CN111138867A - 粘结剂和由其制备的材料 - Google Patents
粘结剂和由其制备的材料 Download PDFInfo
- Publication number
- CN111138867A CN111138867A CN201910405128.9A CN201910405128A CN111138867A CN 111138867 A CN111138867 A CN 111138867A CN 201910405128 A CN201910405128 A CN 201910405128A CN 111138867 A CN111138867 A CN 111138867A
- Authority
- CN
- China
- Prior art keywords
- binder
- fibers
- reactant
- acid
- carbohydrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011230 binding agent Substances 0.000 title claims abstract description 324
- 239000000463 material Substances 0.000 title description 48
- 239000000376 reactant Substances 0.000 claims abstract description 156
- 150000001720 carbohydrates Chemical class 0.000 claims abstract description 70
- 150000001412 amines Chemical class 0.000 claims abstract description 29
- 239000002253 acid Substances 0.000 claims description 105
- 235000014633 carbohydrates Nutrition 0.000 claims description 77
- 239000000835 fiber Substances 0.000 claims description 73
- 239000003365 glass fiber Substances 0.000 claims description 73
- 238000000034 method Methods 0.000 claims description 62
- 235000000346 sugar Nutrition 0.000 claims description 42
- 238000001723 curing Methods 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 36
- 150000007513 acids Chemical class 0.000 claims description 31
- 238000004519 manufacturing process Methods 0.000 claims description 30
- 150000003863 ammonium salts Chemical class 0.000 claims description 22
- 238000001029 thermal curing Methods 0.000 claims description 19
- 150000008163 sugars Chemical class 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 11
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 239000008121 dextrose Substances 0.000 claims description 10
- 239000007822 coupling agent Substances 0.000 claims description 9
- 150000002772 monosaccharides Chemical class 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- 108090000623 proteins and genes Proteins 0.000 claims description 7
- 102000004169 proteins and genes Human genes 0.000 claims description 7
- 150000001413 amino acids Chemical class 0.000 claims description 5
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 5
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims description 4
- 229940120503 dihydroxyacetone Drugs 0.000 claims description 4
- 238000011065 in-situ storage Methods 0.000 claims description 4
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 239000005715 Fructose Substances 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- 229920000297 Rayon Polymers 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004760 aramid Substances 0.000 claims description 3
- 229920006231 aramid fiber Polymers 0.000 claims description 3
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 3
- 239000002964 rayon Substances 0.000 claims description 3
- 229930091371 Fructose Natural products 0.000 claims description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 2
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 2
- 229920000914 Metallic fiber Polymers 0.000 claims 2
- 238000005260 corrosion Methods 0.000 abstract description 14
- 230000007797 corrosion Effects 0.000 abstract description 14
- 239000003112 inhibitor Substances 0.000 abstract description 7
- 239000002210 silicon-based material Substances 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 description 81
- 239000000243 solution Substances 0.000 description 68
- 239000000047 product Substances 0.000 description 63
- 239000007787 solid Substances 0.000 description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 49
- 238000012360 testing method Methods 0.000 description 45
- 238000009413 insulation Methods 0.000 description 42
- XISYMCYXGZPFRD-OVNWPFPBSA-N triazanium;2-hydroxypropane-1,2,3-tricarboxylate;(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal Chemical compound [NH4+].[NH4+].[NH4+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O XISYMCYXGZPFRD-OVNWPFPBSA-N 0.000 description 42
- -1 amino compound Chemical class 0.000 description 39
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 32
- SPFMQWBKVUQXJV-BTVCFUMJSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;hydrate Chemical compound O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O SPFMQWBKVUQXJV-BTVCFUMJSA-N 0.000 description 31
- 238000010998 test method Methods 0.000 description 31
- 229920002451 polyvinyl alcohol Polymers 0.000 description 29
- 239000000126 substance Substances 0.000 description 29
- 239000011152 fibreglass Substances 0.000 description 28
- 210000003625 skull Anatomy 0.000 description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 26
- 229960000673 dextrose monohydrate Drugs 0.000 description 26
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 25
- 150000003839 salts Chemical class 0.000 description 25
- 239000011521 glass Substances 0.000 description 24
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 23
- 239000011324 bead Substances 0.000 description 20
- 229920001187 thermosetting polymer Polymers 0.000 description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 19
- 210000000988 bone and bone Anatomy 0.000 description 19
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 18
- 239000000428 dust Substances 0.000 description 16
- 238000002360 preparation method Methods 0.000 description 16
- 239000007864 aqueous solution Substances 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 15
- 229920002689 polyvinyl acetate Polymers 0.000 description 15
- 239000000853 adhesive Substances 0.000 description 14
- 230000001070 adhesive effect Effects 0.000 description 14
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 14
- 239000002023 wood Substances 0.000 description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 13
- 238000006297 dehydration reaction Methods 0.000 description 13
- 150000004676 glycans Chemical class 0.000 description 13
- 229920001282 polysaccharide Polymers 0.000 description 13
- 239000005017 polysaccharide Substances 0.000 description 13
- 229910000077 silane Inorganic materials 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- AIJULSRZWUXGPQ-UHFFFAOYSA-N Methylglyoxal Chemical compound CC(=O)C=O AIJULSRZWUXGPQ-UHFFFAOYSA-N 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 12
- 230000018044 dehydration Effects 0.000 description 12
- 229920003023 plastic Polymers 0.000 description 12
- 239000004033 plastic Substances 0.000 description 12
- 229920005862 polyol Polymers 0.000 description 12
- 150000003077 polyols Chemical class 0.000 description 12
- 229910021529 ammonia Inorganic materials 0.000 description 11
- 150000008064 anhydrides Chemical class 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 11
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 11
- 229960001031 glucose Drugs 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- 229920001568 phenolic resin Polymers 0.000 description 11
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 10
- 239000002585 base Substances 0.000 description 10
- 238000000926 separation method Methods 0.000 description 10
- 238000007655 standard test method Methods 0.000 description 10
- 230000004580 weight loss Effects 0.000 description 10
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 description 9
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000000123 paper Substances 0.000 description 9
- 239000011118 polyvinyl acetate Substances 0.000 description 9
- 238000011084 recovery Methods 0.000 description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
- 239000001393 triammonium citrate Substances 0.000 description 9
- 235000011046 triammonium citrate Nutrition 0.000 description 9
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 8
- 229920002125 Sokalan® Polymers 0.000 description 8
- 239000004927 clay Substances 0.000 description 8
- 230000001143 conditioned effect Effects 0.000 description 8
- 238000004090 dissolution Methods 0.000 description 8
- 239000011976 maleic acid Substances 0.000 description 8
- 239000002480 mineral oil Substances 0.000 description 8
- 235000010446 mineral oil Nutrition 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- 150000001323 aldoses Chemical class 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 239000012774 insulation material Substances 0.000 description 7
- 150000002584 ketoses Chemical group 0.000 description 7
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000002557 mineral fiber Substances 0.000 description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 7
- 239000012855 volatile organic compound Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 6
- 150000001299 aldehydes Chemical class 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 229960005070 ascorbic acid Drugs 0.000 description 6
- 235000010323 ascorbic acid Nutrition 0.000 description 6
- 239000011668 ascorbic acid Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 239000008234 soft water Substances 0.000 description 6
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 5
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 229960004543 anhydrous citric acid Drugs 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 229960004106 citric acid Drugs 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 5
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 5
- 125000000392 cycloalkenyl group Chemical group 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- 238000000921 elemental analysis Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 125000001072 heteroaryl group Chemical group 0.000 description 5
- 125000000623 heterocyclic group Chemical group 0.000 description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 5
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000001819 mass spectrum Methods 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 229920005646 polycarboxylate Polymers 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- 239000000779 smoke Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 3
- 229930182474 N-glycoside Natural products 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 229920002522 Wood fibre Polymers 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001728 carbonyl compounds Chemical class 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000011094 fiberboard Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 150000002341 glycosylamines Chemical class 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 238000004128 high performance liquid chromatography Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 150000007857 hydrazones Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000004584 polyacrylic acid Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 3
- 150000003627 tricarboxylic acid derivatives Chemical class 0.000 description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 3
- 150000003641 trioses Chemical class 0.000 description 3
- 239000002025 wood fiber Substances 0.000 description 3
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
- CPOLUJRVZOIUHO-UHFFFAOYSA-N 2-(oxo-$l^{5}-phosphanylidyne)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC#P=O CPOLUJRVZOIUHO-UHFFFAOYSA-N 0.000 description 2
- CWNNYYIZGGDCHS-UHFFFAOYSA-N 2-methylideneglutaric acid Chemical compound OC(=O)CCC(=C)C(O)=O CWNNYYIZGGDCHS-UHFFFAOYSA-N 0.000 description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 125000003172 aldehyde group Chemical group 0.000 description 2
- 150000001312 aldohexoses Chemical class 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 229940077731 carbohydrate nutrients Drugs 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000002144 chemical decomposition reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 description 2
- 229960002303 citric acid monohydrate Drugs 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- 238000007791 dehumidification Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 125000004663 dialkyl amino group Chemical group 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 239000012210 heat-resistant fiber Substances 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 150000002386 heptoses Chemical class 0.000 description 2
- 150000002402 hexoses Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 229910052901 montmorillonite Inorganic materials 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000036284 oxygen consumption Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 150000002972 pentoses Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 229920000137 polyphosphoric acid Polymers 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 2
- 229940079877 pyrogallol Drugs 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 239000012086 standard solution Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003538 tetroses Chemical class 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 2
- DJKGDNKYTKCJKD-BPOCMEKLSA-N (1s,4r,5s,6r)-1,2,3,4,7,7-hexachlorobicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound ClC1=C(Cl)[C@]2(Cl)[C@H](C(=O)O)[C@H](C(O)=O)[C@@]1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-BPOCMEKLSA-N 0.000 description 1
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 1
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- OQBLGYCUQGDOOR-UHFFFAOYSA-L 1,3,2$l^{2}-dioxastannolane-4,5-dione Chemical compound O=C1O[Sn]OC1=O OQBLGYCUQGDOOR-UHFFFAOYSA-L 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- HORQAOAYAYGIBM-UHFFFAOYSA-N 2,4-dinitrophenylhydrazine Chemical compound NNC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HORQAOAYAYGIBM-UHFFFAOYSA-N 0.000 description 1
- NDTDVKKGYBULHF-UHFFFAOYSA-N 2-(1-hydroxy-3-phenylnaphthalen-2-yl)-3-phenylnaphthalen-1-ol Chemical compound C=1C2=CC=CC=C2C(O)=C(C=2C(=CC3=CC=CC=C3C=2O)C=2C=CC=CC=2)C=1C1=CC=CC=C1 NDTDVKKGYBULHF-UHFFFAOYSA-N 0.000 description 1
- KEZYHIPQRGTUDU-UHFFFAOYSA-N 2-[dithiocarboxy(methyl)amino]acetic acid Chemical compound SC(=S)N(C)CC(O)=O KEZYHIPQRGTUDU-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- XIRDTMSOGDWMOX-UHFFFAOYSA-N 3,4,5,6-tetrabromophthalic acid Chemical compound OC(=O)C1=C(Br)C(Br)=C(Br)C(Br)=C1C(O)=O XIRDTMSOGDWMOX-UHFFFAOYSA-N 0.000 description 1
- WZHHYIOUKQNLQM-UHFFFAOYSA-N 3,4,5,6-tetrachlorophthalic acid Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(O)=O WZHHYIOUKQNLQM-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 108010005094 Advanced Glycation End Products Proteins 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 238000003691 Amadori rearrangement reaction Methods 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 238000006418 Brown reaction Methods 0.000 description 1
- FVYXYCJFEUVDRC-UHFFFAOYSA-N C(C=C)(=O)OC(C=C)=O.C=C Chemical compound C(C=C)(=O)OC(C=C)=O.C=C FVYXYCJFEUVDRC-UHFFFAOYSA-N 0.000 description 1
- 229920002825 CELVOL ® 203 Polymers 0.000 description 1
- 229920002816 CELVOL ® 205 Polymers 0.000 description 1
- 229920002835 CELVOL ® 305 Polymers 0.000 description 1
- 229920002827 CELVOL ® 502 Polymers 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- YTBSYETUWUMLBZ-UHFFFAOYSA-N D-Erythrose Natural products OCC(O)C(O)C=O YTBSYETUWUMLBZ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-CBPJZXOFSA-N D-Gulose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O WQZGKKKJIJFFOK-CBPJZXOFSA-N 0.000 description 1
- WQZGKKKJIJFFOK-WHZQZERISA-N D-aldose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-WHZQZERISA-N 0.000 description 1
- LKDRXBCSQODPBY-JDJSBBGDSA-N D-allulose Chemical compound OCC1(O)OC[C@@H](O)[C@@H](O)[C@H]1O LKDRXBCSQODPBY-JDJSBBGDSA-N 0.000 description 1
- YTBSYETUWUMLBZ-IUYQGCFVSA-N D-erythrose Chemical compound OC[C@@H](O)[C@@H](O)C=O YTBSYETUWUMLBZ-IUYQGCFVSA-N 0.000 description 1
- MNQZXJOMYWMBOU-VKHMYHEASA-N D-glyceraldehyde Chemical compound OC[C@@H](O)C=O MNQZXJOMYWMBOU-VKHMYHEASA-N 0.000 description 1
- HAIWUXASLYEWLM-UHFFFAOYSA-N D-manno-Heptulose Natural products OCC1OC(O)(CO)C(O)C(O)C1O HAIWUXASLYEWLM-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-NQXXGFSBSA-N D-ribulose Chemical compound OC[C@@H](O)[C@@H](O)C(=O)CO ZAQJHHRNXZUBTE-NQXXGFSBSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-UHFFFAOYSA-N D-threo-2-Pentulose Natural products OCC(O)C(O)C(=O)CO ZAQJHHRNXZUBTE-UHFFFAOYSA-N 0.000 description 1
- YTBSYETUWUMLBZ-QWWZWVQMSA-N D-threose Chemical compound OC[C@@H](O)[C@H](O)C=O YTBSYETUWUMLBZ-QWWZWVQMSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-WUJLRWPWSA-N D-xylulose Chemical compound OC[C@@H](O)[C@H](O)C(=O)CO ZAQJHHRNXZUBTE-WUJLRWPWSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 206010056474 Erythrosis Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical group C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 1
- 208000007976 Ketosis Diseases 0.000 description 1
- WQZGKKKJIJFFOK-VSOAQEOCSA-N L-altropyranose Chemical compound OC[C@@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-VSOAQEOCSA-N 0.000 description 1
- HSNZZMHEPUFJNZ-UHFFFAOYSA-N L-galacto-2-Heptulose Natural products OCC(O)C(O)C(O)C(O)C(=O)CO HSNZZMHEPUFJNZ-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 229920002861 MOWIOL ® 3-83 Polymers 0.000 description 1
- 229920002858 MOWIOL ® 4-88 Polymers 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- CFGPOQAHCQQVHW-UHFFFAOYSA-N N-silylpropan-1-amine Chemical compound CCCN[SiH3] CFGPOQAHCQQVHW-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000005819 Potassium phosphonate Substances 0.000 description 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
- HAIWUXASLYEWLM-AZEWMMITSA-N Sedoheptulose Natural products OC[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@](O)(CO)O1 HAIWUXASLYEWLM-AZEWMMITSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 150000001320 aldopentoses Chemical class 0.000 description 1
- 150000001330 aldotetroses Chemical class 0.000 description 1
- 150000001333 aldotrioses Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- 125000005103 alkyl silyl group Chemical group 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000002639 bone cement Substances 0.000 description 1
- ZNFNDZCXTPWRLQ-UHFFFAOYSA-N butane-1,1,1-tricarboxylic acid Chemical compound CCCC(C(O)=O)(C(O)=O)C(O)=O ZNFNDZCXTPWRLQ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000004786 cone calorimetry Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- AAOVKJBEBIDNHE-UHFFFAOYSA-N diazepam Chemical compound N=1CC(=O)N(C)C2=CC=C(Cl)C=C2C=1C1=CC=CC=C1 AAOVKJBEBIDNHE-UHFFFAOYSA-N 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- YXXXKCDYKKSZHL-UHFFFAOYSA-M dipotassium;dioxido(oxo)phosphanium Chemical compound [K+].[K+].[O-][P+]([O-])=O YXXXKCDYKKSZHL-UHFFFAOYSA-M 0.000 description 1
- 235000019820 disodium diphosphate Nutrition 0.000 description 1
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 1
- 229940038485 disodium pyrophosphate Drugs 0.000 description 1
- 239000002706 dry binder Substances 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005837 enolization reaction Methods 0.000 description 1
- UQPHVQVXLPRNCX-UHFFFAOYSA-N erythrulose Chemical compound OCC(O)C(=O)CO UQPHVQVXLPRNCX-UHFFFAOYSA-N 0.000 description 1
- FFYWKOUKJFCBAM-UHFFFAOYSA-N ethenyl 2-methylprop-2-enoate Chemical class CC(=C)C(=O)OC=C FFYWKOUKJFCBAM-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 description 1
- 150000002454 idoses Chemical class 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- BJHIKXHVCXFQLS-PQLUHFTBSA-N keto-D-tagatose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)C(=O)CO BJHIKXHVCXFQLS-PQLUHFTBSA-N 0.000 description 1
- 150000002574 ketohexoses Chemical class 0.000 description 1
- 150000002581 ketopentoses Chemical class 0.000 description 1
- 150000002586 ketotetroses Chemical class 0.000 description 1
- 150000002588 ketotrioses Chemical class 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 230000003061 melanogenesis Effects 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 239000006012 monoammonium phosphate Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- XCVNDBIXFPGMIW-UHFFFAOYSA-N n-ethylpropan-1-amine Chemical compound CCCNCC XCVNDBIXFPGMIW-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- RCCYSVYHULFYHE-UHFFFAOYSA-N pentanediamide Chemical compound NC(=O)CCCC(N)=O RCCYSVYHULFYHE-UHFFFAOYSA-N 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 229940093916 potassium phosphate Drugs 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000004007 reversed phase HPLC Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- HSNZZMHEPUFJNZ-SHUUEZRQSA-N sedoheptulose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO HSNZZMHEPUFJNZ-SHUUEZRQSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UDEJEOLNSNYQSX-UHFFFAOYSA-J tetrasodium;2,4,6,8-tetraoxido-1,3,5,7,2$l^{5},4$l^{5},6$l^{5},8$l^{5}-tetraoxatetraphosphocane 2,4,6,8-tetraoxide Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])(=O)O1 UDEJEOLNSNYQSX-UHFFFAOYSA-J 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
- 238000000825 ultraviolet detection Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/321—Starch; Starch derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
- B32B17/04—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/12—General methods of coating; Devices therefor
- C03C25/14—Spraying
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H5/00—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium
- C07H5/04—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
- C08F251/02—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof on to cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/02—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/82—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to sound only
- E04B1/84—Sound-absorbing elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/88—Insulating elements for both heat and sound
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
- F16L59/026—Mattresses, mats, blankets or the like
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/14—Arrangements for the insulation of pipes or pipe systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/69—Autogenously bonded nonwoven fabric
- Y10T442/691—Inorganic strand or fiber material only
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Architecture (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Acoustics & Sound (AREA)
- Mechanical Engineering (AREA)
- Structural Engineering (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Wood Science & Technology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Genetics & Genomics (AREA)
- Biotechnology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Catalysts (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Nonwoven Fabrics (AREA)
- Reinforced Plastic Materials (AREA)
- Materials For Medical Uses (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Glass Compositions (AREA)
Abstract
在非集合或松散集合物质中产生或促进粘结力的粘结剂。该粘结剂包含:包括(i)胺和(ii)碳水化合物的梅拉德反应物;任选地,含硅化合物和/或缓蚀剂。
Description
本申请是申请日为2006年7月26日、申请号为201510598949.0、发明名称为“粘结剂和由其制备的材料”的中国发明专利申请的分案申请。上述申请号为201510598949.0的中国发明专利申请是申请日为 2006年7月26日、申请号为201210263009.2、发明名称为“粘结剂和由其制备的材料”的中国发明专利申请的分案申请。上述申请号为 201210263009.2的中国发明专利申请是申请日2006年7月26日、申请号200680035430.0、发明名称“粘结剂和由其制备的材料”的发明专利申请的分案申请。
相关申请的交叉引用
本申请依据35U.S.C.§119(e)要求于2005年7月26日提交的美国临时申请序列号60/702,456、和于2005年12月22日提交的美国临时申请序列号60/743,071的权益,该两篇文献的公开内容据此在此引入作为参考。
发明背景
粘结剂可用于由非集合或松散集合的物质制造材料。例如,粘结剂能够使两个或更多个表面成为一体。粘结剂可以广泛地分为两个主类:有机和无机粘结剂,其中该有机材料再细分成动物、植物和合成来源的那些。粘结剂的另一种分类方法基于这些化合物的化学性质: (1)蛋白质或蛋白质衍生物;(2)淀粉、纤维素或胶料和它们的衍生物; (3)热塑性合成树脂;(4)热固性合成树脂;(5)天然树脂和沥青;(6) 天然和合成橡胶和(7)无机粘结剂。粘结剂还可以根据它们所用于的目的分类:(1)粘结刚性表面,如硬质塑料,和金属;和(2)粘结挠性表面,尤其如软质塑料和薄金属片材等。
热塑性粘结剂包括各种聚合材料如聚乙酸乙烯酯、聚乙烯醇缩丁醛、聚乙烯醇及其它聚乙烯基树脂;聚苯乙烯树脂;丙烯酸和甲基丙烯酸酯树脂;氰基丙烯酸酯;和各种其它合成树脂如聚异丁烯聚酰胺、 courmaroneidene产物和硅氧烷。这些热塑性粘结剂可以具有持久的可溶性和可熔性以致它们在应力下蠕变和当受热时软化。它们可用于制造各种产品,例如胶带。
热固性粘结剂包括各种苯酚-醛、脲-醛、蜜胺-醛,及其它缩聚材料如呋喃树脂和聚氨酯树脂。热固性粘结剂的特征在于:可以通过利用热或催化作用转变成不溶和不熔的材料。包含苯酚-、间苯二酚-、脲-、蜜胺-甲醛,苯酚糠醛等的粘结剂组合物可用于粘结织物、塑料、橡胶和许多其它材料。
如上所指出,粘结剂可用于由非集合或松散集合的物质制造材料。因此,能够起粘结剂作用的组合物是合乎需要的。
发明概述
根据本发明一个示例性实施方案的固化或未固化的粘结剂可以包含以下特征中的一种或多种或它们的组合。此外,根据本发明的材料可以包含以下特征中的一种或多种或它们的组合:
首先,应理解的是,本发明的粘结剂可以用于各种制造应用以在非集合或松散集合物质的汇集物中产生或促进粘结力。汇集物包括两种或更多种组分。该粘结剂在该汇集物的至少两种组分中产生或促进粘结力。例如,本发明的粘结剂能够将物质的汇集物固定在一起以致该物质按抵抗分离的方式粘附。本文描述的粘结剂可以用于制造任何材料。
本发明粘结剂的一个潜在特征是它们是无甲醛的。因此,该粘结剂布置于其上的材料也可以是无甲醛的(例如,玻璃纤维)。此外,本发明粘结剂与其它已知的粘结剂相比可以具有降低的三甲胺含量。
至于本发明粘结剂的化学成分,它们可以包括酯和/或聚酯化合物。粘结剂可以包括与植物油如大豆油结合的酯和/或聚酯化合物。另外,粘结剂可以包括与有机酸的钠盐结合的酯和/或聚酯化合物。粘结剂可以包括无机酸的钠盐。粘结剂还可以包括有机酸的钾盐。此外,粘结剂可以包括无机酸的钾盐。所述粘结剂可以包括与粘土添加剂,如蒙脱土结合的酯和/或聚酯化合物。
另外,本发明的粘结剂可以包括梅拉德(Maillard)反应的产物。例如,参见图2。如图2所示,梅拉德反应产生蛋白黑素,即结构不同的高分子量、呋喃环和含氮的聚合物,这取决于反应物和它们的制备条件。蛋白黑素显示随加热温度和加热时间而增加的C∶N比例、不饱和度和化学芳香性。(参见,Ames,J.M.的“The Maillard Browning Reaction-anupdate,”Chemistry and Industry(Great Britain),1988,7,558-561,该文献的公开内容据此在此引入作为参考)。因此,本发明的粘结剂可以经由梅拉德反应制得并因此包含蛋白黑素。应理解的是,本发明的粘结剂可以包含蛋白黑素,或其它梅拉德反应产物,该产物通过单独的方法产生然后简单地添加到构成该粘结剂的组合物中。该粘结剂中的蛋白黑素可以是水不溶性的。此外,该粘结剂可以是热固性粘结剂。
制备蛋白黑素的梅拉德反应物可以包括与还原糖碳水化合物反应物起反应的胺反应物。例如,单体多元羧酸的铵盐可以与以下物质起反应:(i)呈其醛糖或酮糖形式的单糖或(ii)多糖,或(iii)它们的结合物。在另一个变体中,聚合物多元羧酸的铵盐可以与以下物质接触: (i)呈其醛糖或酮糖形式的单糖或(ii)多糖,或(iii)它们的结合物。在又一个变体中,氨基酸可以与以下物质接触:(i)呈其醛糖或酮糖形式的单糖,或(ii)多糖或(iii)它们的结合物。而且,肽可以与以下物质接触:(i)呈其醛糖或酮糖形式的单糖或(ii)多糖,或(iii)它们的结合物。此外,蛋白质可以与以下物质接触:(i)呈其醛糖或酮糖形式的单糖或(ii)多糖或(iii)它们的结合物。
还应理解的是,本发明的粘结剂可以包括在梅拉德反应的非糖变体中产生的蛋白黑素。在这些反应中,胺反应物与非碳水化合物羰基反应物接触。在一个示例性的变体中,单体多元羧酸的铵盐与非碳水化合物羰基反应物如,丙酮醛、乙醛、巴豆醛、2-呋喃甲醛、醌、抗坏血酸等接触,或与它们的结合物接触。在另一个变体中,聚合物多元羧酸的铵盐可以与非碳水化合物羰基反应物如,丙酮醛、乙醛、巴豆醛、2-呋喃甲醛、醌、抗坏血酸等接触,或与它们的结合物接触。在又一个示例性变体中,氨基酸可以与非碳水化合物羰基反应物如,丙酮醛、乙醛、巴豆醛、2-呋喃甲醛、醌、抗坏血酸等接触,或与它们的结合物接触。在另一个示例性变体中,肽可以与非碳水化合物羰基反应物如,丙酮醛、乙醛、巴豆醛、2-呋喃甲醛、醌、抗坏血酸等接触,或与它们的结合物接触。在又一个示例性变体中,蛋白质可以与非碳水化合物羰基反应物如,丙酮醛、乙醛、巴豆醛、2-呋喃甲醛、醌、抗坏血酸等接触,或与它们的结合物接触。
本文论述的蛋白黑素可以由蛋白黑素的反应物化合物产生。将这些反应物化合物置于在碱性pH值下的水溶液中并因此不是腐蚀性的。也就是说,碱性溶液阻止或抑制了由化学分解所引起的物质如金属的腐蚀或磨损,该化学分解例如由酸造成。该反应物化合物可以包括还原糖碳水化合物反应物和胺反应物。此外,该反应物化合物可以包括非碳水化合物羰基反应物和胺反应物。
还应理解的是,本文描述的粘结剂可以由蛋白黑素的反应物化合物本身制成。也就是说,一旦将梅拉德反应物混合,该混合物就可以起本发明粘结剂的作用。这些粘结剂可以用来制造未固化的、无甲醛物质,如纤维材料。
在该替代方案中,由梅拉德反应的反应物制成的粘结剂可以是固化的。这些粘结剂可用来制造固化的无甲醛物质,如纤维组合物。这些组合物是耐水的,并且如上所指出,包括水不溶性蛋白黑素。
应理解的是,本文描述的粘结剂可以用于由非集合或松散集合的物质的汇集物制造产品。例如,这些粘结剂可以用来制造纤维产品。这些产品可以由织造或非织造纤维制成。该纤维可以是耐热或非耐热的纤维或它们的结合物。在一个示例性的实施方案中,粘结剂用来粘结玻璃纤维以制造玻璃纤维产品。在另一个示例性的实施方案中,粘结剂用来制造纤维素组合物。对于纤维素组合物,粘结剂可用来粘结纤维素物质以制造,例如,具有合乎需要的物理性能(例如,机械强度) 的木纤维板。
本发明的一个实施方案涉及由非集合或松散集合的物质的汇集物制造产品的方法。使用该方法的一个实例是制造玻璃纤维。然而,如上所指出,该方法可以用于制造任何材料,只要当使用时该方法产生或促进了粘结力。该方法可以包括让所述纤维接触可热固化的含水粘结剂。该粘结剂可以包括(i)多元羧酸的铵盐反应物和(ii)还原糖碳水化合物反应物。这两种反应物是蛋白黑素的反应物(即,这些反应物当在引发梅拉德反应的条件下反应时产生蛋白黑素)。该方法还可以包括从与该纤维接触的粘结剂中除去水(即,该粘结剂是脱水的)。该方法还可以包括将与该玻璃纤维接触的粘结剂固化(例如,将该粘结剂热固化)。
使用这一方法的另一个实例是制造纤维素材料。该方法可以包括让所述纤维素材料(例如,纤维素纤维)接触可热固化的含水粘结剂。该粘结剂可以包括(i)多元羧酸的铵盐反应物和(ii)还原糖碳水化合物反应物。如上所指出,这两种反应物是蛋白黑素的反应物化合物。该方法还可以包括从与该纤维素材料接触的粘结剂中除去水。如前所述,该方法还可以包括将该粘结剂固化(例如,热固化)。
该粘结剂的一种使用方式是将玻璃纤维粘结在一起以致它们变得组织成玻璃纤维垫。该玻璃纤维的垫可以经加工而形成几类玻璃纤维材料中的一种,如玻璃纤维绝缘材料。在一个实例中,玻璃纤维材料可以具有按大约80wt%-大约99wt%存在的玻璃纤维。该未固化的粘结剂可以用来将玻璃纤维固定在一起。该固化的粘结剂可以用来将玻璃纤维固定在一起.
