CN110757975A - Printing process not easy to wipe for glass products - Google Patents
Printing process not easy to wipe for glass products Download PDFInfo
- Publication number
- CN110757975A CN110757975A CN201911085747.0A CN201911085747A CN110757975A CN 110757975 A CN110757975 A CN 110757975A CN 201911085747 A CN201911085747 A CN 201911085747A CN 110757975 A CN110757975 A CN 110757975A
- Authority
- CN
- China
- Prior art keywords
- glass
- hydrofluoric acid
- wax film
- printing
- printing process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/34—Printing on other surfaces than ordinary paper on glass or ceramic surfaces
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/213—SiO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention discloses a printing process for glass products, which is not easy to abrade, and comprises the following steps of melting paraffin, coating the paraffin on the parts of the cleaned glass products needing to be printed, and forming a layer of wax film on the glass; removing the middle part of the wax film to enable the wax film to be a hollow rectangular frame or a circular frame; adding hydrofluoric acid into the frame-shaped wax film, and standing for a period of time; washing the hydrofluoric acid on the glass product with water, scraping off a wax film, and etching the contact part of the glass and the hydrofluoric acid to form a frosted surface through the hydrofluoric acid; according to the method, the part of the glass product needing to be printed is processed into the frosted surface in advance, the contact area between the printing ink and the printing part is increased conveniently, the adhesion and solidification stability of the printing ink can be increased, the high-temperature and vacuum environment is adopted when the printing ink is solidified, the silicon dioxide can form a glassy and compact silicon dioxide film on the surface of the printing ink conveniently, the strength of the silicon dioxide film formed in the mode is high, and the scratch resistance of the printing ink can be increased.
Description
Technical Field
The invention belongs to the technical field of glass product printing, and particularly relates to a printing process which is not easy to wipe and remove and used for glass products.
Background
The printing is a copying technology for original manuscript graphic and text information, its most important feature is that it can reproduce the graphic and text information on various printing materials, so to speak, its finished product can be extensively and permanently stored, and this is a printing on glass product, and is more convenient for distinguishing and propaganda of company brand.
The existing printing process for glass products has the problems that the glass products have smooth surfaces and cannot absorb ink like paper, so that the ink is difficult to solidify on the glass products, and a silica oxide film formed by a conventional method has low strength and is not resistant to rubbing.
Disclosure of Invention
The present invention is directed to a printing process for glass products that is not easily erased, so as to solve the problems mentioned in the background art.
In order to achieve the purpose, the invention provides the following technical scheme: a printing process for a glass article that is not easily abraded, comprising the steps of:
s1, melting paraffin, and then coating the melted paraffin on the part of the cleaned glass product to be printed to form a wax film on the glass;
s2, removing the middle part of the wax film to enable the wax film to be a hollow rectangular frame or a circular frame;
s3, adding hydrofluoric acid into the frame-shaped wax film, and standing for a period of time;
s4, washing hydrofluoric acid on the glass product with water, scraping off a wax film, and etching the contact part of the glass and the hydrofluoric acid to form a frosted surface through the hydrofluoric acid;
s5, adding silicon dioxide into the printing ink;
s6, printing on the frosted surface of the glass product by using a printing machine;
s7, placing the glass product in a vacuum environment for heating, then gradually cooling for 1-2 hours, wherein the silicon dioxide can form a glassy and compact silicon dioxide film in a printing mode during cooling, then taking out the glass product, and placing the glass product in a natural environment for natural cooling.
Preferably, the minimum height of the wax film in the step S1 is 0.5 cm.
Preferably, the standing time in the step S3 is 25 to 35 minutes.
Preferably, the chemical reaction equation for etching glass with hydrofluoric acid in step S4 is SiO2(S) +4hf (aq) ═ SiF4(g) = +2H2O (l).
Preferably, in the step S7, the heating temperature is 60-70 ℃, and the heating rate is 20C/min.
Preferably, the natural cooling time in step S7 is 1 h.
Compared with the prior art, the invention has the beneficial effects that:
this application is through processing into frosting with the position that glass products need be printed in advance, be convenient for increase printing ink and the area of contact who bears the printing position to the stability that can multiplicable printing ink adhesion solidification, and adopt high temperature and vacuum environment when printing ink solidifies, the silica of being convenient for can form glass state and compact silica film on printing ink surface, the intensity of the silica film that this kind of mode formed is big, the scrubbing resistance of multiplicable printing ink, and then adopt natural cooling, can prevent excessive volatilization of silica film surface oxygen.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention and not to limit the invention.
FIG. 1 is a flow chart of the present invention;
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the terms "vertical", "upper", "lower", "horizontal", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of describing the present invention and simplifying the description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention.
In the description of the present invention, it should also be noted that, unless otherwise explicitly specified or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly and may, for example, be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; either directly or indirectly through intervening media, or through the communication between two elements. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
Referring to fig. 1, the present invention provides a technical solution: a printing process for a glass article that is not easily abraded, comprising the steps of:
s1, melting paraffin, and then coating the melted paraffin on the part to be printed on the cleaned glass product to form a layer of wax film on the glass, wherein the lowest height of the wax film is 0.5cm according to the curvature of the surface of the glass bottle so as to prevent hydrofluoric acid from leaking from the wax film;
s2, removing the middle part of the wax film to enable the wax film to be a hollow rectangular frame or a circular frame;
s3, adding hydrofluoric acid into the frame-shaped wax film, and standing for 30 minutes to facilitate the hydrofluoric acid to be fully etched with the glass product;
s4, washing the hydrofluoric acid on the glass product with water, scraping off the wax film, and polishing the contact part of the hydrofluoric acid etched glass and the hydrofluoric acid to form a polished surface, wherein the chemical reaction equation of the hydrofluoric acid etched glass is SiO2(S) +4hf (aq) ═ SiF4(g) × 2H2O (l);
s5, adding silicon dioxide into the printing ink;
s6, printing on the frosted surface of the glass product by using a printing machine;
s7, placing the glass product in a vacuum environment, heating to 60 ℃, then gradually cooling for 1h, wherein the silicon dioxide can form a glassy and compact silicon dioxide film on the surface of the printing ink during cooling, the strength of the silicon dioxide film formed in the way is high, then taking out the glass product, and placing the glass product in a natural environment for natural cooling for 1h, so that excessive volatilization of oxygen on the surface of the silicon dioxide film can be prevented, and the silicon dioxide film easily cracks due to excessive volatilization of oxygen.
In this embodiment, preferably, in step S7, the heating temperature is 60 to 70 degrees, and the heating rate is 20C/min.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (6)
1. A printing process for glass products which is not easily abraded is characterized by comprising the following steps:
s1, melting paraffin, and then coating the melted paraffin on the part of the cleaned glass product to be printed to form a wax film on the glass;
s2, removing the middle part of the wax film to enable the wax film to be a hollow rectangular frame or a circular frame;
s3, adding hydrofluoric acid into the frame-shaped wax film, and standing for a period of time;
s4, washing hydrofluoric acid on the glass product with water, scraping off a wax film, and etching the contact part of the glass and the hydrofluoric acid to form a frosted surface through the hydrofluoric acid;
s5, adding silicon dioxide into the printing ink;
s6, printing on the frosted surface of the glass product by using a printing machine;
s7, placing the glass product in a vacuum environment for heating, then gradually cooling for 1-2 hours, wherein the silicon dioxide can form a glassy and compact silicon dioxide film on the surface of the printing ink during cooling, then taking out the glass product, and placing the glass product in a natural environment for natural cooling.
2. The printing process for a glass article that is not easily abraded according to claim 1, wherein: the minimum height of the wax film in the step S1 is 0.5 cm.
3. The printing process for a glass article that is not easily abraded according to claim 1, wherein: and the standing time in the step S3 is 25-35 minutes.
4. The printing process for a glass article that is not easily abraded according to claim 1, wherein: the chemical reaction equation for etching glass with hydrofluoric acid in step S4 is SiO2(S) +4hf (aq) ═ SiF4(g) × +2H2O (l).
5. The printing process for a glass article that is not easily abraded according to claim 1, wherein: in the step S7, the temperature is increased to 60-70 ℃, and the heating rate is 20C/min.
