CN110242973A - A kind of carbon fiber production exhaust-gas treatment pipe-line system - Google Patents

A kind of carbon fiber production exhaust-gas treatment pipe-line system Download PDF

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Publication number
CN110242973A
CN110242973A CN201910510237.7A CN201910510237A CN110242973A CN 110242973 A CN110242973 A CN 110242973A CN 201910510237 A CN201910510237 A CN 201910510237A CN 110242973 A CN110242973 A CN 110242973A
Authority
CN
China
Prior art keywords
exhaust
exhaust gas
pipe
main pipeline
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910510237.7A
Other languages
Chinese (zh)
Inventor
孙兴祥
夏建明
陈文书
孙春根
孔令强
郭建军
傅春盛
李飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Baojing Carbon Material Co ltd
Original Assignee
Zhejiang Jingye Xinxing Material Co Ltd
Zhejiang Jinggong Carbon Fiber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Jingye Xinxing Material Co Ltd, Zhejiang Jinggong Carbon Fiber Co Ltd filed Critical Zhejiang Jingye Xinxing Material Co Ltd
Priority to CN201910510237.7A priority Critical patent/CN110242973A/en
Publication of CN110242973A publication Critical patent/CN110242973A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J11/00Devices for conducting smoke or fumes, e.g. flues 
    • F23J11/02Devices for conducting smoke or fumes, e.g. flues  for conducting smoke or fumes originating from various locations to the outside, e.g. in locomotive sheds, in garages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J13/00Fittings for chimneys or flues 
    • F23J13/02Linings; Jackets; Casings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2213/00Chimneys or flues
    • F23J2213/30Specific materials

Abstract

The present invention relates to a kind of carbon fiber production exhaust-gas treatment pipe-line systems, when being produced using new waste gas provided by the present application processing pipe-line system, the exhaust gas that low temperature carbonization furnace generates is under the negative pressure driving that entire incineration system generates, exhaust pipe I is sequentially entered by Waste gas outlet, exhaust pipe II, exhaust gas main pipeline, in exhaust gas main pipeline, burner ignites exhaust gas, a part of substance burns in exhaust gas, exhaust gas after burning enters burned waste gas system by exhaust pipe III and incineration system connecting tube together with unburned exhaust gas and carries out further burning disposal, atmosphere is discharged into eventually by chimney high-altitude.The good effect of the application is: allowing a part of exhaust gas first to burn in exhaust gas main pipeline, and can realize Hand scarf;It completes that the burning disposal of a part of exhaust gas is reduced the processing pressure of incineration system, plays certain positive effect in terms of improving operating load and environment protection standard before entering incineration system.

