CN111999262A - 一种检测氟化氢气体谐波吸收的方法及系统 - Google Patents
一种检测氟化氢气体谐波吸收的方法及系统 Download PDFInfo
- Publication number
- CN111999262A CN111999262A CN202010870372.5A CN202010870372A CN111999262A CN 111999262 A CN111999262 A CN 111999262A CN 202010870372 A CN202010870372 A CN 202010870372A CN 111999262 A CN111999262 A CN 111999262A
- Authority
- CN
- China
- Prior art keywords
- signal
- absorption
- hydrogen fluoride
- laser
- fluoride gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 148
- 239000007789 gas Substances 0.000 title claims abstract description 127
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 229910000040 hydrogen fluoride Inorganic materials 0.000 title claims abstract description 75
- 230000003287 optical Effects 0.000 claims abstract description 43
- 230000001360 synchronised Effects 0.000 claims abstract description 16
- 230000005284 excitation Effects 0.000 claims abstract description 11
- 230000000875 corresponding Effects 0.000 claims abstract description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 15
- 230000003321 amplification Effects 0.000 claims description 8
- 238000003199 nucleic acid amplification method Methods 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000010926 purge Methods 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- 230000002194 synthesizing Effects 0.000 claims description 3
- 230000035507 absorption Effects 0.000 description 108
- 238000001514 detection method Methods 0.000 description 7
- 210000003800 Pharynx Anatomy 0.000 description 3
- 210000002345 respiratory system Anatomy 0.000 description 3
- 206010022114 Injury Diseases 0.000 description 2
- 210000004072 Lung Anatomy 0.000 description 2
- 210000001331 Nose Anatomy 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006011 modification reaction Methods 0.000 description 2
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 210000001508 Eye Anatomy 0.000 description 1
- 210000000936 Intestines Anatomy 0.000 description 1
- 210000000088 Lip Anatomy 0.000 description 1
- 210000000214 Mouth Anatomy 0.000 description 1
- 210000004400 Mucous Membrane Anatomy 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- 210000002784 Stomach Anatomy 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000001186 cumulative Effects 0.000 description 1
