CN111001027B - Ecological generation liquid capable of releasing negative ions and preparation method thereof - Google Patents

Ecological generation liquid capable of releasing negative ions and preparation method thereof Download PDF

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Publication number
CN111001027B
CN111001027B CN201911276529.5A CN201911276529A CN111001027B CN 111001027 B CN111001027 B CN 111001027B CN 201911276529 A CN201911276529 A CN 201911276529A CN 111001027 B CN111001027 B CN 111001027B
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parts
solution
negative ions
chloroplast
ecological
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CN111001027A (en
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俞兆振
黄强
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Hanxin Guangdong Communication Equipment Co ltd
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Hanxin Guangdong Communication Equipment Co ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION, OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS, OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS, OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/22—Ionisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D49/00—Separating dispersed particles from gases, air or vapours by other methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor

Abstract

The invention relates to an ecological generating solution for releasing negative ions, which is prepared from the following components in parts by weight: 0.2-0.3 part of defoaming agent, 0.5-0.55 part of wetting agent, 0.1-0.5 part of preservative, 0.1-0.5 part of mildew preventive, 15-50 parts of negative ion stock solution, 5-20 parts of water-soluble resin, 5-10 parts of chloroplast, 1.5-2 parts of polyvinyl acetate solution, 1-2 parts of penetrating fluid and the balance of deionized water, wherein the negative ion stock solution comprises 10-15 parts of diatom, 6-10 parts of wormwood, 10-15 parts of nopalxochia, 6-8 parts of plant fiber, 8-12 parts of nano gull powder and 10-15 parts of seaweed. By adding chloroplast and related additives, photosynthesis is enhanced, negative ions are released, active oxygen is produced, harmful gases such as indoor formaldehyde and toluene are effectively removed, smoke and dust are eliminated, peculiar smell is removed, sterilization and bacteriostasis are realized, the indoor environment is purified, and the indoor air quality is obviously improved.