此外,还描述了纤维产品,该纤维产品包括与纤维素纤维,如刨花或锯屑的垫中的那些纤维素纤维接触的粘结剂。该垫可以经加工而形成几类木纤维板产品中的一种。在一个变体中,该粘结剂是未固化的。在这一变体中,未固化的粘结剂可以用来将纤维素纤维固定在一起。在该替代方案中,固化的粘结剂可以用来将纤维素纤维固定在一起。
在考虑以下示例性实施方案的详细描述后,本发明的附加特征对本领域技术人员来说将是显而易见的,所述示例性实施方案如当前领会的那样举例说明实施本发明的最佳方式。
附图简述
图1示出了制备蛋白黑素的许多示例性反应物;
图2举例说明了当使还原糖与氨基化合物反应时的梅拉德反应示意图;
图3示出了本公开内容的干燥粘结剂的一个示例性实施方案的 FT-IR谱图;
图4示出了本公开内容的固化粘结剂的一个示例性实施方案的 FT-IR谱图;
图5示出了用本公开内容的粘结剂的一个示例性实施方案制造的玻璃纤维管绝缘材料的650°F热表面性能;
图6示出了用本公开内容的粘结剂的一个示例性实施方案制造的玻璃纤维管绝缘材料的1000°F热表面性能。
详细描述
尽管本发明可采用各种修改和替代形式,但是将在此详细描述特定实施方案。然而,应当理解,不存在将本发明限制到所述特殊形式的意图,而是相反,希望涵盖属于本发明精神和范围内的所有修改、等同物和替代方案。
本文所使用的术语“无甲醛”是指粘结剂或包括粘结剂的材料由于干燥和/或固化释放小于大约1ppm甲醛。该1ppm基于被测量甲醛释放量的样品的重量。
“固化”表示粘结剂已经暴露于可引发化学变化的条件下。这些化学变化的实例包括,但不限于,粘结剂组分的(i)共价键接,(ii) 氢键接,和将粘结剂中的聚合物和/或低聚物化学交联。与未固化的粘结剂相比,这些变化可以增加粘结剂的耐久性和耐溶剂性。将粘结剂固化可以引起热固性材料的形成。另外,固化可以包括蛋白黑素的产生。这些蛋白黑素可以由蛋白黑素的反应物化合物的梅拉德反应产生。此外,与未固化的粘结剂相比,固化的粘结剂可以引起汇集物中的物质之间的粘附性增加。固化可以由例如,热、电磁辐射或电子束引发。
在其中粘结剂中的化学变化(例如聚合和交联)引起水释放的情况下,可以通过所释放的水量大于仅由干燥产生的水量来测定固化。用来测量在干燥过程中相比于在粘结剂固化时所释放的水量的技术在本领域中是为人熟知的。
根据上面的段落,未固化的粘结剂是还没有被固化的粘结剂。
本文所使用的术语“碱性”表示具有大于或等于大约7的pH值的溶液。例如,溶液的pH值可以小于或等于大约10。此外,溶液可以具有大约7-大约10,或大约8-大约10,或大约9-大约10的pH值。
本文所使用的术语“铵”包括但不限于,+NH4、+NH3R1和+NH2R1R2,其中R1和R2各自独立地在+NH2R1R2中被选择,并且其中R1和R2选自烷基、环烷基、链烯基、环烯基、杂环基、芳基和杂芳基。
术语“烷基”是指碳原子的饱和一价链,它可以是任选支化的;术语“环烷基”是指碳原子的一价链,其一部分形成环;术语“链烯基”是指碳原子的包括至少一个双键的不饱和一价链,其可以是任选支化的;术语“环烯基”是指碳原子的不饱和一价链,其一部分形成环;术语“杂环基”是指碳和杂原子的一价链,其中该杂原子选自氮、氧和硫,该链的一部分(包括至少一个杂原子)形成环;术语“芳基”是指碳原子的芳族单环或多核环,如苯基、萘基等;术语“杂芳基”是指碳原子和至少一个选自氮、氧和硫的杂原子的芳族单环或多核环,如吡啶基、嘧啶基、吲哚基、苯并唑基等。应该理解的是每个烷基、环烷基、链烯基、环烯基和杂环基可以任选地被独立选择的基团取代,如烷基,卤代烷基,羟烷基,氨基烷基,羧酸和它们的衍生物,包括酯、酰胺和腈,羟基,烷氧基,酰氧基,氨基,烷基和二烷基氨基,酰氨基,硫代等,和它们的结合。应进一步理解的是,每个芳基和杂芳基可以任选地被一个或多个独立选择的取代基,如卤素,羟基,氨基,烷基或二烷基氨基,烷氧基,烷基磺酰基,氰基,硝基等取代。
本文所使用的术语“多元羧酸”表示二羧酸、三羧酸、四羧酸、五羧酸和类似的单体多元羧酸,和它们的酸酐,以及结合物,以及聚合物多元羧酸,它们的酸酐,共聚物和结合物。在一个方面中,多元羧酸铵盐反应物是足够非挥发性的以使其能够保留下来以与梅拉德反应(下面论述)的碳水化合物反应物进行反应的能力最大化。在另一个方面中,多元羧酸铵盐反应物可以被其它化学官能团取代。
示例性地,单体多元羧酸可以是二羧酸,包括但不限于,不饱和脂族二羧酸,饱和脂族二羧酸,芳族二羧酸,不饱和环状二羧酸,饱和环状二羧酸,它们的羟基-取代的衍生物等。或者,示例性地,多元羧酸本身可以是三羧酸,包括但不限于,不饱和脂族三羧酸,饱和脂族三羧酸,芳族三羧酸,不饱和环状三羧酸,饱和环状三羧酸,它们的羟基-取代的衍生物等。可以领会,任何此类多元羧酸可以是任选取代的,如被羟基、卤素、烷基、烷氧基等取代。在一个变体中,多元羧酸是饱和的脂族三羧酸,柠檬酸。其它适合的多元羧酸认为包括,但不限于,乌头酸,己二酸,壬二酸,丁烷四羧酸二氢化物,丁烷三羧酸,氯茵酸,柠康酸,双环戊二烯-马来酸加合物,二亚乙基三胺五乙酸,双戊烯和马来酸的加合物,乙二胺四乙酸(EDTA),完全马来酸酐改性的松香,马来酸酐改性的妥尔油脂肪酸,富马酸,戊二酸,间苯二甲酸,衣康酸,用过氧化钾氧化成醇然后成羧酸的马来酸酐改性松香,马来酸,苹果酸,中康酸,经由科尔伯-施密特反应 (KOLBE-Schmidt reaction)与二氧化碳反应而引入3-4个羧基的双酚 A或双酚F,草酸,邻苯二甲酸,癸二酸,琥珀酸,酒石酸,对苯二甲酸,四溴邻苯二甲酸,四氯邻苯二甲酸,四氢邻苯二甲酸,偏苯三酸,苯均三酸等,和它们的酸酐和结合物。
示例性地,聚合物多元羧酸可以是酸,例如,聚丙烯酸、聚甲基丙烯酸、聚马来酸和类似的聚合物多元羧酸,它们的共聚物,它们的酸酐,和它们的混合物。可商购的聚丙烯酸的实例包括 AQUASET-529(Rohm & Haas,Philadelphia,PA,USA)、CRITERION 2000(Kemira,Helsinki,Finland,Europe)、 NF1(H.B.Fuller,St.Paul,MN,USA)和 SOKALAN(BASF,Ludwigshafen,Germany,Europe)。至于SOKALAN,它是丙烯酸和马来酸的水溶性聚丙烯酸类共聚物,具有大约4000的分子量。AQUASET-529是包含用甘油交联的聚丙烯酸,还包含作为催化剂的次磷酸钠的组合物。CRITERION 2000是分子量为大约2000的聚丙烯酸偏盐(partial salt)的酸性溶液。至于NF1,它是包含羧酸官能度和羟基官能度,以及没有这两种官能度的单元的共聚物;NF1还包含链转移剂,如次磷酸钠或有机磷酸盐催化剂。
此外,包括聚合物多元羧酸的组合物还认为可用于制备本文描述的粘结剂,如美国专利号5,318,990、5,661,213、6,136,916和 6,331,350中描述的那些组合物,这些文献的公开内容据此在此引入作为参考。具体来说,在美国专利号5,318,990和6,331,350中,描述了聚合物多元羧酸、多元醇和催化剂的水溶液。
如美国专利号5,318,990和6,331,350所述,聚合物多元羧酸包括含多于一个的侧挂羧基的有机聚合物或低聚物。聚合物多元羧酸可以是由不饱和羧酸,包括但不一定限于,丙烯酸、甲基丙烯酸、巴豆酸、异巴豆酸、马来酸、肉桂酸、2-甲基马来酸、衣康酸、2-甲基衣康酸、α,β-亚甲基戊二酸等制备的均聚物或共聚物。或者,聚合物多元羧酸可以由不饱和酸酐,包括但不一定限于,马来酸酐、衣康酸酐、丙烯酸酐、甲基丙烯酸酐等,以及它们的混合物制备。这些酸和酸酐的聚合方法在化学领域中是公知的。聚合物多元羧酸还可以额外地包括上述不饱和羧酸或酸酐中的一种或多种和一种或多种乙烯基化合物的共聚物,所述乙烯基化合物包括但不一定限于,苯乙烯、α- 甲基苯乙烯、丙烯腈、甲基丙烯腈、丙烯酸甲酯、丙烯酸乙酯、丙烯酸正丁酯、丙烯酸异丁酯、甲基丙烯酸甲酯、甲基丙烯酸正丁酯、甲基丙烯酸异丁酯、甲基丙烯酸缩水甘油酯、乙烯基甲基醚、乙酸乙烯酯等。这些共聚物的制备方法是本领域中公知的。聚合物多元羧酸可以包括聚丙烯酸的均聚物和共聚物。聚合物多元羧酸,尤其是聚丙烯酸聚合物的分子量可以小于10000,小于5000,或大约3000或更低。例如,分子量可以是2000。
如美国专利号5,318,990和6,331,350所述,多元醇(在包括聚合物多元羧酸的组合物中)包含至少两个羟基。该多元醇应该是足够非挥发性的以致它将基本上保留下来,用于在加热和固化操作过程中与组合物中的聚合物多元羧酸起反应。多元醇可以是分子量小于大约1000 的带有至少两个羟基的化合物,例如乙二醇、甘油、季戊四醇、三羟甲基丙烷、山梨糖醇、蔗糖、葡萄糖、间苯二酚、儿茶酚、焦棓酚、乙醇酸化脲(glycolla ted urea)、1,4-环己烷二醇、二乙醇胺、三乙醇胺和某些反应性多元醇,例如,β-羟烷基酰胺如,双[N,N-二(β- 羟乙基)]己二酰二胺,或者它可以是包含至少两个羟基的加成聚合物例如,聚乙烯醇、部分水解的聚乙酸乙烯酯,和(甲基)丙烯酸羟乙酯、 (甲基)丙烯酸羟丙酯的均聚物或共聚物等。
如美国专利号5,318,990和6,331,350所述,催化剂(在包括聚合物多元羧酸的组合物中)是含磷促进剂,其可以是分子量小于大约 1000的化合物,例如碱金属聚磷酸盐、碱金属磷酸二氢盐、多磷酸和烷基次膦酸,或者它可以是带有含磷基团的低聚物或聚合物,例如,在次磷酸钠存在下形成的丙烯酸和/或马来酸的加成聚合物,在含磷盐链转移剂或终止剂存在下由烯属不饱和单体制备的加成聚合物,和含酸官能化单体残基的加成聚合物,例如,共聚合的甲基丙烯酸磷酰基乙酯,和类似的膦酸酯,和共聚合的乙烯基磺酸单体,和它们的盐。基于聚合物多元羧酸和多元醇的总重量,该含磷促进剂可以按大约 1wt%-大约40wt%的含量使用。基于聚合物多元羧酸和多元醇的总重量,可以使用大约2.5wt%-大约10wt%的含磷促进剂含量。这些催化剂的实例包括但不限于,次磷酸钠、亚磷酸钠、亚磷酸钾、焦磷酸二钠、焦磷酸四钠、三聚磷酸钠、六偏磷酸钠、磷酸钾、聚偏磷酸钾、聚磷酸钾、三聚磷酸钾、三偏磷酸钠和四偏磷酸钠,以及它们的混合物。
认为可用于制备本文所述粘结剂的美国专利号5,661,213和 6,136,916中描述的包括聚合物多元羧酸的组合物包括聚合物多元羧酸、含至少两个羟基的多元醇和含磷促进剂的水溶液,其中羧酸基的当量值与羟基的当量值的比例为大约1∶0.01-大约1∶3。
如美国专利号5,661,213和6,136,916中公开那样,聚合物多元羧酸可以是含至少两个羧酸基的聚酯或含至少两种共聚合的羧酸官能化单体的加成聚合物或低聚物。聚合物多元羧酸优选是由至少一种烯属不饱和单体形成的加成聚合物。该加成聚合物可以呈以下形式:加成聚合物在含水介质中的溶液,例如已经溶于碱性介质中的碱溶性树脂;含水分散体,例如,乳液聚合的分散体;或含水悬浮液。该加成聚合物必须包含至少两个羧酸基、酸酐基团或它们的盐。基于加成聚合物的重量,可以按大约1wt%-100wt%的含量使用烯属不饱和羧酸例如,甲基丙烯酸、丙烯酸、巴豆酸、富马酸、马来酸、2-甲基马来酸、衣康酸、2-甲基衣康酸、α,β-亚甲基戊二酸、一烷基马来酸酯和一烷基富马酸酯;烯属不饱和酸酐,例如,马来酸酐、衣康酸酐、丙烯酸酐和甲基丙烯酸酐;和它们的盐。额外的烯属不饱和单体可以包括丙烯酸酯单体,包括丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯、丙烯酸2-乙基己基酯、丙烯酸癸酯、甲基丙烯酸甲酯、甲基丙烯酸丁酯、甲基丙烯酸异癸酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯和甲基丙烯酸羟丙酯;丙烯酰胺或取代的丙烯酰胺;苯乙烯或取代的苯乙烯;丁二烯;乙酸乙烯酯或其它乙烯基酯;丙烯腈或甲基丙烯腈等。包含至少两个羧酸基、酸酐基团或它们的盐的加成聚合物可以具有大约300-大约10,000,000的分子量。可以使用大约1000-大约250,000的分子量。当加成聚合物是具有羧酸、酸酐或它们的盐的碱溶性树脂时,以加成聚合物的总重量计,可以使用大约5wt%-大约30wt%的含量,大约 10,000-大约100,000的分子量。这些额外聚合物的制备方法是本领域中公知的。
如美国专利号5,661,213和6,136,916所述,多元醇(在包括聚合物多元羧酸的组合物中)包含至少两个羟基并且应该是足够非挥发性的以致它将基本上保留下来,用于在加热和固化操作过程中与组合物中的聚合物多元羧酸起反应。多元醇可以是分子量小于大约1000 的带有至少两个羟基的化合物,例如,乙二醇,甘油,季戊四醇,三羟甲基丙烷,山梨糖醇,蔗糖,葡萄糖,间苯二酚,儿茶酚,焦棓酚,乙醇酸化脲,1,4-环己烷二醇,二乙醇胺,三乙醇胺和某些反应性多元醇,例如,β-羟烷基酰胺,例如,双[N,N-二(β-羟乙基))己二酰二胺、双[N,N-二(β-羟丙基)]壬二酰胺、双[N-N-二(β-羟丙基)]己二酰二胺、双[N-N-二(β-羟丙基)]戊二酰胺、双[N-N-二(β-羟丙基)] 琥珀酰胺和双[N-甲基-N-(β-羟乙基)]草酰胺,或者它可以是含至少两个羟基的加成聚合物例如,聚乙烯醇,部分水解的聚乙酸乙烯酯,和(甲基)丙烯酸羟乙酯、(甲基)丙烯酸羟丙酯的均聚物或共聚物等。
如美国专利号5,661,213和6,136,916所述,含磷促进剂(在包括聚合物多元羧酸的组合物中)可以是分子量小于大约1000的化合物,例如碱金属次磷酸盐,碱金属亚磷酸盐,碱金属聚磷酸盐,碱金属磷酸二氢盐,多磷酸和烷基次膦酸,或者它可以是带有含磷基团的低聚物或聚合物,例如在次磷酸钠存在下形成的丙烯酸和/或马来酸的加成聚合物,在含磷盐链转移剂或终止剂存在下由烯属不饱和单体制备的加成聚合物,和含酸官能化单体残基的加成聚合物例如,共聚合的甲基丙烯酸磷酰基乙酯,和类似的膦酸酯,和共聚合的乙烯基磺酸单体,和它们的盐。基于多元酸和多元醇的总重量,该含磷促进剂可以按大约1wt%-大约40wt%的含量使用。基于多元酸和多元醇的总重量,可以使用大约2.5wt%-大约10wt%的含磷促进剂含量。
本文所使用的术语“胺碱”包括但不限于,氨,伯胺即NH2R1和仲胺即NHR1R2,其中R1和R2各自独立地在NHR1R2中被选择,并且其中 R1和R2选自本文所限定的烷基、环烷基、链烯基、环烯基、杂环基、芳基和杂芳基。示例性地,该胺碱在足以在热固化过程中促进热固性粘结剂形成的条件下可以是基本上挥发性的或基本上非挥发性的。示例性地,胺碱可以是基本上挥发性的碱,例如氨、乙胺、二乙胺、二甲胺和乙基丙基胺。或者,胺碱可以是基本上非挥发性的碱,例如苯胺、1-萘胺、2-萘胺和对氨基苯酚。
本文所使用的“还原糖”表示包含醛基,或可以异构化(即互变异构)以包含醛基的一种或多种糖,该醛基在梅拉德反应条件下可与氨基反应并且该醛基可以用例如,Cu+2氧化来提供羧酸。还可以领会,任何此类碳水化合物反应物可以是任选取代的,如被羟基、卤素、烷基、烷氧基等取代。进一步可领会,在任何此类碳水化合物反应物中,存在一个或多个手性中心,并且在每个手性中心处的两种可能的光学异构体认为包括在在此描述的本发明中。此外,还应理解的是,任何此类碳水化合物反应物的各种光学异构体,以及它们的各种几何异构体的各种混合物,包括外消旋混合物,或其它非对映体混合物可以用于在此描述的一个或多个实施方案中。
本文所使用的术语“纤维”表示适用于耐受升高的温度的耐热纤维。此类纤维的实例包括但不限于,矿物纤维、芳族聚酰胺纤维,陶瓷纤维,金属纤维,碳纤维,聚酰亚胺纤维,某些聚酯纤维,人造丝纤维和玻璃纤维。示例性地,暴露在大于大约120℃的温度下时此类纤维基本上不受影响。
图1示出了梅拉德反应的反应物的实例。胺反应物的实例包括蛋白质、肽、氨基酸、聚合物多元羧酸的铵盐和单体多元羧酸的铵盐。如所示,“铵”可以是[-NH4]x、[+NH3R1]x和[-NH2R1R2]x,其中x是至少大约1。至于-NH2R1R2,R1和R2各自独立地选择。此外,R1和R2选自如上所述的烷基、环烷基、链烯基、环烯基、杂环基、芳基和杂芳基。图1还显示了用于制备蛋白黑素的还原糖反应物的实例,包括单糖,呈它们的醛糖或酮糖形式,多糖或它们的结合物。用于制备蛋白黑素的示例性非碳水化合物羰基反应物也示出在图1中并且包括各种醛,例如丙酮醛和糠醛,以及诸如抗坏血酸和醌的化合物。
图2示出了梅拉德反应的示意图,该反应致使蛋白黑素的产生。在其初始阶段中,梅拉德反应涉及碳水化合物反应物例如,还原糖(应指出,该碳水化合物反应物可以来自能够在梅拉德反应条件下产生还原糖的物质)。该反应也涉及将该碳水化合物反应物(例如,还原糖) 与胺反应物(即具有氨基的化合物)缩合。换言之,该碳水化合物反应物和胺反应物是用于梅拉德反应的蛋白黑素反应物。这两种成分的缩合产生N-取代的葡基胺。对于梅拉德反应的更详细的描述,参见, Hodge,J.E.Chemistry of Browning Reactions inModel Systems J. Agric.Food Chem.1953,1,928-943,该文献的公开内容据此在此引入作为参考。梅拉德反应中具有游离氨基的化合物可以呈氨基酸形式存在。该游离氨基也可以来自蛋白质,其中该游离氨基可以例如,赖氨酸残基的ε-氨基,和/或末端氨基酸的α-氨基的形式获得。
在此描述的实施梅拉德反应的另一个方面在于,最初地,梅拉德反应物水溶液(其也是粘结剂)如上所述具有碱性pH值。然而,一旦将该溶液布置在非集合或松散集合物质的汇集物上,并且引发固化,该 pH值就会降低(即,该粘结剂变成酸性)。应当理解,当制造材料时,粘结剂和用于该制造的机械设备的元件之间的接触量在固化之前(即,当该粘结剂溶液是碱性时)比在粘结剂固化之后(即,当该粘结剂是酸性时)大。碱性组合物的腐蚀性比酸性组合物小。因此,降低了该制造方法的腐蚀性。
应理解的是,通过使用在此描述的梅拉德反应物水溶液,用来制造玻璃纤维的机械设备没有那么多地暴露于酸性溶液,原因在于,如上所述,梅拉德反应物溶液的pH值是碱性的。另外,在该制造过程中,酸性条件发生的唯一时间是在该粘结剂已经被涂覆到玻璃纤维上之后。一旦将该粘结剂涂覆到玻璃纤维上,与在将该粘结剂涂覆到玻璃纤维上之前的时间相比,该粘结剂和包括该粘结剂的材料与机械设备的元件具有相对更少的接触。因此,降低了玻璃纤维制造(和其它材料的制造)的腐蚀性。
不受理论束缚,梅拉德反应的多元羧酸铵盐和还原糖反应物的共价反应(该反应如本文所述基本上在热固化过程中发生以产生不同结构的棕色含氮聚合物和共聚物的蛋白黑素)被认为包括氨与还原糖碳水化合物反应物的醛结构部分的初始梅拉德反应以提供N-取代的葡基胺,如图2所示。氨如此消耗(其中氨和还原糖碳水化合物反应物结合物起潜在酸催化剂的作用)将预期导致pH值降低,该降低认为促进了多元羧酸的酯化过程和/或脱水以提供其相应的酸酐衍生物。在pH 值≤7时,N-取代的葡基胺的Amadori重排产物,即1-氨基-1-脱氧-2- 酮糖将预期主要经历1,2-烯醇化,作为蛋白黑素产生的前奏,当例如,涉及戊糖时形成糠醛,或当例如,涉及己糖时形成羟甲基糠醛。与蛋白黑素的产生并行地、同时地或顺序地,可以发生涉及蛋白黑素、多元羧酸和/或其相应的酸酐衍生物、和残余碳水化合物的酯化过程,该过程引起广泛的交联。伴随糖脱水反应,于是产生可以经历聚合的共轭双键,产生由聚酯加合物组成的耐水热固性粘结剂,该聚酯加合物通过碳-碳单键的网络互连。与上述反应一致,在本文描述的固化粘结剂的FT-IR谱图中的1734cm-1附近发生强吸收,该吸收在预计为酯羰基C-O振动的1750-1730cm-1的范围之内。上述谱图在图4中示出。
以下论述涉及(i)碳水化合物和胺反应物的实例,它们可以用于梅拉德反应和(ii)如何将这些反应物结合。首先,应当理解,将充当梅拉德反应中的反应物的任何碳水化合物和/或具有伯或仲氨基的化合物可以用于本发明的粘结剂。此类化合物可以由本领域普通技术人员采用在此公开的准则确定和使用。
至于示例性的反应物,还应理解的是,使用多元羧酸的铵盐作为胺反应物是梅拉德反应中的有效反应物。多元羧酸的铵盐可以通过用胺碱中和酸基产生,从而产生多元羧酸铵盐基团。完全的中和(即,基于当量计算的大约100%)可以排除在粘结剂形成之前任何将多元羧酸(一种或多种)中的酸基滴定或部分中和的需要。然而,可以预期的是,低于完全中和不会抑制粘结剂的形成。应指出,将多元羧酸(一种或多种)的酸基中和可以在多元羧酸(一种或多种)与碳水化合物(一种或多种)混合之前或之后进行。
至于碳水化合物反应物,它可以包括含有一种或多种还原糖的一种或多种反应物。在一个方面中,任何碳水化合物反应物应该是足够非挥发性的以使其能够保留下来以与多元羧酸铵盐反应物进行反应的能力最大化。该碳水化合物反应物可以是呈其醛糖或酮糖形式的单糖,包括丙糖、丁糖、戊糖、己糖或庚糖;或多糖;或它们的结合物。碳水化合物反应物可以是还原糖,或能够在热固化条件下就地产生一种或多种还原糖的反应物。例如,当丙糖充当碳水化合物反应物时,或与其它还原糖和/或多糖结合使用时,可以使用丙醛糖或丙酮糖,例如分别为甘油醛和二羟基丙酮。当丁糖充当碳水化合物反应物时,或与其它还原糖和/或多糖结合使用时,可以使用丁醛糖,例如赤藓糖和苏糖;和丁酮糖,如赤藓酮糖。当戊糖充当碳水化合物反应物时,或与其它还原糖和/或多糖结合使用时,可以使用戊醛糖,如核糖、阿拉伯糖、木糖和来苏糖;和戊酮糖,如核酮糖、阿拉伯酮糖、木酮糖和 lvxulose。当己糖充当碳水化合物反应物时,或与其它还原糖和/或多糖结合使用时,可以使用己醛糖,如葡萄糖(即,右旋糖)、甘露糖、半乳糖、阿洛糖、阿卓糖、塔罗糖、古洛糖和艾杜糖;和己酮糖,如果糖、阿洛酮糖、山梨糖和塔格糖。当庚糖充当碳水化合物反应物时,或与其它还原糖和/或多糖结合使用时,可以使用庚酮糖如景天庚酮糖。此类碳水化合物反应物的尚且未知天然存在的其它立体异构体也认为可用于制备在此描述的粘结剂组合物。当多糖充当碳水化合物时,或与单糖结合使用时,可以使用蔗糖、乳糖、麦芽糖,淀粉和纤维素。
另外,梅拉德反应中的碳水化合物反应物可以与非碳水化合物多羟基反应物结合使用。可以与所述碳水化合物反应物结合使用的非碳水化合物多羟基反应物的实例包括但不限于,三羟甲基丙烷、甘油、季戊四醇、聚乙烯醇、部分水解的聚乙酸乙烯酯、完全水解的聚乙酸乙烯酯和它们的混合物。在一个方面中,该非碳水化合物多羟基反应物是足够非挥发性的以使其能够保留下来以与单体或聚合物多元羧酸反应物进行反应的能力最大化。应领会,非碳水化合物多羟基反应物的疏含水可以是确定如在此所述制备的粘结剂的物理性能的一个因素。
当部分水解的聚乙酸乙烯酯充当非碳水化合物多羟基反应物时,可以使用可商购的化合物如87-89%水解的聚乙酸乙烯酯,如DuPont ELVANOL 51-05。DuPont ELVANOL 51-05具有大约22,000-26,000Da 的分子量和大约5.0-6.0厘泊的粘度。认为可用于制备在此描述的粘结剂组合物的其它部分水解的聚乙酸乙烯酯包括但不限于,分子量和粘度与ELVANOL 51-05不同的87-89%水解的聚乙酸乙烯酯,如 DuPont ELVANOL 51-04、ELVANOL51-08、ELVANOL 50-14、ELVANOL 52-22、ELVANOL 50-26、ELVANOL 50-42;和分子量、粘度和/或水解度与ELVANOL 51-05不同的部分水解的聚乙酸乙烯酯,例如DuPont ELVANOL 51-03(86-89%水解)、ELVANOL 70-14(95.0-97.0%水解)、 ELVANOL 70-27(95.5-96.5%水解)、ELVANOL 60-30(90-93%水解)。认为可用于制备在此描述的粘结剂组合物的其它部分水解的聚乙酸乙烯酯包括但不限于,Clariant MOWIOL 15-79、MOWIOL 3-83、MOWIOL 4-88、MOWIOL 5-88、MOWIOL 8-88、MOWIOL18-88、MOWIOL 23-88、 MOWIOL 26-88、MOWIOL 40-88、MOWIOL 47-88和MOWIOL 30-92,以及Celanese CELVOL 203、CELVOL 205、CELVOL 502、CELVOL 504、 CELVOL 513、CELVOL 523、CELVOL 523TV、CELVOL 530、CELVOL 540、 CELVOL540TV、CELVOL 418、CELVOL 425和CELVOL 443。还认为有用的是可以从其它商业供应商获得的类似的或相似的部分水解聚乙酸乙烯酯。
当完全水解的聚乙酸乙烯酯充当非碳水化合物多羟基反应物时,可以使用分子量为大约27,000Da的Clariant MOWIOL 4-98。认为有用的其它完全水解的聚乙酸乙烯酯包括但不限于,DuPont ELVANOL 70-03(98.0-98.8%水解)、ELVANOL 70-04(98.0-98.8%水解)、 ELVANOL 70-06(98.5-99.2%水解)、ELVANOL 90-50(99.0-99.8%水解)、ELVANOL70-20(98.5-99.2%水解)、ELVANOL 70-30(98.5-99.2 %水解)、ELVANOL 71-30(99.0-99.8%水解)、ELVANOL 70-62(98.4-99.8%水解)、ELVANOL 70-63(98.5-99.2%水解)、ELVANOL 70-75(98.5-99.2%水解)、Clariant MOWIOL 3-98、MOWIOL 6-98、MOWIOL 10-98、MOWIOL 20-98、MOWIOL 56-98、MOWIOL 28-99 和Celanese CELVOL 103、CELVOL 107、CELVOL 305、CELVOL 310、 CELVOL 325、CELVOL 325LA和CELVOL 350,以及得自其它商业供应商的类似的或相似的完全水解聚乙酸乙烯酯。
上述梅拉德反应物可以结合来制备包括碳水化合物反应物和胺反应物的含水组合物。这些含水粘结剂代表未固化粘结剂的实例。如下所论述,这些含水组合物可以用作本发明的粘结剂。这些粘结剂是无甲醛、可固化、碱性、含水粘结剂组合物。另外,如上所指出,梅拉德反应物的碳水化合物反应物可以与非碳水化合物多羟基反应物结合使用。因此,提及碳水化合物反应物的任何时候,应当理解它可以与非碳水化合物多羟基反应物结合使用。
在一个示例性的实施方案中,梅拉德反应物的水溶液可以包括(i) 一种或多种多元羧酸的铵盐反应物和(ii)含有还原糖的一种或多种碳水化合物反应物。在让它与待粘结材料接触之前,这一溶液的pH值可以大于或等于大约7。此外,这一溶液可以具有小于或等于大约10的 pH值。多元羧酸反应物(一种或多种)的摩尔数与碳水化合物反应物 (一种或多种)的摩尔数的比例可以为大约1∶4-大约1∶15。在一个实例中,粘结剂组合物中的多元羧酸反应物(一种或多种)的摩尔数与碳水化合物反应物(一种或多种)的摩尔数的比例为大约1∶5。在另一个实例中,多元羧酸反应物(一种或多种)的摩尔数与碳水化合物反应物(一种或多种)的摩尔数的比例为大约1∶6。在又一个实例中,多元羧酸反应物(一种或多种)的摩尔数与碳水化合物反应物(一种或多种)的摩尔数的比例为大约1∶7。
如上所述,含水粘结剂组合物包括(i)一种或多种多元羧酸的铵盐反应物和(ii)含有还原糖的一种或多种碳水化合物反应物。应理解的是,当单体或聚合物多元羧酸的铵盐用作胺反应物时,铵离子的摩尔当量可以等于或可以不等于多元羧酸上存在的酸式盐基团(acid salt group)的摩尔当量。在一个示例性的实例中,当三羧酸用作多元羧酸反应物时,铵盐可以是一取代、二取代或三取代的。因此,铵离子的摩尔当量可以按小于或大致等于多元羧酸中存在的酸式盐基团的摩尔当量的量存在。因此,当多元羧酸反应物是二羧酸时,该盐可以是一取代或二取代的。此外,铵离子的摩尔当量可以按小于或大致等于聚合物多元羧酸中存在的酸式盐基团的摩尔当量的量存在,等等。当使用二羧酸的一取代盐时,或当使用三羧酸的二取代盐时,或当铵离子的摩尔当量按小于聚合物多元羧酸中存在的酸式盐基团的摩尔当量的量存在时,粘结剂组合物的pH值可以要求调节到达到碱性。
所述未固化、无甲醛、可热固化、碱性、含水粘结剂组合物可以用来制造许多不同的材料。具体来说,通过将这些粘结剂置于与待粘结的物质接触,可以使用所述粘结剂在非集合或松散集合的物质中产生或促进粘结力。许多熟知的技术可以用来将该含水粘结剂置于与待粘结的材料接触。例如,可以经由辊涂装置将该含水粘结剂喷涂(例如在粘结玻璃纤维过程中)或涂覆。
可以在玻璃纤维绝缘产品的制备过程中将这些含水粘结剂涂覆到玻璃纤维的垫上(例如,喷涂到该垫上)。一旦让该含水粘结剂与玻璃纤维接触,来自该玻璃纤维的残余热(应指出,该玻璃纤维由熔融玻璃制成并且因此包含残余热)和穿过该纤维垫的空气流将使水从粘结剂中蒸发(即除去)。将水除去使粘结剂的剩余组分作为粘性或半粘性高固体液体的涂层保留在纤维上。这一粘性或半粘性高固体液体的涂层起粘结剂作用。此时,该纤维垫还没有被固化。换言之,该未固化的粘结剂用来粘结该纤维垫中的玻璃纤维。
另外,应当理解,可以将上面描述的含水粘结剂固化。例如,任何上面描述的含水粘结剂可以布置(例如,喷涂)在待粘结的材料上,然后加热。例如,在制备玻璃纤维绝缘产品的情况下,在已经将含水粘结剂涂覆到纤维垫上之后,将该粘结剂涂覆的纤维垫转移至固化炉中。在该固化炉中,将该纤维垫加热(例如,大约300°F-大约600°F) 并且固化该粘结剂。该固化的粘结剂是将该纤维垫的玻璃纤维粘接在一起的无甲醛、耐水性热固性粘结剂。应指出,可以顺序地、同时地或并行地进行干燥和热固化。
至于制造水不溶性粘结剂,当固化时,应理解的是,多元羧酸反应物(一种或多种)上存在的酸式盐基团的摩尔当量数与碳水化合物反应物(一种或多种)上存在的羟基的摩尔当量数的比例可以为大约 0.04∶1-大约0.15∶1。在固化后,这些配制剂产生耐水性热固性粘结剂。在一个变体中,碳水化合物反应物(一种或多种)上存在的羟基的摩尔当量数为多元羧酸反应物(一种或多种)上存在的酸式盐基团的摩尔当量数的大约二十五倍。在另一个变体中,碳水化合物反应物(一种或多种)上存在的羟基的摩尔当量数为多元羧酸反应物(一种或多种) 上存在的酸式盐基团的摩尔当量数的大约十倍。在又一个变体中,碳水化合物反应物(一种或多种)上存在的羟基的摩尔当量数为多元羧酸反应物(一种或多种)上存在的酸式盐基团的摩尔当量数的大约六倍。
在本发明的其它实施方案中,已经固化的粘结剂可以布置在待粘结的材料上。如上所指出,大多数固化的粘结剂通常将包含水不溶性蛋白黑素。因此,这些粘结剂还将是耐水的热固性粘结剂。
如下所论述,可以将各种添加剂引入粘结剂组合物中。这些添加剂为本发明粘结剂赋予附加的合乎需要的特性。例如,粘结剂可以包括含硅偶联剂。许多含硅偶联剂可从Dow-Corning Corporation,Petrarch Systems商购,和通过General Electric Company商购。示例性地,含硅偶联剂包括化合物例如硅醚(silyl ether)和烷基硅醚(alkylsilylether),它们中的每一种可以是任选取代的,例如被卤素、烷氧基、氨基等取代。在一个变体中,该含硅化合物是氨基-取代的硅烷,例如γ-氨丙基三乙氧基硅烷(General ElectricSilicones,SILQUEST A-1101;Wilton,CT;USA)。在另一个变体中,含硅化合物是氨基-取代的硅烷,例如,氨乙基氨丙基三甲氧基硅烷(Dow Z-6020;Dow Chemical,Midland,MI;USA)。在另一个变体中,含硅化合物是γ-缩水甘油氧基丙基三甲氧基硅烷(General ElectricSilicones,SILQUEST A-187)。在又一个变体中,含硅化合物是正丙基胺硅烷(Creanova(从前是Huls America)HYDROSIL 2627;Creanova;Somerset,NJ.;U.S.A.)。
基于溶解的粘结剂固体,所述含硅偶联剂通常按大约0.1wt%-大约1wt%存在于该粘结剂中(即,基于添加到水溶液中的固体的重量,大约0.1%-大约1%)。在一个应用中,可以将这些含硅化合物中的一种或多种添加到含水未固化的粘结剂中。然后将该粘结剂涂覆到待粘结的材料上。之后,如果需要的话,可以将粘结剂固化。这些含硅氧烷的化合物提高了该粘结剂粘附于在其上布置该粘结剂的物质(例如玻璃纤维)的能力。例如,提高该粘结剂粘附于该物质的能力改进了其在非集合或松散集合的物质(一种或多种)中产生或促进粘结力的能力。
包括含硅氧烷偶联剂的粘结剂可以如下制备:将一种或多种多元羧酸反应物的大约10-大约50wt%的水溶液(已经用胺碱中和或就地中和)与含有还原糖的一种或多种碳水化合物反应物的大约10-50wt %的水溶液、和有效量含硅偶联剂混合。在一个变体中,一种或多种多元羧酸反应物和一种或多种碳水化合物反应物(后者含有还原糖)可以作为固体结合,与水混合,然后用含水胺碱(以中和一种或多种多元羧酸反应物)和含硅偶联剂处理该混合物以产生各多元羧酸反应物和各碳水化合物反应物的10-50wt%的水溶液。
在另一个示例性的实施方案中,本发明的粘结剂可以包括一种或多种缓蚀剂。这些缓蚀剂阻止或抑制了由化学分解所引起的物质如金属的腐蚀或磨损,该化学分解由酸造成。当缓蚀剂包括在本发明的粘结剂中时,与其中不存在缓蚀剂的粘结剂的腐蚀性相比,降低了该粘结剂的腐蚀性.在一个实施方案中,这些缓蚀剂可以用来降低本文描述的含玻璃纤维的组合物的腐蚀性。示例性地,缓蚀剂包括以下物质中的一种或多种:除尘油,或磷酸一铵、偏硅酸钠五水合物、蜜胺、草酸锡(II)和/或甲基含氢硅氧烷流体乳液(methylhydrogen silicone fluid emulsion)。当包括在本发明粘结剂中时,基于溶解的粘结剂固体,缓蚀剂通常按大约0.5wt%-大约2wt%存在于该粘结剂中。
通过遵循所公开的准则,本领域普通技术人员将能改变含水粘结剂的反应物的浓度以制备各种各样的粘结剂组合物。具体来说,含水粘结剂组合物可以经配制具有碱性pH值。例如,pH值为大于或等于大约7至小于或等于大约10。可以被操控的粘结剂反应物的实例包括 (i)多元羧酸反应物(一种或多种),(ii)胺碱,(iii)碳水化合物反应物(一种或多种),(iv)含硅偶联剂和(V)缓蚀剂化合物。让本发明的含水粘结剂(例如未固化的粘结剂)的pH值在碱性范围内抑制了与该粘结剂接触的材料,例如制造方法中使用的机器(例如,在制造玻璃纤维中)的腐蚀。应指出,当将酸性粘结剂的腐蚀性与本发明的粘结剂相比时,情况尤其如此。因此,机械设备的“使用期限”增加,同时这些机器的维护成本减小。另外,标准设备可以与本发明的粘结剂一起使用,而不是必须使用将与酸性粘结剂接触的较耐腐蚀性的机器元件,例如不锈钢元件。因此,本文公开的粘结剂降低了所粘结材料的制造成本。
以下实施例更详细地说明了特定实施方案。这些实施例仅是出于说明性目的提供的,并且不应理解为以任何方式将本发明或本发明构思限制到任何特殊的物理构型。例如,虽然在实施例1中将柠檬酸三铵和右旋糖一水合物中的每一种的25%(wt%)水溶液混合以制备含水粘结剂,但是应该理解的是,在本文描述的实施方案的变体中,可以改变多元羧酸铵盐反应物水溶液的重量百分率和还原糖碳水化合物反应物水溶液的重量百分率,而不会影响所描述的本发明的性质。例如,将多元羧酸铵盐反应物的水溶液和还原糖碳水化合物反应物的水溶液混合,它们的重量百分率在大约10-50wt%的范围内。此外,虽然在实施例8-12中使用柠檬酸三铵和右旋糖一水合物溶解的固体占 10-50%(wt%)的水溶液制备粘结剂/玻璃纤维组合物,但是应该理解的是,可以改变含该多元羧酸铵盐反应物/含该还原糖碳水化合物反应物的水溶液的重量百分率,而不会影响所描述的本发明的性质。例如,制备包括多元羧酸铵盐反应物和还原糖碳水化合物反应物的水溶液,它们的重量百分率在大约10-50wt%的范围之外。此外,虽然以下实施例包括多元羧酸的铵(即+NH4)盐作为多元羧酸铵盐反应物,但是应该理解的是,可以使用替换的胺反应物,而不会影响所描述的本发明的性质,例如包括多元羧酸的伯胺盐或仲胺盐。
实施例1
含水柠檬酸三铵-右旋糖粘结剂的制备
根据以下程序制备含水柠檬酸三铵-右旋糖粘结剂:在室温下按体积比将柠檬酸三铵(81.9g柠檬酸、203.7g水和114.4g 19%的氨溶液)和右旋糖一水合物(在150.0g水中的50.0g右旋糖一水合物) 的水溶液(25%)结合:1∶24,1∶12,1∶8,1∶6,1∶5,1∶4和1∶3,其中柠檬酸三铵的相对体积列为“1”。例如,与50mL含水右旋糖一水合物混合的10mL含水柠檬酸三铵提供“1∶5”的溶液,其中柠檬酸三铵与右旋糖一水合物的质量比为大约1∶5,柠檬酸三铵与右旋糖一水合物的摩尔比为大约1∶6,柠檬酸三铵上存在的酸式盐基团的摩尔当量数与右旋糖一水合物上存在的羟基的摩尔当量数的比例为大约 0.10∶1。在室温下搅拌所得的溶液数分钟,此时,将2g样品取出并如实施例2所述进行热固化。
实施例2
由含水柠檬酸三铵-右旋糖粘结剂制备固化的柠檬酸三铵-右旋糖粘结剂样品
将2g如实施例1制备的每种粘结剂的样品放置到三个各1g的铝烘烤盘上。然后让每种粘结剂在预加热的恒温对流炉中经历以下三种常规的烘烤/固化条件以制备相应的固化粘结剂样品:在400°F下15 分钟,在350°F下30分钟,在300°F下30分钟。
实施例3
由含水柠檬酸三铵-右旋糖粘结剂制备的固化柠檬酸三铵-右旋糖粘结剂样品的试验/评价
在将水添加到该铝烘烤盘中并随后在室温下静置之后,通过固化粘结剂样品看起来保持完整并且抵抗溶解的程度,测定如实施例2制备的每种固化的柠檬酸三铵-右旋糖粘结剂样品的湿强度。湿强度标明为溶解(没有湿强度),部分溶解(最小湿强度),软化(中等湿强度),或不可渗透(高湿强度,水不溶性的)。还测定由水与固化的柠檬酸铵- 右旋糖粘结剂样品接触产生的水颜色。下表1示出了根据实施例1制备的柠檬酸三铵-右旋糖粘结剂的示例性实例,根据实施例2的用于它们的固化条件和根据实施例3的试验和评价结果。
实施例4
固化的柠檬酸三铵-右旋糖(1∶6)粘结剂样品的元素分析
对5g如实施例1所述制备并如下所述固化的15%柠檬酸三铵- 右旋糖(1∶6)粘结剂进行碳、氢和氮(即,C、H、N)的元素分析,该0.75 g固化样品包括大约1∶6的柠檬酸三铵与右旋糖一水合物的摩尔比。随温度和时间变化如下固化粘结剂样品:300°F保持1小时;350°F保持0.5小时;和400°F保持0.33小时。在Knoxville,TN的Galbraith Laboratories,Inc.进行元素分析。如表2所示,元素分析揭示在 300°F-350°F内C∶N比例随温度的增加而增加,该结果与已经制备的含蛋白黑素的粘结剂一致。此外,随温度的增加C∶H比例的增加也在表2中示出,该结果与在粘结剂固化过程中发生的脱水(已知的在蛋白黑素形成过程中发生的过程)一致。
实施例5
用来构造玻璃珠壳骨(shell bone)、含玻璃纤维的垫和木纤维板组合物的多元羧酸铵-糖粘结剂的制备
通过以下一般程序制备含水柠檬酸三铵-右旋糖(1∶6)粘结剂,该粘结剂用来构造玻璃珠壳骨和含玻璃纤维的垫:在其中添加了880g 蒸馏水的1加仑反应容器中将粉末状右旋糖一水合物(915g)和粉末状无水柠檬酸(152.5g)结合。在搅拌下向这一混合物中添加265g 19 %的氨水,继续搅拌分钟以达到固体的完全溶解。向所得的溶液中添加3.3gSILQUEST A-1101硅烷以产生pH值~8-9的溶液(使用pH试纸),该溶液含有大约50%的溶解的右旋糖一水合物和溶解的柠檬酸铵固体(按溶液总重量的百分率);在400°F下热固化30分钟后,2g 这一溶液的样品将产生30%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。当除SILQUEST A-1101以外的硅烷包括在柠檬酸三铵-右旋糖(1∶6)粘结剂中时,用SILQUEST A-187硅烷、HYDROSIL 2627硅烷或Z-6020硅烷作出替换。当添加剂包括在柠檬酸三铵-右旋糖(1∶6)粘结剂中以产生粘结剂变体时,以300g等分试样将标准溶液分配在瓶子中,然后向其中提供各种添加剂。
干燥(未固化的)柠檬酸三铵-右旋糖(1∶6)粘结剂的FT-IR谱在图 3中示出,作为由在真空中干燥的10g 30%(溶解的粘结剂固体)粘结剂样品的微观薄膜获得该谱。固化的柠檬酸三铵-右旋糖(1∶6)梅拉德粘结剂的FT-IR谱图在图4中示出,该谱作为由在固化后的10g30 %(溶解的粘结剂固体)粘结剂样品的微观薄膜获得。
当除柠檬酸以外的多元羧酸,除右旋糖以外的糖,和/或添加剂用来制备含水多元羧酸铵-糖粘结剂变体时,使用与上述制备含水柠檬酸三铵-右旋糖(1∶6)粘结剂相同的一般程序。对于多元羧酸铵-糖粘结剂变体,根据需要作出调节以适应例如,二羧酸或聚合物多元羧酸而不是柠檬酸的加入,或适应例如,丙糖而不是右旋糖的加入,或适应例如,一种或多种添加剂的加入。这些调节包括,例如,调节为产生铵盐所必需的氨水的体积,调节为达到多元羧酸铵与糖的所需摩尔比所必需的反应物的量(克),和/或按所需重量百分率包括添加剂。
实施例6
用多元羧酸铵-糖粘结剂制备的玻璃珠壳骨组合物的制备/风化/ 试验
当评价它们的干拉伸强度和“风化”拉伸强度时,用给定粘结剂制备的含玻璃珠的壳骨组合物分别提供采用该特定粘结剂制备的玻璃纤维绝缘材料的可能的拉伸强度和可能的耐久性的示值。预计的耐久性基于壳骨的风化拉伸强度:干拉伸强度的比例。如下制备、风化和试验壳骨:
壳骨的制备程序:
将壳骨模具(Dietert Foundry Testing Equipment;Heated Shell CuringAccessory,Model 366,和Shell Mold Accessory)设置到所需的温度(通常425°F),和使之加热至少一小时。在加热该壳骨模具的同时,如实施例5所述制备大约100g含水多元羧酸铵-糖粘结剂(通常,粘结剂固体占30%)。使用大的玻璃烧杯,通过差值称量727.5g 玻璃珠(Quality Ballotini Impact Beads,Spec.AD,US Sieve 70-140, 106-212微米-#7,得自Potters Industries,Inc.)。将玻璃珠倒入清洁和干燥的混合碗中,该碗安装在电动混合机支架上。获得了大约 75g含水多元羧酸铵-糖粘结剂,然后缓慢地将该粘结剂倒入该混合碗中的玻璃珠中。然后启动该电动混合机并搅拌该玻璃珠/多元羧酸铵 -糖粘结剂混合物一分钟。使用大的抹刀,刮擦搅拌机(混合机)的侧面以除去任何粘结剂的块体,同时还刮擦边缘,其中玻璃珠位于该碗的底部。然后重新启动该混合机另外一分钟,然后从装置中取出该搅拌器(混合机),接着取出装有该玻璃珠/多元羧酸铵-糖粘结剂混合物的混合碗。使用大的抹刀,尽可能多地除去附贴到搅拌器(混合机)上的粘结剂和玻璃珠,然后搅拌到混合碗中的玻璃珠/多元羧酸铵-糖粘结剂混合物中。然后刮擦该碗的侧面以混合任何过量的可能在该侧面上聚集的粘结剂。此时,该玻璃珠/多元羧酸铵-糖粘结剂混合物准备好在壳骨模具中模塑。
壳骨模具的滑道据证实在底部模具压盘内定向排列。使用大的抹刀,然后将玻璃珠/多元羧酸铵-糖粘结剂混合物迅速地添加到在壳骨模具内的三个模具内腔中。弄平每个内腔中的混合物的表面,同时刮去过量的混合物以赋予该壳骨均匀的表面区域。用另外的玻璃珠/多元羧酸铵-糖粘结剂混合物填充存在于任何内腔中的任何不一致或间隙。一旦将玻璃珠/多元羧酸铵-糖粘结剂混合物放入该壳骨内腔,并且使该混合物暴露于热下,固化就开始。因为操控时间会影响试验结果,例如,可能产生具有两个不同固化的层的壳骨,所以一致和迅速地制备壳骨。将该壳骨模具填充之后,就将该顶部压盘迅速地放置在底部压盘上。同时,或其后迅速地,利用秒表启动固化时间的测量,在该固化期间,底部压盘的温度为大约400°F-大约430°F,而顶部压盘的温度为大约440°F-大约470°F。在七分钟过去时,取出顶部压盘并且拔出滑道以致可以取出所有三个壳骨。然后将该新制备的壳骨放置在与该壳骨模具压盘相邻的线架上,并且使之冷却到室温。其后,标记每个壳骨并单独地放置在适当标记的塑料储存袋中。如果不能在制备它们的当天试验壳骨,则将该装有壳骨的塑料袋放入干燥器装置中。
壳骨的调湿(风化)程序:
启动Blue M湿度箱然后经设置提供90°F和90%相对湿度(即, 90°F/90%rH)的风化条件。定期地检测和填充该湿度箱一侧上的水箱,通常每当将它启动时那样做。使该湿度箱在至少4小时的期间内达到规定的风化条件,其中一天的平衡时间是典型的。迅速地装载待风化的壳骨(因为当门打开时,湿度和温度都下降),一次让一个壳骨穿过打开的湿度箱门装载到该湿度箱的上部开槽支架上。记录将该壳骨放入湿度箱中的时间,并且进行风化24小时。其后,打开该湿度箱门并且每次迅速地取出一组壳骨并且单独地放入相应的将被完全密封的塑料储存袋中。通常,每次如上所述将一至四组壳骨风化。立即将经风化的壳骨拿到Instron室中并进行试验。
将壳骨破碎的试验程序:
在该Instron室中,壳骨试验方法加载在5500 R Instron机器上,同时确保安装合适的测力传感器(即,静态测力传感器5kN),并且使该机器暖机十五分钟。在这个时间过程中,校验壳骨试验夹具安装在机器上。将该测力传感器调零并平衡,然后每次如下试验一组壳骨:从壳骨塑料储存袋中取出壳骨然后称量。然后将该重量(克)输入与该 Instron机器连接的计算机中。然后将壳骨的测量厚度(英寸),作为试样厚度,输入与该Instron机器连接的计算机三次。然后将壳骨试样放入Instron机器上的夹具中,并且经由该Instron机器上的键板启动试验。在取出壳骨试样之后,将测量的断裂点输入与该Instron 机器连接的计算机中,并且继续试验直到一组中的所有壳骨被试验。
试验结果在表3-6中示出,该结果是平均干拉伸强度(psi),平均风化拉伸强度(psi)和风化拉伸强度:干拉伸强度的比例。
实施例7
用多元羧酸铵-糖(1∶6)粘结剂制备的含玻璃纤维的纤维垫的制备 /风化/试验
当评价它们的干拉伸强度和“风化”拉伸强度时,用给定粘结剂制备的含玻璃纤维的纤维垫分别提供采用该特定粘结剂制备的玻璃纤维绝缘材料的可能的拉伸强度和可能的耐久性的示值。预计的耐久性基于玻璃纤维垫的“风化”拉伸强度:干拉伸强度的比例。如下制备,风化和试验玻璃纤维垫:
含玻璃纤维的纤维垫的制备程序:
用透明的丙烯酸类树脂板材构造13英寸高×13英寸宽×14英寸深的“Deckel箱”,并与铰链金属框架连接。将多孔板和粗金属筛网的系统安装在Deckel箱下,作为从该箱子到3英寸排水管的过渡段。在该Deckel箱下将织造塑料带(称作“线路”)夹紧。对于混合目的,使用5加仑料桶,该料桶配备有内部垂直肋和高剪切空气马达混合机。通常,将4加仑水和E-玻璃(即,耐热玻璃)纤维(11g,22g或33g) 混合两分钟。典型的E-玻璃具有以下重量百分率组成:SiO2,52.5%; Na2O,0.3%;CaO,22.5%;MgO,1.2%;Al2O3,14.5%;FeO/Fe2O3,0.2%;K2O,0.2%;和B2O3,8.6%。排水管和在线路下的过渡段已预先用水填充以致该Deckel箱的底部是湿润的。将含水玻璃纤维混合物倒入该Deckel箱子并用包含四十九(49)个一英寸孔的板垂直地搅拌。迅速地打开在该排水管线底部的滑动阀并在线路上收集玻璃纤维。已经在该线路下就位的筛网覆盖的框架促进该玻璃纤维样品的转移。借助通过具有25-40英寸水柱吸水管的提取器狭槽将该样品脱水。对于11g样品使用一次通过,对于22g样品使用二次通过,对于33g 样品使用三次通过。将样品转移至第二个筛网覆盖的框架并且取出该成型线。然后将该样品干燥并与该筛网分离。随后,使该样品通过在包含含水多元羧酸铵-糖粘结剂(包含15%如实施例5所述制备的溶解的粘结剂固体)的浴中旋转的3-英寸直径涂布辊,其中该玻璃纤维是用粘结剂饱和的。如下萃取过量的粘结剂:再次通过提取器狭槽以制备含玻璃纤维的纤维垫,在375°F下在炉子中将该纤维垫固化30分钟,该炉子具有向上流动的强制对流空气。
玻璃纤维垫的调湿(风化)程序:
将待调湿的含玻璃纤维的纤维垫放置在TEFLON涂覆的 course-weave带上并且加重以阻止漂浮。对于每种所评价的多元羧酸铵-糖粘结剂,制备一对样品纤维垫。在空气调节的而不是湿度受控的房间中在环境温度和湿度下将该纤维垫调理至少一天。使用具有合适轮廓的冲模从每个纤维垫上切下七个试验样品;按一个方向切下六个试样,按垂直方向切下一个试样,其中每个试样保持分离。每个试样是2英寸宽并且在中部缩减到1英寸宽,而长度大约为12英寸。将每个纤维垫的三个试样放入在37-38℃和90%相对湿度下的“风化”箱中保持24小时。从该箱中取出经风化的试样并储存在可密封的塑料袋中,每个袋子装有湿纸巾,直到即将试验。将玻璃纤维垫破裂的试验程序:
以0.5英寸/分钟的十字头速度设置拉伸试验机。该夹具爪是2 英寸宽并且具有大约1.5英寸夹具。将每个纤维垫的三个干燥试样和三个风化试样进行试验。将干燥试样用于粘结剂含量测量,由烧失量 (LOI)测定。
试验结果在表7中示出,该结果是平均%LOI,平均干拉伸强度 (1b力),平均风化拉伸强度(1b力)和风化拉伸强度:干拉伸强度的比例。
实施例8
柠檬酸三铵-右旋糖(1∶6)粘结剂/玻璃纤维组合物的制备:
未固化的毯子和固化的毯子
在260加仑箱子(tote)中将粉末状右旋糖一水合物(300 1b)和粉末状无水柠檬酸(501b)结合。然后添加软水以达到235加仑的体积。向该混合物中添加9.5加仑19%氨水,并搅拌所得的混合物以达到固体的完全溶解。向所得的溶液中添加0.56 1b SILQUEST A-1101硅烷以产生溶液,该溶液含有15.5%的溶解的右旋糖一水合物和溶解的柠檬酸铵固体(按溶液总重量的百分率);在400°F下热固化30分钟后, 2g这一溶液的样品将产生9.3%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。搅拌该溶液数分钟然后输送到粘结剂泵,其中将它用于制造玻璃纤维绝缘材料,具体来说,形成称为“湿毯子”或未固化的毯子,和“淡黄色毯子”或固化毯子的材料。
使用常规的玻璃纤维制造程序制备未固化的毯子和固化的毯子;此类程序在下面和在美国专利号5,318,990中进行了一般描述,该文献的公开内容据此在此引入作为参考。通常,将粘结剂涂覆到正在生产并形成纤维垫的玻璃纤维上,使水从该粘结剂中挥发,并且将该高固体粘结剂涂覆的玻璃纤维垫加热以使该粘结剂固化并从而制备成品玻璃纤维棒(bat),该玻璃纤维棒可以例如,用作隔热或隔音产品,用于随后制备的复合材料的增强材料等。
如下制备玻璃纤维的多孔纤维垫:将熔融玻璃纤维化并在移动式输送机上立即形成玻璃纤维垫。将玻璃在槽中熔融并供给成纤设备例如旋转器或衬套。将来自该设备的玻璃的纤维细化然后在成型腔室内通常向下吹送。该玻璃纤维通常具有大约2-大约9微米的直径和大约 0.25英寸-大约3英寸的长度。通常,该玻璃纤维的直径为大约3-大约6微米,并且具有大约0.5英寸-大约1.5英寸的长度。在穿孔的环形成型输送机上沉积玻璃纤维。利用适合的喷涂器将粘结剂涂覆到正在进行成型的玻璃纤维上,以致该粘结剂分布在玻璃纤维的所形成的整个纤维垫中。将具有与其粘附的未固化粘结剂的玻璃纤维聚集并借助于从成型输送机下方经由纤维垫抽吸的真空在该成型腔室内的环形输送机上形成纤维垫。包含在玻璃纤维中的残余热以及流过该纤维垫的空气流引起大部分水在纤维垫离开该成型腔室之前从该纤维垫中挥发。(将水除去到未固化的粘结剂起粘结剂作用的程度;对于任何特定的应用,待除去的水的量可以通过本领域普通技术人员用常规试验测定)。
随着该高固体粘结剂涂覆的玻璃纤维纤维垫从该成型腔室排出,它垂直地膨胀,这归因于该玻璃纤维的回弹。然后将该膨胀纤维垫输送到并穿过固化炉,其中让热空气穿过该纤维垫以使该粘结剂固化。在该纤维垫上方和下方的刮板稍微压制该纤维垫以赋予成品预定的厚度和表面光洁度。通常,在大约350°F-大约600°F的温度下操作该固化炉。一般地,纤维垫在该炉子内停留大约0.5分钟-大约3分钟的时间。为了制造常规的隔热或隔音产品,该时间为大约0.75分钟-大约 1.5分钟。具有固化的、刚性粘结剂基体的玻璃纤维从该炉子以棒材形式排出,该棒材可以进行压缩以便包装和装运并且此后当松开时将基本恢复其制造时的垂直尺寸。举例来说,从成型腔室离开时厚度为大约1.25英寸的玻璃纤维垫在转移区中将膨胀到大约9英寸的垂直厚度,并且在固化炉中将稍微压制到大约6英寸的垂直厚度。
如上所述制备的固化毯子产品的标称规格是大约0.09磅/平方英尺的重量,大约0.7磅/立方英尺的密度,大约1.5英寸的厚度,大约十万分之22英寸(5.6微米)的纤维直径,在固化后大约11%的粘结剂含量,和用于除尘的大约0.7%的矿物油含量(除尘油)。将固化炉温度设置在大约460°F。离开成型腔室的未固化毯子表观颜色呈白色至灰白色,而离开该炉子的固化毯子表观颜色呈暗褐色并且是充分粘结的。在收集数卷固化毯子之后,在炉子之前将该垫子破碎,并且还收集未固化的毯子用于实验。
实施例9
柠檬酸三铵-右旋糖(1∶6)粘结剂/玻璃纤维组合物的制备:
风道板
在装有743.2加仑软水的2000加仑混合槽中将粉末状右旋糖一水合物(1800 1b)和粉末状元水柠檬酸(300 1b)结合。在搅拌下向这一混合物中添加52.9加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加9 1b SILQUBST A-1101硅烷以产生 pH值~8的溶液(使用pH试纸),该溶液含有大约25%的溶解的右旋糖一水合物和溶解的柠檬酸铵固体(按溶液总重量的百分率);在400°F 下热固化30分钟后,2g这一溶液的样品将产生15%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将该溶液搅拌数分钟,然后转移至粘结剂收集槽中,从该粘结剂收集槽将该溶液用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“风道板”的产品。
使用常规的玻璃纤维制造程序制备风道板;此类程序在实施例8 中进行了一般性描述。该风道板产品的标称规格是大约0.4磅/平方英尺的重量,大约4.5磅/立方英尺的密度,1英寸的厚度,大约十万分之32英寸(8.1微米)的纤维直径,和大约14.3%的粘结剂含量,和用于除尘的0.7%的矿物油(除尘油)。将固化炉温度设置在大约550°F。离开该炉子的产品表观颜色呈暗褐色并且是充分粘结的。
实施例10
柠檬酸三铵-右旋糖(1∶6)粘结剂/玻璃纤维组合物的制备:
R30住宅用毯子
在装有1104加仑软水的2000加仑混合槽中将粉末状右旋糖一水合物(1200 1b)和粉末状无水柠檬酸(200 1b)结合。在搅拌下向这一混合物中添加42.3加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加6 1b SILQUEST A-1101硅烷以产生 pH值~8的溶液(使用pH试纸),该溶液含有大约13.4%的溶解的右旋糖一水合物和溶解的柠檬酸铵固体(按溶液总重量的百分率);在 400°F下热固化30分钟后,2g这一溶液的样品将产生8%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将该溶液搅拌数分钟,然后转移至粘结剂收集槽中,从该粘结剂收集槽将该溶液用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“R30住宅用毯子”的产品。
使用常规的玻璃纤维制造程序制备R30住宅用毯子;此类程序在实施例8中进行了一般性描述。该R30住宅用毯子产品的标称规格是大约0.4磅/平方英尺的重量,在生产线的末端10英寸厚度的目标恢复,十万分之18英寸(4.6微米)的纤维直径,3.8%粘结剂含量,和用于除尘的0.7%的矿物油含量(除尘油)。将固化炉温度设置在大约 570°F。离开该炉子的产品表观颜色呈褐色并且是充分粘结的。
实施例11
柠檬酸三铵-右旋糖(1∶6)粘结剂/玻璃纤维组合物的制备:
R19住宅用毯子
批料A-1:
在装有1104加仑软水的2000加仑混合槽中将粉末状右旋糖一水合物(1200 1b)和粉末状无水柠檬酸(200 1b)结合。在搅拌下向这一混合物中添加35.3加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加6 1b SILQUEST A-1101硅烷以产生pH值~8的溶液(使用pH试纸),该溶液含有大约13.3%的溶解的右旋糖一水合物和柠檬酸铵固体(按溶液总重量的百分率);在400°F下热固化30分钟后,2g这一溶液的样品将产生8%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将该溶液搅拌数分钟,然后转移至粘结剂收集槽中,从该粘结剂收集槽将该溶液用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“R19住宅用毯子”的产品。
使用常规的玻璃纤维制造程序制备R19住宅用毯子(批料A-1);此类程序在实施例8中进行了一般性描述。该R19住宅用毯子产品的标称规格是大约0.2磅/平方英尺的重量,0.2磅/立方英尺的密度,在生产线的末端6.5英寸厚度的目标恢复,十万分之18英寸(4.6微米)的纤维直径,3.8%粘结剂含量,和0.7%的矿物油含量(用于除尘)。将固化炉温度设置在大约570°F。离开该炉子的产品表现颜色呈褐色并且是充分粘结的。
批料A-2:
在装有558加仑软水的2000加仑混合槽中将粉末状右旋糖一水合物(1200 1b)和粉末状无水柠檬酸(200 1b)结合。在搅拌下向这一混合物中添加35.3加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加5 1b SILQUEST A-1101硅烷以严生 pH值~8的溶液(使用pH试纸),该溶液含有大约20.5%的溶解的右旋糖一水合物和柠檬酸铵固体(按溶液总重量的百分率);在400°F下热固化30分钟后,2g这一溶液的样品将产生12%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将该溶液搅拌数分钟,然后转移至粘结剂收集槽中,从该粘结剂收集槽将该溶液用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“R19住宅用毯子”的产品。
使用常规的玻璃纤维制造程序制备R19住宅用毯子(批料A-2);此类程序在实施例8中进行了一般性描述。该R19住宅用毯子产品的标称规格是大约0.2磅/平方英尺的重量,大约0.4磅/立方英尺的密度,在生产线的末端6.5英寸厚度的目标恢复,十万分之18英寸(4.6 微米)的纤维直径,3.8%粘结剂含量,和0.7%的矿物油含量(用于除尘)。将固化炉温度设置在大约570°F。离开该炉子的产品表观颜色呈褐色并且是充分粘结的。
批料B:
在已经装有167加仑蒸馏水的260加仑International Bulk Container(IBC)中将粉末状右旋糖一水合物(300 1b)和粉末状无水柠檬酸(50 1b)结合。在搅拌下向这一混合物中添加10.6加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加1.5 1b SILQUEST A-1101硅烷以产生pH值~8的溶液(使用pH试纸),该溶液含有大约20.1%的溶解的右旋糖一水合物和柠檬酸铵固体(按溶液总重量的百分率);在400°F下热固化30分钟后,2g这一溶液的样品将产生12%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将装有该含水粘结剂的IBC转移至这样一个区域,即在该位置将粘结剂泵送入成型罩(forming hood)中的粘结剂喷射环,在其中用蒸馏水稀释,然后用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“R19住宅用毯子”的产品。
使用常规的玻璃纤维制造程序制备R19住宅用毯子(批料B);此类程序在实施例8中进行了一般性描述。所制得的R19住宅用毯子产品的标称规格是大约0.2磅/平方英尺的重量,大约0.4磅/立方英尺的密度,在生产线的末端6.5英寸厚度的目标恢复,十万分之18英寸 (4.6微米)的纤维直径,3.8%粘结剂含量,和0.7%的矿物油含量(用于除尘)。将固化炉温度设置在大约570°F。离开该炉子的产品表观颜色呈褐色并且是充分粘结的。
批料C:
在已经装有167加仑蒸馏水的260加仑International Bulk Container(IBC)中将粉末状右旋糖一水合物(300 1b)和粉末状无水柠檬酸(50 1b)结合。在搅拌下向这一混合物中添加10.6加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加1.51b SILQUEST A-1101硅烷,接着添加1.80加仑甲基含氢乳液 BS 1040(由Wacker Chemical Corporation制造)以产生pH值~8的溶液(使用pH试纸),该溶液含有大约20.2%的溶解的右旋糖一水合物和柠檬酸铵固体(按溶液总重量的百分率);在400°F下热固化30分钟后,2g这一溶液的样品将产生12%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将装有该含水粘结剂的IBC转移至这样一个区域,即在该位置将粘结剂泵送入成型罩中的粘结剂喷射环,在其中用蒸馏水稀释,然后用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“R19住宅用毯子”的产品。
使用常规的玻璃纤维制造程序制备R19住宅用毯子(批料C);此类程序在实施例8中进行了一般性描述。所制得的R19住宅用毯子产品的标称规格是大约0.2磅/平方英尺的密度,大约0.4磅/立方英尺的重量,在生产线的末端6.5英寸厚度的目标恢复,十万分之18英寸 (4.6微米)的纤维直径,3.8%粘结剂含量,和0.7%的矿物油含量(用于除尘)。将固化炉温度设置在大约570°F。离开该炉子的产品表观颜色呈褐色并且是充分粘结的。
批料D:
在已经装有167加仑蒸馏水的260加仑International Bulk Container(IBC)中将粉末状右旋糖一水合物(300 1b)和粉末状无水柠檬酸(50 1b)结合。在搅拌下向这一混合物中添加10.6加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加1.5 1b SILQUEST A-1101硅烷,接着添加22 1b粘土产品Bentalite L10(由Southern Clay Products制造)以产生pH值~8的溶液(使用 pH试纸),该溶液含有大约21.0%的溶解的右旋糖一水合物和柠檬酸铵固体(按溶液总重量的百分率);在400°F下热固化30分钟后,2g 这一溶液的样品将产生12.6%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将装有该含水梅拉德粘结剂的IBC转移至这样一个区域,即在该位置将粘结剂泵送入成型罩中的粘结剂喷射环,在其中用蒸馏水稀释,然后用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“R19住宅用毯子”的产品。
使用常规的玻璃纤维制造程序制备R19住宅用毯子(批料D);此类程序在实施例8中进行了一般性描述。那天制得的R19住宅用毯子产品的标称规格是大约0.2磅/平方英尺的重量,大约0.4磅/立方英尺的密度,在生产线的末端6.5英寸厚度的目标恢复,十万分之18 英寸(4.6微米)的纤维直径,3.8%粘结剂含量,和0.7%的矿物油含量(用于除尘)。将固化炉温度设置在大约570°F。离开该炉子的产品表观颜色呈褐色并且是充分粘结的。
实施例12
柠檬酸三铵-右旋糖(1∶6)粘结剂/玻璃纤维组合物的制备:
未固化的绝缘管
在装有215加仑软水的2000加仑混合槽中将粉末状右旋糖一水合物(1200 1b)和粉末状元水柠檬酸(200 1b)结合。在搅拌下向这一混合物中添加42.3加仑19%的氨水,继续搅拌大约30分钟以达到固体的完全溶解。向所得的溶液中添加6 1b SILQUEST A-1101硅烷以产生 pH值~8的溶液(使用pH试纸),该溶液含有大约41.7%的溶解的右旋糖一水合物和溶解的柠檬酸铵固体(按溶液总重量的百分率);在 400°F下热固化30分钟后,2g这一溶液的样品将产生25%固体(该重量损失归因于在热固性粘结剂形成过程中的脱水)。将该溶液搅拌数分钟,然后转移至粘结剂收集槽中,从该粘结剂收集槽将该溶液用于制造玻璃纤维绝缘材料,具体来说,用于形成称作“未固化的绝缘管”的产品。
使用常规的玻璃纤维制造程序制备未固化的绝缘管;此类程序在实施例8中进行了一般性描述。该未固化的绝缘管产品的标称规格是大约0.07磅/平方英尺的重量,大约0.85磅/立方英尺的密度,1英寸的估算厚度,十万分之30英寸(7.6微米)的纤维直径,和当固化时 7%的粘结剂含量。将未固化的绝缘管输送到绝缘管成型区域,在那里,它被铸塑成待用作绝缘管的柱状壳体,具有6英寸的壁和3英寸直径的孔和4磅/立方英尺的密度。采用设置到大约450°F的固化炉将这些壳体固化以生产暗褐色,充分粘结的绝缘管产品。在更高温度下固化的壳体显示不可用并且不能进一步用于试验。
实施例13
柠檬酸三铵-右旋糖(1∶6)粘结剂/纤维素纤维组合物的制备:
木纤维板
使用数种方法来制备用柠檬酸三铵-右旋糖(1∶6)粘结剂粘结的木纤维板/片材。代表性的方法如下,该方法产生强、均匀的样品:从地方农场供应仓库购买呈各种松树木材刨花和锯屑形式的木材。用该“原样”木材以及分离成薄片和锯屑组分的材料制备木纤维板样品。首先在大约200°F的炉子中将木材干燥过夜,该干燥导致该木材刨花除湿 14-15%,该锯屑除湿大约11%。此后,将干木材放入8英寸高×12 英寸宽×10.5英寸深的塑料容器(近似尺寸)中。如实施例5所述制备柠檬酸三铵-右旋糖(1∶6)(粘结剂固体占36%),然后经由液压喷嘴将 160g粘结剂喷涂到该塑料容器中的400g木材样品上,同时将该容器相对于垂直方向倾斜30-40度并缓慢地旋转(大约5-15rpm)。在这一处理期间,轻轻地翻滚该木材同时变得均匀地涂覆。
将树脂浸透过的(resinated)木材的样品放入可折叠框架中并在以下条件下在加热压盘之间压制:树脂浸透过的木材刨花,300psi;树脂浸透过的锯屑,600psi。对于每种树脂浸透过的样品,固化条件是350°F保持25-30分钟。所得的样品板在修整之前大约为10英寸长×10英寸宽和大约0.4英寸厚,内部充分粘结,表面光滑并且当在带锯上修整时切得整齐。经修整的样品密度和所生产的每种经修整样品板的尺寸如下:得自木材刨花的样品板,密度-54pcf,尺寸~8.3 英寸长×9英寸宽×0.36英寸厚;得自锯屑的样品板,密度~44pcf,尺寸~8.7英寸长×8.8英寸宽×0.41英寸厚。每种样品板的经估算的粘结剂含量是~12.6%。
实施例14
柠檬酸三铵-右旋糖(1∶6)粘结剂/玻璃纤维组合物的试验/评价
将实施例8-12的柠檬酸三铵-右旋糖(1∶6)粘结剂/玻璃纤维组合物,即固化的毯子、风道板、R30住宅用毯子、R19住宅用毯子和未固化的绝缘管对比相应的苯酚-甲醛(PF)粘结剂/玻璃纤维组合物试验以下性能中的一种或多种:产品排放物,密度,烧失量,厚度恢复,粉尘,拉伸强度,分离强度,分离强度的耐久性,粘接强度,吸含水,热表面性能,对钢的腐蚀性,抗弯刚度,劲度-刚度,抗压强度,调湿的抗压强度,压缩模量,调湿的压缩模量和点燃时的冒烟。这些试验的结果在表8-13中示出。还测定在实施例8的固化毯子的热解过程中产生的气体化合物,和在实施例12的未固化的绝缘管的热固化过程中产生的气体化合物;这些试验结果在表14-15申示出。固化绝缘管的热表面性能在图5和图6中示出。实施的特定试验和实施这些试验的条件如下:
产品排放物试验
根据AQS Greenguard试验程序测定实施例8的固化毯子和实施例 9的风道板的产品排放物。根据ASTM D5116(“小型环境室室内材料/ 产品有机物排放量测定的标准导则(Standard Guide for Small-Scale Environmental Chamber Determinations ofOrganic Emissions from Indoor Materials/Products)”,美国环境保护局(USEPA))和华盛顿州1994年1月的IAQ Specification监测绝缘产品的总挥发性有机化合物(TVOC)、甲醛、总所选择的醛的排放。在一个星期的暴露时间内收集排放物数据并且测定每种上述物质的所得空气浓度。基于华盛顿州的要求对空气浓度前置量进行计算机监测,所述要求包括标准室内装载和ASHRAE Standard 62-1999通风条件。产品装载基于32m3室内的28.1m2的标准墙壁使用。
排放物试验-所选择的醛
在体积0.0855m3的小型的环境室中试验绝缘产品的分析测量的化学排放物。所选的醛,包括甲醛的排放遵循ASTM D5197(“测定空气中甲醛和其它羰基化合物的标准试验方法(快速取样法)(Standard Test Method for Determination of Forma ldehyde andOther Carbonyl Compounds in Air)(Active Sampler Methodology))使用高效液相色谱法(HPLC)进行测量。使用具有2,4-二硝基苯肼(DNPH)的固体吸附剂盒来收集该环境室空气中的甲醛及其它低分子量羰基化合物。在该盒子中的DNPH试剂与所收集的羰基化合物起反应而形成由该盒子保留的稳定的腙衍生物。采用HPLC-级乙腈将该腙衍生物从盒子洗脱。使用反相高效液相色谱法(HPLC)在UV检测下分析该样品等分试样的低分子量醛腙衍生物。在360nm处测得该衍生物的吸收。使用由腙衍生物的标准溶液制定的多点标定曲线测定所得峰值的质量响应. 基于45L的标准空气体积汇集物,测量值报道至0.2μg的可计量水平。
排放物试验-挥发性有机化合物(VOC)
使用气相色谱法/质谱法联用(GC/MS)检测得到VOC测量值。将腔室空气收集到固体吸附剂上,该固体吸附剂然后热解吸到GC/MS中. 吸附剂收集技术、分离和检测分析方法由USEPA及其它研究人员提供的技术改编而来。该技术遵循USEPA方法1P-1B并且一般适用于沸点为35℃-250℃的C5-C16有机化学物质。基于18L的标准空气体积汇集物,测量值报道至0.4μg的可计量水平。通过GC/MS分离和检测各种 VOC。如下得到总VOC测量值:将由质谱仪获得的所有各种VOC响应值加和,并且相对于甲苯校准总质量。
排放物试验-空气浓度测定
在计算机暴露模型中使用甲醛、总醛和TVOC的排放速度来测定所述物质的可能的空气浓度。计算机模型使用在一个星期的时间内所测得的排放速度变化来测定将因此产生的空气浓度变化。采用以下假设得到模型测量值:建筑物中开放办公室区域的空气在占据空间的呼吸水平区段处是良好混合的;环境条件维持在50%相对湿度和73°F(23 ℃)下;不存在这些物质的其它来源;在所述空间内不存在这些物质的吸收物(sink)或可能的再发射源。特别将USEPA的室内空气暴露模型, 2.0版改编用来适应这种产品和所研究的化学物质。通风和占据参数提供在ASHRAE Standard 62-1999中。
密度
实施例8的固化毯子的密度根据内部试验方法PTL-1“毛毡或棉绒型绝热材料密度和厚度的试验方法(Test Method for Density and Thickness of Blanket or BattThermal Insulation)”测定,该试验方法几乎等同于ASTM C 167。实施例9的风道板的密度根据内部试验方法PTL-3“预制块型绝热材料密度的试验方法(Test Procedure forDensity Preformed Block-Type Thermal Insulation)”测定,该试验方法几乎等同于ASTM C 303。
烧失量(LOI)
实施例8的固化毯子和实施例9的风道板的烧失量根据内部试验方法K-157“固化毯子的烧失量(Ignition Loss of Cured Blanket(LOI))”测定。对在线托盘中的样品进行该试验,该线托盘放在1000°F,+/-50°F的炉中保持15-20分钟以确保完全氧化,该处理之后,称量所得的样品。
分离强度
根据内部试验方法KRD-161测定实施例8的固化毯子、实施例10 的R30住宅用毯子和实施例11的R19住宅用毯子的分离强度,该试验方法几乎等同于ASTM C 686,“矿质纤维绒及毡式绝热材料分离强度 (Parting Strength of Mineral Fiber Ba tt andBlanket-Type Insulation)”。
分离强度的耐久性
在90°F和95%相对湿度下调湿一个星期之后,根据ASTM C 686 “矿质纤维绒及毡式绝热材料分离强度(Parting Strength of Mineral Fiber Ba t t and Blanket-TypeInsulation)”测定实施例 10的R30住宅用毯子和实施例11的R19住宅用毯子的分离强度的耐久性。
拉伸强度
根据内部试验方法KRD-161“拉伸强度试验程序(Tensile Strength TestProcedure)”测定实施例8的固化毯子和实施例11 的R19住宅用毯子的拉伸强度。对在纵向和正交纵向上都冲切的样品进行试验。在75°F和50%相对湿度下将样品调湿24小时。在75°F, 50%相对湿度的试验环境中试验每个纵向上的十个样品。“8字试块” (dogbone)试样如ASTM D638“塑料拉伸性能标准试验方法(Standard Test Method for TensileProperties of Plastics)”中所规定。 2英寸/分钟的十字头速度用于所有试验。
粘结强度
使用内部试验方法KRD-159“玻璃纤维板和毯型产品的粘结强度 (Bond Strengthof Fiberglass Board and Blanket Products)”测定实施例8的固化毯子、实施例10的R30住宅用毯子和实施例11 的R19住宅用毯子的层间粘结强度。将横截面积为6英寸×6英寸的模塑试样胶合到6英寸×7英寸的试样安装板上并放入夹具中,该夹具施加与试样表面垂直的力。12英寸/分钟的十字头速度用于所有试验。
厚度恢复
使用内部试验方法K-123“Recovered Thickness-End of Line Dead PinMethod-Roll Products”知K-109“Test Procedure for Recovered Thickness of RollProducts-Rollover Method”对实施例8的固化毯子进行开包装(Out-of-package)和翻转厚度试验。如下进行厚度恢复的测量:在包装之后15分钟或在更后的时间点,推动销规穿过得自辊压产品的固化毯子样品,直到该销接触位于样品之下的平坦的硬表面,然后用钢尺测量恢复的厚度。使用内部试验方法K-120 “Test Procedure for Determining End-of-Line Dead-Pin Thickness-Batts”和K-128“Test Procedure for Recovered Thicknessof Ba tt Products-Drop Method”对实施例10的R30住宅用毯子和实施例11的R19住宅用毯子进行厚度试验,该两种试验方法与ASTM C 167“毛毡或棉绒型绝热材料厚度和密度的标准试验方法 (Standard Test Methods for Thickness and Density of Blanket orBatt Thermal Insulations)”相似。
粉尘试验
使用内部试验程序K-102“包装的玻璃纤维粉尘试验,棉绒法 (Packaged FiberGlass Dust Test,Batt Method)”对实施例8的固化毯子、实施例10的R30住宅用毯子和实施例11的R19住宅用毯子进行粉尘试验。在过滤器上收集从投入集尘箱中的固化毯子、R30住宅用毯子和R19住宅用毯子中随机选取的样品(毡)释放的粉尘并且通过差值称量测定粉尘的量。
吸水率
使用ASTM C 1104“测定未覆面矿物纤维绝缘材料的水蒸汽吸收率的试验方法(Test Method for Determining the Water Vapor Absorption of Unfaced MineralFiber Insulation)”对实施例8 的固化毯子和实施例11的R19住宅用毯子进行吸水率(wt%)试验。
抗弯刚度(EI)
根据NAIMA AHS 100-74“矩形刚性管材料抗弯刚度的试验方法 (Test Methodfor Flexural Rigidity of RectangularRigid Duct Materials)”测定实施例9的风道板的抗弯刚度,该抗弯刚度是使刚性风道板弯曲所要求的力偶,即E(弹性模量)和I(惯性弯矩)的乘积。
劲度-刚度
使用内部试验程序K-117“建筑绝缘材料刚度的试验程序(Test Procedure forRigidity of Building Insulation)”对实施例11 的R19住宅用毯子进行劲度-刚度试验。将R19住宅用毯子的样品,大约47.5英寸长(±0.5英寸)放置在劲度试验装置的中心支撑杆上,该装置包括直接位于该中心支撑杆后面的量角器标度。让样品的端部自由悬挂,通过沿着样品的下缘瞄准同时阅读量角器标度记录样品每一端处的角度(度)。
抗压强度
根据ASTM C 165“绝热材料压缩性能测量的标准试验方法(Standard TestMethod for Measuring Compressive Properties of Thermal Insulations)”测定实施例9的风道板的抗压强度。
调湿(conditioned)抗压强度
在90°F和95%相对湿度下一个星期后,根据ASTM C 165“绝热材料压缩性能测量的标准试验方法(Standard Test Method for Measuring Compressive Properties ofThermal Insulations)”测定实施例9的风道板的调湿抗压强度。
压缩模量
根据ASTM C 165“绝热材料压缩性能测量的标准试验方法 (Standard TestMethod for Measuring Compressive Properties of Thermal Insulations)”测定实施例9的风道板的压缩模量。
调湿压缩模量
在90°F和95%相对湿度下一个星期后,根据ASTM C 165“绝热材料压缩性能测量的标准试验方法(Standard Test Method for Measuring Compressive Properties ofThermal Insulations)”测定实施例9的风道板的调湿压缩模量。
热表面性能
使用ASTM C 411“高温绝热材料受热面性能的试验方法(Test Me thod for HotSurface Performance of High Temperature Thermal Insulation)”对实施例8的固化毯子、实施例10的R30住宅用毯子和实施例11的R19住宅用毯子进行热表面性能试验。使用ASTM C411 “高温绝热材料受热面性能的试验方法(Test Method for Hot SurfacePerformance of High Temperature Thermal Insulation)”在650°F 和1000°F下对实施例12的固化绝缘管产品的3×6英寸部分进行热表面性能试验。在管的热表面温度之上在该绝缘材料中不存在可测量的内部温度上升。
对钢的腐蚀性
使用内部试验程序Knauf PTL-14对实施例10的R30住宅用毯子和实施例11的R19住宅用毯子进行对钢试件的腐蚀性试验,该试验程序几乎等同于ASTM C 665。
点燃时的冒烟
使用ASTM E 1354“使用耗氧量热计测试材料和产品的热和可见烟雾释放速率的方法(Test Method for Heat and Visible Smoke Release Rates for Materials andProducts Using an Oxygen Consumption Calorimeter)”通过锥量热法测定实施例8的固化毯子的点燃时的冒烟(计算比熄灭面积(SEA))。
在热解过程中产生的气体化合物
如下测定在实施例8的固化毯子的热解过程中产生的气体化合物:将大约10g固化毯子放入试管中,然后将该试管加热到1000°F 保持2.5分钟,此时在顶部空间取样并在以下条件下通过气相色谱法/ 质谱法(GC/MS)分析:炉子,50℃保持一分钟-10℃/分钟至300℃保持 10分钟;入口,280℃无分流;柱,HP-5 30mm×0.32mm×0.25μm;柱流体,1.11mL/分钟氦气;检测器,MSD 280℃;注射体积,1mL;检测器模式,扫描34-700amu;阈值,50;采样速度,22scan/秒。相对于质谱谱图的Wiley库藏,对样品中的色谱峰值的质谱进行计算机检索。报道最佳匹配。产生了0-99的质量指数(与库藏谱图匹配的紧密度)。仅报道质量指数大于或等于90的峰值的标识。
在热固化过程中产生的气体化合物
如下测定在实施例12的未固化绝缘管的热固化过程中产生的气体化合物:将大约0.6g未固化的绝缘管放入试管中,然后将该试管加热到540°F保持2.5分钟,此时在顶部空间取样并在以下条件下通过气相色谱法/质谱法分析:炉子,50℃保持一分钟-10℃/分钟至300 ℃保持10分钟;入口,280℃无分流;柱,HP-530mm×0.32mm×0.25 μm;柱流体,1.11mL/分钟氦气;检测器,MSD 280℃;注射体积,1mL;检测器模式,扫描34-700amu;阈值,50;采样速度,22scan/秒。相对于质谱谱图的Wiley库藏,对样品中的色谱峰值的质谱进行计算机检索。报道最佳匹配。产生了0-99的质量指数(与库藏谱图匹配的紧密度)。仅报道质量指数大于或等于90的峰值的标识。
表1固化的柠檬酸三铵-右旋糖粘结剂样品g的试验/评价结果
a得自实施例1
bMW=243g/mol;25%(wt%)溶液
cMW=198g/mol;25%(wt%)溶液
d近似
e与不同的氨气味有关
表2固化的柠檬酸三铵-右旋糖(1∶6)粘结剂样品b随温度和时间变化的元素分析结果
a得自实施例4
表3用柠檬酸三铵-右旋糖(1∶6)粘结剂bvs.标准PF粘结剂制备的玻璃珠壳骨组合物a的所测得的拉伸强度
a得自实施例6
b得自实施例5
c九个壳骨样品的平均值
d在五个月的时间内制备的柠檬酸三铵-右旋糖(1∶6)粘结剂的七种不同批料之一
e在五个月的时间内制备的柠檬酸三铵-右旋糖(1∶6)粘结剂的七种不同批料的平均值
表4用柠檬酸三铵-右旋糖(1∶6)粘结剂变体bvs.标准PF粘结剂制备的玻璃珠壳骨组合物a的所测得的拉伸强度
a得自实施例6
b得自实施例5
c九个壳骨样品的平均值
d在五个月的时间内制备的柠檬酸三铵-右旋糖(1∶6)粘结剂的七种不同批料的平均值
eSilres BS 1042是甲基含氢聚硅氧烷的50%固体乳液
f复制样品
g复制样品
hLE 46是聚二甲基硅氧烷的35%固体乳液
iTPX5688/AQUA-TRETE BSM40是烷基硅烷的40%乳液
jPGN,粘土等级,蒙脱土,得自Nanocor
kCloisite NA+,得自Southern Clay Products的粘土的钠盐
lBlown Soya Emulsion(25%),大豆油与PEG 400二油酸酯(基于固体4%)和瓜尔胶(基于固体1%)的25%固体乳液
mBentolite L-10,得自Southern Clay Products的粘土
nMichem 45745PE乳液(50%),低分子量聚乙烯的25%固体乳液
o骨胶溶液,30%固体溶液
pAxel INT-26-LF95,脂肪类、脱模剂/乳液
qISO Chill Whey 9010
r没有计算
s没有测量
表5用多元羧酸铵-右旋糖粘结剂变体bvs.多元羧酸类粘结剂vs.标准PF粘结剂制备的玻璃珠壳骨组合物a的所测得的拉伸强度
a得自实施例6
b得自实施例5
c九个壳骨样品的平均值
d在五个月的时间内制备的柠檬酸三铵-右旋糖(1∶6)粘结剂的七种不同批料的平均值
c200g AQUASET-529+87g 19%氨+301g右旋糖+301g水为 30%溶液
f300mL粘结剂c+0.32g SILQUEST A-1101的溶液
g200g AQUASET-529+87g 19%氨+101g水+0.6g SILQUEST A-1101
hAQUASET-529+SILQUEST A-1101(以0.5%粘结剂固体),稀释到30%固体
i136g季戊四醇+98g马来酸酐+130g水,回流30分钟;232g 所得的溶液与170g水和0.6g SILQUEST A-1101混合
j136g季戊四醇+98g马来酸酐+130g水+1.5mL 66%对甲苯磺酸,回流30分钟;232g所得的溶液与170g水和0.6g SILQUEST A-1101混合
k220g粘结剂i+39g 19%的氨+135g右旋糖+97g水+0.65g SILQUEST A-1101
l128g柠檬酸+45g季戊四醇+125g水,回流20分钟;所得的混合物稀释到30%固体并且基于固体以0.5%添加SILQUEST A-1101
m200g Kemira CRITERION 2000+23g甘油+123g水+0.5g SILQUEST A-1101
n200g Kemira CRITERION 2000+30g甘油+164g水+0.6g SILQUEST A-1101
o100g BASF SOKALAN CP 10S+57g 19%氨+198g右旋糖+180g 水+0.8g SILQUESTA-1101
p211g H.B.Fuller NF1+93g 19%氨+321g右旋糖+222g水 +1.33g SILQUEST A-1101
表6用多元羧酸铵-糖粘结剂变体bvs.标准PF粘结剂制备的玻璃珠壳骨组合物g的所测得的拉伸强度
a得自实施例6
b得自实施例5
c九个壳骨样品的平均值
d七种批料的平均值
eDHA=二羟基丙酮
f一羧酸盐
g非羧酸
hpH>7
表7采用多元羧酸铵-糖(1∶6)粘结剂变体bvs.标准PF粘结剂制e备的玻璃纤维垫g的所测得的拉伸强度和烧失量
a得自实施例7
b得自实施例5
c三个玻璃纤维垫的平均值
dDex=右旋糖
eFruc=果糖
fDHA=二羟基丙酮
g甘油替换25wt%DHA
hPETol=季戊四醇替换25wt%DHA
iPVOH=聚乙烯醇(86-89%水解的聚乙酸乙烯酯,MW~22K-26K),替换20wt%DHA
jDuctliner粘结剂
表8.实施例8的固化毯子的试验结果:柠檬酸三铵-右旋糖(1∶6)粘结剂vs.标准PF粘结剂
表9.实施例8的固化毯子的点燃时的冒烟:柠檬酸三铵-右旋糖(1∶6) 粘结剂vs.标准PF粘结剂
aSEA=比熄灭面积
表10.实施例9的风道板的试验结果:柠檬酸三铵-右旋糖(1∶6)粘结剂vs.标准PF粘结剂
表11实施例10的R30住宅用毯子的试验结果:柠檬酸三铵-右旋糖 (1∶6)粘结剂vs.标准PF粘结剂
a蛋白黑素粘结剂;产生5%烧失量的标称机器条件
b蛋白黑素粘结剂;将烧失量增加到6.3%的机器调节
c蛋白黑素粘结剂;将烧失量增加到6.6%的机器调节
d没有测量
表12实施例11(批料A-1)的R19住宅用毯子的试验结果:柠檬酸三铵-右旋糖(1∶6)粘结剂vs.标准PF粘结剂
表14在采用柠檬酸铵-右旋糖(1∶6)粘结剂制备的固化毯子(得自实施例8)的热解过程中产生的气体化合物的GC/MS分析
表15在采用柠檬酸铵-右旋糖(1∶6)粘结剂制备的未固化绝缘管(得自实施例12)的热固化过程中产生的气体化合物的GC/MS分析
虽然上面已经描述和/或举例说明了本发明的某些实施方案,但是应认为相当多的变体及其修改是可能的。因此,本发明不限于本文描述和/或举例说明的特定实施方案。
Claims (17)
1.制备纤维产品的方法,该方法包括:
-使非集合或松散集合的非织造纤维的汇集物与未固化的、不含甲醛的粘结剂接触;和
