CN111670271A - Surface treatment device and surface treatment method - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及一种用于对处理孔的内壁面实施表面处理的表面处理装置和表面处理方法。The present invention relates to a surface treatment device and a surface treatment method for performing surface treatment on the inner wall surface of a treatment hole.
背景技术Background technique
例如,如日本发明专利公开公报特开2013-159832号所记载那样,通过使电解处理液在插入有管状的电极的处理孔的内部流通的同时,在电极与处理孔的内壁面之间通电,来对该内壁面实施电镀、阳极氧化膜形成等表面处理。For example, as described in Japanese Patent Application Laid-Open Publication No. 2013-159832, the electrolytic treatment solution is passed through the inside of the treatment hole in which the tubular electrode is inserted, and the current is passed between the electrode and the inner wall surface of the treatment hole. The inner wall surface is subjected to surface treatment such as electroplating and anodic oxide film formation.
发明内容SUMMARY OF THE INVENTION
本发明是与这种技术相关联而提出的,本发明的主要目的在于,提供一种表面处理装置,即使是具有延伸方向不同的多个直线状部的处理孔,该表面处理装置也能够不经过掩蔽(masking)等复杂的工序而高效且高质量地对该处理孔的内壁面进行表面处理。The present invention has been proposed in relation to such a technique, and the main object of the present invention is to provide a surface treatment apparatus that can not The inner wall surface of the processing hole is surface-treated with high efficiency and high quality through complicated steps such as masking.
另外,本发明的另一个目的在于,提供一种表面处理方法,即使是具有延伸方向不同的多个的直线状部的处理孔,该表面处理方法也能够不经过掩蔽等复杂的工序而高效且高质量地对该处理孔的内壁面进行表面处理。In addition, another object of the present invention is to provide a surface treatment method capable of efficiently and efficiently without complicated steps such as masking, even for treatment holes having a plurality of linear portions having different extending directions. The inner wall surface of the processing hole is surface-treated with high quality.
根据本发明的一技术方案,提供一种表面处理装置,其具有电极,通过使电解处理液在插入有该电极的处理孔的内部流通,并且在所述电极与所述处理孔的内壁面之间通电,来对该内壁面实施表面处理,在该表面处理装置中,所述电极由第1电极和第2电极构成,该第1电极和该第2电极隔着绝缘部件以电绝缘的状态被一体化,所述第1电极从具有弯折部的所述处理孔的一个开口插入,所述第2电极从所述处理孔的另一个开口插入,通过所述第1电极的第1顶端部和所述第2电极的所述第2顶端部在所述弯折部的内部经由所述绝缘部件抵接,所述第1电极和所述第2电极被一体化。According to one aspect of the present invention, there is provided a surface treatment apparatus including an electrode, and by allowing an electrolytic treatment solution to flow inside a treatment hole into which the electrode is inserted, and between the electrode and the inner wall surface of the treatment hole The inner wall surface is subjected to surface treatment by supplying electricity between the two surfaces. In this surface treatment device, the electrode is composed of a first electrode and a second electrode, and the first electrode and the second electrode are in a state of being electrically insulated via an insulating member. are integrated, the first electrode is inserted from one opening of the processing hole having a bent portion, the second electrode is inserted from the other opening of the processing hole, and passes through the first tip of the first electrode The first electrode and the second electrode are integrated with the first electrode and the second electrode in contact with the second distal end portion of the second electrode inside the bent portion via the insulating member.
在此,例如,对于在延伸方向的中途具有弯折部的处理孔,其从一个开口到弯折部之间的直线状部(第1直线状部)和从另一个开口到弯折部之间的直线状部(第2直线状部)之间彼此的延伸方向不同。在例如使用外观形状为直线状的一般电极来对处理孔的内壁面进行表面处理的情况下,首先,实施掩蔽,以使电解处理溶液不与第1直线状部的内壁面接触。接着,从处理孔的另一个开口插入电极,使电极与第2直线状部的内壁面相向。Here, for example, for a processing hole having a bent portion in the middle of the extending direction, the linear portion (first linear portion) from one opening to the bent portion and the gap from the other opening to the bent portion The extending directions of the linear portions (second linear portions) between them are different from each other. For example, when the inner wall surface of the processing hole is surface-treated using a general electrode having a linear external shape, first, masking is performed so that the electrolytic treatment solution does not come into contact with the inner wall surface of the first linear portion. Next, the electrode is inserted through the other opening of the processing hole so that the electrode faces the inner wall surface of the second linear portion.
接着,进行通电工序来对该内壁面实施表面处理,该通电工序为:使电解处理液在处理孔的内部流通,并且在电极和第2直线状部的内壁面之间通电。接着,去除对第1直线状部的内壁面实施的掩蔽,并对实施了表面处理的第2直线状部的内壁面实施掩蔽。接着,与对第2直线状部的内壁面实施的表面处理相同,对第1直线状部的内壁面也进行通电工序来实施表面处理。即,为了使用外观形状为直线状的一般的电极来对具有弯折部的处理孔进行表面处理,需要进行多个掩蔽工序、多个通电工序。Next, the inner wall surface is surface-treated by an energization step of passing the electrolytic treatment solution through the treatment hole and energizing between the electrode and the inner wall surface of the second linear portion. Next, masking was performed on the inner wall surface of the first linear portion, and masking was performed on the inner wall surface of the surface-treated second linear portion. Next, similarly to the surface treatment performed on the inner wall surface of the second linear portion, the inner wall surface of the first linear portion is also subjected to an electrification step to perform surface treatment. That is, in order to surface-treat the processing hole which has a bending part using the general electrode whose external appearance shape is a linear shape, it is necessary to carry out a plurality of masking steps and a plurality of energization steps.
但是,在具有如上述那样被一体化的第1电极和第2电极的本发明所涉及的表面处理装置中,能够在使第1电极与处理孔的第1直线状部的内壁面相向,并且使第2电极与第2直线状部的内壁面相向的状态下进行通电工序。据此,能够不经过掩蔽等复杂的工序而通过共同的通电工序对处理孔的第1直线状部的内壁面和第2直线状部的内壁面双方实施表面处理。However, in the surface treatment apparatus according to the present invention having the first electrode and the second electrode integrated as described above, the first electrode and the inner wall surface of the first linear portion of the treatment hole can face each other, and The energization step is performed in a state in which the second electrode faces the inner wall surface of the second linear portion. This makes it possible to perform surface treatment on both the inner wall surface of the first linear portion and the inner wall surface of the second linear portion of the processing hole through a common energization step without going through complicated steps such as masking.
而且,由于第1电极和第2电极被绝缘,因此,能够对第1电极和第2电极独立地供给电流来进行通电。据此,例如与不使第1电极和第2电极绝缘,而将电流从第1电极的基端侧经由第1顶端部和第2顶端部供给到第2电极的基端侧的情况相比,能够抑制在处理孔的第1直线状部的内壁面和第2直线状部的内壁面之间产生电流分布差异。其结果,能够对处理孔的第1直线状部和第2直线状部双方的内壁面大致均匀地进行表面处理。Furthermore, since the first electrode and the second electrode are insulated, the first electrode and the second electrode can be energized by independently supplying current. According to this, for example, compared with the case where the current is supplied from the base end side of the first electrode to the base end side of the second electrode via the first tip portion and the second tip portion without insulating the first electrode and the second electrode. , it is possible to suppress a difference in current distribution from occurring between the inner wall surface of the first linear portion and the inner wall surface of the second linear portion of the processing hole. As a result, the inner wall surfaces of both the first linear portion and the second linear portion of the processing hole can be substantially uniformly surface-treated.
如上所述,根据该表面处理装置,即使在处理孔由具有弯折部的形状构成的情况下,也能够对该处理孔的内壁面高效且高质量地进行表面处理。As described above, according to the surface treatment apparatus, even when the treatment hole is formed of a shape having a bent portion, the inner wall surface of the treatment hole can be surface-treated with high efficiency and high quality.
在上述表面处理装置中,优选为,所述第1电极和所述第2电极是具有管状部分的中空体,在所述第1顶端部设置有封闭所述第1电极的顶端的第1封闭部,在所述第2顶端部设置有封闭所述第2电极的顶端的第2封闭部,在所述第1电极设置有第1内侧电极,该第1内侧电极在所述第1电极的内部沿轴向延伸,并与所述第1封闭部电连接,在所述第2电极设置有第2内侧电极,该第2内侧电极在所述第2电极的内部沿轴向延伸,并与所述第2封闭部电连接。In the above-mentioned surface treatment apparatus, it is preferable that the first electrode and the second electrode are hollow bodies having a tubular portion, and a first sealing member for sealing a distal end of the first electrode is provided in the first distal end portion. A second closing portion for closing the distal end of the second electrode is provided on the second distal end portion, and a first inner electrode is provided on the first electrode, and the first inner electrode is located on the side of the first electrode. The inside extends in the axial direction and is electrically connected to the first closing portion, and a second inside electrode is provided on the second electrode, the second inside electrode extends in the axial direction inside the second electrode, and is connected to the second electrode. The second closing portion is electrically connected.
在该情况下,通过经由第1内侧电极向第1电极供给电流,据此能够使电流从设置有第1封闭部的第1顶端部侧流向基端侧。同样,第2电极也能够通过经由第2内部电极向第2电极供给电流而使电流从设置有第2封闭部的第2顶端部侧流向基端侧。据此,能够在第1封闭部及第2封闭部与处理孔的弯折部的内壁面之间良好地进行通电,因此,也能够对处理孔的弯折部的内壁面有效地实施表面处理。In this case, by supplying a current to the first electrode via the first inner electrode, the current can flow from the side of the first distal end portion where the first closing portion is provided to the side of the proximal end portion. Similarly, in the second electrode, by supplying a current to the second electrode via the second inner electrode, the current can flow from the second distal end portion side where the second closing portion is provided to the proximal end side. According to this, it is possible to satisfactorily conduct electricity between the first sealing portion and the second sealing portion and the inner wall surface of the bent portion of the processing hole, so that the inner wall surface of the bent portion of the processing hole can also be effectively surface-treated. .
