CN110330045A - A method of calcium chloride in recycling permanent violet refined wastewater - Google Patents
A method of calcium chloride in recycling permanent violet refined wastewater Download PDFInfo
- Publication number
- CN110330045A CN110330045A CN201910644001.2A CN201910644001A CN110330045A CN 110330045 A CN110330045 A CN 110330045A CN 201910644001 A CN201910644001 A CN 201910644001A CN 110330045 A CN110330045 A CN 110330045A
- Authority
- CN
- China
- Prior art keywords
- calcium chloride
- permanent violet
- refined wastewater
- recycling
- wastewater
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 title claims abstract description 51
- 229910001628 calcium chloride Inorganic materials 0.000 title claims abstract description 49
- 239000001110 calcium chloride Substances 0.000 title claims abstract description 49
- 239000002351 wastewater Substances 0.000 title claims abstract description 39
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000004064 recycling Methods 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 36
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 230000001105 regulatory effect Effects 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 239000003595 mist Substances 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000004065 wastewater treatment Methods 0.000 abstract description 2
- 238000000746 purification Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000005374 membrane filtration Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000019612 pigmentation Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- BBNQQADTFFCFGB-UHFFFAOYSA-N purpurin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC(O)=C3C(=O)C2=C1 BBNQQADTFFCFGB-UHFFFAOYSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/20—Halides
- C01F11/24—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
The invention discloses a kind of method of calcium chloride in recycling permanent violet refined wastewater, the method for calcium chloride is permanent violet refined wastewater to be cooled to 3 ~ 5 DEG C material a is obtained by filtration in the recycling permanent violet refined wastewater；Material a is regulated and controled to calcium chloride mass percentage concentration and obtains material b for 10 ~ 30%；Material b is carried out to spray-fluidized-bed drying at a temperature of 300 ~ 350 DEG C and obtains object calcium chloride.The present invention effectively realizes wastewater zero discharge, calcium chloride is recycled completely, not only save raw material, reduce cost for wastewater treatment, and calcium chloride circulating repetition is used by carrying out scientific processing to permanent violet refined wastewater.After the present invention can be handled calcium chloride wastewater, anhydrous calcium chloride is obtained, purity can reach 98% or more, and water-insoluble is lower than 0.1%, can meet permanent violet purification and use.
Description
Technical field
The invention belongs to chemical technology fields, and in particular to a method of calcium chloride in recycling permanent violet refined wastewater.
Background technique
Permanent violet crude product is blackish green powdery product, and pigment Violet 23 # product, the production can be obtained after refining pigmentation
There are many ways to product are the organic high-grade pigment of dioxazine, refine pigmentation, one of which be using permanent violet crude product with
Calcium chloride turns crystalline substance by ball mill grinding, and the powder material after grinding cooks iron through peracid, is obtaining face after washing is dry
Expect purple 23# product.A large amount of chloride containing calcium waste water is generated in washing process.Calcium chloride wastewater is evaporated place by factory at present
Reason, remaining calcium chloride waste residue cannot recycle use, therefore urgently develop a kind of method that can solve above-mentioned technical problem.
Summary of the invention
The purpose of the present invention is to provide a kind of methods of calcium chloride in recycling permanent violet refined wastewater.
The object of the present invention is achieved like this, the method for calcium chloride in the recycling permanent violet refined wastewater, including
Following steps:
A, permanent violet refined wastewater is cooled to 3 ~ 5 DEG C and material a is obtained by filtration；
B, material a is regulated and controled to calcium chloride mass percentage concentration and obtains material b for 10 ~ 30%；
C, material b is subjected at a temperature of 300 ~ 350 DEG C spray-fluidized-bed drying and obtains object calcium chloride.
The present invention effectively realizes wastewater zero discharge, by chlorination by carrying out scientific processing to permanent violet refined wastewater
Calcium recycles completely, not only saves raw material, reduces cost for wastewater treatment, and calcium chloride circulating repetition is used.The present invention can be with
After calcium chloride wastewater is handled, anhydrous calcium chloride is obtained, purity can reach 98% or more, and water-insoluble is lower than 0.1%, can meet forever
Gu purpurine system uses.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated, but the present invention is limited in any way,
Based on present invention teach that it is made it is any transform or replace, all belong to the scope of protection of the present invention.
