CN110668477A - Process and system for producing sintered magnesia by taking magnesium hydroxide as raw material - Google Patents

Abstract

The invention relates to a process and a system for producing sintered magnesia by taking magnesium hydroxide as a raw material, wherein the system comprises a filter cake storage bin, a variable combined feeding unit, a quick drying device, a shaftless screw conveyor, a bucket elevator I, a suspension roasting device, a high-temperature high-pressure ball pressing system, a bucket elevator II, a shaft kiln feeding bin and a high-temperature shaft kiln; feeding a magnesium hydroxide filter cake prepared from seawater or brine as a raw material by a variable combined feeding unit, drying in a quick drying device, and conveying the dried magnesium hydroxide powder to a suspension roasting device by a shaftless screw conveyor for roasting to obtain high-activity magnesium oxide powder; and (3) carrying out circulating hot-pressing on the high-activity magnesia powder by a high-temperature high-pressure ball pressing system, and then feeding the high-activity magnesia powder into a high-temperature shaft kiln for calcination to obtain a sintered magnesia product. The invention has short process flow, low production energy consumption, little environmental pollution and low production cost; the prepared high-purity and high-density sintered magnesite product can replace a magnesite calcined sintered magnesite product and an electric smelting product.

Description

A process and system for producing sintered magnesia with magnesium hydroxide as raw material

technical field

The invention relates to the technical field of production of magnesia materials, in particular to a process and system for producing sintered magnesia by using magnesium hydroxide as a raw material.

Background technique

At present, there are two main methods of producing magnesia in the world: one is calcined or fused with natural magnesite, and the other is made by calcining magnesium hydroxide obtained from seawater or brine at high temperature. Obtaining high-density, high-purity sintered magnesia products has always been the development direction of magnesia production.

my country's Liaoning region has high-quality magnesite resources. Since the 1990s, it has become the main production base and export base of the global magnesia market. However, the long-term disorderly and extensive mining has led to the decline of ore quality, waste of resources, ecological damage and serious environmental pollution. At the same time, China is rich in seawater and brine resources, which can produce tens of millions of tons of magnesium-rich concentrated seawater and brine every year. Magnesia products produced from magnesium hydroxide after chemical treatment of seawater and brine are more likely to have a purity of 98%. Above, the bulk density can reach more than 3.45g/ ^cm3 ; but the existing technology that uses magnesium hydroxide as raw material to produce magnesia generally has the problems of long process flow and high production cost, and there are few domestic related production enterprises.

Aiming at the problems of increasing scarcity of magnesite resources, especially high-quality magnesite resources and serious damage to the ecological environment, the present invention deeply researches and develops a method for preparing sintered magnesia by using magnesium hydroxide prepared from seawater or brine as raw material, It is conducive to shortening the process flow, promoting energy-saving and consumption-reducing technologies, and reducing production costs. Its products can eventually replace magnesite calcined magnesia products, which is of great significance to promoting the sustainable development of magnesium resources and energy conservation and environmental protection.

SUMMARY OF THE INVENTION

The invention provides a process and system for producing sintered magnesia by using magnesium hydroxide as a raw material, which has the advantages of short process flow, low production energy consumption, low environmental pollution and low production cost; Sand products can replace magnesite calcined sintered magnesia products and fused products, used as raw materials for the production of various magnesia refractory bricks and unshaped refractories, and are widely used in metallurgy, petrochemical, non-ferrous and other high-temperature industries; it is beneficial to reduce Natural resources and energy consumption, improve the ecological environment, and realize the sustainable development of magnesium resources.

In order to achieve the above object, the present invention adopts the following technical solutions to realize:

A process for producing sintered magnesia with magnesium hydroxide as raw material, the magnesium hydroxide filter cake obtained from seawater or brine is used as raw material, fed through a variable combined feeding unit, and sent to a rapid drying device for drying, and the drying process is carried out. The resulting magnesium hydroxide powder is transported to a suspension roasting device for roasting by a shaftless screw conveyor to obtain high-activity magnesium oxide powder; the high-activity magnesium oxide powder is subjected to circulating hot-pressing balls through a high-temperature and high-pressure ball pressing system and then sent to a high-temperature vertical calcined in a kiln to obtain sintered magnesia products.

