CN112510252B - 作为锂电池用的Li超级离子导体、固体电解质和涂层的锂钾元素氧化物化合物 - Google Patents
作为锂电池用的Li超级离子导体、固体电解质和涂层的锂钾元素氧化物化合物 Download PDFInfo
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- CN112510252B CN112510252B CN202010952947.8A CN202010952947A CN112510252B CN 112510252 B CN112510252 B CN 112510252B CN 202010952947 A CN202010952947 A CN 202010952947A CN 112510252 B CN112510252 B CN 112510252B
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- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 40
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000000576 coating method Methods 0.000 title claims abstract description 9
- 239000007784 solid electrolyte Substances 0.000 title abstract description 20
- 239000010416 ion conductor Substances 0.000 title abstract description 14
- OILJKQSQOGTECA-UHFFFAOYSA-N lithium potassium oxygen(2-) Chemical class [O-2].[K+].[Li+] OILJKQSQOGTECA-UHFFFAOYSA-N 0.000 title abstract description 5
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 75
- 239000000463 material Substances 0.000 claims abstract description 58
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000007787 solid Substances 0.000 claims abstract description 32
- 150000001875 compounds Chemical class 0.000 claims abstract description 30
- 239000003792 electrolyte Substances 0.000 claims abstract description 27
- 230000004913 activation Effects 0.000 claims abstract description 12
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 5
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- 238000002441 X-ray diffraction Methods 0.000 claims description 21
- 239000013078 crystal Substances 0.000 claims description 19
- 230000005855 radiation Effects 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- CAKRAHQRJGUPIG-UHFFFAOYSA-M sodium;[4-azaniumyl-1-hydroxy-1-[hydroxy(oxido)phosphoryl]butyl]-hydroxyphosphinate Chemical compound [Na+].NCCCC(O)(P(O)(O)=O)P(O)([O-])=O CAKRAHQRJGUPIG-UHFFFAOYSA-M 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 10
- 239000002131 composite material Substances 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 8
- OBTSLRFPKIKXSZ-UHFFFAOYSA-N lithium potassium Chemical compound [Li].[K] OBTSLRFPKIKXSZ-UHFFFAOYSA-N 0.000 abstract description 5
- 150000002500 ions Chemical class 0.000 abstract description 3
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 238000004088 simulation Methods 0.000 description 13
- 239000004020 conductor Substances 0.000 description 12
- 150000001450 anions Chemical class 0.000 description 11
- 238000011160 research Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 239000006182 cathode active material Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000011149 active material Substances 0.000 description 4
- 239000006183 anode active material Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 239000002019 doping agent Substances 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 229910052723 transition metal Inorganic materials 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910003405 Li10GeP2S12 Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000329 molecular dynamics simulation Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 239000006069 physical mixture Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 101000827703 Homo sapiens Polyphosphoinositide phosphatase Proteins 0.000 description 1
- 239000002227 LISICON Substances 0.000 description 1
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 1
- 229910018869 La0.5Li0.5TiO3 Inorganic materials 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- -1 Li 3 PS 4 Chemical class 0.000 description 1
- 229910009178 Li1.3Al0.3Ti1.7(PO4)3 Inorganic materials 0.000 description 1
