CN112236303A - Flame-retardant modified asphalt waterproof roll coating material, flame-retardant self-adhesive asphalt waterproof roll and preparation method thereof - Google Patents

Flame-retardant modified asphalt waterproof roll coating material, flame-retardant self-adhesive asphalt waterproof roll and preparation method thereof Download PDF

Info

Publication number
CN112236303A
CN112236303A CN201980029462.7A CN201980029462A CN112236303A CN 112236303 A CN112236303 A CN 112236303A CN 201980029462 A CN201980029462 A CN 201980029462A CN 112236303 A CN112236303 A CN 112236303A
Authority
CN
China
Prior art keywords
flame
retardant
layer
parts
asphalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201980029462.7A
Other languages
Chinese (zh)
Inventor
窦登裕
吴士玮
刘金景
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Oriental Yuhong Building Materials Co ltd
Original Assignee
Huizhou Oriental Yuhong Building Materials Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huizhou Oriental Yuhong Building Materials Co ltd filed Critical Huizhou Oriental Yuhong Building Materials Co ltd
Publication of CN112236303A publication Critical patent/CN112236303A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B11/00—Layered products comprising a layer of bituminous or tarry substances
    • B32B11/04—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B11/046—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B11/00—Layered products comprising a layer of bituminous or tarry substances
    • B32B11/10—Layered products comprising a layer of bituminous or tarry substances next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • E—FIXED CONSTRUCTIONS
    • E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
    • E02D31/02—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against ground humidity or ground water
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/66—Sealings
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
    • E04D5/10—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Electromagnetism (AREA)
  • Hydrology & Water Resources (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Paleontology (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The waterproof coiled material comprises a metal glass fiber grid composite flame-retardant layer, a flame-retardant modified asphalt layer, a glass fiber tire flame-retardant layer, a flame-retardant self-adhesive asphalt layer and an isolation layer which are sequentially arranged from top to bottom. The thickness is thin, so that the building energy-saving trend is met; cold self-adhesion construction, high bonding strength, good heat resistance, no open fire construction, convenient construction, safety and environmental protection; the flame-retardant fireproof door has excellent waterproof flame-retardant performance, multiple layers of flame-retardant materials are cooperatively flame-retardant, the fireproof grade is B1, and the combustion is stopped after the door leaves a fire source. The flame-retardant waterproof coating is particularly suitable for building waterproofing with high waterproof requirements, can be flame-retardant from inside to outside and from outside to inside, and has excellent flame-retardant performance and wide application prospect.