- 229920005994 diacetyl cellulose Polymers 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000001665 lethal Effects 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000004936 stimulating Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 238000000041 tunable diode laser absorption spectroscopy Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/39—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N21/0303—Optical path conditioning in cuvettes, e.g. windows; adapted optical elements or systems; path modifying or adjustment
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/061—Sources
Abstract
本发明提供一种检测氟化氢气体谐波吸收的方法及系统,通过信号发生器产生锯齿波信号和三角波信号;将三角波信号作为信号发生器的输入信号与锯齿波信号进行叠加,获取叠加信号;将叠加信号作为激光器的激励源,使激光器生成波长可调谐的激光;将所产生的激光分别通过装有氟化氢气体的待测光程气体吸收池、以及装有氟化氢气体的参考光程气体吸收池,获取两组对应的吸收信号;通过前置放大器对吸收信号进行放大,并将放大后的信号输入锁相放大器中;将三角波信号作为锁相放大器的同步信号,通过同步信号对放大后的信号进行锁相;分析对氟化氢气体的谐波吸收。本发明可以通过光程气体吸收池吸收氟化氢气体,并同时可以检测氟化氢气体谐波吸程度。
Description
技术领域
本发明涉及气体检测技术领域,特别是涉及一种检测氟化氢气体谐波吸收的方法及系统。
背景技术
由于氟化氢(化学式:HF)是一种极强的腐蚀剂,有剧毒。它是无色的气体,但是在空气中只要超过3ppm就会产生刺激的味道。氢氟酸可以透过皮肤黏膜、呼吸道及肠胃道吸收,若不慎发生氢氟酸暴露,即会对人体造成不同程度的伤害,主要伤害有:刺激鼻、咽、眼睛及呼吸道;高浓度蒸气会严重的灼伤唇、口、咽及肺;可能造成液体蓄积于肺中及死亡;122ppm浓度下暴露1分钟会严重刺激鼻、咽、及呼吸道;50ppm浓度下暴露数分钟可能致死。为了解决实验中出现的氟化氢气体,目前一般通过弱碱性的水瓶来进行吸收,并在吸收后检测氟化氢气体的吸收程度。
发明内容
鉴于以上所述现有技术的缺点,本发明的目的在于提供一种检测氟化氢气体谐波吸收的方法及系统,用于研究氟化氢气体吸收的程度。
为实现上述目的及其他相关目的,本发明提供一种检测氟化氢气体谐波吸收的方法,包括以下步骤:
通过信号发生器产生一路锯齿波信号和一路三角波信号;
将所述三角波信号作为所述信号发生器的输入信号与所述锯齿波信号进行叠加,获取叠加信号;
将所述叠加信号作为激光器的激励源,使所述激光器生成波长可调谐的激光;
将所产生的激光分别通过装有氟化氢气体的待测光程气体吸收池、以及装有氟化氢气体的参考光程气体吸收池,获取两组对应的吸收信号;
通过前置放大器对所述吸收信号进行放大,并将放大后的信号输入锁相放大器中;
将所述三角波信号作为所述锁相放大器的同步信号,通过所述同步信号对放大后的信号进行锁相;分析对氟化氢气体的谐波吸收。
可选地,还包括采集锁相后的信号,将锁相后的信号转换为数字信号;根据所述数字信号分析对氟化氢气体的谐波吸收。
可选地,将激光通过装有氟化氢气体的待测光程气体吸收池前,还包括利用纯氮气将气体吸收池吹扫干净。
可选地,利用纯氮气将气体吸收池吹扫干净后,采集当前时刻的吸收数据,并将当前时刻的吸收数据作为零点数据;
获取所述待测光程气体吸收池通过激光后的吸收数据,记为待测吸收数据;
计算所述待测吸收数据与所述零点数据的差值,记为真实吸收数据。
可选地,将锁相后的信号转换为数字信号前,还包括计算转换器的转换频率;有:
f=k×2x;
其中,k为扫频频率;x为转换器的分辨率;f为转换器的转换频率。
本发明还提供一种检测氟化氢气体谐波吸收的系统,包括有:
信号发生器,用于产生一路锯齿波信号和一路三角波信号;
信号合成模块,用于将所述三角波信号作为所述信号发生器的输入信号与所述锯齿波信号进行叠加;
激光器,用于将叠加信号作为激励源,使所述激光器生成波长可调谐的激光;
待测光程气体吸收池,用于盛装待测氟化氢气体,并吸收所述激光,产生待测吸收信号;
参考光程气体吸收池,用于盛装参考氟化氢气体,并吸收所述激光,产生参考吸收信号;
