Disclosure of Invention
In order to solve the defects of the prior art, the invention provides the water-absorbing core body with no glue reverse absorption and the preparation process thereof, which have good penetration effect and high water absorption efficiency, ensure that the skin surface is kept dry and comfortable, and greatly reduce the problems of red buttocks, allergy, microorganism breeding and the like.
In order to achieve the purpose, the technical scheme provided by the invention is as follows:
The invention relates to a glue-free reverse absorption water absorption core body, which comprises an upper ES chemical fiber layer, a middle high polymer water absorption resin layer and a lower wood pulp ES chemical fiber mixed layer, wherein the middle high polymer water absorption resin layer is wrapped in the middle by the upper ES chemical fiber layer and the lower wood pulp ES chemical fiber mixed layer, and the upper ES chemical fiber layer and the lower wood pulp ES chemical fiber mixed layer are formed into an integrated structure through heat treatment.
Preferably, the particle size of the high polymer water-absorbing resin in the middle high polymer water-absorbing resin layer is 100-300 mesh.
Preferably, the gram weight of the upper ES chemical fiber layer is 20-60 g/m 2, the gram weight of the lower wood pulp ES chemical fiber mixed layer is 50-200 g/m 2, and the dosage of the high polymer water-absorbent resin in the middle high polymer water-absorbent resin layer is 100-400 g/m 2.
Preferably, the thickness of the lower wood pulp ES chemical fiber mixed layer is larger than that of the upper ES chemical fiber layer.
Preferably, the high polymer water-absorbing resin layer comprises a first high polymer water-absorbing resin and a second high polymer water-absorbing resin, wherein the first high polymer water-absorbing resin permeates the lower surface of the upper ES chemical fiber layer, and the second high polymer water-absorbing resin permeates the upper surface of the lower wood pulp ES chemical fiber mixed layer.
Preferably, the particle size of the first high polymer water-absorbing resin is 120-300 meshes, the particle size of the second high polymer water-absorbing resin is 100-120 meshes, the water absorption rate of the first high polymer water-absorbing resin is 50-180 times, the water absorption rate of the second high polymer water-absorbing resin is 110-260 times, the dosage of the first high polymer water-absorbing resin is 50-200 g/m 2, and the dosage of the second high polymer water-absorbing resin is 50-200 g/m 2.
A preparation process of a non-adhesive reverse absorption water absorption core body comprises the following steps:
paving the wood pulp ES chemical fiber mixed layer on a workbench, arranging an exhaust fan and a vibrator below the wood pulp ES chemical fiber mixed layer, and uniformly spraying high-molecular water-absorbent resin on the upper side surface of the wood pulp ES chemical fiber mixed layer;
Under the action of an exhaust fan and a vibrator, the high molecular water-absorbing resin permeates into the wood pulp ES chemical fiber mixed layer;
paving the ES chemical fiber layer above the wood pulp ES chemical fiber mixed layer under the action of an exhaust fan;
(4) And (3) performing heat treatment to enable the ES fibers on the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer to be mutually adhered to form a formed body, cooling, rolling and cutting to obtain the water-absorbing core body with no glue reverse absorption.
Preferably, in the step (4), the temperature of the heating treatment is 100-150 ℃.
A preparation process of a non-adhesive reverse absorption water absorption core body comprises the following steps:
(1) Paving an ES chemical fiber layer and a wood pulp ES chemical fiber mixed layer on a workbench, arranging an exhaust fan and a vibrator below the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer, uniformly spraying a first polymer water-absorbent resin on the upper side surface of the ES chemical fiber layer, and uniformly spraying a second polymer water-absorbent resin on the upper side surface of the wood pulp ES chemical fiber mixed layer;
(2) Under the action of an exhaust fan and a vibrator, the first high-molecular water-absorbent resin permeates into the ES chemical fiber layer, and the second high-molecular water-absorbent resin permeates into the wood pulp ES chemical fiber mixed layer;
(3) The upper side surface of the ES chemical fiber layer is turned downwards, and the ES chemical fiber layer is paved above the wood pulp ES chemical fiber mixed layer under the action of an exhaust fan;
(4) And (3) performing heat treatment to enable the ES fibers on the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer to be mutually adhered to form a formed body, cooling, rolling and cutting to obtain the water-absorbing core body with no glue reverse absorption.
