CN112542606A - Soft package lithium battery and air tightness detection method thereof - Google Patents
Soft package lithium battery and air tightness detection method thereof Download PDFInfo
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- CN112542606A CN112542606A CN201910900818.1A CN201910900818A CN112542606A CN 112542606 A CN112542606 A CN 112542606A CN 201910900818 A CN201910900818 A CN 201910900818A CN 112542606 A CN112542606 A CN 112542606A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M3/00—Investigating fluid-tightness of structures
- G01M3/02—Investigating fluid-tightness of structures by using fluid or vacuum
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Battery Mounting, Suspending (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Secondary Cells (AREA)
Abstract
本发明涉及一种软包锂电池及其气密检测方法。软包锂电池包括电池壳体；芯包，设置于所述电池壳体内，所述芯包包括间隔设置的正极极耳和负极极耳，所述正极极耳与所述负极极耳均延伸至所述电池壳体外部；气袋，所述气袋可操作地释放被检气体，所述气袋设置于所述电池壳体内，且位于所述正极极耳与所述负极极耳之间。本发明提供的软包锂电池及其气密检测方法，通过挤破气袋，是气袋中的被检气体释放至电池壳体内部，再通过气体检测设备进行气密检测，可直接获得对软包锂电池封装效果的结果，检测精度高，不会出现漏判。
The invention relates to a soft-pack lithium battery and an airtight detection method thereof. The soft-pack lithium battery includes a battery casing; a core pack is arranged in the battery casing, the core pack includes a positive electrode tab and a negative electrode tab arranged at intervals, and the positive electrode tab and the negative electrode tab both extend to The outside of the battery case; an air bag, the air bag is operable to release the gas to be tested, the air bag is arranged in the battery case and is located between the positive electrode tab and the negative electrode tab. In the soft-pack lithium battery and its airtight detection method provided by the present invention, by squeezing the air bag, the gas to be tested in the air bag is released to the inside of the battery case, and then airtight detection is carried out by gas detection equipment, and the airtightness detection method can be directly obtained. The results of the packaging effect of the soft-pack lithium battery have high detection accuracy and will not be missed.
Description
Technical Field
The invention relates to the technical field of battery tightness detection, in particular to a soft package lithium battery and an air tightness detection method thereof.
Background
The soft package lithium battery is a common lithium battery and has the advantages of good safety performance, light weight, large capacity, small internal resistance, flexible appearance design and the like.
The chemical system in the lithium battery is active in property, and the lithium battery is very easy to generate side reaction with external moisture and air to cause the performance degradation or the failure of the battery, so that the packaging airtightness is very important for the reliability and the safety of the lithium battery. How to effectively detect the air tightness of the soft package lithium battery and ensure that the packaged defective products cannot flow into the consumer market has very important significance.
The existing leakage detection method for the soft package lithium battery cannot ensure the air tightness of the soft package lithium battery due to the defects of low detection precision, easy missing judgment and the like.
Disclosure of Invention
Therefore, the soft package lithium battery with high detection precision and the air tightness detection method thereof need to be provided for solving the problems of low detection precision, easy missing judgment and the like of the existing leakage detection method of the soft package lithium battery.
A soft-package lithium battery comprises a battery shell; the core bag is arranged in the battery shell and comprises a positive electrode lug and a negative electrode lug which are arranged at intervals, and the positive electrode lug and the negative electrode lug both extend to the outside of the battery shell; an air pocket operable to release a gas to be detected, the air pocket disposed within the battery case between the positive tab and the negative tab.
Above-mentioned soft packet of lithium cell utilizes the air pocket structure to make and is detected gaseous encapsulation in battery case's inside, then is the air pocket through external force and breaks, and the gas detected in the air pocket can release to battery case inside this moment, can carry out the airtight detection after the encapsulation to this soft packet of lithium cell through gaseous check out test set, and this detection can directly obtain the result to soft packet of lithium cell encapsulation effect, and the detection precision is high, can not appear the phenomenon of louing to judge.
