CN112724636A - Weather-proof, solvent corrosion-resistant and noise-reducing PC/ABS alloy material and preparation method thereof - Google Patents
Weather-proof, solvent corrosion-resistant and noise-reducing PC/ABS alloy material and preparation method thereof Download PDFInfo
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- CN112724636A CN112724636A CN202011593266.3A CN202011593266A CN112724636A CN 112724636 A CN112724636 A CN 112724636A CN 202011593266 A CN202011593266 A CN 202011593266A CN 112724636 A CN112724636 A CN 112724636A
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- alloy material
- abs alloy
- noise reduction
- weather resistance
- solvent corrosion
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- 239000000956 alloy Substances 0.000 title claims abstract description 34
- 239000002904 solvent Substances 0.000 title claims abstract description 24
- 238000005260 corrosion Methods 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title abstract description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 10
- 230000003078 antioxidant Effects 0.000 claims abstract description 9
- 238000005336 cracking Methods 0.000 claims abstract description 5
- 239000011259 mixed solution Substances 0.000 claims abstract description 5
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 43
- -1 phosphite ester compounds Chemical class 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L Calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000004698 Polyethylene (PE) Substances 0.000 claims description 3
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims 1
- 235000019439 ethyl acetate Nutrition 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 4
- 239000004417 polycarbonate Substances 0.000 description 30
- 229920000122 Acrylonitrile butadiene styrene Polymers 0.000 description 28
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000006011 modification reaction Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N Acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N Phosphite Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a weather-resistant, solvent corrosion-resistant and noise-reducing PC/ABS alloy material and a preparation method thereof, wherein the material comprises the following components in parts by mass: 60 parts of PC, 5-25 parts of ABS, 10-30 parts of AES, 2.5 parts of toughening agent, 2 parts of compatilizer, 0.2 part of antioxidant and 0.3 part of lubricant. The preparation method of the PC/ABS alloy material is simple, the overall noise reduction performance of the product is increased by at least 20% compared with that of the common PC/ABS alloy material, the color difference after 500h weather resistance test is not more than 1.3, and the cracking time in a mixed solution of ethyl acetate and ethanol is 2-7 min.
Description
Technical Field
The invention belongs to the technical field of PC/ABS alloy material modification preparation, and particularly relates to a PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction and a preparation method thereof.
Background
The PC/ABS integrates the excellent performances of PC and ABS, and has wide application in the fields of automobiles, communication, household appliances and the like. With the improvement of living standard of people, the automobile consumption market is more and more exploded, so that the consumption of PC/ABS alloy materials in the automobile field is rapidly increased. The PC/ABS alloy is often used as the first choice material for automotive interior trim parts such as center control panels, armrests and air outlets, but the PC/ABS alloy has poor weather resistance and solvent resistance, and the manufactured parts generate noise due to friction during assembly and long-term use, so that the defects limit the wider application of the PC/ABS alloy.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, provides a PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction and a preparation method thereof, and solves the problems in the background art.
One of the technical schemes adopted by the invention for solving the technical problems is as follows: provides a PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction.
The composition comprises the following components in parts by mass: 60 parts of PC, 5-25 parts of ABS, 10-30 parts of AES, 2.5 parts of toughening agent, 2 parts of compatilizer, 0.2 part of antioxidant and 0.3 part of lubricant.
In a preferred embodiment of the present invention, the PC is a medium-viscosity PC resin or a low-viscosity PC resin.
In a preferred embodiment of the present invention, the melt index of the ABS is 20g/10 min. The minimum addition amount of ABS is 5 wt%.
In a preferred embodiment of the present invention, the melt index of AES is 20g/10 min. The AES has excellent formability, impact resistance and glossiness, and also has excellent weather resistance and polar solvent corrosion resistance, and the ethylene propylene diene monomer rubber can improve the viscoelastic property of the material, and when the addition percentage of the AES is not less than 10 wt%, the AES can convert the internal friction caused by noise mechanical energy into heat energy consumption to achieve the noise reduction effect; when the addition percentage of AES is less than 10 wt%, the AES is only used as an elastomer, plays a certain toughening role, and has little effect on improving weather resistance and solvent resistance, especially on improving noise reduction performance.
In a preferred embodiment of the present invention, the toughening agent is butadiene-styrene copolymer grafted polymethyl methacrylate.
In a preferred embodiment of the present invention, the compatibilizer is one of a styrene-maleic anhydride copolymer or a styrene-acrylonitrile-maleic anhydride copolymer.
In a preferred embodiment of the present invention, the antioxidant is hindered phenol and phosphite compounds.
In a preferred embodiment of the present invention, the lubricant is at least one of calcium stearate and polyethylene wax.