Preferably, in the step (4), the temperature of the heating treatment is 100-150 ℃.
Compared with the prior art, the technical scheme provided by the invention has the following beneficial effects:
Compared with the bonding condition of adopting a bonding agent, the invention has the advantages that the liquid infiltration speed is high, the dryness of the upper layer is ensured to the greatest extent, and the manufacturing is more environment-friendly and sanitary.
The invention has no adhesive in the middle, so that liquid can quickly infiltrate from the ES chemical fiber layer to the lower wood pulp ES chemical fiber mixed layer, the middle polymer water-absorbing resin layer absorbs in the infiltration process, the diffusion effect always exists in the liquid infiltration process, the liquid which has permeated to the wood pulp ES chemical fiber mixed layer can be completely diffused after reaching the lower wood pulp ES chemical fiber mixed layer, and the liquid which has permeated to the wood pulp ES chemical fiber mixed layer can reversely infiltrate from the two ends of the water-absorbing core to the middle polymer water-absorbing resin layer, thus the moisture can be quickly absorbed, and the absorption efficiency of the water-absorbing core is improved.
The invention adopts the macromolecule water-absorbent resin with different grain sizes, the grain size of the macromolecule water-absorbent resin at the upper side is large, and the grain size of the macromolecule water-absorbent resin at the lower side is small, so that the gap between the macromolecule water-absorbent resins at the upper side is large, and the liquid can be quickly infiltrated downwards. Meanwhile, the macromolecule water-absorbent resin on the upper side is relatively weak, so that the macromolecule water-absorbent resin on the upper part of the macromolecule water-absorbent resin is not expanded rapidly to close gaps among particles when liquid seeps downwards, the liquid seeps downwards conveniently, and the upper ES chemical fiber layer is kept in a dry state, so that a human body can feel more comfortable when wearing the macromolecule water-absorbent resin.
Detailed Description
The invention will be further understood by reference to the following examples which are given to illustrate the invention but are not intended to limit the scope of the invention.
Examples
As shown in fig. 1, the present embodiment relates to a glue-free reverse absorption absorbent core, which includes an upper layer ES chemical fiber layer 1, a middle polymer absorbent resin layer 2 and a lower layer wood pulp ES chemical fiber mixed layer 3, wherein the upper layer ES chemical fiber layer 1 and the lower layer wood pulp ES chemical fiber mixed layer 3 wrap the middle polymer absorbent resin layer 2 in the middle, and the upper layer ES chemical fiber layer 1 and the lower layer wood pulp ES chemical fiber mixed layer 3 are formed into an integral structure through heat treatment.
The thickness of the lower wood pulp ES chemical fiber mixed layer 3 is larger than that of the upper ES chemical fiber layer 1. The particle size of the high molecular water-absorbing resin in the middle high molecular water-absorbing resin layer 2 is 100mesh. The gram weight of the upper ES chemical fiber layer 1 is 30g/m 2, the gram weight of the lower wood pulp ES chemical fiber mixed layer 3 is 90g/m 2, and the dosage of the high polymer water-absorbent resin in the middle high polymer water-absorbent resin layer 2 is 250g/m 2.