Description

Flame-retardant modified asphalt waterproof roll coating material, flame-retardant self-adhesive asphalt waterproof roll and preparation method thereof
Technical Field
The invention belongs to the technical field of building waterproof coiled materials, and particularly relates to a coating material for a flame-retardant modified asphalt waterproof coiled material, a flame-retardant self-adhesive asphalt waterproof coiled material and a preparation method thereof.
Background
The construction of self-adhesion coiled material need not use naked light, and the construction is convenient, and water-proof effects is good, is an environment-friendly waterproof material, and the wide application is in the waterproof engineering of all kinds of civilian and industrial buildings, but ordinary self-adhesion coiled material high temperature resistance can be poor, and the waterproof layer is destroyed easily under the high temperature environment to lose water-proof effects, and ordinary pitch coiled material does not possess fire-retardant characteristic, can't use at the high building waterproof position of some fire prevention requirements. At the present stage, building energy conservation is a development trend, water resistance and heat preservation generally exist at the same time, and the fire-proof grade of a heat-preservation material is low, so that research and development of a self-adhesive waterproof coiled material with good flame retardant property and excellent high temperature resistance are particularly important. The main technical approach of the existing flame-retardant asphalt waterproof coiled material is to realize the flame-retardant function by adding mineral granules or adding a flame-retardant coating, so that the flame-retardant asphalt waterproof coiled material is thick in thickness, large in bearing capacity, high in cost, single in function, not ideal in flame-retardant effect, and not beneficial to energy conservation and environmental protection.
Chinese patent application CN201610398590.7 self-cleaning flame-retardant self-adhesive modified asphalt waterproof coiled material discloses a self-cleaning flame-retardant self-adhesive modified asphalt waterproof coiled material, which comprises a tire base layer, wherein the upper and lower surfaces of the tire base layer are respectively impregnated with an upper SBS self-adhesive modified asphalt mastic layer and a lower SBS self-adhesive modified asphalt mastic layer, the upper part of the upper mastic layer is sequentially covered with a flame-retardant layer and a super-hydrophobic self-cleaning layer, and the lower mastic layer is covered with a protective layer.
Chinese patent application CN 201610399904.5 discloses a flame-retardant waterproof roll, which comprises a surface protection layer, a reinforcing layer, a flame-retardant layer, a waterproof roll layer, an isolation film and a waterproof coating layer, which are sequentially stacked.
The Chinese patent application CN201710154732.X discloses a flame-retardant modified asphalt waterproof coiled material, which sequentially comprises the following components from top to bottom: the flame retardant is fully coated with two acrylic water-based paint flame retardants, 1mm thick asbestos fiber mesh cloth, 1.5mm thick SBR modified asphalt waterproof coiled material and 1mm thick glass fiber felt base cloth.
The Chinese patent application CN 201811134248.1 discloses a high heat-resistant flame-retardant self-adhesive waterproof coiled material, which comprises an upper surface isolation layer, a self-adhesive binder layer, a base and a lower surface isolation layer; the self-adhesive rubber comprises, by weight, 20-30 parts of 90# asphalt, 5-10 parts of 10# asphalt, 10-20 parts of aromatic oil, 20-30 parts of SBS, 5-10 parts of polypropylene, 5-10 parts of phenolic resin, 5-10 parts of SBR, 10-15 parts of rubber powder, 5-10 parts of light calcium carbonate and 2-6 parts of a mixed flame retardant. This thermal-insulated waterproofing membrane of pitch from the bottom up includes first barrier film, first pitch layer, child basic unit, second pitch layer, second barrier film and reflection thermal-protective layer in proper order.
Chinese patent application CN 201811134252.8 discloses an exposed flame-retardant strong cross-film self-adhesive waterproof roll and a preparation method thereof, wherein the anti-aging layer on the surface of the roll comprises terpolymer ASA70-80 parts, white master batch 2-3 parts, antioxidant 1-2 parts, ultraviolet absorbent 3-5 parts, flame retardant 20-30 parts, and flame-retardant strong cross-film waterproof layer comprising high-density polyethylene 60-80 parts, KT resin 10-20 parts, antioxidant 1-2 parts and flame retardant 20-30 parts.
The coiled material described in the chinese patent application CN 201610399904.5 has a flame retardant layer coated on the upper surface, and flame retardant is mainly performed by the flame retardant material on the upper surface, and the flame retardant layer is poly phosphoric acid amine; the coil flame-retardant layer described in the chinese patent application CN 201610399904.5 is self-adhesive modified asphalt, but the waterproof flame-retardant components and the formula are not described; the flame retardant technology adopted by the coiled material described in the Chinese patent application CN201710154732.X is that the total thickness of an acrylic water-based paint flame retardant and a 1mm thick asbestos fiber mesh cloth coiled material exceeds 4 mm; the flame-retardant self-adhesive coiled material described in the Chinese patent application CN 201811134248.1 is mainly subjected to flame retardance through a flame-retardant self-adhesive formula, the added flame retardant is mainly an inorganic flame retardant magnesium hydroxide, secondary and tertiary flame retardance is not carried out on the structure, and the flame-retardant effect is limited only by the formula; the flame-retardant self-adhesive coiled material described in the chinese patent application CN 201811134252.8 is mainly an exposed flame-retardant strong cross-film self-adhesive waterproof coiled material, and flame-retardant is performed through the flame-retardant cross-film on the surface.
Disclosure of Invention
The invention aims to solve the problems of thick thickness, heavy weight, high energy consumption, poor bonding and heat resistance of the common flame-retardant coiled material and the problem of low flame-retardant grade of the conventional flame-retardant self-adhesive coiled material.
In order to achieve the above object, a first aspect of the present invention provides a flame-retardant modified asphalt waterproofing membrane coating material, which comprises the following raw materials:
100-150 parts of low-grade petroleum asphalt, 15-40 parts of high-grade petroleum asphalt, 25-40 parts of polymer modifier, 5-8 parts of tackifier, 5-10 parts of flame retardant, 4-8 parts of functional assistant and 15-20 parts of first filler;
the low-grade petroleum asphalt is selected from at least one of 50# -90# petroleum asphalt;