根据本发明的另一技术方案,提供一种表面处理装置,其具有电极,通过使电解处理液在插入有该电极的处理孔的内部流通,并且在所述电极与所述处理孔的内壁面之间通电,来对该内壁面实施表面处理,在该表面处理装置中,所述电极由第1电极和第2电极构成,该第1电极和该第2电极隔着绝缘部件以电绝缘的状态被一体化,所述处理孔由第1处理孔和第2处理孔构成,其中,所述第2处理孔在该第1处理孔的内壁面设置有开口,在被插入到所述第1处理孔的所述第1电极的面向所述第2处理孔的所述开口的部分设置有被插入部,通过在所述被插入部插入所述第2电极的顶端部,所述第1电极和所述第2电极被一体化,所述绝缘部件夹设在所述被插入部和所述第2电极的所述顶端部之间。According to another aspect of the present invention, there is provided a surface treatment apparatus including an electrode, and by allowing an electrolytic treatment solution to flow inside a treatment hole into which the electrode is inserted, the electrode and the inner wall surfaces of the treatment hole are formed. The inner wall surface is subjected to surface treatment by energizing between them. In this surface treatment device, the electrode is composed of a first electrode and a second electrode, and the first electrode and the second electrode are electrically insulated via an insulating member. The state is integrated, and the processing hole is composed of a first processing hole and a second processing hole, wherein the second processing hole is provided with an opening on the inner wall surface of the first processing hole, and is inserted into the first processing hole. A portion to be inserted in the processing hole of the first electrode facing the opening of the second processing hole is provided with an inserted portion, and the first electrode is inserted into the inserted portion by inserting the distal end portion of the second electrode. The insulating member is integrated with the second electrode, and the insulating member is interposed between the inserted portion and the distal end portion of the second electrode.
由第1处理孔和在该第1处理孔的内壁面设置有开口的第2处理孔、换言之从第1处理孔分支的第2处理孔构成的处理孔也具有延伸方向不同的多个直线状部。在使用外观形状为直线状的一般电极对这样的处理孔的内壁面进行表面处理的情况下,也需要对每个第1处理孔和第2处理孔进行掩蔽或通电工序。The processing hole formed of the first processing hole and the second processing hole provided with an opening in the inner wall surface of the first processing hole, in other words, the second processing hole branching from the first processing hole also has a plurality of linear shapes with different extending directions. department. When the inner wall surface of such a processing hole is surface-treated using a general electrode having a linear external shape, masking or conduction steps are also required for each of the first processing hole and the second processing hole.
对此,在具有如上述那样被一体化的第1电极和第2电极的本发明所涉及的表面处理装置中,能够在使第1电极与第1处理孔的内壁面相向,并且使第2电极与第2处理孔的内壁面相向的状态下进行通电工序。据此,能够不经过掩蔽等复杂的工序而通过共同的通电工序对第1处理孔和第2处理孔双方的内壁面实施表面处理。另外,由于第1电极和第2电极被绝缘,因此,能够对第1电极和第2电极独立地供给电流来进行通电。据此,能够对第1处理孔和第2处理孔双方的内壁面大致均匀地进行表面处理。On the other hand, in the surface treatment apparatus according to the present invention having the first electrode and the second electrode integrated as described above, the first electrode and the inner wall surface of the first treatment hole can face each other, and the second electrode can be made to face the inner wall surface of the first treatment hole. The energization step is performed in a state where the electrodes face the inner wall surface of the second processing hole. According to this, it is possible to perform surface treatment on the inner wall surfaces of both the first processing hole and the second processing hole by a common energization step without going through complicated steps such as masking. In addition, since the first electrode and the second electrode are insulated, the first electrode and the second electrode can be energized by independently supplying current. Accordingly, the inner wall surfaces of both the first processing hole and the second processing hole can be substantially uniformly surface-treated.
如上所述,根据该表面处理装置,即使在处理孔由具有分支部的形状构成的情况下,也能够对该处理孔的内壁面高效且高质量地进行表面处理。As described above, according to the surface treatment apparatus, even when the treatment hole is formed of the shape having the branch portion, the inner wall surface of the treatment hole can be efficiently and efficiently surface treated with high quality.
在上述表面处理装置中,优选为,所述第1电极是具有管状部分的中空体,所述被插入部由贯通所述第1电极的周壁的孔构成,在所述被插入部的内部设置有所述绝缘部件,在所述绝缘部件形成有内螺纹,在所述第2电极的所述顶端部形成有外螺纹,通过所述内螺纹与所述外螺纹的旋合,所述第1电极和所述第2电极被定位固定。在该情况下,由于能够在良好地维持第1处理孔和第2处理孔各自的内壁面与第1电极和第2电极的外周面的位置关系的状态下进行通电工序,因此,能够进一步高质量地进行表面处理。In the above-mentioned surface treatment apparatus, it is preferable that the first electrode is a hollow body having a tubular portion, and the inserted portion is formed of a hole penetrating a peripheral wall of the first electrode, and is provided inside the inserted portion. The insulating member is provided with an internal thread formed on the insulating member, an external thread is formed on the distal end portion of the second electrode, and the first The electrode and the second electrode are positioned and fixed. In this case, since the energization process can be performed in a state in which the positional relationship between the inner wall surfaces of the first processing holes and the second processing holes and the outer peripheral surfaces of the first and second electrodes is well maintained, it is possible to further increase the Quality finish.
在上述表面处理装置中,优选为,在所述第1电极的顶端部设置有封闭部,该封闭部封闭该第1电极的顶端,且面向有底的所述第1处理孔的底面,在所述第1电极的内部设置有内侧电极,该内侧电极沿该第1电极的轴向延伸,并与所述封闭部电连接。在该情况下,通过从内侧电极供给电流,能够使电流从设置有封闭部的第1电极的顶端部侧流向基端侧。据此,由于能够在封闭部与第1处理孔的底面之间良好地进行通电,因此,也能够对该底面有效地实施表面处理。In the above-mentioned surface treatment apparatus, it is preferable that a closing portion is provided at the distal end portion of the first electrode, the closing portion closes the distal end of the first electrode and faces the bottom surface of the bottomed first processing hole, An inner electrode is provided inside the first electrode, the inner electrode extends along the axial direction of the first electrode, and is electrically connected to the sealing portion. In this case, by supplying the current from the inner electrode, the current can be caused to flow from the distal end side to the proximal end side of the first electrode in which the closing portion is provided. According to this, since electricity can be satisfactorily conducted between the closed portion and the bottom surface of the first processing hole, the bottom surface can also be effectively surface-treated.
根据本发明的另一技术方案,提供一种表面处理装置,其具有电极,通过使电解处理液在插入有该电极的处理孔的内部流通,并且在所述电极和所述处理孔的内壁面之间通电,来对该内壁面实施表面处理,在该表面处理装置中,所述电极由第1电极和第2电极构成,该第1电极和该第2电极隔着绝缘部件以电绝缘的状态被一体化,所述第1电极和所述第2电极是具有管状部分的中空体,所述第1电极的外径大于所述第2电极的外径,所述处理孔由有底的第1处理孔和与该第1处理孔交叉的有底的第2处理孔构成,在被插入到所述第1处理孔的所述第1电极的、配置在所述第1处理孔与所述第2处理孔的交叉部的部分,沿所述第2处理孔的延伸方向形成有贯插孔,被插入到所述第2处理孔的所述第2电极贯插于所述贯插孔,从而与所述第1电极一体化,所述绝缘部件夹设在所述贯插孔和所述第2电极之间。According to another aspect of the present invention, there is provided a surface treatment apparatus including an electrode, and by allowing an electrolytic treatment solution to flow inside a treatment hole into which the electrode is inserted, the electrode and the inner wall surfaces of the treatment hole The inner wall surface is subjected to surface treatment by energizing between them. In this surface treatment device, the electrode is composed of a first electrode and a second electrode, and the first electrode and the second electrode are electrically insulated via an insulating member. The state is integrated, the first electrode and the second electrode are hollow bodies having a tubular portion, the outer diameter of the first electrode is larger than the outer diameter of the second electrode, and the processing hole is made of a bottomed A first processing hole and a bottomed second processing hole intersecting the first processing hole are constituted, and between the first processing hole and the second processing hole of the first electrode inserted into the first processing hole A through hole is formed at the intersection of the second processing hole along the extending direction of the second processing hole, and the second electrode inserted into the second processing hole is inserted through the through hole so as to be integrated with the first electrode, and the insulating member is sandwiched between the through hole and the second electrode.
由第1处理孔和与该第1处理孔交叉的第2处理孔构成的处理孔也具有延伸方向不同的多个直线状部。在使用外观形状为直线状的一般电极对这样的处理孔的内壁面进行表面处理的情况下,也需要对每个第1处理孔和第2处理孔进行掩蔽或通电工序。The processing hole composed of the first processing hole and the second processing hole intersecting with the first processing hole also has a plurality of linear portions having different extending directions. When the inner wall surface of such a processing hole is surface-treated using a general electrode having a linear external shape, masking or conduction steps are also required for each of the first processing hole and the second processing hole.
