CN110529671A - A kind of oil well carbon silica gel high pressure wire braided hose - Google Patents
A kind of oil well carbon silica gel high pressure wire braided hose Download PDFInfo
- Publication number
- CN110529671A CN110529671A CN201910716834.5A CN201910716834A CN110529671A CN 110529671 A CN110529671 A CN 110529671A CN 201910716834 A CN201910716834 A CN 201910716834A CN 110529671 A CN110529671 A CN 110529671A
- Authority
- CN
- China
- Prior art keywords
- steel wire
- layer
- silica gel
- sebific duct
- high pressure
- Prior art date
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 55
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 34
- 239000000741 silica gel Substances 0.000 title claims abstract description 34
- 229910002027 silica gel Inorganic materials 0.000 title claims abstract description 34
- 239000003129 oil well Substances 0.000 title claims abstract description 26
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 58
- 239000010959 steel Substances 0.000 claims abstract description 58
- 230000008520 organization Effects 0.000 claims abstract description 24
- 239000010439 graphite Substances 0.000 claims abstract description 18
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 18
- 239000003292 glue Substances 0.000 claims abstract description 16
- 238000004804 winding Methods 0.000 claims abstract description 16
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 8
- 239000003623 enhancer Substances 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 68
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000003921 oil Substances 0.000 claims description 17
- 239000000047 product Substances 0.000 claims description 10
- 238000004073 vulcanization Methods 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 230000003712 anti-aging effect Effects 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 239000002071 nanotube Substances 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 150000001558 benzoic acid derivatives Chemical class 0.000 claims description 3
- 238000007664 blowing Methods 0.000 claims description 3
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000010440 gypsum Substances 0.000 claims description 3
- 229910052602 gypsum Inorganic materials 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010074 rubber mixing Methods 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims description 3
- 239000006228 supernatant Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 125000005375 organosiloxane group Chemical group 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims 1
- 238000007710 freezing Methods 0.000 abstract description 5
- 230000008014 freezing Effects 0.000 abstract description 5
- 230000006978 adaptation Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 229920002472 Starch Polymers 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 description 21
- 239000000463 material Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- -1 Siloxanes Chemical class 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229940069428 antacid Drugs 0.000 description 1
- 239000003159 antacid agent Substances 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000005439 thermosphere Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D23/00—Producing tubular articles
- B29D23/001—Pipes; Pipe joints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/005—Hoses, i.e. flexible pipes consisting completely or partially of material other than fibres, plastics or metal
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
- F16L11/08—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall
- F16L11/088—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising a combination of one or more layers of a helically wound cord or wire with one or more braided layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L57/00—Protection of pipes or objects of similar shape against external or internal damage or wear
- F16L57/06—Protection of pipes or objects of similar shape against external or internal damage or wear against wear
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
- F16L59/029—Shape or form of insulating materials, with or without coverings integral with the insulating materials layered
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/04—Arrangements using dry fillers, e.g. using slag wool
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/10—Bandages or covers for the protection of the insulation, e.g. against the influence of the environment or against mechanical damage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
A kind of oil well carbon silica gel high pressure wire braided hose comprising interior sebific duct, the interior sebific duct is mainly by being that 10-16% carbon, 42-53% silica gel, 12-18% Nano graphite and 22-27% nitrile rubber component are constituted with mass percent；Steel wire organization level is set on the outside of the interior sebific duct, canvas layer is set between the steel wire organization level and interior sebific duct, the canvas layer is two-sided brushed with the sub- glue of slurry, it starches in sub- glue and contains bind enhancer, the canvas layer and steel wire, which is compiled into, is repeated in three layers or more, gauge of wire is 1-2mm, adjacent steel wire organization level is wound with opposite repercussion, the helical angle of winding is 45 degree or so, the outermost steel wire organization level is externally provided with spongy layer, spongy layer is tightened by gauze winding, the spongy layer is externally provided with non-metallic wear resistant layer, non-metallic wear resistant layer is bellows composition.The present invention can be from subzero tens degree to tens degree above freezing to the adaptation of temperature, and warm season limit of not being bullied, service life greatly improves.
Description
Technical field
The invention belongs to petroleum technology fields, especially provide a kind of oil well carbon silica gel high pressure wire braided hose.
Background technique
During well workover, often carry out conveying high-pressure fluid using to high-pressure hose.It is roughly divided into two processes,
It is generally made of General Purpose Rubber or plastics in high-voltage tube a few years ago, the pipeline of plastic material can not be arbitrarily bent, for needing pipe
The general selection rubber material of the random folded bent in road, but the general wearability of sebific duct, intensity, ageing resistance is made all in General Purpose Rubber
Lower, especially the service life of hose is shorter during high-pressure delivery；Technical staff had invented high pressure steel volume in recent years
Sebific duct is generally exactly in internal layer or outer layer setting sebific duct, and middle layer improves intensity with steel wire braid, further according to the need of function
Some functional layers are set wherein, for example form flame-retardant layer using fire proofing, form heat-insulated thermosphere etc. using heat-barrier material,
Its various performance all greatly improves, such as Publication No. CN206054980U, publication date 2017.03.29；
The fire-retardant high pressure steel wire of oil resistant disclosed in CN204533877U, the Chinese utility model patent that publication date is 2015.08.05 weaves glue
Pipe, relatively common rubber hose, the characteristics such as Gao Shuiwen strong with acid resistance, resistance to, oil resistant, wear-resisting.But above-mentioned high pressure steel
Silk braided construction hose be restricted in terms of climate temperature, general hot weather construction operation, it is above freezing to thirty or forty degree can normal operation
Construction, but begin to bulge, husking or even crack occur to autumn and winter temperature to subzero construction operation fuse, especially
It the use of the crack occurred is even more frequently to occur in the Northern Hemisphere in winter, such as Northeast Area of China, the lower place performance of temperature
It is more obvious.Crack causes high-pressure hose to leak, and unbearable high-pressure fluid not only misses especially in the pressure of 15MPa or more
Work is mistaken, and also pollution environment, cost are also higher.The main reason for causing the above problem is that material selection is incorrect, can not be resisted tight
It is cold, low-temperature resistance.As Daqing oil field recover the oil nine operation groups, the factory high pressure rubber hose braided with steel wire that has a Φ 51*4*20 specification used less than
Occur within three months bulge 18, it is small such as walnut as large as egg；There are also a similar sebific ducts to use husking nearly three in two months
Rice, has seriously affected production and its personal safety, has caused serious economic loss.These problems all need to improve.
Summary of the invention
The present invention solve above-mentioned technical problem, a kind of oil well carbon silica gel sebific duct is provided, keep it is good it is wear-resisting,
Acidproof, oil resistant, it is anti-aging on the basis of, can not be bullied the warm season from subzero tens degree to tens degree above freezing to the adaptation of temperature
Section limitation, service life greatly improve.
The present invention solves the technical solution that technical problem uses:
A kind of oil well carbon silica gel high pressure wire braided hose comprising interior sebific duct, the interior sebific duct mainly by with
Mass percent is that 10-16% carbon, 42-53% silica gel, 12-18% Nano graphite and 22-27% nitrile rubber component are constituted；
Steel wire organization level is set on the outside of the interior sebific duct, canvas layer is set between the steel wire organization level and interior sebific duct, it is described
Canvas layer is two-sided to be starched brushed with sub- glue is starched and contains bind enhancer in sub- glue, and the bind enhancer is 20-24 by mass fraction
Part cobaltous octadecanate, 45-60 parts to benzoic acid salt, 4-10 parts of silane coupling agent, 1-5 parts of fatty acid and 15-22 parts of gypsum, it is described
Canvas layer and steel wire, which are compiled into, is repeated in three layers or more, and gauge of wire 1-2mm, adjacent steel wire organization level is with opposite
Repercussion winding, the helical angle of winding are 45 degree or so, and the outermost steel wire organization level is externally provided with spongy layer, spongy layer by
Gauze winding tightens, and the spongy layer is externally provided with non-metallic wear resistant layer, and non-metallic wear resistant layer is bellows composition, can fold.
Above-mentioned canvas layer and steel wire organization level is successively preferably provided with four layers.
It further include the antioxidant that mass percent is 1-2% anti-aging agent and 2-4% in the component of above-mentioned interior sebific duct.
Above-mentioned fuse main body mainly by with mass percent be 13% carbon, 47% silica gel, 15% Nano graphite and
25% nitrile rubber component is constituted.
Above-mentioned Nano graphite is nano tube structure, be length for what time the graphite cylinder shape of micron, single layer
For six face shape planar structures, radial is nano-scale, draw ratio 1:10.
Further include in the component of above-mentioned fuse main body mass percent be 1-2% deaeration agent, deaeration agent may be selected organic
Siloxanes or polyethers or silicon and ether graft product.
The preparation process of -6 any oil well carbon silica gel sebific ducts according to claim 1 comprising following step
It is rapid:
It 1) is 10-16% carbon, 42-53% silica gel, 12-18% Nano graphite and 22-27% butyronitrile by mass percent
Rubber weighs respective amount and is stirred together, is then 1-2% deaeration agent in rubber mixing machine mass percent is wherein added
It is kneaded into film；
2) film is molded into the sebific duct of various different sizes with bulb-blowing machine, is used as interior sebific duct；
3) two-sided inside and outside smear on cementing machine of canvas is starched into sub- glue, be then included outside sebific duct, outside interior sebific duct
Portion is being constituted steel wire organization level with 45 degree of direction winding steel wires, is then repeated in canvas layer and steel wire braid more than three times,
And the adjacent establishment of steel wire twice winding carries out in the opposite direction；
4) molded product of step 3) is put into your primary steam sulfidization molding of vulcanizing tank, vulcanization time is 5-8 hours, sulphur
Changing temperature is 200-500 degrees Celsius；
5) vulcanization terminates, and after placing cooling in 1-2 hours, spongy layer is wrapped up on the outside of its finished product, spongy layer is tightened with gauze；
6) bellows, the both ends of bellows or middle section interval 50-100mm are set on the outside again after sponge tightens
It is fastened on internal sponge layer, and end part seal lives spongy layer.
Preceding claims any oil well carbon silica gel sebific duct can be drained on the tank car of oil field and be used or in oil field
Steam coach supernatant washing oil wells are used using or oil field cleaning vehicle cleaning oil well.
Beneficial effects of the present invention:
1, by using the molding high pressure steel sebific duct of material of the new component such as carbon silica gel, guarantee it is good it is wear-resisting,
Oil resistant, it is acidproof and anti-aging on the basis of, it is wider to the use scope in thermal climate season, be adapted to subzero tens degree arrive
Tens degrees Celsius above freezing, it is particularly suitable for the Northern Hemisphere regional winter, in the case that in northeast, use in winter keeps 15MPa pressure,
Continuous use will appear the phenomenon that any husking, bulge and cracking for three months, its service life greatly improves compared with the prior art,
It reduces costs, and improves work efficiency, also reduce the pollution of environment；
2, setting multilayer is repeated by canvas layer and steel wire floor, on the one hand can increases its flexibility, it on the other hand can be with
Enhance its intensity, opposite can reduce steel wire diameter, reduce pipeline quality, and be brushed with containing bind enhancer in canvas bilayer
Slurry glue, glue industry can penetrate into the gap of adjacent wires, and right steel wire radially can also form entirety, to further enhance
The intensity of steel wire；
3, by the way that spongy layer is arranged in steel wire floor outer layer, spongy layer has thermal and insulating performance, winter can be prevented low
Damage of the temperature to internal pipeline, and tightened on the outside of spongy layer with gauze, it can allow spongy layer more consolidation, can further completely cut off in this way
Outer low temperature enters in spongy layer；
4, addition age resister, antioxidant can be further improved its anti-aging, oxidation resistant performance in new component,
It can be further improved its service life；
5, bubbles volume in the fuse in forming process can further be removed by deaeration agent being added in new component, and it is closely knit to improve its
Degree and intensity, also can be further improved its service life；
6, by the way that non-metallic wear resistant layer is arranged outside spongy layer, on the one hand internal spongy layer can be protected, it is another
Aspect improves the abrasion between high pressure rubber hose braided with steel wire and other components, and completely also very convenient using bellows folding, mentions
The high convenience using operation
7, due to the presence of mixing material Nano graphite, with compound with regular structure, large specific surface area, intensity is high, has stone
The excellent intrinsic property (heat-resisting, corrosion-resistant, heat shock resistance and self-lubrication) of ink, is the rubber material of high-performance and function
Reinforced filling；
8, winding angle counter-wound is rotated between multilayer steel wire organization level adjacent layer, can further increase twining for steel wire
Around intensity.
Detailed description of the invention
It is illustrated below in conjunction with attached drawing with embodiment
Fig. 1 is structural schematic diagram of the invention；
Fig. 2 is cross-sectional view of the Fig. 1 at C-C.
Specific embodiment
Embodiment, referring to attached drawing 1-2, a kind of oil well carbon silica gel high pressure wire braided hose comprising interior sebific duct 1,
The interior sebific duct mainly by with mass percent be 10-16% carbon, 42-53% silica gel, 12-18% Nano graphite and 22-
27% nitrile rubber component is constituted；Steel wire organization level 3, the steel wire organization level and interior sebific duct are set on the outside of the interior sebific duct
Between canvas layer 2 is set, the canvas layer is two-sided to be starched brushed with sub- glue is starched and contains bind enhancer in sub- glue, the bonding
Promoting agent by mass fraction is 20-24 parts of cobaltous octadecanates, 45-60 parts to benzoic acid salt, 4-10 parts of silane coupling agent, fatty acid 1-5
Part and gypsum 15-22 part, the canvas layer and steel wire, which are compiled into, is successively spaced repeatedly three layers or more, gauge of wire 1-
The surface of 2mm, steel wire coat zinc coat, and it is 8-10% fluxing agent that zinc mass fraction is added in galvanizing process, and described helps plating
The preferred ammonium chloride of agent and zinc chloride match according to a certain percentage, have more excellent adhesion and surface flatness, adjacent
Steel wire organization level is wound with opposite repercussion, and the helical angle of winding is 45 degree or so, outside the outermost steel wire organization level
Equipped with spongy layer 4, spongy layer is tightened by gauze winding, and the spongy layer is externally provided with non-metallic wear resistant layer 5, and non-metallic wear resistant layer is wave
Line pipe is constituted.
Preferably, interior sebific duct internal coat hydrophobic layer, hydrophobic layer tension of the water in interior sebific duct can also be can reduce again,
Reduce frictional force, to reduce the pressure loss during conveying high-pressure water, for example polytetrafluoroethylene (PTFE) can be used in hydrophobic layer.
Preferably, the canvas layer and steel wire organization level are successively preferably provided with four layers.
It preferably, further include mass percent in the component of the fuse main body for 1-2% deaeration agent, deaeration agent is optional
Organosiloxane or polyethers or silicon and ether graft product are selected, such deaeration agent price is low, and deaeration effect is good.
It preferably, further include mass percent in the component of the fuse main body is the anti-of 1-2% anti-aging agent and 2-4%
Oxidant.
Preferably, the fuse main body is mainly by being that 15% carbon, 45% silica gel, 17% graphite are received with mass percent
Rice and 23% nitrile rubber component are constituted.
Preferably, the Nano graphite is nano tube structure, be length for what time the graphite cylinder shape of micron,
Its single layer is six face shape planar structures, and radial is nano-scale, and draw ratio 1:10, nano tube structure is regular, large specific surface area,
Intensity is high, with graphite excellent intrinsic property (heat-resisting, corrosion-resistant, heat shock resistance and self-lubrication, biocompatibility, heat
The property led, electrical conductance are good), it is the reinforced filling of the rubber material of high-performance and function.But carbon nanotube clinging tendency and chemistry are lazy
Property chamber, cause the dispersibility and the reduction of caking property of rubber, thus must using either physically or chemically improving, than
Such as the draw ratio of carbon nanotube can be can reduce by the way that zinc oxide is added in mixing material, sulphur is added wherein can be to carbon
Nanotube carries out solution and twines.
The preparation process of above-mentioned oil well carbon silica gel sebific duct comprising following step:
It 1) is 10-16% carbon, 42-53% silica gel, 12-18% Nano graphite and 22-27% butyronitrile by mass percent
Rubber weighs respective amount and is stirred together, is then 1-2% deaeration agent in rubber mixing machine mass percent is wherein added
It is kneaded into film；
2) film is molded into the sebific duct of various different sizes with bulb-blowing machine, is used as interior sebific duct；
3) two-sided inside and outside smear on cementing machine of canvas is starched into sub- glue, be then included outside sebific duct, outside interior sebific duct
Portion is being constituted steel wire organization level with 45 degree of direction winding steel wires, is then repeated in canvas layer and steel wire braid more than three times,
And the adjacent establishment of steel wire twice winding carries out in the opposite direction；
4) molded product of step 3) is put into your primary steam sulfidization molding of vulcanizing tank, vulcanization time is 5-8 hours, sulphur
Changing temperature is 200-500 degrees Celsius；
5) vulcanization terminates, and after placing cooling in 1-2 hours, spongy layer is wrapped up on the outside of its finished product, spongy layer is tightened with gauze；
6) bellows, the both ends of bellows or middle section interval 50-100mm are set on the outside again after sponge tightens
It is fastened on internal sponge layer, and end part seal lives spongy layer.
Preferably, the step before vulcanization terminates can coat polytetrafluoroethylene ethylene layer in interior sebific duct.
Preferably, metal joint, convenient also extraneous pipeline connection are also equipped in outermost layer steel wire organization level end.
Preferably, by finished product packing, seal up for safekeeping.
The present invention has extensive usage, can drain and use or in oil field steam coach supernatant on the tank car of oil field
Washing oil wells are used using or oil field cleaning vehicle cleaning oil well.
General Purpose Rubber pipe, existing high pressure rubber hose braided with steel wire and carbon silica gel high pressure rubber hose braided with steel wire of the invention property at normal temperature
It can compare, such as the following table 1:
Table 1
By the molding above-mentioned carbon silica gel self-sealing core of the above method in oil fields such as Daqing oil field, Panjins in winter reality
It tests, is utilized respectively the General Purpose Rubber pipe, existing high pressure rubber hose braided with steel wire and carbon silica gel high pressure of the invention of Φ 51*4*20 specification
The time that rubber hose braided with steel wire uses under the pressure of 15MPa at different temperatures, such as the following table 2
Table 2
As shown in Table 2, under the high pressure of subzero 30 degree or less 15MPa, General Purpose Rubber pipe and existing high pressure rubber hose braided with steel wire
It is not available, common sebific duct is also subjected to incessantly 15MPa high pressure between subzero 30 degree of subzero, and existing high pressure steel compiles glue
The time that pipe uses is shorter, only to could use the performance for reaching the application for three months or more under room temperature, and the carbon of the application
Plain silica gel high pressure rubber hose braided with steel wire can all be used without husking, bulge or cracking for a long time in subzero 50 to 50 degree above freezing
The phenomenon that.The thermal adaptability of the application is wider, and especially at very low temperature, the oil well conveying for being very suitable to the Northern Hemisphere is high
Press the use of fluid.
Preferably, other components can be added in the mixed component of the application in order to increase the function of the application, such as
In order to further enhance its Antacid effectiveness, can wherein be added mass fraction be 1-2% diatomite, 2-4% zinc oxide and
A small amount of rosin, such as 0.5-1%.Such as in order to further enhance its heat resistance, it is 2-3% that mass fraction can be added wherein
The carbon fiber and a small amount of stearic acid of nm-class active calcium carbonate, 1-2%, such as 0.5-1%.
With the oil well of the present invention matching used water suction hose specification of carbon silica gel high pressure wire braided hose: Φ 102*
8*10；Φ152*10*10；Matching used rubber steam hose specification: Φ 25*8*20；Matching used water-supply-pipe specification: Φ 25*
6*20；Φ32*8*20.
Protection scope of the present invention is not limited to the above embodiments, it is clear that those skilled in the art can be to this hair
It is bright to carry out various changes and deformation without departing from scope and spirit of the present invention.If these changes and deformation belong to power of the present invention
In the range of benefit requirement and its equivalent technologies, then including the intent of the present invention also includes these changes and deforms.
Claims (8)
1. a kind of oil well carbon silica gel high pressure wire braided hose comprising interior sebific duct (1), it is characterised in that: described is interior
Sebific duct mainly by with mass percent be 10-16% carbon, 42-53% silica gel, 12-18% Nano graphite and 22-27% nitrile rubber
Component is constituted；Steel wire organization level (3) are set on the outside of the interior sebific duct, sail is set between the steel wire organization level and interior sebific duct
Layer of cloth (2), the canvas layer is two-sided to be starched brushed with sub- glue is starched and contains bind enhancer in sub- glue, the bind enhancer by
Mass fraction is 20-24 parts of cobaltous octadecanates, 45-60 parts to benzoic acid salt, 4-10 parts of silane coupling agent, 1-5 parts of fatty acid and gypsum
15-22 parts, the canvas layer and steel wire are compiled into and are repeated in three layers or more, gauge of wire 1-2mm, adjacent steel wire
Organization level is wound with opposite repercussion, and the helical angle of winding is 45 degree or so, and the outermost steel wire organization level is externally provided with
Spongy layer (4), spongy layer are tightened by gauze winding, and the spongy layer is externally provided with non-metallic wear resistant layer (5), and non-metallic wear resistant layer is wave
Line pipe is constituted.
2. oil well according to claim 1 carbon silica gel high pressure wire braided hose, it is characterised in that: the canvas
Layer and steel wire organization level are successively preferably provided with four layers.
3. oil well according to claim 1 carbon silica gel high pressure wire braided hose, it is characterised in that: the interior glue
It further include the antioxidant that mass percent is 1-2% anti-aging agent and 2-4% in the component of pipe.
4. oil well according to claim 1 carbon silica gel high pressure wire braided hose, it is characterised in that: the fuse
Main body is mainly by being that 13% carbon, 47% silica gel, 15% Nano graphite and 25% nitrile rubber component are constituted with mass percent.
5. oil well according to claim 1 carbon silica gel high pressure wire braided hose, it is characterised in that: the graphite
Nanometer be nano tube structure, be length be what time the graphite cylinder shape of micron, single layer be six face shape planar structures, diameter
To for nano-scale, draw ratio 1:10.
6. oil well according to claim 1 carbon silica gel high pressure wire braided hose, it is characterised in that: the fuse
It further include mass percent in the component of main body for 1-2% deaeration agent, organosiloxane or polyethers or silicon and ether may be selected in deaeration agent
Graft product.
7. the preparation process of -6 any oil well carbon silica gel high pressure wire braided hoses according to claim 1, special
Sign is: it is comprised the following steps that
It 1) is that 10-16% carbon, 42-53% silica gel, 12-18% Nano graphite and 22-27% nitrile rubber weigh by mass percent
Respective amount is stirred together, is then that 1-2% deaeration agent is kneaded plastic in rubber mixing machine mass percent is wherein added
Piece；
2) film is molded into the sebific duct of various different sizes with bulb-blowing machine, is used as interior sebific duct；
3) by canvas it is two-sided it is inside and outside on cementing machine smear the sub- glue of slurry, be then included outside sebific duct, outside interior sebific duct
Steel wire organization level is constituted with 45 degree of direction winding steel wires, is then repeated in canvas layer and steel wire braid more than three times, and
The adjacent establishment of steel wire twice winding carries out in the opposite direction；
4) molded product of step 3) is put into your primary steam sulfidization molding of vulcanizing tank, vulcanization time is 5-8 hours, curing temperature
It is 200-500 degrees Celsius；
5) vulcanization terminates, and after placing cooling in 1-2 hours, spongy layer is wrapped up on the outside of its finished product, spongy layer is tightened with gauze；
6) bellows is set on the outside again after sponge tightens, and the both ends of bellows or middle section interval 50-100mm are fastened on
On internal sponge layer, and end part seal lives spongy layer.
8. claim 1-6 any oil well carbon silica gel high pressure wire braided hose, can drain on the tank car of oil field makes
Oil well is cleaned using or oil field cleaning vehicle with or oil field steam coach supernatant washing oil wells to use.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022104134A1 (en) * | 2020-11-12 | 2022-05-19 | Brain Drip LLC | Methods and materials for intelligent composite renewal system for standalone, storage, and renewed pipelines, including for reduced carbon emission and for conversion of in place pipelines for conveyance of hydrogen and other clean fuels |
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