CN110790374A - Inversion A2O + composite MBR sewage treatment device and treatment method thereof - Google Patents
Inversion A2O + composite MBR sewage treatment device and treatment method thereof Download PDFInfo
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Abstract
本发明公开了一种倒置A2/O+复合式MBR污水处理装置及其处理方法,包括按水流方向依次设置的超细格栅、缺氧池、厌氧池、好氧池、复合式MBR反应器;通过超细格栅的预处理污水由泵抽入缺氧池,缺氧池一端连接后续处理回流污泥和回流硝化液管道,缺氧池出水直接进入厌氧池、好氧池,好氧池一端设有硝化液回流管道回流至缺氧池,好氧池出水进入复合式MBR反应器;经MBR池中立体弹性填料、膜组件处理的污水可排放,MBR池一端设有污泥回流管道回流至缺氧池,同时设有污泥排出管道,排出剩余污泥。本发明能够强化脱氮除磷效果,降低工艺能耗,显著提升出水水质标准。
The invention discloses an inverted A 2 /O+ composite MBR sewage treatment device and a treatment method thereof, comprising ultrafine grids, anoxic ponds, anaerobic ponds, aerobic ponds, and composite MBR reactions arranged in sequence according to the direction of water flow The pretreated sewage passing through the ultra-fine grid is pumped into the anoxic tank, one end of the anoxic tank is connected to the subsequent treatment return sludge and the return nitrification liquid pipeline, and the effluent from the anoxic tank directly enters the anaerobic tank and the aerobic tank. One end of the oxygen tank is equipped with a nitrifying liquid return pipe to return to the anoxic tank, and the effluent from the aerobic tank enters the composite MBR reactor; the sewage treated by the three-dimensional elastic packing and membrane module in the MBR tank can be discharged, and one end of the MBR tank is equipped with a sludge return The pipeline returns to the anoxic tank, and a sludge discharge pipeline is installed to discharge the excess sludge. The invention can strengthen the denitrification and phosphorus removal effect, reduce the energy consumption of the process, and significantly improve the effluent quality standard.
Description
技术领域technical field
本发明涉及城镇污水处理技术领域,具体涉及一种倒置A2/O+复合式MBR污水处理装置及其处理方法。The invention relates to the technical field of urban sewage treatment, in particular to an inverted A 2 /O+ composite MBR sewage treatment device and a treatment method thereof.
背景技术Background technique
随着城镇污水厂排放标准的提高,传统的污水处理工艺已无法满足排放要求,迫切需要对传统的污水处理工艺进行提标改造。With the improvement of the discharge standards of urban sewage plants, the traditional sewage treatment process can no longer meet the discharge requirements, and it is urgent to upgrade the traditional sewage treatment process.
传统的A2/O工艺存在三个明显缺点:1)厌氧区居前,回流污泥中的硝酸盐对厌氧区产生不利影响;2)缺氧区位于系统中部,反硝化在碳源分配上居于不利地位;3)存在内循环,系统排放的剩余污泥实际只有一少部分经历了完整的释磷、吸磷过程。因此提出倒置A2/O工艺,将厌氧与缺氧位置倒置,反硝化的碳源优先获得满足,强化脱氮能力,但常规倒置A2/O工艺存在进水分配不当的缺点,且采用同一回流系统,悬浮物出水稳定性不足,反硝化效率较低。The traditional A 2 /O process has three obvious shortcomings: 1) the anaerobic zone is in the front, and the nitrate in the returning sludge has an adverse effect on the anaerobic zone; 2) the anoxic zone is located in the middle of the system, and denitrification occurs in the carbon source. Disadvantages in distribution; 3) There is an internal circulation, and only a small part of the excess sludge discharged from the system actually undergoes a complete process of phosphorus release and phosphorus absorption. Therefore, an inverted A 2 /O process is proposed, in which the anaerobic and anoxic positions are inverted, the carbon source of denitrification is preferentially satisfied, and the denitrification capacity is strengthened. However, the conventional inverted A 2 /O process has the disadvantage of improper water distribution, and the use of In the same reflux system, the effluent stability of suspended solids is insufficient, and the denitrification efficiency is low.
MBR污水处理是现代污水处理的一种常用方式,MBR污水处理是一种将活性污泥法和一体化浸没式膜分离系统相结合的新型污水处理技术,典型MBR系统的流程可以描述如下:污水经过格栅流入调节池,调节池中的污水被泵输送至缺氧区,将淀粉、纤维、碳水化合物和可溶性有机化合物等悬浮污染物分解为有机酸,大分子有机物分解为小分子有机物,不溶性有机物转化为可溶性有机物。然后污水进入好氧区进行有机物生物降解,同时进行生物硝化反应,并通过回流到缺氧区进行反硝化,完成脱氮功能。不能被降解的杂质和活性污泥被膜组件分离后留在膜池内,膜过滤产水则达标回用或排放。MBR污水处理一般设置于生化处理之后,取代传统二沉池,可以进行高效固液分离,具有出水水质稳定,剩余污泥产量少等优点,但同时也存在投资较高、能耗高、运行成本高等不足,亟需进行改进。MBR sewage treatment is a common method of modern sewage treatment. MBR sewage treatment is a new sewage treatment technology that combines activated sludge method and integrated submerged membrane separation system. The flow of a typical MBR system can be described as follows: Sewage After passing through the grid, it flows into the adjustment tank, and the sewage in the adjustment tank is pumped to the anoxic area, where the suspended pollutants such as starch, fiber, carbohydrates and soluble organic compounds are decomposed into organic acids, and macromolecular organic compounds are decomposed into small molecular organic compounds, insoluble Organic matter is converted into soluble organic matter. Then the sewage enters the aerobic zone for organic biodegradation, and at the same time, the biological nitrification reaction is carried out, and the denitrification is carried out by returning to the anoxic zone to complete the denitrification function. Impurities that cannot be degraded and activated sludge are separated by the membrane module and remain in the membrane tank, and the membrane filtration water is reused or discharged up to the standard. MBR sewage treatment is generally installed after biochemical treatment, replacing the traditional secondary sedimentation tank, and can carry out high-efficiency solid-liquid separation, with the advantages of stable effluent quality and less excess sludge output, but at the same time, there are also high investment, high energy consumption, and operating costs. The high level is insufficient and needs to be improved urgently.
发明内容SUMMARY OF THE INVENTION
针对现有技术的不足,本发明提供了一种倒置A2/O+复合式MBR污水处理装置,有效解决倒置A2/O反硝化效率低的问题,同时降低MBR工艺中能耗与运行成本问题。In view of the deficiencies of the prior art, the present invention provides an inverted A 2 /O+ composite MBR sewage treatment device, which effectively solves the problem of low denitrification efficiency of the inverted A 2 /O and reduces the energy consumption and operating cost in the MBR process. .
为了实现上述目的,本发明采用以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
一种倒置A2/O+复合式MBR污水处理装置,包括按进水方向依次设置的超细格栅、缺氧池、厌氧池、好氧池和复合式MBR反应器;An inverted A 2 /O+ composite MBR sewage treatment device, comprising ultra-fine grids, anoxic pools, anaerobic pools, aerobic pools and composite MBR reactors arranged in sequence according to the direction of water inflow;
好氧池设有硝化液回流管道,好氧池通过硝化液回流管道连接到缺氧池;复合式MBR反应器设有污泥回流管道,复合式MBR反应器通过污泥回流管道连接到缺氧池;硝化液回流管道和污泥回流管道汇合后的管道上设有回流泵,用于抽吸硝化液和污泥;The aerobic tank is provided with a nitrification liquid return pipe, and the aerobic tank is connected to the anoxic tank through the nitrification liquid return pipe; the compound MBR reactor is provided with a sludge return pipe, and the compound MBR reactor is connected to the anoxic tank through the sludge return pipe. pool; a return pump is provided on the pipeline where the nitrification liquid return pipeline and the sludge return pipeline meet, which is used to pump the nitrification liquid and sludge;
超细格栅通过进水管连接到缺氧池和厌氧池,进水管上设有多点进水管,污水通过多点进水管分别连接到缺氧池和厌氧池;多点进水管连接到缺氧池的管道上设有缺氧池进水阀门,用于控制缺氧池的进水;多点进水管连接到厌氧池的管道上设有厌氧池进水阀门,用于控制厌氧池的进水;The ultra-fine grid is connected to the anoxic tank and the anaerobic tank through the water inlet pipe. There are multi-point water inlet pipes on the water inlet pipe. The sewage is respectively connected to the anoxic tank and the anaerobic tank through the multi-point water inlet pipe; Anoxic tank inlet valve is installed on the pipeline of anoxic tank to control the inflow of anoxic tank; multi-point water inlet pipe is connected to the pipeline of anaerobic tank with anaerobic tank inlet valve to control the anaerobic tank The water inlet of the oxygen tank;
复合式MBR池包括填料立方、MBR膜组件和曝气系统,填料立方和MBR膜组件按水流方向依次设置,曝气系统位于填料立方和MBR膜组件的下方;填料立方包括立体填料和立方骨架,所述立体填料固定安装在立方骨架内部,曝气系统包括曝气管,曝气管上方安装有格栅支架;所述的立方骨架通过连接扣与格栅支架活动连接;所述的MBR膜组件亦是通过连接扣与格栅支架活动连接;The composite MBR tank includes packing cube, MBR membrane module and aeration system. The packing cube and MBR membrane module are arranged in sequence according to the direction of water flow, and the aeration system is located under the packing cube and MBR membrane module; the packing cube includes three-dimensional packing and cubic skeleton. The three-dimensional packing is fixedly installed inside the cubic frame, the aeration system includes an aeration pipe, and a grid support is installed above the aeration pipe; the cubic frame is movably connected with the grid support through a connecting buckle; the MBR membrane assembly It is also movably connected with the grille bracket through the connecting buckle;
所述的立体填料由软性醛化纤维压扣在塑料圆片上构成,立体填料的单元直径为150~200mm,立体填料之间间距80~100mm。The three-dimensional filler is formed by pressing soft aldehyde fibers on a plastic disc, the unit diameter of the three-dimensional filler is 150-200 mm, and the spacing between the three-dimensional fillers is 80-100 mm.
本发明的填料立方采用半固定连接的方式,便于安装拆卸,可以大大缩短填料更换时间,MBR膜组件也是如此,和曝气系统共用支架,无需重复安装,结构简单,使用方便。此外,立体填料的布置可使其与污水之间接触均匀,接触面积更大。这样,在MBR池前部设置填料立方,污水先经过填料立方及填料下部的曝气系统,在其表面形成生物膜,作为膜组件前置处理,再进入膜组件系统,降低膜组件压力,同时减少活性污泥回流,能够大幅度降低MBR池的能耗;且污泥回流与硝化液回流共用一套泵系统,进一步降低了能耗。The packing cube of the present invention adopts the semi-fixed connection method, which is convenient for installation and disassembly, and can greatly shorten the packing replacement time. The same is true for the MBR membrane module, which shares the bracket with the aeration system, does not need repeated installation, has a simple structure and is convenient to use. In addition, the arrangement of the three-dimensional packing can make the contact with the sewage uniform and the contact area is larger. In this way, a packing cube is set at the front of the MBR tank, and the sewage first passes through the packing cube and the aeration system at the lower part of the packing to form a biofilm on the surface, which is used as the pretreatment of the membrane module, and then enters the membrane module system to reduce the pressure of the membrane module. Reducing the return of activated sludge can greatly reduce the energy consumption of the MBR tank; and the return of the sludge and the return of the nitrification solution share a pump system, which further reduces the energy consumption.
作为优选,所述的连接扣为滑轮和卡扣。Preferably, the connecting buckle is a pulley and a buckle.
作为优选,超细格栅的栅条之间距离0.2~2mm,超细格栅之间间隔0.1mm。Preferably, the distance between the grid bars of the ultra-fine grid is 0.2-2 mm, and the interval between the ultra-fine grid is 0.1 mm.
作为优选,MBR膜组件为中空纤维膜组件或平板膜组件。Preferably, the MBR membrane module is a hollow fiber membrane module or a flat membrane module.
作为优选,MBR膜组件主要由膜片组成,膜片与膜片之间有效距离大于100mm。Preferably, the MBR membrane module is mainly composed of membranes, and the effective distance between the membranes is greater than 100 mm.
作为优选,曝气管直径15-20mm,开孔在同一轴线,开孔2-4mm,穿孔间距100-150mm。Preferably, the diameter of the aeration pipe is 15-20mm, the openings are on the same axis, the openings are 2-4mm, and the perforation spacing is 100-150mm.
作为优选,复合式MBR池设计膜通量在出厂设计余量的基础上增加30%~50%。Preferably, the designed membrane flux of the composite MBR pool is increased by 30% to 50% on the basis of the factory design margin.
本发明还提供了一种倒置A2/O+复合式MBR污水处理方法,运行成本低,处理效果好。The invention also provides an inverted A 2 /O+ composite MBR sewage treatment method, which has low operation cost and good treatment effect.
所述的倒置A2/O+复合式MBR污水处理方法,包括以下步骤:The inverted A 2 /O+ composite MBR sewage treatment method comprises the following steps:
步骤一:经过预处理的污水通过超细格栅,截留污水中微小的悬浮物、纤维等杂质;Step 1: The pretreated sewage passes through the ultra-fine grid to retain tiny suspended solids, fibers and other impurities in the sewage;
步骤二:然后污水依次流经缺氧池、厌氧池、好氧池,进行脱氮除磷;当厌氧池的C:N:P不满足100:5:1时,打开厌氧池进水阀门使经步骤一处理后的污水流入厌氧池,补充碳源,直至C:N:P为100:5:1,关闭厌氧池进水阀门;Step 2: Then the sewage flows through the anoxic tank, the anaerobic tank, and the aerobic tank in turn for denitrification and phosphorus removal; when the C:N:P of the anaerobic tank does not meet the 100:5:1 ratio, the anaerobic tank is opened to enter. The water valve makes the sewage treated in step 1 flow into the anaerobic tank to supplement the carbon source until the C:N:P is 100:5:1, and close the water inlet valve of the anaerobic tank;
步骤三:将脱氮除磷处理后的污水泵入复合式MBR反应器;回流泵抽吸好氧池中的硝化混合液,通过硝化液回流管道使硝化混合液回流至缺氧池;Step 3: pump the sewage after denitrification and phosphorus removal into the composite MBR reactor; the reflux pump sucks the nitrification mixture in the aerobic tank, and returns the nitrification mixture to the anoxic tank through the nitrification liquid return pipeline;
步骤四:进入复合式MBR反应器的污水经填料立方接触氧化、曝气系统增强氧化和MBR膜组件过滤,出水;回流泵抽吸复合式MBR反应器中的污泥,通过污泥回流管道使污泥回流至缺氧池。Step 4: The sewage entering the composite MBR reactor is contacted and oxidized by the packing cube, enhanced by the aeration system and filtered by the MBR membrane module, and the water is discharged; The sludge is returned to the anoxic tank.
缺氧池接收原污水、复合式MBR反应器回流污泥和好氧池回流硝化液,缺氧池中反硝化菌利用污水中的有机物作为碳源,将NO3 --N和NO2 --N还原为N2释放至空气;厌氧池接收来自缺氧池经反硝化富含聚磷菌的污泥和污水,同时采用多点进水方式,根据水质状况进原污水以补充碳源,厌氧池主要进行释磷过程,复合式MBR反应器接收好氧池出水,污水经填料立方接触氧化后至膜组件系统,经膜组件系统过滤后出水。Anoxic tank receives raw sewage, compound MBR reactor return sludge and aerobic tank return nitrification solution, denitrifying bacteria in anoxic tank use organic matter in sewage as carbon source, NO 3 - -N and NO 2 - - N is reduced to N 2 and released to the air; the anaerobic tank receives sludge and sewage rich in phosphorus-accumulating bacteria after denitrification in the anoxic tank, and at the same time adopts a multi-point water inflow method, and feeds the raw sewage according to the water quality to supplement the carbon source, The anaerobic tank mainly carries out the phosphorus release process, the composite MBR reactor receives the effluent from the aerobic tank, and the sewage is contacted and oxidized by the packing cube to the membrane module system, and the water is filtered by the membrane module system.
作为优选,所述的硝化混合液回流80%~120%至缺氧池,所述的污泥回流150%~180%至缺氧池。Preferably, 80%-120% of the nitrification mixed solution is returned to the anoxic tank, and 150%-180% of the sludge is returned to the anoxic tank.
作为优选,缺氧池水力停留时间0.5~2.5h,厌氧池水力停留时间1~2h,好氧池水力停留时间2.5~4h,复合式MBR池水力停留时间0.5~1.5h。Preferably, the hydraulic retention time of the anoxic pool is 0.5-2.5 h, the hydraulic retention time of the anaerobic pool is 1-2 h, the hydraulic retention time of the aerobic pool is 2.5-4 h, and the hydraulic retention time of the compound MBR pool is 0.5-1.5 h.
作为优选,步骤四中,汽水比24:1,溶解氧控制在3-5mg/L;曝气鼓风机采用变频调速技术。将汽水比、溶氧量控制在一定范围,能够使运行成本的效果之间达到平衡,避免能源浪费。Preferably, in step 4, the ratio of soda to water is 24:1, and the dissolved oxygen is controlled at 3-5mg/L; the aeration blower adopts frequency conversion speed regulation technology. Controlling the ratio of soda to water and the amount of dissolved oxygen within a certain range can achieve a balance between the effect of operating costs and avoid energy waste.
作为优选,MBR膜组件的包裹物用高压水枪或自来水喷洗,单个膜片的处理量低于1.5m3/hr。Preferably, the wrapping of the MBR membrane module is sprayed with a high-pressure water gun or tap water, and the processing capacity of a single membrane is less than 1.5 m 3 /hr.
本发明通过对现有的倒置A2/O工艺进行技术革新,通过改变进水方式及更新参数克服A2/O反硝化效率低的问题:采用两点进水的方式避免倒置使反硝化效率降低。根据污水水质状况控制进入缺氧池和好氧池的污水比例,保证碳源满足硝化反硝化需要而不溢出,工艺中活性污泥经历全部的释磷、吸磷过程,在除磷方面具有“群体效应”,磷的去除效果显著提升,缺氧区位于工艺的首端,允许反硝化优先获得碳源,进一步强化系统的脱氮能力。The present invention overcomes the problem of low denitrification efficiency of A 2 /O by carrying out technical innovation on the existing inverted A 2 /O process, by changing the water inflow mode and updating parameters: the inversion method is adopted to avoid inversion and increase the denitrification efficiency. reduce. Control the proportion of sewage entering the anoxic and aerobic tanks according to the water quality of the sewage to ensure that the carbon source meets the needs of nitrification and denitrification without overflowing. In the process, the activated sludge undergoes all the processes of phosphorus release and phosphorus absorption, and has the "high" in phosphorus removal. Group effect”, the phosphorus removal effect is significantly improved, and the anoxic zone is located at the beginning of the process, allowing denitrification to preferentially obtain carbon sources, further enhancing the denitrification capacity of the system.
本发明采用复合式MBR工艺,将生物接触氧化与膜组件结合,创新性引入可拆卸填料立方置于膜组件前,与曝气系统相结合,降低膜组件压力,提高膜组件的性能以及清洗更换频率,同时减少活性污泥回流量,大大降低能耗。将污泥回流系统与好氧硝化液回流合并,两者共用一套回流泵系统,不仅降低工程造价,也进一步降低了运行能耗。此外,通过对膜片的设计和曝气环境的调整等等,使本发明综合处理污水能力达到最优化,节省能源,节省成本的同时提高经济效益。The invention adopts a composite MBR process, combines biological contact oxidation with membrane components, innovatively introduces removable packing cubes to be placed in front of the membrane components, and combines with the aeration system to reduce the pressure of the membrane components, improve the performance of the membrane components, and clean and replace them. frequency, while reducing the return flow of activated sludge, greatly reducing energy consumption. The sludge return system and the aerobic nitrification liquid return are combined, and the two share a return pump system, which not only reduces the project cost, but also further reduces the operating energy consumption. In addition, through the design of the diaphragm and the adjustment of the aeration environment, etc., the comprehensive sewage treatment capacity of the present invention is optimized, energy is saved, costs are saved, and economic benefits are improved at the same time.
附图说明Description of drawings
图1为本发明的工艺流程图。Fig. 1 is a process flow diagram of the present invention.
图2为本发明的装置结构示意图。FIG. 2 is a schematic diagram of the device structure of the present invention.
图3为填料立方和曝气系统布置图。Figure 3 shows the layout of the packing cube and aeration system.
其中,各数字代表含义如下:1、超细格栅;2、缺氧池;3、厌氧池;4、好氧池;5、复合式MBR池;11、进水管;12、进水管污水泵;13、多点进水管;21、缺氧池进水阀门;22、回流污泥阀门;23、硝化液回流阀门;24、回流泵;31、厌氧池进水阀门;41、好氧池污水泵;42、好氧池出水管;43、硝化液回流管道;51、填料立方;52、MBR膜组件;53、曝气系统;54、污泥回流管道;55、污泥排出管道;56、自吸泵;511、立体填料;512、立方骨架;513、连接扣;514、格栅支架;531、曝气管。Among them, the meanings of each number are as follows: 1. Ultrafine grid; 2. Anoxic tank; 3. Anaerobic tank; 4. Aerobic tank; 5. Composite MBR tank; 11. Inlet pipe; Pump; 13. Multi-point water inlet pipe; 21. Anoxic tank inlet valve; 22. Sludge return valve; 23. Nitrification liquid return valve; 24. Return pump; 31. Anaerobic tank inlet valve; Pool sewage pump; 42, aerobic tank outlet pipe; 43, nitrification liquid return pipe; 51, packing cube; 52, MBR membrane module; 53, aeration system; 54, sludge return pipe; 55, sludge discharge pipe; 56, self-priming pump; 511, three-dimensional packing; 512, cubic frame; 513, connection buckle; 514, grille bracket; 531, aeration pipe.
具体实施方式Detailed ways
为使本发明实施例的目的和技术方案更加清楚,下面将结合本发明实施例的附图,对本发明实施例的技术方案进行清楚、完整地描述。显然,所描述的实施例是本发明的一部分实施例,而不是全部的实施例。基于所描述的本发明的实施例,本领域普通技术人员在无需创造性劳动的前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose and technical solutions of the embodiments of the present invention clearer, the technical solutions of the embodiments of the present invention will be described clearly and completely below with reference to the accompanying drawings of the embodiments of the present invention. Obviously, the described embodiments are some, but not all, embodiments of the present invention. Based on the described embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present invention.
本技术领域技术人员可以理解,除非另外定义,这里使用的所有术语(包括技术术语和科学术语)具有与本发明所属领域中的普通技术人员的一般理解相同的意义。还应该理解的是,诸如通用字典中定义的那些术语应该被理解为具有与现有技术的上下文中的意义一致的意义,并且除非像这里一样定义,不会用理想化或过于正式的含义来解释。It will be understood by those skilled in the art that, unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It should also be understood that terms such as those defined in general dictionaries should be understood to have meanings consistent with their meanings in the context of the prior art and, unless defined as herein, are not to be taken in an idealized or overly formal sense. explain.
实施例1Example 1
如图1所示,一种倒置A2/O+复合式MBR装置,包括按水流方向依次设置的超细格栅1、缺氧池2、厌氧池3、好氧池4和复合式MBR池5。As shown in Figure 1 , an inverted A2/O+ composite MBR device includes ultrafine grids 1,
如图2所示,超细格栅1之间平行设置,两格栅间隔0.1mm,超细格栅1由栅条组成,栅条之间距离0.2~2mm,用于过滤预处理水中较细的颗粒物。As shown in Figure 2, the ultra-fine grids 1 are arranged in parallel, and the distance between the two grids is 0.1 mm. The ultra-fine grid 1 is composed of grid bars, and the distance between the grid bars is 0.2-2 mm, which is used to filter finer pretreated water. of particulate matter.
超细格栅1通过进水管11连接到缺氧池2和厌氧池3,进水管11上设有多点进水管13,污水通过多点进水管13分别连接到缺氧池2和厌氧池3;多点进水管13连接到缺氧池2的管道上设有缺氧池进水阀门21,用于控制缺氧池2的进水;多点进水管13连接到厌氧池3的管道上设有厌氧池进水阀门31,用于控制厌氧池3的进水;多点进水方式可以补充厌氧池3所需碳源。The ultra-fine grid 1 is connected to the
缺氧池2、厌氧池3、好氧池4按进水方向依次设置。和传统的AAO相反,缺氧池2置于厌氧池3之前,反硝化的碳源优先获得满足,强化脱氮能力;聚磷菌经厌氧池3释磷后直接进入好氧池4,可以更加充分利用在厌氧条件下形成的吸磷动力。The
好氧池4通过好氧池出水管42连接到复合式MBR池5,好氧池出水管42上设有好氧池污水泵41,将污水抽吸至复合式MBR池5;好氧池4的一端还通过硝化液回流管道43连接到缺氧池2,其上设有硝化液回流阀门23。复合式MBR池5的一端设有污泥回流管道54,通过污泥回流阀门22和缺氧池2连接,使污泥回流至缺氧池2。硝化液回流管道43和污泥回流管道54汇合后的管道上设有回流泵24,用于抽吸硝化液和污泥。The aerobic pool 4 is connected to the
复合式MBR池5上还有污泥排出管道55和自吸泵56,污泥排出管道55用于排出剩余污泥,自吸泵56用于抽吸净水。The
复合式MBR池5包括填料立方51、MBR膜组件52和曝气系统53,填料立方51和MBR膜组件52按水流方向依次设置。The
如图3所示,曝气系统53包括曝气管531,曝气管531上方安装有格栅支架514。所述的填料立方51通过连接扣513与格栅支架514活动连接;所述的MBR膜组件52亦是通过连接扣513与格栅支架514活动连接;使曝气系统53安装于填料立方51和MBR膜组件52的下方。本实施例的连接扣513为滑轮和卡扣,当然本发明的连接扣不限于此。As shown in FIG. 3 , the aeration system 53 includes an
填料立方51包括立体填料511和立方骨架512,所述立体填料511固定安装在立方骨架512内部。立体填料511由软性醛化纤维压扣在塑料圆片上构成,立体填料511的单元直径为150~200mm,立体填料511之间间距80~100mm。本实施例利用立体弹性填料与污水接触产生的生物膜在好氧环境下进一步强化脱氮除磷效果,同时降低后置MBR膜组件的压力负荷,减少MBR膜组件的清理频率,提升使用周期。The packing cube 51 includes a three-
MBR膜组件52由多个膜片组成,每个膜片与填料立方51的间隙对应一路曝气管531。MBR膜组件52可根据实际污水情况选择中空纤维膜组件或平板膜组件。所述膜组件52系统中膜片与膜片之间有效距离大于100mm,膜组件包裹物积累一定程度需用高压水枪或自来水喷洗,单个膜组件处理量低于1.5m3/hr。The MBR membrane assembly 52 is composed of a plurality of membrane sheets, and the gap between each membrane sheet and the packing cube 51 corresponds to one
所述好氧池4硝化液回流与复合式MBR池5污泥回流及排出采用同一套回流泵系统,采用回流泵24,以达到节能目的。Said aerobic tank 4 nitrification liquid return and
上述倒置A2/O+复合式MBR污水处理方法,包括以下步骤:The above-mentioned inverted A 2 /O+ composite MBR sewage treatment method comprises the following steps:
污水经过预处理后,通过超细格栅1,截留污水中微小的悬浮物、纤维等杂质。After the sewage is pretreated, it passes through the ultra-fine grid 1 to retain tiny suspended solids, fibers and other impurities in the sewage.
污水通过进水管11,由进水管污水泵12泵入缺氧池2,缺氧池中反硝化菌利用污水中的有机物作为碳源,将NO3 --N和NO2 --N还原为N2释放至空气。The sewage passes through the inlet pipe 11 and is pumped into the
缺氧池2出水进入厌氧池3,厌氧池3接收来自缺氧池经反硝化富含聚磷菌的污泥和污水,同时采用多点进水方式,当C:N:P不足100:5:1时,补充碳源并根据水质状况进原污水以补充碳源,厌氧池主要进行释磷过程。The effluent of the
好氧池接收厌氧池出水,好氧池中有机氮被氨化继而被硝化,磷随着聚磷菌的摄取,浓度降低,同时好氧池硝化混合液按比例回流至缺氧池。好氧池4通过硝化液回流管道43使硝化液回流至缺氧池2,以补充硝态氮。The aerobic tank receives the effluent of the anaerobic tank, the organic nitrogen in the aerobic tank is ammoniated and then nitrified, the phosphorus concentration decreases with the intake of phosphorus accumulating bacteria, and the nitrification mixture of the aerobic tank is returned to the anoxic tank in proportion. The aerobic tank 4 returns the nitrifying liquid to the
污水经过缺氧池2、厌氧池3、好氧池4脱氮除磷后,经好氧池出水管42进入复合式MBR池5,先经过填料立方51接触氧化、吸附,再经过MBR膜组件52过滤,达到排放标准,经自吸泵56出水。回流泵24抽吸复合式MBR反应器5中的污泥,通过污泥回流管道43使污泥回流至缺氧池2;剩余污泥通过污泥排出管道55排出。After the sewage passes through the
复合式MBR池5的污泥按比例回流至缺氧池2,剩余污泥经污泥排出管道55排出。The sludge in the
所述好氧池4回流至缺氧池2的硝化液回流比为80%~120%;所述复合式MBR池5回流至缺氧池的活性污泥的回流比为150%~180%。The return ratio of the nitrification solution from the aerobic tank 4 to the
缺氧池水力停留时间0.5~2.5h,厌氧池水力停留时间1~2h,好氧池水力停留时间2.5~4h,复合式MBR池水力停留时间0.5~1.5h。The hydraulic retention time of anoxic pool is 0.5-2.5h, the hydraulic retention time of anaerobic pool is 1-2h, the hydraulic retention time of aerobic pool is 2.5-4h, and the hydraulic retention time of compound MBR pool is 0.5-1.5h.
所述复合式MBR池5设计膜通量应在出厂设计余量的基础上增加30%~50%;所述复合式MBR池5曝气穿孔管直径15-20mm,开孔需在同一轴线,开孔2-4mm,穿孔间距100-150mm,曝气量根据经验值估计,汽水比24:1,溶解氧控制在3-5mg/L;曝气鼓风机采用变频调速技术。The designed membrane flux of the
实施例2Example 2
利用实施例1的装置和方法对经预处理后的生活污水进行处理,具体工艺条件:水力停留时间7.5h,MBR池水力停留时间1.5h,硝化液回流比为120%;活性污泥的回流比为180%;复合式MBR池立体弹性填料单元直径200mm,填料间距80mm;选用平板膜,膜通量设计余量增加30%;膜片之间有效距离大于120mm,采用自来水喷洗,单个膜组件处理量低于1.2m3/hr;选用直径20mm曝气穿孔管,开孔2mm,穿孔间距100mm,汽水比24:1,溶解氧控制在3-5mg/L。Using the device and method of Example 1 to treat the pretreated domestic sewage, the specific process conditions: hydraulic retention time 7.5h, MBR pool hydraulic retention time 1.5h, nitrification solution reflux ratio of 120%; The ratio is 180%; the diameter of the three-dimensional elastic packing unit of the composite MBR pool is 200mm, and the packing spacing is 80mm; the flat membrane is used, and the design allowance of the membrane flux is increased by 30%; The processing capacity of the module is less than 1.2m 3 /hr; the diameter of the aeration perforated pipe is 20mm, the opening is 2mm, the perforation spacing is 100mm, the steam-water ratio is 24:1, and the dissolved oxygen is controlled at 3-5mg/L.
污水厂规模2万吨/天,进水平均COD 352.5mg/L,BOD5 124.7mg/L,氨氮25.6mg/L,总氮32.2mg/L,总磷4.1mg/L。The scale of the sewage plant is 20,000 tons/day. The average influent water is COD 352.5mg/L, BOD 5 124.7mg/L, ammonia nitrogen 25.6mg/L, total nitrogen 32.2mg/L, and total phosphorus 4.1mg/L.
出水水质为COD 20.5mg/L,BOD5 3.2mg/L,氨氮1.6mg/L,总氮2.0mg/L,总磷0.18mg/L,出水水质达到准Ⅳ类水标准。The effluent water quality is COD 20.5mg/L, BOD 5 3.2mg/L, ammonia nitrogen 1.6mg/L, total nitrogen 2.0mg/L, total phosphorus 0.18mg/L, and the effluent quality reaches the quasi-IV class water standard.
实施例3Example 3
某污水厂的进水水质为:平均COD 422.4mg/L,BOD5 141.9mg/L,氨氮28.3mg/L,总氮36.2mg/L,总磷5.6mg/L。The influent water quality of a sewage plant is: average COD 422.4mg/L, BOD 5 141.9mg/L, ammonia nitrogen 28.3mg/L, total nitrogen 36.2mg/L, and total phosphorus 5.6mg/L.
该污水厂原有的污水处理工艺为A2/O+MBR工艺,处理规模1万吨/天,水力停留时间9h,MBR池水力停留时间2h,硝化液回流比200%,活性污泥回流比200%,选用中空纤维膜,单个膜组件处理量低于1.0m3/hr,直径18mm曝气穿孔管,开孔1.8mm,穿孔间距150mm,汽水比24:1。经污水厂原有污水处理工艺处理后,出水水质为COD 50.5mg/L,BOD5 10.4mg/L,氨氮4.8mg/L,总氮13.5mg/L,总磷0.48mg/L,满足一级a排放标准。The original sewage treatment process of this sewage plant is A 2 /O+MBR process, the treatment scale is 10,000 tons/day, the hydraulic retention time is 9h, the hydraulic retention time of the MBR tank is 2h, the nitrifying solution reflux ratio is 200%, and the activated sludge reflux ratio is 200%. 200%, hollow fiber membrane is selected, the processing capacity of a single membrane module is less than 1.0m 3 /hr, the diameter of the aeration perforated pipe is 18mm, the opening is 1.8mm, the perforation spacing is 150mm, and the steam-water ratio is 24:1. After being treated by the original sewage treatment process of the sewage treatment plant, the effluent water quality is COD 50.5mg/L, BOD 5 10.4mg/L, ammonia nitrogen 4.8mg/L, total nitrogen 13.5mg/L, and total phosphorus 0.48mg/L, which meet the first grade. aEmission standards.
按照实施例1的结构,对污水厂原有的污水处理工艺进行改造:生化池改变管道的进出水顺序,形成倒置A2/O工艺无需新建水池,MBR池进原有曝气方式不变,膜组件参数进行优化,在膜组件前部设置本发明的填料立方。改造后水力停留时间8h,MBR池水力停留时间1.5h,硝化液回流比为100%;活性污泥的回流比为150%;复合式MBR池立体弹性填料单元直径200mm,填料间距100mm;保留原膜组件与曝气系统,优化膜组件参数,膜通量设计余量增加35%;单个膜组件处理量低于1.2m3/hr。将污水厂原有污水处理工艺改造成本发明的结构,对污水进行处理后,出水水质为COD 32.3mg/L,BOD5 8.9mg/L,氨氮1.9mg/L,总氮2.3mg/L,总磷0.36mg/L,可达地表Ⅴ类水标准。According to the structure of Example 1, the original sewage treatment process of the sewage treatment plant is transformed: the biochemical tank changes the order of water in and out of the pipeline, and the inverted A 2 /O process does not need to build a new tank, and the original aeration mode of the MBR tank remains unchanged, The parameters of the membrane module are optimized, and the packing cube of the present invention is arranged at the front of the membrane module. After the transformation, the hydraulic retention time is 8h, the hydraulic retention time of the MBR tank is 1.5h, the reflux ratio of nitrification solution is 100%; the reflux ratio of activated sludge is 150%; the diameter of the three-dimensional elastic packing unit of the composite MBR tank is 200mm, and the packing spacing is 100mm; For membrane modules and aeration systems, the parameters of membrane modules are optimized, and the design margin of membrane flux is increased by 35%; the processing capacity of a single membrane module is less than 1.2m 3 /hr. The original sewage treatment process of the sewage plant is transformed into the structure of the present invention. After the sewage is treated, the effluent quality is COD 32.3mg/L, BOD 5 8.9mg/L, ammonia nitrogen 1.9mg/L, total nitrogen 2.3mg/L, total nitrogen Phosphorus 0.36mg/L, which can reach the standard of surface V water.
虽然本发明已以较佳实施例揭露如上,然其并非用以限定本发明。本发明所属技术领域中具有通常知识者,在不脱离本发明的精神和范围内,当可作各种的更动与润饰。因此,本发明的保护范围当视权利要求书所界定者为准。Although the present invention has been disclosed above with preferred embodiments, it is not intended to limit the present invention. Those skilled in the art to which the present invention pertains can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be determined according to the claims.
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