CN112028476A - Preparation method of lead-free barium-free environment-friendly crystal glass - Google Patents

Preparation method of lead-free barium-free environment-friendly crystal glass Download PDF

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Publication number
CN112028476A
CN112028476A CN202010956445.2A CN202010956445A CN112028476A CN 112028476 A CN112028476 A CN 112028476A CN 202010956445 A CN202010956445 A CN 202010956445A CN 112028476 A CN112028476 A CN 112028476A
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China
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cavity
block
grinding
rotating
rotating shaft
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CN202010956445.2A
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CN112028476B (en
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张宝清
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Zhejiang Huayi Industry And Trade Co ltd
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Pujiang Xinyan Crystal Crafts Co ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/095Glass compositions containing silica with 40% to 90% silica, by weight containing rare earths
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B1/00Preparing the batches
    • C03B1/02Compacting the glass batches, e.g. pelletising
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

Abstract

The invention discloses a preparation method of lead-free barium-free environment-friendly crystal glass, relating to the technical field of glass processing; the glass comprises the following components in percentage by weight: SiO 242.3-48.3%, K2O 5.4.4-6.0%, Na2O 3.0.0-3.6%, B2O33.0-4.3%, CaO 0-1.2%, Li2O0.5-1.2%, TiO22.0-6.0%, ZrO21.0-5.0%, SrO 8-18%, La2O 36-16%, Y2O 30-20%, Sb2O30.5-1.0%; the integrated type structure directly puts ground powder into the melting structure, avoids the powder from floating in the air, ensures the working environment, avoids the powder from floating in the air and being sucked by workers to cause body damage, thereby protecting the body health of the workers.

Description

Preparation method of lead-free barium-free environment-friendly crystal glass
Technical Field
The invention belongs to the technical field of glass processing, and particularly relates to a preparation method of lead-free and barium-free environment-friendly crystal glass.
Background
Lead oxide (PbO) and barium oxide (BaO) are common components in traditional crystals, and can improve the refractive index and the dispersion rate of glass. In the existing glass formula, the content of PbO and BaO in the glass component is increased in order to improve the refractive index and the dispersion ratio. When the lead crystal glass product is used, lead dissolved out in the process of using the product as a water utensil, a wine utensil and a tableware is very toxic and harmful to human health. The barium oxide introduced into the barium crystal which is widely developed at present also belongs to the high-toxicity oxides. The Europe and developed countries have limits on harmful elements such As Pb, Ba, As, Be, Cd, Hg, Sb, Se and Cr, and the development of a formula of lead-free barium-free environment-friendly crystal glass is imperative. Similar research reports exist in China, but the refractive index of the high-lead crystal is difficult to achieve under the condition of not adding lead and barium.
In the processing process of the crystal glass, large individual bodies in the raw materials of the glass need to be crushed and ground, the particles of the raw materials are smaller, the melting speed is higher in the subsequent melting step process, the melting effect is better, if the ground particles are too small, the particles are easy to scatter in the air and are easy to be inhaled into the lung by workers frequently when being collected, so that the lung is greatly damaged, meanwhile, strip-shaped or sheet-shaped blocks cannot smoothly pass through a conventional grinding machine and cannot enter a grinding area due to different sizes and shapes of the individual bodies of the raw materials, so that the materials cannot be processed in time, the waste of the materials is caused, or the raw material ratio is different to a certain degree due to the fact that part of large materials cannot be ground, so that the quality of a final product is poor, furthermore, generally, the equipment in the aspect has a larger individual structure and a larger occupied area, so that the walking range of workers is greatly reduced, and the workers are easily injured.
Disclosure of Invention
The invention provides a preparation method of lead-free barium-free environment-friendly crystal glass, which is used for overcoming the defects of the prior art and protecting the environment and saving the occupied area.
In order to achieve the purpose, the invention adopts the following technical scheme: a preparation method of lead-free and barium-free environment-friendly crystal glass is characterized by comprising the following steps: the glass comprises the following components in percentage by weight: 242.3 to 48.3% of SiOx, 5.4 to 6.0% of K2O 5.4, 3.0 to 3.6% of Na2O 3.0, 26 to 4.3% of B2O33.0, 0 to 1.2% of CaO, 0.5 to 1.2% of Li2O0, 22.0 to 6.0% of TiO22, 21.0 to 5.0% of ZrO21, 8 to 18% of SrO, 25 to 16% of La2O 36, 25 to 20% of Y2O 30, and 30.5 to 1.0% of Sb2O30. The process comprises the following steps: (1) batching: calculating the mass of the corresponding raw materials according to the mass percentage of each component, and weighing each raw material; and (2) drying raw materials: the moisture content in each raw material is reduced by utilizing natural drying and electric drying; (3) mixing and stirring: grinding the dried raw materials by using a glass manufacturing all-in-one machine with grinding and melting functions, and melting the mixture for 2-3h at the temperature of 1500-; (4) clarifying at 1500 ℃ for 0.5-1 h; (5) shaping the crystal glass by manual or mechanical mode; and (6) annealing the crystal glass after the shaping is finished to obtain the lead-free barium-free environment-friendly crystal glass. The raw material powder grinding machine in the step 3 comprises a shell arranged on the ground, a cover shell arranged on the shell, a crushing structure arranged in the shell, a motor used for driving the crushing structure, a feeding hole arranged on the cover shell and a discharging hole arranged on one side of the shell; the crushing structure comprises a first cavity arranged in the shell, a rotating shaft fixedly connected to the motor, a crushing knife arranged on the rotating shaft, a feed opening arranged at the bottom of the first cavity, a stirring structure sleeved on the rotating shaft, a grinding structure arranged at the bottom of the first cavity and a melting structure arranged below the grinding structure; the material is put into the first cavity from the feeding hole, the crushing cutter arranged on the rotating shaft rotates along with the rotating shaft driven by the motor, so that the material is pre-crushed, meanwhile, the material in the first cavity is continuously stirred through the arrangement of the stirring structure, the material at the lower part is continuously moved upwards and rolled, the material pretreated by the crushing cutter falls into the grinding structure from the feeding hole, so that more fine powder is obtained, and then the powder can directly enter the melting structure through the feeding hole to be melted; through the integrated design, the occupied area is smaller, the occupied space is saved, the method is more suitable for manufacturing small-batch high-quality artware, the activity space of workers is ensured, the safety of the workers in working is improved, through the arrangement of the crushing cutter, when the materials enter the first cavity, the crushing cutter preferentially pre-crushes the materials, so that the strip-shaped or sheet-shaped blocks are processed into blocks which are easier to perform the subsequent grinding stage, the problem that the blocks cannot enter the grinding structure due to the shape difference is avoided, the utilization rate of the materials is increased, the condition that the quality of final products is poor due to the fact that part of the individual large and singular materials cannot enter the grinding structure is effectively avoided, and the condition that the quality of the final products is poor is caused due to the fact that the components in the final molten products are lost, so that the quality of the artware is ensured; meanwhile, the powder after grinding is directly put into the melting structure through the integrated structure, so that the powder is prevented from floating in the air, the working environment is ensured, the powder is prevented from floating in the air and being sucked by workers, the damage to the bodies is avoided, and the health of the workers is protected.
