CN110436478A - A kind of lamelliform CHA type SSZ-13 zeolite molecular sieve material and preparation method thereof - Google Patents

Abstract

The present invention provides a kind of preparation methods of lamelliform CHA type SSZ-13 zeolite molecular sieve material, its step includes: that trivalent silicon source, hydroxyl ion source and inorganic cation source are added to N, clear solution is stirred to get in N, N- trimethyl -1- adamantyl Ammonia；Tetravalence silicon source is added in the clear solution and is stirred, deionized water then is added and alcohol source obtains mixed solution；The mixed solution is subjected to crystallization by hydro-thermal reaction in hydrothermal reaction kettle；After crystallization by reaction kettle mixture quenching, be filtered, washed, be dried to obtain crystallization product；The crystallization product is calcined to obtain CHA type SSZ-13 zeolite molecular sieve material.The present invention also provides a kind of lamelliform CHA type SSZ-13 zeolite molecular sieve materials.A kind of lamelliform CHA type SSZ-13 zeolite molecular sieve material provided by the invention and preparation method thereof, production cost is low, suitable for mass production.

Description

A kind of thin layer CHA type SSZ-13 zeolite molecular sieve material and preparation method thereof

technical field

The invention relates to the technical field of zeolite molecular sieve synthesis, in particular to a thin-layer CHA type SSZ-13 zeolite molecular sieve material and a preparation method thereof.

Background technique

In recent studies, the synthesis of zeolite nanosheets to shorten intracatalyst diffusion pathways has received great attention. The size reduction from 3D (micron-sized crystals) to 2D (layered zeolites) can eliminate inaccessible internal regions while maintaining the catalytic activity of pristine zeolites. Therefore, the pores of 2D (layered zeolite) molecular sieves are more open, the specific surface area is larger, and there are more contact acid sites, which is conducive to the diffusion of reactants, reactions and products. New ways, therefore, of zeolite nanosheets and nanowires are very useful industrially.

Invention patent (CN201610915336.X) obtained SAPO-34 molecular sieve with thin-layer flakes by changing the order of adding raw materials and the ratio of silicon to aluminum. Ryoo et al. developed a class of diquaternary ammonium compounds as two-in-one templates, and further synthesized nanosheet zeolites with MFI and BEA topologies (Choi, M. et al. Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts. Nature 461, 246–249(2009).). Wang et al. synthesized layered SAPO-34 zeolite molecular sieves by introducing TPOAC into a conventional synthesis system (Wang, C. et al. Dual template-directed synthesis of SAPO-34 nanosheet assemblies with improved stability in the methanol to olefins reaction. J. Mater. Chem. A 3, 5608–5616(2015)). The molecular sieves synthesized by the above references have achieved breakthroughs in both enhanced catalytic activity and reduced diffusion limitations. However, the key materials they use in the synthesis of molecular sieves are either complex in structure or too expensive to purchase, with high synthesis costs and poor economic benefits, which limits their mass production and is difficult to expand to large-scale industrial applications.

Contents of the invention

The technical problem to be solved by the present invention is to provide a thin-layer CHA type SSZ-13 zeolite molecular sieve material with low production cost and its preparation method.

In order to solve the above-mentioned technical problems, the invention provides a kind of preparation method of thin-layer CHA type SSZ-13 zeolite molecular sieve material, comprising the following steps:

adding trivalent aluminum source, hydroxide ion source and inorganic cation source to N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution and stirring to obtain a clear solution;

adding a tetravalent silicon source to the clarified solution and stirring, then adding deionized water and an alcohol source to obtain a mixed solution;

The mixed solution is crystallized by hydrothermal reaction in a hydrothermal reaction kettle;

After the crystallization is completed, the mixture in the reactor is quenched, filtered, washed, and dried to obtain a crystallized product;

Calcining the crystallized product to obtain a CHA type SSZ-13 zeolite molecular sieve material;

Wherein, the molar ratio of the silicon element in the tetravalent silicon source to the aluminum element in the trivalent aluminum source is 134-50:1;

The molar ratio of the inorganic cation in the inorganic cation source to the silicon element in the tetravalent silicon source is 0.05-0.2:1;

The molar ratio of the alcohol source to the silicon element in the tetravalent silicon source is 0.1-0.4:1;

The mole of silicon element in the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution and the tetravalent silicon source in the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution The ratio is 0.25-0.2:1;

The aluminum element in the trivalent aluminum source is calculated by Al ₂ O ₃ content, and the silicon element in the tetravalent silicon source is calculated by SiO ₂ content.

