CN111718016A - Ultrafine Nanogenerator - Google Patents

Ultrafine Nanogenerator Download PDF

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CN111718016A
CN111718016A CN201910205687.5A CN201910205687A CN111718016A CN 111718016 A CN111718016 A CN 111718016A CN 201910205687 A CN201910205687 A CN 201910205687A CN 111718016 A CN111718016 A CN 111718016A
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尹兆龙
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Beijing North Hongtuo Environmental Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F7/00Aeration of stretches of water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/74Treatment of water, waste water, or sewage by oxidation with air
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/34Organic compounds containing oxygen
    • C02F2101/345Phenols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
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  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)

Abstract

本发明提供一种超细纳米发生装置,包括:进水喷嘴、气液混合腔、出水口和进气口;所述进水喷嘴与水泵连接,在所述气液混合腔内壁上设置有螺旋凹槽,所述进气口设置在所述气液混合腔上并与所述螺旋凹槽连通。本发明的超细纳米发生装置,快速提高溶氧水平,大幅降低供氧电耗;减少剩余污泥量及降低药剂使用量;出水水质优化。

Figure 201910205687

The invention provides an ultra-fine nano-generating device, comprising: a water inlet nozzle, a gas-liquid mixing chamber, a water outlet and an air inlet; the water inlet nozzle is connected with a water pump, and a spiral is arranged on the inner wall of the gas-liquid mixing chamber a groove, the air inlet is arranged on the gas-liquid mixing chamber and communicates with the spiral groove. The ultra-fine nano-generating device of the invention can rapidly increase the dissolved oxygen level, greatly reduce the power consumption of oxygen supply, reduce the amount of excess sludge and reduce the usage of chemicals, and optimize the water quality of the effluent.

Figure 201910205687

Description

超细纳米发生装置Ultrafine Nanogenerator

技术领域technical field

本发明涉及废水处理技术领域,尤其涉及一种超细纳米发生装置。The invention relates to the technical field of wastewater treatment, in particular to an ultrafine nanometer generating device.

背景技术Background technique

人类活动排放的污染已经超出了水域自我净化能力的极限,通常自然水域的天然溶解氧含量为1ppm左右。人类活动排放的污染已经超出了水域自我净化能力的极限,通常自然水域的天然溶解氧含量为 1ppm左右。由于水中没有溶解氧,导致水中生长的各种好氧生物大量死亡而沉入水底,腐烂变质后沉积为水底淤泥,构成了水域中的内污染源,再加上垃圾、污水等其它污染物继续排入水中,导致水域的富养化污染程度进一步恶化,从而爆发多种重度污染表象,如发臭、蓝藻、赤潮、水葫芦等。因此污水处理过程实际上是给水中提供充足的活性氧的过程,只有保证水中有充足的活性氧、溶解氧,才能保证污水处理彻底,并且污水处理后没有后续污泥污染问题。The pollution emitted by human activities has exceeded the limit of the water's self-purification ability, and the natural dissolved oxygen content of natural waters is usually about 1ppm. The pollution emitted by human activities has exceeded the limit of the self-purification capacity of waters, and the natural dissolved oxygen content of natural waters is usually about 1ppm. Because there is no dissolved oxygen in the water, a large number of aerobic organisms growing in the water die and sink to the bottom of the water. After decaying and metamorphism, they are deposited as bottom sludge, which constitutes an internal pollution source in the water area. In addition, other pollutants such as garbage and sewage continue to be discharged. Into the water, the eutrophic pollution of the water area is further deteriorated, resulting in the outbreak of a variety of severe pollution manifestations, such as odor, cyanobacteria, red tide, water hyacinth, etc. Therefore, the sewage treatment process is actually a process of supplying sufficient active oxygen to the water. Only by ensuring that there are sufficient active oxygen and dissolved oxygen in the water can the sewage treatment be thorough and there will be no subsequent sludge pollution after sewage treatment.