The variable combined feeding unit is composed of a manual gate valve, a star feeder, a screw conveyor, a shredder and a frequency conversion motor. The feeding end of the variable combined feeding unit is provided with a manual gate valve; the star feeding The machine and screw conveyor are driven by frequency conversion motor. The feed end of the screw conveyor is equipped with a shredder; the manual gate valve can directly adjust the feeding amount. The shredder is used to break up the agglomerated materials and feed them in a star shape. The machine and screw conveyor are used for forced feeding and conveying, and have the function of further dispersing and homogenizing the material; the frequency conversion motor is used to adjust the feeding speed.

The rapid drying device utilizes the residual heat of the flue gas of the suspension roasting device for drying, the hot flue gas inlet temperature is 300-450°C, and the flue gas discharge temperature is 50-150°C; the flue gas outlet is connected to a flue gas purification treatment system; after drying The water content of magnesium hydroxide is less than or equal to 5%.

The suspension roasting device utilizes the waste heat of the flue gas of the high-temperature shaft kiln for roasting, the hot flue gas inlet temperature is 500-650°C, and the flue gas discharge temperature is 300-450°C; the suspension roasting device is provided with 2-5 cyclones.

The high-temperature and high-pressure briquetting system includes a pre-pressing device and a high-pressure device, which are used for cyclic hot-pressing of the lightly burned magnesium oxide, and the hot-pressing temperature is 400-600°C; the line pressure of the briquetting machine is 80-110kN/cm; The ball groove is almond-shaped or peach-pit-shaped, with a capacity of 10-20 cm ³ .

The high-temperature shaft kiln uses heavy oil or natural gas as fuel, and is controlled by a PLC control system for continuous production, and the calcination temperature is 1800-2000°C.

The produced sintered magnesia has a MgO content of ≥98 percent and a bulk density of ≥3.45 g/cm ³ .

The system for producing sintered magnesia using magnesium hydroxide as a raw material according to the present invention includes a filter cake silo, a variable combined feeding unit, a rapid drying device, a shaftless screw conveyor, a bucket elevator, a suspension roasting device, a high temperature High-pressure ball press system, bucket elevator II, shaft kiln feeding bin and high temperature shaft kiln; the discharge port of the filter cake storage bin is connected with the feed port of the variable combined feeding unit; the outlet of the variable combined feeding unit The material port is connected to the feed port of the quick drying device, the discharge port of the quick drying device is connected to the feed port of the shaftless screw conveyor, and the discharge port of the shaftless screw conveyor is connected to the feeding end of the bucket elevator 1. The discharge end of the first type elevator is connected to the feed port of the suspension roasting device; the discharge port of the suspension roasting device is connected to the feed port of the high temperature and high pressure briquetting system, and the discharge port of the high temperature and high pressure briquetting system is connected to the bucket elevator 2 The feeding end of the second bucket elevator is connected to the feed port of the feed bin of the shaft kiln, and the discharge port of the feed bin of the shaft kiln is connected to the feed port of the high temperature shaft kiln.

The flue gas outlet of the high-temperature shaft kiln is connected to the roasting heat source inlet of the suspension roasting device through the first flue gas pipeline, and the flue gas outlet of the suspension roasting device is connected to the drying heat source inlet of the quick drying device through the second flue gas pipeline; The flue gas outlet is connected to the flue gas inlet of the flue gas purification treatment system through the third flue gas pipeline, and the clean flue gas outlet of the flue gas purification treatment system is connected to the chimney.

The variable combined feeding unit, rapid drying device, shaftless screw conveyor, suspension roasting device, high temperature and high pressure ball pressure system and high temperature shaft kiln are all fully enclosed structures.

Compared with the prior art, the beneficial effects of the present invention are:

1) the present invention realizes the effective utilization of seawater or brine resources, compared with the traditional high-purity magnesia production process, the sintered magnesia preparation process of the present invention is a continuous, fully enclosed production process, and the magnesium hydroxide raw material is dried, Roasting to remove bound water, high temperature briquetting, high temperature sintering and other processes to make sintered magnesia, only one set of fuel system and one set of kiln flue gas purification treatment and exhaust system are set up to make full use of the waste heat of flue gas, the process is simple, The process is short, the environmental pollution is small, and the energy saving and environmental protection benefits are good;

2) The variable combined feeding unit is used for feeding. The equipment has a compact structure and is completely closed. It is easy to install on-site and has no dust overflow; the manual gate valve can directly adjust the amount of material, reduce the running resistance of the star feeder, and can completely Cut off the material flow, which is convenient for maintenance operations in the event of failure; the shredder is used to break up the agglomerated materials for subsequent transportation; the star feeder and screw conveyor can perform forced feeding and transportation, and have the functions of further breaking up, Homogenization can improve the drying efficiency of magnesium hydroxide filter cake; adopt frequency conversion motor drive system, can adjust the feeding speed and realize automatic control;

3) The shaftless screw conveyor adopts fully enclosed conveying, the screw surface is easy to clean, has a compact structure, saves space, and has low energy consumption, and the magnesium hydroxide is not polluted, leaked, and difficult to block;

4) Use a suspension roasting device to remove the bound water of magnesium hydroxide at a temperature of 500 to 650 ° C, because the lower the roasting temperature, the smaller the size of the magnesium oxide grains obtained by decomposition, and the better the high temperature sintering performance after briquetting. The traditional two-step calcination method of magnesite to produce high-purity magnesia can produce active magnesia by light burning at about 900 °C, while magnesium hydroxide begins to decompose and debond water at about 300 °C, which can produce double vacancies after debonding. , the structure is relaxed and the defects are increased, which is conducive to promoting the sintering of magnesium oxide;

5) The suspension roasting device is divided into two stages of preheating and roasting, without a combustion system, the roasting temperature is low, the number of cyclones is reduced, the structure is simple, and the operation is convenient; the heat source of the suspension roasting device comes from the hot flue gas of the high-temperature shaft kiln, and The flue gas discharged from the suspension roasting device can also be used for the secondary use of the rapid drying device, which reduces the production cost and energy consumption, and realizes energy saving and consumption reduction;

6) The calcined magnesia does not need to be cooled and directly hot-pressed, which can avoid volume shrinkage after cooling of the magnesia, and the bulk density of the spheroids can be increased by 0.1 to 0.3 g/cm ³ compared with the prior art; the cyclic briquetting process is adopted (The crushed material under the sieve is returned to the system for re-balling) to solve the problem of difficulty in forming powder materials into balls and improve the ball-forming rate;

7) The high-temperature shaft kiln realizes fully automatic control through the PLC control system. The whole system only sets up a fuel system at the high-temperature shaft kiln to make full use of the waste heat of the flue gas;

8) The prepared sintered magnesia has high purity, few impurities, uniform and stable quality, and the bulk density can reach more than 3.45 g/cm ³ . The refractory products made from it as raw materials have good high temperature performance, heat resistance strength, excellent slag resistance and erosion resistance, and long service life. They are high-quality high-end refractory raw materials with broad application fields and prospects.

Description of drawings

1 is a schematic structural diagram of a system for producing sintered magnesia using magnesium hydroxide as a raw material according to the present invention.

Fig. 2 is a process flow diagram of the present invention for producing sintered magnesia with magnesium hydroxide as a raw material.

In the picture: 1. Filter cake storage bin 2. Variable combined feeding unit 3. Fast drying device 4. Shaftless screw conveyor 5. Bucket elevator 1 6. Suspension roasting device 7. High temperature and high pressure briquetting system 8. Bucket Type elevator II 9. Shaft kiln feed bin 10. High temperature shaft kiln 11. Flue gas purification treatment system 12. Chimney 13. Fuel system

Detailed ways

The specific embodiments of the present invention will be further described below in conjunction with the accompanying drawings:

As shown in Figure 1 and Figure 2, a process for producing sintered magnesia with magnesium hydroxide as a raw material according to the present invention, the magnesium hydroxide filter cake obtained from seawater or brine is a raw material, and the variable combined feeding unit 2 The feeding material is sent to the rapid drying device 3 for drying, and the dried magnesium hydroxide powder is transported to the suspension roasting device 6 for roasting by the shaftless screw conveyor 4 to obtain high-activity magnesium oxide powder; The powder is subjected to circulating hot pressing by the high temperature and high pressure ball pressing system 7 and then sent to the high temperature shaft kiln 10 for calcination to obtain sintered magnesia products.

The variable combined feeding unit 2 is composed of a manual gate valve, a star feeder, a screw conveyor, a shredder and a frequency conversion motor. The feeding end of the variable combined feeding unit 2 is provided with a manual gate valve; The feeder and screw conveyor are driven by frequency conversion motor, and the feed end of the screw conveyor is equipped with a shredder; the manual gate valve can directly adjust the feeding amount, and the shredder is used to break up the agglomerated materials. The feeder and screw conveyor are used for forced feeding and conveying, and have the function of further dispersing and homogenizing the material; the frequency conversion motor is used to adjust the feeding speed.

The rapid drying device 3 utilizes the residual heat of the flue gas from the suspension roasting device 6 for drying. The temperature of the hot flue gas entering is 300-450°C, and the temperature of the flue gas discharging is 50-150°C; the flue gas outlet is connected to the flue gas purification treatment system; The water content of the dried magnesium hydroxide is less than or equal to 5%.

The suspension roasting device 6 utilizes the waste heat of the flue gas of the high-temperature shaft kiln 10 for roasting, the temperature of the hot flue gas entering is 500-650°C, and the temperature of the flue gas discharging is 300-450°C; the suspension roasting device 6 is provided with 2-5 cyclones .

The high-temperature and high-pressure briquetting system 7 includes a pre-pressing device and a high-pressure device, which are used for cyclic hot-pressing of the lightly fired magnesia, and the hot-pressing temperature is 400-600°C; ; The ball groove is almond-shaped or peach-pit-shaped, with a capacity of 10 to 20 cm ³ .

The high-temperature shaft kiln 10 uses heavy oil or natural gas as fuel, and is controlled by a PLC control system for continuous production, and the calcination temperature is 1800-2000°C.

The produced sintered magnesia has a MgO content of ≥98 percent and a bulk density of ≥3.45 g/cm ³ .

The system for producing sintered magnesia using magnesium hydroxide as a raw material according to the present invention comprises a filter cake silo 1, a variable combined feeding unit 2, a quick drying device 3, a shaftless screw conveyor 4, a bucket elevator 1 5. Suspension roasting device 6, high temperature and high pressure briquetting system 7, bucket elevator 2 8, shaft kiln feed bin 9 and high temperature shaft kiln 10; the discharge port of the filter cake storage bin 1 and the variable joint feeding unit The feed port of 2 is connected; the discharge port of the variable combined feeding unit 2 is connected to the feed port of the quick drying device 3, and the discharge port of the quick drying device 3 is connected to the feed port of the shaftless screw conveyor 4. The discharge port of conveyor 4 is connected to the feeding end of bucket elevator one 5, and the discharge end of bucket elevator one 5 is connected to the feeding port of suspension roasting device 6; the discharge port of suspension roasting device 6 is connected to high temperature and high pressure The feeding port of the ball pressing system 7 and the discharging port of the high temperature and high pressure ball pressing system 7 are connected to the feeding end of the second bucket elevator 8 , and the discharging end of the second bucket elevator 8 is connected to the feeding end of the shaft kiln feeding bin 9 . The feed port, the discharge port of the feed bin 9 of the shaft kiln is the feed port of the high temperature shaft kiln 10 .

The flue gas outlet of the high temperature shaft kiln 10 is connected to the roasting heat source inlet of the suspension roasting device 6 through the first flue gas pipeline, and the flue gas outlet of the suspension roasting device 6 is connected to the drying heat source inlet of the quick drying device 3 through the second flue gas pipeline; The flue gas outlet of the quick drying device 3 is connected to the flue gas inlet of the flue gas purification processing system 11 through the third flue gas pipeline, and the clean flue gas outlet of the flue gas purification processing system 11 is connected to the chimney 12 .

The variable combined feeding unit 2, the quick drying device 3, the shaftless screw conveyor 4, the suspension roasting device 6, the high temperature and high pressure briquetting system 7 and the high temperature shaft kiln 10 are all fully enclosed structures.

A process for producing sintered magnesia with magnesium hydroxide as a raw material according to the present invention is as follows:

1) The magnesium hydroxide filter cake prepared from seawater or brine stored in the filter cake silo 1 is first scattered and transported through the variable combined feeding unit 2 (commercially available set equipment), and the feeding rate is based on the magnesia sand. depending on the output;

2) sending the scattered magnesium hydroxide into the quick drying device 3 for drying, and the drying temperature is 300-450° C. to obtain magnesium hydroxide with a moisture content≤5%;

3) the dried magnesium hydroxide is transported to the suspension roasting device 6 by the shaftless screw conveyor 4 and the bucket elevator-5, and the delivery rate of the shaftless screw conveyor 4 is determined according to the output of magnesia;

4) After the magnesium hydroxide powder is preheated in the preheating section in the suspension roasting device 6, it enters the roasting section for roasting, and the suspension roasting device is provided with 2 to 5 cyclones (the number of cyclones is determined according to the output of magnesia and the specifications of the cyclone cylinder. ), the roasting temperature is 500℃～650℃;

5) The activated magnesium oxide after roasting is directly sent into the closed high temperature and high pressure ball pressing system 7 for circulating hot pressing, after pre-pressing and high-pressure pressing, the ball material is sent to the shaft kiln feed bin 9 through the bucket elevator 2 8 , the crushed material is returned to the high temperature and high pressure ball pressing system 7 for circulating ball pressing (Fig. 1 shows a circulating ball pressing method, but the present invention is not limited to this method), and the hot pressing temperature is 400°C to 600°C.

6) The green pellets in the feed bin 9 of the shaft kiln are sent to the high-temperature shaft kiln 10 for calcination, and the calcination temperature is 1800-2000° C. to obtain a sintered magnesia product;

7) The high-temperature shaft kiln 10 is provided with a combustion system 13, and the hot flue gas produced by it is sent to the suspension roasting device 6 for roasting magnesium hydroxide, and the temperature of the hot flue gas is 500-650 ° C; the hot flue gas generated by the suspension roasting device 6 is sent to The magnesium hydroxide is dried in the quick drying device 3, and the temperature of the flue gas is 300-450°C; the temperature of the flue gas discharged from the quick-drying device 3 is 50-150°C;

8) After the flue gas discharged from the rapid drying device 3 is treated by the flue gas purification treatment system 11 and reaches the standard, it is discharged through the chimney 12 .

In the above-mentioned technological process, step 1), step 2) and step 3) are mainly to carry out the preliminary treatment of raw materials, including the dispersion and drying of magnesium hydroxide filter cake, to obtain magnesium hydroxide powder, and its purpose is to suspend magnesium hydroxide in suspension. Preparation for roasting in the roasting device; Step 4) roasting the dried magnesium hydroxide in a suspension roasting device to obtain high-activity magnesia, the purpose of which is to prepare for high-quality magnesia calcined in a high-temperature shaft kiln; Step 5) The calcined active magnesia powder is subjected to circulating hot-pressing balls to increase the bulk density of the magnesia balls, which is helpful for calcining high-density magnesia in the high-temperature shaft kiln; step 6) calcining the magnesia balls in the high-temperature shaft kiln to obtain High-density, high-quality magnesia; step 7) and step 8) are the rational utilization of the waste heat of the flue gas of the high-temperature shaft kiln and the suspension roasting device and the purification process of the flue gas, and the process of the present invention minimizes the impact on the environment. Pollution and waste of resources, to achieve energy saving and environmental protection.

In summary, a process and system for producing sintered magnesia using magnesium hydroxide as a raw material according to the present invention, through the simplification and automatic control of the process flow, the use of low-temperature roasting and circulating hot pressing, reduction of fuel combustion and rational utilization of flue gas. , and finally realized the purpose of fully automatic control, energy saving and environmental protection of sintered magnesia production.

The above description is only a preferred embodiment of the present invention, but the protection scope of the present invention is not limited to this. The equivalent replacement or change of the inventive concept thereof shall be included within the protection scope of the present invention.