The stirring structure comprises a first convex tooth arranged on the radial periphery of the rotating shaft, a rotating ring sleeved on the rotating shaft, a sliding groove used for fixing the rotating ring and rotatably connected to the cover shell, a second cavity arranged in the rotating ring, a second convex tooth arranged on the side wall of the second cavity, a first gear arranged in the second cavity and used for linking the first convex tooth and the second convex tooth, a stirring rod fixedly connected to the rotating ring, a first material guide inclined plane arranged on the stirring rod, a third cavity arranged in the rotating shaft, a spiral block arranged in the third cavity, an air vent arranged on the rotating shaft, an air cavity arranged below the rotating ring, an air ejector pipe arranged below the air cavity, an air storage cavity arranged in the shell, an air inlet arranged on the side wall of the heating air cavity and a drying agent arranged in the air storage cavity; the rotating shaft driven by the motor drives the first convex teeth to rotate in the rotating process, and the first convex teeth and the second convex teeth are linked through the first gear, so that the rotating shaft drives the rotating ring to rotate; the rotation of the rotating shaft drives the first convex teeth to rotate around the shaft core of the rotating shaft, the first convex teeth and the second convex teeth are linked through the matching of the first gear, so that the rotation of the first convex teeth drives the rotating ring provided with the second convex teeth to rotate, the stirring rod arranged outside the rotating ring rotates around the shaft core of the rotating shaft along with the rotating ring, the rod body of the stirring rod is attached to the side wall of the first cavity body, the stirring rod can be inclined, so that the material retained at the bottom is upwards driven along the side wall along with the stirring rod in the stirring process, the material at the bottom is turned to the upper layer, meanwhile, the stirring shaft is provided with a first material guide inclined plane, when the stirring rod plays a role of rolling, the rolled material is gathered to the middle, in the rotating process of the rotating shaft, the spiral block arranged in the rotating shaft rotates along with the rotating shaft, the rotation of the spiral block plays a role of conveying air, the air in the air storage cavity is conveyed upwards, so that the air enters the air cavity along a third cavity in the rotating shaft, is finally sprayed out of the air injection pipe and is blown onto the materials, and the drying degree of the materials is increased; through the arrangement of the first convex teeth and the second convex teeth, the high-speed rotating shaft is transmitted to the stirring rod in a mode of higher force at lower speed, so that the stirring rod can rotate at a stable middle speed, the stirring rod is arranged in a spiral form, so that the material is shoveled to continuously move upwards in the rotating process, the material in a stacking state below is turned to the upper layer, the material can be better grabbed by the grinding structure below, the position of the material can be continuously adjusted in the turning process, the material can be better crushed, the material is decomposed into small individual block-shaped structures, the utilization rate of the material is ensured, the proportioning of a formula is ensured, the quality of a final product is improved, and meanwhile, the air heated by the melting structure below in the conveying gas storage cavity is moved upwards due to the conveying effect of the spiral block in the third cavity, because the air storage cavity is internally provided with the drying agent, the air entering the air storage cavity is ensured to be in a dry state, then, dry hot air is sprayed to the internal materials through the air spraying pipe, the materials are dried, the moisture content in the materials is reduced, the drying degree of the materials is ensured, the condition that the melting speed of the materials is slow due to the fact that the moisture can be reduced in the drying process of the materials is ensured, the hardened condition is reduced, the quality of the final glass artware is effectively guaranteed, and the clarity of the glass artware is ensured.
The grinding structure comprises a fourth cavity arranged below the first cavity, a rotating block sleeved on the rotating shaft, a grinding channel formed by a gap between the fourth cavity and the rotating block, a discharging cavity arranged below the grinding channel, a material guide ring arranged in the discharging cavity, a dustproof groove arranged at the joint of the rotating block and the rotating shaft, third convex teeth arranged on the radial periphery of the bottom of the rotating shaft, a fifth cavity arranged in the rotating block, fourth convex teeth arranged on the side wall of the fifth cavity, and a second gear arranged in the fifth cavity and used for matching the third convex teeth and the fourth convex teeth; the third convex tooth and the fourth convex tooth are matched through the second gear, so that linkage is performed, namely when the motor drives the rotating shaft to rotate, the third convex tooth arranged on the rotating shaft rotates around the shaft core of the rotating shaft, the fourth convex tooth arranged in the fifth cavity in the rotating block is driven by the third convex tooth, so that the rotating block is driven to rotate around the rotating shaft, a dustproof groove is formed between the rotating block and the rotating shaft and used for preventing dust from entering, the material falls into the grinding channel from the discharging port, and the particles of the material are gradually reduced in the grinding process along with the continuous movement of the material along the grinding channel and finally fall into the discharging cavity, and finally are gathered to one side of the discharging cavity along with the inclination of the guide ring and finally discharged; through the arrangement of the third convex tooth and the fourth convex tooth, the transmission is completed through the second gear, so that the speed of transmitting the high-speed rotation of the rotating shaft to the rotating block is reduced, the rotating speed of the rotating block is relatively slow, but larger force is obtained, the material is conveniently crushed, meanwhile, the burden of the rotating shaft is reduced, the abrasion of the rotating shaft is reduced, the service life is prolonged, the arrangement of the dustproof groove effectively avoids dust from entering a gap between the rotating shaft and the rotating block, the blocking condition is avoided, the possibility of abrasion of instruments is reduced, the material guide ring is an annular block which is obliquely arranged, the material is gathered at a discharge port, the possibility of reduction of utilization rate due to accumulation of the material is avoided, the material is finely ground through the arrangement of the structure, the material is effectively reduced, the material is reduced, the drying is effectively facilitated, and the subsequent melting process is effectively facilitated, the possibility of particle blocks in the molten liquid is reduced, and the clarity of the molten liquid is effectively improved, so that the quality of a final product is ensured.
The drying in the step 2 is natural drying and electric drying, so that the moisture of the raw materials is reduced to be below 5 percent.
The annealing in the step 6 comprises the following steps: the temperature is kept in a muffle furnace at 580 ℃ for 5h, and then the temperature is cooled along with the muffle furnace.
The grinding channel comprises first grinding teeth, second grinding teeth, a first buffering section, a grinding chute, a second buffering section, a discharging chute, a second material guide inclined plane and an iron removing structure, the first grinding teeth are arranged around the inner wall of the fourth cavity in a radial direction for one circle, the second grinding teeth are arranged below the first grinding teeth, the first buffering section is arranged between the first grinding teeth and the second grinding teeth, the grinding chute is arranged below the second grinding teeth, the second buffering section is arranged between the second grinding teeth and the grinding chute, the discharging chute is arranged at the tail end of the grinding chute, the second material guide inclined plane is arranged on the rotating block, and the iron; the material enters the grinding channel from the feed opening at the bottom of the first cavity, and along with the rotation of the rotating shaft, the rotating block is driven to rotate, the rotation of the rotating block enables the large material falling into the grinding channel to be ground by the first grinding teeth, the large material continuously moves downwards in the grinding process and is crushed in the process of moving downwards along the grinding channel, so that the large material is decomposed into smaller individuals, then the crushed material to a certain degree moves centrifugally in the rotating process along the first gentle section, and then moves to the tail end, the crushed material enters a working area of the second grinding teeth along the second guide slope, and is ground to be finer sand particles under the grinding of the second grinding teeth, then the crushed material centrifugally moves along the second gentle section and enters the grinding chute which is an inclined channel from coarse to fine, and at the moment, the sand particles are further ground in the structure, the grinding action is continuously exerted in the rotating process, meanwhile, the material is provided with the trend of centrifugal motion, and the material ground to the final thickness falls along the blanking chute; the massive objects are separated from each other through the first grinding teeth, the grinding section provided with the first grinding teeth can crush large individuals of the massive objects, the crushed individuals can move along the first gentle sections under centrifugal motion, the gentle sections are arranged to provide certain accommodating space, so that the individuals subjected to primary grinding can temporarily exist in the first gentle sections, meanwhile, the first gentle sections are also a screening process, the individuals still large cannot move outwards in the rotating process, the individuals are continuously ground under the action of the first grinding teeth, the second grinding teeth are similar to the first grinding teeth, but the second grinding teeth are of a more sharp structure relative to the first grinding teeth, namely, the first grinding teeth pay more attention to crushing, the second grinding teeth pay more attention to grinding, the grinding chute at the final stage is used for finally grinding the materials, and the structure is arranged to effectively ensure that the materials are sufficiently ground and crushed, thereby ensuring the powder thickness of the final grinding finished product and ensuring the quality of the final product of the glass.
The iron removing structure comprises a fifth cavity arranged on the side wall of the fourth cavity, an electromagnet arranged in the fifth cavity, a power supply fixedly connected to the side wall of the shell, an oblique opening arranged at the bottom of the fifth cavity, a first rotating part arranged on one side of the oblique opening, a door body arranged on the first rotating part, a second elastic part arranged in the oblique opening and used for resetting the door body, a discharge opening arranged on the side wall of the shell, a first metal block arranged on the door body and a power-off structure arranged on the electromagnet; in the grinding process, a power supply is communicated with an electromagnet, the electrified electromagnet is attached with magnetism to a certain degree, then an iron block in an adsorbed material enters a fifth cavity, the iron block is attracted to push a door body, meanwhile, a first metal block on the door body is attracted by the electromagnet, so that the door body rotates around a first rotating piece, the electromagnet plays a role in assisting the opening of the door body, when the iron block enters the fifth cavity, the power supply is disconnected through a power-off structure, the door body closes the door body under the action of the elastic force of a second elastic piece to complete the closing, the electromagnet after the power-off cannot attract the iron block due to the loss of the magnetic force, the iron block falls under the action of gravity, falls on the bottom of the fifth cavity with the closed door body, then slides downwards along the fifth cavity, and finally is discharged from a material discharge port; the opening that the bevel was opened for the slope, inclination is opposite with the direction of rotation, thereby avoided the material to carry out accumulational possibility in the bevel, the mode through the electro-magnet will contain the raw materials of taking iron and clear away, thereby guaranteed that final glass product can be limpid and transparent, avoid the glass that the iron ion leads to turn yellow the possibility, simultaneously through the setting of outage structure, with the adsorption interruption intercommunication or the disconnection of electro-magnet, thereby effectively thereby avoided too much iron ore to pile up on the electro-magnet, lead to final electro-magnet to get the adsorption efficiency decline, lead to can't produce the deironing effect to subsequent material, guaranteed the clearance effect to iron in the raw materials, in time the mode of switching on and off will effectively help the discharge of iron plate, thereby guaranteed final glass product's clarity.