对此,在具有如上述那样被一体化的第1电极和第2电极的本发明所涉及的表面处理装置中,能够在使第1电极与第1处理孔的内壁面相向,并且使第2电极与第2处理孔的内壁面相向的状态下进行通电工序。据此,能够不经过掩蔽等复杂的工序而通过共同的通电工序对第1处理孔和第2处理孔双方的内壁面实施表面处理。另外,由于第1电极和第2电极被绝缘,因此,能够对第1电极和第2电极独立地供给电流来进行通电。据此,能够对第1处理孔和第2处理孔双方的内壁面大致均匀地进行表面处理。On the other hand, in the surface treatment apparatus according to the present invention having the first electrode and the second electrode integrated as described above, the first electrode and the inner wall surface of the first treatment hole can face each other, and the second electrode can be made to face the inner wall surface of the first treatment hole. The energization step is performed in a state where the electrodes face the inner wall surface of the second processing hole. According to this, it is possible to perform surface treatment on the inner wall surfaces of both the first processing hole and the second processing hole by a common energization step without going through complicated steps such as masking. In addition, since the first electrode and the second electrode are insulated, the first electrode and the second electrode can be energized by independently supplying current. Accordingly, the inner wall surfaces of both the first processing hole and the second processing hole can be substantially uniformly surface-treated.
综上,根据该表面处理装置,即使在处理孔由具有交叉部的形状构成的情况下,也能够对该处理孔的内壁面高效且高质量地进行表面处理。In summary, according to this surface treatment apparatus, even when the treatment hole is formed of a shape having an intersecting portion, the inner wall surface of the treatment hole can be surface-treated with high efficiency and high quality.
在上述表面处理装置中,优选为,所述第2电极被插入到直径比所述第1处理孔小的所述第2处理孔。这样,根据比第1电极的外径小的第2电极的外径,使第2电极的外周面与直径比第1处理孔小的第2处理孔的内壁面相向。据此,抑制了第1处理孔和第2处理孔双方的内壁面产生电流密度差,从而容易对第1处理孔和第2处理孔双方的内壁面大致均匀地实施表面处理。In the above-described surface treatment apparatus, preferably, the second electrode is inserted into the second treatment hole having a diameter smaller than that of the first treatment hole. In this way, according to the outer diameter of the second electrode smaller than the outer diameter of the first electrode, the outer peripheral surface of the second electrode is made to face the inner wall surface of the second treatment hole having a diameter smaller than that of the first treatment hole. Thereby, the difference in current density between the inner wall surfaces of the first processing hole and the second processing hole is suppressed, and the inner wall surfaces of both the first processing hole and the second processing hole can be easily surface-treated substantially uniformly.
在上述表面处理装置中,优选为,在所述第1电极的顶端部形成有封闭部,该封闭部封闭该第1电极的顶端,且面向所述第1处理孔的底面,所述第1电极的内径比所述第2电极的外径大,在所述第1电极的内部设置有内侧电极,该内侧电极通过该第1电极的内周面与所述第2电极的外周面之间,沿该第1电极的轴向延伸,并与所述第1电极的所述封闭部电连接。In the above-mentioned surface treatment apparatus, preferably, a closing portion is formed at a distal end portion of the first electrode, the closing portion closes the distal end of the first electrode and faces a bottom surface of the first processing hole, and the first The inner diameter of the electrode is larger than the outer diameter of the second electrode, and an inner electrode is provided inside the first electrode, and the inner electrode passes between the inner peripheral surface of the first electrode and the outer peripheral surface of the second electrode , which extends along the axial direction of the first electrode and is electrically connected to the closing portion of the first electrode.
在该情况下,通过从内侧电极供给电流,能够使电流从设置有封闭部的第1电极的顶端部侧向基端侧流动,因此,也能够对第1处理孔的面向封闭部的底面有效地实施表面处理。In this case, by supplying the current from the inner electrode, the current can be made to flow from the distal end side to the proximal end side of the first electrode in which the closing portion is provided, and therefore, the bottom surface of the first processing hole facing the closing portion can also be effective. surface treatment.
在上述表面处理装置中,优选为,在所述第2电极的顶端部设置有封闭部,该封闭部被配置成封闭该第2电极的顶端,且面向所述第2处理孔的底面,在所述第2电极设置有内侧电极,该内侧电极在所述第2电极的内部沿轴向延伸,并与所述第2电极的所述封闭部电连接。在该情况下,也能够有效地对第2处理孔的面向第2电极的封闭部的底面实施表面处理。In the above-mentioned surface treatment apparatus, it is preferable that a closing portion is provided at the distal end portion of the second electrode, the closing portion is arranged to close the distal end of the second electrode and face the bottom surface of the second processing hole, The second electrode is provided with an inner electrode that extends axially inside the second electrode and is electrically connected to the closing portion of the second electrode. Also in this case, the bottom surface of the closed portion of the second processing hole facing the second electrode can be effectively surface-treated.
根据本发明的另一实施方式,提供一种表面处理方法,其使用由第1电极和第2电极构成的电极来对处理孔的内壁面实施表面处理,该表面处理方法具有一体化工序和通电工序,其中,所述一体化工序为:在处理孔的内部,将所述第1电极和所述第2电极隔着绝缘部件以电绝缘的状态一体化;所述通电工序为:使电解处理液在所述处理孔的内部流通,同时在所述第1电极及所述第2电极与所述处理孔的内壁面之间通电,在所述一体化工序中,在所述第1电极的第1顶端部和所述第2电极的第2顶端部中的至少任一方设置所述绝缘部件,从具有弯折部的所述处理孔的一个开口插入所述第1电极,并且从所述处理孔的另一个开口插入所述第2电极,在所述弯折部的内部,经由所述绝缘部件使所述第1顶端部与所述第2顶端部抵接。According to another embodiment of the present invention, there is provided a surface treatment method for subjecting the inner wall surface of a treatment hole to a surface treatment using an electrode composed of a first electrode and a second electrode, the surface treatment method including an integration step and energization step, wherein the integration step includes: integrating the first electrode and the second electrode in a state of being electrically insulated via an insulating member in the inside of the processing hole; and the energization step includes electrolytic treatment The liquid flows in the inside of the processing hole, and at the same time, electricity is energized between the first electrode and the second electrode and the inner wall surface of the processing hole. In the integration step, the first electrode is The insulating member is provided in at least one of the first distal end portion and the second distal end portion of the second electrode, the first electrode is inserted through one opening of the processing hole having a bent portion, and the first electrode is inserted from the The second electrode is inserted into the other opening of the processing hole, and the first distal end portion is brought into contact with the second distal end portion via the insulating member inside the bent portion.
在处理孔的内部,通过如上述那样将第1电极和第2电极一体化的一体化工序,能够在使第1电极与从处理孔的一个开口到弯折部之间的直线状部(第1直线状部)的内壁面相向,并且使第2电极与从另一个开口到弯折部之间的直线状部(第2直线状部)的内壁面相向的状态下,进行通电工序。据此,不经过掩蔽等复杂的工序而能够通过共同的通电工序对第1直线状部和第2直线状部双方的内壁面实施表面处理。另外,由于第1电极和第2电极被绝缘,因此,能够对第1电极和第2电极独立地供给电流来进行通电。据此,能够对处理孔的第1直线状部和第2直线状部双方的内壁面大致均匀地进行表面处理。Inside the treatment hole, through the integration process of integrating the first electrode and the second electrode as described above, the first electrode and the linear portion (the first electrode) between the one opening of the treatment hole and the bent portion can be formed. The energization step is performed in a state in which the inner wall surfaces of the linear portion (1) face each other and the second electrode faces the inner wall surface of the linear portion (second linear portion) from the other opening to the bent portion. According to this, it is possible to perform surface treatment on the inner wall surfaces of both the first linear portion and the second linear portion through a common energization step without going through complicated steps such as masking. In addition, since the first electrode and the second electrode are insulated, the first electrode and the second electrode can be energized by independently supplying current. Accordingly, the inner wall surfaces of both the first linear portion and the second linear portion of the processing hole can be substantially uniformly surface-treated.
综上,根据该表面处理方法,即使在处理孔由具有弯折部的形状构成的情况下,也能够对该处理孔的内壁面高效且高质量地进行表面处理。In conclusion, according to this surface treatment method, even when the treatment hole is formed of a shape having a bent portion, the inner wall surface of the treatment hole can be surface-treated with high efficiency and high quality.
在上述表面处理方法中,优选为,在所述通电工序中,经由第1内侧电极向所述第1电极通电,并且经由第2内侧电极向所述第2电极通电,其中,所述第1内侧电极在由具有管状部分的中空体构成的所述第1电极的内部沿轴向延伸,且与封闭所述第1电极的顶端的第1封闭部电连接;所述第2内侧电极在由具有管状部分的中空体构成的所述第2电极的内部沿轴向延伸,且与封闭所述第2电极的顶端的第2封闭部电连接。In the above-mentioned surface treatment method, preferably, in the energization step, electricity is supplied to the first electrode through a first inner electrode, and electricity is supplied to the second electrode through a second inner electrode, wherein the first electrode is energized. The inner electrode extends in the axial direction inside the first electrode composed of a hollow body having a tubular portion, and is electrically connected to a first closing portion that closes the tip of the first electrode; the second inner electrode is formed by The inside of the second electrode formed of a hollow body having a tubular portion extends in the axial direction, and is electrically connected to a second closing portion that closes the distal end of the second electrode.
