CN110204234A - A kind of preparation method of the hollow bulky grain material of bivalve layer - Google Patents
A kind of preparation method of the hollow bulky grain material of bivalve layer Download PDFInfo
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- CN110204234A CN110204234A CN201910334195.6A CN201910334195A CN110204234A CN 110204234 A CN110204234 A CN 110204234A CN 201910334195 A CN201910334195 A CN 201910334195A CN 110204234 A CN110204234 A CN 110204234A
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- water
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- bulky grain
- hollow
- absorbing resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/12—Multiple coating or impregnating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F2003/001—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a kind of preparation methods of the hollow bulky grain material of bivalve layer, using can water swelling resin as kernel, the most moisture of resin kernel elder generation pre-absorption, preparation is added with the hypostracum reinforced solution of a small amount of staple fiber, resin kernel for having been approached saturation absorbs, and web is formed in resin core surface, form hypostracum;Using balling technique, on surface, package can form the cementing material of intensity;After material hardening forms intensity, particle again passes by the solution containing penetration material with viscosity, and particle superficies is allowed to form a crust layer;It is conserved by the way of drying, releases the moisture of water-absorbing resin completely, form thermal curing, and formed hollow.The features such as prepared bivalve layer particulate material has good anti-dropping capability, has both specific strength height, and thermal and insulating performance is good, fire resistance is high, crack resistance is good.
Description
Technical field
The invention belongs to environmental treatments, building thermal insulation material field, it can also be used to agricultural ridging material, and in particular to a kind of
The preparation method of the hollow bulky grain material of bivalve layer.
Background technique
In recent years, as global water resources pollution is on the rise, biofilter obtains extensively in the technique of sewage treatment
Using.Haydite is a kind of shaggy porous mass as a kind of filtrate, and microorganism adhesion is good, has certain adsorption energy
Power is used widely in water process as biofilter material and matrix.
There is 103496866 B of patented product CN at present, disclosed hud typed unburned lightweight aggregate is as a kind of unburned pottery
Grain, has been applied, but this hud typed unburned lightweight aggregate toughness is poor in terms of building heat preservation, environmental treatment, in bulk
When with forklift be easily destroyed leak out EPS kernel;If, due to the presence of its kernel, particle overall porosity is lower, mistake as filtrate
Filter ability is inadequate.A kind of slug type light hollow haydite, uses the side of sintering disclosed in 102936127 A of patented product CN
EPS core removal in haydite is reached hollow by formula, but this mode energy consumption for preparing haydite is big, and haydite toughness is poor.
The beautiful China's research of the Huang of Liaoning building Professional School is prepared for a kind of more shell baking-free ceramicites, but this baking-free ceramicite density is larger,
Specific strength is lower, and porosity and water absorption rate are low, if filter capacity is insufficient as biofilter material.
Summary of the invention
In view of the deficiencies of the prior art, the present invention proposes a kind of preparation method of the hollow bulky grain material of bivalve layer, prepared
The bivalve hollow bulky grain material of layer have that crack resistance is high, the high (intensity under unit intensity, i.e., identical close of light weight, specific strength
Under degree, intensity is high;Or under same intensity, density is low), good toughness, the characteristics such as thermal insulation property and fire resistance are good, in particle
Sky, porosity is higher, has good filter capacity.
Technical scheme is as follows:
A kind of preparation method of the hollow bulky grain material of bivalve layer, comprising the following steps:
Step 1) carries out pre- full water process to it using water absorbing resin particle as kernel, water extent control of satisfying 75~
90%;
Step 2) configures hypostracum reinforced solution, is placed in hypostracum for water saturated water-absorbing resin has been inhaled made from step 1)
In reinforced solution, stirring;
Step 3) selects portland cement sill or phosphate cement sill as cementing material, will be through step 2) place
The water-absorbing resin and cementing material of reason wrap up shelling using balling technique;
Step 4) carries out 1~4h of natural curing to the water-absorbing resin of step 3) package shelling obtained;
Step 5) configures outer shell reinforced solution, sprays the outer shell to the step 4) material surface obtained conserved
Reinforced solution;
Step 6) material that handles through step 5) is carried out it is closed, drying maintenance to get.