In one embodiment, a gap is formed between the air pocket and each of the positive electrode tab and the negative electrode earphone.
In one embodiment, the air pocket is located at an intermediate position between the positive electrode tab and the negative electrode tab.
In one embodiment, a gap is formed between the air pocket and the core pack.
In one embodiment, the battery case has a first receiving cavity and a second receiving cavity separated from the first receiving cavity, the core package is placed in the first receiving cavity, and the air bag is placed in the second receiving cavity.
In one embodiment, the cavity shape of the second accommodating cavity is matched with the shape of the air bag.
In one embodiment, the detected gas is one or more of nitrogen, hydrogen or inert gas; the inert gas is helium, neon, argon, krypton, xenon or radon.
In one embodiment, the air pocket is spherical, elliptical or square in shape.
In one embodiment, the material of the air bag is one or more of PP, PE, PET or PVC.
The airtight detection method for the soft package lithium battery comprises the following steps: the position of the battery shell corresponding to the air bag is pressed under the action of external force, so that the air bag is broken, and the detected gas is released into the battery shell; and detecting whether the detected gas escapes from the soft package lithium battery.
Drawings
Fig. 1 is a schematic structural diagram of a soft-packed lithium battery according to an embodiment of the present invention;
fig. 2 is a schematic structural diagram of another view angle of the soft package lithium battery shown in fig. 1.
Detailed Description
To facilitate an understanding of the invention, the invention will now be described more fully with reference to the accompanying drawings. Preferred embodiments of the present invention are shown in the drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
When an element is referred to as being "on" another element, it can be directly on the other element or intervening elements may also be present, unless otherwise specified. It will also be understood that when an element is referred to as being "between" two elements, it can be the only one between the two elements, or one or more intervening elements may also be present.
Where the terms "comprising," "having," and "including" are used herein, another element may be added unless an explicit limitation is used, such as "only," "consisting of … …," etc. Unless mentioned to the contrary, terms in the singular may include the plural and are not to be construed as being one in number.
Furthermore, the drawings are not 1: 1, and the relative dimensions of the various elements in the figures are drawn for illustration only and not necessarily to true scale.
In order to facilitate understanding of the technical solution of the present invention, before the detailed description, a method for detecting the air tightness of the conventional soft package lithium battery will be described first.
The conventional leak detection method is based on a pressure drop method, namely, a battery is placed in a closed vacuum cavity, the vacuum cavity is vacuumized and then is kept for several minutes, and if the vacuum degree of the vacuum cavity is reduced to exceed a certain numerical value, the battery is judged to have leakage. The pressure drop method has too low detection precision, can only identify large leakage samples, and is easy to cause leakage judgment on micro leakage samples.
In addition, some soft package lithium battery production enterprises can extract samples to perform high-temperature and high-humidity (such as 45 ℃ and about 90% of relative humidity) storage tests in the production process so as to accelerate the permeation process of external moisture and air, and the air tightness of the batteries of the production batch is judged through the thickness change of the batteries before and after the test and the storage. The method also has the defects of low detection precision and easy occurrence of missing judgment, and the lithium battery can be irreversibly damaged by high-temperature and high-humidity test, so that the lithium battery can only be subjected to sampling inspection but not full inspection.
Therefore, it is desirable to provide a more reliable soft-package lithium battery with high-precision air tightness detection and an air tightness detection method thereof.
As shown in fig. 1, a lithium battery pack 100 according to an embodiment of the present invention includes a battery case 10, a core pack 20, and an air bag 30.
The core package 20 is disposed in the battery case 10, the core package 20 includes a positive electrode tab 21 and a negative electrode tab 22 disposed at an interval, and the positive electrode tab 21 and the negative electrode tab 22 both extend to the outside of the battery case 10.
The gas pouch 30 is operable to release the test gas, and the gas pouch 30 is disposed within the battery case 10 between the positive electrode tab 21 and the negative electrode tab 22.