- 229910002984 Li7La3Zr2O12 Inorganic materials 0.000 description 1
- 229910011201 Li7P3S11 Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 1
- 229910012305 LiPON Inorganic materials 0.000 description 1
- 239000002228 NASICON Substances 0.000 description 1
- 102100023591 Polyphosphoinositide phosphatase Human genes 0.000 description 1
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- DGDSIQMOMSVSCV-UHFFFAOYSA-N [Ir]=O.[K].[Li] Chemical class [Ir]=O.[K].[Li] DGDSIQMOMSVSCV-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002447 crystallographic data Methods 0.000 description 1
- 238000007418 data mining Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 1
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 1
- CJYZTOPVWURGAI-UHFFFAOYSA-N lithium;manganese;manganese(3+);oxygen(2-) Chemical compound [Li+].[O-2].[O-2].[O-2].[O-2].[Mn].[Mn+3] CJYZTOPVWURGAI-UHFFFAOYSA-N 0.000 description 1
- VGYDTVNNDKLMHX-UHFFFAOYSA-N lithium;manganese;nickel;oxocobalt Chemical compound [Li].[Mn].[Ni].[Co]=O VGYDTVNNDKLMHX-UHFFFAOYSA-N 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052976 metal sulfide Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 229910001251 solid state electrolyte alloy Inorganic materials 0.000 description 1
- 238000010671 solid-state reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002887 superconductor Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/04—Halides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G30/00—Compounds of antimony
- C01G30/006—Halides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G30/00—Compounds of antimony
- C01G30/02—Antimonates; Antimonites
- C01G30/026—Antimonates; Antimonites containing at least two metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G33/00—Compounds of niobium
- C01G33/006—Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G41/00—Compounds of tungsten
- C01G41/006—Compounds containing tungsten, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/002—Compounds containing ruthenium, rhodium, palladium, osmium, iridium or platinum, with or without oxygen or hydrogen, and containing two or more other elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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- H—ELECTRICITY
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/665—Composites
- H01M4/667—Composites in the form of layers, e.g. coatings
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/570,888 US11018375B2 (en) | 2019-09-13 | 2019-09-13 | Lithium potassium element oxide compounds as Li super-ionic conductor, solid electrolyte and coating layer for lithium metal battery and lithium-ion battery |
| US16/570,888 | 2019-09-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112510252A CN112510252A (zh) | 2021-03-16 |
| CN112510252B true CN112510252B (zh) | 2024-05-24 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010952947.8A Active CN112510252B (zh) | 2019-09-13 | 2020-09-11 | 作为锂电池用的Li超级离子导体、固体电解质和涂层的锂钾元素氧化物化合物 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US11018375B2 (https=) |
| JP (1) | JP7582823B2 (https=) |
| CN (1) | CN112510252B (https=) |
| DE (1) | DE102020123739A1 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112186242B (zh) * | 2020-09-29 | 2022-04-15 | 清华大学深圳国际研究生院 | 无机氧化物固态电解质材料、制备方法、锂离子电池及电子装置 |
| JP2023080494A (ja) * | 2021-11-30 | 2023-06-09 | 国立大学法人信州大学 | イリジウム固溶マンガン酸化物 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101378114A (zh) * | 2007-08-30 | 2009-03-04 | 索尼株式会社 | 阳极及其制造方法、二次电池及其制造方法 |
| CN103000934A (zh) * | 2011-09-16 | 2013-03-27 | 苏州宝时得电动工具有限公司 | 锂硫电池 |
| WO2013137224A1 (ja) * | 2012-03-15 | 2013-09-19 | 株式会社 村田製作所 | 全固体電池およびその製造方法 |
| CN104078647A (zh) * | 2013-03-27 | 2014-10-01 | 比亚迪股份有限公司 | 一种锂离子电池负极及其制备方法和锂离子电池 |