the high-grade petroleum asphalt is selected from at least one of 180# -200# petroleum asphalt;
the tackifier comprises at least one of C5-C9 series petroleum resin and polyisobutylene;
the flame retardant comprises at least one of aluminum hydroxide and magnesium hydroxide and a phosphate ester flame retardant.
Preferably, the low-grade petroleum asphalt is 50# petroleum asphalt, such as 50# petroleum asphalt with penetration degree of 55 and softening point of 60-70 ℃.
As a preferable scheme, the high-grade petroleum asphalt is 180# petroleum asphalt, the flash point is 200- & ltSUB & gt 220- & lt/SUB & gt, and if 180# petroleum asphalt meeting the above indexes and having a softening point of 25-30 ℃ and a qualified low-temperature flexibility of-20 ℃ is selected.
Preferably, the first filler is 300-500-mesh light calcium carbonate.
In the present invention, each raw material component can be commercially available.
The preparation method of the flame-retardant modified asphalt waterproof coiled material coating material comprises the following steps: mixing and stirring low-grade petroleum asphalt, high-grade petroleum asphalt, a polymer modifier, a tackifier, a functional assistant and a filler, controlling the temperature to be 170-plus-180 ℃, shearing and mixing, then cooling to be 140-plus-150 ℃, adding a flame retardant and stirring to obtain the flame-retardant modified asphalt waterproof coiled material coating material.
According to a specific embodiment of the invention, the preparation method of the flame-retardant modified asphalt waterproof coil coating material comprises the following steps: mixing and stirring low-grade petroleum asphalt, high-grade petroleum asphalt, a polymer modifier, a tackifier, a functional assistant and a filler at the rotation speed of 2500-.
The invention provides a flame-retardant self-adhesive asphalt waterproof coiled material, which comprises a metal fiberglass mesh composite flame-retardant layer, a flame-retardant modified asphalt layer, a fiberglass tire flame-retardant layer, a flame-retardant self-adhesive asphalt layer and an isolation layer, which are sequentially arranged from top to bottom;
the metal glass fiber grid composite flame-retardant layer comprises an aluminum foil layer, a glass fiber grid layer and an HDPE film layer which are sequentially arranged from top to bottom;
the preparation raw material of the flame-retardant modified asphalt layer is selected from the flame-retardant modified asphalt waterproof coiled material coating material.
Preferably, the edge part of one side of the upper surface of the flame-retardant modified asphalt layer is covered with an isolation edge film. The isolation edge film is preferably an LDPE film.
According to the invention, the glass fiber grid layer is made of glass fiber grid cloth.
According to the invention, the glass fiber tire flame-retardant layer is a glass fiber tire.
Preferably, the isolation layer is made of LDPE film.
Preferably, the flame-retardant self-adhesive asphalt layer comprises the following raw materials:
100-150 parts of low-grade petroleum asphalt, 35-60 parts of high-grade petroleum asphalt, 15-30 parts of polymer modifier, 6-10 parts of tackifier, 8-12 parts of flame retardant, 5-10 parts of functional assistant and 30-60 parts of second filler;
the low-grade petroleum asphalt is selected from at least one of 50# -90# petroleum asphalt;
the high-grade petroleum asphalt is selected from at least one of 180# -200# petroleum asphalt;
the tackifier comprises at least one of C5-C9 series petroleum resin and polyisobutylene;
the flame retardant comprises aluminum hydroxide and antimony trioxide;
the functional assistant comprises at least one of an antioxidant, an anti-aging agent and a light stabilizer.
Preferably, the low-grade petroleum asphalt is 50# petroleum asphalt, such as 50# petroleum asphalt with penetration degree of 55 and softening point of 60-70 ℃.
As a preferable scheme, the high-grade petroleum asphalt is 180# petroleum asphalt, the flash point is 200- & ltSUB & gt 220- & lt/SUB & gt, and if 180# petroleum asphalt meeting the above indexes and having a softening point of 25-30 ℃ and a qualified low-temperature flexibility of-20 ℃ is selected.
Preferably, the polymer modifier is selected from at least one of SSBR, SEBS, APAO, PSBR, SIS, SBS and polyethylene wax.
Preferably, the functional assistant includes at least one of an antioxidant, an anti-aging agent and a light stabilizer.
Preferably, the second filler is light calcium carbonate with 700-900 meshes.
According to a specific embodiment of the invention, the preparation method of the flame-retardant self-adhesive asphalt layer coating material comprises the following steps: mixing and stirring low-grade petroleum asphalt, high-grade petroleum asphalt, a polymer modifier, a tackifier, a functional assistant, a filler and a flame retardant for 25-35min at the temperature of 140-.
Preferably, the thickness of the flame-retardant self-adhesive asphalt waterproof roll is 1.5-2.0 mm.
According to a particular embodiment of the invention, a unit grammage of 20. + -.5 g/m may be used2An aluminum foil layer with the thickness of 0.04 plus or minus 0.01 mm;
according to a particular embodiment of the present invention,the unit gram weight can be selected to be 20 +/-5 g/m2The glass fiber mesh cloth with the thickness of 0.07 +/-0.02 mm is used for the glass fiber mesh layer;
according to a specific embodiment of the present invention, the unit gram weight of 40 + -5 g/m can be selected2HDPE film layer with thickness of 0.04 plus or minus 0.01 mm;
according to the invention, the aluminum foil layer, the glass fiber grid layer and the HDPE film layer in the metal glass fiber grid composite flame-retardant layer can be compounded into a whole through glue.
According to a specific embodiment of the present invention, a grammage of 80 + -10 g/m may be selected2And the glass fiber tire with the thickness of 0.7 +/-0.1 mm is used as the flame-retardant layer of the glass fiber tire.
According to a specific embodiment of the present invention, the thickness of the flame-retardant modified asphalt layer may be set to 0.3 to 0.6 mm;
according to a specific embodiment of the invention, the thickness of the flame-retardant self-adhesive asphalt layer can be set to 0.3-0.6 mm;
according to a specific embodiment of the present invention, the thickness of the release layer can be set to 0.03. + -. 0.005mm, for example 35g/m in gram weight2And an LDPE film with a thickness of 0.03 mm.
The third aspect of the invention provides a preparation method of the flame-retardant self-adhesive asphalt waterproof roll, which comprises the following steps: when the isolating layer passes through the primary thickness-fixing roller, coating a coating material of the flame-retardant self-adhesive asphalt layer on the isolating layer; paving a glass fiber tire flame-retardant layer before the isolation layer passes through a secondary thickness-fixing roller, performing secondary oiling and thickness fixing after the paving is finished, and coating a coating material of a flame-retardant modified asphalt layer on the glass fiber tire flame-retardant layer; and then covering the metal glass fiber grid composite flame-retardant layer on the upper surface of the coiled material, and then cooling, forming, rolling and packaging to obtain the flame-retardant self-adhesive asphalt waterproof coiled material.