在该情况下,能够在第1封闭部及第2封闭部与处理孔的弯折部的内壁面之间良好地进行通电,因此,也能够对处理孔的弯折部的内壁面有效地实施表面处理。In this case, since electricity can be favorably conducted between the first and second closing portions and the inner wall surface of the bent portion of the treatment hole, it can also be effectively applied to the inner wall surface of the bent portion of the treatment hole. Surface treatment.
根据本发明的另一技术方案,提供一种表面处理方法,其使用由第1电极和第2电极构成的电极来对处理孔的内壁面实施表面处理,该表面处理方法具有一体化工序和通电工序,其中,所述一体化工序为:在处理孔的内部,将所述第1电极和所述第2电极隔着绝缘部件以电绝缘的状态一体化;所述通电工序为:使电解处理液在所述处理孔的内部流通,并且在所述第1电极及所述第2电极与所述处理孔的内壁面之间通电,在所述一体化工序中,将第1电极插入到由第1处理孔和第2处理孔构成的所述处理孔的所述第1处理孔,且将所述第2电极插入到所述第2处理孔,并且将所述第2电极的顶端部经由所述绝缘部件插入到所述第1电极的被插入部,其中,所述第1处理孔为有底的处理孔,所述第2处理孔为在该第1处理孔的内壁面设置有开口的处理孔,所述被插入部设置于所述第1电极的面向所述第2处理孔的所述开口的部分。According to another aspect of the present invention, there is provided a surface treatment method for subjecting an inner wall surface of a treatment hole to a surface treatment using an electrode composed of a first electrode and a second electrode, the surface treatment method including an integration step and energization step, wherein the integration step includes: integrating the first electrode and the second electrode in a state of being electrically insulated via an insulating member in the inside of the processing hole; and the energization step includes electrolytic treatment The liquid flows through the inside of the processing hole, and electricity is energized between the first electrode and the second electrode and the inner wall surface of the processing hole, and in the integration step, the first electrode is inserted into the The first treatment hole of the treatment hole constituted by the first treatment hole and the second treatment hole, the second electrode is inserted into the second treatment hole, and the tip portion of the second electrode is inserted through the first treatment hole. The insulating member is inserted into the inserted portion of the first electrode, wherein the first treatment hole is a treatment hole with a bottom, and the second treatment hole is provided with an opening in an inner wall surface of the first treatment hole of the processing hole, the inserted portion is provided on a portion of the first electrode facing the opening of the second processing hole.
在处理孔的内部,通过如上述那样将第1电极和第2电极一体化的一体化工序,能够在使第1电极与第1处理孔的内壁面相向,并使第2电极与第2处理孔的内壁面相向的状态下进行通电工序。据此,不经过掩蔽等复杂的工序而能够通过共同的通电工序对第1处理孔和第2处理孔双方的内壁面实施表面处理。另外,由于第1电极和第2电极被绝缘,因此,在通电工序中,能够对第1电极和第2电极独立地供给电流来进行通电。据此,能够对第1处理孔和第2处理孔双方的内壁面大致均匀地进行表面处理。In the inside of the treatment hole, through the integration process of integrating the first electrode and the second electrode as described above, the first electrode and the inner wall surface of the first treatment hole can face each other, and the second electrode and the second treatment hole can be made to face each other. The energization step is performed in a state where the inner wall surfaces of the holes face each other. According to this, it is possible to perform surface treatment on the inner wall surfaces of both the first processing hole and the second processing hole by a common energization step without going through complicated steps such as masking. In addition, since the first electrode and the second electrode are insulated, in the energization step, the first electrode and the second electrode can be energized by independently supplying current. Accordingly, the inner wall surfaces of both the first processing hole and the second processing hole can be substantially uniformly surface-treated.
综上,即使在处理孔由具有分支部的形状构成的情况下,也能够对该处理孔的内壁面高效且高质量地进行表面处理。In conclusion, even when the processing hole is formed of a shape having a branch, the inner wall surface of the processing hole can be surface-treated with high efficiency and high quality.
在上述表面处理方法中,优选为,所述第1电极由具有管状部分的中空体构成,所述被插入部由贯通所述第1电极的周壁的孔构成,在所述一体化工序中,使在设置于所述被插入部的内部的所述绝缘部件上形成的内螺纹与在所述第2电极的所述顶端部上形成的外螺纹旋合,而将所述第1电极和所述第2电极定位固定。在该情况下,能够在良好地维持第1处理孔及第2处理孔各自的内壁面与第1电极和第2电极的外周面的位置关系的状态下进行通电工序,因此能够进一步高质量地进行表面处理。In the above surface treatment method, preferably, the first electrode is formed of a hollow body having a tubular portion, the inserted portion is formed of a hole penetrating a peripheral wall of the first electrode, and in the integration step, The internal thread formed on the insulating member provided inside the inserted portion is screwed with the external thread formed on the distal end portion of the second electrode, and the first electrode and the The second electrode is positioned and fixed. In this case, the energization process can be performed in a state in which the positional relationship between the inner wall surfaces of the first processing hole and the second processing hole and the outer peripheral surfaces of the first electrode and the second electrode is maintained favorably, so that the high quality can be further improved. Surface treatment.
在上述表面处理方法中,优选为,在所述通电工序中,在使封闭所述第1电极的顶端的第1封闭部面向所述第1处理孔的底面的状态下,经由第1内侧电极向所述第1电极通电,其中,所述第1内侧电极在所述第1电极的内部沿轴向延伸,并与所述第1封闭部电连接。在该情况下,能够在第1电极的封闭部与第1处理孔的底面之间良好地进行通电,因此,也对该表面有效地实施表面处理。In the above-mentioned surface treatment method, preferably, in the energization step, the first inner electrode is passed through the first inner electrode in a state in which the first closing portion that closes the distal end of the first electrode faces the bottom surface of the first treatment hole. The first electrode is energized, wherein the first inner electrode extends in the axial direction inside the first electrode, and is electrically connected to the first closing portion. In this case, since electricity can be satisfactorily conducted between the closed portion of the first electrode and the bottom surface of the first processing hole, the surface is also effectively surface-treated.
根据本发明的另一技术方案,提供一种表面处理方法,其使用由第1电极和第2电极构成的电极对处理孔的内壁面实施表面处理,该表面处理方法具有一体化工序和通电工序,其中,所述一体化工序为:在处理孔的内部,将所述第1电极和所述第2电极隔着绝缘部件以电绝缘的状态一体化;所述通电工序为:使电解处理液在所述处理孔的内部流通,并且在所述第1电极及所述第2电极与所述处理孔的内壁面之间通电,所述第1电极和所述第2电极是具有管状部分的中空体,在所述一体化工序中,将外径大于所述第2电极的外径的第1电极插入到由第1处理孔和第2处理孔构成的所述处理孔的所述第1处理孔之后,将所述第2电极插入到所述第2处理孔,并将该第2电极经由所述绝缘部件贯插于所述第1电极的贯插孔,其中,所述第1处理孔为有底的处理孔,所述第2处理孔为与该第1处理孔交叉的有底的处理孔,该贯插孔形成于所述第1电极的配置在所述第1处理孔和所述第2处理孔的交叉部的部分。According to another aspect of the present invention, there is provided a surface treatment method for subjecting an inner wall surface of a treatment hole to a surface treatment using an electrode consisting of a first electrode and a second electrode, the surface treatment method including an integration step and an electrification step. , wherein the integration step is: in the inside of the processing hole, the first electrode and the second electrode are integrated in a state of electrical insulation via an insulating member; It circulates inside the processing hole, and conducts electricity between the first electrode and the second electrode having a tubular portion and the inner wall surface of the processing hole. A hollow body, wherein in the integration step, a first electrode having an outer diameter larger than an outer diameter of the second electrode is inserted into the first processing hole composed of a first processing hole and a second processing hole After processing the hole, the second electrode is inserted into the second processing hole, and the second electrode is inserted into the through hole of the first electrode via the insulating member, wherein the first processing The hole is a bottomed processing hole, the second processing hole is a bottomed processing hole intersecting with the first processing hole, and the through hole is formed in the first electrode and disposed between the first processing hole and the first processing hole. The portion of the intersection of the second processing hole.
在处理孔的内部,通过如上述那样将第1电极和第2电极一体化的一体化工序,能够在使第1电极与第1处理孔的内壁面相向,并使第2电极与第2处理孔的内壁面相向的状态下进行通电工序。据此,不经过掩蔽等复杂的工序而能够通过共同的通电工序对第1处理孔和第2处理孔双方的内壁面实施表面处理。另外,由于第1电极和第2电极被绝缘,因此,在通电工序中,能够对第1电极和第2电极独立地供给电流来进行通电。据此,能够对第1处理孔和第2处理孔双方的内壁面大致均匀地进行表面处理。In the inside of the treatment hole, through the integration process of integrating the first electrode and the second electrode as described above, the first electrode and the inner wall surface of the first treatment hole can face each other, and the second electrode and the second treatment hole can be made to face each other. The energization step is performed in a state where the inner wall surfaces of the holes face each other. According to this, it is possible to perform surface treatment on the inner wall surfaces of both the first processing hole and the second processing hole by a common energization step without going through complicated steps such as masking. In addition, since the first electrode and the second electrode are insulated, in the energization step, the first electrode and the second electrode can be energized by independently supplying current. Accordingly, the inner wall surfaces of both the first processing hole and the second processing hole can be substantially uniformly surface-treated.
综上,根据该表面处理方法,即使在处理孔由具有交叉部的形状构成的情况下,也能够对该处理孔的内壁面高效且高质量地进行表面处理。In summary, according to this surface treatment method, even when the treatment hole is formed of a shape having an intersecting portion, the inner wall surface of the treatment hole can be surface-treated with high efficiency and high quality.