信号放大模块,用于对两组吸收信号进行放大;
锁相模块,用于将所述三角波信号作为同步信号,对经过所述信号放大模块放大后的信号进行锁相;
控制模块,用于分析锁相后的信号,确定对氟化氢气体的谐波吸收。
可选地,所述信号发生器为AD9850发生芯片组成。
可选地,所述激光器为DFB激光器。
可选地,所述激光器可调谐电流范围为15~120mA;且电流每改变1mA时,激光器中心波长改变0.01nm。
如上所述,本发明提供一种检测氟化氢气体谐波吸收的方法及系统,具有以下有益效果:通过信号发生器产生一路锯齿波信号和一路三角波信号;将三角波信号作为信号发生器的输入信号与锯齿波信号进行叠加,获取叠加信号;将叠加信号作为激光器的激励源,使激光器生成波长可调谐的激光;将所产生的激光分别通过装有氟化氢气体的待测光程气体吸收池、以及装有氟化氢气体的参考光程气体吸收池,获取两组对应的吸收信号;通过前置放大器对吸收信号进行放大,并将放大后的信号输入锁相放大器中;将三角波信号作为锁相放大器的同步信号,通过同步信号对放大后的信号进行锁相;分析对氟化氢气体的谐波吸收。本发明可以通过光程气体吸收池吸收氟化氢气体,并同时可以检测氟化氢气体谐波吸程度。
附图说明
图1为检测氟化氢气体谐波吸收的方法流程示意图。
图2为0ppm/1m光程气体吸收池的吸收数据示意图。
图3为100ppm/1m光程气体吸收池的吸收数据示意图。
图4为0ppm/1m光程气体吸收池的二次谐波吸收数据示意图。
图5为100ppm/1m光程气体吸收池的二次谐波吸收数据示意图。
图6(a)至图6(f)分别为0ppm/1ppm/2ppm/3ppm/4ppm/5ppm氟化氢气体的待测吸收数据示意图。
图7(a)至图7(f)分别为0ppm/1ppm/2ppm/3ppm/4ppm/5ppm氟化氢气体的真实吸收数据示意图。
图8为0ppm/1ppm/2ppm/3ppm/4ppm/5ppm氟化氢气体100次真实吸收数据的累加数据示意图。
图9为每组后50次真实吸收数据的检出限示意图。
图10为检测氟化氢气体谐波吸收的系统硬件结构示意图。
具体实施方式
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。需说明的是,在不冲突的情况下,以下实施例及实施例中的特征可以相互组合。
需要说明的是,以下实施例中所提供的图示仅以示意方式说明本发明的基本构想,遂图式中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,且其组件布局型态也可能更为复杂。
请参阅图1,本发明提供一种检测氟化氢气体谐波吸收的方法,包括以下步骤:
S100,通过信号发生器产生一路锯齿波信号和一路三角波信号;
S200,将三角波信号作为信号发生器的输入信号与锯齿波信号进行叠加,获取叠加信号;
S300,将叠加信号作为激光器的激励源,使激光器生成波长可调谐的激光;
S400,将所产生的激光分别通过装有氟化氢气体的待测光程气体吸收池、以及装有氟化氢气体的参考光程气体吸收池,获取两组对应的吸收信号;
S500,通过前置放大器对吸收信号进行放大,并将放大后的信号输入锁相放大器中;
S600,将三角波信号作为锁相放大器的同步信号,通过同步信号对放大后的信号进行锁相;分析对氟化氢气体的谐波吸收。具体地,采集锁相后的信号,将锁相后的信号转换为数字信号;根据数字信号分析对氟化氢气体的谐波吸收。
作为示例,本申请的实施例使用激光驱动器来驱动1312nm激光器,产生对应的激光;再将激光分别通过0ppm/1m光程气体吸收池(参考光程气体吸收池)与100ppm/1m光程气体吸收池(待测光程气体吸收池)中,得到两组的吸收信号。重复采集100次两组的吸收信号,并进行可视化显示,如图2和图3所示。由图2和图3可知,无氟化氢气体存在时,1312nm附近无吸收存在;有氟化氢气体存在时,1312nm附近有明显吸收峰。
根据上述记载,在对氟化氢气体进行谐波吸收实验时,由信号发生器产生一路锯齿波信号与一路三角波信号,三角波信号同时作为信号发生器的输入信号与锯齿波信号叠加。叠加后的信号作为激励源并输入给激光器,激光器根据输入的激励源生成一个可调谐的电流信号来驱动激光器,使激光器自身产生波长调谐的激光。将所产生的激光信号经过气体池吸收后被铟镓砷传感器吸收,信号经前置放大器放大后进入锁相放大器。锁相放大器使用信号发生器产生的三角波信号作为同步信号进行锁相,锁相输出结果直接进入PCI数据采集卡被采集成数字信号。本申请实施例使用激光驱动器驱动1312nm激光器,输出激光后,分别通过100ppm/1m光程气体吸收池与0ppm/1m光程气体吸收池,得到两组锁相输出信号如图4和图5所示。由图4和图5可以看出,氟化氢气体在1312nm附近有吸收峰存在,同时吸收很弱的锁相信号在经过锁相放大后变的很强。