Further, the tetravalent silicon source is one or more of white carbon black, silica sol or tetraethyl orthosilicate, and the trivalent aluminum source is aluminum isopropoxide, aluminum hydroxide, aluminum nitrate or One or more of aluminum sulfate, the hydroxide ion source is sodium hydroxide or/and potassium hydroxide, and the inorganic cation source is ammonium nitrate, ammonium chloride, potassium hydroxide, sodium hydroxide, chlorine One or more in potassium chloride or sodium chloride, and the alcohol source is one or more in isopropanol, cyclohexanol, glycerol or n-propanol.

Further, the tetravalent silicon source is white carbon black, the trivalent aluminum source is aluminum nitrate and aluminum hydroxide, the inorganic cation source is sodium hydroxide or potassium hydroxide, and the alcohol source is isopropanol or cyclohexanol.

Further, the mass fraction of the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution is 25%.

Further, the reaction temperature of the hydrothermal reaction is 135°C-200°C, and the hydrothermal reaction time is 5-7d.

Further, the reaction temperature of the hydrothermal reaction is 150° C. to 180° C., and the hydrothermal reaction time is 5 days.

Further, the drying of the crystallized product is carried out in a blast drying oven at a drying temperature of 50° C. to 100° C. for 10 to 48 hours.

Further, the drying temperature is 60°C-90°C, and the drying time is 12-40h.

Further, the calcination of the crystallized product is to raise the temperature of the crystallized product from normal temperature to 150°C in flowing air and keep it warm for 1h, then raise the temperature to 580°C at a rate of 1°C/min and keep it warm in air for 12h.

The present invention also provides a thin-layer CHA type SSZ-13 zeolite molecular sieve material, the thin-layer CHA type SSZ-13 zeolite molecular sieve material is a thin-layer sheet CHA type SSZ-13 zeolite molecular sieve material, and the molecular sieve is Composed of a sheet structure with a minimum size of 1-3nm, the thin-layered CHA type SSZ-13 zeolite molecular sieve material has a petal-shaped sheet structure in the form of a scanning electron microscope.

The preparation method of a thin-layered CHA type SSZ-13 zeolite molecular sieve material provided by the present invention uses simple, cheap and easy-to-purchase alcohols as zeolite growth regulators, and does not require secondary surfactants or hard templates. Template, can synthesize thin-layer flake CHA type SSZ-13 zeolite molecular sieve material, the production process is simple, the raw material is cheap and easy to obtain, and the energy consumption is low, the product crystallinity is high, the production cost is low, the economic benefit is good, and it is suitable for mass production , can be extended to large-scale industrial applications. Simultaneously, the CHA type SSZ-13 zeolite molecular sieve material prepared by the preparation method of the thin-layered CHA type SSZ-13 zeolite molecular sieve material provided by the present invention is obtained by adding alcohols to control the morphology of the zeolite, so the present invention A thin-layered CHA-type SSZ-13 zeolite molecular sieve material provided is a thin-layered CHA-type SSZ-13 zeolite molecular sieve, which is composed of a sheet structure with a minimum size of several nanometers (1-3nm). The SEM photo of the scanning electron microscope shows a petal-shaped sheet structure. This thin-layer sheet-like CHA type SSZ-13 zeolite molecular sieve material can shorten the diffusion path and improve the catalytic effect.

Description of drawings

Fig. 1 is the flow chart of the preparation method of a kind of thin layer CHA type SSZ-13 zeolite molecular sieve material that the embodiment of the present invention provides;

Fig. 2 is the XRD spectrogram of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material obtained by the preparation method of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material provided in Example 1 of the present invention;

Fig. 3 is the SEM photo of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material prepared by the preparation method of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material provided in Example 1 of the present invention;

Fig. 4 is the XRD spectrogram of the thin layered CHA type SSZ-13 zeolite molecular sieve material prepared by the preparation method of the CHA type SSZ-13 zeolite molecular sieve material provided in Example 2 of the present invention;

Fig. 5 is the SEM photo of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material prepared by the preparation method of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material provided by Example 2 of the present invention;

6 is the XRD spectrum of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material prepared by the preparation method of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material provided in Example 3 of the present invention;

Fig. 7 is a SEM photo of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material prepared by the preparation method of the thin-layered CHA-type SSZ-13 zeolite molecular sieve material provided in Example 3 of the present invention.