The power-off structure comprises a sixth cavity arranged above the fifth cavity, a first magnetic block arranged on the rotating block, a second magnetic block capable of moving back and forth in the sixth cavity, a seventh cavity arranged above the sixth cavity, a power-on block embedded in the seventh cavity, a first power line used for connecting the power-on block and a power supply, a second power line used for connecting the electromagnet and the power supply, and a fixing structure used for fixing the second magnetic block; when the rotating block rotates under the driving of the rotating shaft, the first magnetic block arranged on the rotating block does circular motion around the shaft core of the rotating shaft, the first magnetic block doing circular motion continuously performs corresponding attraction or repulsion action on the second magnetic block in an anode-cathode alternating mode in the rotating process, so that the second magnetic block is controlled to move back and forth in the sixth cavity, when the second magnetic block is positioned at the near shaft end in the sixth cavity, the connection between the electromagnet and the electrified block is disconnected, the electromagnet is not communicated with a power supply at the moment, the electromagnet is nonmagnetic, the iron block adsorbed on the electromagnet falls down due to gravity, when the rotating block rotates for a certain angle, the other end of the first magnetic block is close to the second magnetic block, the second magnetic block slides along the sixth cavity, so that the second magnetic block slides to the far shaft end of the sixth cavity, and the second magnetic block plays a role in communicating the electrified block and the electromagnet at the moment, the electromagnet has magnetism; through the rotation of commentaries on classics piece to constantly switch over first magnetic path and be close to in the polarity of second magnetic path, thereby realized the removal of second magnetic path, thereby with the removal of second magnetic path the carrier of switching on and off, effectively realized the form of discontinuous switching on and off electricity, this in-process need not to use all the other energy, and the energy saving is favorable to sustainable development more, has guaranteed the work efficiency and the work effect of electro-magnet simultaneously, has effectively guaranteed the quality of end product.
The fixing structure comprises an eighth cavity arranged above the sixth cavity, a fixing block capable of moving back and forth in the eighth cavity, fixing chutes arranged on two sides of the fixing block, a first elastic piece arranged in the eighth cavity and used for resetting the fixing block, a ninth cavity arranged on one side of the eighth cavity, a second metal block arranged in the ninth cavity, and a rope body used for connecting the second metal block and the fixing block; the fixing block has the function of blocking the second magnetic block from moving under the action of the first elastic part and has the function of fixing, when the two ends with the highest magnetism of the first magnetic block are close to the second metal block, the second metal block faces the near-axis core end of the eighth cavity under the action of the magnetism, the fixing block connected with the second metal block through the rope moves upwards due to the movement of the second metal block, the fixing of the second magnetic block is released due to the upward movement of the fixing block, then the second magnetic block moves to the other end corresponding to the second magnetic block under the action of the first magnetic block, and then the fixing block moves downwards due to the separation of the first magnetic block and is extruded to the most corner of the sixth cavity through the fixing inclined groove formed in the fixing block; through the attraction of first magnetic path to the second metal block, thereby control the removal of fixed block, thereby the effect of fixed second magnetic path has been played, thereby the circular telegram effect of electromagnetic block has effectively been guaranteed, simultaneously through the setting of fixed chute, when the second magnetic path fails to remove extreme position, the fixed block will extrude downwards under the effect of first elastic component, thereby promote the second magnetic path and reach the assigned position, thereby the effect of second magnetic path as circular telegram structure has been guaranteed, the stability of apparatus has been increased, the deironing effect has effectively been guaranteed, thereby final product quality has been guaranteed.
The melting structure comprises a drawer capable of moving back and forth at the bottom of the shell, a heating block arranged at the bottom of the drawer, a groove arranged on the inner wall of the drawer, a quartz crucible arranged in the drawer, ear-shaped blocks arranged on two sides of the quartz crucible, a material gathering cavity arranged above the drawer, a communicating pipeline for communicating a feed opening with the material gathering cavity, a chute arranged on the side wall of the communicating pipeline, a plugging sheet capable of moving back and forth in the chute for sealing the communicating pipeline, a first inclined surface arranged on the plugging sheet, a tenth cavity arranged on the side wall of the chute, a first clamping port arranged on the drawer, a sliding block capable of moving back and forth in the tenth cavity, a first clamping block arranged at two ends of the sliding block and corresponding to the clamping port, a second inclined surface arranged on the sliding block and used for matching with the first inclined surface to push the sliding block to move, an eleventh cavity arranged on the side wall of the chute, a second clamping block arranged, The second clamping interface is arranged on the plugging sheet, the push block is arranged at the other end of the eleventh cavity, the third elastic piece is arranged in the eleventh cavity and used for resetting the push block, and the protruding block is arranged on the drawer and used for pushing the push block; the material will enter and gather the material intracavity along the communicating pipe, slide down along gathering the material intracavity afterwards, get into quartz crucible, along with the continuous intensification of heating block, quartz crucible heats up constantly, thus make the inside material melt, when needing to take out the molten material outwards, promote the shutoff piece to move inwards, the shutoff piece of inward movement will pass through the cooperation between second inclined plane and the first inclined plane, thus promote the slider to move upwards, the slider that moves upwards drives the joint piece to move upwards simultaneously, the joint piece shifts out from the joint mouth, thus the drawer can be taken out, when the drawer is taken out, the ejector pad loses the extrusion of the protruding piece on the drawer, thus outwards ejecting under the effect of third elastic component, the ejector pad will extrude the airtight part in the eleventh cavity at this moment, thus the second joint piece outwards stretches out the joint and forms the fixing to the shutoff piece in second joint mouth, only when the drawer is reset, the second clamping block retracts into the eleventh cavity, and the plugging piece is not limited any more and can be pulled out; when the drawer need be taken out, it is terminal to need to go into the spout with the shutoff piece card, unblock is fixed to the drawer in the time of sealing the intercommunication pipeline, and taking out of drawer will carry out spacing fixed to the shutoff piece simultaneously, thereby this in-process has avoided the material residue whereabouts of top to fall into the below to lead to piling up because the shutoff effect of shutoff piece, melt again under the high temperature effect and become the block that possesses certain viscidity, lead to the drawer can't open, lead to the fact the condition of damage to the apparatus, the setting of this structure, when having guaranteed that the drawer is not in the casing, the shutoff piece is in the encapsulated situation all the time, on the one hand can make both part work from top to bottom can not interfere with each other, on the other hand has avoided the loss of material, save material cost, avoid piling up of.
Lead and barium in the glass material are zero in addition, so that the glass material is environment-friendly and meets the environment-friendly requirement; the prepared glass has the characteristics of similar refractive index (nD is more than or equal to 1.56) of high-lead crystal, dispersion coefficient (vd is more than or equal to 60), density (d is more than or equal to 2.94g/cm3), transmittance (t is more than or equal to 88%) and good chemical stability.
Wherein in the course of working to crystal glass, design through the integral type, area is littleer, occupation of land space has been practiced thrift, more be fit for the preparation of the high-quality handicraft of small batch, the powder after the integral type structure will be ground simultaneously directly drops into the melting structure in, the powder has been avoided drifting away in the air, thereby operational environment has been guaranteed, avoid the powder to drift away and inhaled by the workman in the air, lead to the damage of health, thereby workman's healthy has been protected, set up through broken sword afterwards, will take precedence to carry out the pre-crushing to the raw materials, avoid in rectangular shape can't get into the grinding structure, the utilization ratio of material has been increased.
Drawings
FIG. 1 is a schematic structural diagram of the present invention.
Fig. 2 is a right side view of the present invention.
Fig. 3 is a schematic perspective cross-sectional view taken along line a-a of fig. 2.
Fig. 4 is an enlarged schematic view of a portion a of fig. 3.
Fig. 5 is an enlarged schematic view of fig. 3 at B.
Fig. 6 is a partially enlarged schematic view of fig. 5.
Fig. 7 is an enlarged schematic view at C in fig. 3.
Fig. 8 is a perspective cross-sectional view of fig. 2 taken along line B-B.
Fig. 9 is a perspective cross-sectional view of fig. 2 taken along line C-C.
