaporation concentration technology, so that the energy is recycled, the utilization rate of the energy is improved, no external steam is input in the whole evaporation process, and the low energy consumption is realized.
The process of flash evaporation concentration and concentrated solution drying is adopted, and the method has the advantages of small occupied area of equipment, low investment and operation cost, high automation degree and the like.
Drawings
FIG. 1 is a schematic diagram of the working principle of the system and method for advanced treatment of wastewater from wet desulphurization of coal-fired boiler of the present invention;
FIG. 2 is a schematic diagram of the operation of the flash evaporation concentration stage of desulfurized wastewater of the present invention.
The reference numbers illustrate:
1. a coal-fired boiler; 2. a denitration device; 3. an air preheater; 4. a dust remover; 5. a tubular dust collector; 6. a fan; 7. a spray dryer (spray dryer); 8. a flue; 80. an ash conveying device; 9. compressing air; 10. a feed pump; 11. desulfurization waste water concentrated solution; 12. a thickener; 13. a multi-effect flash evaporator; 14. an evaporation circulating pump; 15. a circulation pump; 16. a low-temperature economizer; 17. a heat exchanger; 18. a condensation water tank; 19. a vacuum pump; 20. a condensate pump; 21. returning cooling water; 22. cooling water; 23. emptying; 24. recycling the condensed water; 25. hot flue gases; 26. hot flue gases; 27. desulfurized wastewater (from filtrate tank);
91. a primary heater; 92. a dual-effect heater; 93. a triple effect heater; 131. a one-effect flash evaporator; 132. a two-effect flash evaporator; 133. a triple effect flash evaporator; 270. a feed pump; 120. a sludge discharge pump; 30. a vacuum pump; 31. a drain tank; 17. a heat exchanger.
Detailed Description
The present invention will now be described in order to more clearly understand the technical features, objects, and effects of the present invention.
A factory is planned with a total installed capacity of 1920 MW. Wherein, the stage I engineering 2X 300MW unit adopts a circulating fluidized bed boiler with natural circulation as a main unit and adopts a direct air-cooling steam extraction type steam turbine generator unit; the second stage of the extension project is a 2 multiplied by 660MW high-efficiency ultra-supercritical coal-fired air cooling unit, and a flue gas desulfurization and denitration facility is synchronously constructed in a matched manner. The deslagging of the whole plant adopts a mechanical deslagging system and a dry deslagging process, the ash removal system adopts a cloth bag dedusting and dry ash removal process, and the desulfurization process adopts a limestone-gypsum wet flue gas desulfurization system and a one-furnace one-tower desulfurization device.
A2X 300MW unit boiler of the project at the I stage is provided with a low-temperature economizer, the smoke temperature at the inlet of the air preheater is 370 ℃, the smoke temperature at the inlet of the electric dust collector passes through the low-temperature economizer at 120 ℃, the smoke temperature at the inlet of the electric dust collector does not pass through the low-temperature economizer at 155 ℃, the smoke temperature at the inlet of the desulfurizing tower is 90 ℃, and the smoke temperature at the outlet is 50 ℃.
And (3) wet desulphurization is adopted for the flue gas of the boiler in the I stage and the II stage, the industrial water in a factory area, the high-salt-content drainage of a boiler make-up water treatment system and the qualified industrial wastewater are treated, the desulfurization wastewater quantity of the 2 x 300MW unit in the I stage engineering is 8t/h, the desulfurization wastewater quantity in the II stage is 14t/h, and the total amount is 22 t/h. The main components of the desulfurized wastewater are shown in Table 2.
TABLE 2 desulfurized Water quality
The flow rate of the desulfurization wastewater of the engineering boiler in the I and II stages is 22t/h, a pretreatment system is not needed for the desulfurization wastewater, the desulfurization wastewater is preheated by directly utilizing the heat of a low-temperature economizer, then the desulfurization wastewater is concentrated by triple effect flash evaporation, the concentration rate can reach 90 percent, the online concentration is automatically adjusted by 50 to 90 percent, about 2.2t/h of concentrated solution after the desulfurization wastewater is concentrated enters two unit spray dryers respectively for evaporation and drying, the amount of the dried concentrated solution of each boiler is 1.1t/h, the generated dust and water vapor are introduced into a flue before electric precipitation along with flue gas, the chlorine ions and other solid particles and metal elements are captured by the aid of electricity during the dust removal, and the evaporated water vapor enters a desulfurization tower. The water vapor generated in the flash evaporation concentration process can be recovered to the desulfurization process water or water supplement with other purposes after condensation.