The method of calcium chloride in the recycling permanent violet refined wastewater, comprising the following steps:
A, permanent violet refined wastewater is cooled to 3 ~ 5 DEG C and material a is obtained by filtration；
B, material a is regulated and controled to calcium chloride mass percentage concentration and obtains material b for 10 ~ 30%；
C, material b is subjected at a temperature of 300 ~ 350 DEG C spray-fluidized-bed drying and obtains object calcium chloride.
The pressure filtered in step A is 0.1 ~ 0.5MPa.
Described is filtered into film filtering.
The filter sizes of the film filtering are 0.1 ~ 10.0 μm.
Regulation described in step B is evaporation or plus water.
The evaporation is evaporated when calcium chloride mass percentage concentration is lower than 10 ~ 30% in material a.
The evaporation is evaporated at 80 ~ 95 DEG C of temperature.
Described plus water is to carry out adding water when calcium chloride mass percentage concentration is higher than 10 ~ 30% in material a.
Described plus water is to add deionized water or plus secondary distilled water.
The hot blast temperature of the spray drying is 320 DEG C.
Case is embodied, the present invention will be further described below:
Embodiment 1
1000kg permanent violet fine work is produced, calcium chloride 5000kg is needed, calcium chloride wastewater 25000kg is generated, by being filtered to remove
Water-insoluble, the water-insoluble in waste water are 0.01% hereinafter, permanent violet refined wastewater is cooled to 3 ~ 5 DEG C being with filter sizes
10.0 μm of membrane filtration obtains material a；Material a is evaporated to regulation to calcium chloride mass percentage concentration at 95 DEG C of temperature is
30% obtains material b；By material b pass through spray-fluidized-bed drying device, hot blast temperature be 320 DEG C, 265 DEG C of dry materials final temperature, chlorination
Calcium product water content 0.01%, content 99.2%, reaches using standard.
Embodiment 2
1000kg permanent violet fine work is produced, calcium chloride 5000kg is needed, calcium chloride wastewater 25000kg is generated, by being filtered to remove
Water-insoluble, the water-insoluble in waste water is 0.01% hereinafter, it is 0.1 that permanent violet refined wastewater, which is cooled to 3 DEG C with filter sizes,
μm membrane filtration obtain material a；Add deionized water to regulate and control to calcium chloride mass percentage concentration material a and obtains material for 10%
b；Material b is passed through into spray-fluidized-bed drying device, hot blast temperature is 300 DEG C, and 255 DEG C of dry materials final temperature, calcium chloride product is aqueous
Amount 0.02%, content 99.15% reaches using standard.
Embodiment 3
1000kg permanent violet fine work is produced, calcium chloride 5000kg is needed, calcium chloride wastewater 25000kg is generated, by being filtered to remove
Water-insoluble, the water-insoluble in waste water are 0.01% hereinafter, permanent violet refined wastewater is cooled to 3 ~ 5 DEG C being with filter sizes
5.0 μm of membrane filtration obtains material a；Add secondary distilled water to regulate and control to calcium chloride mass percentage concentration material a to obtain for 20%
Material b；By material b pass through spray-fluidized-bed drying device, hot blast temperature be 350 DEG C, 275 DEG C of dry materials final temperature, calcium chloride product
Water content 0.015%, content 99.1%, reaches using standard.
Claims (10)
1. a kind of method of calcium chloride in recycling permanent violet refined wastewater, it is characterised in that the following steps are included:
A, permanent violet refined wastewater is cooled to 3 ~ 5 DEG C and material a is obtained by filtration；
B, material a is regulated and controled to calcium chloride mass percentage concentration and obtains material b for 10 ~ 30%；
C, material b is subjected at a temperature of 300 ~ 350 DEG C spray-fluidized-bed drying and obtains object calcium chloride.
2. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 1, it is characterised in that mistake in step A
The pressure of filter is 0.1 ~ 0.5MPa.
3. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 2, it is characterised in that the mistake
Filter is that film filters.
4. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 3, it is characterised in that the film
The filter sizes of filtering are 0.1 ~ 10.0 μm.
5. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 1, it is characterised in that institute in step B
The regulation stated is evaporation or plus water.
6. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 5, it is characterised in that the steaming
Hair is evaporated when calcium chloride mass percentage concentration is lower than 10 ~ 30% in material a.
7. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 5 or 6, it is characterised in that described
Evaporation is evaporated at 80 ~ 95 DEG C of temperature.
8. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 5, it is characterised in that described adds
Water is to carry out adding water when calcium chloride mass percentage concentration is higher than 10 ~ 30% in material a.
9. the method for calcium chloride in the recycling permanent violet refined wastewater according to claim 5 or 8, it is characterised in that described
Adding water is to add deionized water or plus secondary distilled water.
10. the method for calcium chloride in recycling permanent violet refined wastewater according to claim 1, it is characterised in that the spray
The dry hot blast temperature of mist is 320 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910644001.2A CN110330045A (en) | 2019-07-17 | 2019-07-17 | A method of calcium chloride in recycling permanent violet refined wastewater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910644001.2A CN110330045A (en) | 2019-07-17 | 2019-07-17 | A method of calcium chloride in recycling permanent violet refined wastewater |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110330045A true CN110330045A (en) | 2019-10-15 |
Family
ID=68145431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910644001.2A Pending CN110330045A (en) | 2019-07-17 | 2019-07-17 | A method of calcium chloride in recycling permanent violet refined wastewater |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110330045A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1240219A (en) * | 1998-06-19 | 2000-01-05 | 科莱恩有限公司 | Novel crystal modification of C.I. pigment red 53:2 (gamma-phase) |
| JP2000248190A (en) * | 1999-03-04 | 2000-09-12 | Dainippon Ink & Chem Inc | Red pigment wet cake composition and lithography ink |
| WO2003059501A1 (en) * | 2001-12-28 | 2003-07-24 | Kaisei Kogyo Co., Ltd. | Apparatus and method for granulating mixed hydrate of calcium chloride and sodium chloride, and granule of the mixed hydrate |
| CN101712661A (en) * | 2009-12-01 | 2010-05-26 | 宁波东港电化有限责任公司 | Method for producing epoxy chloropropane |
| CN102504567A (en) * | 2011-11-01 | 2012-06-20 | 东台市新锦泰化工有限公司 | Environment-friendly production method for permanent violet RL |
| CN103275517A (en) * | 2013-05-27 | 2013-09-04 | 南通龙翔化工有限公司 | Method for effectively recovering grinding medium in pigmentation process |
| CN105858700A (en) * | 2016-04-06 | 2016-08-17 | 王玉平 | Novel production technique for preparing calcium chloride from carbide slag |
| CN107033065A (en) * | 2017-05-04 | 2017-08-11 | 曲靖众合成化工有限公司 | A kind of method that efficient process permanent violet nitrifies waste liquid |
-
2019
- 2019-07-17 CN CN201910644001.2A patent/CN110330045A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1240219A (en) * | 1998-06-19 | 2000-01-05 | 科莱恩有限公司 | Novel crystal modification of C.I. pigment red 53:2 (gamma-phase) |
| JP2000248190A (en) * | 1999-03-04 | 2000-09-12 | Dainippon Ink & Chem Inc | Red pigment wet cake composition and lithography ink |
| WO2003059501A1 (en) * | 2001-12-28 | 2003-07-24 | Kaisei Kogyo Co., Ltd. | Apparatus and method for granulating mixed hydrate of calcium chloride and sodium chloride, and granule of the mixed hydrate |
| CN101712661A (en) * | 2009-12-01 | 2010-05-26 | 宁波东港电化有限责任公司 | Method for producing epoxy chloropropane |
| CN102504567A (en) * | 2011-11-01 | 2012-06-20 | 东台市新锦泰化工有限公司 | Environment-friendly production method for permanent violet RL |
| CN103275517A (en) * | 2013-05-27 | 2013-09-04 | 南通龙翔化工有限公司 | Method for effectively recovering grinding medium in pigmentation process |
| CN105858700A (en) * | 2016-04-06 | 2016-08-17 | 王玉平 | Novel production technique for preparing calcium chloride from carbide slag |
| CN107033065A (en) * | 2017-05-04 | 2017-08-11 | 曲靖众合成化工有限公司 | A kind of method that efficient process permanent violet nitrifies waste liquid |
Non-Patent Citations (2)
| Title |
|---|
| 化学工业部天津化工研究院等: "《化工产品手册 无机化工产品》", 31 October 1993, 化学工业出版社 * |
| 章华正: "酞菁蓝颜料生产中废硫酸的循环利用", 《化工技术经济》 * |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191015 |
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