The preparation process of the water-absorbing core body for the non-adhesive reverse absorption comprises the following steps:
(1) Paving the wood pulp ES chemical fiber mixed layer on a workbench, arranging an exhaust fan and a vibrator below the wood pulp ES chemical fiber mixed layer, and uniformly spraying high-molecular water-absorbent resin on the upper side surface of the wood pulp ES chemical fiber mixed layer;
(2) Under the action of an exhaust fan and a vibrator, the high molecular water-absorbing resin permeates into the wood pulp ES chemical fiber mixed layer;
(3) Paving the ES chemical fiber layer above the wood pulp ES chemical fiber mixed layer under the action of an exhaust fan;
(4) And (3) performing heat treatment to enable the ES fibers on the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer to be mutually adhered to form a formed body, cooling, rolling and cutting to obtain the water-absorbing core body with no glue reverse absorption.
In the step (4), the temperature of the heat treatment was 120 ℃.
As shown in fig. 3, above the middle of the ES chemical fiber layer 1 on the upper layer of the non-adhesive reverse absorption water absorption core, 80ml of the test solution is poured, the test solution rapidly permeates downwards and diffuses to the periphery, most of the upper ES chemical fiber layer 1 keeps dry all the time, the test solution is absorbed in the middle high molecular water absorption resin layer 2, and the test solution permeated into the lower wood pulp ES chemical fiber mixed layer 3 begins to reversely permeate into the middle high molecular water absorption resin layer 2 to be absorbed.
According to the method for measuring the slip quantity in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the water absorbent core body with the glue-free reverse absorption is manufactured into a baby diaper as a sample, the sample is placed on an inclined plate with the inclination of (30+/-2) DEG, 100mm is taken from two ends of the center point of the water absorbent core body with the glue-free reverse absorption in the sample respectively towards the upper side to serve as a test area, 50ml of test solution is measured, the surface of the test solution free flow channel sample flows along the inclined plane, and the slip quantity is finally measured to be 11.6ml through multiple experiments and is lower than 20ml of the national standard.
According to the method for measuring the rewet amount in the national standard GB/T28004-2011 paper diapers (sheets and pads) of the people's republic of China, the water absorbent core body with the reverse absorption without glue is manufactured into a medium-sized baby paper diaper serving as a sample, 60ml of test solution is freely flowed to the surface of the center of the sample through a funnel, the same amount of test solution is injected into the funnel again in 5 minutes, a plurality of layers of filter paper with the diameter of 100mm are placed on the surface of the sample in 10 minutes, meanwhile, a standard pressing block is pressed on the filter paper, the standard pressing block is removed in 1 minute of pressing, the measurement mode is adopted for multiple tests, and the average rewet amount of the finally measured sample is 5.7g and is lower than 10g of the national standard.
According to the method for measuring the leakage amount in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the water absorbent core body with no glue reverse absorption is manufactured into an adult paper diaper which is used as a sample, the sample is laid on a horizontal table top, 80ml of test solution is measured by a separating funnel, the test solution is poured into the central position of the sample at a constant speed within 30 seconds, and after 5 minutes, no liquid leakage is observed around the sample.
Examples
As shown in fig. 2, the present embodiment relates to a non-adhesive reverse absorption absorbent core, which includes an upper layer ES chemical fiber layer 1, a middle polymer absorbent resin layer 2 and a lower layer wood pulp ES chemical fiber mixed layer 3, wherein the upper layer ES chemical fiber layer 1 and the lower layer wood pulp ES chemical fiber mixed layer 3 wrap the middle polymer absorbent resin layer 2 in the middle, and the upper layer ES chemical fiber layer 1 and the lower layer wood pulp ES chemical fiber mixed layer 3 are formed into an integral structure through heat treatment.
The thickness of the lower wood pulp ES chemical fiber mixed layer 3 is larger than that of the upper ES chemical fiber layer 1. The gram weight of the upper ES chemical fiber layer 1 is 30g/m 2, and the gram weight of the lower wood pulp ES chemical fiber mixed layer 3 is 90g/m 2.
The high polymer water-absorbing resin layer 2 comprises a first high polymer water-absorbing resin 21 and a second high polymer water-absorbing resin 22, wherein the first high polymer water-absorbing resin 21 permeates the lower surface of the upper ES chemical fiber layer 1, and the second high polymer water-absorbing resin 22 permeates the upper surface of the lower wood pulp ES chemical fiber mixed layer 3.