Detailed ways

Referring to Fig. 1, a method for preparing a thin-layered CHA type SSZ-13 zeolite molecular sieve material provided by an embodiment of the present invention includes the following steps:

Step 1) adding trivalent aluminum source, hydroxide ion source and inorganic cation source to N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution and stirring to obtain a clear solution;

Step 2) adding a tetravalent silicon source to the clarified solution and stirring, then adding deionized water and an alcohol source to obtain a mixed solution;

Step 3) crystallizing the mixed solution through a hydrothermal reaction in a hydrothermal reaction kettle;

Step 4) After the crystallization is completed, the mixture in the reactor is quenched, filtered, washed, and dried to obtain a crystallized product;

Step 5) Calcining the crystallized product to obtain a CHA type SSZ-13 zeolite molecular sieve material.

Wherein, the molar ratio of the silicon element in the tetravalent silicon source to the aluminum element in the trivalent aluminum source is 134-50:1;

The molar ratio of the inorganic cation in the inorganic cation source to the silicon element in the tetravalent silicon source is 0.05-0.2:1;

The molar ratio of the alcohol source to the silicon element in the tetravalent silicon source is 0.1-0.4:1;

The mole of silicon element in the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution and the tetravalent silicon source in the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution The ratio is 0.25-0.2:1;

The aluminum element in the trivalent aluminum source is calculated by Al ₂ O ₃ content, and the silicon element in the tetravalent silicon source is calculated by SiO ₂ content.

Wherein, the tetravalent silicon source is one or more of white carbon black, silica sol or tetraethyl orthosilicate, and the trivalent aluminum source is aluminum isopropoxide, aluminum hydroxide, aluminum nitrate or sulfuric acid One or more of aluminum, the hydroxide ion source is sodium hydroxide or potassium hydroxide, and the inorganic cation source is ammonium nitrate, ammonium chloride, potassium hydroxide, sodium hydroxide, potassium chloride or One or more of sodium chloride, and the alcohol source is one or more of isopropanol, cyclohexanol, glycerol or n-propanol.

Wherein, the tetravalent silicon source is white carbon black, the trivalent aluminum source is aluminum nitrate or aluminum hydroxide, the inorganic cation source is sodium hydroxide or potassium hydroxide, and the alcohol source is isopropanol or Cyclohexanol.

Wherein, the mass fraction of the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution is 25%.

Wherein, the reaction temperature of the hydrothermal reaction is 135°C-200°C, and the hydrothermal reaction time is 5-7d.

Wherein, the reaction temperature of the hydrothermal reaction is 150° C. to 180° C., and the hydrothermal reaction time is 5 days.

Wherein, the drying of the crystallized product is carried out in a blast drying oven at a drying temperature of 50° C. to 100° C. for 10 to 48 hours.

Wherein, the drying temperature is 60°C-90°C, and the drying time is 12-40h.

Wherein, the calcination of the crystallization product is to raise the temperature of the crystallization product from normal temperature to 150° C. in flowing air and keep it warm for 1 hour, then raise the temperature to 580° C. at a rate of 1° C./min and hold it in air for 12 hours.

The thin-layer CHA type SSZ-13 zeolite molecular sieve material prepared by the above preparation method in the present invention is a thin-layer sheet CHA type SSZ-13 zeolite molecular sieve material, and the molecular sieve is composed of a sheet structure with a minimum size of 1-3nm Composition, the SEM photo of the thin-layered CHA type SSZ-13 zeolite molecular sieve material shows a petal-shaped sheet structure.

The preparation method of a thin-layered CHA type SSZ-13 zeolite molecular sieve material provided by the present invention will be specifically described below through specific examples.