在上述表面处理方法中,优选为,在所述一体化工序中,将所述第2电极插入到直径比所述第1处理孔小的所述第2处理孔。在该情况下,抑制了第1处理孔和第2处理孔双方的内壁面产生电流密度差,从而容易对第1处理孔和第2处理孔双方的内壁面大致均匀地实施表面处理。In the above-described surface treatment method, preferably, in the integration step, the second electrode is inserted into the second treatment hole having a diameter smaller than that of the first treatment hole. In this case, the difference in current density between the inner wall surfaces of the first and second treatment holes is suppressed, and the inner wall surfaces of both the first and second treatment holes can be easily surface-treated substantially uniformly.
在上述表面处理方法中,优选为,所述第1电极的内径比所述第2电极的外径大,在所述通电工序中,在使封闭所述第1电极的顶端的封闭部面向第1处理孔的底面的状态下,经由内侧电极向所述第1电极通电,其中,该内侧电极通过所述第1电极的内周面和所述第2电极的外周面之间,沿该第1电极的轴向延伸,并与所述第1电极的所述封闭部电连接。在该情况下,通过从第1电极的内侧电极供给电流,能够使电流从第1电极的顶端部侧流向基端侧,因此,也能够有效地对第1处理孔的面向第1电极的封闭部的底面实施表面处理。In the above-mentioned surface treatment method, it is preferable that the inner diameter of the first electrode is larger than the outer diameter of the second electrode, and in the energization step, a sealing portion for sealing a distal end of the first electrode faces the first electrode. 1. In the state where the bottom surface of the hole is processed, the first electrode is energized through the inner electrode passing between the inner peripheral surface of the first electrode and the outer peripheral surface of the second electrode along the first electrode. The first electrode extends in the axial direction and is electrically connected to the closing portion of the first electrode. In this case, by supplying the current from the inner electrode of the first electrode, the current can be made to flow from the distal end side of the first electrode to the proximal end side, so that the surface of the first processing hole facing the first electrode can also be effectively closed The bottom surface of the part is surface-treated.
在上述表面处理方法中,优选为,在所述通电工序中,在使封闭所述第2电极的顶端的封闭部面向第2处理孔的底面的状态下,经由内侧电极向所述第2电极通电,其中,所述内侧电极在所述第2电极的内部沿轴向延伸,并与所述第2电极的所述封闭部电连接。在该情况下,通过从第2电极的内侧电极供给电流,能够使电流从第2电极的顶端部侧流向基端侧,因此,也能够对第2处理孔的面向第2电极的封闭部的底面有效地实施表面处理。In the above-described surface treatment method, preferably, in the energization step, the second electrode is directed to the second electrode via the inner electrode in a state in which the closing portion that closes the tip of the second electrode faces the bottom surface of the second treatment hole. energization, wherein the inner electrode extends in the axial direction inside the second electrode, and is electrically connected to the closed portion of the second electrode. In this case, by supplying the current from the inner electrode of the second electrode, the current can be made to flow from the distal end side of the second electrode to the proximal end side, and therefore, it is also possible to control the sealing portion of the second processing hole facing the second electrode. The bottom surface is effectively surface treated.
附图说明Description of drawings
图1是本发明的第1实施方式所涉及的表面处理装置和通过该表面处理装置对内壁进行表面处理的处理孔的主要部分概略结构图。FIG. 1 is a schematic configuration diagram of a main part of a surface treatment apparatus according to a first embodiment of the present invention and a treatment hole for surface treatment of an inner wall by the surface treatment apparatus.
图2是图1的主要部分放大图。FIG. 2 is an enlarged view of a main part of FIG. 1 .
图3是图1的表面处理装置的变形例所涉及的电极和处理孔的主要部分放大图。FIG. 3 is an enlarged view of a main part of an electrode and a processing hole according to a modification of the surface treatment apparatus of FIG. 1 .
图4是本发明的第2实施方式所涉及的表面处理装置和通过该表面处理装置对内壁进行表面处理的处理孔的主要部分概略结构图。4 is a schematic configuration diagram of a main part of a surface treatment apparatus according to a second embodiment of the present invention and a treatment hole for surface treatment of an inner wall by the surface treatment apparatus.
图5是图4的主要部分放大图。FIG. 5 is an enlarged view of the main part of FIG. 4 .
图6是本发明的第3实施方式所涉及的表面处理装置和通过该表面处理装置对内壁进行表面处理的处理孔的主要部分概略结构图。6 is a schematic configuration diagram of a main part of a surface treatment apparatus according to a third embodiment of the present invention and a treatment hole for surface treatment of an inner wall by the surface treatment apparatus.
图7是图6的主要部分放大图。FIG. 7 is an enlarged view of the main part of FIG. 6 .
图8是图7的电极的沿着VIII-VIII的向视剖视图。FIG. 8 is a cross-sectional view of the electrode of FIG. 7 taken along arrow VIII-VIII.
具体实施方式Detailed ways
列举优选的实施方式,参照附图对本发明所涉及的表面处理装置和表面处理方法详细地进行说明。此外,在下面的图中,对于起到相同或同样的功能和效果的结构要素标注相同的附图标记,有时省略重复的说明。The surface treatment apparatus and the surface treatment method according to the present invention will be described in detail with reference to the accompanying drawings by citing preferred embodiments. In addition, in the following drawings, the same code|symbol is attached|subjected to the component which has the same or the same function and effect, and the overlapping description may be abbreviate|omitted.
本发明所涉及的表面处理装置和表面处理方法可适宜地应用于例如电镀、电解蚀刻、电解脱脂、电沉积涂装、阳极氧化、阴极氧化、电解抛光、或这些处理的前处理或后处理等对被处理面进行电表面处理的情况。下面,对表面处理装置和表面处理方法进行电镀的例子进行说明,当然,并不限定于此。The surface treatment apparatus and the surface treatment method according to the present invention can be suitably applied to, for example, electroplating, electrolytic etching, electrolytic degreasing, electrodeposition coating, anodizing, cathodic oxidation, electropolishing, or pretreatment or posttreatment of these treatments, etc. The case where electrical surface treatment is performed on the surface to be treated. Hereinafter, an example in which electroplating is performed by a surface treatment apparatus and a surface treatment method will be described, but of course, it is not limited to this.