-热固化所述粘结剂,
其中所述未固化的粘结剂是含水粘结剂溶液,其包含:包括(i)胺反应物和(ii)碳水化合物反应物的梅拉德反应物,所述碳水化合物反应物选自一种或多种还原糖、在热固化条件下原位产生一种或多种还原糖的一种或多种碳水化合物和它们的组合;并且其中所述胺反应物选自下组:蛋白质,肽,氨基酸,具有伯氨基的化合物,具有仲氨基的化合物,和一种或多种单体或聚合物多元羧酸的铵盐。
2.通过将纤维粘结在一起以致它们变得组织成纤维垫来制备纤维产品的方法,该方法包括:
-使非织造纤维与未固化的、不含甲醛的粘结剂接触;和
-热固化所述粘结剂,
其中所述未固化的粘结剂是含水粘结剂溶液,其包含:包括(i)胺反应物和(ii)碳水化合物反应物的梅拉德反应物,所述碳水化合物反应物选自一种或多种还原糖、在热固化条件下原位产生一种或多种还原糖的一种或多种碳水化合物和它们的组合;并且其中所述纤维包含选自下组的纤维:芳族聚酰胺纤维、陶瓷纤维、金属纤维、碳纤维、聚酰亚胺纤维、聚酯纤维、嫘萦纤维和玻璃纤维。
3.权利要求1的方法,其中所述纤维包含选自下组的纤维:芳族聚酰胺纤维、陶瓷纤维、金属纤维、碳纤维、聚酰亚胺纤维、聚酯纤维、嫘萦纤维和玻璃纤维。
4.权利要求2的方法,其中所述胺反应物选自下组:蛋白质,肽,氨基酸,具有伯氨基的化合物,具有仲氨基的化合物,和一种或多种单体或聚合物多元羧酸的铵盐。
5.权利要求2或3的方法,其中所述纤维以在80重量%-99重量%范围内的量存在。
6.权利要求1的方法,其中所述胺反应物包含具有伯氨基的化合物。
7.权利要求1或2的方法,其中所述胺反应物是梅拉德反应中的非蛋白质伯胺反应物NH2-R1,其中R1是被选自至少一个氨基和至少一个氨基烷基的基团取代的烷基。
8.权利要求7的方法,其中R1不包含仲胺基团。
9.权利要求1或2的方法,其中所述碳水化合物反应物选自一种或多种还原糖。
10.权利要求1或2的方法,其中所述碳水化合物反应物包括单糖还原糖,其包括以下物质中的至少一种:右旋糖、木糖、果糖和二羟基丙酮。
11.权利要求1或2的方法,其中所述未固化的粘结剂还包含含硅偶联剂。
12.权利要求1或2的方法,其中所述纤维与其接触的所述未固化的粘结剂具有碱性pH。
13.权利要求1或2的方法,其中与所述纤维接触的所述未固化的粘结剂被脱水和随后固化。
14.权利要求1或2的方法,其中所述未固化的粘结剂基本上由(i)胺反应物和(ii)碳水化合物反应物组成。
15.权利要求13的方法,其中所述未固化的粘结剂包含一种或多种添加剂。
16.权利要求1或2的方法,其中所述粘结剂的固化基本上由梅拉德反应构成。
17.权利要求1或2的方法,其中所述未固化的粘结剂由(i)一种或多种胺反应物、(ii)一种或多种碳水化合物反应物和(iii)任选的一种或多种添加剂组成。
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US70245605P | 2005-07-26 | 2005-07-26 | |
US60/702,456 | 2005-07-26 | ||
US74307105P | 2005-12-22 | 2005-12-22 | |
US60/743,071 | 2005-12-22 | ||
PCT/US2006/028929 WO2007014236A2 (en) | 2005-07-26 | 2006-07-26 | Binders and materials made therewith |
CN2006800354300A CN101287788B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006800354300A Division CN101287788B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111138867A true CN111138867A (zh) | 2020-05-12 |
CN111138867B CN111138867B (zh) | 2022-06-21 |
Family
ID=37533550
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210263009.2A Active CN102766423B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
CN201710712430.XA Active CN107541183B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
CN201910405128.9A Active CN111138867B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
CN201510598949.0A Active CN105176461B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
CN2006800354300A Expired - Fee Related CN101287788B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210263009.2A Active CN102766423B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
CN201710712430.XA Active CN107541183B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510598949.0A Active CN105176461B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
CN2006800354300A Expired - Fee Related CN101287788B (zh) | 2005-07-26 | 2006-07-26 | 粘结剂和由其制备的材料 |
Country Status (15)
Country | Link |
---|---|
US (18) | US7888445B2 (zh) |
EP (6) | EP2433983A1 (zh) |
JP (6) | JP5455169B2 (zh) |
KR (13) | KR20210016069A (zh) |
CN (5) | CN102766423B (zh) |
AU (1) | AU2006272595C1 (zh) |
BR (1) | BRPI0614664B1 (zh) |
CA (2) | CA2615780C (zh) |
DK (2) | DK2574639T3 (zh) |
EA (2) | EA035452B1 (zh) |
ES (2) | ES2732298T3 (zh) |
PL (2) | PL2574639T3 (zh) |
SI (2) | SI2574639T1 (zh) |
TR (1) | TR201508968T3 (zh) |
WO (1) | WO2007014236A2 (zh) |
Families Citing this family (192)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7934494B1 (en) * | 2003-10-10 | 2011-05-03 | Donna Gail Schneider | Collapsible heating apparatus |
US7842382B2 (en) | 2004-03-11 | 2010-11-30 | Knauf Insulation Gmbh | Binder compositions and associated methods |
EA200700832A1 (ru) | 2004-10-13 | 2007-08-31 | Кнауф Инсулэйшн Гмбх | Полиэфирные связующие композиции |
KR20210016069A (ko) * | 2005-07-26 | 2021-02-10 | 크나우프 인설레이션, 인크. | 접착제 및 이들로 만들어진 물질 |
US20220267635A1 (en) * | 2005-07-26 | 2022-08-25 | Knauf Insulation, Inc. | Binders and materials made therewith |
DE102005063381B4 (de) * | 2005-11-28 | 2009-11-19 | Saint-Gobain Isover G+H Ag | Verfahren zur Herstellung von formaldehydfrei gebundener Mineralwolle sowie Mineralwolleprodukt |
US9169364B2 (en) | 2006-06-16 | 2015-10-27 | Georgia-Pacific Chemicals Llc | Binder compositions and methods for making and using same |
US9217065B2 (en) * | 2006-06-16 | 2015-12-22 | Georgia-Pacific Chemicals Llc | Binder compositions for making fiberglass products |
US7638592B2 (en) * | 2007-01-16 | 2009-12-29 | Battelle Memorial Institute | Formaldehyde free binders |
US8501838B2 (en) | 2007-01-25 | 2013-08-06 | Knauf Insulation Sprl | Composite wood board |
US20100086726A1 (en) | 2007-01-25 | 2010-04-08 | Roger Jackson | Mineral fibre board |
EP2457954A1 (en) * | 2007-01-25 | 2012-05-30 | Knauf Insulation | Composite wood board |
WO2008089849A1 (en) * | 2007-01-25 | 2008-07-31 | Knauf Insulation Limited | Hydroponics growing medium |
SI2108006T1 (sl) | 2007-01-25 | 2021-02-26 | Knauf Insulation Gmbh | Veziva in s tem narejeni materiali |
EP2126179B1 (en) * | 2007-01-25 | 2014-10-22 | Knauf Insulation | Formaldehyde-free mineral fibre insulation product |
EP2109594A1 (en) * | 2007-01-25 | 2009-10-21 | Knauf Insulation Limited | Mineral fibre insulation |
WO2008127936A2 (en) * | 2007-04-13 | 2008-10-23 | Knauf Insulation Gmbh | Composite maillard-resole binders |
CA2692489A1 (en) * | 2007-07-05 | 2009-01-08 | Knauf Insulation Gmbh | Hydroxymonocarboxylic acid-based maillard binder |
AU2014221228B2 (en) * | 2007-08-03 | 2016-07-21 | Knauf Insulation Sprl | Binders |
GB0715100D0 (en) * | 2007-08-03 | 2007-09-12 | Knauf Insulation Ltd | Binders |
FR2924719B1 (fr) * | 2007-12-05 | 2010-09-10 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un monosaccharide et/ou un polysaccharide et un acide organique polycarboxylique, et produits isolants obtenus. |
US9419286B2 (en) | 2011-01-13 | 2016-08-16 | GM Global Technology Operations LLC | Wet lamination process for reducing mud cracking in fuel cell components |
US9647274B2 (en) | 2008-01-11 | 2017-05-09 | GM Global Technology Operations LLC | Method of making a proton exchange membrane using a gas diffusion electrode as a substrate |
US9722269B2 (en) | 2008-01-11 | 2017-08-01 | GM Global Technology Operations LLC | Reinforced electrode assembly |
US9780399B2 (en) | 2008-01-11 | 2017-10-03 | GM Global Technology Operations LLC | Electrode assembly with integrated reinforcement layer |
PE20100438A1 (es) * | 2008-06-05 | 2010-07-14 | Georgia Pacific Chemicals Llc | Composicion de suspension acuosa con particulas de materiales valiosos e impurezas |
US20090302276A1 (en) * | 2008-06-09 | 2009-12-10 | Sears Pretroleum & Transport Corporation And Sears Ecological Applications Co., Llc | Anticorrosive composition |
PL2285754T3 (pl) * | 2008-06-13 | 2018-12-31 | Benjamin Moore & Co. | Wodne kompozycje powłokowe z minimalną emisją związków lotnych |
FR2935707B1 (fr) | 2008-09-11 | 2012-07-20 | Saint Gobain Isover | Composition d'encollage pour laine minerale a base de sucre hydrogene et produits isolants obtenus |
US20110169182A1 (en) * | 2008-10-23 | 2011-07-14 | Honeywell International Inc. | Methods of forming bulk absorbers |
US9238747B2 (en) | 2008-11-17 | 2016-01-19 | Basf Se | Stain blocking compositions |
PL2223941T3 (pl) | 2009-02-27 | 2019-04-30 | Rohm & Haas | Szybkoutwardzalna kompozycja węglowodanowa |
EP2223940B1 (en) | 2009-02-27 | 2019-06-05 | Rohm and Haas Company | Polymer modified carbohydrate curable binder composition |
EP2230222A1 (en) | 2009-03-19 | 2010-09-22 | Rockwool International A/S | Aqueous binder composition for mineral fibres |
EP2419556A1 (en) * | 2009-04-13 | 2012-02-22 | Owens Corning Intellectual Capital, LLC | Soft fiber insulation product |
DE102009018688B4 (de) | 2009-04-23 | 2017-03-02 | Knauf Insulation | Mineralwolleprodukt |
US8864893B2 (en) | 2009-10-09 | 2014-10-21 | Owens Corning Intellectual Capital, Llc | Bio-based binders for insulation and non-woven mats |
US9718729B2 (en) | 2009-05-15 | 2017-08-01 | Owens Corning Intellectual Capital, Llc | Biocides for bio-based binders, fibrous insulation products and wash water systems |
US20110003522A1 (en) * | 2009-05-15 | 2011-01-06 | Liang Chen | Bio-based aqueous binder for fiberglass insulation materials and non-woven mats |
FR2946352B1 (fr) * | 2009-06-04 | 2012-11-09 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un saccharide, un acide organique polycarboxylique et un silicone reactif, et produits isolants obtenus |
US20110021101A1 (en) * | 2009-06-29 | 2011-01-27 | Hawkins Christopher M | Modified starch based binder |
WO2011015946A2 (en) * | 2009-08-07 | 2011-02-10 | Knauf Insulation | Molasses binder |
US9604878B2 (en) | 2009-08-11 | 2017-03-28 | Johns Manville | Curable fiberglass binder comprising salt of inorganic acid |
US8708162B2 (en) * | 2009-08-19 | 2014-04-29 | Johns Manville | Polymeric fiber webs with binder comprising salt of inorganic acid |
US9994482B2 (en) * | 2009-08-11 | 2018-06-12 | Johns Manville | Curable fiberglass binder |
US9034970B2 (en) | 2009-08-11 | 2015-05-19 | Johns Manville | Curable fiberglass binder comprising salt of inorganic acid |
US8372900B2 (en) * | 2009-08-19 | 2013-02-12 | Johns Manville | Cellulosic composite with binder comprising salt of inorganic acid |
SI2464773T1 (sl) | 2009-08-11 | 2017-12-29 | Johns Manville | Postopek za vezavo steklenih vlaken in izdelkov iz steklenih vlaken |
US8377564B2 (en) * | 2009-08-19 | 2013-02-19 | Johns Manville | Cellulosic composite |
US20110040010A1 (en) * | 2009-08-11 | 2011-02-17 | Kiarash Alavi Shooshtari | Curable fiberglass binder comprising salt of inorganic acid |
US9676954B2 (en) | 2009-08-11 | 2017-06-13 | Johns Manville | Formaldehyde-free binder compositions and methods of making the binders under controlled acidic conditions |
US8651285B2 (en) * | 2009-08-19 | 2014-02-18 | Johns Manville | Performance polymeric fiber webs |
US9365963B2 (en) | 2009-08-11 | 2016-06-14 | Johns Manville | Curable fiberglass binder |
CA2771321A1 (en) * | 2009-08-20 | 2011-02-24 | Georgia-Pacific Chemicals Llc | Modified binders for making fiberglass products |
US20110223364A1 (en) * | 2009-10-09 | 2011-09-15 | Hawkins Christopher M | Insulative products having bio-based binders |
FR2951189B1 (fr) | 2009-10-13 | 2011-12-09 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un sucre reducteur et un sel metallique d'acide inorganique, et produits isolants obtenus |
BR112012013476A2 (pt) * | 2009-12-02 | 2016-05-24 | Georgia Pacific Chemicals Llc | composições aglutinantes para a produção de produtos de fibra de vidro |
US20110135907A1 (en) * | 2009-12-09 | 2011-06-09 | Kiarash Alavi Shooshtari | Fiber reinforced composite materials and methods for their manufacture and use |
DE102009059320A1 (de) * | 2009-12-23 | 2011-06-30 | Cofresco Frischhalteprodukte GmbH & Co. KG, 32427 | Substrat mit antimikrobieller Beschichtung, ein antimikrobielles Verpackungsmaterial, sowie Verfahren zur Herstellung derselben |
KR101202503B1 (ko) | 2010-03-09 | 2012-11-16 | (주)엘지하우시스 | 진공 단열 패널용 심재 및 이를 제조하는 방법 |
CA2793795A1 (en) | 2010-03-31 | 2011-10-06 | Knauf Insulation Gmbh | Insulation products having a non-aqueous moisturizer |
EP2386605B1 (en) | 2010-04-22 | 2017-08-23 | Rohm and Haas Company | Durable thermosets from reducing sugars and primary polyamines |
EP2386394B1 (en) | 2010-04-22 | 2020-06-10 | Rohm and Haas Company | Durable thermoset binder compositions from 5-carbon reducing sugars and use as wood binders |
US9493603B2 (en) | 2010-05-07 | 2016-11-15 | Knauf Insulation Sprl | Carbohydrate binders and materials made therewith |
AU2011249759B2 (en) | 2010-05-07 | 2014-11-06 | Knauf Insulation | Carbohydrate polyamine binders and materials made therewith |
US9045678B2 (en) * | 2010-05-17 | 2015-06-02 | Georgia-Pacific Chemicals Llc | Proppants for use in hydraulic fracturing of subterranean formations |
WO2011146848A1 (en) | 2010-05-21 | 2011-11-24 | Cargill, Incorporated | Blown and stripped blend of soybean oil and corn stillage oil |
US20130082205A1 (en) * | 2010-06-07 | 2013-04-04 | Knauf Insulation Sprl | Fiber products having temperature control additives |
JP5616291B2 (ja) | 2010-06-11 | 2014-10-29 | ローム アンド ハース カンパニーRohm And Haas Company | ジアルデヒドから製造された5−および6−員環式エナミン化合物からの速硬化性熱硬化性物質 |
BR112013001630A2 (pt) * | 2010-07-23 | 2016-05-24 | Rockwool Internat | produto de fibras minerais unidas tendo alta resistência ao fogo e à decomposição exotérmica a temperaturas elevadas. |
EP2415721A1 (en) | 2010-07-30 | 2012-02-08 | Rockwool International A/S | Compacted body for use as mineral charge in the production of mineral wool |
FR2964099B1 (fr) * | 2010-08-30 | 2012-08-17 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un sucre non reducteur et un sel metallique d'acide inorganique, et produits isolants obtenus. |
FR2964012B1 (fr) * | 2010-08-31 | 2017-07-21 | Rockwool Int | Culture de plantes dans un substrat a base de laine minerale comprenant un liant |
US20130174758A1 (en) * | 2010-09-17 | 2013-07-11 | Knauf Insulation Gmbh | Organic acid carbohydrate binders and materials made therewith |
FR2966822B1 (fr) * | 2010-11-02 | 2017-12-22 | Saint-Gobain Technical Fabrics Europe | Liant pour mat de fibres, notamment minerales, et produits obtenus |
US9012346B2 (en) | 2010-11-04 | 2015-04-21 | GM Global Technology Operations LLC | Wet lamination process for reducing mud cracking in fuel cell components |
JP5977015B2 (ja) * | 2010-11-30 | 2016-08-24 | ローム アンド ハース カンパニーRohm And Haas Company | 還元糖およびアミンの安定な反応性熱硬化性配合物 |
FR2968008B1 (fr) | 2010-11-30 | 2014-01-31 | Saint Gobain Isover | Composition d'encollage pour fibres, notamment minerales, comprenant un sucre non reducteur et un sel d'ammonium d'acide inorganique, et produits resultants. |
US8708163B2 (en) | 2010-12-15 | 2014-04-29 | Johns Manville | Spunbond polyester fiber webs |
US8651286B2 (en) | 2010-12-15 | 2014-02-18 | Johns Manville | Spunbond polyester mat with binder comprising salt of inorganic acid |
US20120168054A1 (en) * | 2011-01-04 | 2012-07-05 | Owens Corning Intellectual Capital, Llc | Use of silicones to improve fiberglass insulation products |
JP5879521B2 (ja) * | 2011-03-31 | 2016-03-08 | パナソニックIpマネジメント株式会社 | 接着用組成物 |
EP2694717B1 (en) | 2011-04-07 | 2017-06-28 | Cargill, Incorporated | Bio-based binders including carbohydrates and a pre-reacted product of an alcohol or polyol and a monomeric or polymeric polycarboxylic acid |
FR2974104B1 (fr) | 2011-04-15 | 2014-08-15 | Saint Gobain Isover | Composition d'encollage pour laine minerale resistant au feu et produit isolant obtenu |
WO2012152731A1 (en) | 2011-05-07 | 2012-11-15 | Knauf Insulation | Liquid high solids binder composition |
FR2975690B1 (fr) | 2011-05-25 | 2014-06-13 | Saint Gobain Isover | Composition d'encollage exempte de formaldehyde pour fibres, notamment minerales, et produits resultants. |
FR2975689B1 (fr) | 2011-05-25 | 2014-02-28 | Saint Gobain Isover | Composition d'encollage exempte de formaldehyde pour fibres, notamment minerales, et produits resultants. |
WO2012166414A1 (en) * | 2011-05-27 | 2012-12-06 | Cargill, Incorporated | Bio-based binder systems |
US20120309246A1 (en) | 2011-06-03 | 2012-12-06 | Alexander Tseitlin | Curable biopolymer nanoparticle latex binder for mineral, natural organic, or synthetic fiber products and non-woven mats |
FR2976584B1 (fr) | 2011-06-17 | 2014-12-12 | Saint Gobain Isover | Composition d'encollage pour laine minerale a base de sel d'acide lignosulfonique et d'oligosaccharide, et produits isolants obtenus. |
FR2976582B1 (fr) | 2011-06-17 | 2014-12-26 | Saint Gobain Isover | Composition d'encollage pour laine minerale a faible emission de composes organiques volatils, et produits isolants obtenus. |
US9957409B2 (en) | 2011-07-21 | 2018-05-01 | Owens Corning Intellectual Capital, Llc | Binder compositions with polyvalent phosphorus crosslinking agents |
GB201115172D0 (en) * | 2011-09-02 | 2011-10-19 | Knauf Insulation Ltd | Carbohydrate based binder system and method of its production |
ITMI20111897A1 (it) | 2011-10-19 | 2013-04-20 | Milano Politecnico | Resina legante per nontessuti, in particolare per la produzione di supporti per membrane bituminose, procedura per la sua preparazione e nontessuto ottenuto con l'uso della resina suddetta. |
FR2981647B1 (fr) | 2011-10-20 | 2019-12-20 | Saint-Gobain Isover | Composition d'encollage a faible teneur en formaldehyde pour laine minerale resistant au feu et produit isolant obtenu. |
FR2985725B1 (fr) * | 2012-01-17 | 2015-06-26 | Saint Gobain Isover | Composition d'encollage pour fibres, notamment minerales, a base d'acide humique et/ou fulvique, et produits isolants resultants. |
CN103317586B (zh) * | 2012-03-21 | 2016-04-27 | 中南林业科技大学 | 一种环保型无胶碎料板及其制备方法 |
GB201206193D0 (en) * | 2012-04-05 | 2012-05-23 | Knauf Insulation Ltd | Binders and associated products |
CA2870898C (en) | 2012-04-18 | 2019-03-12 | Knauf Insulation Gmbh | Molding apparatus and process |
WO2013163242A1 (en) | 2012-04-27 | 2013-10-31 | Georgia-Pacific Chemicals Llc | Composite products made with lewis acid catalyzed binder compositions that include tannins and multifunctional aldehydes |
EP2669325B1 (en) | 2012-05-29 | 2016-01-13 | Rohm and Haas Company | Bio-based flame resistant thermosetting binders with improved wet resistance |
EP2669349B1 (en) * | 2012-05-29 | 2014-06-04 | Rohm and Haas Company | Aqueous amine-carbohydrate thermosets having reduced weight loss upon cure and improved early dry strength |
WO2013179323A1 (en) | 2012-06-01 | 2013-12-05 | Stm Technologies S.R.L. | Formaldehyde free binding composition, for mineral fibres |
US11472987B2 (en) * | 2012-06-07 | 2022-10-18 | Johns Manville | Formaldehyde free binder compositions with urea-aldehyde reaction products |
US10815593B2 (en) | 2012-11-13 | 2020-10-27 | Johns Manville | Viscosity modified formaldehyde-free binder compositions |
US9394431B2 (en) | 2012-06-07 | 2016-07-19 | Johns Manville | Formaldehyde free binder compositions with urea-aldehyde reaction products |
US8980774B2 (en) | 2012-06-15 | 2015-03-17 | Hexion Inc. | Compositions and methods for making polyesters and articles therefrom |
US9695311B2 (en) | 2012-07-27 | 2017-07-04 | Johns Manville | Formaldehyde-free binder compositions and methods of making the binders |
GB201214734D0 (en) | 2012-08-17 | 2012-10-03 | Knauf Insulation Ltd | Wood board and process for its production |
CA2892900C (en) | 2012-12-05 | 2020-08-11 | Benedicte Pacorel | Method for manufacturing an article comprising a collection of matter bound by a cured binder |
US8734613B1 (en) | 2013-07-05 | 2014-05-27 | Usg Interiors, Llc | Glass fiber enhanced mineral wool based acoustical tile |
US9598600B2 (en) * | 2013-09-20 | 2017-03-21 | Georgia-Pacific Chemicals Llc | Modified phenolic resins for making composite products |
CA2926033C (en) | 2013-10-16 | 2021-06-15 | Rockwool International A/S | Man-made vitreous fibres |
CN103555266B (zh) * | 2013-10-31 | 2016-02-17 | 林世旺 | 一种金卡粘结剂及其制备方法 |
CN103589886A (zh) * | 2013-11-17 | 2014-02-19 | 湖南金马铝业有限责任公司 | 一种粉末冶金法生产碳化硅铝基复合材料用粘结剂 |
WO2015084372A1 (en) | 2013-12-05 | 2015-06-11 | Ecosynthetix Ltd. | Formaldehyde free binder and multi-component nanoparticle |