After the desulfurization wastewater is treated by the technologies of flash evaporation concentration and concentrated solution drying, water is evaporated and condensed for 90% recycling, the rest of water enters a desulfurization tower in a steam form and is absorbed by the desulfurization tower, the recovery rate of the water is 100%, and the generated solid particles are completely removed in a dust form through electric precipitation, so that the real zero emission of no waste gas, no wastewater and no waste solid discharge in the desulfurization wastewater treatment is realized.
The technical scheme is provided with a double-row flash evaporation concentration system, and concentrated solution is conveyed to spray drying systems arranged at the tail parts of two boilers for drying.
The invention mainly comprises two stages: one is a flash concentration stage, as shown in fig. 1 and 2; the other is a subsequent concentrate drying stage, as shown in fig. 1. Specifically, the overall work flow of the invention is as follows:
the desulfurization wastewater 27 (from a filtrate water tank) with the wastewater flow rate of 22t/h enters a multi-effect flash evaporator 13 through an evaporation circulating pump 14, is subjected to triple-effect flash concentration, the concentration rate can reach 90%, and is automatically adjustable in an online 50% -90%, about 2.2t/h of concentrated solution 11 after the desulfurization wastewater is concentrated enters a spray dryer 7 through a thickener 12 for evaporation drying (for example, the concentrated solution enters two unit spray dryers for evaporation drying, the amount of the dried concentrated solution of each boiler is 1.1t/h), the generated dust and water vapor are introduced into a flue 8 along with flue gas, for example, the flue before electric precipitation, chloride ions and other solid particles and metal elements are captured by electric precipitation, and the evaporated water vapor enters a desulfurization tower. The water vapor generated in the flash evaporation concentration process can be recovered to the desulfurization process water or water supplement with other purposes after condensation.
The hot flue gas 25 and the hot flue gas 26 exchange heat in the low-temperature economizer 16, the multi-effect flash evaporator 13 is respectively connected with the low-temperature economizer 16 and the circulating pump 15 to realize heat exchange, and the desulfurization wastewater 27 is directly preheated by using the heat of the low-temperature economizer 16 without a pretreatment system.
Water vapor is generated in the flash evaporation concentration process, and cooling water return water 21 is formed after heat exchange and condensation of the heat exchanger 17 and can be recycled to desulfurization process water or water supplement for other purposes. In addition, the water vapor generated in the flash evaporation concentration process can enter a condensation water tank 18 after heat exchange and condensation of a heat exchanger 17, and then passes through a vacuum pump 19 and evacuation 23; the condensate water can also be recycled 24 by the condensate pump 20; wherein, the cooling water 22 can exchange heat through the heat exchanger 17; the cooling water return 21 enters the condensation water tank 18.
As shown in fig. 1, the working flow of the concentrate drying stage is as follows:
the concentrated solution 11 enters a spray dryer 7 through a thickener 12 and a feed pump 10 for evaporation drying, compressed air 9 is introduced into the spray dryer 7, the generated dust and water vapor are introduced into a flue 8 along with flue gas, for example, the flue is introduced into a flue before electric precipitation, chloride ions and other solid particles and metal elements are captured by electric precipitation, and the evaporated water vapor enters a desulfurizing tower. Dust removal and ash removal is performed by means of dust removal means 80 in the dust separator 4 and the flue 8.
In addition, a denitration device 2 and an air preheater 3 are arranged in the coal-fired boiler 1, the coal-fired boiler 1 is connected with a dust remover 4, the coal-fired boiler 1 is also connected with a pipe type dust remover 5 and a fan 6, the fan 6 is connected with a spray dryer 7, and the pipe type dust remover 5 is connected with a flue 8 so as to realize dust removal.
As shown in fig. 1 and fig. 2, the specific working process of the flash evaporation concentration stage is as follows:
the desulfurized waste water 27 (from the filtrate tank) is concentrated by evaporation by triple effect flash evaporation. The multi-effect flash evaporator specifically includes, for example, a one-effect flash evaporator 131, a two-effect flash evaporator 132, and a three-effect flash evaporator 133.