如图1所示,第1实施方式所涉及的表面处理装置10在处理孔12的内壁面形成电镀膜(未图示)。作为电镀膜的一例,能够列举出锌镍复合电镀膜等由锌合金构成的膜。在该情况下,能够使用由混合氯化锌、氯化镍、氯化铵等而制备的电镀浴构成的电解处理液来形成电镀膜。As shown in FIG. 1 , the
处理孔12例如形成于铸造用模具14,且是被供给用于冷却该铸造用模具14的冷却水的冷却通路,在延伸方向的中途具有弯折部16。即,处理孔12的第1直线状部20和第2直线状部24彼此的延伸方向不同,其中,第1直线状部20是从一个开口18到弯折部16之间的部分;第2直线状部24是从另一个开口22到弯折部16之间的部分。The
铸造用模具14由合金钢材等形成,向处理孔12内供给冷却水。据此,执行温度控制,以在成型时将铸造用模具14保持在最佳温度,或者在成型之后对铸造用模具14高效地进行冷却。由于在该处理孔12的内壁面附着有因与冷却水接触而产生的腐蚀生成物、因冷却水中的钙等而产生的堆积物等(下面,将它们统称为附着物),因此,若冷却水与铸造用模具14的热交换、冷却水的流通受到妨碍,则存在难以稳定地进行铸造用模具14的温度控制的担忧。因此,通过使用表面处理装置10在处理孔12的内壁面形成电镀膜,来抑制附着物附着在该内壁面。据此,能够将铸造用模具14的温度维持在最佳温度。The casting
表面处理装置10主要具有电极30、供液部31、排液部32、泵33、处理液罐34和未图示的外部电源。The
电极30由具有管状部分的中空的第1电极36和第2电极38构成,其中,所述管状部分例如由涂有铂的钛等形成。另外,第1电极36的从供液部31突出的部分被插入到处理孔12的第1直线状部20,第2电极38的从排液部32突出的部分被插入到处理孔12的第2直线状部24。在第1实施方式中,对于被插入到处理孔12的第1电极36和第2电极38,分别以处理孔12的开口18、22侧为基端侧、以弯折部16侧为顶端侧进行说明。The
如图2所示,在第1电极36的顶端部分、即第1顶端部40上设置有第1封闭部42,该第1封闭部42封闭第1电极36的管状部分的顶端。在第1电极36的内部设置有第1内侧电极44,该第1内侧电极44沿该第1电极36的轴向延伸且一端侧与第1封闭部42电连接。第1内侧电极44的另一端侧通过供液部31延伸到处理孔12的外侧,并与外部电源连接。As shown in FIG. 2 , the distal end portion of the
第2电极38与第1电极36同样地构成。即,在第2电极38的顶端部分、即第2顶端部46上设置有第2封闭部48,在第2电极38的内部设置有一端侧与第2封闭部48电连接的第2内侧电极50。第2内侧电极50的另一端侧通过排液部32延伸到处理孔12的外侧,并与外部电源连接。The
第1电极36和第2电极38通过各自的第1顶端部40和第2顶端部46在弯折部16的内部经由绝缘部件52抵接,从而以电绝缘的状态被一体化。即,在第1顶端部40和第2顶端部46中的于弯折部16的内部彼此抵接的部分分别设置有绝缘部件52。The
第1顶端部40和第2顶端部46的设置有绝缘部件52的位置根据处理孔12的第1直线状部20和第2直线状部24所成的角度θ等来进行调整。例如,如图2所示的处理孔12那样,在角度θ比较大的情况下,在第1顶端部40和第2顶端部46各自的顶端面侧(第1封闭部42和第2封闭部48)设置绝缘部件52即可。The positions at which the insulating
另外,例如,如图3所示的处理孔12那样,在角度θ比较小的情况下,将第1封闭部42配置成面向第2直线状部24的内壁面,在第1顶端部40的外周面设置绝缘部件52,在第2封闭部48的顶端面侧设置绝缘部件52即可。In addition, for example, as in the
此外,由于将绝缘部件52设置成能够使第1电极36与第2电极38电绝缘即可,因此,例如也可以将绝缘部件52仅设置于第1顶端部40和第2顶端部46中的任一方。In addition, since the insulating
供液部31以能够拆装的方式被安装在处理孔12的一个开口18,排液部32以能够拆装的方式被安装在处理孔12的另一个开口22。泵33通过供给配管54和供液部31向第1直线状部20的内壁面和第1电极36的外周面之间供给电解处理液。据此,电解处理液从处理孔12的一个开口18朝向另一个开口22,在第1电极36的外周面和第1直线状部20的内壁面之间以及第2电极38的外周面和第2直线状部24的内壁面之间流通后,通过排液部32从处理孔12排出到回收配管56。The
处理液罐34回收如上述那样通过排放部32从处理孔12排出到回收配管56的电解处理液。此外,被回收的电解处理液通过泵33再次被供给到供液部31,在表面处理装置10和处理孔12之间进行循环。The
此外,在代替由电镀浴构成的电解处理液而使例如脱脂清洗液、蚀刻液、污渍(smut)去除液、水等在处理孔内流通的情况下,只要利用泵33将由上述液体构成的处理液通过供液部31供给到处理孔12即可。另外,将通过排液部32从处理孔12排出的上述液体回收到处理液罐34中即可。In addition, in the case where, for example, a degreasing cleaning liquid, an etching liquid, a smut removal liquid, water, etc., are circulated in the processing hole instead of the electrolytic treatment liquid composed of a plating bath, the treatment composed of the above-mentioned liquid can be carried out by the
外部电源经由第1内侧电极44和第2内侧电极50向第1电极36和第2电极38供给电流。即,如图2中的箭头E所示,来自外部电源的电流分别经由第1内侧电极44和第2内侧电极50流到第1封闭部42和第2封闭部48。然后,电流沿着从第1封闭部42和第2封闭部48朝向第1电极36和第2电极38的基端侧的方向流动。据此,能够在第1电极36和第1直线状部20的内壁面之间以及第2电极38和第2直线状部24的内壁面之间分别产生电位差。The external power supply supplies current to the
第1实施方式所涉及的表面处理装置10基本上如上述那样构成。下面,对于第1实施方式所涉及的表面处理方法,列举使用表面处理装置10对处理孔12的内壁面实施作为表面处理的电镀处理的例子来进行说明。The
在该表面处理方法中,首先,进行一体化工序,即在处理孔12的内部,将第1电极36和第2电极38隔着绝缘部件52以电绝缘的状态一体化。具体而言,将第1电极36插入到处理孔12的第1直线状部20,并且将供液部31安装在处理孔12的一个开口18。同样,将第2电极38插入到处理孔12的第2直线状部24,并且将排液部32安装在处理孔12的另一个开口22。据此,在弯折部16的内部,经由绝缘部件52使第1顶端部40和第2顶端部46抵接,从而将第1电极36和第2电极38一体化。In this surface treatment method, first, an integration step is performed, that is, the
接着,通过供液部31和排液部32使脱脂清洗液(例如水溶性碱性清洗剂等)在处理孔12中流通,从而进行从该处理孔12的内壁面去除油成分的脱脂工序。Next, a degreasing step of removing oil components from the inner wall surface of the
接着,通过供液部31和排液部32使蚀刻液(例如,10重量%的盐酸水溶液或10重量%的硫酸水溶液等)在处理孔12中流通,从而进行从处理孔12的内壁面去除氧化膜的蚀刻处理工序。该蚀刻处理工序也可以从外部电源经由第1内侧电极44和第2内侧电极50向第1电极36和第2电极38供给电流,通过电解蚀刻(阳极电解)来进行。Next, an etching solution (for example, a 10 wt % hydrochloric acid aqueous solution or a 10 wt % sulfuric acid aqueous solution, etc.) is circulated through the
接着,通过经由供液部31和排液部32使污渍去除液(例如氢氧化钠和柠檬酸钠的混合溶液等)在处理孔12中流通,从而进行污渍去除工序。通过进行污渍去除工序,例如在上述蚀刻处理工序中去除氧化膜,即使不溶于水的金属成分(污渍)露出到处理孔12的内壁面的情况下,也能够从处理孔12内去除该污渍。Next, the stain removal step is performed by circulating a stain removing liquid (eg, a mixed solution of sodium hydroxide and sodium citrate, etc.) through the
此外,污渍去除工序也可以与蚀刻处理工序同样地通过电解处理(阴极电解或阳极电解)来进行。在该情况下,由于在处理孔12中污渍去除液被电解而产生氧,因此,能够进一步有效地去除污渍。In addition, the stain removal process can also be performed by electrolytic treatment (cathode electrolysis or anodic electrolysis) similarly to the etching treatment process. In this case, since the stain removing liquid is electrolyzed in the
接着,进行通电工序,即,通过供液部31和排液部32使电解处理液在处理孔12中流通,并且从外部电源向第1内侧电极44和第2内侧电极50供给电流,从而在第1电极36和第2电极38与处理孔12的内壁面之间通电。据此,能够在处理孔12的内壁面形成电镀膜。Next, an energization step is performed, that is, the electrolytic treatment liquid is circulated through the
因此,在第1实施方式中,通过使用如上述那样被一体化的第1电极36和第2电极38,能够在使第1电极36的外周面与第1直线状部20的内壁面相向,并且使第2电极38的外周面与第2直线状部24的内壁面相向的状态下进行通电工序。据此,能够不经过掩蔽等复杂的工序而通过共同的通电工序对处理孔12的第1直线状部20和第2直线状部24双方的内壁面实施表面处理。Therefore, in the first embodiment, by using the
而且,由于第1电极36和第2电极38被绝缘,因此能够对第1电极36和第2电极38分别独立地供给电流来进行通电。据此,例如与如下这样的情况相比,能够抑制在处理孔12的第1直线状部20的内壁面与第2直线状部24的内壁面之间产生电流分布差异,其中,该情况为,不将第1电极36和第2电极38绝缘,使电流从第1电极36经由第1顶端部40和第2顶端部46流到第2电极38的基端侧。其结果,能够对处理孔12的内壁面大致均匀地进行表面处理,从而能够形成厚度大致均匀的高质量的电镀膜。Furthermore, since the
综上,根据第1实施方式所涉及的表面处理装置10和表面处理方法,即使对于具有弯折部16的处理孔12,也能够高效且高质量地对该处理孔12的内壁面进行表面处理。这样一来,在处理孔12的内壁面形成大致均匀厚度的电镀膜,从而能够有效地抑制附着物附着在该内壁面上。在附着物对内壁面的附着或生成物在内壁面上的生成被抑制的处理孔12中,由于能够使冷却水在其内部良好地流通,或使该冷却水与铸造用模具14良好地进行热交换,因此,能够稳定地进行铸造用模具14的温度控制。进而,能够将铸造用模具14的温度维持在最佳温度。In conclusion, according to the
另外,如上所述,在表面处理装置10中,在第1电极36上设置第1封闭部42和第1内侧电极44,在第2电极38上设置第2封闭部48和第2内侧电极50。并且,在通电工序中,通过将电流经由第1内侧电极44供给到第1电极36,使电流从设置有第1封闭部42的第1顶端部40侧流向基端侧。另外,第2电极38同样,通过将电流经由第2内侧电极50供给到第2电极38,使电流从设置有第2封闭部48的第2顶端部46侧流向基端侧。据此,能够在第1封闭部42及第2封闭部48与弯折部16的内壁面之间良好地进行通电,因此,也能够对弯折部16的内壁面有效地实施表面处理。In addition, as described above, in the