Description

A kind of carbon fiber production exhaust-gas treatment pipe-line system
Technical field
The invention belongs to technical field of carbon fiber preparation, the exhaust-gas treatment suitable for carbon fiber production carbonisation.
Background technique
Polyacrylonitrile-based carbon fibre is a kind of artificial synthetic fiber, is passed through by acrylonitrile and itaconic acid or other comonomers The fibrous polymer obtained after the processing of the series of process such as polymerization, spinning, pre-oxidation and carbonization.Polyacrylonitrile-based carbon fibre With high specific strength, high ratio modulus, high temperature resistant, resistant to chemical etching, endurance, heat-resisting, shock resistance, anti-radiation, easy conductive, heat transfer With a series of excellent properties such as specific gravity is small, belong to typical high-performance fiber.In carbon fiber production process, polyacrylonitrile fibril High-temperature heat treatment is carried out by oxidation furnace and carbide furnace, occurs largely to chemically react and produce by-product in heat treatment process, Especially low-temperature carbonization stage, fiber weightlessness under 400-800 DEG C of processing reach 40% or so, generate a large amount of exhaust gas and coke Oil, the exhaust gas that low-temperature carbonization is timely and effectively discharged are low temperature carbonization furnace designs and guarantee stable product quality and stable Key point.
The design of low temperature carbonization furnace is generally equipped with multiple groups Waste gas outlet, low-temperature carbonization in the more violent temperature section of reaction The exhaust gas of generation, which by exhaust piping is connected to waste gas combustion furnace and burn reaching, to be discharged into after discharge standard by chimney high-altitude Atmosphere.The major impetus of low-temperature carbonization exhaust gas discharge derives from the negative pressure draft of incinerator, because there are a considerable amount of in exhaust gas High-molecular weight by-products, the slightly lower tar that will be condensed into of temperature is adhered on exhaust piping, although in exhaust piping design It is pipe insulation to prevent tar from condensing that electrically heat tracing mode, which will be taken, but in the actual production process, with runing time Extension, the waste discharge effect of exhaust piping can worse and worse, and finally resulting in low-temperature carbonization kiln gas can not be discharged, can only shut down into Row pipeline cleaning, often primary cleaning needs 12-18 hours, and under normal duty, general operation is just needed to pipeline for 7-15 days It is once cleared up, biggish economic loss can all be caused to enterprise by shutting down cleaning every time.Meanwhile carbon fiber carbonization device at In Analysis of Nested Design, the processing capacity of burned waste gas system has one to match with design and operation load, once in order to improve equipment operation Efficiency, slightly raising load, will result in incineration system overtemperature, form volume increase bottleneck.
Exhaust-gas treatment in carbon fiber preparation process is as a hot subject in field, about burned waste gas system Correlative study is more, but the transformation of off-gas piping system is rarely reported.
Summary of the invention
It is an object of the invention to solve the tar condensation problem of exhaust piping in carbon fiber production process and solve life Producing line improves the matching problem of incineration system after operating load, provides a kind of novel exhaust-gas treatment pipe-line system;The application can To effectively improve the cycle of operation of carbon fiber production line, it can be achieved that Hand scarf, improves the operational efficiency of device, existing set is solved The matching problem of standby operating load and incineration system.
The purpose of the present invention is achieved through the following technical solutions:
A kind of carbon fiber production exhaust-gas treatment pipe-line system, in order to solve the coke of exhaust piping in carbon fiber production process Oily condensation problem and the matching problem for solving incineration system after production line raising operating load, need exhaust gas being sent into incinerator Before, a degree of burning processing is directly carried out in exhaust piping.
A kind of carbon fiber production exhaust-gas treatment pipe-line system, it includes Waste gas outlet, four-way valve, exhaust pipe I, Triple valve, exhaust pipe II, exhaust gas main pipeline, exhaust pipe III, four-way pipe, incinerator connecting tube, exhaust gas main pipeline are protected Warm liner and burner;
A kind of carbon fiber production is connected to the exhaust gas discharge of low temperature carbonization furnace with exhaust-gas treatment pipe-line system by four-way valve Mouthful, there are blank flanges for one end, are used for Hand scarf Waste gas outlet, and Waste gas outlet is symmetrical arranged in low-temperature carbonization furnace body, General 2-4 group.
Exhaust pipe I is vertical tube, and lower end is connected with Waste gas outlet four-way valve, and upper end is connected with triple valve, and material is 310S is symmetrical arranged, general 2-4 group in low-temperature carbonization furnace body.
Triple valve connects the upper end of exhaust pipe I and one end of exhaust pipe II (transverse tube).
Exhaust pipe II is transverse tube, and one end connects triple valve, and one end connects exhaust gas main pipeline, material 310S, low Temperature carbonization furnace body is symmetrical arranged, general 2-4 group.
Low-temperature carbonization furnace exhaust by exhaust pipe II be sent into exhaust gas main pipeline, material 310S, the one of exhaust gas main pipeline End is equipped with diesel fuel burner, and insulating lining is housed inside exhaust gas main pipeline, and liner material is mullite, exhaust gas main pipeline it is another End is equipped with blind plate, and in carbon fiber production process, the burner and blind plate at exhaust gas main pipeline both ends can dismantle carry out scarfing cinder at any time Operation.