Preferably, the partial size for having inhaled water saturated water-absorbing resin is 2~7mm.
Preferably, the hypostracum reinforced solution is made of by weight percentage following raw material: 10~30% sodium metasilicate,
0.5~5% silicon dioxide powder, 5~30% industrial starch, 0.5~2% fibrous material, remaining is water.
Preferably, the fibrous material is polypropylene fibre, 2~3mm of length.
Preferably, the outer shell reinforced solution is made of by weight percentage following raw material: 5~20% sodium metasilicate, 0
~3% silicon dioxide powder, remaining is water.
Preferably, the temperature of step 6) the drying maintenance is 100~150 DEG C.
The present invention has the advantage that
(1) combustible material is free of, the fire resistance of aggregate is effectively increased as inner nuclear material using water-absorbing resin.It adopts
It with 100~150 DEG C of drying maintenance method, is on the one hand dehydrated water-absorbing resin kernel, to form hollow structure, reduces close
Degree;On the other hand, internal evaporation water can make Shell Materials form sufficient steam curing, be conducive to improve bulky grain
The specific strength of material.
(2) later period using the solution containing strengthening material as water-absorbing resin adsorbs liquid, and the ratio that aggregate can be improved is strong
Degree is conducive to aggregate early stage transport.
(3) aggregate premature brittle, easily rupturable feature can be obviously improved mixed with fiber in the strengthening material of hypostracum.
(4) outer layer also uses the solution containing strengthening material, and spraying particles or roller coating contain the solution of penetration material, allows particle
Surface forms a crust layer.
(5) kernel is resin, if because the presence of no oxygen, will not burn when high temperature, and melting as building thermal insulation material
When change, then absorption heat is needed to alleviate the rate of propagation of fire to reduce the spread speed of heat.
(6) porosity of the hollow bulky grain material of bivalve layer prepared by the present invention is big, and macroporosity can guarantee good heat preservation
Performance, for being remarkably improved the thermal insulation property of product in insulating product;The water absorption rate of material can also be effectively improved, is absorbed water
For rate through detecting up to 17% or more, drainage capacity is strong.
Detailed description of the invention
Fig. 1 is the preparation method flow chart of the hollow bulky grain material of bivalve layer;
Fig. 2 is the finished figure of the hollow bulky grain material of bivalve layer;
Fig. 3 is the cross-section diagram of the hollow bulky grain material of bivalve layer;
Fig. 4 is the section partial enlarged view of the hollow bulky grain material of bivalve layer.
Specific embodiment
The present invention is further elaborated in the following with reference to the drawings and specific embodiments.
Embodiment 1
A kind of preparation method of the hollow bulky grain material of bivalve layer, preparation process is as shown in Figure 1, selected material and step
It is as follows:
(1) using diameter after water suction is the water-absorbing resin of 6mm as kernel, and water-absorbing resin water conservation extent control exists in advance
75%.
(2) it prepares hypostracum reinforced solution and 2% silicon dioxide powder and 0.5% is added using 30% sodium silicate solution
Polypropylene fibre (2~3mm of length).
(3) water saturated water-absorbing resin will have been inhaled to be placed in hypostracum reinforced solution, has been slowly stirred 1min.
(4) ingredient is used to add 20% miberal powder to add 40% flyash as cementing material for 40% portland cement
(1-1 group);Or the phosphate cement that ingredient is 75% adds 25% flyash as cementing material (1-2 group).
(5) pretreated water-absorbing resin and cementing material are placed in together in pan-pelletizer and wrap up in powder balling-up.
(6) outer shell reinforced solution is prepared, using 5% sodium silicate solution.
(7) by the material natural curing 4h (1-1 group) of balling-up or 1h (1-2 group), the material conserved is placed in rotary drum
In, atomized spray outer shell reinforced solution.