Like this, soft packet of lithium cell 100 utilizes the air pocket 30 structure to make and is detected gaseous encapsulation in the inside of battery case 10, then makes air pocket 30 break through external force, and the gas pocket 30 is examined gaseous can release to battery case 10 inside this moment, can seal the airtight detection after this soft packet of lithium cell through gaseous check out test set, and this detection can directly obtain the result to soft packet of lithium cell encapsulation effect, and detection precision is high, can not appear the phenomenon of louing to judge.
Further, since the air bag 30 containing the gas to be detected is provided between the positive electrode tab 21 and the negative electrode tab 22, the space occupied by the air bag is small, the internal size of the battery is not changed, the package of the soft pack lithium battery 100 is not affected, and the air bag 30 is not enough to form a space for moving the battery cell 20 or the positive electrode tab 21 or the negative electrode tab 22 after being broken.
In the embodiment of the present invention, it is noted that the soft pack lithium battery 100 is a semi-finished soft pack lithium battery, and the finished soft pack lithium battery does not include the air pocket 30.
Specifically, in an embodiment, according to the packaging process of the lithium-ion soft-package battery 100, the packaging edge of the battery case 10 of the lithium-ion soft-package battery 100 is divided into a top sealing edge 11, a side sealing edge 12, and two sealing edges 13, where the positive electrode tab 21 and the negative electrode tab 22 are both disposed at the top sealing edge 11. Here, the packaging process of the soft package lithium battery will not be described in detail. Further, tab glue 14 can be disposed at the positive tab 21 and the negative tab 22, and the tab glue 14 is melt-bonded with the battery case 10 of the aluminum-plastic film in the packaging process, so as to realize the packaging of the positive tab 21 and the negative tab 22 at the top sealing edge 11.
In some embodiments, a gap is formed between the air pockets 30 and both the cathode tab 21 and the anode tab 22. In this way, since the air pockets 30 do not have a positional overlapping relationship with the positive electrode tab 21 and the negative electrode tab 22, it is further ensured that the fixation of the positive electrode tab 21 and the negative electrode tab 22 is not affected by the space generated by the broken air pockets 30 after the breakage of the air pockets 30.
Further, the air pockets 30 are located at intermediate positions between the cathode tab 21 and the anode tab 22. In this way, the influence on the fixation of the cathode tab 21 and the anode tab 22 can be further reduced. It should be understood that the intermediate position is a central position of a line connecting the positive electrode tab 21 and the negative electrode tab 22, and the center of the air pocket 30 may coincide with the center or may have some deviation, which may be caused by manufacturing error, etc., and is not limited herein.
In some embodiments, a gap is formed between the airbag 30 and the core package 20. Also, the provision of the gap further ensures that the fixation of the core pack 20 is not affected by the space generated by the ruptured gas bag 30 after the rupture of the gas bag 30.
It should be noted that, in order not to affect the packaging of the soft package lithium battery 100, there is a gap between the air bag 30 and the top sealing edge 11, and the gap can avoid the air bag 30 from being crushed or broken by heat during the packaging process.
In some embodiments, the battery case 10 has a first receiving cavity and a second receiving cavity separated from the first receiving cavity, the core package 20 is placed in the first receiving cavity, and the air bag 30 is placed in the second receiving cavity. The second accommodating cavity can prevent the position of the expected gas bag 30 from deviating in the manufacturing process of the soft package lithium battery 100 to affect the fixation of the positive electrode tab 21, the negative electrode tab 22 and the battery cell 20, and can provide a space for the gas bag 30 to prevent the aluminum plastic films on the two sides of the gas bag 30 from extruding the gas bag 30 to break in the two-sealing and exhausting process, thereby affecting the subsequent airtight detection. Specifically, the second accommodating cavity may be formed together with a pit (first accommodating cavity) punched out to accommodate the battery cell 20 in the aluminum plastic film forming process.