EP2884259A1 (en) | 2013-12-11 | 2015-06-17 | Rockwool International A/S | Method for detecting curing of the binder in a mineral fibre product |
WO2015120252A1 (en) | 2014-02-07 | 2015-08-13 | Knauf Insulation, Llc | Uncured articles with improved shelf-life |
FR3018281B1 (fr) * | 2014-03-06 | 2016-02-19 | Saint Gobain Isover | Composition de liant pour laine minerale |
KR101871541B1 (ko) * | 2014-03-31 | 2018-06-26 | 주식회사 케이씨씨 | 수성 바인더 조성물 및 이를 사용하여 섬유상 재료를 결속하는 방법 |
FR3019815B1 (fr) * | 2014-04-15 | 2016-05-06 | Saint Gobain Isover | Composition d'encollage a base de saccharide non reducteur et de saccharide hydrogene, et produits isolants obtenus. |
KR101830472B1 (ko) * | 2014-04-18 | 2018-02-21 | 주식회사 케이씨씨 | 수성 열경화성 바인더 조성물 및 이를 사용하여 섬유상 재료를 결속하는 방법 |
EP2947117B2 (en) | 2014-05-19 | 2022-10-26 | Rockwool International A/S | Analytical binder for mineral wool products |
GB201408909D0 (en) * | 2014-05-20 | 2014-07-02 | Knauf Insulation Ltd | Binders |
KR101861404B1 (ko) * | 2014-06-10 | 2018-05-29 | 주식회사 케이씨씨 | 수성 복합 접착제 조성물 및 이를 사용하여 섬유상 재료를 결속하는 방법 |
KR101871542B1 (ko) * | 2014-06-10 | 2018-06-27 | 주식회사 케이씨씨 | 공정수의 재활용이 가능한 수성 접착제 조성물 및 이를 사용하여 섬유상 재료를 결속하는 방법 |
CH709783A1 (de) | 2014-06-16 | 2015-12-31 | Flumroc Ag | Verfahren zur Herstellung eines wasserlöslichen Prepolymers und Prepolymer, hergestellt nach dem Verfahren. |
US9447221B2 (en) * | 2014-07-03 | 2016-09-20 | Johns Manville | Formaldehyde-free melamine carbohydrate binders for improved fire- resistant fibrous materials |
GB201412709D0 (en) | 2014-07-17 | 2014-09-03 | Knauf Insulation And Knauf Insulation Ltd | Improved binder compositions and uses thereof |
GB201413402D0 (en) * | 2014-07-29 | 2014-09-10 | Knauf Insulation Ltd | Laminates |
PL2990494T3 (pl) | 2014-08-25 | 2017-06-30 | Rockwool International A/S | Biologiczny środek wiążący |
JP6601816B2 (ja) * | 2014-09-12 | 2019-11-06 | 群栄化学工業株式会社 | 熱硬化型バインダー組成物及びこれを用いた無機繊維製品 |
WO2016109164A2 (en) * | 2014-12-30 | 2016-07-07 | Georgia-Pacific Chemicals Llc | Composite products containing a powdered binder and methods for making and using same |
CA2974499C (fr) | 2015-01-30 | 2023-01-24 | Saint-Gobain Isover | Composition d'encollage pour laine minerale a base de lignosulfonate et d'un compose carbonyle, et produits isolants obtenus |
FR3033326B1 (fr) * | 2015-03-02 | 2018-10-26 | Saint-Gobain Isover | Mousses thermodurcies et procede de fabrication |
US9718946B2 (en) | 2015-04-13 | 2017-08-01 | Johns Manville | Catalyst formulations with reduced leachable salts |
FR3035402B1 (fr) | 2015-04-27 | 2019-04-05 | Saint-Gobain Isover | Mousses thermodurcies et procede de fabrication |
KR102037839B1 (ko) * | 2015-05-20 | 2019-10-31 | 주식회사 케이씨씨 | 바인더 조성물 및 이를 사용하여 섬유상 재료를 결속하는 방법 |
JP6662587B2 (ja) | 2015-08-05 | 2020-03-11 | ヘンケルジャパン株式会社 | 水系接着用組成物 |
GB201517882D0 (en) * | 2015-10-09 | 2015-11-25 | Knauf Insulation Ltd | Wood particle boards |
GB201517867D0 (en) | 2015-10-09 | 2015-11-25 | Knauf Insulation Ltd | Wood particle boards |
JP2017115139A (ja) | 2015-12-18 | 2017-06-29 | ヘンケルジャパン株式会社 | 水系接着用組成物 |
EP3397047A2 (en) * | 2015-12-29 | 2018-11-07 | Rockwool International A/S | Growth substrate product |
CA2954365C (en) | 2016-01-11 | 2023-01-03 | Owens Corning Intellectual Capital, Llc | Unbonded loosefill insulation |
PT3199312T (pt) * | 2016-01-28 | 2021-05-21 | Ursa Insulation Sa | Resina curável melhorada para lã mineral |
JP6796938B2 (ja) | 2016-03-28 | 2020-12-09 | ヘンケルジャパン株式会社 | 水系接着用組成物 |
EP3455182B1 (en) | 2016-05-13 | 2021-03-31 | Rockwool International A/S | Mineral wool products |
WO2018206128A1 (en) | 2017-05-11 | 2018-11-15 | Rockwool International A/S | Method of producing a plant growth substrate |
GB201610063D0 (en) | 2016-06-09 | 2016-07-27 | Knauf Insulation Ltd | Binders |
JP7032863B2 (ja) * | 2016-09-16 | 2022-03-09 | 群栄化学工業株式会社 | セルロース布紙含浸用組成物、これを用いた含浸物及び成形物 |
EP3558888A1 (en) | 2016-12-23 | 2019-10-30 | Rockwool International A/S | Binders with improved recycling properties |
HRP20230296T1 (hr) | 2016-12-23 | 2023-05-12 | Rockwool A/S | Metoda za obradu materijala od mineralne vune |
GB201701569D0 (en) | 2017-01-31 | 2017-03-15 | Knauf Insulation Ltd | Improved binder compositions and uses thereof |
CN110366588B (zh) * | 2017-02-24 | 2021-08-24 | 松下知识产权经营株式会社 | 用于热压成型的粘合剂、木质板及其制造方法 |
KR101922644B1 (ko) * | 2017-04-13 | 2018-11-27 | 씨제이제일제당 주식회사 | 바인더 조성물, 물품 및 물품 제조방법 |
JP6580626B2 (ja) * | 2017-05-29 | 2019-09-25 | ヘンケルジャパン株式会社 | 水系接着用組成物 |
US11102998B1 (en) | 2017-08-25 | 2021-08-31 | The Hershey Company | Binders and methods of making and using the same |
US10920920B2 (en) | 2017-08-30 | 2021-02-16 | Rockwool International A/S | Use of a mineral wool product |
CN111247278B (zh) * | 2017-08-30 | 2022-10-28 | 洛克沃国际公司 | 矿棉产品的用途 |
FR3074797B1 (fr) | 2017-12-13 | 2019-12-20 | Saint-Gobain Isover | Procede de fabrication de laine minerale |
GB201721228D0 (en) | 2017-12-19 | 2018-01-31 | Knauf Insulation Ltd | Binders and associated products |
GB201804908D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Binder compositions and uses thereof |
GB201804907D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Composite products |
FR3080850B1 (fr) | 2018-05-04 | 2022-08-12 | Saint Gobain Isover | Materiau d’isolation thermique |
GB2574206B (en) * | 2018-05-29 | 2023-01-04 | Knauf Insulation Sprl | Briquettes |
CN108994980A (zh) * | 2018-07-16 | 2018-12-14 | 湖北萨莱玛木结构工程有限公司 | 一种复合木板及其生产工艺 |
KR102101842B1 (ko) | 2018-08-01 | 2020-04-17 | 주식회사 케이씨씨 | 수성 바인더 조성물 |
CN109232786B (zh) * | 2018-08-14 | 2021-02-05 | 中南林业科技大学 | 用于制备空气滤纸的水性胶黏剂及其制备方法和应用 |
CN109517580B (zh) * | 2018-11-10 | 2021-01-08 | 宁波工程学院 | 一种竹液-胶原多肽复合胶黏剂的制备方法 |
JP7289637B2 (ja) * | 2018-11-27 | 2023-06-12 | ヘンケルジャパン株式会社 | 水系接着剤 |
FR3091702B1 (fr) | 2019-01-11 | 2021-01-01 | Saint Gobain Isover | Procédé de fabrication d’un produit d’isolation à base de laine minérale |
EP3683170A1 (en) | 2019-01-18 | 2020-07-22 | URSA Insulation, S.A. | Pack of insulating panels |
JP7021157B2 (ja) * | 2019-08-28 | 2022-02-16 | ヘンケルジャパン株式会社 | 水系接着用組成物の製造方法 |
FR3101343B1 (fr) | 2019-09-26 | 2021-10-22 | Saint Gobain Isover | Methode de recyclage des eaux issues d’un procede de fabrication d’un matelas de fibres minerales |
CN110684485B (zh) * | 2019-10-30 | 2021-05-07 | 南京林业大学 | 超高固含量的胶合板用环保胶黏剂、制备方法及其应用 |
KR20220115584A (ko) | 2019-12-09 | 2022-08-17 | 오웬스 코닝 인텔렉츄얼 캐피탈 엘엘씨 | 유리섬유 절연 제품 |
US11813833B2 (en) | 2019-12-09 | 2023-11-14 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
EP3835276A1 (en) | 2019-12-10 | 2021-06-16 | Saint-Gobain Isover | Method for producing mineral wool composites |
EP4107327B1 (en) | 2020-02-17 | 2024-07-24 | Unilin, BV | Board, method for manufacturing a board and a panel comprising such board material |
FR3108635B1 (fr) | 2020-03-24 | 2022-04-01 | Saint Gobain Isover | Procédé de fabrication de produits d’isolation à base de laine minérale utilisant un liant solide |
US20220064408A1 (en) * | 2020-09-01 | 2022-03-03 | Owens Corning Intellectual Capital, Llc | Aqueous binder compositions for mineral wool products |
FR3116542B1 (fr) | 2020-11-20 | 2022-11-18 | Saint Gobain Adfors | Composition de liant à base d’ingrédients biosourcés et son utilisation pour former des voiles non-tissés de fibres de verre |
WO2022258505A1 (en) | 2021-06-07 | 2022-12-15 | Basf Se | Process of producing a lignocellulosic composite, corresponding lignocellulosic composite, and use thereof |
FR3123828A1 (fr) | 2021-06-15 | 2022-12-16 | Saint-Gobain Adfors | Armature de renfort en fibres minérales pour dalles souples de revêtement de sol |
KR102561168B1 (ko) * | 2021-08-27 | 2023-07-31 | 벽산페인트 주식회사 | 친환경 단열재용 바인더 조성물 및 그의 제조방법 |
CA3240134A1 (en) * | 2022-01-31 | 2023-08-03 | Ryohei Mori | Thermoplastic composition |
BE1030512B1 (nl) * | 2022-05-10 | 2023-12-11 | Flooring Ind Ltd Sarl | Lijm voor platen |
WO2023218343A1 (en) * | 2022-05-10 | 2023-11-16 | Flooring Industries Limited, Sarl | Glue for boards |
BE1030513B1 (nl) * | 2022-05-10 | 2023-12-11 | Flooring Ind Ltd Sarl | Lijm voor platen |
WO2024088944A1 (en) | 2022-10-28 | 2024-05-02 | Basf Se | Process of producing a lignocellulosic composite and corresponding binder composition, lignocellulosic composite, kit and use |
WO2024121397A1 (en) | 2022-12-09 | 2024-06-13 | Knauf Insulation | Mineral fibre products |
WO2024163321A1 (en) * | 2023-01-31 | 2024-08-08 | Knauf Insulation, Inc. | Binder-mediated cutability of insulation products |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4259190A (en) * | 1979-09-13 | 1981-03-31 | Ppg Industries, Inc. | Glass fibers with reduced tendency to form gumming deposits and sizing composition |
US5582682A (en) * | 1988-12-28 | 1996-12-10 | Ferretti; Arthur | Process and a composition for making cellulosic composites |
KR19990037115A (ko) * | 1997-10-27 | 1999-05-25 | 쉬한 존 엠. | 열경화성 폴리사카라이드 |
WO2003071879A1 (en) * | 2002-02-22 | 2003-09-04 | Genencor International, Inc. | Browning agent |
CN1668700A (zh) * | 2002-07-15 | 2005-09-14 | 罗克伍尔国际公司 | 用于矿物纤维的无甲醛含水粘合剂组合物 |
Family Cites Families (475)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1886353A (en) | 1922-04-27 | 1932-11-01 | John Stogdell Stokes | Synthetic resin and method of making same |
US1801052A (en) | 1923-02-06 | 1931-04-14 | Meigsoid Corp | Resinous condensation product and process of making same |
US1801053A (en) | 1925-01-22 | 1931-04-14 | Meigsoid Corp | Carbohydrate product and process of making same |
US1902948A (en) | 1931-08-14 | 1933-03-28 | A M Castle & Co | Welding electrode |
US1964263A (en) | 1932-06-15 | 1934-06-26 | Anker Holth Mfg Company | Spraying fixture |
BE420665A (zh) | 1936-03-20 | |||
US2261295A (en) | 1936-09-30 | 1941-11-04 | Walther H Duisberg | Artificial textile materials |
US2215825A (en) * | 1938-03-16 | 1940-09-24 | Matilda Wallace | Core binder |
US2362086A (en) | 1941-08-26 | 1944-11-07 | Resinous Prod & Chemical Co | Volume stabilized acid absorbing resin |
US2371990A (en) | 1942-02-18 | 1945-03-20 | Du Pont | Polymeric esters |
BE471265A (zh) | 1942-04-02 | |||
BE472469A (zh) | 1942-06-16 | |||
US2500665A (en) | 1944-03-30 | 1950-03-14 | Owens Corning Fiberglass Corp | High-temperature insulation and method of manufacture |
BE472470A (zh) | 1945-07-11 | |||
GB809675A (en) | 1955-05-23 | 1959-03-04 | Corn Prod Refining Co | Improvements in or relating to refractory insulating block and method of making same |
US2875073A (en) | 1955-05-23 | 1959-02-24 | Corn Prod Refining Co | Core binder and process of making cores |
US2894920A (en) | 1957-02-12 | 1959-07-14 | Ramos Thomas | Resinous composition comprising epoxy resin, curing agent and mixture of dextrines, maltose and dextrose and process for preparing |
US2965504A (en) | 1958-04-01 | 1960-12-20 | Corn Products Co | Process for preparation of refractory insulating blocks |
GB979991A (en) | 1960-01-14 | 1965-01-06 | Polygram Casting Co Ltd | Improvements in or relating to thermosetting compositions based on carbohydrates |
US3038462A (en) | 1960-07-21 | 1962-06-12 | Gen Electric | Oven liner |
US3231349A (en) * | 1960-11-21 | 1966-01-25 | Owens Corning Fiberglass Corp | Production of vitreous fiber products |
NL275294A (zh) | 1961-03-08 | 1900-01-01 | ||
US3138473A (en) | 1962-01-26 | 1964-06-23 | Gen Mills Inc | Compositions and process to increase the wet strength of paper |
US3222243A (en) | 1962-07-11 | 1965-12-07 | Owens Corning Fiberglass Corp | Thermal insulation |
DE1905054U (de) | 1964-03-05 | 1964-11-26 | Guenter Manzke Produktion Und | Bauelement zur seitlichen fahrbahnbegrenzung. |
US3232821A (en) * | 1964-12-11 | 1966-02-01 | Ferro Corp | Felted fibrous mat and apparatus for manufacturing same |
US3297419A (en) * | 1965-08-17 | 1967-01-10 | Fyr Tech Products Inc | Synthetic fuel log and method of manufacture |
DE1905054A1 (de) | 1968-02-05 | 1969-08-21 | Dierks Forests Inc | Mischung zur Herstellung eines Bindemittels und Verfahren zu ihrer Verwendung |
US3856606A (en) * | 1968-06-17 | 1974-12-24 | Union Carbide Corp | Coupling solid substrates using silyl peroxide compounds |
US3551365A (en) | 1968-11-29 | 1970-12-29 | Ralph Matalon | Composite cross - linking agent/resin former compositions and cold-setting and heat - setting resins prepared therefrom |
US3616181A (en) * | 1969-11-05 | 1971-10-26 | Owens Corning Fiberglass Corp | Moldable article of glass fibers and a modified phenolic binder |
BE758740A (fr) * | 1969-11-12 | 1971-04-16 | Owens Corning Fiberglass Corp | Appret amylace et fibres amidonnees presentant des caracteristiques de sechage ameliorees |
SU374400A1 (ru) | 1970-07-09 | 1973-03-20 | Способ получения нетканых материалов | |
US3867119A (en) | 1970-07-20 | 1975-02-18 | Paramount Glass Mfg Co Ltd | Apparatus for manufacturing glass fibers |
US3784408A (en) | 1970-09-16 | 1974-01-08 | Hoffmann La Roche | Process for producing xylose |
US3826767A (en) | 1972-01-26 | 1974-07-30 | Calgon Corp | Anionic dextran graft copolymers |
US3791807A (en) | 1972-05-02 | 1974-02-12 | Certain Teed Prod Corp | Waste water reclamation in fiber glass operation |
US3961081A (en) | 1972-06-05 | 1976-06-01 | Mckenzie Carl O | Molasses feed block for animals and method of making same |
US4144027A (en) | 1972-07-07 | 1979-03-13 | Milliken Research Corporation | Product and process |
IT971367B (it) | 1972-11-30 | 1974-04-30 | Sir Soc Italiana Resine Spa | Procedimento per la preparazione continua di poliesteri insaturi |
US3955031A (en) | 1973-01-18 | 1976-05-04 | Owens-Corning Fiberglas Corporation | Flame resistant building material |
US4201857A (en) | 1973-02-22 | 1980-05-06 | Givaudan Corporation | Novel condensation products having high activity to insolubilize proteins and protein-insolubilized products |
US4186053A (en) | 1973-02-22 | 1980-01-29 | Givaudan Corporation | Insolubilized enzyme product |
CH579109A5 (zh) | 1973-02-22 | 1976-08-31 | Givaudan & Cie Sa | |
US3802897A (en) * | 1973-02-23 | 1974-04-09 | Anheuser Busch | Water resistant starch adhesive |
US3809664A (en) | 1973-08-16 | 1974-05-07 | Us Agriculture | Method of preparing starch graft polymers |
DE2360876A1 (de) * | 1973-12-06 | 1975-06-12 | Bayer Ag | Kationische farbstoffe |
US4054713A (en) | 1973-12-28 | 1977-10-18 | Kao Soap Co., Ltd. | Process for preparing glass fiber mats |
SE7410542L (sv) | 1974-01-29 | 1976-01-12 | Givaudan & Cie Sa | Kondensationsprodukter. |
GB1469331A (en) | 1974-02-18 | 1977-04-06 | Pfizer Ltd | Flavouring agent |
US4183997A (en) | 1974-02-22 | 1980-01-15 | John Jansky | Bonding of solid lignocellulosic material |
US4107379A (en) | 1974-02-22 | 1978-08-15 | John Stofko | Bonding of solid lignocellulosic material |
US4014726A (en) * | 1974-03-18 | 1977-03-29 | Owens-Corning Fiberglas Corporation | Production of glass fiber products |
US3907724A (en) | 1974-04-10 | 1975-09-23 | Monsanto Co | Phenolic binders for mineral fiber thermal insulation |
US3919134A (en) | 1974-04-10 | 1975-11-11 | Monsanto Co | Thermal insulation of mineral fiber matrix bound with phenolic resin |
US3922466A (en) | 1974-09-16 | 1975-11-25 | Owens Corning Fiberglass Corp | Silane coupling agents |
US3956204A (en) | 1975-03-10 | 1976-05-11 | Monsanto Company | Antipunking phenolic resin binder systems for mineral fiber thermal insulation |
US4184986A (en) | 1975-08-19 | 1980-01-22 | Givaudan Corporation | Novel condensation products having high activity to insolubilize proteins and protein-insolubilized products |
CH594370A5 (zh) | 1975-08-26 | 1978-01-13 | Maggi Ag | |
US4028290A (en) | 1975-10-23 | 1977-06-07 | Hercules Incorporated | Highly absorbent modified polysaccharides |
JPS52142736A (en) | 1976-05-24 | 1977-11-28 | Sumitomo Durez Co | Method of accelerating hardening of phenolic adhesive |
CA1090026A (en) | 1976-07-22 | 1980-11-18 | John P. Gibbons | Carbohydrate-phenol based condensation resins incorporating nitrogen-containing compounds |
US4048127A (en) * | 1976-07-22 | 1977-09-13 | Cpc International Inc. | Carbohydrate-based condensation resin |
US4217414A (en) | 1976-11-01 | 1980-08-12 | Cpc International Inc. | Process for separating and recovering vital wheat gluten from wheat flour and the like |
US4148765A (en) | 1977-01-10 | 1979-04-10 | The Dow Chemical Company | Polyester resins containing dicyclopentadiene |
US4097427A (en) * | 1977-02-14 | 1978-06-27 | Nalco Chemical Company | Cationization of starch utilizing alkali metal hydroxide, cationic water-soluble polymer and oxidant for improved wet end strength |
JPS5717850Y2 (zh) | 1977-02-16 | 1982-04-14 | ||
JPS53113784A (en) | 1977-03-17 | 1978-10-04 | Koei Chemical Co | Scale removing agent |
DE2721186C2 (de) * | 1977-05-11 | 1986-04-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung eines Gemisches von niedermolekularen Polyhydroxylverbindungen |
US4201247A (en) | 1977-06-29 | 1980-05-06 | Owens-Corning Fiberglas Corporation | Fibrous product and method and apparatus for producing same |
AU530553B2 (en) | 1978-05-09 | 1983-07-21 | Commonwealth Scientific And Industrial Research Organisation | Treatment of textile materials |
DE2833138A1 (de) | 1978-07-28 | 1980-02-07 | Bayer Ag | Methylolierte mono- und oligosaccharide |
US4506684A (en) | 1978-08-02 | 1985-03-26 | Philip Morris Incorporated | Modified cellulosic smoking material and method for its preparation |
US4333484A (en) | 1978-08-02 | 1982-06-08 | Philip Morris Incorporated | Modified cellulosic smoking material and method for its preparation |
HU186349B (en) | 1979-01-23 | 1985-07-29 | Magyar Tudomanyos Akademia | Process for producing polymeres containing metals of side-groups in complex bond |
US4265963A (en) | 1979-01-26 | 1981-05-05 | Arco Polymers, Inc. | Flameproof and fireproof products containing monoethanolamine, diethylamine or morpholine |
US4233432A (en) | 1979-05-10 | 1980-11-11 | United States Steel Corporation | Dicyclopentadiene polyester resins |
US4310585A (en) | 1979-06-15 | 1982-01-12 | Owens-Corning Fiberglas Corporation | Fibrous product formed of layers of compressed fibers |
US4296173A (en) * | 1979-09-13 | 1981-10-20 | Ppg Industries, Inc. | Glass fibers with reduced tendency to form gumming deposits and sizing composition comprising two starches with different amylose content |
US4246367A (en) | 1979-09-24 | 1981-01-20 | United States Steel Corporation | Dicyclopentadiene polyester resins |
US4278573A (en) | 1980-04-07 | 1981-07-14 | National Starch And Chemical Corporation | Preparation of cationic starch graft copolymers from starch, N,N-methylenebisacrylamide, and polyamines |
US4379101A (en) | 1980-06-04 | 1983-04-05 | Allen Industries, Inc. | Forming apparatus and method |
US4330443A (en) | 1980-06-18 | 1982-05-18 | The United States Of America As Represented By The Secretary Of Agriculture | Dry chemical process for grafting acrylic and methyl acrylic ester and amide monomers onto starch-containing materials |