根据上述记载,本申请实施例使用配气仪配置低浓度氟化氢气体,研究不同浓度的谐波吸收程度。将激光通过装有氟化氢气体的待测光程气体吸收池前,还包括利用纯氮气将待测光程气体吸收池吹扫干净。利用纯氮气将气体吸收池吹扫干净后,采集当前时刻的吸收数据,并将当前时刻的吸收数据作为零点数据;获取待测光程气体吸收池通过激光后的吸收数据,记为待测吸收数据;计算待测吸收数据与零点数据的差值,记为真实吸收数据。具体地,首先使用高纯氮将气室吹扫干净,再依次配比1ppm、2ppm、3ppm、4ppm、5ppm的HF气体,将氟化氢气体通入光程10cm的光程气体吸收池,获取每组对应的吸收信号。采集100次的待测吸收信号数据,对吸收后的信号进行分析。采集的待测数据如图6(a)至图6(f)所示。
将通入高纯氮气体时采集到的数据做累加平均,作为零点数据,将5组待测吸收数据与零点数据相减后得到真实吸收数据,真实吸收数据如图7(a)至图7(f)所示。
分别将5组100次真实吸收数据做加权累加,累加数据如图8所示。由数据可以看出,累加数据比较稳定,同时在改变配气仪配气浓度时,吸收数据有明显的上升和下降。
舍弃数据明显变化的前50组数据,将后50组累加数据量化为气体浓度后,对浓度数据进行分析,按照IUPAC的建议,以三倍标准差为检出限,得到该5组测量数据的灵敏度或检出限如图9所示。
由数据可以看出在10cm光程的情况下,氟化氢气体在1312nm附近检出限可达0.5ppm以下。基于前述理论分析中的朗伯比尔定律,光程加长后对应检出限会等比例降低,在1m光程下,使用二次谐波方法推断氟化氢气体检出限小于50ppb。
本发明还提供一种检测氟化氢气体谐波吸收的系统,包括有:
信号发生器,用于产生一路锯齿波信号和一路三角波信号;
信号合成模块,用于将三角波信号作为信号发生器的输入信号与锯齿波信号进行叠加;
激光器,用于将叠加信号作为激励源,使所述激光器生成波长可调谐的激光;
待测光程气体吸收池,用于盛装待测氟化氢气体,并吸收激光,产生待测吸收信号;
参考光程气体吸收池,用于盛装参考氟化氢气体,并吸收激光,产生参考吸收信号;
信号放大模块,用于对两组吸收信号进行放大;
锁相模块,用于将三角波信号作为同步信号,对经过信号放大模块放大后的信号进行锁相;
控制模块,用于分析锁相后的信号,确定对氟化氢气体的谐波吸收。
本申请实施例中,激光器为DFB激光器。其中,激光器选择的指标分别为中心波长在1278nm附近,输出功率大于10mW,激光器线宽MHz量级。由激光器参数特性可以看出,激光器接收可调谐电流范围是15~120mA,电流每改变1mA激光器中心波长改变0.01nm。温度不变的情况下,激光器可调谐范围约为1nm。一般而言,用于TDLAS检测的激光器在使用过程中温度不需要调谐,只需要改变驱动激光器的电流信号来改变激光器的波长。使用二次谐波技术时,这个信号需要两个原始波形进行叠加,一个是变换相对比较缓慢但是幅度较大的锯齿波,用于频率扫描;一个是频率较高但是幅度较低的正弦波,用于锁相放大。两个信号经过比例叠加后加载到激光器上,继而可产生出原始信号,叠加后的信号如图10所示。
本申请实施例中,将锁相后的信号转换为数字信号前,还包括计算转换器的转换频率;有:
f=k×2x;
其中,k为扫频频率;x为转换器的分辨率;f为转换器的转换频率。
以扫频速率为5HZ,DA转换器的分辨率为16位为例,完全插补的情况下,DA转换器的转换速率需要达到320KHz,普通DA芯片就可以达到这种要求。
若以正弦波信号为20KHz,DA转换器的分辨率为16位为例,完全插补情况下,DA转换器的转换速率需要达到1.28GHz。如此高的转换速率,普通DA基本无法完成,需要使用专用DA或者dds芯片。经过实验研究后,本申请实施例选择AD9850作为二次谐波产生芯片,即作为信号发生器的发生芯片。AD9850是一款高度集成的器件,采用先进的DDS技术,内置一个高速、高性能数模转换器和比较器,共同构成完整的数字可编程频率合成器和时钟发生器。以精密时钟源作为基准时,AD9850能产生频谱纯净的频率/相位可编程、模拟输出正弦波。该正弦波可以直接用作频率源,或转换为适合便捷时钟发生器应用的方波。同时,AD9850内置一个高速比较器,其经过配置可以接受DAC的(外部)滤波输出,以产生“展开式”低抖动方波输出,这样该器件便可用作便捷时钟发生器。
综上所述,本发明提供一种检测氟化氢气体谐波吸收的方法及系统,通过信号发生器产生一路锯齿波信号和一路三角波信号;将三角波信号作为信号发生器的输入信号与锯齿波信号进行叠加,获取叠加信号;将叠加信号作为激光器的激励源,使激光器生成波长可调谐的激光;将所产生的激光分别通过装有氟化氢气体的待测光程气体吸收池、以及装有氟化氢气体的参考光程气体吸收池,获取两组对应的吸收信号;通过前置放大器对吸收信号进行放大,并将放大后的信号输入锁相放大器中;将三角波信号作为锁相放大器的同步信号,通过同步信号对放大后的信号进行锁相;分析对氟化氢气体的谐波吸收。本发明可以通过光程气体吸收池吸收氟化氢气体,并同时可以检测氟化氢气体谐波吸程度。
上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。
Claims (9)
1.一种检测氟化氢气体谐波吸收的方法,其特征在于,包括以下步骤:
通过信号发生器产生一路锯齿波信号和一路三角波信号;
将所述三角波信号作为所述信号发生器的输入信号与所述锯齿波信号进行叠加,获取叠加信号;
将所述叠加信号作为激光器的激励源,使所述激光器生成波长可调谐的激光;