Description

Ecological generation liquid capable of releasing negative ions and preparation method thereof
Technical Field
The invention relates to the field of ecological anion generating solution, in particular to ecological generating solution for releasing anions and a preparation method thereof.
Background
The discovery and application of negative ions are the works of human beings in the nineteenth century, the first international academic society proves that the negative ions have the efficacy on human bodies, the German physicist Philips Lavenna doctor considers that the place where the natural environment of the earth is beneficial to the health of human bodies is the periphery of a waterfall, a scholarer in the year of nine and three O publishes a paper for treating diseases by using air negative ions, the American also publishes the statistical data of the negative ions, and the ratio of the positive ions to the negative ions in the atmosphere of the 21 st century is 1.2: 1 modern social development has disrupted the balance of ions in nature, and in 1930 the us desspaver proposed the insight that negative ions can produce a sense of well-being and improve the healthy environment.
There are three major mechanisms for the generation of negative ions in air in nature:
1. the atmosphere is ionized by ultraviolet rays, cosmic rays, radioactive substances, thunderstorm, storm and other factors to generate negative ions.
2. Water flows at high speed under the action of gravity in natural processes such as waterfall impact, fine wave pushing, rolling, rainstorm falling and the like, and water molecules are cracked to generate negative ions.
3. The photoelectric effect formed by the discharge of the tips of the leaves and branches of the trees and the photosynthesis of the green plants in the forest ionizes the air to generate negative ions.
When the human confirms that the negative ions have the effect on the human body, in order to improve the environment and promote the health, a large number of negative ion generators are invented, two approaches are mainly adopted, one approach is to utilize high-voltage electricity to generate ionization so as to enable air to generate negative ions, the other approach is to utilize natural mineral substances to be processed by scientific sources, a lot of negative ion releasing materials on the earth, generally energy stones, various ores, seaweed seabed stones and light shale containing protein are utilized, the materials are processed into fine powder by adopting a high-tech technology and are matched with high polymer materials, a lot of products can be researched and applied to textile industry, plastic products, paper products and the like to form various negative ion functional products, the negative ion releasing quantity of the products can reach 1200-5000 per cubic centimeter, and the negative ion releasing quantity is not inferior to the natural environment of the human body in suburbs and fields.
In conclusion, in addition to natural phenomena (such as ultraviolet photosynthesis lightning, etc.), human beings develop many anion products with their own wisdom, the principle is basically consistent, and electrons e in the atmosphere (O2, N2, C02, S02, H20) are released when air and other specific environment exist in the condition capable of emitting anions, and the electrons react with C02 and H20 as follows:
H20+e←→02(H20)m
C02+e←→C04(H20)m
C04+(H20)2+H2←→02(H20)m+C02
thereby generating negative ions.
Therefore, the negative ion ecological generating liquid for improving the negative ion release effect by enhancing the photosynthesis reaction is provided
Disclosure of Invention
In order to solve the problems, the invention adopts the following technical scheme: an ecological generation liquid for releasing negative ions is prepared from the following components in parts by weight: 0.2-0.3 part of defoaming agent, 0.5-0.55 part of wetting agent, 0.1-0.5 part of preservative, 0.1-0.5 part of mildew preventive, 15-50 parts of negative ion stock solution, 5-20 parts of water-soluble resin, 5-10 parts of chloroplast, 1.5-2 parts of polyvinyl acetate solution, 1-2 parts of penetrating fluid and the balance of deionized water, wherein the negative ion stock solution comprises 10-15 parts of diatom, 6-10 parts of wormwood, 10-15 parts of nopalxochia, 6-8 parts of plant fiber, 8-12 parts of nano gull powder and 10-15 parts of seaweed.
Further, the anion stock solution also comprises 5-15 parts of paleontolite powder.
Further comprises 0.4-0.8 part of photosynthetic bacteria culture solution.
Further, the water-soluble resin is acrylic resin.
A preparation method of ecological generating liquid releasing negative ions comprises the following steps:
s1, respectively crushing 15 parts of diatom, 10 parts of wormwood, 10 parts of nopalxochia, 6 parts of plant fiber, 8 parts of nano gull rock powder and 10 parts of seaweed, and simultaneously mixing 5 parts of chloroplast into 10 parts of acrylic resin for storage and later use;
s2, mixing and stirring 15 parts of diatom, 10 parts of wormwood, 10 parts of nopalxochia, 6 parts of plant fiber, 8 parts of nano gull rock powder, 10 parts of seaweed, 2 parts of polyvinyl acetate solution and deionized water prepared in the step S1 at a stirring speed of 10r/min for 30 min;
s3, injecting a mixed solution of 5 parts of chloroplast and 10 parts of acrylic resin into the mixed solution prepared in the step S2, and continuously stirring at a low speed of 1r/min for 60 min;
s4, adding 0.3 part of defoaming agent, 0.5 part of wetting agent, 0.5 part of preservative and 0.1 part of mildew preventive into the solution mixed in the step S3, and stirring at the stirring speed of 3r/min for 20 min;
s5, filtering the solution obtained in the step S4 to obtain a final generation solution.
Further, in the step S1, when the acrylic resin and the chloroplast are mixed, the mixture is homogenized for 30min, and an acid-base balance regulator is added to adjust the PH value to 6.5-7.5.
Further, a 2000-mesh filter screen is adopted in the filtering step in the step S5.
The working principle of the invention is as follows: the photosynthesis effect of the ecological generation liquid is enhanced by adding chloroplasts, and plants or plant extracts such as wormwood, nopalxochia, plant fibers and the like are used as nutrients and supplied to the chloroplasts for photosynthesis loss. Various additives are used for prolonging the preservation time of the ecological generating solution, and after the ecological generating solution consumes light nutrients, the release of negative ions can be continuously provided by replacing the ecological generating solution.
The acrylic resin is a generic term for polymers of acrylic acid, methacrylic acid and derivatives thereof. The acrylic resin coating is a thermoplastic or thermosetting resin coating prepared by using (methyl) acrylate and styrene as main components and acrylic resin obtained by copolymerizing the (methyl) acrylate and styrene with other acrylate, or an acrylic radiation coating.
The new type composite white latex of polyvinyl acetate solution is named as polyvinyl acetate solution, and is used for adhering woodware, cloth, leather, etc. The preparation method comprises the following steps: in the first step, the weight ratio of corn starch: water (10-12): 100, preparing the mixture into starch solution, adding hydrogen peroxide and a catalyst C1 while stirring, and heating to 45-60 ℃. After reacting for 1-2 h, adding a sodium hydroxide solution, adjusting the pH value to 9-10, keeping the temperature for 1h to fully gelatinize the mixture, and then adding a borax solution and stirring uniformly for later use. And a second step of adding polyvinyl alcohol and water [ polyvinyl alcohol: water (10-30): 100 ℃, heating to 85-95 ℃ under stirring, and completely dissolving the polyvinyl alcohol. And preserving the heat for 30-40 min. And thirdly, cooling the polyvinyl alcohol solution obtained in the last step to 80 ℃, adding hydrochloric acid, stirring for lO-20min, adding formaldehyde to enable the acidic solution to carry out hydroformylation reaction, then keeping the temperature, stirring for 1-2 h, and adding a proper amount of sodium hydroxide solution. Adjusting the pH value to 7-8, and continuously stirring for 10-30 min for later use. Fourthly, adding a proper amount of water into the latex stabilizer K-02 to prepare a 10% solution for later use. Fifthly, putting stearic acid into a small container, and heating the stearic acid until the stearic acid is completely dissolved under stirring. Then slowly dripping the latex stabilizer prepared in one step to obtain milky viscous liquid. And sixthly, slowly adding the material prepared in the last step into the solution obtained in the third step under stirring (the temperature is kept at about 80 ℃). Fully stirring for 30min after the addition, and then cooling to 30-40 ℃, adding the material prepared in the first step, urea and the composite promoter Ca-01. And fully stirring for 30-40 min to obtain the composite white latex with milky appearance, solid content of 30-40% and pH value of 5-6.
The invention has the beneficial effects that: by adding chloroplast and related additives, photosynthesis is enhanced, negative ions are released, active oxygen is produced, harmful gases such as indoor formaldehyde and toluene are effectively removed, smoke and dust are eliminated, peculiar smell is removed, sterilization and bacteriostasis are realized, the indoor environment is purified, and the indoor air quality is obviously improved.
Detailed Description
The ecological generating solution for releasing the negative ions provided by the embodiment of the invention is prepared from the following components in parts by weight: 0.2-0.3 part of defoaming agent, 0.5-0.55 part of wetting agent, 0.1-0.5 part of preservative, 0.1-0.5 part of mildew preventive, 15-50 parts of negative ion stock solution, 5-20 parts of water-soluble resin, 5-10 parts of chloroplast, 1.5-2 parts of polyvinyl acetate solution, 1-2 parts of penetrating fluid and the balance of deionized water, wherein the negative ion stock solution comprises 10-15 parts of diatom, 6-10 parts of wormwood, 10-15 parts of nopalxochia, 6-8 parts of plant fiber, 8-12 parts of nano gull powder and 10-15 parts of seaweed.
Further, the anion stock solution also comprises 5-15 parts of paleontolite powder.
Further comprises 0.4-0.8 part of photosynthetic bacteria culture solution.
Further, the water-soluble resin is acrylic resin.
A preparation method of ecological generating liquid releasing negative ions comprises the following steps:
s1, respectively crushing 15 parts of diatom, 10 parts of wormwood, 10 parts of nopalxochia, 6 parts of plant fiber, 8 parts of nano gull rock powder and 10 parts of seaweed, and simultaneously mixing 5 parts of chloroplast into 10 parts of acrylic resin for storage and later use;
s2, mixing and stirring 15 parts of diatom, 10 parts of wormwood, 10 parts of nopalxochia, 6 parts of plant fiber, 8 parts of nano gull rock powder, 10 parts of seaweed, 2 parts of polyvinyl acetate solution and deionized water prepared in the step S1 at a stirring speed of 10r/min for 30 min;
s3, injecting a mixed solution of 5 parts of chloroplast and 10 parts of acrylic resin into the mixed solution prepared in the step S2, and continuously stirring at a low speed of 1r/min for 60 min;
s4, adding 0.3 part of defoaming agent, 0.5 part of wetting agent, 0.5 part of preservative and 0.1 part of mildew preventive into the solution mixed in the step S3, and stirring at the stirring speed of 3r/min for 20 min;
s5, filtering the solution obtained in the step S4 to obtain a final generation solution.
Further, in the step S1, when the acrylic resin and the chloroplast are mixed, the mixture is homogenized for 30min, and an acid-base balance regulator is added to adjust the PH value to 6.5-7.5.
Further, a 2000-mesh filter screen is adopted in the filtering step in the step S5.
Example 1:
0.2 part of defoaming agent, 0.5 part of wetting agent, 0.1 part of preservative, 0.1 part of mildew preventive, 5 parts of acrylic resin, 5 parts of chloroplast, 2 parts of polyvinyl acetate solution, 2 parts of penetrating fluid, 10 parts of tourmaline powder, 15 parts of diatom, 6 parts of wormwood, 10 parts of nopalxochia, 6 parts of plant fiber, 12 parts of nano gull powder, 15 parts of seaweed, 5 parts of biochemical stone powder, 0.4 part of photosynthetic bacteria culture solution and the balance of deionized water.
Example 2:
0.2 part of defoaming agent, 0.5 part of wetting agent, 0.5 part of preservative, 0.5 part of mildew preventive, 20 parts of acrylic resin, 10 parts of chloroplast, 2 parts of polyvinyl acetate solution, 2 parts of penetrating fluid, 5 parts of tourmaline powder, 10 parts of diatom, 10 parts of wormwood, 15 parts of nopalxochia, 8 parts of plant fiber, 8 parts of nano gull powder, 10 parts of seaweed, 10 parts of biochemical stone powder, 0.6 part of photosynthetic bacteria culture solution and the balance of deionized water.
Example 3:
0.3 part of defoaming agent, 0.55 part of wetting agent, 0.5 part of preservative, 0.5 part of mildew preventive, 20 parts of acrylic resin, 10 parts of chloroplast, 2 parts of polyvinyl acetate solution, 2 parts of penetrating fluid, 10 parts of tourmaline powder, 15 parts of diatom, 10 parts of wormwood, 15 parts of nopalxochia, 8 parts of plant fiber, 12 parts of nano gull powder, 15 parts of seaweed, 15 parts of biochemical stone powder, 0.8 part of photosynthetic bacteria culture solution and the balance of deionized water.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (7)

1. An ecological generating solution for releasing negative ions is characterized by being prepared from the following components in parts by weight: 0.2-0.3 part of defoaming agent, 0.5-0.55 part of wetting agent, 0.1-0.5 part of preservative, 0.1-0.5 part of mildew preventive, 15-50 parts of negative ion stock solution, 5-20 parts of water-soluble resin, 5-10 parts of chloroplast, 1.5-2 parts of polyvinyl acetate solution, 1-2 parts of penetrating fluid and the balance of deionized water, wherein the negative ion stock solution comprises 10-15 parts of diatom, 6-10 parts of wormwood, 10-15 parts of nopalxochia, 6-8 parts of plant fiber, 8-12 parts of nano gull powder and 10-15 parts of seaweed.
2. The ecological generating solution for releasing negative ions according to claim 1, characterized in that: the anion stock solution also comprises 5-15 parts of ancient biochemical stone powder.
3. The ecological generating solution for releasing negative ions according to claim 2, characterized in that: also comprises 0.4 to 0.8 portion of photosynthetic bacteria culture solution.
4. The ecological generating solution for releasing negative ions according to claim 3, characterized in that: the water-soluble resin is acrylic resin.
5. A method for preparing anion releasing ecological generating solution according to claim 4, comprising the following steps:
s1, respectively crushing 15 parts of diatom, 10 parts of wormwood, 10 parts of nopalxochia, 6 parts of plant fiber, 8 parts of nano gull rock powder and 10 parts of seaweed, and simultaneously mixing 5 parts of chloroplast into 10 parts of acrylic resin for storage and later use;
s2, mixing and stirring 15 parts of diatom, 10 parts of wormwood, 10 parts of nopalxochia, 6 parts of plant fiber, 8 parts of nano gull rock powder, 10 parts of seaweed, 2 parts of polyvinyl acetate solution and deionized water prepared in the step S1 at a stirring speed of 10r/min for 30 min;
s3, injecting mixed liquid of 5 parts of chloroplast and 10 parts of acrylic resin into the mixed liquid prepared in the step S2, adding 0.6 part of photosynthetic bacteria culture solution, and continuing to stir at a slow speed, wherein the stirring speed is 1r/min, and the stirring time is 60 min;
s4, adding 10 parts of paleontolite powder, 0.3 part of defoaming agent, 0.5 part of wetting agent, 0.5 part of preservative and 0.1 part of mildew preventive into the solution mixed in the step S3, and stirring at the stirring speed of 3r/min for 20 min;
s5, filtering the solution obtained in the step S4 to obtain a final generation solution.
6. The method for preparing the anion releasing ecological generating solution according to claim 5, wherein the method comprises the following steps: and in the step S1, when the acrylic resin and the chloroplast are mixed, homogenizing for 30min, and adding an acid-base balance regulator to regulate the pH value to 6.5-7.5.
7. The method for preparing the anion releasing ecological generating solution according to claim 5, wherein the method comprises the following steps: the filtering step in the step S5 adopts a 2000-mesh filter screen.
CN201911276529.5A 2019-12-12 2019-12-12 Ecological generation liquid capable of releasing negative ions and preparation method thereof Active CN111001027B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003339848A (en) * 2002-05-24 2003-12-02 Kazumi Toushin Method of manufacturing water repellent-minus ion generating substance
CN107267072A (en) * 2017-07-10 2017-10-20 佛山富离子环保科技有限公司 A kind of anion that discharges has the coating of air-cleaning function
CN107456952A (en) * 2017-08-28 2017-12-12 陕西师范大学 A kind of preparation method for catching light oxygen release papery coating material
CN109082160A (en) * 2018-06-11 2018-12-25 刁萌萌 A kind of release anion quick-dry type environmental protection coating material and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003339848A (en) * 2002-05-24 2003-12-02 Kazumi Toushin Method of manufacturing water repellent-minus ion generating substance
CN107267072A (en) * 2017-07-10 2017-10-20 佛山富离子环保科技有限公司 A kind of anion that discharges has the coating of air-cleaning function
CN107456952A (en) * 2017-08-28 2017-12-12 陕西师范大学 A kind of preparation method for catching light oxygen release papery coating material
CN109082160A (en) * 2018-06-11 2018-12-25 刁萌萌 A kind of release anion quick-dry type environmental protection coating material and preparation method

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