Example 1

A preparation method of thin-layer CHA type SSZ-13 zeolite molecular sieve material, comprising the following steps:

(1) Add 0.1683g KOH solid and 0.1683g Al(NO ₃ ) ₃ ·9H ₂ O into 3.165g TMAdOH solution (25wt%), and start the magnetic stirrer at 300 rpm until a clear solution is obtained.

(2) Then add 0.9g of white carbon black, and add the white carbon black as the silicon source to the clear solution obtained in the previous step. After adding the silicon source dropwise, it can be observed that the clear liquid in the beaker gradually becomes turbid, accompanied by system viscosity. obvious improvement.

(3) After adding the white carbon black, the plastic beaker was sealed with paraffin film, and the magnetic stirring speed was adjusted to 500 rpm, and stirred at room temperature for 1 hour at this speed. Reduce the rotation speed of the magnetic stirrer to 300 rpm, and slowly add 5.73ml of deionized water and 0.541ml of cyclohexanol dropwise into the system already containing the organic structure directing agent, aluminum source and silicon source with a pipette.

(4) Transfer the above-mentioned mixed solution into a hydrothermal reaction kettle at a hydrothermal reaction temperature of 160° C., and perform a hydrothermal reaction for 4 days;

(5) After the crystallization is completed, take out the reaction kettle and quench it quickly with flowing water, separate the precipitate through filtration, wash with distilled water until the pH value of the filtrate is 6-7, and finally wash with absolute ethanol for 3 times;

(6) Dry the product in a blast drying oven at a drying temperature of 70°C for 24 hours to obtain the product. Calcinate the crystallized product, rapidly raise the temperature from room temperature to 150°C in flowing air and keep it warm for 1 hour, and then heat it at 1°C/min The temperature was raised to 580°C at a certain rate and kept in air for 12 hours to obtain a thin-layered CHA type SSZ-13 zeolite molecular sieve.

The XRD spectrum of the thin-layer CHA type SSZ-13 zeolite molecular sieve of gained is as shown in Figure 2, as can be seen from Figure 2, the XRD spectrum of the thin-layer CHA type SSZ-13 zeolite molecular sieve that the embodiment of the present invention makes It completely corresponds to the standard CHA spectrogram and contains characteristic peaks, indicating that the zeolite synthesized by the embodiment of the present invention is a thin-layer CHA type SSZ-13 zeolite molecular sieve; the SEM photo of the thin-layer CHA type SSZ-13 zeolite molecular sieve as shown in Figure 3 As shown, it can be seen from its SEM photo that the structure of the thin-layered CHA type SSZ-13 zeolite molecular sieve prepared in the embodiment of the present invention is indeed thin-layered.

Example 2

A preparation method of thin-layer CHA type SSZ-13 zeolite molecular sieve material, comprising the following steps:

(1) Add 0.1067g NaOH solid and 0.15g Al(NO ₃ ) ₃ ·9H ₂ O to 2.813g TMAdOH solution (25wt%), and start a magnetic stirrer at 300 rpm until a clear solution is obtained.

(2) Then add 0.8g of white carbon black, and add the white carbon black as the silicon source to the clear solution obtained in the previous step. After adding the silicon source dropwise, it can be observed that the clear liquid in the beaker gradually becomes turbid, accompanied by the viscosity of the system. obvious improvement.

(3) After adding the white carbon black, the plastic beaker was sealed with paraffin film, and the magnetic stirring speed was adjusted to 500 rpm, and stirred at room temperature for 1 hour at this speed. Reduce the rotation speed of the magnetic stirrer to 300 rpm, and slowly add 5.73 ml of deionized water and 0.3961 ml of isopropanol dropwise into the system containing the organic structure directing agent, aluminum source and silicon source with a pipette.

(4) Transfer the above mixed solution into a hydrothermal reaction kettle for 6 days at a hydrothermal reaction temperature of 160°C;

(5) After the crystallization is completed, take out the reaction kettle and quench it quickly with flowing water, separate the precipitate through filtration, wash with distilled water until the pH value of the filtrate is 6-7, and finally wash with absolute ethanol for 3 times;

(6) Dry the product in a blast drying oven at a drying temperature of 70°C for 24 hours to obtain the product. Calcinate the crystallized product, rapidly raise the temperature from room temperature to 150°C in flowing air and keep it warm for 1 hour, and then heat it at 1°C/min The temperature was raised to 580°C at a certain rate and kept in air for 12 hours to obtain a thin-layered CHA type SSZ-13 zeolite molecular sieve.