The particle size of the first high polymer water absorbent resin 21 is 200 meshes, the particle size of the second high polymer water absorbent resin is 100 meshes, the water absorption rate of the first high polymer water absorbent resin is 100 times, the water absorption rate of the second high polymer water absorbent resin is 200 times, the dosage of the first high polymer water absorbent resin is 100g/m 2, and the dosage of the second high polymer water absorbent resin is 100g/m 2.
The preparation process of the water-absorbing core body for the non-adhesive reverse absorption comprises the following steps:
(1) Paving an ES chemical fiber layer and a wood pulp ES chemical fiber mixed layer on a workbench, arranging an exhaust fan and a vibrator below the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer, uniformly spraying a first polymer water-absorbent resin on the upper side surface of the ES chemical fiber layer, and uniformly spraying a second polymer water-absorbent resin on the upper side surface of the wood pulp ES chemical fiber mixed layer;
(2) Under the action of an exhaust fan and a vibrator, the first high-molecular water-absorbent resin permeates into the ES chemical fiber layer, and the second high-molecular water-absorbent resin permeates into the wood pulp ES chemical fiber mixed layer;
(3) The upper side surface of the ES chemical fiber layer is turned downwards, and the ES chemical fiber layer is paved above the wood pulp ES chemical fiber mixed layer under the action of an exhaust fan;
(4) And (3) performing heat treatment to enable the ES fibers on the ES chemical fiber layer and the wood pulp ES chemical fiber mixed layer to be mutually adhered to form a formed body, cooling, rolling and cutting to obtain the water-absorbing core body with no glue reverse absorption.
In the step (4), the temperature of the heat treatment was 120 ℃.
As shown in fig. 3, above the middle of the ES chemical fiber layer 1 on the upper layer of the non-adhesive reverse absorption water absorption core, 80ml of the test solution is poured, the test solution rapidly permeates downwards and diffuses to the periphery, most of the upper ES chemical fiber layer 1 keeps dry all the time, the test solution is absorbed in the middle high molecular water absorption resin layer 2, and the test solution permeated into the lower wood pulp ES chemical fiber mixed layer 3 begins to reversely permeate into the middle high molecular water absorption resin layer 2 to be absorbed.
According to the method for measuring the slip quantity in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the water absorbent core body with the glue-free reverse absorption is manufactured into a baby diaper as a sample, the sample is placed on an inclined plate with the inclination of (30+/-2) DEG, 100mm is taken from two ends of the center point of the water absorbent core body with the glue-free reverse absorption in the sample respectively towards the upper side to serve as a test area, 50ml of test solution is measured, the surface of the test solution free flow channel sample flows along the inclined plane, and the slip quantity is finally measured to be 9.7ml through multiple experiments and is lower than 20ml of the national standard.
According to the method for measuring the rewet amount in the national standard GB/T28004-2011 paper diapers (sheets and pads) of the people's republic of China, the water absorbent core body with the reverse absorption without glue is manufactured into a medium-sized baby paper diaper serving as a sample, 60ml of test solution is freely flowed to the surface of the center of the sample through a funnel, the same amount of test solution is injected into the funnel again in 5 minutes, a plurality of layers of filter paper with the diameter of 100mm are placed on the surface of the sample in 10 minutes, meanwhile, a standard pressing block is pressed on the filter paper, the standard pressing block is removed in 1 minute of pressing, the measurement mode is adopted for multiple tests, and the average rewet amount of the finally measured sample is 4.9g and is lower than 10g of the national standard.
According to the method for measuring the leakage amount in the paper diaper (sheet or pad) of the national standard GB/T28004-2011 of the people's republic of China, the water absorbent core body with no glue reverse absorption is manufactured into an adult paper diaper which is used as a sample, the sample is laid on a horizontal table top, 80ml of test solution is measured by a separating funnel, the test solution is poured into the central position of the sample at a constant speed within 30 seconds, and after 5 minutes, no liquid leakage is observed around the sample.