Fig. 10 is a front view of the present invention.
Fig. 11 is a perspective cross-sectional view of fig. 10 taken along line D-D.
Fig. 12 is an enlarged schematic view at D in fig. 11.
Fig. 13 is a perspective cross-sectional view of fig. 10 taken along line E-E.
Fig. 14 is an enlarged schematic view at E in fig. 13.
Detailed Description
As shown in FIGS. 1 to 14, a method for preparing lead-free and barium-free environment-friendly crystal glass is characterized in that: the glass comprises the following components in percentage by weight: 242.3 to 48.3% of SiOx, 5.4 to 6.0% of K2O 5.4, 3.0 to 3.6% of Na2O 3.0, 26 to 4.3% of B2O33.0, 0 to 1.2% of CaO, 0.5 to 1.2% of Li2O0, 22.0 to 6.0% of TiO22, 21.0 to 5.0% of ZrO21, 8 to 18% of SrO, 25 to 16% of La2O 36, 25 to 20% of Y2O 30, and 30.5 to 1.0% of Sb2O30. The process comprises the following steps: (1) batching: calculating the mass of the corresponding raw materials according to the mass percentage of each component, and weighing each raw material; and (2) drying raw materials: the water content in the raw materials is reduced by utilizing natural drying and electric drying, and the water content of the raw materials is reduced to be below 5 percent by utilizing the natural drying and the electric drying. (ii) a (3) mixing and stirring: grinding the dried raw materials by using a glass manufacturing all-in-one machine with grinding and melting functions, and melting the mixture for 2-3h at the temperature of 1500-; (4) clarifying at 1500 ℃ for 0.5-1 h; (5) shaping the crystal glass by manual or mechanical mode; and (6) annealing the crystal glass after the shaping is finished, preserving the heat in a muffle furnace at 580 ℃ for 5 hours, and then cooling the crystal glass along with the muffle furnace to obtain the lead-free barium-free environment-friendly crystal glass. The raw material powder grinding machine in the step 3 comprises a shell 1, a cover shell 2, a crushing structure 3, a motor 4, a feeding hole 21 and a discharging hole 22; the shell 1 is arranged on the ground, the cover shell 2 is arranged on the shell, the crushing structure 3 is arranged in the shell, the motor 4 is used for driving the crushing structure, the motor is the prior art directly purchased from the market, and the description is omitted here, the feed inlet 21 is arranged on the cover shell, the feed inlet is arranged on the cover shell, and the discharge outlet 22 is arranged on one side of the shell; the crushing structure 3 comprises a first cavity 31, a rotating shaft 32, a crushing knife 33, a feed opening 34, a stirring structure 5, a grinding structure 6 and a melting structure 10; the first cavity 31 is arranged in the shell, the rotating shaft 32 is fixedly connected to the motor, the crushing knife 33 is arranged on the rotating shaft, the crushing knife is of a conventional structure, the description is omitted, the feed opening 34 is arranged at the bottom of the first cavity, the stirring structure 5 is sleeved on the rotating shaft, the grinding structure 6 is arranged at the bottom of the first cavity, the melting structure 10 is arranged below the grinding structure, the material is put into the first cavity from the feed opening, the crushing knife arranged on the rotating shaft rotates along with the rotating shaft driven by the motor, so that the material is pre-crushed, meanwhile, the material in the inner part is continuously turned through the arrangement of the stirring structure, the material at the lower part is continuously moved upwards and rolled, the material pre-treated by the crushing knife falls into the grinding structure from the feed opening, so that more fine powder is obtained, and then the powder can directly enter into the melting structure through the feed opening, melting is carried out.
As shown in fig. 3-4 and 8, the stirring structure 5 includes a first protruding tooth 51, a rotating ring 52, a sliding groove 53, a second cavity 54, a second protruding tooth 55, a first gear 56, a stirring rod 57, a first material guiding inclined plane 58, a third cavity 59, a spiral block 510, a vent 511, an air cavity 512, an air injection pipe 513, an air storage cavity 514, an air inlet 515, and a drying agent 516; the first convex tooth 51 is arranged on the radial periphery of the rotating shaft, the rotating ring 52 is sleeved on the rotating shaft, the rotating ring is a ring-mounted block body, the sliding groove 53 is used for fixing the rotating ring to be rotatably connected on the cover shell, the second cavity 54 is arranged in the rotating ring, the second convex tooth 55 is arranged on the side wall of the second cavity, the first gear 56 is arranged in the second cavity and is used for linking the first convex tooth with the second convex tooth, the stirring rod 57 is fixedly connected on the rotating ring, the stirring rod is a rod body fixedly connected on the rotating ring and attached to the bottom surface of the first cavity, preferably, the stirring rod can be spiral, the first guide inclined plane 58 is arranged on the stirring rod so as to play a role of gathering materials towards the middle, the third cavity 59 is arranged in the rotating shaft, the spiral block 510 is arranged in the third cavity, the spiral block is a structure similar to a spiral feeder and arranged in the third cavity, the vent hole 511 is arranged on the rotating shaft, and the air cavity 512 is, the gas injection pipe 513 is arranged below the gas cavity, the gas storage cavity 514 is arranged in the shell, the gas inlet 515 is arranged on the side wall of the heating gas cavity, and the drying agent 516 is arranged in the gas storage cavity and is selected more, such as calcium oxide and the like; the rotating shaft driven by the motor drives the first convex teeth to rotate in the rotating process, and the first convex teeth and the second convex teeth are linked through the first gear, so that the rotating shaft drives the rotating ring to rotate; the rotation of the rotating shaft drives the first convex teeth to rotate around the shaft core of the rotating shaft, the first convex teeth and the second convex teeth are linked through the matching of the first gear, so the rotation of the first convex teeth drives the rotating ring provided with the second convex teeth to rotate, the stirring rod arranged outside the rotating ring rotates around the shaft core of the rotating shaft along with the rotating ring, the rod body of the stirring rod is attached to the side wall of the first cavity body, and the stirring rod is spirally arranged, so the material retained at the bottom is upwards driven along the side wall along with the stirring rod in the stirring process, the material at the bottom is turned to the upper layer, meanwhile, the first material guide inclined plane is arranged on the stirring shaft, when the stirring rod plays a role of rolling, the material rolled up is gathered to the middle, in the rotating process of the rotating shaft, the spiral block arranged in the rotating shaft rotates along with the rotating shaft, and the rotation of the spiral block plays a role of conveying air, the air in the air storage cavity is conveyed upwards, so that the air enters the air cavity along the third cavity in the rotating shaft, is finally sprayed out of the air injection pipe and is blown onto the materials, and the drying degree of the materials is increased.
As shown in fig. 3-5 and 9, the grinding structure 6 includes a fourth cavity 61, a rotating block 62, a grinding channel 63, a discharging cavity 64, a material guiding ring 65, a dust-proof groove 66, a third convex tooth 67, a fifth cavity 68, a fourth convex tooth 69 and a second gear 610; the fourth cavity 61 is arranged below the first cavity, the rotating block 62 is sleeved on the rotating shaft and is in a step structure, the grinding channel 63 is formed by a gap between the fourth cavity and the rotating block, the discharging cavity 64 is arranged below the grinding channel, the material guide ring 65 is arranged in the discharging cavity, the dustproof groove 66 is arranged at the joint of the rotating block and the rotating shaft, the third convex tooth 67 is arranged on the radial periphery of the bottom of the rotating shaft, the fifth cavity 68 is arranged in the rotating block, the fourth convex tooth 69 is arranged on the side wall of the fifth cavity, and the second gear 610 is arranged in the fifth cavity and is used for matching the third convex tooth and the fourth convex tooth; third dogtooth cooperates through the second gear with the fourth dogtooth, thereby link, when the motor drives the pivot and rotates promptly, establish and will rotate round pivot axle core at the epaxial third dogtooth of commentaries on classics, the fourth dogtooth that sets up in the fifth cavity in the commentaries on classics piece will receive the drive of third dogtooth, thereby it rotates round the pivot to drive the commentaries on classics piece, be provided with dustproof recess between commentaries on classics piece and the pivot, be used for preventing the entering of dust, the material will fall into in the grinding passageway from the feed opening, along with the material along the continuous removal of grinding passageway, the material will reduce gradually at the in-process granule of grinding, finally fall into the ejection of compact intracavity, finally along with the slope of guide ring, to ejection of compact chamber one side gathering, final discharge.