6. The printing process for a glass article that is not easily abraded according to claim 1, wherein: the natural cooling time in step S7 is 1 h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911085747.0A CN110757975A (en) | 2019-11-07 | 2019-11-07 | Printing process not easy to wipe for glass products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911085747.0A CN110757975A (en) | 2019-11-07 | 2019-11-07 | Printing process not easy to wipe for glass products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110757975A true CN110757975A (en) | 2020-02-07 |
Family
ID=69336850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911085747.0A Pending CN110757975A (en) | 2019-11-07 | 2019-11-07 | Printing process not easy to wipe for glass products |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110757975A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1609029A (en) * | 2004-09-29 | 2005-04-27 | 高国樑 | Method of forming notched color fine pattern on the surface of glass product |
| CN101041555A (en) * | 2006-03-22 | 2007-09-26 | 郑州恒昊玻璃技术有限公司 | Ornamental glass having etching pattern and multicolor pattern and and method for manufacturing same |
| CN105543844A (en) * | 2015-12-14 | 2016-05-04 | 广东星弛光电科技有限公司 | Preparation method of colorless anti-reflection anti-fingerprint membrane for mobile phone glass panel |
| CN106881069A (en) * | 2017-03-09 | 2017-06-23 | 吉林师范大学 | A kind of preparation method and application of temperature response type europium ion trace composite membrane |
| CN106985468A (en) * | 2015-12-18 | 2017-07-28 | 旭硝子株式会社 | Glass laminate with diaphragm |
| CN108250754A (en) * | 2016-12-28 | 2018-07-06 | 东京应化工业株式会社 | Containing silicone resin composition, containing silicone resin film, silica membrane, illuminated display element panel and luminous display unit |
| CN109551644A (en) * | 2017-09-27 | 2019-04-02 | 徐元庆 | A kind of household appliance glass production technology |
| CN109664628A (en) * | 2018-12-21 | 2019-04-23 | 东莞市银泰丰光学科技有限公司 | A kind of production method of novel dumb light anti-dazzle glas |
| CN109852136A (en) * | 2018-12-28 | 2019-06-07 | 湖南松井新材料股份有限公司 | One-component ink and water-based ink coating for 3C glass |
-
2019
- 2019-11-07 CN CN201911085747.0A patent/CN110757975A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1609029A (en) * | 2004-09-29 | 2005-04-27 | 高国樑 | Method of forming notched color fine pattern on the surface of glass product |
| CN101041555A (en) * | 2006-03-22 | 2007-09-26 | 郑州恒昊玻璃技术有限公司 | Ornamental glass having etching pattern and multicolor pattern and and method for manufacturing same |
| CN105543844A (en) * | 2015-12-14 | 2016-05-04 | 广东星弛光电科技有限公司 | Preparation method of colorless anti-reflection anti-fingerprint membrane for mobile phone glass panel |
| CN106985468A (en) * | 2015-12-18 | 2017-07-28 | 旭硝子株式会社 | Glass laminate with diaphragm |
| CN108250754A (en) * | 2016-12-28 | 2018-07-06 | 东京应化工业株式会社 | Containing silicone resin composition, containing silicone resin film, silica membrane, illuminated display element panel and luminous display unit |
| CN106881069A (en) * | 2017-03-09 | 2017-06-23 | 吉林师范大学 | A kind of preparation method and application of temperature response type europium ion trace composite membrane |
| CN109551644A (en) * | 2017-09-27 | 2019-04-02 | 徐元庆 | A kind of household appliance glass production technology |
| CN109664628A (en) * | 2018-12-21 | 2019-04-23 | 东莞市银泰丰光学科技有限公司 | A kind of production method of novel dumb light anti-dazzle glas |
| CN109852136A (en) * | 2018-12-28 | 2019-06-07 | 湖南松井新材料股份有限公司 | One-component ink and water-based ink coating for 3C glass |
Non-Patent Citations (1)
| Title |
|---|
| 肖九梅: "玻璃装饰制品的蚀刻丝印艺术", 《网印工业》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5066617B2 (en) | Glass substrate for cover glass of portable terminal device and method for manufacturing the same | |
| JP2690106B2 (en) | Optical fiber manufacturing method | |
| CN103229130B (en) | Contact panel strengthening glass sheets and utilize its contact panel tempered glass board fabrication method | |
| KR20100125279A (en) | Damage resistant glass article for use as a cover plate in electronic devices | |
| CA1333524C (en) | Method for making glass articles with defect-free surfaces and soluble glasses therefor | |
| GB1431352A (en) | Method of making a glass body | |
| KR20110137820A (en) | Glass having anti-glare surface and method of making | |
| WO2012153797A1 (en) | Process for producing cover glass for electronic appliance, and holder for glass substrate for cover glass for electronic appliance | |
| KR20210022045A (en) | Chemically toughened glass article having no optical orange skin and method for producing the same | |
| CN104556717A (en) | TFT glass substrate thinning environment-friendly etching solution and thinning process thereof | |
| JPWO2016117476A1 (en) | Chemically tempered glass and method for producing the same | |
| CN102364375B (en) | Lens cleaning device for mobile equipment | |
| CN105171941A (en) | Preparing method for sapphire touch screen panel | |
| CN110757975A (en) | Printing process not easy to wipe for glass products | |
| CN213673501U (en) | Quick not damaged glass burnishing device | |
| CN111847849A (en) | Glass hot bending process and application of glass hot bending process in 3D glass preparation method | |
| CN111811904A (en) | Preparation method of GCr15 high-temperature laser confocal in-situ dynamic observation sample | |
| CN105171583A (en) | Preparing method for sapphire touch screen panel | |
| CN107857471A (en) | A kind of preparation method of gradient color glass | |
| JP2009067958A (en) | Treating agent for forming antifouling coating on optically functional laminate | |
| CN201326036Y (en) | Silicon nitride film baking device of quartz crucible for polysilicon solar battery cast ingot | |
| CN111039564B (en) | Matte toughened protective glass and preparation method and application thereof | |
| CN105150031A (en) | Production method for sapphire frameless touch screen panel | |
| CN105171940A (en) | Manufacturing method for sapphire frame-free touch screen panel | |
| CN112140666A (en) | Mobile phone toughened film repairing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200207 |
|
| RJ01 | Rejection of invention patent application after publication |