The second technical scheme adopted by the invention for solving the technical problems is as follows: the preparation method of the PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction is provided, and comprises the following steps:
weighing the required PC, ABS, AES, toughening agent, compatilizer, antioxidant and lubricant according to the proportion, and blending for 2-10min in a high-speed mixer; and (3) feeding the mixture into a double-screw extruder through a feeder, and performing melt blending, extrusion, cooling, granulation and drying to obtain the PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction.
Compared with the background technology, the technical scheme has the following advantages:
according to the invention, the PC/ABS alloy material is prepared by high-dose AES modification, the preparation method is simple, the overall noise reduction performance of the obtained product is increased by at least 20% compared with that of the common PC/ABS alloy material, the color difference after 500h weather resistance test is not more than 1.3, the cracking time in a mixed solution of ethyl acetate and ethanol is 2-7 min, and the PC/ABS alloy material has good weather resistance, solvent corrosion resistance and noise reduction performance.
Detailed Description
In the following examples, PC is polycarbonate, and medium-viscosity or low-viscosity PC resin is selected, such as Japanese imperial 1250Y;
ABS is acrylonitrile-butadiene-styrene copolymer, preferably 20g/10min melt index, as exemplified by Shanghai high bridge, 8391;
AES is acrylonitrile-ethylene propylene diene monomer-styrene copolymer, preferably 20g/10min melt index, as exemplified by Sumitomo, UB-500A;
the toughening agent is butadiene-styrene copolymer grafted polymethyl methacrylate, such as the examples using U.S. Rohm and Haas, EXL 2690;
the compatilizer is one of styrene-maleic anhydride copolymer and styrene-acrylonitrile-maleic anhydride copolymer; uses Huawen SMA-700, SMA-800 as the embodiment;
the antioxidant is hindered phenol and phosphite ester compound.
The lubricant is one or more of calcium stearate and polyethylene wax.
The following examples and comparative examples were prepared as follows:
weighing the required PC, ABS, AES, toughening agent, compatilizer, antioxidant and lubricant according to the proportion, and blending for 2-10min in a high-speed mixer; feeding the mixture into a double-screw extruder through a feeder, melting, blending, extruding, cooling, granulating, and drying the obtained particles for later use.
TABLE 1 raw material ratios of examples and comparative examples
| Raw materials/part by mass | Comparative example 1 | Example 1 | Example 2 | Example 3 |
| PC | 60 | 60 | 60 | 60 |
| ABS | 35 | 25 | 15 | 5 |
| AES | 0 | 10 | 20 | 30 |
| Toughening agent | 2.5 | 2.5 | 2.5 | 2.5 |
| Compatilizer | 2 | 2 | 2 | 2 |
| Antioxidant agent | 0.2 | 0.2 | 0.2 | 0.2 |
| Lubricant agent | 0.3 | 0.3 | 0.3 | 0.3 |
The examples and comparative examples were tested for performance by the following method:
1. and (3) weather resistance test: preparing a sample into a sample plate, testing according to a standard method of SAE J2527 for 500h, and testing the change delta E of the color difference value on the surface of the sample plate after the test is finished;
2. and (3) solvent corrosion resistance test: the sample was prepared as a tensile sample, and the sample was put into a mixed solution of ethyl acetate/ethanol in a volume ratio of 1/1, and the time at which cracking started was calculated, the longer the time, the better the chemical resistance.
3. And (3) testing the noise reduction performance: each sample is made into a square open box of 100 × 100cm, the box is vertically placed on a clamp, 100g of steel balls are used for freely falling at a position 1m vertically above the box to impact the bottom of the box, and the noise reduction effect of the material is judged by testing the sound intensity below the box through a decibel tester placed inside the box.
TABLE 2 test of the properties of the examples and comparative examples
As can be seen from Table 2, the noise reduction performance of the PC/ABS alloy material of the embodiment is respectively increased by 20%, 37.6% and 47.7% compared with the common PC/ABS alloy material of the comparative example 1, the maximum weather resistance color difference of the product is not more than 1.3, and the cracking time in the mixed solution of ethyl acetate and ethanol is at least 200% of that of the common PC/ABS alloy material, which shows that the PC/ABS alloy material of the invention has good weather resistance, solvent corrosion resistance and noise reduction performance.
The above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.
Claims (10)
1. A PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction is characterized in that: the composition comprises the following components in parts by mass: 60 parts of PC, 5-25 parts of ABS, 10-30 parts of AES, 2.5 parts of toughening agent, 2 parts of compatilizer, 0.2 part of antioxidant and 0.3 part of lubricant.
2. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the PC adopts medium-viscosity PC resin or low-viscosity PC resin.
3. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the melt index of the ABS is 20g/10 min.
4. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the melt index of the AES is 20g/10 min.
5. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the toughening agent is butadiene-styrene copolymer grafted polymethyl methacrylate.
6. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the compatilizer is one of styrene-maleic anhydride copolymer or styrene-acrylonitrile-maleic anhydride copolymer.
7. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the antioxidant is hindered phenol and phosphite ester compounds.
8. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the lubricant is at least one of calcium stearate and polyethylene wax.
9. The PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in claim 1, wherein: the noise reduction performance of the PC/ABS alloy material is increased by at least 20%, the color difference after 500h weather resistance test is not more than 1.3, and the cracking time in a mixed solution of acetic ether and ethanol is 2-7 min.
10. The method for preparing the PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction as claimed in any one of claims 1 to 9, wherein the method comprises the following steps: weighing the required PC, ABS, AES, toughening agent, compatilizer, antioxidant and lubricant according to the proportion, and blending for 2-10min in a high-speed mixer; and (3) feeding the mixture into a double-screw extruder through a feeder, and performing melt blending, extrusion, cooling, granulation and drying to obtain the PC/ABS alloy material with weather resistance, solvent corrosion resistance and noise reduction.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011593266.3A CN112724636A (en) | 2020-12-29 | 2020-12-29 | Weather-proof, solvent corrosion-resistant and noise-reducing PC/ABS alloy material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011593266.3A CN112724636A (en) | 2020-12-29 | 2020-12-29 | Weather-proof, solvent corrosion-resistant and noise-reducing PC/ABS alloy material and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN112724636A true CN112724636A (en) | 2021-04-30 |
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| CN202011593266.3A Pending CN112724636A (en) | 2020-12-29 | 2020-12-29 | Weather-proof, solvent corrosion-resistant and noise-reducing PC/ABS alloy material and preparation method thereof |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2014476A1 (en) * | 1989-09-22 | 1991-03-22 | Michael K. Laughner | Molding compositions comprising carbonate polymer, rubber modified vinyl aromatic-nitrile graft copolymer and methyl(meth)acrylate-butadiene-styrene graft copolymer and blow molding and thermoforming processes using such compositions |
| CN101268142A (en) * | 2005-11-30 | 2008-09-17 | 大科能树脂有限公司 | Resin composition for direct metal plating, molded article, and metal-plated molded article |
| CN101824203A (en) * | 2010-05-19 | 2010-09-08 | 威海联桥新材料科技股份有限公司 | Solid polycondensation type phosphate ester inflaming retarding ABS/PC (Acrylonitrile Butadiene Styrene/Polycarbonate) alloy and preparation method thereof |
| CN101928450A (en) * | 2010-05-11 | 2010-12-29 | 上海陈立实业有限公司 | Automobile skylight decorating part material |
| JP2014237855A (en) * | 2014-09-24 | 2014-12-18 | テクノポリマー株式会社 | Thermoplastic resin composition having reduced creaking sound and molded article |
| CN104629319A (en) * | 2013-11-07 | 2015-05-20 | 殷培花 | High-toughness strengthened PC/ABS alloy and preparation method thereof |
| CN105102533A (en) * | 2013-04-08 | 2015-11-25 | 大科能树脂有限公司 | Contacting component and structure containing said contacting component |
-
2020
- 2020-12-29 CN CN202011593266.3A patent/CN112724636A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2014476A1 (en) * | 1989-09-22 | 1991-03-22 | Michael K. Laughner | Molding compositions comprising carbonate polymer, rubber modified vinyl aromatic-nitrile graft copolymer and methyl(meth)acrylate-butadiene-styrene graft copolymer and blow molding and thermoforming processes using such compositions |
| CN101268142A (en) * | 2005-11-30 | 2008-09-17 | 大科能树脂有限公司 | Resin composition for direct metal plating, molded article, and metal-plated molded article |
| CN101928450A (en) * | 2010-05-11 | 2010-12-29 | 上海陈立实业有限公司 | Automobile skylight decorating part material |
| CN101824203A (en) * | 2010-05-19 | 2010-09-08 | 威海联桥新材料科技股份有限公司 | Solid polycondensation type phosphate ester inflaming retarding ABS/PC (Acrylonitrile Butadiene Styrene/Polycarbonate) alloy and preparation method thereof |
| CN105102533A (en) * | 2013-04-08 | 2015-11-25 | 大科能树脂有限公司 | Contacting component and structure containing said contacting component |
| CN104629319A (en) * | 2013-11-07 | 2015-05-20 | 殷培花 | High-toughness strengthened PC/ABS alloy and preparation method thereof |
| JP2014237855A (en) * | 2014-09-24 | 2014-12-18 | テクノポリマー株式会社 | Thermoplastic resin composition having reduced creaking sound and molded article |
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