Device and method for deep purification treatment and reuse of mine water for production
Technical Field
The invention relates to mine water treatment equipment, in particular to a device and a treatment method for deep purification treatment and reuse of mine water in production, and belongs to the technical field of mine water treatment equipment.
Background
China is one of the countries which are acknowledged to be seriously deficient in water resources of individuals in the world, along with the continuous increase of population and the rapid development of economy, the demand of industrial, agricultural and domestic water is more and more, so that the situation of fresh water resource deficiency is increasingly serious, China is the country with the largest coal yield in the world in the 21 st century, and meanwhile, the discharge amount and the production amount of mine water of coal mines are the first of industrial wastewater in China, so the level of mine water resource treatment is improved, a new mine water resource treatment technology is popularized, mine water recycling is developed for production, and mine water recycling is a necessary choice for mine development.
The mine water has the characteristics of underground water and obvious characteristics of the coal mine industry, the characteristics of the mine water depend on the geological environment of the finished coal and the chemical components of minerals of the coal bottom layer, and the mine water is closely related to the production process and the like. In order to protect the safety of underground mining production engineering and prevent mine flood caused by excessive mine water flowing into a mine tunnel, the mine water needs to be pumped out of a mine in the mining process, the treatment standard does not meet the production and discharge requirements, huge water resource waste is formed, and meanwhile pollutants contained in the mine water destroy a local ecological system.
The treatment technology and the effect are determined by the properties of the mine water and the application after treatment, when the acid and the alkali of the mine water are basically neutral and have no toxic heavy metal substances, suspended matters become the key points of purification treatment, the mine water has the difficulties of large content and concentration difference of the suspended matters, small granularity, light specific gravity and low settling speed, and the mine water also contains partial ions, a small amount of organic matters and a large amount of bacteria, the key point of treating the mine water is to remove the suspended matters and the bacteria, and how to better remove the harmful substances is the technical problem existing at present.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the device and the method for deeply purifying and reusing mine water for production are characterized in that an automatic dosing device and an automatic control system of polyaluminium chloride (PAC) and Polyacrylamide (PAM) are additionally arranged between a high-level sewage storage and regulation tank and purification equipment, so that the dosing amount is regulated according to the change of inflow, the dosage of a medicament is accurately controlled, and the flocculation effect is exerted to the maximum extent. By organically combining the MBR technology with the traditional wastewater biological treatment technology, the solid-liquid separation efficiency is greatly improved, and the CODcr and SS indexes of the mine water after deep purification are lower than specified values. The mode of preparing sodium hypochlorite on site by a generator replaces chlorine gas to disinfect the purified mine water, so that the operation cost is reduced, accurate medicine adding is realized, the disinfection effect is improved, the mine water is recycled to an underground production system, and the existing problems are effectively solved.
The technical scheme of the invention is as follows: the device comprises a ground water storage tank, a high-position primary-sedimentation water storage regulating tank, a reuse water tank and an underground production water supply system, wherein the ground water storage tank is connected with the high-position primary-sedimentation water storage regulating tank through a water pipe, the high-position primary-sedimentation water storage regulating tank is connected with a multi-medium filter through a pipeline for a purifying device, the multi-medium filter is connected to the underground production water supply system through a membrane biological reaction tank and the reuse water tank, and an automatic chemical feeding device is arranged on the water pipe.
The device is also provided with a sodium hypochlorite generating device which is connected to the reuse water pool through a pipeline.
The bottom of the purifying device is connected with a sludge concentration tank through a pipeline, and the sludge concentration tank is connected with a high-level primary sedimentation water storage regulating tank through a pipeline.
The upper part of the multi-medium filter is connected with the purification device through a pipeline.