GB2078805A (en) * | 1980-06-27 | 1982-01-13 | Tba Industrial Products Ltd | Fire and Weld Splash Resistant for Glass Fabric |
EP0044614A3 (en) | 1980-06-27 | 1982-05-19 | TBA Industrial Products Limited | Improvements in and relating to glass fabrics |
US4361588A (en) | 1980-07-30 | 1982-11-30 | Nutrisearch Company | Fabricated food products from textured protein particles |
US4400496A (en) | 1980-09-22 | 1983-08-23 | University Of Florida | Water-soluble graft copolymers of starch-acrylamide and uses therefor |
JPS57101100U (zh) | 1980-12-12 | 1982-06-22 | ||
JPS57101100A (en) | 1980-12-15 | 1982-06-23 | Nitto Boseki Co Ltd | Production of mineral fiberboard |
JPS5811193B2 (ja) | 1981-02-02 | 1983-03-01 | 三菱瓦斯化学株式会社 | 細菌菌体の製造方法 |
US4396430A (en) | 1981-02-04 | 1983-08-02 | Ralph Matalon | Novel foundry sand binding compositions |
US4357194A (en) | 1981-04-14 | 1982-11-02 | John Stofko | Steam bonding of solid lignocellulosic material |
JPS5811193A (ja) | 1981-07-11 | 1983-01-21 | Ricoh Co Ltd | 感熱記録材料 |
US4393019A (en) | 1981-11-30 | 1983-07-12 | The United States Of America As Represented By The Secretary Of Agriculture | Method of pressing reconstituted lignocellulosic materials |
FR2529917A1 (fr) | 1982-07-06 | 1984-01-13 | Saint Gobain Isover | Procede et dispositif pour la formation de feutre de fibres contenant un produit additionnel |
US4464523A (en) | 1983-05-16 | 1984-08-07 | National Starch And Chemical Corporation | Process for the preparation of graft copolymers of cellulose derivatives and diallyl, dialkyl ammonium halides |
US4668716A (en) * | 1983-09-30 | 1987-05-26 | Union Carbide Corporation | Novel fatty ethenoid acylaminoorganosilicon compounds and their use as a coupling agent |
US4524164A (en) * | 1983-12-02 | 1985-06-18 | Chemical Process Corporation | Thermosetting adhesive resins |
US4654259A (en) | 1984-02-14 | 1987-03-31 | Carbocol Inc. | Method and composition for bonding solid lignocellulosic material |
FR2559793B1 (fr) | 1984-02-17 | 1986-12-19 | Saint Gobain Isover | Procede de production de matelas de fibres minerales a partir d'un materiau fondu |
US4714727A (en) | 1984-07-25 | 1987-12-22 | H. B. Fuller Company | Aqueous emulsion coating for individual fibers of a cellulosic sheet providing improved wet strength |
GB2170208B (en) | 1985-01-29 | 1988-06-22 | Enigma Nv | A formaldehyde binder |
JPS61195647A (ja) | 1985-02-27 | 1986-08-29 | Kanebo Shokuhin Kk | ビタ−チヨコの製法 |
US4754056A (en) | 1985-04-05 | 1988-06-28 | Desoto, Inc. | Radiation-curable coatings containing reactive pigment dispersants |
JPS61195647U (zh) | 1985-05-27 | 1986-12-05 | ||
SE8504501D0 (sv) | 1985-09-30 | 1985-09-30 | Astra Meditec Ab | Method of forming an improved hydrophilic coating on a polymer surface |
US4828643A (en) | 1986-02-19 | 1989-05-09 | Masonite Corporation | Liquified cellulosic fiber, resin binders and articles manufactured therewith, and method of manufacturing same |
US4692478A (en) | 1986-03-14 | 1987-09-08 | Chemical Process Corporation | Process for preparation of resin and resin obtained |
JPH0734023B2 (ja) | 1986-05-09 | 1995-04-12 | 松下電器産業株式会社 | 機器の終了報知器 |
US4780339A (en) * | 1986-07-30 | 1988-10-25 | National Starch And Chemical Corporation | Sized glass fibers and method for production thereof |
DE3629470A1 (de) | 1986-08-29 | 1988-03-10 | Basf Lacke & Farben | Carboxylgruppen und tertiaere aminogruppen enthaltendes polykondensations- und/oder additionsprodukt, ueberzugsmittel auf der basis desselben sowie deren verwendung |
IL80298A (en) | 1986-10-14 | 1993-01-31 | Res & Dev Co Ltd | Eye drops |
US4720295A (en) | 1986-10-20 | 1988-01-19 | Boris Bronshtein | Controlled process for making a chemically homogeneous melt for producing mineral wool insulation |
US5013405A (en) | 1987-01-12 | 1991-05-07 | Usg Interiors, Inc. | Method of making a low density frothed mineral wool |
GB8809486D0 (en) | 1987-04-22 | 1988-05-25 | Micropore International Ltd | Procedure to manufacture thermal insulating material for use at high temperatures |
US4845162A (en) * | 1987-06-01 | 1989-07-04 | Allied-Signal Inc. | Curable phenolic and polyamide blends |
DE3734752A1 (de) | 1987-10-14 | 1989-05-03 | Basf Ag | Verfahren zur herstellung von waessrigen (meth)acrylsaeureester-copolymer-dispersionen in zwei stufen und deren verwendung als impraegnier-, ueberzugs- und bindemittel fuer flaechige fasergebilde |
SE464687B (sv) | 1987-11-10 | 1991-06-03 | Biocarb Ab | Foerfarande foer framstaellning av en gelprodukt |
FR2626578B1 (fr) | 1988-02-03 | 1992-02-21 | Inst Francais Du Petrole | Polymeres amino-substitues et leur utilisation comme additifs de modification des proprietes a froid de distillats moyens d'hydrocarbures |
US5095054A (en) | 1988-02-03 | 1992-03-10 | Warner-Lambert Company | Polymer compositions containing destructurized starch |
US5441713A (en) | 1988-04-29 | 1995-08-15 | Nalco Fuel Tech | Hardness suppression in urea solutions |
JPH0299655A (ja) | 1988-08-03 | 1990-04-11 | Sequa Chemicals Inc | 繊維マット用澱紛系バインダー組成物およびその製造方法 |
US4988780A (en) | 1988-08-15 | 1991-01-29 | Allied-Signal | Flame resistant article made of phenolic triazine and related method using a pure cyanato novolac |
US4918861A (en) | 1988-11-15 | 1990-04-24 | Hobbs Bonded Fibers | Plant growth bed with high loft textile fibers |
DE3839171A1 (de) | 1988-11-19 | 1990-05-23 | Bayer Ag | Waessriges beschichtungsmittel, ein verfahren zu seiner herstellung und seine verwendung |
CA2005321A1 (en) | 1988-12-28 | 1990-06-28 | Arthur Ferretti | Thermosettable resin intermediate |
US5371194A (en) | 1988-12-28 | 1994-12-06 | Ferretti; Arthur | Biomass derived thermosetting resin |
US4992519A (en) | 1989-02-01 | 1991-02-12 | Borden, Inc. | Binder composition with low formaldehyde emission and process for its preparation |
US5198492A (en) | 1989-02-13 | 1993-03-30 | Rohn And Haas Company | Low viscosity, fast curing binder for cellulose |
US5278222A (en) * | 1989-02-13 | 1994-01-11 | Rohm And Haas Company | Low viscosity, fast curing binder for cellulose |
JPH0734023Y2 (ja) | 1989-04-17 | 1995-08-02 | 川崎重工業株式会社 | 粉粒体等の秤量輸送装置 |
AT393272B (de) | 1989-06-07 | 1991-09-25 | Rettenbacher Markus Dipl Ing | Verfahren zur herstellung von extrudierten, direkt expandierten biopolymerprodukten und holzfaserplatten, verpackungs- und isoliermaterialien |
US5037930A (en) | 1989-09-22 | 1991-08-06 | Gaf Chemicals Corporation | Heterocyclic quaternized nitrogen-containing cellulosic graft polymers |
DE68909870T2 (de) | 1989-11-08 | 1994-02-10 | Shell Int Research | Weiche flexible Polyurethanschaumstoffe, Verfahren zu deren Herstellung sowie in diesem Verfahren verwendbare Polyolzusammensetzung. |
JP2515411B2 (ja) | 1989-12-01 | 1996-07-10 | 新王子製紙株式会社 | 感熱記録材料の製造方法 |
JP2926513B2 (ja) | 1989-12-11 | 1999-07-28 | 住友化学工業株式会社 | 樹脂組成物およびその製造方法 |
US5151465A (en) | 1990-01-04 | 1992-09-29 | Arco Chemical Technology, L.P. | Polymer compositions and absorbent fibers produced therefrom |
EP0442406B1 (en) * | 1990-02-14 | 1995-07-26 | Material Engineering Technology Laboratory, Inc. | Filled and sealed, self-contained mixing container |
JP2574051B2 (ja) | 1990-02-28 | 1997-01-22 | 明治製菓株式会社 | インドール酢酸生合成酵素をコードする遺伝子 |
DK0445578T3 (da) | 1990-03-03 | 1994-11-21 | Basf Ag | Formlegemer |
RU1765996C (ru) | 1990-06-11 | 1995-08-27 | Назаров Петр Васильевич | Способ изготовления тепло- и звукоизоляционных изделий |
FR2663049B1 (fr) | 1990-06-12 | 1994-05-13 | Isover Saint Gobain | Recyclage de produits fibreux dans une ligne de production de matelas a partir de fibres. |
US5041595A (en) * | 1990-09-26 | 1991-08-20 | Union Carbide Chemicals And Plastics Technology Corporation | Method for manufacturing vinylalkoxysilanes |
US6495656B1 (en) * | 1990-11-30 | 2002-12-17 | Eastman Chemical Company | Copolyesters and fibrous materials formed therefrom |
ATE224435T1 (de) | 1990-12-28 | 2002-10-15 | K C Shen Technology Internat L | Wärmehärtbares harz und verbundstoff aus lignozellulosematerial |
GB9100277D0 (en) | 1991-01-07 | 1991-02-20 | Courtaulds Fibres Ltd | Adhesive |
US5240498A (en) | 1991-01-09 | 1993-08-31 | Martin Marietta Magnesia Specialties Inc. | Carbonaceous binder |
US5217741A (en) | 1991-01-25 | 1993-06-08 | Snow Brand Milk Products Co., Ltd. | Solution containing whey protein, whey protein gel, whey protein powder and processed food product produced by using the same |
GB9108604D0 (en) | 1991-04-22 | 1991-06-05 | Nadreph Ltd | Gel products and a process for making them |
IT1249309B (it) * | 1991-05-03 | 1995-02-22 | Faricerca Spa | Polisaccaridi di tipo cationico |
US5143582A (en) * | 1991-05-06 | 1992-09-01 | Rohm And Haas Company | Heat-resistant nonwoven fabrics |
US5128407A (en) | 1991-07-25 | 1992-07-07 | Miles Inc. | Urea extended polyisocyanates |
DE4127733A1 (de) | 1991-08-22 | 1993-02-25 | Basf Ag | Pfropfpolymerisate aus saccharidstrukturen enthaltenden naturstoffen oder deren derivaten und ethylenisch ungesaettigten verbindungen und ihre verwendung |
US5123949A (en) | 1991-09-06 | 1992-06-23 | Manville Corporation | Method of introducing addivites to fibrous products |
GB9126828D0 (en) * | 1991-12-18 | 1992-02-19 | British American Tobacco Co | Improvements relating to smoking articles |
DE4142261A1 (de) | 1991-12-20 | 1993-06-24 | Man Technologie Gmbh | Verfahren und vorrichtung zur herstellung von verbundbauteilen |
JPH05186635A (ja) * | 1992-01-10 | 1993-07-27 | Goyo Paper Working Co Ltd | 包装用材料 |
DE4202248A1 (de) | 1992-01-28 | 1993-07-29 | Belland Ag | Verfahren zur wiedergewinnung von in waessrig alkalischem oder saurem milieu geloesten polymeren |
FR2688791B1 (fr) | 1992-03-20 | 1995-06-16 | Roquette Freres | Composition liante pour la preparation d'un nouvel agglomere a base de materiaux finement divises, procede mettant en óoeuvre cette composition et nouvel agglomere obtenu. |
US5550189A (en) * | 1992-04-17 | 1996-08-27 | Kimberly-Clark Corporation | Modified polysaccharides having improved absorbent properties and process for the preparation thereof |
US6077883A (en) | 1992-05-19 | 2000-06-20 | Johns Manville International, Inc. | Emulsified furan resin based glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions |
AU5347294A (en) | 1992-05-19 | 1994-01-04 | Schuller International, Inc. | Glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions |
US5534612A (en) * | 1992-05-19 | 1996-07-09 | Schuller International, Inc. | Glass fiber binding compositions, process of making glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions |
US5389716A (en) | 1992-06-26 | 1995-02-14 | Georgia-Pacific Resins, Inc. | Fire resistant cured binder for fibrous mats |
US5661213A (en) | 1992-08-06 | 1997-08-26 | Rohm And Haas Company | Curable aqueous composition and use as fiberglass nonwoven binder |
US5582670A (en) | 1992-08-11 | 1996-12-10 | E. Khashoggi Industries | Methods for the manufacture of sheets having a highly inorganically filled organic polymer matrix |
US5434233A (en) * | 1992-08-12 | 1995-07-18 | Kiely; Donald E. | Polyaldaramide polymers useful for films and adhesives |
US5538783A (en) | 1992-08-17 | 1996-07-23 | Hansen; Michael R. | Non-polymeric organic binders for binding particles to fibers |
US5352480A (en) | 1992-08-17 | 1994-10-04 | Weyerhaeuser Company | Method for binding particles to fibers using reactivatable binders |
US5589256A (en) | 1992-08-17 | 1996-12-31 | Weyerhaeuser Company | Particle binders that enhance fiber densification |
US6391453B1 (en) | 1992-08-17 | 2002-05-21 | Weyernaeuser Company | Binder treated particles |
US7144474B1 (en) | 1992-08-17 | 2006-12-05 | Weyerhaeuser Co. | Method of binding particles to binder treated fibers |
US5300192A (en) | 1992-08-17 | 1994-04-05 | Weyerhaeuser Company | Wet laid fiber sheet manufacturing with reactivatable binders for binding particles to fibers |
US5543215A (en) | 1992-08-17 | 1996-08-06 | Weyerhaeuser Company | Polymeric binders for binding particles to fibers |
US5547541A (en) | 1992-08-17 | 1996-08-20 | Weyerhaeuser Company | Method for densifying fibers using a densifying agent |
US5807364A (en) | 1992-08-17 | 1998-09-15 | Weyerhaeuser Company | Binder treated fibrous webs and products |
US5308896A (en) | 1992-08-17 | 1994-05-03 | Weyerhaeuser Company | Particle binders for high bulk fibers |
NZ255814A (en) | 1992-08-17 | 1996-06-25 | Weyerhaeuser Co | Particle binders for high bulk fibres for absorbent articles |
US5641561A (en) | 1992-08-17 | 1997-06-24 | Weyerhaeuser Company | Particle binding to fibers |
US6340411B1 (en) | 1992-08-17 | 2002-01-22 | Weyerhaeuser Company | Fibrous product containing densifying agent |
FR2694894B1 (fr) | 1992-08-20 | 1994-11-10 | Coletica | Utilisation d'une réaction de transacylation entre un polysaccharide estérifié et une substance polyaminée ou polyhydroxylée pour la fabrication de microparticules, procédé et composition. |
DE4233622C2 (de) | 1992-10-06 | 2000-01-05 | Rolf Hesch | Preßverfahren zum Beschichten eines Werkstückes und Presse zur Durchführung des Verfahrens |
FR2697023B1 (fr) | 1992-10-16 | 1994-12-30 | Roquette Freres | Polymère soluble hypocalorique du glucose et procédé de préparation de ce polymère . |
US5300144A (en) | 1992-11-02 | 1994-04-05 | Martin Marietta Magnesia Specialties, Inc. | Binder composition |
JP3173680B2 (ja) | 1992-12-03 | 2001-06-04 | 共同印刷株式会社 | Lcdカラーフィルタ基板端面の皮膜除去方法およびその装置 |
EP0601417A3 (de) | 1992-12-11 | 1998-07-01 | Hoechst Aktiengesellschaft | Physiologisch verträglicher und physiologisch abbaubarer, Kohlenhydratrezeptorblocker auf Polymerbasis, ein Verfahren zu seiner Herstellung und seine Verwendung |
US5376614A (en) | 1992-12-11 | 1994-12-27 | United Technologies Corporation | Regenerable supported amine-polyol sorbent |
US5545279A (en) * | 1992-12-30 | 1996-08-13 | Hall; Herbert L. | Method of making an insulation assembly |
US5672659A (en) | 1993-01-06 | 1997-09-30 | Kinerton Limited | Ionic molecular conjugates of biodegradable polyesters and bioactive polypeptides |
US6221958B1 (en) | 1993-01-06 | 2001-04-24 | Societe De Conseils De Recherches Et D'applications Scientifiques, Sas | Ionic molecular conjugates of biodegradable polyesters and bioactive polypeptides |
US5863985A (en) | 1995-06-29 | 1999-01-26 | Kinerton Limited | Ionic molecular conjugates of biodegradable polyesters and bioactive polypeptides |
CA2154562A1 (en) * | 1993-01-23 | 1994-08-04 | Helmut Schiwek | Glass fiber manufacturing process and plant |
IL104734A0 (en) * | 1993-02-15 | 1993-06-10 | Univ Bar Ilan | Bioactive conjugates of cellulose with amino compounds |
DE69413434T2 (de) | 1993-02-26 | 1999-04-01 | Mitsui Chemicals, Inc., Tokio/Tokyo | Harze für elektrophotographische Entwickler |
US5981719A (en) | 1993-03-09 | 1999-11-09 | Epic Therapeutics, Inc. | Macromolecular microparticles and methods of production and use |
US6090925A (en) | 1993-03-09 | 2000-07-18 | Epic Therapeutics, Inc. | Macromolecular microparticles and methods of production and use |
US5554730A (en) | 1993-03-09 | 1996-09-10 | Middlesex Sciences, Inc. | Method and kit for making a polysaccharide-protein conjugate |
DE4308089B4 (de) | 1993-03-13 | 2004-05-19 | Basf Ag | Formaldehydfreie Bindemittel für Holz |
JPH07228857A (ja) * | 1993-05-31 | 1995-08-29 | Mitsui Toatsu Chem Inc | 耐熱性接着剤溶液 |
US5929184A (en) | 1993-06-02 | 1999-07-27 | Geltex Pharmaceuticals, Inc. | Hydrophilic nonamine-containing and amine-containing copolymers and their use as bile acid sequestrants |
US6855337B1 (en) | 1993-06-17 | 2005-02-15 | Carle Development Foundation | Bear derived isolate and method |
US5340868A (en) | 1993-06-21 | 1994-08-23 | Owens-Corning Fiberglass Technology Inc. | Fibrous glass binders |
US5318990A (en) | 1993-06-21 | 1994-06-07 | Owens-Corning Fiberglas Technology Inc. | Fibrous glass binders |
JP3399588B2 (ja) | 1993-07-20 | 2003-04-21 | 東洋紡績株式会社 | 筆記具用インク |
ES2140558T3 (es) | 1993-09-29 | 2000-03-01 | Grace W R & Co | Producto aditivo para cemento mejorado, con propiedades reologicas mejoradas, y procedimiento para la formacion del mismo. |
US5416139A (en) | 1993-10-07 | 1995-05-16 | Zeiszler; Dennis E. | Structural building materials or articles obtained from crop plants or residues therefrom and/or polyolefin materials |
US5393849A (en) | 1993-10-19 | 1995-02-28 | Georgia-Pacific Resins, Inc. | Curable polyester/polyamino compositions |
JP2811540B2 (ja) | 1993-10-20 | 1998-10-15 | 呉羽化学工業株式会社 | ガスバリヤー性フィルム及びその製造方法 |
US5503920A (en) | 1993-12-27 | 1996-04-02 | Owens-Corning Fiberglass Technology, Inc. | Process for improving parting strength of fiberglass insulation |
DE4406172C2 (de) | 1994-02-25 | 2003-10-02 | Sanol Arznei Schwarz Gmbh | Polyester |
DE4408688A1 (de) | 1994-03-15 | 1995-09-21 | Basf Ag | Formaldehydfreie Binde-, Imprägnier- oder Beschichtungsmittel für faserförmige Flächengebilde |
US5955448A (en) | 1994-08-19 | 1999-09-21 | Quadrant Holdings Cambridge Limited | Method for stabilization of biological substances during drying and subsequent storage and compositions thereof |
GB9411080D0 (en) | 1994-06-02 | 1994-07-20 | Unilever Plc | Treatment |
GB9412007D0 (en) | 1994-06-15 | 1994-08-03 | Rockwell International A S | Production of mineral fibres |
US5580856A (en) | 1994-07-15 | 1996-12-03 | Prestrelski; Steven J. | Formulation of a reconstituted protein, and method and kit for the production thereof |
US5492756A (en) | 1994-07-22 | 1996-02-20 | Mississippi State University | Kenaf core board material |
DE4432899A1 (de) * | 1994-09-15 | 1996-03-21 | Wacker Chemie Gmbh | Vernetzbare Polymerpulver-Zusammensetzungen |
CN1079811C (zh) * | 1994-11-21 | 2002-02-27 | 旭化成株式会社 | 高分子复合材料 |
DE69633368T2 (de) | 1995-02-07 | 2005-02-17 | Daicel-Degussa Ltd. | Zementabbindeverzögerer und zementabbindeverzögererfolie |
SI0810981T2 (sl) | 1995-02-21 | 2009-04-30 | Rockwool Lapinus Bv | Postopek za izdelavo produkta iz mineralne volne |
DE59500267D1 (de) | 1995-03-24 | 1997-07-03 | Giulini Chemie | Amphotere Polymerisatdispersion, Verfahren zur Herstellung und deren Verwendung |
US5919831A (en) | 1995-05-01 | 1999-07-06 | Philipp; Warren H. | Process for making an ion exchange material |
US5670585A (en) | 1995-06-13 | 1997-09-23 | Schuller International, Inc. | Use of polyacrylic acid and other polymers as additives in fiberglass formaldehyde based binders |
US5562740A (en) * | 1995-06-15 | 1996-10-08 | The Procter & Gamble Company | Process for preparing reduced odor and improved brightness individualized, polycarboxylic acid crosslinked fibers |
US5720796A (en) | 1995-08-08 | 1998-02-24 | W. R. Grace & Co.-Conn. | Process of using roll press grinding aid for granulated blast furnace slag |
US5942123A (en) * | 1995-09-05 | 1999-08-24 | Mcardle; Blaise | Method of using a filter aid protein-polysaccharide complex composition |
US5788423A (en) | 1995-09-08 | 1998-08-04 | G.P. Industries, Inc. | Masonry block retaining wall with attached keylock facing panels and method of constructing the same |
WO1997020000A2 (en) | 1995-11-28 | 1997-06-05 | Kimberly-Clark Worldwide, Inc. | Improved colorant stabilizers |