现有的微纳米装置的工作原理是,污水从该装置的入水口高压打入到气水混合腔中,再从气水混合腔另一端的出水口喷出,水流在气水混合腔中流动时形成负压状态,在气水混合腔上还设置有一进气口,当气水混合腔内处于负压的状态时,气体从进气口吸入并与气水混合腔内的污水混合,从出水口喷出。现有的纳米装置所产生的气泡在水中最多不超过200万个/ml/h,气泡直径约为1-100微米,颜色白浊,气泡缓慢上浮后在水中消失,存在时间约4-8小时。现有技术的纳米装置所产生的气泡直径大,存在时间短。The working principle of the existing micro-nano device is that sewage is injected into the gas-water mixing chamber at high pressure from the water inlet of the device, and then ejected from the water outlet at the other end of the gas-water mixing chamber, and the water flows in the gas-water mixing chamber. A negative pressure state is formed when the air-water mixing chamber is in a negative pressure state. When the air-water mixing chamber is in a negative pressure state, the gas is inhaled from the air inlet and mixed with the sewage in the air-water mixing chamber. The water outlet spits out. The bubbles generated by the existing nano-devices are no more than 2 million/ml/h in water at most, the diameter of the bubbles is about 1-100 microns, the color is cloudy, the bubbles slowly float up and disappear in the water, and the existence time is about 4-8 hours. . The bubbles generated by the nanodevices of the prior art have large diameters and short existence times.

发明内容SUMMARY OF THE INVENTION

本发明所要解决的技术问题在于,针对现有技术的不足提供提供一种超细纳米发生装置,通过气水混合腔中的螺旋凹槽所产生的超细纳米气泡,气泡直径小,因此在水中存留时间长。The technical problem to be solved by the present invention is to provide an ultra-fine nano-generating device in view of the deficiencies of the prior art. The ultra-fine nano-bubbles generated by the spiral grooves in the gas-water mixing chamber have small bubble diameters, so they cannot be used in water. Long retention time.

本发明所要解决的技术问题是通过如下技术方案实现的:The technical problem to be solved by the present invention is achieved through the following technical solutions:

本发明一种超细纳米发生装置,包括:进水喷嘴、气液混合腔、出水口和进气口;所述进水喷嘴与水泵连接,在所述气液混合腔内壁上设置有螺旋凹槽,所述进气口设置在所述气液混合腔上并与所述螺旋凹槽连通。The invention relates to an ultra-fine nano-generating device, comprising: a water inlet nozzle, a gas-liquid mixing chamber, a water outlet and an air inlet; the water inlet nozzle is connected with a water pump, and a spiral concave is arranged on the inner wall of the gas-liquid mixing chamber The air inlet is arranged on the gas-liquid mixing chamber and communicates with the spiral groove.

更好地,所述螺旋凹槽深度为1-2毫米,宽度为1-2毫米。Preferably, the depth of the spiral groove is 1-2 mm, and the width is 1-2 mm.

更好地,所述气液混合腔为密封腔。Preferably, the gas-liquid mixing chamber is a sealed chamber.

本发明的超细纳米发生装置,快速提高溶氧水平,大幅降低供氧电耗;减少剩余污泥量及降低药剂使用量;出水水质优化。The ultra-fine nano-generating device of the invention can rapidly increase the dissolved oxygen level, greatly reduce the power consumption of oxygen supply, reduce the amount of excess sludge and reduce the usage of chemicals, and optimize the water quality of the effluent.

下面结合附图和具体实施例对本发明的技术方案进行详细地说明。The technical solutions of the present invention will be described in detail below with reference to the accompanying drawings and specific embodiments.

附图说明Description of drawings

图1为本发明超细纳米发生装置的结构示意图;Fig. 1 is the structural representation of the ultrafine nanometer generating device of the present invention;

图2为图1中A-A向剖视图。FIG. 2 is a cross-sectional view taken along the line A-A in FIG. 1 .