Exhaust gas after the burning of exhaust gas main pipeline part enters exhaust pipe III, and III one end of exhaust pipe connects exhaust gas Main pipeline, one end are connected with four-way pipe, material 310S.
Incinerator connecting tube one end is connected with incineration system, and one end is connected by four-way pipe with exhaust pipe III, material For 310S.There are blind plates at the other both ends of four-way pipe, are convenient to clean operation.
When being produced using new waste gas provided by the invention processing pipe-line system, the exhaust gas of low temperature carbonization furnace generation Under the negative pressure driving that entire incineration system generates, exhaust pipe I, exhaust pipe are sequentially entered by Waste gas outlet II, exhaust gas main pipeline, in exhaust gas main pipeline, burner ignites exhaust gas, and a part of substance burns in exhaust gas, after burning Exhaust gas together with unburned exhaust gas by exhaust pipe III and incineration system connecting tube enter burned waste gas system carry out into The burning disposal of one step is discharged into atmosphere eventually by chimney high-altitude.
Compared with prior art, the positive effect of the present invention is:
It is of the invention to be mainly characterized by allowing a part of exhaust gas first to burn in exhaust gas main pipeline, on the one hand avoid It because tar caused by temperature drop condenses in exhaust gas transmission process, and can realize Hand scarf, reduce because shutting down cleaning bring warp Ji loss;On the other hand it completes to reduce the place of incineration system to the burning disposal of a part of exhaust gas before entering incineration system Pressure is managed, plays certain positive effect in terms of improving operating load and environment protection standard.
Detailed description of the invention
The structural schematic diagram one of Fig. 1 a the application
The structural schematic diagram two of Fig. 1 b the application
The structural schematic diagram three of Fig. 1 c the application;
The label in accompanying drawing is:
1, low temperature carbonization furnace;2, Waste gas outlet four-way valve;3, exhaust pipe I;4, triple valve;5, exhaust pipe Ⅱ;6, exhaust gas main pipeline;7, exhaust pipe III;8, four-way pipe;9, incinerator connecting tube;10, exhaust gas main pipeline insulating lining; 11, burner.
Specific embodiment
A kind of carbon fiber production of the present invention presented below handles the specific embodiment of pipe-line system with new waste gas.
Embodiment 1
Refer to attached drawing 1a, 1b, 1c, a kind of carbon fiber production new waste gas processing pipe-line system, by exhaust gas master It installs burner and insulating lining in pipeline additional, burning disposal is carried out to a part of exhaust gas, system includes: low temperature carbonization furnace 1;Exhaust gas Discharge outlet four-way valve 2, exhaust pipe I 3;Triple valve 4;Exhaust pipe II 5;Exhaust gas main pipeline 6;Exhaust pipe III 7;Four Siphunculus 8;Incinerator connecting tube 9;Exhaust gas main pipeline insulating lining 10;Burner 11.
A kind of carbon fiber production is connected to the exhaust gas discharge of low temperature carbonization furnace with exhaust-gas treatment pipe-line system by four-way valve Mouthful, there are blank flanges for one end, are used for Hand scarf Waste gas outlet, and Waste gas outlet is symmetrical arranged in low-temperature carbonization furnace body, General 2-4 group.
Exhaust pipe I is vertical tube, and lower end is connected with Waste gas outlet four-way valve, and upper end is connected with triple valve, and material is 310S is symmetrical arranged, general 2-4 group in low-temperature carbonization furnace body.
Triple valve connects the upper end of exhaust pipe I and one end of exhaust pipe II (transverse tube).
Exhaust pipe II is transverse tube, and one end connects triple valve, and one end connects exhaust gas main pipeline, material 310S, low Temperature carbonization furnace body is symmetrical arranged, general 2-4 group.
Low-temperature carbonization furnace exhaust by exhaust pipe II be sent into exhaust gas main pipeline, material 310S, the one of exhaust gas main pipeline End is equipped with diesel fuel burner, and insulating lining is housed inside exhaust gas main pipeline, and liner material is mullite, exhaust gas main pipeline it is another End is equipped with blind plate, and in carbon fiber production process, the burner and blind plate at exhaust gas main pipeline both ends can dismantle carry out scarfing cinder at any time Operation.
Exhaust gas after the burning of exhaust gas main pipeline part enters exhaust pipe III, and III one end of exhaust pipe connects exhaust gas Main pipeline, one end are connected with four-way pipe, material 310S.
Incinerator connecting tube one end is connected with incineration system, and one end is connected by four-way pipe with exhaust pipe III, material For 310S.There are blind plates at the other both ends of four-way pipe, are convenient to clean operation.
In production process, the exhaust gas that low temperature carbonization furnace generates is under the negative pressure driving that entire incineration system generates, by useless Gas discharge outlet sequentially enters exhaust pipe I 3, exhaust pipe II 5, exhaust gas main pipeline, and in exhaust gas main pipeline, burner will Exhaust gas ignites, and a part of substance burns in exhaust gas, and HCN concentration reduces 30-50% in exhaust gas, the exhaust gas after burning together with Unburned exhaust gas enters burned waste gas system and is further burned by exhaust pipe III 7 and incineration system connecting tube Processing, is discharged into atmosphere eventually by chimney high-altitude.
Before handling pipe-line system using new waste gas provided by the invention, when production line operation reaches certain load, burn After burning system often causes Concatenate shut-down, new waste gas to handle pipe-line system use due to overtemperature alarm, produce load is improved 30%, incineration system works well, exhaust gas emission compliance.