A treatment method for deep purification treatment and reuse of mine water in a production device comprises the following steps: pumping underground mine sewage from the underground to a ground water storage tank through a pump, adjusting the water quantity entering a subsequent deep purification treatment system, conveying the mine sewage to a high-level primary sedimentation water storage adjusting tank, removing large-size floaters and suspended matters mainly comprising organic matters after intercepting the sewage, reducing the concentration of suspended solids in the sewage, overflowing the primarily filtered mine water into a pipe water conveying pipe in the high-level primary sedimentation water storage adjusting tank by utilizing high-level pressure difference of the mine water through a pipeline, connecting the water conveying pipe with an automatic dosing device of polyaluminium chloride (PAC) and Polyacrylamide (PAM), adjusting the dosing quantity according to the change of inflow water, and accurately controlling the dosing quantity of a medicament; secondly, the preliminarily filtered mine sewage, the polymeric flocculant and the coagulant aid enter a purification device, namely a labyrinth sloping plate purification treatment system, under the actions of flocculant compression double electric layers, electric neutralization, tape winding net capture, adsorption bridging and the like, COD (chemical oxygen demand) particulate matters are precipitated, larger flocs are formed among inorganic particles, a huge surface adsorption effect is increased, and the concentration of suspended matters of microorganisms and inorganic matters is greatly reduced; thirdly, the sludge treated by the purifying device is discharged to a sludge concentration tank for concentration by a siphon sludge discharge pipeline, and clear liquid returns to the high-level primary sedimentation water storage regulating tank to be mixed with subsequent mine sewage again under the action of flocculation ions, so that the operation load of the purifying device is reduced, and the cost of adding a flocculating agent is saved; fourthly, the mine sewage treated by the purification device enters a multi-medium filter, and after multi-medium filtration, activated carbon filtration and back flushing, the sewage which does not accord with the condition that the mine sewage flows out of the multi-medium filter is conveyed to the purification device again for circular treatment; the mine water meeting the discharge standard is conveyed to a membrane bioreactor, namely an MBR reaction tank, the characteristic of organic combination of a membrane separation technology and a traditional wastewater treatment technology is utilized to deeply purify the relatively purified mine water, and the suspended substance and the turbidity of the mine water after ultrafiltration meet the recycling production standard; and fifthly, discharging the deeply purified mine water to a reuse water pool, quantitatively conveying sodium hypochlorite into the reuse water pool by a sodium hypochlorite generating device, performing high-efficiency and safe strong sterilization and disinfection, and enabling the deeply purified terminal water to be recycled to the underground production water supply system through a pipeline.
The invention has the beneficial effects that: compared with the prior art, the water treatment method has the advantages that the automatic dosing device and the automatic control system are adopted, the dosing amount is adjusted according to the change of the inflow water, the dosage of the medicament is accurately controlled, the flocculation effect is exerted to the maximum extent, the situations that medicament solution concentration is too high, too low, dry powder is easy to agglomerate and the like due to inaccurate medicament dry powder addition caused by manual feeding are prevented, the mine water treatment cost is saved, the defects that a medicament solvent cannot be fully dissolved through long-time stirring, the effect is small, the effect is poor and the like are avoided, the preliminary purification quality of mine water is improved, the characteristics of stable and reliable operation are realized, the automation degree is greatly improved, and the labor intensity of workers is reduced.
According to the invention, in the primary purification process, mine water which does not meet the requirement of entering the subsequent treatment process is circulated and enters the primary purification link, so that the dosage of flocculating agents, coagulant aids and other medicaments is reduced, the subsequent mine water treatment effect is improved, the advanced treatment difficulty and the system pressure are relieved, and the advanced treatment is ensured to relieve the water quality to reach the standard.
Aiming at the characteristics of more mine water suspended matters, large difference of particle size distribution and the like, the mine water deep purification method fully utilizes the links of filtering systems such as multi-medium filtering, activated carbon filtering, back flushing and the like, performs ultrafiltration under the action of membrane bioreaction, and performs sterilization and disinfection by using a sodium hypochlorite solution, thereby ensuring that the mine water suspended matters, turbidity and the like after deep purification meet production indexes, and ensuring the safe use of the treated mine water.
Drawings
FIG. 1 is a schematic flow chart of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings.
Example 1: as shown in the attached figure 1, the device for deep purification treatment and reuse of mine water for production comprises a ground water storage tank 1, a high-position primary-sedimentation water storage regulating tank 2, a reuse water tank 9 and an underground production water supply system 11, wherein the ground water storage tank 1 is connected with the high-position primary-sedimentation water storage regulating tank 2 through a water pipe 3, the high-position primary-sedimentation water storage regulating tank 2 is connected with a multi-medium filter 7 through a purification device 5 by a pipeline, the multi-medium filter 7 is connected to the underground production water supply system 11 through a membrane biological reaction tank 8 and the reuse water tank 9, and an automatic chemical feeding device 4 is arranged on the water pipe 3.
Further, the device is also provided with a sodium hypochlorite generating device 10, and the sodium hypochlorite generating device 10 is connected to the reuse water tank 9 through a pipeline.
Further, the bottom of the purifying device 5 is connected with a sludge concentration tank 6 through a pipeline, and the sludge concentration tank 6 is connected with the high-level primary sedimentation water storage regulating tank 2 through a pipeline.