具体实施方式Detailed ways

图1为本发明超细纳米发生装置的结构示意图,图2为图1中A-A 向剖视图。如图1并参考图2所示,一种超细纳米发生装置,包括:进水喷嘴1、气液混合腔2、出水口3和进气口4;所述进水喷嘴1与水泵连接,在所述气液混合腔2内壁上设置有螺旋凹槽21,所述进气口4设置在所述气液混合腔2上并与所述螺旋凹槽21连通。所述螺旋凹槽21深度为1-2毫米,宽度为1-2毫米。优选地,所述螺旋凹槽21 深度为0.5毫米,宽度为1.5毫米。优选地,所述气液混合腔2为密封腔。FIG. 1 is a schematic structural diagram of an ultra-fine nano-generating device of the present invention, and FIG. 2 is a cross-sectional view taken along the line A-A in FIG. 1 . As shown in Figure 1 and with reference to Figure 2, an ultra-fine nano-generating device includes: a water inlet nozzle 1, a gas-liquid mixing chamber 2, a water outlet 3 and an air inlet 4; the water inlet nozzle 1 is connected to a water pump, A spiral groove 21 is arranged on the inner wall of the gas-liquid mixing chamber 2 , and the air inlet 4 is arranged on the gas-liquid mixing chamber 2 and communicates with the spiral groove 21 . The depth of the spiral groove 21 is 1-2 mm, and the width is 1-2 mm. Preferably, the helical groove 21 has a depth of 0.5 mm and a width of 1.5 mm. Preferably, the gas-liquid mixing chamber 2 is a sealed chamber.

工作原理:进水喷嘴1对准螺旋凹槽21加压喷水,水经过螺旋凹槽21形成加速喷射而出,原理形同于步枪枪管(滑膛线),在水加压同时进气口4形成负压,也就是说,由于气液混合腔2为密封腔,因此水流通过水泵的压力在气液混合腔2中经过螺旋凹槽21加速排出,在排出的同时产生负压极速吸气,在出水口3形成气水混合体,空气被水切割成纳米结构。Working principle: The water inlet nozzle 1 is aligned with the spiral groove 21 to pressurize the water, and the water is accelerated and sprayed out through the spiral groove 21. The principle is similar to the rifle barrel (smooth rifling). 4. Negative pressure is formed, that is to say, since the gas-liquid mixing chamber 2 is a sealed chamber, the water flow is accelerated and discharged through the spiral groove 21 in the gas-liquid mixing chamber 2 through the pressure of the water pump, and a negative pressure is generated at the same time as it is discharged. , a gas-water mixture is formed at the water outlet 3, and the air is cut into nanostructures by water.