将所产生的激光分别通过装有氟化氢气体的待测光程气体吸收池、以及装有氟化氢气体的参考光程气体吸收池,获取两组对应的吸收信号;
通过前置放大器对所述吸收信号进行放大,并将放大后的信号输入锁相放大器中;
将所述三角波信号作为所述锁相放大器的同步信号,通过所述同步信号对放大后的信号进行锁相;分析对氟化氢气体的谐波吸收。
2.根据权利要求1所述的检测氟化氢气体谐波吸收的方法,其特征在于,还包括采集锁相后的信号,将锁相后的信号转换为数字信号;根据所述数字信号分析对氟化氢气体的谐波吸收。
3.根据权利要求1所述的检测氟化氢气体谐波吸收的方法,其特征在于,将激光通过装有氟化氢气体的待测光程气体吸收池前,还包括利用纯氮气将气体吸收池吹扫干净。
4.根据权利要求3所述的检测氟化氢气体谐波吸收的方法,其特征在于,利用纯氮气将气体吸收池吹扫干净后,采集当前时刻的吸收数据,并将当前时刻的吸收数据作为零点数据;
获取所述待测光程气体吸收池通过激光后的吸收数据,记为待测吸收数据;
计算所述待测吸收数据与所述零点数据的差值,记为真实吸收数据。
5.根据权利要求2所述的检测氟化氢气体谐波吸收的方法,其特征在于,将锁相后的信号转换为数字信号前,还包括计算转换器的转换频率;有:
f=k×2x;
其中,k为扫频频率;x为转换器的分辨率;f为转换器的转换频率。
6.一种检测氟化氢气体谐波吸收的系统,其特征在于,包括有:
信号发生器,用于产生一路锯齿波信号和一路三角波信号;
信号合成模块,用于将所述三角波信号作为所述信号发生器的输入信号与所述锯齿波信号进行叠加;
激光器,用于将叠加信号作为激励源,使所述激光器生成波长可调谐的激光;
待测光程气体吸收池,用于盛装待测氟化氢气体,并吸收所述激光,产生待测吸收信号;
参考光程气体吸收池,用于盛装参考氟化氢气体,并吸收所述激光,产生参考吸收信号;
信号放大模块,用于对两组吸收信号进行放大;
锁相模块,用于将所述三角波信号作为同步信号,对经过所述信号放大模块放大后的信号进行锁相;
控制模块,用于分析锁相后的信号,确定对氟化氢气体的谐波吸收。
7.根据权利要求6所述的检测氟化氢气体谐波吸收的系统,其特征在于,所述信号发生器为AD9850发生芯片组成。
8.根据权利要求6所述的检测氟化氢气体谐波吸收的系统,其特征在于,所述激光器为DFB激光器。
9.根据权利要求8所述的检测氟化氢气体谐波吸收的系统,其特征在于,所述激光器可调谐电流范围为15~120mA;且电流每改变1mA时,激光器中心波长改变0.01nm。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010870372.5A CN111999262A (zh) | 2020-08-26 | 2020-08-26 | 一种检测氟化氢气体谐波吸收的方法及系统 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010870372.5A CN111999262A (zh) | 2020-08-26 | 2020-08-26 | 一种检测氟化氢气体谐波吸收的方法及系统 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111999262A true CN111999262A (zh) | 2020-11-27 |
Family
ID=73470921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010870372.5A Pending CN111999262A (zh) | 2020-08-26 | 2020-08-26 | 一种检测氟化氢气体谐波吸收的方法及系统 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111999262A (zh) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102419330A (zh) * | 2011-12-07 | 2012-04-18 | 重庆市电力公司电力科学研究院 | 一种氟化氢hf气体含量检测装置及方法 |
CN102468805A (zh) * | 2010-11-03 | 2012-05-23 | 北京普源精电科技有限公司 | 一种扫频信号发生器及扫频信号的产生方法 |
CN204177739U (zh) * | 2014-10-09 | 2015-02-25 | 河北钢铁股份有限公司 | 双相锁相放大器 |
CN105021568A (zh) * | 2015-08-11 | 2015-11-04 | 江苏师范大学 | 基于多模激光光谱技术的甲烷气体浓度检测装置 |
-
2020
- 2020-08-26 CN CN202010870372.5A patent/CN111999262A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102468805A (zh) * | 2010-11-03 | 2012-05-23 | 北京普源精电科技有限公司 | 一种扫频信号发生器及扫频信号的产生方法 |