Further, the upper part of the multimedia filter 7 is connected to the purification apparatus 5 through a pipe.
A treatment method for deep purification treatment and reuse of mine water in a production device comprises the following steps: pumping underground mine sewage from the underground to a ground water storage tank 1 through a pump, adjusting the water quantity entering a subsequent deep purification treatment system, conveying the mine sewage to a high-level primary sedimentation water storage adjusting tank 2, removing large-size floaters and suspended matters mainly comprising organic matters after the sewage is intercepted, reducing the concentration of suspended solids in the sewage, overflowing preliminarily filtered mine water into a pipe water conveying pipe 3 in the high-level primary sedimentation water storage adjusting tank 2 through a pipeline by utilizing the high-level pressure difference of the mine water, connecting the water conveying pipe 3 with an automatic dosing device 4 of polyaluminium chloride PAC and Polyacrylamide (PAM), adjusting the dosing quantity according to the change of inflow water, and accurately controlling the dosing quantity; secondly, the preliminarily filtered mine sewage, the polymeric flocculant and the coagulant aid enter a purification device 5, namely a labyrinth sloping plate purification treatment system, under the actions of flocculant compression double electric layers, electric neutralization, tape winding net capture, adsorption bridging and the like, COD (chemical oxygen demand) particulate matters are precipitated, larger flocs are formed among inorganic particles, the huge surface adsorption effect is increased, and the suspended matter concentration of microorganisms and inorganic matters is greatly reduced; thirdly, the sludge treated by the purifying device 5 is discharged to a sludge concentration tank 6 for concentration by a siphon sludge discharge pipeline, and clear liquid returns to the high-level primary sedimentation water storage regulating tank 2 to be mixed with subsequent mine sewage again under the action of flocculation ions, so that the operation load of the purifying device is reduced, and the cost of adding a flocculating agent is saved; fourthly, the mine sewage treated by the purification device 5 enters the multi-media filter 7, and after multi-media filtration, activated carbon filtration and back flushing, the sewage which does not accord with the condition that the mine sewage flows out of the multi-media filter 7 is conveyed to the purification device 5 again for circular treatment; the mine water meeting the discharge standard is conveyed to a membrane bioreactor 8, namely an MBR reaction tank, the characteristic of organic combination of a membrane separation technology and a traditional wastewater treatment technology is utilized to deeply purify the relatively purified mine water, and the suspended substance and the turbidity of the mine water after ultrafiltration meet the recycling production standard; and fifthly, discharging the deeply purified mine water to a reuse water tank 9, conveying sodium hypochlorite to the reuse water tank 9 by a sodium hypochlorite generating device 10 in a fixed amount, performing high-efficiency and safe strong sterilization and disinfection, and returning the deeply purified terminal water to the underground production water supply system 11 through a pipeline.
The water treatment method comprises an automatic chemical feeding device and an automatic control system, the chemical feeding amount is adjusted according to the change of the water inflow, the chemical dosage is accurately controlled, the flocculation effect is exerted to the maximum extent, the situations that chemical dry powder is not accurately added due to manual feeding, the concentration of a chemical solution is too high, too low, the dry powder is easy to agglomerate and the like are easily caused, the mine water treatment cost is saved, the defects that a chemical solvent cannot be fully dissolved through long-time stirring, the effect is small, the effect is poor and the like are overcome, the primary purification quality of mine water is improved, the automatic control method has the characteristics of stable and reliable operation, the automation degree is greatly improved, and the labor intensity of.
According to the invention, in the primary purification process, mine water which does not meet the requirement of entering the subsequent treatment process is circulated and enters the primary purification link, so that the dosage of flocculating agents, coagulant aids and other medicaments is reduced, the subsequent mine water treatment effect is improved, the advanced treatment difficulty and the system pressure are relieved, and the advanced treatment is ensured to relieve the water quality to reach the standard.
Aiming at the characteristics of more mine water suspended matters, large difference of particle size distribution and the like, the mine water deep purification method fully utilizes the links of filtering systems such as multi-medium filtering, activated carbon filtering, back flushing and the like, performs ultrafiltration under the action of membrane bioreaction, and performs sterilization and disinfection by using a sodium hypochlorite solution, thereby ensuring that the mine water suspended matters, turbidity and the like after deep purification meet production indexes, and ensuring the safe use of the treated mine water.
The present invention is not described in detail, but is known to those skilled in the art. Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.