Comparative example 1
Comparative example 1 the upper ES chemical fiber layer of example 1 was replaced with a wood pulp fiber layer, and the wood pulp fiber layer was bonded together with the intermediate high-molecular water-absorbent resin layer and the lower wood pulp ES chemical fiber mixed layer by hot melt adhesive to prepare a water-absorbent core of comparative example 1 having the same thickness as in example 1.
Comparative example 1 absorbent cores and the non-adhesive reverse absorbent cores of example 1, both having dimensions 16 x 16cm, were taken as test subjects. As shown in FIG. 4, 80ml of the test solution was poured at a uniform rate over 30 seconds over the center point of the horizontally placed comparative example 1 water-absorbent core and the non-adhesive reverse-absorbent core under the same conditions, and the diffusion of the test solution at the upper surfaces (i.e., upper layers) of the comparative example 1 water-absorbent core and the non-adhesive reverse-absorbent core was observed. In the absorbent core of comparative example 1, the liquid oozes slowly after pouring, and most of the liquid diffuses outward, and the test solution has not yet poured at 15s, i.e., has completely diffused to a position 8cm from the center point on the upper surface (i.e., the edge of the core). In the water-absorbing core body with no glue reverse absorption, after the test solution is poured, the liquid quickly infiltrates downwards, the upper liquid is only diffused to the position 3.6cm away from the central point on the upper surface at 30s, and basically keeps the upper surface from diffusing outwards, and other positions on the upper surface of the core body keep dry and comfortable, and the liquid is basically absorbed by the middle layer and the lower layer.
Comparative example 2
In comparative example 2, the water-absorbent core material having the same structure as in example 1 was obtained, and the upper ES chemical fiber layer, the middle high-molecular water-absorbent resin layer and the lower wood pulp ES chemical fiber mixed layer were bonded together by hot melt adhesive to prepare a water-absorbent core having the same thickness as in example 1.
Comparative example 2 absorbent cores and the non-adhesive reverse absorbent cores of example 1, both having dimensions 16 x 16cm, were taken as test subjects. As shown in fig. 4, 80ml of the test solution was poured at a uniform rate over 30 seconds over the center point of the horizontally placed water-absorbent core of example 2 and the non-adhesive reverse-absorbent core under the same conditions, and the diffusion condition of the test solution on the upper surfaces (i.e., upper layers) of the water-absorbent core of comparative example 2 and the non-adhesive reverse-absorbent core was observed. In the absorbent core of comparative example 2, the liquid oozes slowly after pouring, and most of the liquid diffuses outward, and the test solution has not yet poured at 15s, i.e., has completely diffused to a position 8cm from the center point on the upper surface (i.e., the edge of the core). In the non-adhesive reverse absorption water absorption core, after the test solution is poured, the liquid quickly infiltrates downwards, and is only diffused to the position 3.6cm away from the center point at the 30s, and basically keeps the upper surface from diffusing outwards, and other positions on the upper surface of the core keep dry, so that the liquid is basically absorbed by the middle layer and the lower layer.
The comparison example 1 and the comparison example 2 are combined to show that the test solution in the water absorption core of the invention without glue reverse absorption has high infiltration speed and low surface diffusion speed in the water absorption core. The ES chemical fiber layer has a faster infiltration effect than the wood pulp fiber layer, and the adhesive used for bonding has a larger influence on the infiltration of the test solution.
The invention and its embodiments have been described above by way of illustration and not limitation, and the actual construction is not limited thereto as illustrated in the accompanying drawings. Therefore, those skilled in the art should not creatively design structural ways and embodiments similar to the technical scheme without departing from the gist of the present invention, and the structural ways and embodiments are all within the protection scope of the present invention.