(8) closed, be placed in 110 DEG C of baking ovens conserve to get.
Prepared properties of product are shown in Table 1-1 and 1-2 group in 1.
Embodiment 2
A kind of preparation method of the hollow bulky grain material of bivalve layer, preparation process is as shown in Figure 1, selected material and step
It is as follows:
(1) using diameter after water suction is the water-absorbing resin of 6mm as kernel, and water-absorbing resin water conservation extent control exists in advance
75%.
(2) it prepares hypostracum reinforced solution, using 10% sodium silicate solution, adds 5% technical grade starch and 2%
Polypropylene fibre (2~3mm of length).
(3) water saturated water-absorbing resin will have been inhaled to be placed in hypostracum reinforced solution, has been slowly stirred 1min.
(4) ingredient is used to add 10% flyash-Si sill as cementing material (2-1 for 90% phosphate cement
Group);Or the portland cement that ingredient is 50% adds 50% flyash-Si sill as cementing material (2-2 group).
(5) pretreated water-absorbing resin and cementing material are placed in together in pan-pelletizer and wrap up in powder balling-up.
(6) it prepares outer shell reinforced solution and 3% silicon dioxide powder is added using 20% sodium silicate solution.
(7) by the material natural curing 1h (2-1 group) of balling-up or 4h (2-2 group), good material will have been conserved and be placed in spiral
In conveyer, atomized spray outer shell reinforced solution.
(8) closed, be placed in 110 DEG C of baking ovens conserve to get.
Prepared properties of product are shown in Table 2-1 and 2-2 group in 1.
The performance of the hollow bulky grain material of 1 bivalve of table layer
As shown in Table 1, the hollow bulky grain material of bivalve layer that prepared by success, lighter weight, porosity is big, and water absorption rate is high, filter
Outlet capacity is strong, and has certain intensity, can be applied to biofilter material well.Macroporosity can guarantee good heat insulating ability
Can, for being remarkably improved the thermal insulation property of product in insulating product;The water absorption rate of material, water absorption rate can also be effectively improved
Through detecting up to 17% or more.Finished product is as shown in Figure 2,3, 4.
The above is only a part of implementation method of the invention, it should be pointed out that: for the ordinary skill people of technical field
For member, without departing from the principle of the present invention, several improvements and modifications being expected can also be made, these improvement
It also should be regarded as protection scope of the present invention with retouching.
Claims (6)
1. a kind of preparation method of the hollow bulky grain material of bivalve layer, which comprises the following steps:
Step 1) carries out pre- full water process to it using water absorbing resin particle as kernel, and water extent control of satisfying is 75~90%;
Step 2) configures hypostracum reinforced solution, will step 1) is obtained has inhaled water saturated water-absorbing resin and be placed in hypostracum reinforcing
In solution, stirring;
Step 3) selects portland cement sill or phosphate cement sill as cementing material, will handle through step 2)
Water-absorbing resin and cementing material are using balling technique package shelling;
Step 4) carries out 1~4h of natural curing to the water-absorbing resin of step 3) package shelling obtained;
Step 5) configures outer shell reinforced solution, sprays the outer shell to the step 4) material surface obtained conserved and strengthens
Solution;
Step 6) material that handles through step 5) is carried out it is closed, drying maintenance to get.
2. a kind of preparation method of the hollow bulky grain material of bivalve layer according to claim 1, which is characterized in that described to have inhaled
The partial size of water saturated water-absorbing resin is 2~7mm.
3. a kind of preparation method of the hollow bulky grain material of bivalve layer according to claim 1, which is characterized in that the inner casing
Layer reinforced solution be made of by weight percentage following raw material: 10~30% sodium metasilicate, 0.5~5% silicon dioxide powder, 5
~30% industrial starch, 0.5~2% fibrous material, remaining is water.
4. a kind of preparation method of the hollow bulky grain material of bivalve layer according to claim 3, which is characterized in that the fiber
Material is polypropylene fibre, 2~3mm of length.