Claims (10)

1. a technique for producing sintered magnesia with magnesium hydroxide as a raw material, is characterized in that, the magnesium hydroxide filter cake obtained with seawater or brine is a raw material, and is fed into a fast drying device through variable combination feeding unit feeding After drying, the dried magnesium hydroxide powder is transported to a suspension roasting device by a shaftless screw conveyor for roasting to obtain high-activity magnesium oxide powder; The balls are then sent to a high-temperature shaft kiln for calcination to obtain sintered magnesia products. 2. a kind of technique of producing sintered magnesia with magnesium hydroxide as raw material according to claim 1, is characterized in that, described variable joint feeding unit is composed of manual gate valve, star feeder, screw conveyor It is composed of a shredder and a frequency conversion motor. The feed end of the variable combined feeding unit is equipped with a manual gate valve; the star feeder and the screw conveyor are driven by the inverter motor, and the feed end of the screw conveyor is equipped with a shredder; The manual gate valve can directly adjust the feeding amount, the crusher is used to break up the agglomerated materials, the star feeder and the screw conveyor are used for forced feeding and conveying, and have the function of further breaking up and homogenizing the materials. The role of the variable frequency motor is used to adjust the feeding speed. 3. a kind of technique of producing sintered magnesia with magnesium hydroxide as raw material according to claim 1, is characterized in that, described rapid drying device utilizes the flue gas waste heat of suspension roasting device to dry, and hot flue gas enters temperature is 300～450℃, the flue gas discharge temperature is 50～150℃; the flue gas outlet is connected to the flue gas purification treatment system; the water content of the dried magnesium hydroxide is ≤5%. 4. a kind of technique of producing sintered magnesia with magnesium hydroxide as raw material according to claim 1, is characterized in that, described suspension roasting device utilizes the flue gas waste heat of high temperature shaft kiln to roast, and hot flue gas enters temperature is 500～650℃, flue gas discharge temperature is 300～450℃; 2～5 cyclones are set in the suspension roasting device. 5. a kind of technology of producing sintered magnesia with magnesium hydroxide as raw material according to claim 1, is characterized in that, described high temperature and high pressure briquetting system comprises pre-pressing device and high-pressure device, is used for light-burning after Magnesium oxide is subjected to cyclic hot pressing, and the hot pressing temperature is 400-600°C; the line pressure of the briquetting machine is 80-110 kN/cm ^; 6. a kind of technique of producing sintered magnesia with magnesium hydroxide as raw material according to claim 1, is characterized in that, described high temperature shaft kiln takes heavy oil or natural gas as fuel, is controlled by PLC control system to carry out continuous production, calcining The temperature is 1800～2000℃. 7 . The process for producing sintered magnesia with magnesium hydroxide as a raw material according to claim 1 , wherein the produced sintered magnesia has a MgO content of ≥98% and a bulk density of ≥3.45 g/cm ³ . 8. a system for producing sintered magnesia with magnesium hydroxide as a raw material for realizing any one of the processes described in claims 1-7, is characterized in that, comprising filter cake silo, variable joint feeding unit, quick drying device, shaftless screw conveyor, bucket elevator 1, suspension roasting device, high temperature and high pressure briquetting system, bucket elevator 2, shaft kiln feed bin and high temperature shaft kiln; the discharge port of the filter cake storage bin It is connected with the feeding port of the variable combined feeding unit; the discharging port of the variable combined feeding unit is connected to the feeding port of the quick drying device, and the discharging port of the quick drying device is connected to the feeding port of the shaftless screw conveyor. The discharge port of the screw conveyor is connected to the feeding end of the first bucket elevator, and the discharge end of the first bucket elevator is connected to the feeding port of the suspension roasting device; the discharge port of the suspension roasting device is connected to the high temperature and high pressure ball pressing system. The feeding port, the discharge port of the high temperature and high pressure ball pressure system is connected to the feeding end of the second bucket elevator, and the discharging end of the second bucket elevator is connected to the feeding port of the feed bin of the shaft kiln. The discharge port is the feed port of the high temperature shaft kiln. 9. A system for producing sintered magnesia with magnesium hydroxide as a raw material according to claim 8, wherein the flue gas outlet of the high temperature shaft kiln is connected to the roasting heat source of the suspension roasting device through the first flue gas pipeline The inlet, the flue gas outlet of the suspension roasting device is connected to the drying heat source inlet of the quick drying device through the second flue gas pipeline; the flue gas outlet of the rapid drying device is connected to the flue gas inlet of the flue gas purification treatment system through the third flue gas pipeline, and the flue gas The net flue gas outlet of the purification treatment system is connected to the chimney. 10. A system for producing sintered magnesia with magnesium hydroxide as a raw material according to claim 8, wherein the variable combined feeding unit, fast drying device, shaftless screw conveyor, suspension roasting device, The high temperature and high pressure briquetting system and the high temperature shaft kiln are all closed structures.

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