Further, the cavity shape of the second accommodating cavity is matched with the shape of the air bag 30. In this way, the second receiving chamber can be used to fix the gas bag 30 in the predetermined position, and on the other hand, the internal space of the battery case 10 is not unnecessarily occupied.
In some embodiments, the shape of the gas pouch 30 is spherical, elliptical, or square, and preferably, the shape of the gas pouch 30 is elliptical. The oval air bag 30 is round and flat, so that the battery case 10 of the aluminum plastic film is not easy to be punctured after packaging, and the protrusion of the plane where the positive electrode tab 21 or the negative electrode tab 22 is located is not too high. Specifically, the longitudinal direction of the air pockets 30 is parallel to the positive electrode tab 21 or the negative electrode tab 22.
In some embodiments, the material of the airbag 30 is one or more of PP (polypropylene), PE (polyethylene), PET (polyethylene terephthalate), or PVC (polyvinyl chloride). Preferably, the material of the airbag 30 is PP. It should be understood that the material of gas pouch 30 should not react with any substance in battery case 10, for example, with an electrolyte.
In some embodiments, the detected gas is one or more of nitrogen, hydrogen, or an inert gas, and the inert gas is helium, neon, argon, krypton, xenon, or radon. Preferably, the test gas is helium.
Based on the soft package lithium battery 100, the invention further provides an air tightness detection method of the soft package lithium battery, which comprises the following steps:
s110: the position of the battery shell 10 corresponding to the air bag 30 is pressed under the action of external force, so that the air bag 30 is broken, and the detected gas is released into the battery shell 10;
the external force action can be manual crushing or equipment crushing, and the positive pole lug 21 and the negative pole lug 22 are not influenced in the extruding process. The rupture of the gas bag 30 will release the gas to be detected into the battery case 10 for subsequent detection.
Specifically, the shape of the air pocket 30 is spherical, elliptical or square, and preferably, the shape of the air pocket 30 is elliptical.
The material of the air bag 30 is one or a combination of more of PP (polypropylene), PE (polyethylene), PET (polyethylene terephthalate) or PVC (polyvinyl chloride). Preferably, the material of the airbag 30 is PP.
The detected gas is one or a combination of a plurality of nitrogen, hydrogen or inert gas, and the inert gas is helium, neon, argon, krypton, xenon or radon. Preferably, the test gas is helium.
S120: and detecting whether the detected gas escapes from the soft package lithium battery 100.
Wherein, accessible gaseous check out test set detects soft packet of lithium cell 100 whether have the gas that is detected to escape, and specifically, gaseous check out test set can be vacuum box leak hunting equipment, including vacuum box, the vacuum pumping equipment and the leak detector that have the vacuum chamber. And (5) placing the soft-package lithium battery 100 after the step (S110) into a vacuum chamber of a vacuum box, vacuumizing the vacuum chamber by using vacuumizing equipment, and checking whether the detected gas leaks in the leak detector.
Compared with the prior art, the soft package lithium battery 100 and the air tightness detection method thereof have the following advantages:
(1) the air bag 30 containing the gas to be detected is arranged between the positive electrode tab 21 and the negative electrode tab 22, so that the occupied space is small, the internal size of the battery is not changed basically, the packaging of the soft package lithium battery 100 is not influenced, and in addition, after the air bag 30 is broken, the space for moving the battery cell 20 or the positive electrode tab 21 and the negative electrode tab 22 is not formed enough;
(2) gaps are formed among the air pockets 30, the positive electrode tabs 21 and the negative electrode tabs 22, so that the fixation of the positive electrode tabs 21 and the negative electrode tabs 22 cannot be influenced by the space generated after the air pockets 30 are broken;
(3) by arranging the battery shell 10 with the second accommodating cavity, the air bag 30 is placed in the second accommodating cavity, so that on one hand, the position of the air bag 30 can be prevented from being deviated in the manufacturing process of the soft package lithium battery 100, on the other hand, a space is provided for the air bag 30, and the air bag 30 is prevented from being extruded and broken by aluminum-plastic films on two sides of the air bag 30 in the two-sealing and exhausting process, so that the subsequent air tightness detection is influenced;
(4) by arranging the shape of the second accommodating cavity to match the shape of the air bag 30, on one hand, the accommodating cavity can be used for fixing the air bag 30 at a preset position, and on the other hand, the redundant inner space of the battery shell 10 is not occupied;
(5) by pressing the battery case 10 at a position corresponding to the gas bag 30, the gas bag can be easily broken without affecting the package.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. A soft-packed lithium battery, comprising:
a battery case;
the core bag is arranged in the battery shell and comprises a positive electrode lug and a negative electrode lug which are arranged at intervals, and the positive electrode lug and the negative electrode lug both extend to the outside of the battery shell;
an air pocket operable to release a gas to be detected, the air pocket disposed within the battery case between the positive tab and the negative tab.