According to a specific embodiment of the invention, the preparation method of the flame-retardant self-adhesive asphalt waterproof roll comprises the following steps: when the isolating layer passes through the primary thickness-fixing roller, coating a waterproof coiled material coating material of the prepared flame-retardant self-adhesive asphalt layer on the isolating layer by using an oil coating box, controlling the oil coating temperature to be 140-150 ℃, adjusting the thickness as required, and then carrying out primary cooling on a cooling device (a steel belt, a large roller or a water bed); paving a glass fiber tire flame-retardant layer before the isolation layer passes through a secondary thickness-fixing roller, coating the flame-retardant modified asphalt layer with a coating cover material prepared by coating an oil coating box on the glass fiber tire flame-retardant layer after the paving is finished, wherein the oil coating temperature is required to be controlled to be 140-150 ℃, and the thickness is adjusted as required; and then covering the upper surface of the coiled material with the metal glass fiber grid composite flame-retardant layer, wherein the coating temperature is required to be 40-50 ℃, covering an isolation edge film on one side edge of the upper surface, entering a water bed after the film is covered, and cooling, forming, rolling and packaging to obtain the flame-retardant self-adhesive asphalt waterproof coiled material.
The invention has the beneficial effects that:
the flame-retardant self-adhesive asphalt waterproof coiled material is thin in thickness and is suitable for the trend of building energy conservation; cold self-adhesion construction, high bonding strength, good heat resistance, no open fire construction, convenient construction, safety and environmental protection; the flame-retardant fireproof door has excellent waterproof flame-retardant performance, multiple layers of flame-retardant materials are cooperatively flame-retardant, the fireproof grade is B1, and the combustion is stopped after the door leaves a fire source. The flame-retardant waterproof coating is particularly suitable for building waterproofing with high waterproof requirements, can be flame-retardant from inside to outside and from outside to inside, and has excellent flame-retardant performance and wide application prospect.
The flame-retardant self-adhesive asphalt waterproof coiled material has two main functions, namely waterproofing and flame retardance, the waterproofing mainly depends on a flame-retardant modified asphalt layer, a flame-retardant self-adhesive asphalt layer and a metal glass fiber grid composite flame-retardant layer on the surface, the flame retardance has a flame-retardant effect through the synergistic action of multiple layers, and the metal glass fiber grid composite flame-retardant layer, the flame-retardant modified asphalt layer, the glass fiber tire flame-retardant layer and the flame-retardant self-adhesive asphalt layer are sequentially arranged from top to bottom. The structure is advanced and reasonable, the multilayer synergistic effect is realized, the flame retardant advantage and the waterproof advantage of each layer are fully exerted, and the waterproof and flame retardant effects are really realized; and the whole thickness of the coiled material is controlled to be below 2.0mm, and the mode of combining inorganic and organic flame retardants is adopted in the aspect of a flame-retardant formula, wherein the flame-retardant modified asphalt layer is mainly made of organic flame retardants, the flame-retardant self-adhesive asphalt layer is required to be bonded with a base layer, the inorganic flame retardants are mainly used, the two types of the inorganic flame retardants supplement each other, and the comprehensive waterproof flame-retardant effect can be improved.
The main technical parameters of the invention are as follows: the thickness of the coiled material is less than or equal to 2.0 mm; the peeling strength of the coiled material and the aluminum plate is more than or equal to 2.5N/mm; the heat resistance is 100 ℃, and the sliding, dripping and flowing are avoided; fire rating B1, stop burning after leaving the fire source.
Additional features and advantages of the invention will be set forth in the detailed description which follows.
Drawings
The above and other objects, features and advantages of the present invention will become more apparent by describing in more detail exemplary embodiments thereof with reference to the attached drawings.
Fig. 1 shows a schematic structural diagram of a flame-retardant self-adhesive asphalt waterproofing roll according to an embodiment of the present invention.
Description of reference numerals: the composite flame-retardant asphalt composite material comprises, by weight, 1-a metal glass fiber grid composite flame-retardant layer, 11-an aluminum foil layer, 12-a glass fiber grid layer, 13-a HDPE film layer, 2-a flame-retardant modified asphalt layer, 3-a glass fiber tire flame-retardant layer, 4-a flame-retardant self-adhesive asphalt layer, 5-an isolation layer and 6-an isolation edge film.
Detailed Description
Preferred embodiments of the present invention will be described in more detail below. While the following describes preferred embodiments of the present invention, it should be understood that the present invention may be embodied in various forms and should not be limited by the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
As shown in fig. 1, the flame-retardant self-adhesive asphalt waterproof roll provided in the embodiment of the invention comprises a metal fiberglass mesh composite flame-retardant layer 1, a flame-retardant modified asphalt layer 2, a fiberglass tire flame-retardant layer 3, a flame-retardant self-adhesive asphalt layer 4 and an isolation layer 5 which are sequentially arranged from top to bottom. The metal glass fiber grid composite flame-retardant layer 1 comprises an aluminum foil layer 11, a glass fiber grid layer 12 and an HDPE film layer 13 which are sequentially arranged from top to bottom. And an isolation edge film 6 is covered on the edge part of one side of the upper surface of the flame-retardant modified asphalt layer, and an LDPE film is adopted.