The desulfurization wastewater 27 sequentially enters a first-effect flash evaporator 131, a second-effect flash evaporator 132 and a third-effect flash evaporator 133 through a feeding pump 270 to realize third-effect flash evaporation, the first-effect flash evaporator 131 is connected with a first-effect heater 91 through an evaporation circulating pump 14, the second-effect flash evaporator 132 is connected with a second-effect heater 92 through the evaporation circulating pump 14, and the third-effect flash evaporator 133 is connected with a third-effect heater 93 through the evaporation circulating pump 14. The desulfurization wastewater 27 enters a thickener 12 after triple effect flash evaporation, and forms a desulfurization wastewater concentrated solution 11 through a dredge pump 120;
wherein, a part of the water vapor from the triple effect flash evaporator 133 and the thickener 12 passes through the heat exchanger 17 to form cooling water return 21, the other part of the water vapor enters the condensation water tank 18 after passing through the heat exchanger 17 for heat exchange, and the condensation water tank 18 is connected with a vacuum pump 19. The condensate tank 18 is connected to a condensate pump 20 for realizing condensate recycling 24. The cooling water 22 exchanges heat in the heat exchanger 17.
The first effect heater 91 is connected to the drain tank 31, the drain tank 31 stores the recovered condensed water, and is connected to the vacuum pump 30, and the drain tank 31 is connected to the low-temperature economizer 16 through the circulation pump 15. The hot flue gas 25 enters the low-temperature economizer 16, and after heat exchange, the hot flue gas 26 leaves the low-temperature economizer 16.
The invention has the following advantages:
1. really realizing zero discharge of wastewater
The desulfurization wastewater is subjected to triple-effect flash concentration by adopting a flash concentration and concentrated solution drying technology, and then is dried by a spray drying system and sent to electric precipitation for capture. The evaporated clean water is recycled, and the real zero discharge of no waste water, no waste gas and no waste solid after the waste water treatment is realized.
2. Low operation cost
The technical process does not need a three-header pretreatment system, so that on one hand, the high medicament cost and the operation cost are reduced, on the other hand, the generation of high-salt mud cakes is avoided, and the recontamination of the added medicament to the wastewater is reduced; the tail flue gas waste heat is used for heating, and no steam is consumed; the flash evaporation concentration technology has a simple system and high automation degree, and does not need to increase operation and maintenance personnel; no medicine is needed after the operation; no consumption material, only the consumption of electricity cost, and the cost of water treatment per ton is less than 10 yuan. The highest recovery of high-quality water can reach 95 percent, and the water cost can be saved.
3. Energy saving and consumption reduction by using waste heat at tail of flue
The triple-effect flash evaporation concentration technology is adopted, so that the energy recycling is realized, and the utilization rate of the energy is improved. The desulfurization wastewater is heated by using the heat of the low-temperature economizer, no external steam is input in the whole evaporation process, and low energy consumption is realized.
4. High recovery rate of waste water and excellent quality of recovered water
After the desulfurization wastewater is subjected to evaporation treatment, the maximum wastewater recovery rate can reach 95%, and the concentration is continuously and automatically adjusted from 50% to 95%. After flash evaporation, the water obtained after evaporation and condensation of the desulfurization wastewater belongs to distilled product water and can be used for boiler water supplement.
5. The system is simple, small in maintenance amount and high in automation degree
The desulfurization wastewater flash evaporation concentration system adjusts the liquid level, concentration and temperature in the container by controlling the operation of the pump and the valve. By optimizing system control, remote monitoring, one-key starting and unattended operation can be realized. The main equipment of the system is a container and a pump, as long as the pump is subjected to routine maintenance.
6. The concentrated solution has high drying speed
Spray drying is flash drying, and the whole process from wet material to dry powder product is completed in only 20 s. The concentrated solution drying system has small volume, small occupied area and high heat efficiency.
7. The whole system can not be scaled
Because the technologies of low-temperature flash evaporation, calcium sulfate crystal seeds, high-speed circulation and the like are adopted, the salts in the desulfurization wastewater mainly exist in the forms of sulfate, chloride, sulfite, carbonate and gypsum, and the salts can not cause scaling in the evaporation process.
The above description is only an exemplary embodiment of the present invention, and is not intended to limit the scope of the present invention. In order that the components of the present invention may be combined without conflict, it is intended that all equivalent changes and modifications made by those skilled in the art without departing from the spirit and principles of the present invention shall fall within the protection scope of the present invention.
Claims (10)
1. The advanced treatment method for the wet desulphurization wastewater of the coal-fired boiler is characterized by comprising the following steps:
step A: carrying out flash evaporation concentration on the desulfurization wastewater from the coal-fired boiler to form a desulfurization wastewater concentrated solution;
and B: the concentrated solution of the desulfurization wastewater enters a spray dryer for evaporation and drying, dust and water vapor generated in the evaporation and drying process are introduced into a flue before electric precipitation along with flue gas, chloride ions, other solid particles and metal elements are captured by electric precipitation, and the evaporated water vapor enters a desulfurization tower.