Claims (6)

1. a kind of carbon fiber production exhaust-gas treatment pipe-line system, which is characterized in that it includes Waste gas outlet, four-way valve gives up Gas delivery pipe I, triple valve, exhaust pipe II, exhaust gas main pipeline, exhaust pipe III, four-way pipe, incinerator connecting tube are given up Gas main pipeline insulating lining and burner;
The Waste gas outlet of low temperature carbonization furnace is connected to by four-way valve, there are blank flanges for one end, and Waste gas outlet is in low temperature The furnace body that is carbonized is symmetrical arranged;
Exhaust pipe I is vertical tube, and lower end is connected with Waste gas outlet four-way valve, and upper end is connected with triple valve, in low-temperature carbonization Furnace body is symmetrical arranged;
Triple valve connects the upper end of exhaust pipe I and one end of exhaust pipe II;
Exhaust pipe II is transverse tube, and one end connects triple valve, and one end connects exhaust gas main pipeline, symmetrically sets in low-temperature carbonization furnace body It sets;
Low-temperature carbonization furnace exhaust is sent into exhaust gas main pipeline by exhaust pipe II, and one end of exhaust gas main pipeline is equipped with diesel combustion Device, exhaust gas main pipeline inside are equipped with insulating lining, and the other end of exhaust gas main pipeline is equipped with blind plate;
Exhaust gas after the burning of exhaust gas main pipeline part enters exhaust pipe III, and III one end of exhaust pipe connects exhaust gas supervisor Road, one end are connected with four-way pipe;
Incinerator connecting tube one end is connected with incineration system, and one end is connected by four-way pipe with exhaust pipe III, four-way pipe In addition there are blind plates at both ends.
2. a kind of carbon fiber production exhaust-gas treatment pipe-line system as described in claim 1, which is characterized in that Waste gas outlet Number 2-4 group.
3. a kind of carbon fiber production exhaust-gas treatment pipe-line system as described in claim 1, which is characterized in that exhaust pipe I number is 2-4 group.
4. a kind of carbon fiber production exhaust-gas treatment pipe-line system as described in claim 1, which is characterized in that exhaust pipe II number is 2-4 group.
5. a kind of carbon fiber production exhaust-gas treatment pipe-line system as described in claim 1, which is characterized in that insulating lining Material is mullite.
6. the production method that exhaust-gas treatment pipe-line system is used in a kind of carbon fiber production as described in claim 1, which is characterized in that The exhaust gas that low temperature carbonization furnace generates sequentially enters exhaust gas by Waste gas outlet under the negative pressure driving that entire incineration system generates Delivery pipe I, exhaust pipe II, exhaust gas main pipeline, in exhaust gas main pipeline, burner ignites exhaust gas, a part of in exhaust gas Substance burns, and the exhaust gas after burning enters together with unburned exhaust gas by exhaust pipe III and incineration system connecting tube Burned waste gas system carries out further burning disposal, is discharged into atmosphere eventually by chimney high-altitude.
CN201910510237.7A 2019-06-13 2019-06-13 A kind of carbon fiber production exhaust-gas treatment pipe-line system Pending CN110242973A (en)