As shown in fig. 3 and 5, the grinding channel 63 includes a first grinding tooth 631, a second grinding tooth 632, a first smoothing section 633, a grinding chute 634, a second smoothing section 635, a feeding chute 636, a second material guiding inclined plane 637, and an iron removing structure 7; the first grinding teeth 631 are wound on the inner wall of the fourth cavity in a radial circle, the grinding teeth are square teeth and used for crushing large blocks, the second grinding teeth 632 are arranged below the first grinding teeth, the second grinding teeth are arranged in a tooth shape and used for crushing small blocks, the first buffering section 633 is arranged between the first grinding teeth and the second grinding teeth, the grinding chute 634 is arranged below the second grinding teeth, the grinding chute is thick to thin in one section, the second buffering section 635 is arranged between the second grinding teeth and the grinding chute, the blanking chute 636 is arranged at the tail end of the grinding chute, the second guide inclined plane 637 is arranged on the rotating block, and the iron removing structure 7 is arranged on the side wall of the fourth cavity; the material enters the grinding channel from the feed opening at the bottom of the first cavity, and along with the rotation of the rotating shaft, the rotating block is driven to rotate, the rotation of the rotating block enables the large material falling into the grinding channel to be ground by the first grinding teeth, the large material continuously moves downwards in the grinding process and is crushed in the process of moving downwards along the grinding channel, so that the large material is decomposed into smaller individuals, then the crushed material to a certain degree moves centrifugally in the rotating process along the first gentle section, and then moves to the tail end, the crushed material enters a working area of the second grinding teeth along the second guide slope, and is ground to be finer sand particles under the grinding of the second grinding teeth, then the crushed material centrifugally moves along the second gentle section and enters the grinding chute which is an inclined channel from coarse to fine, and at the moment, the sand particles are further ground in the structure, and when the grinding action is continuously exerted in the rotating process, the material is provided with the trend of centrifugal motion, and the material ground to the final thickness falls down along the blanking chute.
As shown in fig. 3, 5 and 12, the iron removing structure 7 includes a fifth cavity 71, an electromagnet 72, a power supply 73, a bevel 74, a first rotating member 75, a door 76, a second elastic member 77, a discharge port 78, a first metal block 79 and a power-off structure 8; the fifth cavity 71 is arranged on the side wall of the fourth cavity, the electromagnet 72 is arranged in the fifth cavity, the power supply 73 is fixedly connected to the side wall of the shell, the power supply and the electromagnet are all available on the market, and are not described herein, the bevel 74 is arranged at the bottom of the fifth cavity, the first rotating member 75 is arranged on one side of the bevel, the door body 76 is arranged on the first rotating member, the second elastic member 77 is arranged in the bevel for resetting the door body, the second elastic member is arranged as a spring member, the discharge port 78 is arranged on the side wall of the shell, the first metal block 79 is arranged on the door body, the metal block is a structure capable of being attracted by a magnet, and can be an iron block, and the power-off structure 8 is arranged on the electromagnet; the power communicates with each other with the electro-magnet in the course of grinding, the electro-magnet of circular telegram will attach the magnetism of certain degree, in the iron plate entering fifth cavity in the material will be adsorbed afterwards, the iron plate receives the attraction and will promote the door body, the first metal block on the door body receives the attraction of electro-magnet simultaneously, thereby the door body will rotate round first rotating member, the electro-magnet has played the effect of opening of the supplementary door body, when the iron plate got into in the fifth cavity, at this moment, through the outage structure with the power disconnection, the door body will be because under the spring action of second elastic component, close the door body, thereby accomplish and seal, electro-magnet after the outage is owing to lose magnetic force, can't attract the iron plate, the iron plate falls down under the action of gravity, fall in the fifth cavity bottom that the door body has closed, slide downwards along the fifth cavity afterwards, discharge iron plate from row material mouthful.
As shown in fig. 5-6, the power cutoff structure 8 includes a sixth cavity 81, a first magnetic block 82, a second magnetic block 83, a seventh cavity 84, a power-on block 85, a first power-on wire 86, a second power-on wire 87, and a fixing structure 9; the sixth cavity 81 is arranged above the fifth cavity, the first magnetic block 82 is arranged on the rotating block, the second magnetic block 83 can move back and forth in the sixth cavity, the first magnetic block and the second magnetic block are both permanent magnet structures with strong magnetism, the seventh cavity 84 is arranged above the sixth cavity, the electrifying block 85 is embedded in the seventh cavity, the electrifying block is a touch-type connected block body and used for increasing the contact area of electrification, the first electrifying wire 86 is used for connecting the electrifying block and a power supply, the second electrifying wire 87 is used for connecting an electromagnet and the power supply, the first electrifying wire and the second electrifying wire are copper wires which can be directly purchased in the market, the description is omitted, and the fixing structure 9 is used for fixing the second magnetic block; when the rotating block rotates under the driving of the rotating shaft, the first magnetic block arranged on the rotating block does circular motion around the shaft core of the rotating shaft, the first magnetic block doing circular motion continuously performs corresponding attraction or repulsion action on the second magnetic block in an anode-cathode alternating mode in the rotating process, so that the second magnetic block is controlled to move back and forth in the sixth cavity, when the second magnetic block is positioned at the near shaft end in the sixth cavity, the connection between the electromagnet and the electrified block is disconnected, the electromagnet is not communicated with a power supply at the moment, the electromagnet is nonmagnetic, the iron block adsorbed on the electromagnet falls down due to gravity, when the rotating block rotates for a certain angle, the other end of the first magnetic block is close to the second magnetic block, the second magnetic block slides along the sixth cavity, so that the second magnetic block slides to the far shaft end of the sixth cavity, and the second magnetic block plays a role in communicating the electrified block and the electromagnet at the moment, the electromagnet is magnetic.
As shown in fig. 6, the fixing structure 9 includes an eighth cavity 91, a fixing block 92, a fixing chute 93, a first elastic member 94, a ninth cavity 95, a second metal block 96, and a rope 97; the eighth cavity 91 is arranged above the sixth cavity, the fixing block 92 can move back and forth in the eighth cavity, the fixing chutes 93 are arranged on two sides of the fixing block, the first elastic piece 94 is arranged in the eighth cavity and used for resetting the fixing block, the first elastic piece is arranged as a spring, the ninth cavity 95 is arranged on one side of the eighth cavity, the second metal block 96 is arranged in the ninth cavity, the second metal block is similar to the first metal block and can also be an iron block, the rope 97 is used for connecting the second metal block with the fixing block, and the rope can be selected from a chain and the like, so that the strength of the rope is improved; the fixed block will be under the effect of first elastic component, played the removal that blocks the second magnetic path, played fixed effect, when the both ends that first magnetic path magnetism is the highest are close to the second metal block, the second metal block will be towards the paraxial core end of eighth cavity under the magnetic action, because the removal of second metal block, the fixed block that links to each other with it through the rope will move upwards, the rebound of fixed block will remove the fixed to the second magnetic path, the second magnetic path will move to corresponding other end under the effect of first magnetic path afterwards, because keeping away from of first magnetic path, the fixed block will move downwards, through the fixed chute that sets up on it, extrude the second magnetic path to the nook of sixth cavity.
As shown in fig. 3, 7, and 13-14, the melting structure 10 includes a drawer 101, a heating block 102, a groove 103, a quartz crucible 104, an ear block 105, a material gathering cavity 106, a communicating pipe 107, a chute 108, a blocking piece 109, a first inclined plane 1010, a tenth cavity 1011, a first clamping port 1012, and the drawer 101 can move back and forth at the bottom of the housing, the heating block 102 is disposed at the bottom of the drawer, the heating block can refer to the internal structure of the furnace, and is not described herein, the groove 103 is disposed on the inner wall of the drawer, the quartz crucible 104 is disposed in the drawer, the quartz crucible is the prior art directly purchased from the market, and is not described herein, the ear block 105 is disposed at two sides of the quartz crucible, the material gathering cavity 106 is disposed above the drawer, the communicating pipe 107 is used for communicating a discharge port with the material gathering cavity, the chute 108 is disposed on the side wall of the communicating pipe, the blocking piece 109 can move back and forth in, the first inclined plane 1010 is arranged on the plugging sheet, the tenth cavity 1011 is arranged on the side wall of the sliding chute, the first clamping interface 1012 is arranged on the drawer, the slide block 1013 can move back and forth in the tenth cavity, the first clamping block 1014 is arranged at two ends of the slide block and corresponds to the clamping interfaces, the second inclined plane 1015 is arranged on the slide block and is used for being matched with the first inclined plane to push the slide block to move, the eleventh cavity 1016 is arranged on the side wall of the sliding chute, the second clamping block 1017 arranged in the eleventh cavity, the second clamping interface 1018 arranged on the plugging sheet and the push block 1019 are arranged at the other end of the eleventh cavity, the third elastic piece 1020 is arranged in the eleventh cavity and is used for resetting the push block, and the convex block 1021 is arranged on the drawer and; the material will enter and gather the material intracavity along the communicating pipe, slide down along gathering the material intracavity afterwards, get into quartz crucible, along with the continuous intensification of heating block, quartz crucible heats up constantly, thus make the inside material melt, when needing to take out the molten material outwards, promote the shutoff piece to move inwards, the shutoff piece of inward movement will pass through the cooperation between second inclined plane and the first inclined plane, thus promote the slider to move upwards, the slider that moves upwards drives the joint piece to move upwards simultaneously, the joint piece shifts out from the joint mouth, thus the drawer can be taken out, when the drawer is taken out, the ejector pad loses the extrusion of the protruding piece on the drawer, thus outwards ejecting under the effect of third elastic component, the ejector pad will extrude the airtight part in the eleventh cavity at this moment, thus the second joint piece outwards stretches out the joint and forms the fixing to the shutoff piece in second joint mouth, only when the drawer resets, the second clamping block retracts into the eleventh cavity, and the plugging piece is not limited and can be pulled out outwards.