2. The method for the advanced treatment of the wastewater generated by the wet desulphurization of the coal-fired boiler according to claim 1, wherein in the step A, the desulfurization wastewater is preheated by directly utilizing the heat of the low-temperature economizer without a pretreatment system.
3. The method for the advanced treatment of the wet desulphurization wastewater of the coal-fired boiler according to claim 1, wherein in the step A, the flash concentration adopts triple-effect flash concentration.
4. The method for the advanced treatment of the wet desulphurization wastewater of the coal-fired boiler according to claim 1, wherein in the step A, the liquid level, the concentration and the temperature in the container are adjusted by controlling the operation of the pump and the valve, so as to realize the flash evaporation concentration of the desulphurization wastewater.
5. The method for the advanced treatment of wastewater generated by wet desulfurization of coal-fired boiler according to claim 1, wherein in the step B, the number of the spray dryers is two, and the two spray dryers are arranged in parallel.
6. The advanced treatment system for the wet desulphurization wastewater of the coal-fired boiler is characterized in that the advanced treatment method for the wet desulphurization wastewater of the coal-fired boiler according to claim 1 is adopted, and comprises the following steps: a flash concentration system and a spray drying system connected to each other.
7. The advanced wastewater treatment system for wet desulfurization of coal-fired boiler according to claim 6, characterized in that the flash concentration system comprises: in series: first effect flash vessel, two effect flash vessel, three effect flash vessel, thickener and dredge pump, the concentrated system of flash distillation still includes: a cooling water return pipeline connected with the thickener and a condensation water tank connected with the cooling water return pipeline.
8. The advanced wastewater treatment system for wet desulfurization of coal-fired boiler according to claim 7, wherein a heat exchanger is provided between the cooling water return line and the condensate tank.
9. The advanced wastewater treatment system for wet desulfurization of coal-fired boiler according to claim 6, wherein the spray drying system comprises: the spray dryer and the electric dust removal front flue connected with the spray dryer are connected, and the electric dust removal front flue is connected with the desulfurizing tower.
10. The advanced wastewater treatment system for wet desulfurization of coal-fired boiler according to claim 6, wherein the number of spray dryers is two, and two of said spray dryers are disposed in parallel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110093040.5A CN112875785A (en) | 2021-01-25 | 2021-01-25 | Deep treatment system and method for wet desulphurization wastewater of coal-fired boiler |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110093040.5A CN112875785A (en) | 2021-01-25 | 2021-01-25 | Deep treatment system and method for wet desulphurization wastewater of coal-fired boiler |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112875785A true CN112875785A (en) | 2021-06-01 |
Family
ID=76050665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110093040.5A Pending CN112875785A (en) | 2021-01-25 | 2021-01-25 | Deep treatment system and method for wet desulphurization wastewater of coal-fired boiler |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112875785A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113526591A (en) * | 2021-06-30 | 2021-10-22 | 中国能源建设集团江苏省电力设计院有限公司 | Energy-saving desulfurization waste water concentration and drying zero discharge system |
| CN113582278A (en) * | 2021-09-08 | 2021-11-02 | 南京工业大学 | Desulfurization waste water integrated processing system |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011012756A1 (en) * | 2011-03-01 | 2012-09-06 | Terranova Energy Gmbh | Thermal processing of solid fuels, preferably coal dust produced via hydrothermal carbonization of a biomass, comprises post-treating an exhaust gas stream in a combustion chamber |
| WO2012128330A1 (en) * | 2011-03-24 | 2012-09-27 | 三菱重工業株式会社 | Spray-drying device for dehydrated filtrate from desulfurization wastewater, exhaust gas treatment system and method |
| CN109879343A (en) * | 2019-03-25 | 2019-06-14 | 上海思九科技发展有限公司 | A kind of processing system and processing method of catalytic cracking and desulfurizing waste water |
| CN111056584A (en) * | 2020-01-15 | 2020-04-24 | 山东神华山大能源环境有限公司 | A system and method for zero-discharge treatment of desulfurization wastewater |
| CN111892112A (en) * | 2020-08-31 | 2020-11-06 | 中电华创电力技术研究有限公司 | A treatment system for zero discharge of desulfurization wastewater in coal-fired power plants |