The XRD spectrum of the thin-layer CHA type SSZ-13 zeolite molecular sieve of gained is as shown in Figure 4, as can be seen from Figure 4, the XRD spectrum of the thin-layer CHA type SSZ-13 zeolite molecular sieve that the embodiment of the present invention makes It completely corresponds to the standard CHA spectrogram and contains characteristic peaks, indicating that the zeolite synthesized by the embodiment of the present invention is a thin-layer CHA type SSZ-13 zeolite molecular sieve; the SEM photo of the thin-layer CHA type SSZ-13 zeolite molecular sieve as shown in Figure 5 As shown, it can be seen from the SEM photos that the structure of the thin-layered CHA type SSZ-13 zeolite molecular sieve prepared in the embodiment of the present invention is indeed thin-layered.

Example 3

A preparation method of thin-layer CHA type SSZ-13 zeolite molecular sieve material, comprising the following steps:

(1) Add 0.08g NaOH solid and 0.0636g Al(OH) ₃ into 1.688g TMAdOH solution (25wt%), and start the magnetic stirrer, set the rotation speed to 300 rpm until a clear solution is obtained.

(2) Then add 0.6g of white carbon black, and add the white carbon black as the silicon source to the clear solution obtained in the previous step. After adding the silicon source dropwise, it can be observed that the clear liquid in the beaker gradually becomes turbid, accompanied by the viscosity of the system. obvious improvement.

(3) After adding the white carbon black, the plastic beaker was sealed with paraffin film, and the magnetic stirring speed was adjusted to 500 rpm, and stirred at room temperature for 1 hour at this speed. Reduce the rotational speed of the magnetic stirrer to 300 rpm, and slowly add 5.934 ml of deionized water and 0.495 ml of cyclohexanol dropwise into the system containing the organic structure directing agent, aluminum source and silicon source with a pipette.

(4) Transfer the above-mentioned mixed solution into a hydrothermal reaction kettle at a hydrothermal reaction temperature of 160° C., and perform a hydrothermal reaction for 5 days;

(5) After the crystallization is completed, take out the reaction kettle and quench it quickly with flowing water, separate the precipitate through filtration, wash with distilled water until the pH value of the filtrate is 6-7, and finally wash with absolute ethanol for 3 times;

(6) Dry the product in a blast drying oven at a drying temperature of 70°C for 24 hours to obtain the product. Calcinate the crystallized product, rapidly raise the temperature from room temperature to 150°C in flowing air and keep it warm for 1 hour, and then heat it at 1°C/min The temperature was raised to 580°C at a certain rate and kept in air for 12 hours to obtain a thin-layered CHA type SSZ-13 zeolite molecular sieve.

The XRD spectrum of the thin-layered CHA type SSZ-13 zeolite molecular sieve obtained is shown in Figure 6, as can be seen from Figure 6, the XRD spectrum of the thin-layered CHA type SSZ-13 zeolite molecular sieve prepared by the embodiment of the present invention It completely corresponds to the standard CHA spectrogram and contains characteristic peaks, indicating that the zeolite synthesized by the embodiment of the present invention is a thin-layer CHA type SSZ-13 zeolite molecular sieve; the SEM photo of the obtained thin-layer CHA type SSZ-13 zeolite molecular sieve is shown in Figure 7 As shown, it can be seen from the SEM photos that the structure of the thin-layered CHA type SSZ-13 zeolite molecular sieve prepared in the embodiment of the present invention is indeed thin-layered.

Finally, it should be noted that the above specific embodiments are only used to illustrate the technical solutions of the present invention without limitation, although the present invention has been described in detail with reference to examples, those of ordinary skill in the art should understand that the technical solutions of the present invention can be carried out Modifications or equivalent replacements without departing from the spirit and scope of the technical solution of the present invention shall be covered by the claims of the present invention.