JPH09157627A (ja) | 1995-12-13 | 1997-06-17 | Sekisui Chem Co Ltd | 水溶性粘着剤組成物 |
US6458889B1 (en) | 1995-12-18 | 2002-10-01 | Cohesion Technologies, Inc. | Compositions and systems for forming crosslinked biomaterials and associated methods of preparation and use |
US7883693B2 (en) | 1995-12-18 | 2011-02-08 | Angiodevice International Gmbh | Compositions and systems for forming crosslinked biomaterials and methods of preparation of use |
US6407225B1 (en) | 1995-12-21 | 2002-06-18 | The Dow Chemical Company | Compositions comprising hydroxy-functional polymers |
AU682630B2 (en) | 1996-01-11 | 1997-10-09 | Kowng Young Pharm. & Chem. Co., Ltd. | Non-heating food binder |
US5788243A (en) | 1996-01-23 | 1998-08-04 | Harshaw; Bob F. | Biodegradable target |
DE19606394A1 (de) * | 1996-02-21 | 1997-08-28 | Basf Ag | Formaldehydfreie, wäßrige Bindemittel |
US6139619A (en) | 1996-02-29 | 2000-10-31 | Borden Chemical, Inc. | Binders for cores and molds |
US5922403A (en) | 1996-03-12 | 1999-07-13 | Tecle; Berhan | Method for isolating ultrafine and fine particles |
WO1997039330A1 (en) | 1996-04-12 | 1997-10-23 | Oncor, Inc. | Method and composition for controlling formaldehyde fixation by delayed quenching |
US6072086A (en) | 1996-04-12 | 2000-06-06 | Intergen Company | Method and composition for controlling formaldehyde fixation by delayed quenching |
DE19621573A1 (de) | 1996-05-29 | 1997-12-04 | Basf Ag | Thermisch härtbare, wäßrige Zusammensetzungen |
US5719092A (en) * | 1996-05-31 | 1998-02-17 | Eastman Kodak Company | Fiber/polymer composite for use as a photographic support |
DE69734315T2 (de) | 1996-06-25 | 2006-05-18 | Hexion Speciality Chemicals, Inc., Columbus | Bindemittel für giessformen und kerne |
US5807514A (en) * | 1996-07-10 | 1998-09-15 | Owens-Corning Fiberglas Technology, Inc. | Manufacturing of foam-containing composites |
CA2212470A1 (en) | 1996-08-21 | 1998-02-21 | Rohm And Haas Company | A formaldehyde-free, accelerated cure aqueous composition for bonding glass fiber-heat resistant nonwovens |
US6067821A (en) | 1996-10-07 | 2000-05-30 | Owens Corning Fiberglas Technology, Inc. | Process for making mineral wool fibers from lumps of uncalcined raw bauxite |
NL1004379C2 (nl) | 1996-10-29 | 1998-05-08 | Borculo Cooep Weiprod | Toepassing van suikeraminen en suikeramiden als lijm, alsmede nieuwe suikeraminen en suikeramiden. |
JP2001503461A (ja) | 1996-11-04 | 2001-03-13 | ハンツマン・アイシーアイ・ケミカルズ・エルエルシー | 硬質ポリウレタンフォーム |
US20020161108A1 (en) | 2000-03-09 | 2002-10-31 | Stepan Company, A Corporation Of The State Of Delaware | Emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids |
US6310227B1 (en) | 1997-01-31 | 2001-10-30 | The Procter & Gamble Co. | Reduced calorie cooking and frying oils having improved hydrolytic stability, and process for preparing |
CZ293298B6 (cs) | 1997-02-03 | 2004-03-17 | Isover Saint-Gobain | Pojivo pro minerální vlnu a jím pojený produkt z minerální vlny |
US5932665A (en) | 1997-02-06 | 1999-08-03 | Johns Manville International, Inc. | Polycarboxy polymer acid binders having reduced cure temperatures |
JPH10234314A (ja) | 1997-02-24 | 1998-09-08 | Miyoujiyou Shokuhin Kk | 食品に焦げ目をつけるための組成物 |
DE69821922T2 (de) * | 1997-03-19 | 2004-12-16 | Danisco Usa, Inc. | Polymerisation von Mono- und Disacchariden mit niedrigen Mengen an Mineralsäuren |
US6475552B1 (en) * | 1997-03-19 | 2002-11-05 | Danisco Finland Oy | Polymerization of mono and disaccharides using low levels of polycarboxylic acids |
CN1089727C (zh) | 1997-04-11 | 2002-08-28 | 广州市环境保护科学研究所 | 阳离子/两性接枝型聚丙烯酰胺絮凝剂的制备方法 |
TW408152B (en) | 1997-04-25 | 2000-10-11 | Rohm & Haas | Formaldehyde-free curable composition and method for bonding heat-resistant fibers of a nonwoven material by using the composition |
EP0979324B1 (de) * | 1997-05-02 | 2002-12-04 | Henkel Dorus GmbH & Co. KG | Thermoplastisches verbundmaterial |
US5954869A (en) | 1997-05-07 | 1999-09-21 | Bioshield Technologies, Inc. | Water-stabilized organosilane compounds and methods for using the same |
DK0878135T3 (da) | 1997-05-15 | 2002-06-17 | Nestle Sa | Fremgangsmåde til fremstilling og ekstraktion af aromaer |
DE19721691A1 (de) | 1997-05-23 | 1998-11-26 | Basf Ag | Klebstoffe auf Basis einer wässrigen Polymerdispersion, Verfahren zu ihrer Herstellung und ihre Verwendung |
IT1292024B1 (it) | 1997-05-28 | 1999-01-25 | Balzaretti Modigliani Spa | Procedimento e dispositivo di riciclaggio di scarti in una produzione di fibre minerali |
DE19729161A1 (de) * | 1997-07-08 | 1999-01-14 | Basf Ag | Thermisch härtbare, wässrige Zusammensetzungen |
JP3188657B2 (ja) | 1997-07-24 | 2001-07-16 | 株式会社第一化成 | 錠剤又は顆粒状製品 |
US5977232A (en) | 1997-08-01 | 1999-11-02 | Rohm And Haas Company | Formaldehyde-free, accelerated cure, aqueous composition for bonding glass fiber heat-resistant nonwovens |
DE19735959A1 (de) | 1997-08-19 | 1999-02-25 | Basf Ag | Verwendung thermisch härtbarer, wässriger Zusammensetzungen als Bindemittel für Formkörper |
US5983586A (en) | 1997-11-24 | 1999-11-16 | Owens Corning Fiberglas Technology, Inc. | Fibrous insulation having integrated mineral fibers and organic fibers, and building structures insulated with such fibrous insulation |
US6171654B1 (en) * | 1997-11-28 | 2001-01-09 | Seydel Research, Inc. | Method for bonding glass fibers with cross-linkable polyester resins |
JP3721530B2 (ja) | 1997-12-12 | 2005-11-30 | 昭和電工株式会社 | 繊維処理剤組成物 |
US6143243A (en) | 1997-12-29 | 2000-11-07 | Prestone Products Corporation | Method of inhibiting cavitation-erosion corrosion of aluminum surfaces using carboxylic acid based compositions comprising polymerizable-acid graft polymers |
NL1008041C2 (nl) | 1998-01-16 | 1999-07-19 | Tidis B V I O | Toepassing van een wateroplosbaar bindmiddelsysteem voor de productie van glas- of steenwol. |
EP0933021A1 (en) | 1998-02-02 | 1999-08-04 | Rockwool International A/S | Process for the manufacture of a mineral wool planth growth substrate and the obtainable mineral wool plant growth substrate |
EP0936060A1 (en) | 1998-02-13 | 1999-08-18 | Rockwool International A/S | Man-made vitreous fibre products and their use in fire protection systems |
EP1064437B2 (en) | 1998-03-19 | 2008-12-24 | Rockwool International A/S | Process and apparatus for preparation of a mineral fibre product. |
US6140445A (en) * | 1998-04-17 | 2000-10-31 | Crompton Corporation | Silane functional oligomer |
US6171444B1 (en) | 1998-04-22 | 2001-01-09 | Sri International | Method and composition for the sizing of paper with a mixture of a polyacid and a polybase |
US6291023B1 (en) | 1998-04-22 | 2001-09-18 | Sri International | Method and composition for textile printing |
US6197383B1 (en) * | 1998-04-22 | 2001-03-06 | Sri International | Method and composition for coating pre-sized paper with a mixture of a polyacid and a polybase |
EP1084167B2 (en) | 1998-05-18 | 2010-08-18 | Rockwool International A/S | Stabilized aqueous phenolic binder for mineral wool and production of mineral wool products |
DK1088012T3 (da) | 1998-05-18 | 2010-07-19 | Knauf Fiber Glass Gmbh | Fiberglas-bindemiddelsammensætninger og fremgangsmåde til disse |
CA2332621C (en) | 1998-05-28 | 2004-07-20 | Owens Corning | Corrosion inhibiting composition for polyacrylic acid based binders |
CA2458333C (en) | 1998-05-28 | 2005-08-09 | Owens Corning | Corrosion inhibiting composition for polyacrylic acid based binders |
JP3907837B2 (ja) * | 1998-06-12 | 2007-04-18 | 富士フイルム株式会社 | 画像記録材料 |
US5993709A (en) | 1998-06-23 | 1999-11-30 | Bonomo; Brian | Method for making composite board using phenol formaldehyde binder |
DE19833920A1 (de) | 1998-07-28 | 2000-02-03 | Basf Ag | Textile Flächengebilde |
US6468668B1 (en) | 1998-09-14 | 2002-10-22 | Canon Kabushiki Kaisha | Cellulosic composite product and a method of producing the same |
US6331350B1 (en) | 1998-10-02 | 2001-12-18 | Johns Manville International, Inc. | Polycarboxy/polyol fiberglass binder of low pH |
EP0990727A1 (en) | 1998-10-02 | 2000-04-05 | Johns Manville International Inc. | Polycarboxy/polyol fiberglass binder |
US6231721B1 (en) | 1998-10-09 | 2001-05-15 | Weyerhaeuser Company | Compressible wood pulp product |
JP4554012B2 (ja) | 1998-10-13 | 2010-09-29 | パナソニック株式会社 | アルミニウム電解コンデンサ |
WO2000023193A1 (en) * | 1998-10-20 | 2000-04-27 | William Whitelaw | Particle separator and method of separating particles |
CN1251738A (zh) | 1998-10-21 | 2000-05-03 | 朱国和 | 一种无土栽培用介质产品及其生产方法 |
JP2000178881A (ja) * | 1998-12-15 | 2000-06-27 | Fuji Spinning Co Ltd | セルロース系布帛の加工法 |
US6214265B1 (en) | 1998-12-17 | 2001-04-10 | Bayer Corporation | Mixed PMDI/resole resin binders for the production of wood composite products |
EP1038433B1 (fr) | 1999-03-19 | 2008-06-04 | Saint-Gobain Cultilene B.V. | Substrat de culture hors-sol |
US6440204B1 (en) | 1999-03-31 | 2002-08-27 | Penford Corporation | Packaging and structural materials comprising potato peel waste |
US6210472B1 (en) | 1999-04-08 | 2001-04-03 | Marconi Data Systems Inc. | Transparent coating for laser marking |
AU3680300A (en) * | 1999-04-16 | 2000-11-02 | San-Ei Gen F.F.I., Inc. | Sucralose-containing composition and eatable product comprising the same |
US6331513B1 (en) | 1999-04-28 | 2001-12-18 | Jacam Chemicals L.L.C. | Compositions for dissolving metal sulfates |
AU4477900A (en) | 1999-05-14 | 2000-12-05 | Dow Chemical Company, The | Process for preparing starch and epoxy-based thermoplastic polymer compositions |
DE19923118A1 (de) | 1999-05-19 | 2000-11-23 | Henkel Kgaa | Chromfreies Korrosionsschutzmittel und Korrosionsschutzverfahren |
JP2000327841A (ja) | 1999-05-24 | 2000-11-28 | Canon Inc | 糖鎖高分子組成物からなる成形体 |
US6194512B1 (en) | 1999-06-28 | 2001-02-27 | Owens Corning Fiberglas Technology, Inc. | Phenol/formaldehyde and polyacrylic acid co-binder and low emissions process for making the same |
DE19930555C1 (de) * | 1999-07-02 | 2001-01-18 | Basf Coatings Ag | Wäßriger Beschichtungsstoff, insbesondere wäßriger Füller oder Steinschlagschutzgrund |
US6133347A (en) | 1999-07-09 | 2000-10-17 | Mbt Holding Ag | Oligomeric dispersant |
EP1086932A1 (en) * | 1999-07-16 | 2001-03-28 | Rockwool International A/S | Resin for a mineral wool binder comprising the reaction product of an amine with a first and second anhydride |
EP1238037B1 (en) | 1999-07-26 | 2011-08-31 | Minnesota Corn Processors LLC | De-icing composition |
US7814512B2 (en) | 2002-09-27 | 2010-10-12 | Microsoft Corporation | Dynamic adjustment of EPG level of detail based on user behavior |
US6306997B1 (en) | 1999-07-29 | 2001-10-23 | Iowa State University Research Foundation, Inc. | Soybean-based adhesive resins and composite products utilizing such adhesives |
US6281298B1 (en) | 1999-08-20 | 2001-08-28 | H. B. Fuller Licensing & Financing Inc. | Water-based pressure sensitive adhesives having enhanced characteristics |
US20030148084A1 (en) | 2000-02-11 | 2003-08-07 | Trocino Frank S. | Vegetable protein adhesive compositions |
CA2400747A1 (en) | 2000-02-11 | 2001-08-16 | Heartland Resource Technologies Llc | Vegetable protein adhesive compositions |
US20020028857A1 (en) | 2000-03-31 | 2002-03-07 | Holy Norman L. | Compostable, degradable plastic compositions and articles thereof |
US6410036B1 (en) | 2000-05-04 | 2002-06-25 | E-L Management Corp. | Eutectic mixtures in cosmetic compositions |
US20020096278A1 (en) | 2000-05-24 | 2002-07-25 | Armstrong World Industries, Inc. | Durable acoustical panel and method of making the same |
EP1164163A1 (en) | 2000-06-16 | 2001-12-19 | Rockwool International A/S | Binder for mineral wool products |
DE10030563B4 (de) | 2000-06-21 | 2005-06-30 | Agrolinz Melamin Gmbh | Faserverbunde hoher Dimensionsstabilität, Bewitterungsresistenz und Flammfestigkeit, Verfahren zu deren Herstellung sowie deren Verwendung |
EP1170265A1 (en) | 2000-07-04 | 2002-01-09 | Rockwool International A/S | Binder for mineral wool products |
JP2002060253A (ja) * | 2000-08-15 | 2002-02-26 | Canon Inc | ガラス被覆用または積層ガラス中間膜用樹脂 |
US6379739B1 (en) | 2000-09-20 | 2002-04-30 | Griffith Laboratories Worldwide, Inc. | Acidulant system for marinades |
CN1235964C (zh) * | 2000-09-20 | 2006-01-11 | 国家淀粉及化学投资控股公司 | 用于交朕体系的组合物及其交联方法 |
US6613378B1 (en) | 2000-10-18 | 2003-09-02 | The United States Of America As Represented By The Secretary Of Agriculture | Sugar-based edible adhesives |
US6525009B2 (en) | 2000-12-07 | 2003-02-25 | International Business Machines Corporation | Polycarboxylates-based aqueous compositions for cleaning of screening apparatus |
DE10101944A1 (de) | 2001-01-17 | 2002-07-18 | Basf Ag | Zusammensetzungen für die Herstellung von Formkörpern aus feinteiligen Materialien |
FR2820736B1 (fr) | 2001-02-14 | 2003-11-14 | Saint Gobain Isover | Procede et dispositif de formation de laine minerale |
US7816514B2 (en) | 2001-02-16 | 2010-10-19 | Cargill, Incorporated | Glucosamine and method of making glucosamine from microbial biomass |
JP3750552B2 (ja) | 2001-03-28 | 2006-03-01 | 日東紡績株式会社 | ガラス繊維巻糸体の製造方法およびガラス繊維織物の製造方法 |
US6989171B2 (en) | 2001-04-02 | 2006-01-24 | Pacifichealth Laboratories, Inc. | Sports drink composition for enhancing glucose uptake into the muscle and extending endurance during physical exercise |
US20020197352A1 (en) | 2001-04-02 | 2002-12-26 | Pacifichealth Laboratories, Inc. | Sports drink composition for enhancing glucose uptake into the muscle and extending endurance during physical exercise |
DE10116810A1 (de) | 2001-04-04 | 2002-12-19 | Wacker Chemie Gmbh | Bindemittel und deren Verwendung in Verfahren zur Herstellung von Formteilen auf der Basis von Mineralfasern |
NZ549563A (en) | 2001-04-10 | 2008-01-31 | Danisco Usa Inc | Carbohydrate polymers prepared by the polymerization of mono and disaccharides with monocarboxylic acids and lactones |
CN1638651A (zh) | 2001-04-10 | 2005-07-13 | 丹尼斯科美国公司 | 单糖和二糖与一元羧酸和内酯的聚合 |
US20030040239A1 (en) | 2001-05-17 | 2003-02-27 | Certainteed Corporation | Thermal insulation containing supplemental infrared radiation absorbing material |
US7157524B2 (en) | 2001-05-31 | 2007-01-02 | Owens Corning Fiberglas Technology, Inc. | Surfactant-containing insulation binder |
NL1018568C2 (nl) | 2001-07-17 | 2003-01-21 | Tno | Winning van polysachariden uit plantaardig en microbieel materiaal. |
JP2004060058A (ja) | 2002-07-24 | 2004-02-26 | Mitsubishi Heavy Ind Ltd | 複合材料用繊維基材 |
US6755938B2 (en) * | 2001-08-20 | 2004-06-29 | Armstrong World Industries, Inc. | Fibrous sheet binders |
JP4135387B2 (ja) * | 2001-08-31 | 2008-08-20 | 東洋製罐株式会社 | ガスバリアー材、その製法、ガスバリアー層形成用コーティング液及びガスバリアー材を備えた包装材 |
US20040161993A1 (en) | 2001-09-06 | 2004-08-19 | Gary Tripp | Inorganic fiber insulation made from glass fibers and polymer bonding fibers |
TWI320039B (en) * | 2001-09-21 | 2010-02-01 | Lactam-containing compounds and derivatives thereof as factor xa inhibitors | |
US20030087095A1 (en) | 2001-09-28 | 2003-05-08 | Lewis Irwin Charles | Sugar additive blend useful as a binder or impregnant for carbon products |
US6592211B2 (en) | 2001-10-17 | 2003-07-15 | Hewlett-Packard Development Company, L.P. | Electrostatic mechanism for inkjet printers resulting in improved image quality |
US6822042B2 (en) | 2001-10-24 | 2004-11-23 | Temple-Inland Forest Products Corporation | Saccharide-based resin for the preparation of composite products |
US6858074B2 (en) | 2001-11-05 | 2005-02-22 | Construction Research & Technology Gmbh | High early-strength cementitious composition |
JP3787085B2 (ja) | 2001-12-04 | 2006-06-21 | 関東化学株式会社 | フォトレジスト残渣除去液組成物 |
JP4464596B2 (ja) | 2002-02-15 | 2010-05-19 | 日本合成化学工業株式会社 | バインダー |
WO2003070843A1 (en) | 2002-02-20 | 2003-08-28 | E.I. Du Pont De Nemours And Company | Lacquers containing highly branched copolyester polyol |
WO2003072637A1 (en) | 2002-02-22 | 2003-09-04 | Insert Therapeutics, Inc. | Carbohydrate-modified polymers, compositions and uses related thereto |
US6992203B2 (en) | 2002-03-26 | 2006-01-31 | Jh Biotech, Inc. | Metal complexes produced by Maillard Reaction products |
DE10218871A1 (de) * | 2002-04-26 | 2003-11-13 | Degussa | Verfahren zur Imprägnierung von porösen mineralischen Substraten |
US6955844B2 (en) | 2002-05-24 | 2005-10-18 | Innovative Construction And Building Materials | Construction materials containing surface modified fibers |
FR2839966B1 (fr) | 2002-05-27 | 2004-07-23 | Saint Gobain Isover | Media filtrant comprenant des fibres minerales obtenues par centrifugation |
AU2003245285A1 (en) | 2002-06-06 | 2003-12-22 | Georgia-Pacific Resins, Inc. | Epoxide-type formaldehyde free insulation binder |
WO2003106561A1 (en) | 2002-06-18 | 2003-12-24 | Georgia-Pacific Resins, Inc. | Polyester-type formaldehyde free insulation binder |
US20040002567A1 (en) | 2002-06-27 | 2004-01-01 | Liang Chen | Odor free molding media having a polycarboxylic acid binder |
FR2842189B1 (fr) | 2002-07-12 | 2005-03-04 | Saint Gobain Isover | Produit d'isolation notamment thermique et son procede de fabrication |
US6887961B2 (en) * | 2002-07-26 | 2005-05-03 | Kimberly-Clark Worldwide, Inc. | Absorbent binder composition and method of making it |
US6962714B2 (en) | 2002-08-06 | 2005-11-08 | Ecolab, Inc. | Critical fluid antimicrobial compositions and their use and generation |
US7384881B2 (en) | 2002-08-16 | 2008-06-10 | H.B. Fuller Licensing & Financing, Inc. | Aqueous formaldehyde-free composition and fiberglass insulation including the same |
US20040048531A1 (en) | 2002-09-09 | 2004-03-11 | Hector Belmares | Low formaldehyde emission panel |
US7090745B2 (en) | 2002-09-13 | 2006-08-15 | University Of Pittsburgh | Method for increasing the strength of a cellulosic product |
DE60315472T2 (de) | 2002-09-24 | 2008-04-30 | Asahi Kasei Chemicals Corp. | Glycolsaüre copolymer und verfahren zu dessen herstellung |
EP1556067B1 (en) * | 2002-10-08 | 2012-12-05 | Danisco US Inc. | Phenolic binding peptides |
US6818694B2 (en) | 2002-10-10 | 2004-11-16 | Johns Manville International, Inc. | Filler extended fiberglass binder |
US7201825B2 (en) | 2002-10-25 | 2007-04-10 | Weyerhaeuser Company | Process for making a flowable and meterable densified fiber particle |
US7141626B2 (en) | 2002-10-29 | 2006-11-28 | National Starch And Chemical Investment Holding Corporation | Fiberglass non-woven catalyst |
US6699945B1 (en) * | 2002-12-03 | 2004-03-02 | Owens Corning Fiberglas Technology, Inc. | Polycarboxylic acid based co-binder |
US7026390B2 (en) | 2002-12-19 | 2006-04-11 | Owens Corning Fiberglas Technology, Inc. | Extended binder compositions |
US20040131874A1 (en) * | 2003-01-08 | 2004-07-08 | Georgia-Pacific Resins, Inc. | Reducing odor in fiberglass insulation bonded with urea-extended phenol-formaldehyde resins |
US7201778B2 (en) | 2003-01-13 | 2007-04-10 | North Carolina State University | Ionic cross-linking of ionic cotton with small molecular weight anionic or cationic molecules |
US6884849B2 (en) * | 2003-02-21 | 2005-04-26 | Owens-Corning Fiberglas Technology, Inc. | Poly alcohol-based binder composition |