本发明的超细纳米发生装置所产生的纳米气泡在水中4.6亿个 /ml/h,气泡直径50-155纳米,无色透明,粘性力比浮力大,会产生布朗运动,能在水中存留数周或数月。根据1mm=1000μm=1000nm,直径1μm气泡在一定体积下表面积比理论上是直径1mm气泡的1000倍,即空气和水的接触面积就增加了1000倍,各种反应速度也增加了 1000倍以上。而纳米气泡的平均直径在50-155nm,这就意味着处理能力是普通曝气的10万倍以上。纳米气泡在水中只做布朗运动,而纳米气泡是1mm气泡上升速度的1/2000。考虑到比表面积的增加,纳米气泡的气体溶解力比一般空气增加20万倍以上。当然纳米气泡的情况下可直接超越饱和度溶解。可以使溶氧值迅速达到超饱和状态。从而提升氧的利用率,使污水中磷酸盐被微生物吸收。纳米气泡在水中的溶解是一个气泡逐渐缩小的过程,压力的上升会增加气体的溶解速度,伴随着表面积比的增加,气泡缩小的速度会变的越来越快,从而最终溶解到水中,理论上气泡即将消失时的所受压力为无限大。因为纳米气泡带有负电荷的特性,在水中会将带有正电荷的污染物或病毒吸附与纳米气泡的周边,纳米气泡在压力下慢慢变小最后在大约4000MPa 左右破裂,纳米气泡在高压力破碎之际,瞬间除了高压之外还会产生高温,由于小纳米气泡破裂瞬间产生的高压高温能量将污染物或细菌分解消灭。而同时将破坏污染物成分分离浮于水面。纳米气泡破裂瞬间,由于气液界面消失的剧烈变化,界面上聚集的高浓度离子将积蓄的化学能一下子释放出来,此时可激发产生大量的羟基自由基。羟基自由基具有超高的氧化还原电位,其产生的超强氧化作用可降解水中正常条件下难以氧化分解的有机污染物(如:苯酚等),实现对水质的净化。这个原理和自身增压溶解一样,纳米气泡即使在水体中气体含量达到过饱和条件时,仍可继续进行气体的传质过程并保持高效的传质效率,使得硝化速度快,去除氨氮彻底。也是基于大的比表面积,气泡上升速度慢及自身增压溶解而最后消失水中的原理,大大提高气体(空气,氧气,臭氧,二氧化碳等)在水中的溶解度。The nano-bubbles generated by the ultra-fine nano-generating device of the present invention are 460 million/ml/h in water, the diameter of the bubbles is 50-155 nanometers, colorless and transparent, the viscous force is greater than the buoyancy force, can produce Brownian motion, and can survive several times in water. weeks or months. According to 1mm=1000μm=1000nm, the surface area ratio of a bubble with a diameter of 1μm under a certain volume is theoretically 1000 times that of a bubble with a diameter of 1mm, that is, the contact area between air and water is increased by 1000 times, and various reaction speeds have also increased by more than 1000 times. The average diameter of nanobubbles is 50-155nm, which means that the processing capacity is more than 100,000 times that of ordinary aeration. Nanobubbles only do Brownian motion in water, and nanobubbles are 1/2000 of the rising speed of 1mm bubbles. Considering the increase in specific surface area, the gas dissolving power of nanobubbles is more than 200,000 times higher than that of ordinary air. Of course, in the case of nanobubbles, it can dissolve directly beyond saturation. The dissolved oxygen value can quickly reach a supersaturated state. Thereby, the utilization rate of oxygen is improved, so that the phosphate in the sewage is absorbed by the microorganisms. The dissolution of nanobubbles in water is a process in which the bubbles gradually shrink. The increase in pressure will increase the dissolution rate of the gas. With the increase of the surface area ratio, the shrinkage of the bubbles will become faster and faster, and finally dissolve into the water. Theoretical The pressure when the upper bubble is about to disappear is infinite. Because of the negatively charged characteristics of nanobubbles, positively charged pollutants or viruses will be adsorbed to the periphery of nanobubbles in water. The nanobubbles gradually become smaller under pressure and finally burst at about 4000MPa. When the pressure is broken, a high temperature will be generated in addition to the high pressure. Due to the high pressure and high temperature energy generated at the moment when the small nano-bubble bursts, the pollutants or bacteria will be decomposed and eliminated. At the same time, the components of the damaged pollutants are separated and floated on the water surface. When the nanobubble bursts, due to the dramatic change in the disappearance of the gas-liquid interface, the high-concentration ions accumulated on the interface release the accumulated chemical energy at once, which can stimulate and generate a large number of hydroxyl radicals. Hydroxyl radicals have an ultra-high redox potential, and the super-strong oxidation produced by them can degrade organic pollutants (such as phenol, etc.) that are difficult to oxidize and decompose in water under normal conditions, and realize the purification of water quality. This principle is the same as self-pressurized dissolution. Even when the gas content in the water body reaches the supersaturated condition, the nanobubble can continue the gas mass transfer process and maintain high mass transfer efficiency, making the nitrification speed fast and ammonia nitrogen completely removed. It is also based on the principle of large specific surface area, slow rise of bubbles and self-pressurized dissolution and finally disappears in water, greatly improving the solubility of gases (air, oxygen, ozone, carbon dioxide, etc.) in water.

Claims (3)

1. An ultrafine nano-generation device, comprising: the water inlet nozzle, the gas-liquid mixing cavity, the water outlet and the gas inlet are arranged on the water inlet pipe; the water inlet nozzle is connected with the water pump, a spiral groove is formed in the inner wall of the gas-liquid mixing cavity, and the gas inlet is formed in the gas-liquid mixing cavity and communicated with the spiral groove.
2. The ultrafine nanogenerator of claim 1, wherein the spiral groove has a depth of 1-2 mm and a width of 1-2 mm.
3. The ultrafine nano-generation device according to claim 1 or 2, wherein the gas-liquid mixing chamber is a sealed chamber.
CN201910205687.5A 2019-03-19 2019-03-19 Ultrafine Nanogenerator Pending CN111718016A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473365A (en) * 2017-09-11 2017-12-15 梁芳新 A kind of high energy oxygengenerating plant and water treatment system
CN210214952U (en) * 2019-03-19 2020-03-31 北京北方宏拓环境科技有限公司 Superfine nanometer generating device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473365A (en) * 2017-09-11 2017-12-15 梁芳新 A kind of high energy oxygengenerating plant and water treatment system
CN210214952U (en) * 2019-03-19 2020-03-31 北京北方宏拓环境科技有限公司 Superfine nanometer generating device

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Application publication date: 20200929