2. The lithium battery pack as recited in claim 1, wherein a gap is formed between the air pocket and each of the positive electrode tab and the negative electrode tab.
3. The lithium pouch cell of claim 2 wherein the air pocket is located at an intermediate location between the positive tab and the negative tab.
4. The lithium pouch cell of claim 1 wherein a gap is formed between the air pocket and the core pack.
5. The lithium battery pack as claimed in claim 1, wherein the battery case has a first receiving cavity and a second receiving cavity separated from the first receiving cavity, the core pack is disposed in the first receiving cavity, and the air bag is disposed in the second receiving cavity.
6. The lithium battery pack as claimed in claim 5, wherein the shape of the second accommodating cavity matches with the shape of the air bag.
7. The lithium battery pack according to any one of claims 1 to 6, wherein the detected gas is one or more of nitrogen, hydrogen or inert gas;
the inert gas is helium, neon, argon, krypton, xenon or radon.
8. The lithium battery pack as claimed in any one of claims 1 to 6, wherein the shape of the air pocket is spherical, elliptical or square.
9. The lithium battery pack as claimed in any one of claims 1 to 6, wherein the material of the air bag is one or more of PP, PE, PET and PVC.
10. The air tightness detection method of the soft package lithium battery as claimed in any one of claims 1 to 9, characterized by comprising the steps of:
the position of the battery shell corresponding to the air bag is pressed under the action of external force, so that the air bag is broken, and the detected gas is released into the battery shell;
and detecting whether the detected gas escapes from the soft package lithium battery.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910900818.1A CN112542606A (en) | 2019-09-23 | 2019-09-23 | Soft package lithium battery and air tightness detection method thereof |
| PCT/CN2020/117072 WO2021057781A1 (en) | 2019-09-23 | 2020-09-23 | Soft pack lithium battery and airtightness testing method therefor |
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| CN201910900818.1A CN112542606A (en) | 2019-09-23 | 2019-09-23 | Soft package lithium battery and air tightness detection method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116465563A (en) * | 2023-04-23 | 2023-07-21 | 孚能科技(赣州)股份有限公司 | Battery air tightness detection method and battery air tightness detection equipment |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN202423483U (en) * | 2011-12-08 | 2012-09-05 | 深圳市格瑞普电池有限公司 | Flexibly packaged lithium ion battery |
| CN106654354A (en) * | 2016-11-29 | 2017-05-10 | 天津中聚新能源科技有限公司 | Lithium-ion battery and package detection method thereof |
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2019
- 2019-09-23 CN CN201910900818.1A patent/CN112542606A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN202423483U (en) * | 2011-12-08 | 2012-09-05 | 深圳市格瑞普电池有限公司 | Flexibly packaged lithium ion battery |
| CN106654354A (en) * | 2016-11-29 | 2017-05-10 | 天津中聚新能源科技有限公司 | Lithium-ion battery and package detection method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116465563A (en) * | 2023-04-23 | 2023-07-21 | 孚能科技(赣州)股份有限公司 | Battery air tightness detection method and battery air tightness detection equipment |
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Application publication date: 20210323 |