Example 1
A preparation method of lead-free barium-free environment-friendly crystal glass comprises the following glass components in percentage by weight: SiO248.3%, K2O 6.0.0%, Na2O 3.0.0%, B2O33.0%, ZnO 7.5%, CaO 1.2%, Li2O 0.5.5%, TiO22.0%, ZrO21.0%, SrO 18%, La2O 36%, Y2O 33%, and Sb2O30.5%. . The process comprises the following steps: (1) batching: calculating the mass of the corresponding raw materials according to the mass percentage of each component, and weighing each raw material; and (2) drying raw materials: the water content in the raw materials is reduced by utilizing natural drying and electric drying, and the water content of the raw materials is reduced to be below 5 percent by utilizing the natural drying and the electric drying. (ii) a (3) mixing and stirring: grinding the dried raw materials by using a glass manufacturing all-in-one machine with grinding and melting functions, and melting the mixture at 1500 ℃ for 2 h; (4) clarifying at 1500 ℃ for 0.5 h; (5) shaping the crystal glass by manual or mechanical mode; and (6) annealing the crystal glass after the shaping is finished, preserving the heat in a muffle furnace at 580 ℃ for 5 hours, and then cooling the crystal glass along with the muffle furnace to obtain the lead-free barium-free environment-friendly crystal glass.
Example 2
A preparation method of lead-free and barium-free environment-friendly crystal glass is characterized by comprising the following steps: the glass comprises the following components in percentage by weight: SiO245.3%, K2O 6.0.0%, Na2O 3.0.0%, B2O33.0%, ZnO 7.5%, CaO 1.2%, Li2O 0.5.5%, TiO22.0%, ZrO21.0%, SrO 14%, La2O 310%, Y2O 36%, and Sb2O30.5%. The process comprises the following steps: (1) batching: calculating the mass of the corresponding raw materials according to the mass percentage of each component, and weighing each raw material; and (2) drying raw materials: the water content in the raw materials is reduced by utilizing natural drying and electric drying, and the water content of the raw materials is reduced to be below 5 percent by utilizing the natural drying and the electric drying. (ii) a (3) mixing and stirring: grinding the dried raw materials by using a glass manufacturing all-in-one machine with grinding and melting functions, and melting the mixture for 3 hours at 1550 ℃; (4) clarifying at 1500 ℃ for 1 h; (5) shaping the crystal glass by manual or mechanical mode; and (6) annealing the crystal glass after the shaping is finished, preserving the heat in a muffle furnace at 580 ℃ for 5 hours, and then cooling the crystal glass along with the muffle furnace to obtain the lead-free barium-free environment-friendly crystal glass.
Example 3
A preparation method of lead-free and barium-free environment-friendly crystal glass is characterized by comprising the following steps: the glass comprises the following components in percentage by weight: SiO242.3%, K2O 6.0.0%, Na2O 3.0.0%, B2O33.0%, ZnO 7.5%, CaO 1.2%, Li2O 0.5.5%, TiO22.0%, ZrO21.0%, SrO 8%, La2O 316%, Y2O 39%, and Sb2O30.5%. The process comprises the following steps: (1) batching: calculating the mass of the corresponding raw materials according to the mass percentage of each component, and weighing each raw material; and (2) drying raw materials: the water content in the raw materials is reduced by utilizing natural drying and electric drying, and the water content of the raw materials is reduced to be below 5 percent by utilizing the natural drying and the electric drying. (ii) a (3) mixing and stirring: grinding the dried raw materials by using a glass manufacturing all-in-one machine with grinding and melting functions, and melting the mixture for 2.5h at 1525 ℃; (4) clarifying at 1500 ℃ for 1 h; (5) shaping the crystal glass by manual or mechanical mode; and (6) annealing the crystal glass after the shaping is finished, preserving the heat in a muffle furnace at 580 ℃ for 5 hours, and then cooling the crystal glass along with the muffle furnace to obtain the lead-free barium-free environment-friendly crystal glass.
The specific operation flow is as follows:
the material is put into the first cavity 31 from the feeding hole 21, the crushing knife 33 arranged on the rotating shaft 32 rotates along with the rotating shaft driven by the motor 4, so as to pre-crush the material, the stirring rod 57 driven by the motor rotates along with the rotation, the first convex tooth 51 and the second convex tooth 55 are linked through the first gear 56, so that the rotating shaft rotates to drive the rotating ring 52, so as to control the material to roll in the inner part, the material continuously moves upwards along with the rolling, the material is stirred along with the continuous upward movement of the material, and the material is closer to the crushing knife to be crushed, meanwhile, the air heated by the melting structure below in the air storage cavity is conveyed upwards under the conveying action of the spiral block 510 in the third cavity, and the air entering the air storage cavity 514 is ensured to be in a dry state due to the drying agent 516 arranged in the air storage cavity 514, then, the dry hot air is sprayed to the internal materials through the air spraying pipe 513, so as to dry the materials, thereby reducing the moisture content in the materials, the materials with the size fall into the grinding channel 63, the particles of the materials are gradually reduced in the grinding process along with the continuous movement of the materials along the grinding channel, the materials finally fall into the discharging cavity, the materials are finally gathered towards one side of the discharging cavity 64 along with the inclination of the material guiding ring 65 and finally discharged, in the process, the materials are crushed and ground through the first grinding teeth 631 and the second grinding teeth 632 and are decomposed into smaller individuals, then the smaller individuals are centrifugally moved in the rotating process, then the smaller individuals move from the first slow section 633 and the second slow section 635, in the moving process of the two slow sections, the electrified electromagnet 72 is provided with a certain degree of magnetism, then the iron blocks adsorbing the materials enter the fifth cavity 71, and the iron blocks are attracted to push the door body 76, meanwhile, the first metal block 79 on the door body is simultaneously attracted by the electromagnet, so that the door body rotates around the first rotating part 75, the electromagnet plays a role in assisting the opening of the door body, when the iron block enters the fifth cavity, the power supply is disconnected through the movement of the second magnetic block 83 at this time, the door body closes the door body under the action of the elastic force of the second elastic part 77, the iron block falls down under the action of gravity and falls on the bottom of the closed fifth cavity of the door body, then the iron block slides downwards along the fifth cavity, and finally the iron block is discharged from the discharge opening, when the rotating block rotates under the driving of the rotating shaft, the first magnetic block 82 arranged on the rotating block performs circular motion around the shaft core of the rotating shaft, the first magnetic block performing the circular motion performs corresponding attraction or repulsion on the second magnetic block 83 in an alternating positive pole and negative pole manner continuously in the rotating process, so as to control the second magnetic block to move back and forth in the sixth cavity 81, when the second magnetic block is positioned at the near-axis end in the sixth cavity, the connection between the electromagnet and the energizing block 85 is disconnected, so that the electromagnet is in the process of intermittent connection and disconnection, and simultaneously, in the moving process of the second magnetic block, the fixing block 92 plays a role of blocking the second magnetic block from moving under the action of the first elastic element 94, so as to play a role of fixing, when the two ends with the highest magnetism of the first magnetic block are close to the second metal block, the second metal block faces the near-axis core end of the eighth cavity under the action of the magnetism, due to the movement of the second metal block, the fixing block connected with the second metal block through the rope body moves upwards, the fixing of the fixing block is released by the upwards movement of the fixing block, then the second magnetic block moves to the corresponding other end under the action of the first magnetic block, and then due to the distance of the first magnetic block, the fixing block moves downwards, passes through the fixing inclined groove 93 arranged on the fixing block, extrude the second magnetic path to the nook and corner of sixth cavity, thereby guarantee good intercommunication effect, final material will get into and grind and carry out final grinding in the chute, grind to fine granule after along with the communicating pipe gets into gather in material chamber 106, slide down along gathering the material chamber afterwards, get into in quartz crucible 104, along with the continuous intensification of heating block, quartz crucible constantly heaies up, thereby make inside material melt, at the in-process of taking out, then through the setting of shutoff piece 109, make it guarantee when drawer 101 takes out, the communicating pipe is in the encapsulated situation, repeat above-mentioned step and can continue to carry out glass's preparation.