CN102419330A (zh) * | 2011-12-07 | 2012-04-18 | 重庆市电力公司电力科学研究院 | 一种氟化氢hf气体含量检测装置及方法 |
CN204177739U (zh) * | 2014-10-09 | 2015-02-25 | 河北钢铁股份有限公司 | 双相锁相放大器 |
CN105021568A (zh) * | 2015-08-11 | 2015-11-04 | 江苏师范大学 | 基于多模激光光谱技术的甲烷气体浓度检测装置 |
Non-Patent Citations (1)
Title |
---|
王松武等: "《电子创新设计与实践》", 31 May 2010 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104280362B (zh) | 一种高温水汽激光光谱在线检测系统 | |
CN105548075A (zh) | 一种玻璃药瓶内氧气含量的检测装置与方法 | |
CN101617192A (zh) | 同时测量两种或更多气体成份的波长调制光谱 | |
Bradshaw et al. | Photofragmentation two‐photon laser‐induced fluorescence detection of NO2 and NO: Comparison of measurements with model results based on airborne observations during PEM‐Tropics A | |
Yuan et al. | First observation of mesospheric and thermospheric winds by a Fabry-Perot interferometer in China | |
CN103175759A (zh) | 基于多种地基遥感技术获取城市气溶胶复折射指数的方法 | |
CN104198433A (zh) | 一种激光吸收光谱技术在线检测人体呼吸标识性气体浓度的装置及方法 | |
CN104165847B (zh) | 同步测量液膜浓度和厚度的装置以及测量方法 | |
CN108981953B (zh) | 一种基于干涉调制原理的激光吸收光谱测温方法和系统 | |
Roller et al. | Simultaneous NO and CO 2 measurement in human breath with a single IV–VI mid-infrared laser | |
Fried et al. | Versatile integrated tunable diode laser system for high precision: application for ambient measurements of OCS | |
CN109991189B (zh) | 一种基于波数漂移修正的固定点波长调制气体浓度测量装置及其测量方法 | |
CN104848985B (zh) | 一种基于红外激光光谱的真空度检测方法与系统 | |
CN105043930A (zh) | 微结构碱金属气室碱金属蒸汽原子密度的检测装置和方法 | |
CN111999262A (zh) | 一种检测氟化氢气体谐波吸收的方法及系统 | |
CN103575719A (zh) | 分子浓度测量装置和分子浓度测量方法 | |
Zhang et al. | Water vapor detection system based on scanning spectra | |
CN107036983A (zh) | 基于调制光谱实现非均匀燃烧场气体参数定量测量的方法 | |
Zhang et al. | Nitric oxide isotopic analyzer based on a compact dual-modulation Faraday rotation spectrometer | |
Persson et al. | Studies of gas exchange in fruits using laser spectroscopic techniques | |
CN106248444A (zh) | 土壤呼吸co2气体的采集及其碳稳定同位素值测试方法 | |
CN109946237B (zh) | 一种光强增强型光声光谱气体检测系统 | |
RU181296U1 (ru) | Многокомпонентный лидарный газоанализатор среднего ик-диапазона | |
CN108613946A (zh) | 基于激光吸收光谱技术的种子活力测量系统及方法 | |
Ruzhitskaya et al. | Analysis of the Transmission Spectra of Optical Microcavities Using the Mode Broadening Method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |