CN1104946C - 使吸附剂能够重复使用的吸附剂再生方法 - Google Patents

使吸附剂能够重复使用的吸附剂再生方法 Download PDF

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Publication number
CN1104946C
CN1104946C CN96197493A CN96197493A CN1104946C CN 1104946 C CN1104946 C CN 1104946C CN 96197493 A CN96197493 A CN 96197493A CN 96197493 A CN96197493 A CN 96197493A CN 1104946 C CN1104946 C CN 1104946C
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China
Prior art keywords
cao
ash particles
adsorbent
burner
temperature
Prior art date
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Expired - Lifetime
Application number
CN96197493A
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English (en)
Chinese (zh)
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CN1199353A (zh
Inventor
邱正海
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General Electric Technology GmbH
Original Assignee
Alstom SA
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Publication of CN1199353A publication Critical patent/CN1199353A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/79—Injecting reactants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/002—Supplying water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B01J20/3466—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase with steam
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
    • F23C10/08—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases
    • F23C10/10—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases the separation apparatus being located outside the combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2206/00—Fluidised bed combustion
    • F23C2206/10—Circulating fluidised bed
    • F23C2206/103—Cooling recirculating particles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/20—Sulfur; Compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Treating Waste Gases (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CN96197493A 1995-08-21 1996-07-29 使吸附剂能够重复使用的吸附剂再生方法 Expired - Lifetime CN1104946C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US51748695A 1995-08-21 1995-08-21
US08/517,486 1995-08-21

Publications (2)

Publication Number Publication Date
CN1199353A CN1199353A (zh) 1998-11-18
CN1104946C true CN1104946C (zh) 2003-04-09

Family

ID=24060013

Family Applications (1)

Application Number Title Priority Date Filing Date
CN96197493A Expired - Lifetime CN1104946C (zh) 1995-08-21 1996-07-29 使吸附剂能够重复使用的吸附剂再生方法

Country Status (10)

Country Link
KR (1) KR100312360B1 (fi)
CN (1) CN1104946C (fi)
CA (1) CA2230019C (fi)
CZ (1) CZ51098A3 (fi)
FI (1) FI980394A (fi)
IN (1) IN188644B (fi)
PL (1) PL325057A1 (fi)
SE (1) SE9800396L (fi)
TW (1) TW397706B (fi)
WO (1) WO1997006889A1 (fi)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105745493A (zh) * 2013-12-16 2016-07-06 斗山能捷斯有限责任公司 流化床换热器

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6290921B1 (en) * 1999-11-03 2001-09-18 Foster Wheeler Enegeria Oy Method and apparatus for binding pollutants in flue gas
EP1682264B1 (en) * 2003-11-14 2011-04-20 Her Majesty the Queen in Right of Canada as Represented by The Minister of Natural Resources Pre-treatment of lime-based sorbents using hydration
KR100699519B1 (ko) * 2005-11-15 2007-03-23 한국에너지기술연구원 폐기물과 알피에프 연소 전용 순환유동층 보일러
CA2743911C (en) * 2008-11-19 2016-01-12 The Ohio State University Research Foundation Carbonation calcination reaction process for co2 capture using a highly regenerable sorbent
US9074767B2 (en) 2010-02-11 2015-07-07 Alstom Technology Ltd Rotary bottom ash regeneration system
US9657937B2 (en) * 2010-08-23 2017-05-23 Saudi Arabian Oil Company Steam generation system having multiple combustion chambers and dry flue gas cleaning
FI123704B (fi) 2011-02-04 2013-09-30 Foster Wheeler Energia Oy Menetelmä happipolttokiertoleijupetikattilan käyttämiseksi
SE538327C2 (sv) * 2012-08-31 2016-05-17 Marketing I Konsulting Per Anders Brattemo Förfarande för att rena avgaser
CN103446875B (zh) * 2013-07-29 2016-03-30 浙江大学 循环流化床燃烧系统的脱硫剂强化脱硫的方法及其系统
JP2017120151A (ja) * 2015-12-28 2017-07-06 川崎重工業株式会社 燃焼設備

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4312280A (en) * 1980-03-13 1982-01-26 The United States Of America As Represented By The United States Department Of Energy Method of increasing the sulfation capacity of alkaline earth sorbents
US4872423A (en) * 1987-03-25 1989-10-10 Abb Stal Ab Method for improving utilization of sulphur-absorbent when burning fuel in a fluidized bed and a power plant in which fuel is burned in a fluidized bed

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5345883A (en) * 1992-12-31 1994-09-13 Combustion Engineering, Inc. Reactivation of sorbent in a fluid bed boiler

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4312280A (en) * 1980-03-13 1982-01-26 The United States Of America As Represented By The United States Department Of Energy Method of increasing the sulfation capacity of alkaline earth sorbents
US4872423A (en) * 1987-03-25 1989-10-10 Abb Stal Ab Method for improving utilization of sulphur-absorbent when burning fuel in a fluidized bed and a power plant in which fuel is burned in a fluidized bed

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105745493A (zh) * 2013-12-16 2016-07-06 斗山能捷斯有限责任公司 流化床换热器

Also Published As

Publication number Publication date
CZ51098A3 (cs) 1998-07-15
CA2230019C (en) 2002-01-22
SE9800396D0 (sv) 1998-02-11
KR100312360B1 (ko) 2002-02-28
TW397706B (en) 2000-07-11
CA2230019A1 (en) 1997-02-27
KR19990044099A (ko) 1999-06-25
IN188644B (fi) 2002-10-26
FI980394A0 (fi) 1998-02-20
WO1997006889A1 (en) 1997-02-27
CN1199353A (zh) 1998-11-18
SE9800396L (sv) 1998-02-11
PL325057A1 (en) 1998-07-06
FI980394A (fi) 1998-04-20

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C06 Publication
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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: ALSTOM COMPANY

Free format text: FORMER OWNER: ABB RESEARCH CO.,LTD.

Effective date: 20020411

C41 Transfer of patent application or patent right or utility model
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Address before: Zurich

Applicant before: ABB Research Ltd

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Free format text: FORMER OWNER: ALSTOM

Effective date: 20110815

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

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Address after: Baden, Switzerland

Patentee after: Alstom Technology Ltd.

Address before: France, Paris

Patentee before: Alstom

C56 Change in the name or address of the patentee
CP01 Change in the name or title of a patent holder

Address after: Baden, Switzerland

Patentee after: ALSTOM TECHNOLOGY LTD

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Patentee before: Alstom Technology Ltd.

CX01 Expiry of patent term

Granted publication date: 20030409

EXPY Termination of patent right or utility model