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Application Number Priority Date Filing Date Title
CN201910510237.7A CN110242973A (en) 2019-06-13 2019-06-13 A kind of carbon fiber production exhaust-gas treatment pipe-line system

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110975524A (en) * 2019-12-05 2020-04-10 安徽卓锐三维科技有限公司 Flue gas treatment device for laser printing

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001234434A (en) * 2000-02-24 2001-08-31 Toray Ind Inc Method for producing carbon fiber
CN104342784A (en) * 2013-08-02 2015-02-11 中国石油天然气股份有限公司 A waste gas controlling and discharging method of a low-temperature carbonization furnace during carbon fiber production
US20160039118A1 (en) * 2013-03-28 2016-02-11 Elg Carbon Fibre International Gmbh Pyrolysis system and method of recovering carbon fibres from carbon-fibre-containing plastics
CN107541810A (en) * 2017-09-18 2018-01-05 中安信科技有限公司 The tracing system of carbon fibre carbonizing furnace exhaust pipeline
CN210107429U (en) * 2019-06-13 2020-02-21 浙江精功碳纤维有限公司 Waste gas treatment pipeline device for carbon fiber production

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001234434A (en) * 2000-02-24 2001-08-31 Toray Ind Inc Method for producing carbon fiber
US20160039118A1 (en) * 2013-03-28 2016-02-11 Elg Carbon Fibre International Gmbh Pyrolysis system and method of recovering carbon fibres from carbon-fibre-containing plastics
CN104342784A (en) * 2013-08-02 2015-02-11 中国石油天然气股份有限公司 A waste gas controlling and discharging method of a low-temperature carbonization furnace during carbon fiber production
CN107541810A (en) * 2017-09-18 2018-01-05 中安信科技有限公司 The tracing system of carbon fibre carbonizing furnace exhaust pipeline
CN210107429U (en) * 2019-06-13 2020-02-21 浙江精功碳纤维有限公司 Waste gas treatment pipeline device for carbon fiber production

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110975524A (en) * 2019-12-05 2020-04-10 安徽卓锐三维科技有限公司 Flue gas treatment device for laser printing

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Address after: 312000 91 hills, Binhai Industrial Zone, Keqiao District, Shaoxing, Zhejiang

Applicant after: Zhejiang Baojing carbon material Co.,Ltd.

Applicant after: ZHEJIANG JINGYE XINXING MATERIAL Co.,Ltd.

Address before: 312030 91 hills, Binhai Industrial Zone, Keqiao District, Shaoxing, Zhejiang

Applicant before: ZHEJIANG JINGGONG CARBON FIBER Co.,Ltd.

Applicant before: ZHEJIANG JINGYE XINXING MATERIAL Co.,Ltd.

TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20220705

Address after: 312000 91 hills, Binhai Industrial Zone, Keqiao District, Shaoxing, Zhejiang

Applicant after: Zhejiang Baojing carbon material Co.,Ltd.

Address before: 312000 91 hills, Binhai Industrial Zone, Keqiao District, Shaoxing, Zhejiang

Applicant before: Zhejiang Baojing carbon material Co.,Ltd.

Applicant before: Zhejiang Jingye Xinxing Material Co., Ltd