Claims (10)

1. a preparation method of thin-layered CHA type SSZ-13 zeolite molecular sieve material, is characterized in that, comprises the steps: adding trivalent aluminum source, hydroxide ion source and inorganic cation source to N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution and stirring to obtain a clear solution; adding a tetravalent silicon source to the clarified solution and stirring, then adding deionized water and an alcohol source to obtain a mixed solution; The mixed solution is crystallized by hydrothermal reaction in a hydrothermal reaction kettle; After the crystallization is completed, the mixture in the reactor is quenched, filtered, washed, and dried to obtain a crystallized product; Calcining the crystallized product to obtain a thin-layered CHA type SSZ-13 zeolite molecular sieve material; Wherein, the molar ratio of the silicon element in the tetravalent silicon source to the aluminum element in the trivalent aluminum source is 134-50:1; The molar ratio of the inorganic cation in the inorganic cation source to the silicon element in the tetravalent silicon source is 0.05-0.2:1; The molar ratio of the alcohol source to the silicon element in the tetravalent silicon source is 0.1-0.4:1; The mole of silicon element in the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution and the tetravalent silicon source in the N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution The ratio is 0.25-0.2:1; The aluminum element in the trivalent aluminum source is calculated by Al ₂ O ₃ content, and the silicon element in the tetravalent silicon source is calculated by SiO ₂ content. 2. the preparation method of thin-layered CHA type SSZ-13 zeolite molecular sieve material according to claim 1 is characterized in that: described tetravalent silicon source is white carbon black, silica sol or tetraethyl orthosilicate One or more, the trivalent aluminum source is one or more of aluminum isopropoxide, aluminum hydroxide, aluminum nitrate or aluminum sulfate, and the hydroxide ion source is sodium hydroxide or potassium hydroxide , the inorganic cation source is one or more of ammonium nitrate, ammonium chloride, potassium hydroxide, sodium hydroxide, potassium chloride or sodium chloride, and the alcohol source is isopropanol, cyclohexanol, One or more of glycerol or n-propanol. 3. the preparation method of thin layer CHA type SSZ-13 zeolite molecular sieve material according to claim 2 is characterized in that: described tetravalent silicon source is white carbon black, and described trivalent aluminum source is aluminum nitrate and hydrogen Aluminum oxide, the inorganic cation source is sodium hydroxide or potassium hydroxide, and the alcohol source is isopropanol or cyclohexanol. 4. the preparation method of thin-layered CHA type SSZ-13 zeolite molecular sieve material according to claim 1 is characterized in that: described N,N,N-trimethyl-1-adamantyl ammonium hydroxide solution The mass fraction is 25%. 5. The preparation method of the thin-layered CHA type SSZ-13 zeolite molecular sieve material according to claim 1, characterized in that: the reaction temperature of the hydrothermal reaction is 135°C-200°C, and the hydrothermal reaction time is 5-200°C. 7d. 6 . The preparation method of thin-layered CHA type SSZ-13 zeolite molecular sieve material according to claim 1 , characterized in that: the reaction temperature of the hydrothermal reaction is 150° C. to 180° C., and the hydrothermal reaction time is 5 days. 7. The preparation method of thin-layered CHA type SSZ-13 zeolite molecular sieve material according to claim 1, characterized in that: the drying of the crystallized product is drying at 50°C to 100°C in a blast drying oven. Temperature drying 10 ~ 48h. 8 . The preparation method of the thin-layered CHA type SSZ-13 zeolite molecular sieve material according to claim 1 , characterized in that: the drying temperature is 60° C. to 90° C. and the drying time is 12 to 40 hours. 9. The preparation method of the thin-layered CHA type SSZ-13 zeolite molecular sieve material according to claim 1, characterized in that: the calcination of the crystallized product is to heat up the crystallized product from normal temperature to 150 °C in flowing air. °C and keep it warm for 1h, then raise the temperature to 580°C at a rate of 1°C/min and keep it warm in air for 12h. 10. A thin-layered CHA-type SSZ-13 zeolite molecular sieve material according to any one of claims 1-9, characterized in that: the thin-layered CHA-type SSZ-13 zeolite molecular sieve material is a thin-layered flaky CHA Type SSZ-13 zeolite molecular sieve material, the minimum dimension of the thin layer is 1 nm.