Wherein, the aluminum foil layer has a unit gram weight of 11 g/m2The thickness is 0.04 mm;the unit gram weight of the glass fiber mesh layer 12 is 20g/m2The glass fiber mesh cloth is 0.07mm thick; HDPE film layer 13 unit gram weight 40g/m2The thickness is 0.04 mm; the three layers of films are bonded by glue to form a metal fiberglass mesh composite flame-retardant layer 1, and the total gram weight is 85g/m2The thickness is 0.15mm, and the width is 950 mm; the breadth of the glass fiber tire (i.e. the glass fiber tire flame-retardant layer 3) is 990mm, the thickness is 0.7mm, and the gram weight is 80g/m2(ii) a Setting the thickness of the flame-retardant modified asphalt layer to be 0.6 mm; setting the thickness of the flame-retardant self-adhesive asphalt layer to be 0.6 mm; the thickness of the isolation layer is set to be 0.03mm, and the unit gram weight is 35g/m2And an LDPE film with a thickness of 0.03 mm.
In the embodiment of the invention, the preparation method of the flame-retardant modified asphalt layer coating material comprises the following steps: mixing and stirring low-grade petroleum asphalt, high-grade petroleum asphalt, a polymer modifier, a tackifier, a functional assistant and a filler at the temperature of 150 ℃ and the rotating speed of 3000rpm for 30min, controlling the temperature to be 175 ℃, shearing and mixing for 5.5h, then cooling to 150 ℃, adding a flame retardant and stirring for 30min to obtain the flame-retardant modified asphalt layer coating material.
In the embodiment of the invention, the preparation method of the flame-retardant self-adhesive asphalt layer coating material comprises the following steps: mixing and stirring low-grade petroleum asphalt, high-grade petroleum asphalt, a polymer modifier, a tackifier, a functional assistant, a filler and a flame retardant at the temperature of 150 ℃ and the rotating speed of 3000rpm for 30min, gradually raising the temperature, controlling the temperature to be 175 ℃, and shearing and mixing for 6h to obtain the flame-retardant self-adhesive asphalt layer coating material.
In the embodiment of the invention, the preparation method of the flame-retardant self-adhesive asphalt waterproof roll comprises the following steps:
when the isolation layer 5 passes through the primary thickness-fixing roller, coating the prepared waterproof coiled material coating material of the flame-retardant self-adhesive asphalt layer 4 on the isolation layer 5 by using an oil coating box, controlling the oil coating temperature to be 140-150 ℃, adjusting the thickness as required, and then performing primary cooling on a water bed; the method comprises the following steps that a glass fiber tire flame-retardant layer 3 is laid before an isolation layer 5 passes through a secondary thickness-fixing roller, secondary oiling and thickness fixing are carried out after the laying, a coating cover material of a prepared flame-retardant modified asphalt layer 2 is coated on the glass fiber tire flame-retardant layer 3 by using an oiling box, the oiling temperature is required to be controlled to be 140-150 ℃, and the thickness is adjusted as required; and then covering the upper surface of the coiled material with the metal glass fiber grid composite flame-retardant layer 1 at the required coating temperature of 40-50 ℃, covering an isolating edge film 6 on one side edge of the upper surface, entering a water bed after the film is covered, and cooling, forming, rolling and packaging to obtain the flame-retardant self-adhesive asphalt waterproof coiled material.
In the examples of the present invention, the parameters of the phosphate ester used are shown in Table 1:
TABLE 1
Appearance of the product Light yellow liquid Unit of
Phosphorus content 9.50％ ％
Specific gravity of 1.18-1.20 20℃，g/ml
Viscosity of the oil 40-45 25℃，mpa
Acidity of the solution ≤0.1 mg，KOH/g
Water content ≤0.1 ％
Color intensity ≤50 Pt-Co
Flash point 207-220 ℃
In the raw material composition of the flame-retardant self-adhesive asphalt layer according to the embodiment of the present invention, the parameters of the flame retardant are shown in table 2:
TABLE 2
Molecular formula Sb2O3 Al(OH)3 Unit of
Molecular weight 291.5 78
Melting Point 656 300 ℃
Density of 5.3 2.42 g/cm3
Appearance of the product White powder White powder
Whiteness degree ≥97 ≥97 ％
Average particle diameter 0.3-0.9 0.3-0.9 μm
Content (wt.) ≥99.9 ≥99.9 ％
Example 1
In this embodiment, the flame-retardant modified asphalt layer comprises the following raw materials:
105 parts of No. 50 petroleum asphalt, 25 parts of No. 180 petroleum asphalt, 26 parts of polymer modifier (15 parts of SEBS, 5 parts of SSBR and 6 parts of APAO), 5-8 parts of tackifier (4 parts of C5 petroleum resin, 2 parts of C9 petroleum resin and 2 parts of polyisobutylene), 8 parts of flame retardant (4 parts of aluminum hydroxide and 4 parts of phosphate), 4 parts of functional assistant (anti-aging agent BASF IRGAFOS 168, 2 parts of antioxidant BASF IRGANOX 1010 and 2 parts of light calcium carbonate with 400 meshes) and 20 parts of light calcium carbonate with 400 meshes.
In this embodiment, the flame-retardant self-adhesive asphalt layer is composed of the following raw materials:
130 parts of No. 50 petroleum asphalt, 40 parts of No. 180 petroleum asphalt, 31 parts of polymer modifier (5 parts of SEBS, 15 parts of PSBR, 5 parts of SIS and 6 parts of polyethylene wax), 9 parts of tackifier (4 parts of C5 petroleum resin and 5 parts of polyisobutylene), 12 parts of flame retardant (6 parts of aluminum hydroxide and 6 parts of antimony trioxide), 5 parts of functional additive (anti-aging agent BASF IRGAFOS 168, 2 parts of antioxidant BASF IRGANOX 1010 and 3 parts of antioxidant) and 55 parts of 800-mesh light calcium carbonate.
The product test results for example 1 are shown in table 3:
TABLE 3
Figure BDA0002752730840000101
Figure BDA0002752730840000111
Example 2
In this embodiment, the flame-retardant modified asphalt layer comprises the following raw materials:
120 parts of No. 50 petroleum asphalt, 20 parts of No. 180 petroleum asphalt, 23 parts of polymer modifier (SBS 8 parts, SSBR 9 parts and APAO 5 parts), 5-8 parts of tackifier (C5 petroleum resin 3 parts, C9 petroleum resin 3 parts and polyisobutylene 2 parts), 9 parts of flame retardant (aluminum hydroxide 3 parts and phosphate 6 parts), 4 parts of functional additive (anti-aging agent BASF IRGAFOS 168, 2 parts and light stabilizer TINUVIN 622, 2 parts) and 20 parts of 400-mesh light calcium carbonate.
In this embodiment, the flame-retardant self-adhesive asphalt layer is composed of the following raw materials:
120 parts of No. 50 petroleum asphalt, 45 parts of No. 180 petroleum asphalt, 30 parts of polymer modifier (SBS 8 parts, PSBR 12 parts, SSBR 5 parts and polyethylene wax 5 parts), 10 parts of tackifier (C5 petroleum resin 4 parts and polyisobutylene 6 parts), 12 parts of flame retardant (aluminum hydroxide 6 parts and antimony trioxide 6 parts), 5 parts of functional additive (anti-aging agent BASF IRGAFOS 168, 3 parts and antioxidant BASF IRGANOX 1010, 2 parts) and 60 parts of 800-mesh light calcium carbonate.
The product test results for example 2 are shown in table 4:
TABLE 4
Figure BDA0002752730840000112
Figure BDA0002752730840000121
Having described embodiments of the present invention, the foregoing description is intended to be exemplary, not exhaustive, and not limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments.