因此,能够在弯折部16的内壁面上形成膜厚足够的电镀膜,从而能够有效地抑制附着物附着在该弯折部16的内壁面上或生成生成物。在铸造用模具14中,有时将处理孔12中的弯折部16配置在未图示的型腔形成面的附近。在该型腔形成面的附近,优选特别稳定地进行铸造用模具14的温度控制。如上所述,在附着物对内壁面的附着或生成物在内壁面上的生成被抑制的弯折部16中,能够使冷却水在其内部良好地流通,或使该冷却水与铸造用模具14良好地进行热交换。因此,例如,即使在处理孔12中的弯折部16被配置在型腔形成面附近的情况下,也能够稳定地进行铸造用模具14的型腔形成面附近的温度控制。Therefore, a plating film having a sufficient thickness can be formed on the inner wall surface of the folded
接着,边参照图4和图5边对第2实施方式所涉及的表面处理装置60进行说明。表面处理装置60在处理孔62的内壁面上形成电镀膜(未图示)。Next, the
如图4所示,处理孔62也与上述处理孔12同样形成于铸造用模具14,且是被供给用于冷却该铸造用模具14的冷却水的冷却通路。该处理孔62由有底的第1处理孔64和直径比该第1处理孔64小的第2处理孔66构成。在第2处理孔66中,位于与朝铸造用模具14的外部开口的开口67相反的一侧的开口68被设置于第1处理孔64的内壁面。即,处理孔62具有由第1处理孔64和从该第1处理孔64分支的第2处理孔66形成的分支部70。因此,处理孔62也具有延伸方向互不相同的直线状部(第1处理孔64和第2处理孔66)。As shown in FIG. 4 , the
表面处理装置60除了代替电极30而具有电极72之外,与第1实施方式所涉及的表面处理装置10同样地构成。电极72由具有管状部分的中空的第1电极74和第2电极76构成,其中,所述管状部分例如由涂有铂的钛等形成。第1电极74被插入到第1处理孔64,外径比该第1电极74的外径小的第2电极76被插入到第2处理孔66。The
在第2实施方式中,对于被插入到第1处理孔64的第1电极74,将该第1处理孔64的开口77侧作为基端侧,将第1处理孔64的底面78侧作为顶端侧来进行说明。另外,对于被插入到第2处理孔66的第2电极76,将该第2处理孔66的开口67侧作为基端侧,将另一个开口68侧作为顶端侧来进行说明。In the second embodiment, for the
如图5所示,第1电极74除了在面向第2处理孔66的开口68的周壁上设置有被插入部80之外,与上述第1电极36同样地构成。即,在作为第1电极74的顶端部分的第1顶端部40上设置有第1封闭部42,在第1电极74的内部设置有第1内侧电极44。被插入部80由贯通第1电极74的面向第2处理孔66的开口68的周壁的孔构成,在内部设置有环状的绝缘部件82。在该绝缘部件82的内周形成有内螺纹82a。As shown in FIG. 5 , the
第2电极76由管状体构成,在作为该第2电极76的顶端部分的第2顶端部84的外周面形成有能够与绝缘部件82的内螺纹82a旋合的外螺纹84a。第2电极76的基端侧经由排液部32向处理孔62的外侧延伸,并与外部电源连接。The
通过将第2电极76的第2顶端部84插入到第1电极74的被插入部80中,第1电极74和第2电极76被一体化。此时,通过使配设于被插入部80内的绝缘部件82的内螺纹82a与第2顶端部84的外螺纹84a旋合,第1电极74和第2电极76被定位固定。The
下面,对于第2实施方式所涉及的表面处理方法,列举使用表面处理装置60对处理孔62的内壁表面进行作为表面处理的电镀处理的例子来进行说明。Next, the surface treatment method according to the second embodiment will be described by taking an example in which the inner wall surface of the
在该表面处理方法中,首先,进行一体化工序,即在处理孔62的内部,将第1电极74和第2电极76隔着绝缘部件82以电绝缘的状态一体化。具体而言,将第1电极74插入到第1处理孔64,使第1封闭部42面向第1处理孔64的底面78,并且将供液部31安装在第1处理孔64的开口77。接着,将第2电极76插入到第2处理孔66,使第2顶端部84的外螺纹84a与绝缘部件82的内螺纹82a旋合。据此,在将第1电极74和第2电极76一体化之后,将排液部32安装在第2处理孔66的开口67。In this surface treatment method, first, an integration step is performed, that is, the
接着,与第1实施方式所涉及的表面处理方法同样地进行脱脂工序、蚀刻处理工序、污渍去除工序后,进行用于在处理孔62的内壁面形成电镀膜的通电工序。在通电工序中,经由供液部31和排液部32使电解处理液在处理孔62中流通,并且在使第1封闭部42面向第1处理孔64的底面78的状态下,从外部电源经由第1内侧电极44向第1电极74和第2电极76供给电流。这样一来,通过在第1电极74及第2电极76与处理孔62的内壁面之间通电,能够在处理孔62的内壁面形成电镀膜。Next, a degreasing step, an etching treatment step, and a stain removal step are performed in the same manner as in the surface treatment method according to the first embodiment, and then an energization step for forming a plated film on the inner wall surface of the
因此,在第2实施方式中,通过使用如上述那样被一体化的第1电极74和第2电极76,能够在使第1电极74的外周面与第1处理孔64的内壁面相向,并且使第2电极76的外周面与第2处理孔66的内壁面相向的状态下进行通电工序。据此,不经过掩蔽等复杂的工序而能够通过共同的通电工序对第1处理孔64和第2处理孔66双方的内壁面实施表面处理。Therefore, in the second embodiment, by using the
而且,由于第1电极74与第2电极76被绝缘,因此,能够对处理孔62的内壁面大致均匀地进行表面处理,形成厚度大致均匀且高质量的电镀膜。Furthermore, since the
综上,根据第2实施方式所涉及的表面处理装置60和表面处理方法,即使对于具有分支部70的处理孔62,也能够对该处理孔62的内壁面高效且高质量地进行表面处理。这样一来,在处理孔62的内壁面形成大致均匀厚度的电镀膜,从而能够有效地抑制附着物附着在该内壁面上。In conclusion, according to the
如上所述,在一体化工序中,通过内螺纹82a和外螺纹84a的旋合,第1电极74和第2电极76被定位固定。据此,能够在良好地维持第1处理孔64及第2处理孔66各自的内壁面与第1电极74及第2电极76的外周面的位置关系的状态下进行通电工序,因此,能够进一步高质量地进行表面处理。As described above, in the integration process, the
此外,在第2实施方式所涉及的表面处理装置60中,第1电极74的外径大于所述第2电极76的外径,被插入部80由贯通第1电极74的周壁的孔构成。并且,在设置于该被插入部80的内部的绝缘部件82上形成有内螺纹82a,在第2电极76的顶端部形成有外螺纹84a。但是,并不特别限定于这些。例如,被插入部80为了使第1电极74和第2电极76一体化而构成为能够插入第2顶端部84的结构即可。另外,第1电极74和第2电极76也可以通过被插入部80和第2顶端部84经由绝缘部件82嵌合等方式而被定位固定。In addition, in the
另外,如上所述,在第2实施方式中,在第1电极74上设置第1封闭部42和第1内侧电极44,并且在使第1封闭部42面向第1处理孔64的底面78的状态下,经由第1内侧电极44向第1电极74供给电流。据此,能够在第1封闭部42和第1处理孔64的底面78之间良好地进行通电,因此,也能够对该底面78有效地实施表面处理。In addition, as described above, in the second embodiment, the
因此,由于在第1处理孔64的底面78上形成膜厚足够的电镀膜,能够有效地抑制附着物附着在该底面78上,因而,即使在例如第1处理孔64的底面78配置在铸造用模具14的型腔形成面附近的情况下,也能够稳定地进行该型腔形成面附近的温度控制。Therefore, since a plated film with a sufficient film thickness is formed on the
接着,边参照图6~图8边对第3实施方式所涉及的表面处理装置90进行说明。表面处理装置90在处理孔92的内壁面形成电镀膜(未图示)。Next, the
如图6所示,处理孔92也与上述处理孔12同样,形成于铸造用模具14,是供给用于冷却该铸造用模具14的冷却水的冷却通路。该处理孔92由多个(本实施方式中为5个)第1处理孔94和与该第1处理孔94交叉的多个(本实施方式中为2个)第2处理孔96构成。即,处理孔92具有第1处理孔94与第2处理孔96的交叉部98。因此,处理孔92也具有延伸方向互不相同的直线状部(第1处理孔94和第2处理孔96)。As shown in FIG. 6 , the
各第1处理孔94是沿图6的箭头X1X2方向延伸且在其一端侧(箭头X1侧)设置有底面100的有底孔。各第2处理孔96是沿着图6的箭头Y1Y2方向延伸且在其一端侧(箭头Y1侧)设置有底面102的有底孔。另外,第2处理孔96的直径比第1处理孔94的直径小,该第2处理孔96被配设成与第1处理孔94在靠近该第1处理孔94的底面100的位置交叉。此外,在本实施方式中,使第2处理孔96的直径比第1处理孔94的直径小,但并不限定于此,第2处理孔96的直径也可以与第1处理孔94直径相同。Each of the first processing holes 94 is a bottomed hole extending in the direction of arrow X1X2 in FIG. 6 and provided with a
表面处理装置90除了如下结构之外,与第1实施方式的表面处理装置10同样地构成,该结构为:代替上述电极30而具有电极104,代替供液部31和排液部32而具有与第1处理孔94数量相同的第1供排部106和与第2处理孔96数量相同的第2供排部108,代替泵33和处理液罐34而具有未图示的处理液供排机构。The
电极104由与第1处理孔94数量相同的第1电极110和与第2处理孔96数量相同的第2电极112构成。第1电极110和第2电极112分别是具有管状部分的中空体,该管状部分由例如涂有铂的钛等形成。第1电极110被插入到第1处理孔94,外径小于该第1电极110的内径的第2电极112被插入到第2处理孔96。The
在第三实施方式中,对于分别被插入到第1处理孔94和第2处理孔96的第1电极110和第2电极112,以该第1处理孔94和第2处理孔96的开口114、116侧为基端侧且以底面100、102侧为顶端侧来进行说明。In the third embodiment, for the
如图6~图8所示,第1电极110除了设置有处理液流入口118和贯插孔120之外,与上述第1电极36同样地构成。即,在作为第1电极110的顶端部分的第1顶端部40上设置有第1封闭部42,在第1电极110的内部设置有第1内侧电极44。As shown in FIGS. 6 to 8 , the
处理液流入口118贯通形成于第1电极110的比第1封闭部42稍靠基端侧的周壁,在周向上隔开间隔而设置有多个。贯插孔120被设置成沿第2处理孔96的延伸方向贯通被插入到第1处理孔94的第1电极110的配置于交叉部98的部分。The processing
第2电极112除了设置有处理液流入口122之外,与上述第2电极38同样地构成。即,在作为第2电极112的顶端部分的第2顶端部46上设置有第2封闭部48,在第2电极112的内部设置有第2内侧电极50。处理液流入口122贯通形成于第2电极112的比第2封闭部48稍靠基端侧的周壁,在周向上隔开间隔而设置有多个。The