Claims (10)

1. A preparation method of lead-free and barium-free environment-friendly crystal glass is characterized by comprising the following steps: the glass comprises the following components in percentage by weight: SiO 242.3-48.3%, K2O 5.4.4-6.0%, Na2O 3.0.0-3.6%, B2O33.0-4.3%, CaO 0-1.2%, Li2O0.5-1.2%, TiO22.0-6.0%, ZrO21.0-5.0%, SrO 8-18%, La2O 36-16%, Y2O 30-20%, Sb2O30.5-1.0%, and the process comprises the following steps: (1) batching: calculating the mass of the corresponding raw materials according to the mass percentage of each component, and weighing each raw material; and (2) drying raw materials: the moisture content in each raw material is reduced by utilizing natural drying and electric drying; (3) mixing and stirring: grinding the dried raw materials by using a glass manufacturing all-in-one machine with grinding and melting functions, and melting the mixture for 2-3h at the temperature of 1500-; (4) clarifying at 1500 ℃ for 0.5-1 h; (5) shaping the crystal glass by manual or mechanical mode; (6) annealing the crystal glass after shaping to obtain the lead-free barium-free environment-friendly crystal glass, wherein the raw material powder grinding machine in the step (3) comprises a shell (1) arranged on the ground, a cover shell (2) arranged on the shell, a crushing structure (3) arranged in the shell, a motor (4) used for driving the crushing structure, a feeding hole (21) arranged on the cover shell and a discharging hole (22) arranged on one side of the shell; the crushing structure (3) comprises a first cavity (31) arranged in the shell, a rotating shaft (32) fixedly connected to the motor, a crushing cutter (33) arranged on the rotating shaft, a feed opening (34) arranged at the bottom of the first cavity, a stirring structure (5) sleeved on the rotating shaft, a grinding structure (6) arranged at the bottom of the first cavity and a melting structure (10) arranged below the grinding structure; put into wherein the material from the feed inlet, get into in the first cavity, set up and rotate along with the pivot that is driven by the motor in the epaxial broken sword of commentaries on classics, thereby carry out the pre-crushing to the material, simultaneously through the setting of stirring structure, carry out continuous stirring to the material of inside, make the material that is located the lower part constantly rebound and roll, the material through broken sword preliminary treatment will fall into the grinding structure from feed opening department in, thereby obtain more careful powder, in the powder can directly get into the melting structure through the feed opening afterwards, carry out the melting.
2. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 1, which is characterized in that: the stirring structure (5) comprises a first convex tooth (51) arranged on the radial periphery of the rotating shaft, a rotating ring (52) sleeved on the rotating shaft, a sliding groove (53) used for fixing the rotating ring and rotatably connected to the cover shell, a second cavity (54) arranged in the rotating ring, a second convex tooth (55) arranged on the side wall of the second cavity, a first gear (56) arranged in the second cavity and used for linking the first convex tooth and the second convex tooth, a stirring rod (57) fixedly connected to the rotating ring, a first material guide inclined plane (58) arranged on the stirring rod, a third cavity (59) arranged in the rotating shaft, a spiral block (510) arranged in the third cavity, a vent hole (511) arranged on the rotating shaft, an air cavity (512) arranged below the rotating ring, an air ejecting pipe (513) arranged below the air cavity, an air storage cavity (514) arranged in the shell, an air inlet (515) arranged on the side wall of the heating air cavity, a desiccant (516) disposed within the reservoir; the rotating shaft driven by the motor drives the first convex teeth to rotate in the rotating process, and the first convex teeth and the second convex teeth are linked through the first gear, so that the rotating shaft drives the rotating ring to rotate; the rotation of the rotating shaft drives the first convex teeth to rotate around the shaft core of the rotating shaft, the first convex teeth and the second convex teeth are linked through the matching of the first gear, so the rotation of the first convex teeth drives the rotating ring provided with the second convex teeth to rotate, the stirring rod arranged outside the rotating ring rotates around the shaft core of the rotating shaft along with the rotating ring, the rod body of the stirring rod is attached to the side wall of the first cavity body, and the stirring rod is spirally arranged, so the material retained at the bottom is upwards driven along the side wall along with the stirring rod in the stirring process, the material at the bottom is turned to the upper layer, meanwhile, the first material guide inclined plane is arranged on the stirring shaft, when the stirring rod plays a role of rolling, the material rolled up is gathered to the middle, in the rotating process of the rotating shaft, the spiral block arranged in the rotating shaft rotates along with the rotating shaft, and the rotation of the spiral block plays a role of conveying air, the air in the air storage cavity is conveyed upwards, so that the air enters the air cavity along the third cavity in the rotating shaft, is finally sprayed out of the air injection pipe and is blown onto the materials, and the drying degree of the materials is increased.
3. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 1, which is characterized in that: the grinding structure (6) comprises a fourth cavity (61) arranged below the first cavity, a rotating block (62) sleeved on the rotating shaft, a grinding channel (63) formed by a gap between the fourth cavity and the rotating block, a discharging cavity (64) arranged below the grinding channel, a material guide ring (65) arranged in the discharging cavity, a dustproof groove (66) arranged at the joint of the rotating block and the rotating shaft, a third convex tooth (67) arranged on the radial periphery of the bottom of the rotating shaft, a fifth cavity (68) arranged in the rotating block, a fourth convex tooth (69) arranged on the side wall of the fifth cavity, and a second gear (610) arranged in the fifth cavity and used for matching with the third convex tooth and the fourth convex tooth; third dogtooth cooperates through the second gear with the fourth dogtooth, thereby link, when the motor drives the pivot and rotates promptly, establish and will rotate round pivot axle core at the epaxial third dogtooth of commentaries on classics, the fourth dogtooth that sets up in the fifth cavity in the commentaries on classics piece will receive the drive of third dogtooth, thereby it rotates round the pivot to drive the commentaries on classics piece, be provided with dustproof recess between commentaries on classics piece and the pivot, be used for preventing the entering of dust, the material will fall into in the grinding passageway from the feed opening, along with the material along the continuous removal of grinding passageway, the material will reduce gradually at the in-process granule of grinding, finally fall into the ejection of compact intracavity, finally along with the slope of guide ring, to ejection of compact chamber one side gathering, final discharge.
4. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 1, which is characterized in that: the drying in the step (2) is natural drying and electric drying, so that the moisture of the raw materials is reduced to be below 5 percent.
5. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 1, which is characterized in that: the annealing in the step (6) is as follows: the temperature is kept in a muffle furnace at 580 ℃ for 5h, and then the temperature is cooled along with the muffle furnace.
6. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 3, characterized in that: the grinding channel (63) comprises first grinding teeth (631) wound around the inner wall of the fourth cavity in a radial circle, second grinding teeth (632) arranged below the first grinding teeth, a first buffering section (633) arranged between the first grinding teeth and the second grinding teeth, a grinding chute (634) arranged below the second grinding teeth, a second buffering section (635) arranged between the second grinding teeth and the grinding chute, a discharging chute (636) arranged at the tail end of the grinding chute, a second guide inclined plane (637) arranged on the rotating block and an iron removing structure (7) arranged on the side wall of the fourth cavity; the material enters the grinding channel from the feed opening at the bottom of the first cavity, and along with the rotation of the rotating shaft, the rotating block is driven to rotate, the rotation of the rotating block enables the large material falling into the grinding channel to be ground by the first grinding teeth, the large material continuously moves downwards in the grinding process and is crushed in the process of moving downwards along the grinding channel, so that the large material is decomposed into smaller individuals, then the crushed material to a certain degree moves centrifugally in the rotating process along the first gentle section, and then moves to the tail end, the crushed material enters a working area of the second grinding teeth along the second guide slope, and is ground to be finer sand particles under the grinding of the second grinding teeth, then the crushed material centrifugally moves along the second gentle section and enters the grinding chute which is an inclined channel from coarse to fine, and at the moment, the sand particles are further ground in the structure, and when the grinding action is continuously exerted in the rotating process, the material is provided with the trend of centrifugal motion, and the material ground to the final thickness falls down along the blanking chute.
7. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 6, which is characterized in that: the iron removing structure (7) comprises a fifth cavity (71) arranged on the side wall of the fourth cavity, an electromagnet (72) arranged in the fifth cavity, a power supply (73) fixedly connected to the side wall of the shell, an inclined opening (74) arranged at the bottom of the fifth cavity, a first rotating part (75) arranged on one side of the inclined opening, a door body (76) arranged on the first rotating part, a second elastic part (77) arranged in the inclined opening and used for resetting the door body, a discharge opening (78) arranged on the side wall of the shell, a first metal block (79) arranged on the door body, and a power-off structure (8) arranged on the electromagnet; the power communicates with each other with the electro-magnet in the course of grinding, the electro-magnet of circular telegram will attach the magnetism of certain degree, in the iron plate entering fifth cavity in the material will be adsorbed afterwards, the iron plate receives the attraction and will promote the door body, the first metal block on the door body receives the attraction of electro-magnet simultaneously, thereby the door body will rotate round first rotating member, the electro-magnet has played the effect of opening of the supplementary door body, when the iron plate got into in the fifth cavity, at this moment, through the outage structure with the power disconnection, the door body will be because under the spring action of second elastic component, close the door body, thereby accomplish and seal, electro-magnet after the outage is owing to lose magnetic force, can't attract the iron plate, the iron plate falls down under the action of gravity, fall in the fifth cavity bottom that the door body has closed, slide downwards along the fifth cavity afterwards, discharge iron plate from row material mouthful.
8. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 7, which is characterized in that: the power-off structure (8) comprises a sixth cavity (81) arranged above the fifth cavity, a first magnetic block (82) arranged on the rotating block, a second magnetic block (83) capable of moving back and forth in the sixth cavity, a seventh cavity (84) arranged above the sixth cavity, a power-on block (85) embedded in the seventh cavity, a first power-on wire (86) used for connecting the power-on block and a power supply, a second power-on wire (87) used for connecting the electromagnet and the power supply, and a fixing structure (9) used for fixing the second magnetic block; when the rotating block rotates under the driving of the rotating shaft, the first magnetic block arranged on the rotating block does circular motion around the shaft core of the rotating shaft, the first magnetic block doing circular motion continuously performs corresponding attraction or repulsion action on the second magnetic block in an anode-cathode alternating mode in the rotating process, so that the second magnetic block is controlled to move back and forth in the sixth cavity, when the second magnetic block is positioned at the near shaft end in the sixth cavity, the connection between the electromagnet and the electrified block is disconnected, the electromagnet is not communicated with a power supply at the moment, the electromagnet is nonmagnetic, the iron block adsorbed on the electromagnet falls down due to gravity, when the rotating block rotates for a certain angle, the other end of the first magnetic block is close to the second magnetic block, the second magnetic block slides along the sixth cavity, so that the second magnetic block slides to the far shaft end of the sixth cavity, and the second magnetic block plays a role in communicating the electrified block and the electromagnet at the moment, the electromagnet is magnetic.
9. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 8, characterized in that: the fixing structure (9) comprises an eighth cavity (91) arranged above the sixth cavity, a fixing block (92) capable of moving back and forth in the eighth cavity, fixing chutes (93) arranged on two sides of the fixing block, a first elastic part (94) arranged in the eighth cavity and used for resetting the fixing block, a ninth cavity (95) arranged on one side of the eighth cavity, a second metal block (96) arranged in the ninth cavity, and a rope body (97) used for connecting the second metal block and the fixing block; the fixed block will be under the effect of first elastic component, played the removal that blocks the second magnetic path, played fixed effect, when the both ends that first magnetic path magnetism is the highest are close to the second metal block, the second metal block will be towards the paraxial core end of eighth cavity under the magnetic action, because the removal of second metal block, the fixed block that links to each other with it through the rope will move upwards, the rebound of fixed block will remove the fixed to the second magnetic path, the second magnetic path will move to corresponding other end under the effect of first magnetic path afterwards, because keeping away from of first magnetic path, the fixed block will move downwards, through the fixed chute that sets up on it, extrude the second magnetic path to the nook of sixth cavity.
10. The method for preparing lead-free barium-free environment-friendly crystal glass according to claim 1, which is characterized in that: the melting structure (10) comprises a drawer (101) capable of moving back and forth at the bottom of the shell, a heating block (102) arranged at the bottom of the drawer, a groove (103) formed in the inner wall of the drawer, a quartz crucible (104) arranged in the drawer, ear-shaped blocks (105) arranged on two sides of the quartz crucible, a material gathering cavity (106) arranged above the drawer, a communicating pipeline (107) used for communicating a discharging port with the material gathering cavity, a sliding chute (108) formed in the side wall of the communicating pipeline, a plugging sheet (109) capable of moving back and forth in the sliding chute and used for sealing the communicating pipeline, a first inclined plane (1010) arranged on the plugging sheet, a tenth cavity (1011) formed in the side wall of the sliding chute, a first clamping port (1012) formed in the drawer, a sliding block (1013) capable of moving back and forth in the tenth cavity, first clamping blocks (1014) arranged at two ends of the sliding block and corresponding to the clamping ports, a second inclined plane (1015) arranged on the, An eleventh cavity (1016) arranged on the side wall of the sliding chute, a second clamping block (1017) arranged in the eleventh cavity, a second clamping interface (1018) arranged on the plugging sheet, a push block (1019) arranged at the other end of the eleventh cavity, a third elastic piece (1020) arranged in the eleventh cavity and used for resetting the push block, and a convex block (1021) arranged on the drawer and used for pushing the push block; the material will enter and gather the material intracavity along the communicating pipe, slide down along gathering the material intracavity afterwards, get into quartz crucible, along with the continuous intensification of heating block, quartz crucible heats up constantly, thus make the inside material melt, when needing to take out the molten material outwards, promote the shutoff piece to move inwards, the shutoff piece of inward movement will pass through the cooperation between second inclined plane and the first inclined plane, thus promote the slider to move upwards, the slider that moves upwards drives the joint piece to move upwards simultaneously, the joint piece shifts out from the joint mouth, thus the drawer can be taken out, when the drawer is taken out, the ejector pad loses the extrusion of the protruding piece on the drawer, thus outwards ejecting under the effect of third elastic component, the ejector pad will extrude the airtight part in the eleventh cavity at this moment, thus the second joint piece outwards stretches out the joint and forms the fixing to the shutoff piece in second joint mouth, only when the drawer resets, the second clamping block retracts into the eleventh cavity, and the plugging piece is not limited and can be pulled out outwards.
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Publication number Priority date Publication date Assignee Title
JP2000325910A (en) * 1999-05-17 2000-11-28 Daishin Boeki:Kk Method and apparatus for treating waste
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CN104829130A (en) * 2015-05-04 2015-08-12 东华大学 Leadless barium-free environment-friendly type crystal glass and preparation method thereof
CN207641627U (en) * 2017-11-29 2018-07-24 南京天成模塑有限公司 A kind of mold production pulverizer
CN208599920U (en) * 2018-06-07 2019-03-15 广东优冠生物科技有限公司 A kind of environment-friendly type crushing grinding device
CN110280377A (en) * 2019-06-27 2019-09-27 肥西县碧涛建材有限公司 A kind of slag crushing equipment for removing ferric ion
CN210705507U (en) * 2019-09-19 2020-06-09 江苏华彬新材料有限公司 Smashing and melting device for plastic granulation
CN211385295U (en) * 2019-11-11 2020-09-01 常州市道曼新型建材科技有限公司 Natural color stone powder multi-stage grinding machine

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000325910A (en) * 1999-05-17 2000-11-28 Daishin Boeki:Kk Method and apparatus for treating waste
CN204523173U (en) * 2015-04-14 2015-08-05 广东梅雁吉祥水电股份有限公司 A kind of three sections of level connected superfine pulverizers
CN104829130A (en) * 2015-05-04 2015-08-12 东华大学 Leadless barium-free environment-friendly type crystal glass and preparation method thereof
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CN208599920U (en) * 2018-06-07 2019-03-15 广东优冠生物科技有限公司 A kind of environment-friendly type crushing grinding device
CN110280377A (en) * 2019-06-27 2019-09-27 肥西县碧涛建材有限公司 A kind of slag crushing equipment for removing ferric ion
CN210705507U (en) * 2019-09-19 2020-06-09 江苏华彬新材料有限公司 Smashing and melting device for plastic granulation
CN211385295U (en) * 2019-11-11 2020-09-01 常州市道曼新型建材科技有限公司 Natural color stone powder multi-stage grinding machine

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