5. a kind of preparation method of the hollow bulky grain material of bivalve layer according to claim 1, which is characterized in that the shell
Layer reinforced solution be made of by weight percentage following raw material: 5~20% sodium metasilicate, 0~3% silicon dioxide powder, remaining
For water.
6. a kind of preparation method of the hollow bulky grain material of bivalve layer according to claim 1, which is characterized in that step 6) institute
The temperature for stating drying maintenance is 100~150 DEG C.
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CN201910334195.6A CN110204234B (en) | 2019-04-24 | 2019-04-24 | Preparation method of double-shell hollow large granule material |
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CN201910334195.6A CN110204234B (en) | 2019-04-24 | 2019-04-24 | Preparation method of double-shell hollow large granule material |
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CN110204234A true CN110204234A (en) | 2019-09-06 |
CN110204234B CN110204234B (en) | 2021-10-26 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110683860A (en) * | 2019-11-18 | 2020-01-14 | 萍乡学院 | Ceramic hollow ball with double-shell structure and preparation method thereof |
CN113173722A (en) * | 2021-03-31 | 2021-07-27 | 恒尊集团有限公司 | Sintering-free lightweight aggregate, preparation method thereof and lightweight concrete |
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US20040211338A1 (en) * | 2003-04-25 | 2004-10-28 | Georgia-Pacific Gypsum, Inc. | Fire door core |
CN102492175A (en) * | 2011-11-08 | 2012-06-13 | 中国科学技术大学 | Microcapsule flame-retardant adsorption resin and preparation method thereof, and flame-retardant composite material |
CN103496866A (en) * | 2013-09-23 | 2014-01-08 | 东南大学 | Preparation method of novel core-shell type cement-based high-strength lightweight aggregate |
CN106746813A (en) * | 2016-12-16 | 2017-05-31 | 济南大学 | A kind of hollow light skeletal material and preparation method thereof |
CN107614581A (en) * | 2011-04-13 | 2018-01-19 | 希提米克斯公司 | Lightweight synthesis particle and the method for manufacturing lightweight synthesis particle |
CN108892441A (en) * | 2018-03-26 | 2018-11-27 | 武夷山德邦环保节能设备制造有限公司 | Using hollow concrete ball as functional material permeable terrace construction technique |
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Patent Citations (7)
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CN1332767A (en) * | 1998-11-05 | 2002-01-23 | 三井化学株式会社 | Particle containing crosslinked polyamino acid |
US20040211338A1 (en) * | 2003-04-25 | 2004-10-28 | Georgia-Pacific Gypsum, Inc. | Fire door core |
CN107614581A (en) * | 2011-04-13 | 2018-01-19 | 希提米克斯公司 | Lightweight synthesis particle and the method for manufacturing lightweight synthesis particle |
CN102492175A (en) * | 2011-11-08 | 2012-06-13 | 中国科学技术大学 | Microcapsule flame-retardant adsorption resin and preparation method thereof, and flame-retardant composite material |
CN103496866A (en) * | 2013-09-23 | 2014-01-08 | 东南大学 | Preparation method of novel core-shell type cement-based high-strength lightweight aggregate |
CN106746813A (en) * | 2016-12-16 | 2017-05-31 | 济南大学 | A kind of hollow light skeletal material and preparation method thereof |
CN108892441A (en) * | 2018-03-26 | 2018-11-27 | 武夷山德邦环保节能设备制造有限公司 | Using hollow concrete ball as functional material permeable terrace construction technique |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110683860A (en) * | 2019-11-18 | 2020-01-14 | 萍乡学院 | Ceramic hollow ball with double-shell structure and preparation method thereof |
CN110683860B (en) * | 2019-11-18 | 2021-10-22 | 萍乡学院 | Ceramic hollow ball with double-shell structure and preparation method thereof |
CN113173722A (en) * | 2021-03-31 | 2021-07-27 | 恒尊集团有限公司 | Sintering-free lightweight aggregate, preparation method thereof and lightweight concrete |
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