通过将第2电极112贯插到第1电极110的贯插孔120中,第1电极110和第2电极112被一体化。此时,第2电极112的被贯插到贯插孔120中的部分的外周面由绝缘部件124覆盖。即,通过在贯插孔120的内周面与第2电极112的外周面之间夹设有筒状的绝缘部件124,第1电极110和第2电极112被电绝缘。The
另外,如图8所示,第1电极110的第1内侧电极44以避开经由贯插孔120被贯插到第1电极110的第2电极112和绝缘部件124的方式被配设在第1电极110的内周面与第2电极112的外周面之间。In addition, as shown in FIG. 8 , the first
第1供排部106以能够拆装的方式被安装在第1处理孔94的开口114,第2供排部108以能够拆装的方式被安装在第2处理孔96的开口116。处理液供排机构经由第1供排部106向第1处理孔94的内壁面与第1电极110的外周面之间供给电解处理液。同样,通过第2供排部108向第2处理孔96的内壁面与第2电极112的外周面之间供给电解处理液。此外,处理液供排机构、第1供排部106和第2供排部108例如能够使用日本发明专利公开公报特开2015-30897号所记载的结构,因此,省略其详细的说明。The first supply and discharge
这样一来,被供给到第1处理孔94和第2处理孔96的电解处理液通过第1电极110和第2电极112各自的外周面与处理孔92的内周面之间,流向第1电极110和第2电极112的顶端侧。然后,如图7中箭头F所示,从处理液流入口118、122流入到第1电极110和第2电极112各自的内部,在该第1电极110和第2电极112的内部流通至基端侧之后,经由第1供排部106和第2供排部108从处理孔92排出。In this way, the electrolytic treatment solution supplied to the
此外,电解处理液也可以构成为从第1供排部106和第2供排部108供给到第1电极110和第2电极112的内部,通过处理液流入口118、122流出到第1电极110和第2电极112的外部的第1处理孔94和第2处理孔96。In addition, the electrolytic treatment liquid may be supplied from the first supply and
下面,对于第3实施方式所涉及的表面处理方法,列举使用表面处理装置90对处理孔92的内壁表面进行作为表面处理的电镀处理的例子来进行说明。Hereinafter, the surface treatment method according to the third embodiment will be described by taking an example in which the inner wall surface of the
在该表面处理方法中,首先,进行一体化工序,即在处理孔92的内部,将第1电极110和第2电极112隔着绝缘部件124以电绝缘的状态一体化。具体而言,将第1电极110插入到多个第1处理孔94的各个中,使第1封闭部42面向第1处理孔94的底面100,并且在第1处理孔94的开口114安装第1供排部106。此时,分别设置于多个第1电极110的多个贯插孔120沿着第2处理孔96的延伸方向以同轴的方式被配置于交叉部98的内部。In this surface treatment method, first, an integration step is performed, that is, the
接着,通过将第2电极112插入到各第2处理孔96,从而将第2电极112贯插于第1电极110的贯插孔120。此时,在第1电极110的贯插孔120的内部、或第2电极112的外周面中被插入到贯插孔120的部分设置绝缘部件124。据此,将各第2电极112和多个第1电极110隔着绝缘部件124以电绝缘的状态一体化,在此之后,将第2供排部108安装于第2处理孔96的开口116。Next, the
接着,与第1实施方式所涉及的表面处理方法同样,在进行脱脂工序、蚀刻处理工序、污渍去除工序之后,进行用于在处理孔92的内壁面形成电镀膜的通电工序。在通电工序中,使电解处理液经由第1供排部106和第2供排部108在第1处理孔94和第2处理孔96中流通。与此同时,在使第1封闭部42和第2封闭部48分别面向第1处理孔94和第2处理孔96的底面100、102的状态下,从外部电源向第1内侧电极44和第2内侧电极50供给电流。这样一来,通过在第1电极110及第2电极112与第1处理孔94及第2处理孔96的内壁面之间分别通电,从而能够在处理孔92的内壁面形成电镀膜。Next, similarly to the surface treatment method according to the first embodiment, after the degreasing step, the etching treatment step, and the stain removal step, an energization step for forming a plated film on the inner wall surface of the
因此,在第三实施方式中,通过使用如上述那样被一体化的第1电极110和第2电极112,能够在使第1电极110的外周面与第1处理孔94的内壁面相向、并且使第2电极112的外周面与第2处理孔96的内壁面相向的状态下进行通电工序。据此,不经过掩蔽等复杂的工序而能够通过共同的通电工序对第1处理孔94和第2处理孔96双方的内壁面实施表面处理。Therefore, in the third embodiment, by using the
而且,由于第1电极110与第2电极112被绝缘,因此,能够对处理孔92的内壁面大致均匀地进行表面处理,从而形成厚度大致均匀且高质量的电镀膜。Furthermore, since the
综上,根据第3实施方式所涉及的表面处理装置90和表面处理方法,即使对于具有交叉部98的处理孔92,也能够对该处理孔92的内壁面高效且高质量地进行表面处理。这样一来,在处理孔92的内壁面形成大致均匀厚度的电镀膜,从而能够有效地抑制附着物附着在该内壁面上。In conclusion, according to the
如上所述,在第三实施方式中,对应于比第1电极110的外径小的第2电极112的外径,使第2电极112的外周面与直径比第1处理孔94小的第2处理孔96的内壁面相向。据此,能够使第1处理孔94的内壁面与第1电极110的外周面的距离、和第2处理孔96的内壁面与第2电极112的外周面的距离大致一定。因此,抑制了第1处理孔94和第2处理孔96双方的内壁面产生电流密度差,从而容易对第1处理孔94和第2处理孔96双方的内壁面大致均匀地实施表面处理。As described above, in the third embodiment, the outer peripheral surface and diameter of the
如上所述,在第三实施方式中,在第1电极110设置第1封闭部42和第1内侧电极44,并且使第1封闭部42面向第1处理孔94的底面100的状态下,经由第1内侧电极44向第1电极110供给电流。据此,能够在第1封闭部42和第1处理孔94的底面100之间良好地进行通电,因此,也能够有效地对该底面100实施表面处理。As described above, in the third embodiment, the
另外,由于第2电极112也同样地构成,从而能够在第2封闭部48和第2处理孔96的底面102之间良好地进行通电,因此,也能够有效地对该底面102实施表面处理。In addition, since the
因此,在第1处理孔94和第2处理孔96的底面100、102形成膜厚足够的电镀膜,能够有效地抑制附着物附着在该底面100、102上。因此,例如,通过将第1处理孔94的底面100配置在铸造用模具14的型腔形成面的附近,能够稳定地进行该型腔形成面附近的温度控制。Therefore, plating films with sufficient film thicknesses are formed on the bottom surfaces 100 and 102 of the
本发明并不特别限定于上述实施方式,在不脱离其主旨的范围内能够进行各种变形。The present invention is not particularly limited to the above-described embodiments, and various modifications can be made without departing from the gist of the present invention.
例如,在上述实施方式中,在第1电极36、74、110设置第1内侧电极44,在第2电极38、112设置第2内侧电极50,但并不特别限定于此,第1电极36、74、110和第2电极38、112也可以不具有第1内侧电极44和第2内侧电极50。在该情况下,第1电极74、110也可以不具有第1封闭部42,第2电极112也可以不具有第2封闭部48。For example, in the above-described embodiment, the first
[附图标记说明][Description of reference numerals]
10、60、90:表面处理装置;12、62、92:处理孔;14:铸造用模具;16:弯折部;18、22、67、68、77、114、116:开口;20:第1直线状部;24:第2直线状部;30、72、104:电极;31:供液部;32:排液部;36、74、110:第1电极;38、76、112:第2电极;40:第1顶端部;42:第1封闭部;44:第1内侧电极;46、84:第2顶端部;48:第2封闭部;50:第2内侧电极;52、82、124:绝缘部件;10, 60, 90: surface treatment device; 12, 62, 92: processing hole; 14: casting mold; 16: bending part; 18, 22, 67, 68, 77, 114, 116: opening; 20: No. 1 linear part; 24: second linear part; 30, 72, 104: electrode; 31: liquid supply part; 32: liquid discharge part; 36, 74, 110: first electrode; 38, 76, 112: first electrode 2 electrodes; 40: first tip portion; 42: first closing portion; 44: first inner electrode; 46, 84: second tip portion; 48: second closing portion; 50: second inner electrode; 52, 82 , 124: insulating parts;
64、94:第1处理孔;66、96:第2处理孔;70:分支部;78、100、102:底面;80:被插入部;82a:内螺纹;84a:外螺纹;98:交叉部;106:第1供排部;108:第2供排部;118、122:处理液流入口;120:贯插孔。64, 94: 1st processing hole; 66, 96: 2nd processing hole; 70: branch part; 78, 100, 102: bottom surface; 80: inserted part; 82a: female thread; 84a: male thread; 98: cross part; 106: first supply and discharge part; 108: second supply and discharge part; 118, 122: treatment liquid inlet; 120: through hole.
Claims (18)
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| PCT/JP2019/003648 WO2019151487A1 (en) | 2018-02-02 | 2019-02-01 | Surface treatment device and surface treatment method |
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| CN111670271B (en) | 2022-01-14 |
| JP6865304B2 (en) | 2021-04-28 |
| JPWO2019151487A1 (en) | 2020-12-17 |
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