| CN106229447A (zh) * | 2016-08-10 | 2016-12-14 | 东莞永蓝电子科技有限公司 | 一种锂离子电池 |
| WO2017045944A1 (de) * | 2015-09-16 | 2017-03-23 | Robert Bosch Gmbh | Beschichtetes kathodenaktivmaterial für eine batteriezelle |
| CN208489305U (zh) * | 2018-06-27 | 2019-02-12 | 江西星盈科技有限公司 | 一种由复合型固态电解质组成的全固态锂电池 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4668593A (en) | 1986-08-29 | 1987-05-26 | Eltron Research, Inc. | Solvated electron lithium electrode for high energy density battery |
| DE102004010892B3 (de) | 2004-03-06 | 2005-11-24 | Christian-Albrechts-Universität Zu Kiel | Chemisch stabiler fester Lithiumionenleiter |
| US7300722B2 (en) * | 2005-04-11 | 2007-11-27 | The Gillette Company | Lithium battery containing bismuth metal oxide |
| US8784512B2 (en) | 2007-08-13 | 2014-07-22 | University Of Virginia Patent Foundation | Thin film battery synthesis by directed vapor deposition |
| JP5525388B2 (ja) | 2009-09-03 | 2014-06-18 | 日本碍子株式会社 | セラミックス材料及びその製造方法 |
| DE102011013018B3 (de) | 2011-03-04 | 2012-03-22 | Schott Ag | Lithiumionen leitende Glaskeramik und Verwendung der Glaskeramik |
| US9070950B2 (en) | 2012-03-26 | 2015-06-30 | Semiconductor Energy Laboratory Co., Ltd. | Power storage element, manufacturing method thereof, and power storage device |
| JP2016091995A (ja) | 2014-10-30 | 2016-05-23 | 株式会社デンソー | リチウム空気電池及びリチウム空気電池装置 |
| US10446872B2 (en) * | 2015-08-04 | 2019-10-15 | Samsung Electronics Co., Ltd. | Solid electrolyte and lithium battery including the same |
| FR3046498B1 (fr) | 2015-12-31 | 2019-11-29 | I-Ten | Batterie entierement solide comprenant un electrolyte solide et une couche de materiau conducteur ionique |
-
2019
- 2019-09-13 US US16/570,888 patent/US11018375B2/en active Active
-
2020
- 2020-09-11 JP JP2020153091A patent/JP7582823B2/ja active Active
- 2020-09-11 DE DE102020123739.1A patent/DE102020123739A1/de active Pending
- 2020-09-11 CN CN202010952947.8A patent/CN112510252B/zh active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101378114A (zh) * | 2007-08-30 | 2009-03-04 | 索尼株式会社 | 阳极及其制造方法、二次电池及其制造方法 |
| CN103000934A (zh) * | 2011-09-16 | 2013-03-27 | 苏州宝时得电动工具有限公司 | 锂硫电池 |
| WO2013137224A1 (ja) * | 2012-03-15 | 2013-09-19 | 株式会社 村田製作所 | 全固体電池およびその製造方法 |
| CN104078647A (zh) * | 2013-03-27 | 2014-10-01 | 比亚迪股份有限公司 | 一种锂离子电池负极及其制备方法和锂离子电池 |
| WO2017045944A1 (de) * | 2015-09-16 | 2017-03-23 | Robert Bosch Gmbh | Beschichtetes kathodenaktivmaterial für eine batteriezelle |
| CN106229447A (zh) * | 2016-08-10 | 2016-12-14 | 东莞永蓝电子科技有限公司 | 一种锂离子电池 |
| CN208489305U (zh) * | 2018-06-27 | 2019-02-12 | 江西星盈科技有限公司 | 一种由复合型固态电解质组成的全固态锂电池 |
Non-Patent Citations (2)
| Title |
|---|
| FIRST PRINCIPLES COMPUTATIONAL DESIGN OF SOLID IONIC CONDUCTORS THROUGH ION SUBSTITUTION;Qiang Bai;《Doctorial thesis，US，Univ. Maryland》;第71-92页 * |
| Qiang Bai.FIRST PRINCIPLES COMPUTATIONAL DESIGN OF SOLID IONIC CONDUCTORS THROUGH ION SUBSTITUTION.《Doctorial thesis，US，Univ. Maryland》.2019,第71-92页. * |
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| JP2021048127A (ja) | 2021-03-25 |
| JP7582823B2 (ja) | 2024-11-13 |
| CN112510252A (zh) | 2021-03-16 |
| US20210083319A1 (en) | 2021-03-18 |
| DE102020123739A1 (de) | 2021-03-18 |
| US11018375B2 (en) | 2021-05-25 |
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Effective date of registration: 20250224 Address after: Japan Patentee after: Toyota Motor Corp. Country or region after: Japan Patentee after: University OF MARYLAND, COLLEGE PARK Country or region after: U.S.A. Address before: Texas in the United States Patentee before: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, Inc. Country or region before: U.S.A. Patentee before: University OF MARYLAND, COLLEGE PARK |