Claims (10)

1. The flame-retardant modified asphalt waterproof coiled material coating material is characterized by comprising the following raw materials:
100-150 parts of low-grade petroleum asphalt, 15-40 parts of high-grade petroleum asphalt, 25-40 parts of polymer modifier, 5-8 parts of tackifier, 5-10 parts of flame retardant, 4-8 parts of functional assistant and 15-20 parts of first filler;
the low-grade petroleum asphalt is selected from at least one of 50# -90# petroleum asphalt;
the high-grade petroleum asphalt is selected from at least one of 180# -200# petroleum asphalt;
the tackifier comprises at least one of C5-C9 series petroleum resin and polyisobutylene;
the flame retardant comprises at least one of aluminum hydroxide and magnesium hydroxide and a phosphate ester flame retardant.
2. The flame-retardant modified asphalt waterproofing membrane covering material according to claim 1, wherein the first filler is 300-500 mesh light calcium carbonate.
3. The flame-retardant self-adhesive asphalt waterproof coiled material is characterized by comprising a metal fiberglass mesh composite flame-retardant layer, a flame-retardant modified asphalt layer, a fiberglass tire flame-retardant layer, a flame-retardant self-adhesive asphalt layer and an isolating layer which are sequentially arranged from top to bottom;
the metal glass fiber grid composite flame-retardant layer comprises an aluminum foil layer, a glass fiber grid layer and an HDPE film layer which are sequentially arranged from top to bottom;
the flame-retardant modified asphalt layer is prepared from the raw materials selected from the flame-retardant modified asphalt waterproof coiled material coating material of claim 1 or 2.
4. The flame retarded self-adhesive asphalt waterproofing membrane according to claim 3,
the glass fiber base flame-retardant layer adopts a glass fiber base;
the isolation layer is made of an LDPE film.
5. The flame-retardant self-adhesive asphalt waterproofing membrane according to claim 3, wherein the flame-retardant self-adhesive asphalt layer is formed from the following raw materials:
100-150 parts of low-grade petroleum asphalt, 35-60 parts of high-grade petroleum asphalt, 15-30 parts of polymer modifier, 6-10 parts of tackifier, 8-12 parts of flame retardant, 5-10 parts of functional assistant and 30-60 parts of second filler;
the low-grade petroleum asphalt is selected from at least one of 50# -90# petroleum asphalt;
the high-grade petroleum asphalt is selected from at least one of 180# -200# petroleum asphalt;
the tackifier comprises at least one of C5-C9 series petroleum resin and polyisobutylene;
the flame retardant comprises at least one of aluminum hydroxide and magnesium hydroxide, and antimony trioxide.
6. The flame retarded self-adhesive asphalt waterproofing membrane according to claim 5,
the polymer modifier is selected from at least one of SSBR, SEBS, APAO, PSBR, SIS, SBS and polyethylene wax.
7. The flame-retardant self-adhesive asphalt waterproofing membrane according to claim 5, wherein the functional auxiliary agent comprises at least one of an antioxidant, an anti-aging agent and a light stabilizer.
8. The flame-retardant self-adhesive asphalt waterproofing membrane according to claim 5, wherein the second filler is 700-900 mesh light calcium carbonate.
9. The flame-retardant self-adhesive asphalt waterproofing membrane according to claim 3, wherein the thickness of the flame-retardant self-adhesive asphalt waterproofing membrane is 1.5 to 2.0 mm.
10. The preparation method of the flame-retardant self-adhesive asphalt waterproofing membrane according to any one of claims 3 to 9, characterized by comprising the steps of:
when the isolating layer passes through the primary thickness-fixing roller, coating a coating material of the flame-retardant self-adhesive asphalt layer on the isolating layer; paving a glass fiber tire flame-retardant layer before the isolation layer passes through a secondary thickness-fixing roller, performing secondary oiling and thickness fixing after the paving is finished, and coating a coating material of a flame-retardant modified asphalt layer on the glass fiber tire flame-retardant layer; and then covering the metal glass fiber grid composite flame-retardant layer on the upper surface of the coiled material, and then cooling, forming, rolling and packaging to obtain the flame-retardant self-adhesive asphalt waterproof coiled material.
CN201980029462.7A 2019-12-04 2019-12-04 Flame-retardant modified asphalt waterproof roll coating material, flame-retardant self-adhesive asphalt waterproof roll and preparation method thereof Pending CN112236303A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2019/123064 WO2021109035A1 (en) 2019-12-04 2019-12-04 Flame retardant modified asphalt waterproofing coiled material coating, flame retardant self-adhesive asphalt waterproofing coiled material and preparation method therefor

Publications (1)

Publication Number Publication Date
CN112236303A true CN112236303A (en) 2021-01-15

Family

ID=74111688

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980029462.7A Pending CN112236303A (en) 2019-12-04 2019-12-04 Flame-retardant modified asphalt waterproof roll coating material, flame-retardant self-adhesive asphalt waterproof roll and preparation method thereof

Country Status (2)

Country Link
CN (1) CN112236303A (en)
WO (1) WO2021109035A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113861866A (en) * 2021-09-03 2021-12-31 惠州东方雨虹建筑材料有限责任公司 Self-adhesion asphalt waterproof board
CN115538624A (en) * 2022-10-07 2022-12-30 北新防水(广东)有限公司 Low-temperature-resistant self-adhesive modified asphalt waterproof coiled material
CN117777948A (en) * 2023-12-05 2024-03-29 鞍山科顺建筑材料有限公司 Modified asphalt sizing composition and application thereof, sizing and preparation method thereof, waterproof coiled material and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113580694B (en) * 2021-08-10 2023-11-03 福建领航建设集团有限公司 Waterproof coiled material and preparation method thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4617227A (en) * 1985-03-12 1986-10-14 Uniroyal Chemical Company, Inc. Asphalt elastomeric blends
EP1544254A1 (en) * 2003-11-14 2005-06-22 Chem Link Inc. Moisture curable sealer and adhesive composition
CN101070434A (en) * 2007-06-21 2007-11-14 北京东方雨虹防水技术股份有限公司 High-polymer modified pitch, its water-proof roll material and use thereof
CN201512867U (en) * 2009-04-21 2010-06-23 胜利油田大明新型建筑防水材料有限责任公司 Anti-flaming type modified asphalt self-adhesive waterproof roll
CN101818549A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Flame-retardant self-adhesive coiled material
CN202689194U (en) * 2012-07-03 2013-01-23 潍坊市正泰防水材料有限公司 Inflaming retardant and composite self-adhesion waterproof roll
CN204036969U (en) * 2014-08-12 2014-12-24 王永秋 Flame retardant type waterproof roll
CN108148422A (en) * 2017-12-18 2018-06-12 吉林省豫王建能实业股份有限公司 A kind of flame retardant type stereo multi-colour decorative waterproof water coiled material and preparation method thereof
CN109749658A (en) * 2018-11-22 2019-05-14 惠州东方雨虹建筑材料有限责任公司 One kind is from viscous bitumen, heat insulation type without tyre water-proof coiled material and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102848632A (en) * 2012-08-13 2013-01-02 吴江市万事达防水建材有限公司 Thermoplastic polyurethane (TPU)-modified asphalt waterproof coiled material
CN105238084A (en) * 2015-09-24 2016-01-13 天长市金牛防水防腐材料有限公司 Heat-resistance and saline-alkaline-resistance type elastomer modified bitumen waterproof coil material
CN106626598A (en) * 2017-02-27 2017-05-10 北京中联天晟工程材料有限责任公司 Flame-retardant waterproof coiled material and preparation method thereof
CN107090248A (en) * 2017-04-17 2017-08-25 上海禹术防水工程技术有限公司 A kind of uncured rubber asphalt waterproof coating of flame retardant type and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4617227A (en) * 1985-03-12 1986-10-14 Uniroyal Chemical Company, Inc. Asphalt elastomeric blends
EP1544254A1 (en) * 2003-11-14 2005-06-22 Chem Link Inc. Moisture curable sealer and adhesive composition
CN101070434A (en) * 2007-06-21 2007-11-14 北京东方雨虹防水技术股份有限公司 High-polymer modified pitch, its water-proof roll material and use thereof
CN101818549A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Flame-retardant self-adhesive coiled material
CN201512867U (en) * 2009-04-21 2010-06-23 胜利油田大明新型建筑防水材料有限责任公司 Anti-flaming type modified asphalt self-adhesive waterproof roll
CN202689194U (en) * 2012-07-03 2013-01-23 潍坊市正泰防水材料有限公司 Inflaming retardant and composite self-adhesion waterproof roll
CN204036969U (en) * 2014-08-12 2014-12-24 王永秋 Flame retardant type waterproof roll
CN108148422A (en) * 2017-12-18 2018-06-12 吉林省豫王建能实业股份有限公司 A kind of flame retardant type stereo multi-colour decorative waterproof water coiled material and preparation method thereof
CN109749658A (en) * 2018-11-22 2019-05-14 惠州东方雨虹建筑材料有限责任公司 One kind is from viscous bitumen, heat insulation type without tyre water-proof coiled material and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113861866A (en) * 2021-09-03 2021-12-31 惠州东方雨虹建筑材料有限责任公司 Self-adhesion asphalt waterproof board
CN115538624A (en) * 2022-10-07 2022-12-30 北新防水(广东)有限公司 Low-temperature-resistant self-adhesive modified asphalt waterproof coiled material
CN115538624B (en) * 2022-10-07 2023-06-09 北新防水(广东)有限公司 Low-temperature-resistant self-adhesive modified asphalt waterproof coiled material
CN117777948A (en) * 2023-12-05 2024-03-29 鞍山科顺建筑材料有限公司 Modified asphalt sizing composition and application thereof, sizing and preparation method thereof, waterproof coiled material and preparation method thereof
CN117777948B (en) * 2023-12-05 2024-07-26 鞍山科顺建筑材料有限公司 Modified asphalt sizing composition and application thereof, sizing and preparation method thereof, waterproof coiled material and preparation method thereof

Also Published As

Publication number Publication date
WO2021109035A1 (en) 2021-06-10

Similar Documents

Publication Publication Date Title
CN112236303A (en) Flame-retardant modified asphalt waterproof roll coating material, flame-retardant self-adhesive asphalt waterproof roll and preparation method thereof
CN104358362B (en) A kind of heat-insulating flame-retardant bituminized shingle and preparation method thereof
CN110746930B (en) Self-adhesive modified asphalt waterproof coiled material coating material, preparation method thereof and passive self-adhesive asphalt waterproof coiled material special for building
WO2015096562A1 (en) Aqueous expandable nano fireproof coating for cables and preparation method therefor
CN105086895A (en) Hot melt adhesive for non-asphaltic base pre-laid polymeric waterproof rolls, and preparation method thereof
CN103173088B (en) Reflective insulating fire-retardant coating for waterproof roll, and preparation method and use thereof
CN107474793B (en) Self-adhesive waterproof roll cementing material, preparation method thereof and waterproof roll prepared from self-adhesive waterproof roll cementing material
CN112457806A (en) High-temperature-resistant hot-melt pressure-sensitive adhesive and preparation method and application thereof
CN104074337A (en) Aluminum-plastic composite floor and manufacturing method of aluminum-plastic composite floor
CN102086349A (en) Non-curing waterproof glue with double character
CN111253638A (en) Novel porous convex-concave structure fireproof flame-retardant plate elastic material and preparation method and application thereof
CN105176247A (en) Water-resistant fireproof coating
CN110863518A (en) Anti-aging asphalt-based pre-paved waterproof coiled material and preparation method thereof
CN103057193B (en) A-level fireproof aluminum composite board
CN104358373B (en) A kind of heat-insulating flame-retardant light wall tile and preparation method thereof
CN104761993B (en) Polyurethane anticorrosion insulating mold coating and preparation method thereof
CN106634590A (en) Fireproof paint
EP3160239A1 (en) Polyvinyl chloride-free decorative surface coverings
CN102153945A (en) Anti-flaming color polyurethane waterproof paint
CN106046763A (en) Polyurethane insulation and fireproof composite board
JP2014529517A (en) Waterproof coating system for reflecting solar radiation and aqueous coating for forming decorative and reflective layers in the coating system
CN110760289A (en) Flame-retardant self-adhesive waterproof roll cementing material, preparation method thereof and waterproof roll prepared from same
CN112080214A (en) Building composite film
CN115139624A (en) High-temperature-resistant asphalt waterproof coiled material and preparation method thereof
US11447672B2 (en) Tape with acrylic-free adhesive

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20210115

RJ01 Rejection of invention patent application after publication