| CN211921179U (en) * | 2020-02-05 | 2020-11-13 | 浙江浙大网新环境工程有限公司 | Power plant wet desulphurization wastewater zero discharge system |
-
2021
- 2021-01-25 CN CN202110093040.5A patent/CN112875785A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011012756A1 (en) * | 2011-03-01 | 2012-09-06 | Terranova Energy Gmbh | Thermal processing of solid fuels, preferably coal dust produced via hydrothermal carbonization of a biomass, comprises post-treating an exhaust gas stream in a combustion chamber |
| WO2012128330A1 (en) * | 2011-03-24 | 2012-09-27 | 三菱重工業株式会社 | Spray-drying device for dehydrated filtrate from desulfurization wastewater, exhaust gas treatment system and method |
| CN109879343A (en) * | 2019-03-25 | 2019-06-14 | 上海思九科技发展有限公司 | A kind of processing system and processing method of catalytic cracking and desulfurizing waste water |
| CN111056584A (en) * | 2020-01-15 | 2020-04-24 | 山东神华山大能源环境有限公司 | A system and method for zero-discharge treatment of desulfurization wastewater |
| CN211921179U (en) * | 2020-02-05 | 2020-11-13 | 浙江浙大网新环境工程有限公司 | Power plant wet desulphurization wastewater zero discharge system |
| CN111892112A (en) * | 2020-08-31 | 2020-11-06 | 中电华创电力技术研究有限公司 | A treatment system for zero discharge of desulfurization wastewater in coal-fired power plants |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113526591A (en) * | 2021-06-30 | 2021-10-22 | 中国能源建设集团江苏省电力设计院有限公司 | Energy-saving desulfurization waste water concentration and drying zero discharge system |
| CN113526591B (en) * | 2021-06-30 | 2023-02-14 | 中国能源建设集团江苏省电力设计院有限公司 | Energy-saving desulfurization waste water concentration and drying zero discharge system |
| CN113582278A (en) * | 2021-09-08 | 2021-11-02 | 南京工业大学 | Desulfurization waste water integrated processing system |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107129094B (en) | Zero discharge system based on multi-heat-source evaporation desulfurization waste water | |
| CN104803535A (en) | Recycling system and recycling process for recycling salt from desulfurization waste water | |
| CN105217702B (en) | A kind of desulfurization wastewater treatment system | |
| CN206580583U (en) | FGD wastewater zero discharge systems | |
| CN110272082B (en) | Desulfurization waste water evaporation crystallization coupling flue gas reheat integrated system | |
| CN107857321B (en) | Process for zero discharge treatment of wastewater of thermal power plant | |
| CN107337245A (en) | A kind of spraying system that desulfurization wastewater is concentrated using fume afterheat | |
| CN108317503A (en) | A kind of coal-fired power station boiler smoke discharging residual heat and water reclamation system and operation method | |
| CN114604924A (en) | Low-temperature flash evaporation, concentration and crystallization integrated and zero-discharge process for treating desulfurization wastewater by concentrated solution backflow | |
| CN106587231A (en) | FGD wastewater zero discharge system | |
| CN115893559A (en) | A desulfurization wastewater zero discharge system and desulfurization wastewater zero discharge process | |
| CN110182874A (en) | A kind of super low energy consumption flash concentration desulfurization wastewater and industrial brine waste zero emission system | |
| CN113501612A (en) | Energy-concerving and environment-protective type desulfurization waste water zero release processing system | |
| CN112875785A (en) | Deep treatment system and method for wet desulphurization wastewater of coal-fired boiler | |
| CN206940653U (en) | Desulphurization for Coal-fired Power Plant waste water zero discharge device | |
| CN111908686B (en) | Desulfurization wastewater zero-discharge system and method for deep utilization of flue gas waste heat | |
| CN219526302U (en) | Treatment system for zero emission of desulfurization wastewater of coal-fired power plant | |
| CN212198574U (en) | Flue gas condensate water processing system based on wet desulphurization technology | |
| CN112607944A (en) | Coal-fired power plant desulfurization wastewater treatment system and method based on flue gas cooperative treatment | |
| CN217972646U (en) | Ultralow energy consumption desulfurization effluent disposal system | |
| CN212403827U (en) | Desulfurization wastewater zero discharge system utilizing flue gas waste heat of power plant | |
| CN213294703U (en) | Fly ash desalination system containing potassium chloride salt | |
| CN214218240U (en) | Desulfurization wastewater advanced treatment system | |
| CN111499064B (en) | A system and method for zero emission of desulfurization wastewater by carrier gas extraction and bypass flue evaporation | |
| CN215855195U (en) | System for flue gas waste heat utilization and desulfurization waste water zero release coupling |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210601 |


