CN112154194A - 长余辉发光材料 - Google Patents
长余辉发光材料 Download PDFInfo
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- CN112154194A CN112154194A CN201980033929.5A CN201980033929A CN112154194A CN 112154194 A CN112154194 A CN 112154194A CN 201980033929 A CN201980033929 A CN 201980033929A CN 112154194 A CN112154194 A CN 112154194A
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- 239000008213 purified water Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 150000003252 quinoxalines Chemical class 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- FSJWWSXPIWGYKC-UHFFFAOYSA-M silver;silver;sulfanide Chemical compound [SH-].[Ag].[Ag+] FSJWWSXPIWGYKC-UHFFFAOYSA-M 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- LOGJGBXRYQHJQT-UHFFFAOYSA-N tetracen-1-amine Chemical compound C1=CC=C2C=C(C=C3C(N)=CC=CC3=C3)C3=CC2=C1 LOGJGBXRYQHJQT-UHFFFAOYSA-N 0.000 description 1
- OLGBGEZLECIWCT-UHFFFAOYSA-N tetracene-1-carboxylic acid Chemical compound C1=CC=C2C=C(C=C3C(C(=O)O)=CC=CC3=C3)C3=CC2=C1 OLGBGEZLECIWCT-UHFFFAOYSA-N 0.000 description 1
- HGWXLRGMJQVSEY-UHFFFAOYSA-N tetracene-1-thiol Chemical compound C1=CC=C2C=C(C=C3C(S)=CC=CC3=C3)C3=CC2=C1 HGWXLRGMJQVSEY-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000004149 thio group Chemical group *S* 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 210000003437 trachea Anatomy 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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Abstract
一种长余辉发光材料，其包含A)至少一种吸光剂，B)至少一种发光剂，和C)至少一种光化学缓存剂；其中，该吸光剂与发光剂是结构不同的化合物，并且该缓存剂选自式(I)、(II)和/或(III)的一种或多种化合物。该材料的发光强度可以达到商业化无机长余辉粉体SrAl2O4:Eu2+,Dy3+的水平，并且在激发光关闭之后还能持续发光，发光时间可以达到100ms–3600s。
Ar‑CRa＝CRbRc(III)。
Description
PCT国内申请，说明书已公开。
Claims (19)
- PCT国内申请，权利要求书已公开。
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114686215A (zh) * | 2020-12-30 | 2022-07-01 | Tcl科技集团股份有限公司 | 荧光材料及其制备方法和应用 |
| CN114686208A (zh) * | 2020-12-31 | 2022-07-01 | Tcl科技集团股份有限公司 | 一种复合试剂、防伪组合试剂及防伪方法 |
| CN115232073A (zh) * | 2022-09-21 | 2022-10-25 | 南京邮电大学 | 基于1H-萘[2,3-d]咪唑的光响应性有机长余辉材料的制备及其应用 |
| CN116099573A (zh) * | 2023-01-09 | 2023-05-12 | 长沙理工大学 | 一种储存光能的金属有机框架复合催化剂及其制备方法和应用 |
| CN116199899A (zh) * | 2023-03-03 | 2023-06-02 | 深圳职业技术学院 | 一类基于吡唑类有机配体的近红外、纳米金属有机框架材料及其制备方法 |
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| CN112457336B (zh) * | 2020-11-19 | 2021-08-06 | 复旦大学 | 基于bodipy的光扳机分子及应用 |
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| CN114591727B (zh) * | 2020-12-04 | 2024-06-28 | 中国科学院上海有机化学研究所 | 一种有机长余辉发光材料、制备及应用 |
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| CN115947714B (zh) * | 2022-11-01 | 2024-05-14 | 上海泰辉生物科技有限公司 | 光化学缓存剂的合成方法 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114686215A (zh) * | 2020-12-30 | 2022-07-01 | Tcl科技集团股份有限公司 | 荧光材料及其制备方法和应用 |
| CN114686208A (zh) * | 2020-12-31 | 2022-07-01 | Tcl科技集团股份有限公司 | 一种复合试剂、防伪组合试剂及防伪方法 |
| CN115232073A (zh) * | 2022-09-21 | 2022-10-25 | 南京邮电大学 | 基于1H-萘[2,3-d]咪唑的光响应性有机长余辉材料的制备及其应用 |
| CN115232073B (zh) * | 2022-09-21 | 2022-11-22 | 南京邮电大学 | 基于1H-萘[2,3-d]咪唑的光响应性有机长余辉材料的制备及其应用 |
| CN116099573A (zh) * | 2023-01-09 | 2023-05-12 | 长沙理工大学 | 一种储存光能的金属有机框架复合催化剂及其制备方法和应用 |
| CN116199899A (zh) * | 2023-03-03 | 2023-06-02 | 深圳职业技术学院 | 一类基于吡唑类有机配体的近红外、纳米金属有机框架材料及其制备方法 |
| CN116199899B (zh) * | 2023-03-03 | 2023-09-19 | 深圳职业技术学院 | 一类基于吡唑类有机配体的近红外、纳米金属有机框架材料及其制备方法 |
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