US7265169B2 (en) | 2003-03-20 | 2007-09-04 | State of Oregon Acting by and trhough the State Board of Higher Education on Behalf of Oregon State University | Adhesive compositions and methods of using and making the same |
US7056563B2 (en) * | 2003-04-04 | 2006-06-06 | Weyerhaeuser Company | Hot cup made from an insulating paperboard |
DE10317937A1 (de) | 2003-04-17 | 2004-11-04 | Saint-Gobain Isover G+H Ag | Verfahren zur Herstellung von Rohrschalen aus Mineralwolle sowie derartige Rohrschalen |
FR2854626B1 (fr) | 2003-05-07 | 2006-12-15 | Saint Gobain Isover | Produit a base de fibres minerales et dispositif d'obtention des fibres |
US7947766B2 (en) | 2003-06-06 | 2011-05-24 | The Procter & Gamble Company | Crosslinking systems for hydroxyl polymers |
CA2470783A1 (en) | 2003-06-12 | 2004-12-12 | National Starch And Chemical Investment Holding Corporation | Fiberglass nonwoven binder |
US20040254285A1 (en) | 2003-06-12 | 2004-12-16 | Rodrigues Klein A. | Fiberglass nonwoven binder |
US7807077B2 (en) | 2003-06-16 | 2010-10-05 | Voxeljet Technology Gmbh | Methods and systems for the manufacture of layered three-dimensional forms |
US8870814B2 (en) | 2003-07-31 | 2014-10-28 | Boston Scientific Scimed, Inc. | Implantable or insertable medical devices containing silicone copolymer for controlled delivery of therapeutic agent |
CN1251738C (zh) | 2003-08-05 | 2006-04-19 | 王春荣 | 一种治疗灰指甲的中药及其制备方法 |
AU2004201002B2 (en) | 2003-08-26 | 2009-08-06 | Rohm And Haas Company | Curable aqueous composition and use as heat-resistant nonwoven binder |
US20050059770A1 (en) * | 2003-09-15 | 2005-03-17 | Georgia-Pacific Resins Corporation | Formaldehyde free insulation binder |
DE10342858A1 (de) * | 2003-09-15 | 2005-04-21 | Basf Ag | Verwendung formaldehydfreier wässriger Bindemittel für Substrate |
DE10344926B3 (de) | 2003-09-25 | 2005-01-20 | Dynea Erkner Gmbh | Verfahren zur Herstellung von Holzwerkstoffkörpern, Holzwerkstoffkörper sowie nachverformbarer Holzwerkstoffkörper |
EP1678386B2 (de) | 2003-10-06 | 2020-11-18 | Saint-Gobain Isover | Dämmstoffelement aus Mineralfaserfilz für den klemmenden Einbau zwischen Balken |
EP1522642A1 (de) | 2003-10-06 | 2005-04-13 | Saint-Gobain Isover G+H Ag | Dämmstoffbahnen aus einem zu einer Rolle aufgewickelten Mineralfaserfilz für den klemmenden Einbau zwischen Balken |
US20070009582A1 (en) * | 2003-10-07 | 2007-01-11 | Madsen Niels J | Composition useful as an adhesive and use of such a composition |
EP1524282A1 (de) | 2003-10-15 | 2005-04-20 | Sika Technology AG | Zweikomponentige Polyurethanzusammensetzung mit hoher Frühfestigkeit |
US20050208095A1 (en) | 2003-11-20 | 2005-09-22 | Angiotech International Ag | Polymer compositions and methods for their use |
US7297204B2 (en) | 2004-02-18 | 2007-11-20 | Meadwestvaco Corporation | Water-in-oil bituminous dispersions and methods for producing paving compositions from the same |
US7833338B2 (en) | 2004-02-18 | 2010-11-16 | Meadwestvaco Packaging Systems, Llc | Method for producing bitumen compositions |
CN1942525B (zh) | 2004-02-18 | 2010-05-26 | 米德维斯特沃克公司 | 制备沥青组合物的方法 |
US7842382B2 (en) | 2004-03-11 | 2010-11-30 | Knauf Insulation Gmbh | Binder compositions and associated methods |
DE102004033561B4 (de) | 2004-03-11 | 2007-09-13 | German Carbon Teterow Gmbh | Verfahren zur Herstellung von Formaktivkohle |
DE102004013390A1 (de) | 2004-03-17 | 2005-10-06 | Basf Ag | Dachbahnen |
US20050215153A1 (en) | 2004-03-23 | 2005-09-29 | Cossement Marc R | Dextrin binder composition for heat resistant non-wovens |
JP4527435B2 (ja) | 2004-04-19 | 2010-08-18 | 関西ペイント株式会社 | 硬化型組成物及び該組成物を用いた塗装方法 |
US7404875B2 (en) | 2004-04-28 | 2008-07-29 | Georgia-Pacific Consumer Products Lp | Modified creping adhesive composition and method of use thereof |
US6977116B2 (en) | 2004-04-29 | 2005-12-20 | The Procter & Gamble Company | Polymeric structures and method for making same |
US8580953B2 (en) * | 2004-06-21 | 2013-11-12 | Evonik Degussa Gmbh | Water-absorbing polysaccharide and method for producing the same |
US20060044302A1 (en) | 2004-08-25 | 2006-03-02 | Wilson Chen | Notebook DC power sharing arrangement |
EA200700832A1 (ru) | 2004-10-13 | 2007-08-31 | Кнауф Инсулэйшн Гмбх | Полиэфирные связующие композиции |
DE102004051861A1 (de) | 2004-10-26 | 2006-04-27 | Degussa Ag | Verwendung einer wässrigen Dispersion auf Basis eines ungesättigten, amorphen Polyesters auf Basis bestimmter Dicidolisomerer |
US20060099870A1 (en) | 2004-11-08 | 2006-05-11 | Garcia Ruben G | Fiber mat bound with a formaldehyde free binder, asphalt coated mat and method |
US7514027B2 (en) | 2005-02-17 | 2009-04-07 | Saint-Gobain Isover | Process for manufacturing products of mineral wool, in particular monolayer and multilayer products |
FR2882366B1 (fr) | 2005-02-18 | 2008-04-18 | Coletica Sa | Polymere reticule de carbohydrate, notamment a base de polysaccharides et/ou de polyols |
KR100712970B1 (ko) * | 2005-03-03 | 2007-05-02 | 롬 앤드 하아스 컴패니 | 부식을 줄이기 위한 방법 |
US20060231487A1 (en) | 2005-04-13 | 2006-10-19 | Bartley Stuart L | Coated filter media |
DK1885785T3 (da) | 2005-05-06 | 2014-09-22 | Dynea Chemicals Oy | Poly(vinylalkohol)baseret formaldehydfri, hærdbar, vandig sammensætning |
DE102005023431A1 (de) | 2005-05-20 | 2006-11-23 | Juchem Gmbh | Lösung zur Verstärkung der Maillardreaktion und Konzentrat zu deren Herstellung |
DE102005029479A1 (de) | 2005-06-24 | 2007-01-04 | Saint-Gobain Isover G+H Ag | Verfahren zur Herstellung von gebundener Mineralwolle und Bindemittel hierfür |
EP1741726A1 (en) * | 2005-07-08 | 2007-01-10 | Rohm and Haas France SAS | Curable aqueous composition and use as water repellant fiberglass nonwoven binder |
KR20210016069A (ko) | 2005-07-26 | 2021-02-10 | 크나우프 인설레이션, 인크. | 접착제 및 이들로 만들어진 물질 |
KR100669287B1 (ko) | 2005-07-26 | 2007-01-16 | 주식회사 현대오토넷 | 차량용 하드디스크 드라이브 방진 장치 및 그 조립방법 |
US8044129B2 (en) * | 2005-08-26 | 2011-10-25 | Asahi Fiber Glass Company, Limited | Aqueous binder for inorganic fiber and thermal and/or acoustical insulation material using the same |
EP1767566B1 (en) | 2005-09-14 | 2007-04-11 | National Starch and Chemical Investment Holding Corporation | Novel water-based adhesives for industrial applications |
EP1940561A4 (en) | 2005-10-26 | 2009-09-23 | Polymer Ventures Inc | FAT AND WATER RESISTANT ARTICLE |
DE102005063381B4 (de) * | 2005-11-28 | 2009-11-19 | Saint-Gobain Isover G+H Ag | Verfahren zur Herstellung von formaldehydfrei gebundener Mineralwolle sowie Mineralwolleprodukt |
US7872088B2 (en) | 2006-02-16 | 2011-01-18 | Knauf Insulation Gmbh | Low formaldehyde emission fiberglass |
US20070270070A1 (en) | 2006-05-19 | 2007-11-22 | Hamed Othman A | Chemically Stiffened Fibers In Sheet Form |
US20070287018A1 (en) | 2006-06-09 | 2007-12-13 | Georgia-Pacific Resins, Inc. | Fibrous mats having reduced formaldehyde emissions |
US7795354B2 (en) | 2006-06-16 | 2010-09-14 | Georgia-Pacific Chemicals Llc | Formaldehyde free binder |
US9169157B2 (en) | 2006-06-16 | 2015-10-27 | Georgia-Pacific Chemicals Llc | Formaldehyde free binder |
US7803879B2 (en) | 2006-06-16 | 2010-09-28 | Georgia-Pacific Chemicals Llc | Formaldehyde free binder |
US8048257B2 (en) | 2006-06-23 | 2011-11-01 | Akzo Nobel Coating International B.V. | Adhesive system and method of producing a wood based product |
US7579289B2 (en) | 2006-07-05 | 2009-08-25 | Rohm And Haas Company | Water repellant curable aqueous compositions |
US7829611B2 (en) | 2006-08-24 | 2010-11-09 | Rohm And Haas Company | Curable composition |
US7749923B2 (en) | 2006-09-07 | 2010-07-06 | Johns Manville | Facing and faced insulation products |
CN101568498A (zh) * | 2006-11-03 | 2009-10-28 | 太尔公司 | 用于无纺材料的可再生粘合剂 |
US20080160302A1 (en) | 2006-12-27 | 2008-07-03 | Jawed Asrar | Modified fibers for use in the formation of thermoplastic fiber-reinforced composite articles and process |
JP2008163178A (ja) | 2006-12-28 | 2008-07-17 | Advics:Kk | ブレーキ用摩擦材 |
EP2109594A1 (en) | 2007-01-25 | 2009-10-21 | Knauf Insulation Limited | Mineral fibre insulation |
WO2008089849A1 (en) | 2007-01-25 | 2008-07-31 | Knauf Insulation Limited | Hydroponics growing medium |
US20100086726A1 (en) | 2007-01-25 | 2010-04-08 | Roger Jackson | Mineral fibre board |
US8501838B2 (en) * | 2007-01-25 | 2013-08-06 | Knauf Insulation Sprl | Composite wood board |
SI2108006T1 (sl) * | 2007-01-25 | 2021-02-26 | Knauf Insulation Gmbh | Veziva in s tem narejeni materiali |
EP2126179B1 (en) * | 2007-01-25 | 2014-10-22 | Knauf Insulation | Formaldehyde-free mineral fibre insulation product |
WO2008127936A2 (en) * | 2007-04-13 | 2008-10-23 | Knauf Insulation Gmbh | Composite maillard-resole binders |
WO2008141201A1 (en) | 2007-05-10 | 2008-11-20 | Fish Christopher N | Composite materials |
CA2692489A1 (en) * | 2007-07-05 | 2009-01-08 | Knauf Insulation Gmbh | Hydroxymonocarboxylic acid-based maillard binder |
DE102007035334A1 (de) | 2007-07-27 | 2009-01-29 | Boehringer Ingelheim Pharma Gmbh & Co. Kg | Neue substituierte Arylsulfonylglycine, deren Herstellung und deren Verwendung als Arzneimittel |
GB0715100D0 (en) | 2007-08-03 | 2007-09-12 | Knauf Insulation Ltd | Binders |
FR2924719B1 (fr) | 2007-12-05 | 2010-09-10 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un monosaccharide et/ou un polysaccharide et un acide organique polycarboxylique, et produits isolants obtenus. |
JP4927066B2 (ja) | 2007-12-26 | 2012-05-09 | ローム アンド ハース カンパニー | 硬化性組成物 |
JP4789995B2 (ja) | 2007-12-26 | 2011-10-12 | ローム アンド ハース カンパニー | コンポジット材料及びその製造方法 |
DE202008000458U1 (de) | 2008-01-11 | 2008-08-14 | Lechtenböhmer, Hans | Gitterzaun |
PE20100438A1 (es) | 2008-06-05 | 2010-07-14 | Georgia Pacific Chemicals Llc | Composicion de suspension acuosa con particulas de materiales valiosos e impurezas |
CA2742829C (en) | 2008-11-12 | 2017-02-07 | Georgia-Pacific Chemicals Llc | Method for inhibiting ice formation and accumulation |
US8580375B2 (en) | 2008-11-24 | 2013-11-12 | Rohm And Haas Company | Soy composite materials comprising a reducing sugar and methods of making the same |
PL2223941T3 (pl) | 2009-02-27 | 2019-04-30 | Rohm & Haas | Szybkoutwardzalna kompozycja węglowodanowa |
DE102009021555B4 (de) | 2009-05-15 | 2011-06-22 | AGM Mader GmbH, 85221 | Verfahren zur Herstellung eines Bindemittels sowie Verwendung eines solchen Bindemittels zur Herstellung eines Formkörpers |
FR2946352B1 (fr) | 2009-06-04 | 2012-11-09 | Saint Gobain Isover | Composition d'encollage pour laine minerale comprenant un saccharide, un acide organique polycarboxylique et un silicone reactif, et produits isolants obtenus |
WO2011015946A2 (en) | 2009-08-07 | 2011-02-10 | Knauf Insulation | Molasses binder |
US20110040010A1 (en) | 2009-08-11 | 2011-02-17 | Kiarash Alavi Shooshtari | Curable fiberglass binder comprising salt of inorganic acid |
SI2464773T1 (sl) | 2009-08-11 | 2017-12-29 | Johns Manville | Postopek za vezavo steklenih vlaken in izdelkov iz steklenih vlaken |
US9994482B2 (en) | 2009-08-11 | 2018-06-12 | Johns Manville | Curable fiberglass binder |
US8708162B2 (en) | 2009-08-19 | 2014-04-29 | Johns Manville | Polymeric fiber webs with binder comprising salt of inorganic acid |
US8377564B2 (en) | 2009-08-19 | 2013-02-19 | Johns Manville | Cellulosic composite |
US8372900B2 (en) | 2009-08-19 | 2013-02-12 | Johns Manville | Cellulosic composite with binder comprising salt of inorganic acid |
US9365963B2 (en) | 2009-08-11 | 2016-06-14 | Johns Manville | Curable fiberglass binder |
US8680224B2 (en) | 2010-02-01 | 2014-03-25 | Johns Manville | Formaldehyde-free protein-containing binder compositions |
CA2793795A1 (en) | 2010-03-31 | 2011-10-06 | Knauf Insulation Gmbh | Insulation products having a non-aqueous moisturizer |
EP2386394B1 (en) | 2010-04-22 | 2020-06-10 | Rohm and Haas Company | Durable thermoset binder compositions from 5-carbon reducing sugars and use as wood binders |
EP2386605B1 (en) | 2010-04-22 | 2017-08-23 | Rohm and Haas Company | Durable thermosets from reducing sugars and primary polyamines |
US9493603B2 (en) | 2010-05-07 | 2016-11-15 | Knauf Insulation Sprl | Carbohydrate binders and materials made therewith |
AU2011249759B2 (en) | 2010-05-07 | 2014-11-06 | Knauf Insulation | Carbohydrate polyamine binders and materials made therewith |
US20130082205A1 (en) | 2010-06-07 | 2013-04-04 | Knauf Insulation Sprl | Fiber products having temperature control additives |
JP5616291B2 (ja) | 2010-06-11 | 2014-10-29 | ローム アンド ハース カンパニーRohm And Haas Company | ジアルデヒドから製造された5−および6−員環式エナミン化合物からの速硬化性熱硬化性物質 |
US20130174758A1 (en) | 2010-09-17 | 2013-07-11 | Knauf Insulation Gmbh | Organic acid carbohydrate binders and materials made therewith |
FR2978768B1 (fr) | 2011-08-05 | 2014-11-28 | Saint Gobain Isover | Composition d'encollage pour laine minerale a base de saccharide reducteur et de saccharide hydrogene, et produits isolants obtenus |
GB201120137D0 (en) | 2011-11-22 | 2012-01-04 | Dynea Oy | Modified binder compositions |
JP3173680U (ja) | 2011-11-25 | 2012-02-16 | フミエ・ヒノ・ゲレロ | 貧酸素水塊における水質改善装置 |
DE112012005805B4 (de) | 2012-02-03 | 2024-01-04 | Toyota Jidosha Kabushiki Kaisha | Elektrisches Speichersystem und Verfahren zum Bestimmen eines Zustands einer Vielzahl von elektrischen Speicherblöcken |
GB201206193D0 (en) | 2012-04-05 | 2012-05-23 | Knauf Insulation Ltd | Binders and associated products |
US10815593B2 (en) | 2012-11-13 | 2020-10-27 | Johns Manville | Viscosity modified formaldehyde-free binder compositions |
-
2006
- 2006-07-26 KR KR1020217003128A patent/KR20210016069A/ko not_active Application Discontinuation
- 2006-07-26 CN CN201210263009.2A patent/CN102766423B/zh active Active
- 2006-07-26 KR KR1020087003647A patent/KR101328896B1/ko active IP Right Grant
- 2006-07-26 DK DK12198247.4T patent/DK2574639T3/da active
- 2006-07-26 DK DK12198249.0T patent/DK2574640T3/da active
- 2006-07-26 CA CA2615780A patent/CA2615780C/en active Active
- 2006-07-26 AU AU2006272595A patent/AU2006272595C1/en not_active Ceased
- 2006-07-26 TR TR2015/08968T patent/TR201508968T3/tr unknown
- 2006-07-26 KR KR1020227043852A patent/KR20230007522A/ko not_active Application Discontinuation
- 2006-07-26 SI SI200632335T patent/SI2574639T1/sl unknown
- 2006-07-26 KR KR1020157001751A patent/KR101779677B1/ko active IP Right Grant
- 2006-07-26 KR KR1020247012596A patent/KR20240056621A/ko active Search and Examination
- 2006-07-26 WO PCT/US2006/028929 patent/WO2007014236A2/en active Application Filing
- 2006-07-26 PL PL12198247T patent/PL2574639T3/pl unknown
- 2006-07-26 EP EP20110171768 patent/EP2433983A1/en not_active Withdrawn
- 2006-07-26 KR KR1020177034566A patent/KR101963076B1/ko active IP Right Grant
- 2006-07-26 EP EP12198250.8A patent/EP2574641A3/en not_active Ceased
- 2006-07-26 EP EP06788492A patent/EP1919999A2/en not_active Ceased
- 2006-07-26 CA CA3067210A patent/CA3067210C/en active Active
- 2006-07-26 ES ES12198247T patent/ES2732298T3/es active Active
- 2006-07-26 EP EP12198249.0A patent/EP2574640B1/en active Active
- 2006-07-26 JP JP2008524086A patent/JP5455169B2/ja active Active
- 2006-07-26 CN CN201710712430.XA patent/CN107541183B/zh active Active
- 2006-07-26 ES ES12198249T patent/ES2942678T3/es active Active
- 2006-07-26 KR KR1020227014078A patent/KR20220062129A/ko not_active Application Discontinuation
- 2006-07-26 PL PL12198249.0T patent/PL2574640T3/pl unknown
- 2006-07-26 CN CN201910405128.9A patent/CN111138867B/zh active Active
- 2006-07-26 EA EA201490263A patent/EA035452B1/ru not_active IP Right Cessation
- 2006-07-26 EA EA200800424A patent/EA019802B1/ru not_active IP Right Cessation
- 2006-07-26 SI SI200632428T patent/SI2574640T1/sl unknown
- 2006-07-26 EP EP12198247.4A patent/EP2574639B1/en not_active Revoked
- 2006-07-26 CN CN201510598949.0A patent/CN105176461B/zh active Active
- 2006-07-26 KR KR1020167017477A patent/KR101844169B1/ko active IP Right Grant
- 2006-07-26 KR KR1020137034215A patent/KR101501401B1/ko active IP Right Grant
- 2006-07-26 BR BRPI0614664 patent/BRPI0614664B1/pt active IP Right Grant
- 2006-07-26 KR KR1020197032631A patent/KR102212329B1/ko active IP Right Grant
- 2006-07-26 CN CN2006800354300A patent/CN101287788B/zh not_active Expired - Fee Related
- 2006-07-26 KR KR1020197008012A patent/KR20190033650A/ko not_active Application Discontinuation
- 2006-07-26 EP EP20161842.8A patent/EP3696223A1/en active Pending
- 2006-07-26 KR KR1020217026600A patent/KR20210107900A/ko not_active Application Discontinuation
- 2006-07-26 US US11/493,080 patent/US7888445B2/en active Active
- 2006-07-26 KR KR1020137008897A patent/KR101410624B1/ko active IP Right Grant
-
2007
- 2007-01-25 US US11/657,911 patent/US7807771B2/en active Active
- 2007-01-25 US US11/657,963 patent/US7655711B2/en active Active
- 2007-01-25 US US11/657,933 patent/US7772347B2/en active Active
-
2010
- 2010-02-01 US US12/697,573 patent/US7947765B2/en active Active
- 2010-12-22 US US12/976,379 patent/US20110135937A1/en not_active Abandoned
-
2011
- 2011-05-23 US US13/113,394 patent/US8182648B2/en active Active
-
2012
- 2012-12-20 JP JP2012278015A patent/JP5628889B2/ja active Active
-
2013
- 2013-04-19 US US13/866,419 patent/US9434854B2/en active Active
- 2013-04-19 US US13/866,368 patent/US9260627B2/en active Active
- 2013-04-23 US US13/868,233 patent/US9464207B2/en active Active
- 2013-04-23 US US13/868,238 patent/US9040652B2/en active Active
-
2014
- 2014-02-10 JP JP2014023215A patent/JP6152351B2/ja active Active
-
2015
- 2015-06-25 JP JP2015127334A patent/JP2015172207A/ja active Pending
- 2015-08-18 US US14/828,916 patent/US20150353765A1/en not_active Abandoned
-
2016
- 2016-06-09 US US15/177,442 patent/US9926464B2/en active Active
- 2016-12-14 US US15/378,159 patent/US9745489B2/en active Active
-
2017
- 2017-02-27 JP JP2017034902A patent/JP2017095857A/ja not_active Withdrawn
- 2017-08-01 US US15/665,867 patent/US20170335135A1/en not_active Abandoned
-
2018
- 2018-01-19 US US15/875,185 patent/US20180273795A1/en not_active Abandoned
- 2018-09-28 JP JP2018183833A patent/JP2019002029A/ja active Pending
-
2019
- 2019-07-07 US US16/504,310 patent/US20190330492A1/en not_active Abandoned
-
2020
- 2020-12-13 US US17/120,224 patent/US20210095156A1/en not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4259190A (en) * | 1979-09-13 | 1981-03-31 | Ppg Industries, Inc. | Glass fibers with reduced tendency to form gumming deposits and sizing composition |
US5582682A (en) * | 1988-12-28 | 1996-12-10 | Ferretti; Arthur | Process and a composition for making cellulosic composites |
KR19990037115A (ko) * | 1997-10-27 | 1999-05-25 | 쉬한 존 엠. | 열경화성 폴리사카라이드 |
WO2003071879A1 (en) * | 2002-02-22 | 2003-09-04 | Genencor International, Inc. | Browning agent |
CN1668700A (zh) * | 2002-07-15 | 2005-09-14 | 罗克伍尔国际公司 | 用于矿物纤维的无甲醛含水粘合剂组合物 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111138867B (zh) | 粘结剂和由其制备的材料 | |
AU2017201187B2 (en) | Binders and materials made therewith | |
US20240034904A1 (en) | Binders and materials made therewith |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |