CN110885716A - Antibacterial detergent - Google Patents
Antibacterial detergent Download PDFInfo
- Publication number
- CN110885716A CN110885716A CN201911044587.5A CN201911044587A CN110885716A CN 110885716 A CN110885716 A CN 110885716A CN 201911044587 A CN201911044587 A CN 201911044587A CN 110885716 A CN110885716 A CN 110885716A
- Authority
- CN
- China
- Prior art keywords
- antibacterial
- surfactant
- silver
- detergent
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 60
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 59
- 229910052709 silver Inorganic materials 0.000 claims abstract description 56
- 239000004332 silver Substances 0.000 claims abstract description 56
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 53
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000004094 surface-active agent Substances 0.000 claims abstract description 38
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000000284 extract Substances 0.000 claims abstract description 16
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims abstract description 15
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims abstract description 15
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 15
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 15
- 235000009120 camo Nutrition 0.000 claims abstract description 15
- 235000005607 chanvre indien Nutrition 0.000 claims abstract description 15
- 239000011487 hemp Substances 0.000 claims abstract description 15
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 15
- 239000004599 antimicrobial Substances 0.000 claims abstract description 10
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- -1 silver ions Chemical class 0.000 claims description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 16
- 244000025254 Cannabis sativa Species 0.000 claims description 14
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 229930003935 flavonoid Natural products 0.000 claims description 10
- 150000002215 flavonoids Chemical class 0.000 claims description 10
- 235000017173 flavonoids Nutrition 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 9
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 9
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000013824 polyphenols Nutrition 0.000 claims description 6
- 239000002738 chelating agent Substances 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 230000002335 preservative effect Effects 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 241000218236 Cannabis Species 0.000 claims description 4
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 229960003237 betaine Drugs 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 150000002169 ethanolamines Chemical class 0.000 claims description 3
- 229930182470 glycoside Natural products 0.000 claims description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 3
- 159000000000 sodium salts Chemical group 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- 229940071089 sarcosinate Drugs 0.000 claims 1
- 238000005202 decontamination Methods 0.000 abstract description 3
- 230000003588 decontaminative effect Effects 0.000 abstract description 3
- 230000000857 drug effect Effects 0.000 abstract description 2
- 240000004308 marijuana Species 0.000 abstract 2
- 230000000694 effects Effects 0.000 description 17
- 238000012360 testing method Methods 0.000 description 13
- 230000007794 irritation Effects 0.000 description 12
- 229920002494 Zein Polymers 0.000 description 11
- 238000007792 addition Methods 0.000 description 11
- 239000005019 zein Substances 0.000 description 11
- 229940093612 zein Drugs 0.000 description 11
- 230000003385 bacteriostatic effect Effects 0.000 description 10
- 238000010998 test method Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 206010052428 Wound Diseases 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000001914 calming effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000020254 sheep milk Nutrition 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- 208000035143 Bacterial infection Diseases 0.000 description 1
- 201000004569 Blindness Diseases 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 206010010741 Conjunctivitis Diseases 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 206010033557 Palpitations Diseases 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 230000006037 cell lysis Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000002398 materia medica Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007721 medicinal effect Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1206—Water-insoluble compounds free metals, e.g. aluminium grit or flakes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an antibacterial detergent. The antibacterial detergent comprises a surfactant system and an antibacterial agent, wherein the surfactant system is a combination of any two or more of an anionic surfactant, a nonionic surfactant and an amphoteric surfactant; the antimicrobial agent is a composition comprising a cannabis leaf extract and a silver antimicrobial agent. Compared with the prior art, the antibacterial detergent disclosed by the invention can achieve the purpose of decontamination by adopting any two combinations of the anionic surfactant, the nonionic surfactant and the amphoteric surfactant, and the active ingredients of the hemp leaves in the antibacterial agent can effectively stabilize the silver antibacterial agent and enhance the drug effect of the silver antibacterial agent, so that the antibacterial capability of the detergent is stronger.
Description
Technical Field
The invention belongs to the technical field of daily chemical production, and particularly relates to an antibacterial detergent.
Background
The detergent is a common cleaning product in daily life and is widely used for washing tableware, vegetables, melons and fruits and the like. At present, the most important requirements for the detergent are that the detergent has strong antibacterial ability in addition to the detergency. Currently, the most commonly used antibacterial agents are triclosan, triclocarban, and parachlorometaxylenol, and inorganic antibacterial agents, and most of the inorganic antibacterial agents currently commercialized are inorganic substances containing silver or silver ions.
The silver-based antibacterial agent has a long application history and plays a great role in human health. And in terms of safety and antibacterial effect, the inorganic silver antibacterial agent and the silver composite antibacterial agent have the advantages of long acting, high efficiency, broad spectrum, safety and the like. Silver has been found to have natural antibacterial properties and safety in ancient times. At that time, the ancient Egypt people know that the thin silver sheet covers the wound to prevent bacterial infection, the Mongolian people who accelerate wound healing know that the sheep milk contained in the silver container can keep fresh, and the Ministry physicians Li Shizhen in the compendium of materia medica of China has the effects of calming the five internal organs, calming the heart, stopping fright palpitation, eliminating pathogenic qi and the like, can take the sheep milk for a long time to lighten the body and prolong the life, has the raw silver taste and is pungent and cold, is nontoxic, and has the traditional Chinese medicine silver diagnosis and treatment related diseases, and the western medicine silver treatment has the record of over 100 years. In 1884, German obstetrician Crede dropped 1% silver nitrate solution into eyes of newborn infants to prevent conjunctivitis of newborn infants, and the blindness rate of infants was reduced from 10% to 0.2%. In 1893, tests show that silver has a killing effect on microorganisms such as bacteria, and the silver has a wider medical effect until today. 0.5% silver nitrate is a standard solution for treating burns and wounds; the silver nitrate with the concentration of 10-20% can be applied to treat the uterine erosion. The research finds that the silver is in various pairsPathogenic bacteria such as Escherichia coli and Staphylococcus aureus have strong killing effect, and the required concentration is very low, and the general dosage is 10-6And (mass fraction) sterilizing. In terms of safety, silver is one of tissue components in a human body, cells treated by silver ions with very low concentration have no obvious changes of cell aggregation, cell deformation, cell lysis, pH value and the like, and a small amount of silver ions have no obvious harm to the human body. Therefore, the silver-based antibacterial agent is used for improving the antibacterial function of the textile and has sufficient safety.
The silver antibacterial agent has many advantages as an inorganic antibacterial agent, but the silver antibacterial agent has unstable property, nano silver is easy to agglomerate and discolor, silver ions are easy to be converted into brown silver oxide or black simple substance silver through ultraviolet light catalytic reduction, and the appearance of the product and the antibacterial performance are influenced. The composite antibacterial agent is a development direction of antibacterial materials, and many researches prove that the composite antibacterial agent has a better antibacterial effect than that of a single metal ion.
Disclosure of Invention
Based on the above, the invention aims to provide an antibacterial detergent so as to effectively overcome the defects in the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
an antibacterial detergent comprises a surfactant system and an antibacterial agent, wherein the surfactant system is a combination of any two of an anionic surfactant, a nonionic surfactant and an amphoteric surfactant; the antimicrobial agent is a composition comprising a cannabis leaf extract and a silver antimicrobial agent.
Compared with the prior art, the antibacterial detergent disclosed by the invention can achieve the purpose of decontamination by adopting the combination of any two or more of the anionic surfactant, the nonionic surfactant and the amphoteric surfactant, and the hemp leaf extract in the antibacterial agent can effectively stabilize the silver antibacterial agent and enhance the drug effect of the silver antibacterial agent, so that the antibacterial capability of the detergent is stronger.
Further, the active ingredients of the hemp leaf extract are phenolic substances and flavonoid substances; the solvent for extracting the hemp leaf extract is one or more of water, ethanol, glycerol and 1, 3-propylene glycol; the silver antibacterial agent is one or more of colloidal silver simple substance, silver ions or silver complex ions.
Further, in the antibacterial agent, the content of phenolic substances is 0.01-2%, the content of flavonoid substances is 0.0005-2%, and the total content of silver is 50-1000 ppm; the content of the antibacterial agent in the liquid detergent is 0.1-2.5%.
Further, the content of the surfactant system is 10-60%; wherein the weight percentage of the anionic surfactant in the surfactant system is 0-95%, the weight percentage of the nonionic surfactant in the surfactant system is 0-95%, and the weight percentage of the amphoteric surfactant in the surfactant system is 0-20%.
Further, when the content of the surfactant system is more than 35%, the detergent also contains an alcohol solvent, wherein the alcohol solvent is one or a mixture of more than one of glycerol, 1, 3-propylene glycol and ethanol; the content of the solvent is 5-10%.
Further, the anionic surfactant is one or a mixture of more than one of linear alkylbenzene sulfonate, fatty alcohol-polyoxyethylene ether sulfate, fatty alcohol sulfate, α -olefin sulfonate, fatty acid methyl ester sulfonate, secondary alkyl sulfonate, fatty alcohol-polyether carboxylate and fatty acyl sarcosine salt, the anionic surfactant is sodium salt, ammonium salt, potassium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt and isopropylamine salt, and the carbon chain of alkyl or fatty alcohol is a single carbon chain or a mixed carbon chain of C8-C18.
Further, the nonionic surfactant is one or a mixture of more than one of alkanol polyoxyethylene ether, alkyl glycoside, fatty acid methyl ester ethoxylate and alkanolamide, the alkyl of the nonionic surfactant is C10-C18 straight-chain or branched-chain saturated alkyl, and the EO addition number of the polyoxyethylene ether is 6-18.
Further, the amphoteric surfactant is one or more of betaine surfactant, imidazoline surfactant and amine oxide amphoteric surfactant.
Further, the antibacterial liquid detergent also contains an inorganic salt thickener, a preservative, essence, a chelating agent and a pH regulator. The detergent is more stable and durable by adding the thickening agent and the preservative into the detergent. The essence can increase the fragrance of the liquid detergent, and the chelating agent and the pH regulator both increase the stability and the persistence of the liquid detergent.
The surfactant and the antibacterial agent are used together, the antibacterial agent is a compound antibacterial agent formed by compounding effective components of phenols and flavonoids in hemp leaves and a silver antibacterial agent, wherein the phenols and the flavonoids can stabilize the silver antibacterial agent and ensure that silver does not generate physical or chemical reaction, ionic silver does not react with chloride ions in a detergent formula and the effectiveness of the silver ions and the product does not yellow. The hemp leaf extract can also enhance the bactericidal and bacteriostatic effects of the silver ion antibacterial agent. The antibacterial detergent can obviously improve the antibacterial effect, and the detergent does not change color or deteriorate and has longer antibacterial lasting effect.
For a better understanding and practice, the present invention is described in detail below.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
The invention provides an antibacterial detergent which comprises a surfactant system and an antibacterial agent. The detergent is characterized in that the surfactant system is a combination of any two or more of an anionic surfactant, a nonionic surfactant and an amphoteric surfactant, and the detergent also comprises an inorganic salt thickener, a preservative, essence, a chelating agent, a pH regulator and the balance of water.
The antibacterial agent of the present invention comprises a combination of a cannabis leaf extract and a silver antibacterial agent. The active ingredients in the hemp leaf extract are phenolic substances and flavonoid substances, and the silver antibacterial agent is one or more of colloidal silver simple substance, silver ions or silver complex ions. The content of phenolic substances in the antibacterial agent is 0.01-2%, the content of flavonoid substances is 0.0005-2%, and the total content of silver is 50-1000 ppm. The content of the antibacterial agent in the liquid detergent is 0.1-2.5%.
The content of the surfactant system is 10-60%. Wherein, the weight percentage of the anionic surfactant in the surfactant system is 0-95%, the weight percentage of the nonionic surfactant in the surfactant system is 0-95%, and the weight percentage of the amphoteric surfactant in the surfactant system is 0-20%. Preferably, when the total active matter of the detergent is more than 35%, the detergent can also contain an alcohol solvent, wherein the alcohol solvent is one or a mixture of more than one of glycerol, 1, 3-propylene glycol and ethanol. The content of the solvent is 5-10%. The surfactant system is the main substance exerting detergency. The content of the detergent has certain influence on the dirt-removing capacity of the detergent.
Preferably, when extracting hemp leaf, the extraction solvent is one or more of water, ethanol, glycerol, and 1, 3-propylene glycol.
Preferably, the anionic surfactant is one or a mixture of more than one of linear alkylbenzene sulfonate, fatty alcohol-polyoxyethylene ether sulfate, fatty alcohol sulfate, α -olefin sulfonate, fatty acid methyl ester sulfonate, secondary alkyl sulfonate and fatty alcohol-polyether carboxylate, the anionic surfactant is sodium salt, ammonium salt, potassium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt and isopropylamine, and the carbon chain of the alkyl or fatty alcohol is a single carbon chain or a mixed carbon chain of C8-C18.
Preferably, the nonionic surfactant is one or a mixture of more than one of alkanol polyoxyethylene ether, alkyl glycoside, fatty acid methyl ester ethoxylate and alkanolamide, the alkyl group of the nonionic surfactant is a linear or branched saturated alkyl group with C10-C18, and the EO addition number of the polyoxyethylene ether is 6-18.
Preferably, the amphoteric surfactant is one or more of betaine surfactant, imidazoline surfactant and amine oxide amphoteric surfactant.
The following examples are provided to illustrate the composition of the antibacterial detergent of the present invention and its bacteriostatic and bactericidal effects.
Firstly, a basic formula (without an antibacterial agent) of the liquid detergent is prepared, and the liquid detergent comprises a surfactant system, an inorganic salt thickening agent, a preservative, essence, a chelating agent and a pH regulator.
Table 1, this table shows the basic formulations (without added antibacterial agent) of antibacterial detergent examples 1-6 of the present invention, each example tested for bactericidal and bacteriostatic ability and irritation against e.
Table 2, this table shows the bactericidal and bacteriostatic ability and irritation test of each example described in table 1 against e.
Antibacterial and bacteriostatic properties: the method is carried out according to a 5.1.1 suspension quantitative antibacterial test and a 5.2.1 suspension quantitative antibacterial test in a standard WS/T650-2019 antibacterial and antibacterial effect evaluation method, wherein the test concentration is 1%.
Irritation test method: the surfactant irritation test employed the Zein (Zein) method. Zein is a yellow Zein, practically insoluble in water, whose structure is similar to that of keratin found in skin and hair. Zein reacts with irritant substances, such as surfactant solutions, and the like, to denature and dissolve. More aggressive surfactants are more likely to cause denaturation of Zein than less aggressive surfactants, resulting in increased dissolution of Zein. The amount of Zein dissolved represents the skin irritation of the surfactant or formulation.
Taking a sample to be detected, and preparing a solution with the active substance mass fraction/effective substance of 1%. 100g of the solution was taken, 0.5g of Zein was added in succession until it could not be dissolved, and then stirred for 2 hours, followed by filtration. The filter paper and the precipitate were placed in a 45 ℃ oven overnight to dry, weighed, and the amount of Zein dissolved was calculated. The greater the amount of Zein solubilized, the greater the irritation.
Table 2
As can be seen from the above tables 1 and 2, the base formulations of the detergents of examples 1 to 6 exhibited poor bactericidal and bacteriostatic abilities against escherichia coli, staphylococcus aureus and candida albicans without adding an antibacterial substance.
The following are selective additions of antimicrobial substances to the base formulation, the added antimicrobial substances being listed in tables 3-5, respectively.
Table 3, this table lists several groups of silver antimicrobial agents of the present invention with different silver contents.
Table 4, the table lists the content of phenols and flavonoids as active substances in several groups of cannabis extracts of the invention.
Table 5, this table lists the specific compositions of several antimicrobial agents.
The above antibacterial substances were added to the base formulations of examples 1 to 6, respectively, and the addition of each example and the test effect will be described in detail below. The effect test method is the same as table 2.
Table 6, which shows the addition of each antibacterial substance to example 1 and the test effect.
Table 7 shows the addition of each antibacterial substance to example 2 and the test effect. The effect test method is the same as table 2
Table 8, which shows the addition of each antibacterial substance to example 3 and the test effect. The effect test method is the same as table 2
Table 9, which shows the addition of each antibacterial substance to example 4 and the test effect. The effect test method is the same as table 2
Table 10, which shows the addition of each antibacterial substance to example 5 and the test effect. The effect test method is the same as table 2
Table 11, which shows the addition of each antibacterial substance to example 6 and the test effect. The effect test method is the same as table 2
As can be seen from the above tables 3 to 5, the antibacterial agents 1 to 4 of the present invention are composed of silver antibacterial agents 1 to 4 and hemp extract 1 to 4, respectively. And antimicrobial agents 1-4, silver antimicrobial agents 1-4, hemp leaf extract 1-4 were added selectively to the corresponding base formulations of examples 1-6, respectively, as shown in tables 6-11. As can be seen from comparison of tables 6-11 and Table 2, the antibacterial agent of the present invention can significantly enhance the antibacterial and bacteriostatic properties of the detergent, and the irritation is reduced, so that the better use effect can be achieved. The addition of the silver antibacterial agent can only enhance the antibacterial and bacteriostatic performance of the liquid detergent, the irritation performance is not reduced, but is increased, and the irritation of the liquid detergent can be increased instead of reducing the irritation of the liquid detergent. Only the hemp leaf extract is added, so that the bacteriostatic and antibacterial performance of the detergent is not greatly influenced, but the irritation of the detergent can be obviously reduced.
In addition, as can be seen from tables 6 to 11, when the silver antibacterial agent is added alone, compared with the antibacterial agent of the present invention, the hemp leaf extract in the antibacterial agent of the present invention can significantly enhance the bactericidal and bacteriostatic properties of the silver antibacterial agent, and can also reduce the irritation of the detergent.
The antibacterial detergent obtained by compounding the antibacterial agent, the surfactant and other substances has strong decontamination capability and strong sterilization capability. The active components of phenols and flavonoids in the hemp leaves in the antibacterial agent can effectively stabilize the silver antibacterial agent, enhance the effect of the silver antibacterial agent, enable the antibacterial capability of the liquid detergent to be stronger, reduce the irritation caused by the surfactant in the liquid detergent, enhance the sterilization and bacteriostasis effects of the liquid detergent, and are mild and do not harm to skin when in use.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention.
Claims (9)
1. An antibacterial detergent, which comprises a surfactant system and an antibacterial agent, and is characterized in that,
the surfactant system is the combination of any two or more of anionic surfactant, nonionic surfactant and amphoteric surfactant;
the antimicrobial agent is a composition comprising a cannabis leaf extract and a silver antimicrobial agent.
2. An antibacterial detergent according to claim 1, characterized in that: the active ingredients of the hemp leaf extract are phenolic substances and flavonoid substances; the solvent for extracting the hemp leaf extract is one or more of water, ethanol, glycerol and 1, 3-propylene glycol;
the silver antibacterial agent is one or more of colloidal silver simple substance, silver ions or silver complex ions.
3. An antibacterial detergent according to claim 2, characterized in that: in the antibacterial agent, the content of phenolic substances is 0.01-2%, the content of flavonoid substances is 0.0005-2%, and the total content of silver is 50-1000 ppm; the content of the antibacterial agent in the liquid detergent is 0.1-2.5%.
4. An antibacterial detergent according to claim 1, characterized in that: the content of the surfactant system is 10-60%; wherein the weight percentage of the anionic surfactant in the surfactant system is 0-95%, the weight percentage of the nonionic surfactant in the surfactant system is 0-95%, and the weight percentage of the amphoteric surfactant in the surfactant system is 0-20%.
5. An antibacterial detergent according to claim 4, characterized in that: when the content of the surfactant system is more than 35%, the liquid detergent also contains an alcohol solvent, wherein the alcohol solvent is one or a mixture of more than one of glycerol, 1, 3-propylene glycol and ethanol; the content of the solvent is 5-10%.
6. The antibacterial detergent according to any one of claims 1-5, wherein the anionic surfactant is one or a mixture of more than one of linear alkylbenzene sulfonate, fatty alcohol polyoxyethylene ether sulfate, fatty alcohol sulfate, α -olefin sulfonate, fatty acid methyl ester sulfonate, secondary alkyl sulfonate, fatty alcohol polyether carboxylate and fatty acyl sarcosinate, the anionic surfactant is sodium salt, ammonium salt, potassium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt and isopropylamine salt, and the carbon chain of alkyl or fatty alcohol is C8-C18 single carbon chain or mixed carbon chain.
7. An antibacterial detergent according to any one of claims 1-5, wherein: the nonionic surfactant is one or a mixture of more than one of alkanol polyoxyethylene ether, alkyl glycoside, fatty acid methyl ester ethoxylate and alkanolamide, the alkyl of the nonionic surfactant is C10-C18 straight-chain or branched-chain saturated alkyl, and the EO addition number of the polyoxyethylene ether is 6-18.
8. An antibacterial detergent according to any one of claims 1-5, wherein: the amphoteric surfactant is one or more of betaine surfactant, imidazoline surfactant, and amine oxide amphoteric surfactant.
9. An antibacterial detergent according to any one of claims 1-5, wherein: the antibacterial liquid detergent also contains an inorganic salt thickener, a preservative, essence, a chelating agent and a pH regulator.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112375631A (en) * | 2020-11-24 | 2021-02-19 | 云南超越日化有限公司 | Antibacterial laundry detergent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7611858B1 (en) * | 2004-10-21 | 2009-11-03 | University Of Florida Research Foundation, Inc. | Detection of cannabinoid receptor biomarkers and uses thereof |
| CN102925299A (en) * | 2012-11-21 | 2013-02-13 | 广州市南大实业有限公司 | Green antimicrobial cleanser essence as well as preparation method and application thereof |
| CN103484265A (en) * | 2013-09-26 | 2014-01-01 | 陈理敬 | Green antibacterial efficient cleanser essence and preparation method thereof |
| CN110152050A (en) * | 2019-05-30 | 2019-08-23 | 厦门梓素生物科技有限公司 | A kind of functional sanitary towel of the extract containing cannabidiol and preparation method thereof |
| CN110205206A (en) * | 2019-05-07 | 2019-09-06 | 栾云鹏 | A kind of dish washing liquid and preparation method thereof with bactericidal |
-
2019
- 2019-10-30 CN CN201911044587.5A patent/CN110885716A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7611858B1 (en) * | 2004-10-21 | 2009-11-03 | University Of Florida Research Foundation, Inc. | Detection of cannabinoid receptor biomarkers and uses thereof |
| CN102925299A (en) * | 2012-11-21 | 2013-02-13 | 广州市南大实业有限公司 | Green antimicrobial cleanser essence as well as preparation method and application thereof |
| CN103484265A (en) * | 2013-09-26 | 2014-01-01 | 陈理敬 | Green antibacterial efficient cleanser essence and preparation method thereof |
| CN110205206A (en) * | 2019-05-07 | 2019-09-06 | 栾云鹏 | A kind of dish washing liquid and preparation method thereof with bactericidal |
| CN110152050A (en) * | 2019-05-30 | 2019-08-23 | 厦门梓素生物科技有限公司 | A kind of functional sanitary towel of the extract containing cannabidiol and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112375631A (en) * | 2020-11-24 | 2021-02-19 | 云南超越日化有限公司 | Antibacterial laundry detergent and preparation method thereof |
| CN112375631B (en) * | 2020-11-24 | 2021-11-09 | 云南超越日化有限公司 | A kind of antibacterial and antibacterial laundry liquid and preparation method thereof |
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Application publication date: 20200317 |