CN110104874A - A kind of continuous flow wetland type microbiological fuel cell reactor sewage-treatment plant - Google Patents
A kind of continuous flow wetland type microbiological fuel cell reactor sewage-treatment plant Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/16—Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
本发明涉及一种连续流湿地型微生物燃料电池反应器污水处理装置,该装置包括由下至上依次设置的水解酸化池(3),阳极室(6)和人工湿地阴极室,所述的阳极室(6)内填充有厌氧颗粒污泥和颗粒活性炭组成的填料,填料内设有阳极电极(7),所述的人工湿地阴极室内填充有颗粒活性炭,其中设有阴极电极(10),所述的阳极电极(7)与阴极电极(10)通过电阻(13)连接;待处理污水从底部经过水解酸化池(3)水解酸化后进入阳极室(6),发生反应后从顶部流出进入人工湿地阴极室,净化污水的同时产电。与现有技术相比,本发明具有加工工艺简单,使用方法简单,适合各类污水处理使用等优点。
The invention relates to a continuous flow wetland type microbial fuel cell reactor sewage treatment device, which comprises a hydrolytic acidification pool (3), an anode chamber (6) and a constructed wetland cathode chamber arranged sequentially from bottom to top, the anode chamber (6) filled with fillers composed of anaerobic granular sludge and granular activated carbon, the filler is provided with an anode electrode (7), and the cathode chamber of the constructed wetland is filled with granular activated carbon, wherein a cathode electrode (10) is provided. The anode electrode (7) and the cathode electrode (10) are connected through a resistor (13); the sewage to be treated enters the anode chamber (6) after passing through the hydrolysis acidification pool (3) from the bottom, and flows out from the top into the artificial The wetland cathode chamber purifies sewage and generates electricity at the same time. Compared with the prior art, the invention has the advantages of simple processing technology, simple use method, suitable for various sewage treatment and the like.
Description
技术领域technical field
本发明涉及环境工程及水处理工程领域,尤其是涉及一种连续流湿地型微生物燃料电池反应器污水处理装置。The invention relates to the fields of environmental engineering and water treatment engineering, in particular to a continuous flow wetland type microbial fuel cell reactor sewage treatment device.
背景技术Background technique
随着经济和社会的快速发展,解决日益严重的环境污染问题和探寻新的能源是人类社会能够完成可持续发展的两大根本性问题,也是当今世界的两大焦点问题。微生物燃料电池(Microbial Fuel Cell,MFC)技术将这两个问题有效地联系在一起,己引起广泛关注。With the rapid development of economy and society, solving the increasingly serious environmental pollution problem and exploring new energy sources are two fundamental issues for the sustainable development of human society, and they are also two focal issues in the world today. Microbial Fuel Cell (MFC) technology effectively links these two issues together and has attracted widespread attention.
污水中的有机物在产电菌的作用下被分解利用同时产生电能,完成污水处理的同时实现电能的回收。在阳极室中,有机底物在微生物的催化作用下分解为碳氧化物(如CO2)等小分子,同时释放电子和质子。电子通过外电路传递到阴极,质子通过质子交换膜传递到阴极,二者在阴极电极上与电子受体(如O2)结合,发生还原反应(如生成水)。The organic matter in the sewage is decomposed and utilized under the action of the electrogenic bacteria to generate electricity, and the electricity energy is recovered while the sewage treatment is completed. In the anode compartment, organic substrates are decomposed into small molecules such as carbon oxides (such as CO 2 ) under the catalysis of microorganisms, and electrons and protons are released at the same time. The electrons are transferred to the cathode through the external circuit, and the protons are transferred to the cathode through the proton exchange membrane. The two are combined with the electron acceptor (such as O 2 ) on the cathode electrode, and a reduction reaction (such as generating water) occurs.
水污染主要是由人类活动产生的污染物造成,主要包括工业污染源、农业污染源和生活污染源三大部分。人工湿地的投资和运行费用相对较低和易维护,对污水的处理效果好,适用范围广;可缓冲水力负荷和污染负荷的冲击;绿化环境的功能。常规的人工湿地的缺点是占地面积相对较大,大约是传统污水处理工艺的2-3倍左右,容易产生淤积、堵塞等现象。Water pollution is mainly caused by pollutants produced by human activities, mainly including industrial pollution sources, agricultural pollution sources and domestic pollution sources. Constructed wetlands have relatively low investment and operating costs and are easy to maintain. They have good sewage treatment effects and a wide range of applications; they can buffer the impact of hydraulic loads and pollution loads; they have the function of greening the environment. The disadvantage of conventional constructed wetlands is that they occupy a relatively large area, which is about 2-3 times that of traditional sewage treatment processes, and are prone to siltation and blockage.
本发明是在对人工湿地多年研究的基础上,结合MFC技术提出的将人工湿地水质净化与MFC产电合二为一的新探索。在污水治理的同时实现能源化利用,该系统的是一套复合式生态型MFC。The present invention is a new exploration of combining artificial wetland water purification and MFC power generation combined with MFC technology on the basis of many years of research on artificial wetlands. To achieve energy utilization while sewage treatment, the system is a set of composite ecological MFC.
生物阴极型MFC是指用微生物代替Pt等非生物催化剂,实现电子从阴极向最终电子受体传递的微生物燃料电池。好氧生物阴极主要是以氧气、二氧化锰和三价铁等为直接电子受体。厌氧生物阴极型主要是以硝酸盐、硫酸盐、二氧化碳作为终端电子受体。Virdis等采用好氧生物阴极同步实现了废水脱氮与产电,最终脱氮率达到了86.9%以上。高雄英等采用双室MFC反应器,考察了不同初始Cr(VI)浓度下化学阴极与生物阴极MFC的产电及Cr(VI)去除情况。结果表明,在各Cr(VI)浓度梯度(20,28,32,36,40,44mg/L)下生物阴极MFC的产电及Cr(VI)去除性能均较化学阴极MFC更优,生物阴极最大输出电压为180.1mV,是化学阴极的1.3倍。Biocathode MFC refers to a microbial fuel cell in which microorganisms are used instead of non-biological catalysts such as Pt to transfer electrons from the cathode to the final electron acceptor. Aerobic biocathodes mainly use oxygen, manganese dioxide and ferric iron as direct electron acceptors. The anaerobic biological cathode type mainly uses nitrate, sulfate, and carbon dioxide as terminal electron acceptors. Virdis et al. used aerobic bio-cathode to simultaneously realize wastewater denitrification and electricity production, and the final denitrification rate reached more than 86.9%. Gao Xiongying et al. used a double-chamber MFC reactor to investigate the electricity production and Cr(VI) removal of chemical cathode and biocathode MFC at different initial Cr(VI) concentrations. The results showed that the electricity generation and Cr(VI) removal performance of the biocathode MFC were better than those of the chemical cathode MFC under various Cr(VI) concentration gradients (20, 28, 32, 36, 40, 44 mg/L). The maximum output voltage is 180.1mV, which is 1.3 times that of the chemical cathode.
生物阴极不需要昂贵的金属催化剂,阴极微生物能够通过自我繁殖维持稳定的催化能力即提高MFC的稳定性,且微生物在阴极中的新陈代谢会产生有价值的新产物或去除某些污染物,具备替代化学阴极的潜力。The biocathode does not require expensive metal catalysts. The cathode microorganisms can maintain a stable catalytic ability through self-reproduction, which can improve the stability of MFC, and the metabolism of microorganisms in the cathode will produce valuable new products or remove certain pollutants. The potential of chemical cathodes.
本发明是针对现有微生物燃料电池反应器和工艺的不足,对MFC构型和工艺进行了适当的改进和完善,将采用人工湿地型生物阴极的材料选择和优化设计,提高处理效果。The invention aims at the deficiencies of existing microbial fuel cell reactors and processes, and appropriately improves and perfects the MFC configuration and process, adopts the material selection and optimal design of artificial wetland type biological cathodes, and improves the treatment effect.
发明内容Contents of the invention
本发明的目的就是为了克服上述现有技术存在的缺陷而提供一种加工工艺简单,使用方法简单,适合各类污水处理使用的连续流湿地型微生物燃料电池反应器污水处理装置。The object of the present invention is to provide a continuous flow wetland microbial fuel cell reactor sewage treatment device which is simple in processing technology and simple in use method and suitable for various sewage treatment in order to overcome the above-mentioned defects in the prior art.
本发明的目的可以通过以下技术方案来实现:The purpose of the present invention can be achieved through the following technical solutions:
一种连续流湿地型微生物燃料电池反应器污水处理装置,其特征在于,该装置包括由下至上依次设置的水解酸化池,阳极室和人工湿地阴极室,所述的阳极室内填充有厌氧颗粒污泥和颗粒活性炭组成的填料,填料内设有阳极电极,所述的人工湿地阴极室内填充有颗粒活性炭,其中设有阴极电极,所述的阳极电极与阴极电极通过电阻连接;待处理污水从底部经过水解酸化池水解酸化后进入阳极室,发生反应后从顶部流出进入人工湿地阴极室,净化污水的同时产电。A continuous flow wetland type microbial fuel cell reactor sewage treatment device is characterized in that the device includes a hydrolysis acidification tank, an anode chamber and a constructed wetland cathode chamber arranged in sequence from bottom to top, and the anode chamber is filled with anaerobic particles A filler composed of sludge and granular activated carbon, the filler is provided with an anode electrode, and the cathode chamber of the constructed wetland is filled with granular activated carbon, wherein a cathode electrode is provided, and the anode electrode and the cathode electrode are connected through resistance; the sewage to be treated is collected from The bottom enters the anode chamber after being hydrolyzed and acidified by the hydrolytic acidification tank, and flows out from the top into the constructed wetland cathode chamber after the reaction occurs, purifying sewage and generating electricity at the same time.
进一步地,待处理污水通过进水系统输入水解酸化池,进水系统包括进水泵和布水器;所述的布水器由进水管和穿孔板组成,其中进水管连接进水泵,穿孔板设置在水解酸化池底部,污水通过进水泵和进水管输入穿孔板下方,升流通过穿孔板分布后,进入水解酸化池进行水解酸化,将污水中大分子成分分解为小分子成分,利于后续单元处理,提高基质利用效率和缩短MFC启动周期,水解酸化后污水升流进入阳极室。Further, the sewage to be treated is input into the hydrolysis acidification tank through the water inlet system, the water inlet system includes a water inlet pump and a water distributor; the water distributor is composed of a water inlet pipe and a perforated plate, wherein the water inlet pipe is connected to the water inlet pump, and the perforated plate is arranged on At the bottom of the hydrolytic acidification tank, the sewage enters the bottom of the perforated plate through the water inlet pump and the water inlet pipe. After the upflow is distributed through the perforated plate, it enters the hydrolytic acidification tank for hydrolysis and acidification, and the macromolecular components in the sewage are decomposed into small molecular components, which is beneficial to the subsequent unit treatment. Improve the substrate utilization efficiency and shorten the MFC start-up period, and the sewage will flow up into the anode chamber after hydrolysis and acidification.
进一步地,所述的穿孔板上均匀分布有直径为10-15mm的孔,所述的水解酸化池中含有弹性填料。Further, holes with a diameter of 10-15 mm are evenly distributed on the perforated plate, and elastic fillers are contained in the hydrolytic acidification tank.
进一步地,所述的阳极室内下部有填料承托层,上部设有三相分离器,厌氧颗粒污泥和颗粒活性炭置于填料承托层上,所述的三相分离器连接水封罐,水封罐控制三相分离器气室内的压力,使三相分离器处理效率最高,经其处理后悬浮物降低,反应器不需要再设二沉池,水封水压为25-50cm,此室水力停留时间为4-6h,阳极室的混合液经三相分离器进行气液固分离后,厌氧颗粒污泥和颗粒活性炭落回阳极室,水流继续升流进入阴极室。Further, the lower part of the anode chamber has a packing supporting layer, and the upper part is provided with a three-phase separator, anaerobic granular sludge and granular activated carbon are placed on the packing supporting layer, and the three-phase separator is connected to a water-sealed tank, The water-sealed tank controls the pressure in the air chamber of the three-phase separator, so that the treatment efficiency of the three-phase separator is the highest, and the suspended solids are reduced after the treatment. The reactor does not need to set up a secondary settling tank. The hydraulic retention time of the chamber is 4-6h. After the mixed liquid in the anode chamber is separated from the gas-liquid-solid by the three-phase separator, the anaerobic granular sludge and granular activated carbon fall back to the anode chamber, and the water flow continues to rise into the cathode chamber.
进一步地,所述的颗粒活性炭的粒径为3-6mm,厌氧颗粒污泥粒径为3-6mm,两者体积比为1:0.5-2,填料承托层为孔径小于2mm的穿孔不锈钢板或HDPE板。颗粒活性炭的大比表面积利于细菌附着,也利于电子转移。Further, the particle size of the granular activated carbon is 3-6mm, the particle size of the anaerobic granular sludge is 3-6mm, the volume ratio of the two is 1:0.5-2, and the filler supporting layer is perforated stainless steel with a pore size less than 2mm board or HDPE board. The large specific surface area of granular activated carbon is conducive to bacterial attachment and electron transfer.
进一步地,所述的人工湿地阴极室以活性炭为填料,采用填料承托层支撑,人工湿地阴极室上方设有分隔物、植物和出水口,处理后的污水从出水口排出,所述的活性炭粒径为4-8mm,阴极微生物能够通过自我繁殖维持稳定的催化能力即提高MFC的稳定性,且微生物在阴极中的可去除某些污染物,提高出水水质。Further, the cathode chamber of the constructed wetland is filled with activated carbon and supported by a filler supporting layer. There are partitions, plants and water outlets above the cathode chamber of the constructed wetland, and the treated sewage is discharged from the outlet. The activated carbon The particle size is 4-8mm, and the cathode microorganisms can maintain a stable catalytic ability through self-reproduction, which can improve the stability of the MFC, and the microorganisms in the cathode can remove certain pollutants and improve the quality of the effluent.
进一步地,所述的人工湿地阴极室还连接有曝气组件,曝气组件包括曝气机和与其连接的穿孔盘或穿孔管,穿孔盘或穿孔管位于人工湿地阴极室中部,当植物所产氧气不足时,采用曝气机经穿孔盘或穿孔管曝气,气水体积比为3-20:1。Further, the cathode chamber of the constructed wetland is also connected with an aeration assembly, the aeration assembly includes an aerator and a perforated disk or a perforated tube connected thereto, the perforated disk or perforated pipe is located in the middle of the cathode chamber of the constructed wetland, when the plant produces When the oxygen is insufficient, use an aerator to aerate through a perforated plate or a perforated tube, and the air-to-water volume ratio is 3-20:1.
进一步地,所述的分隔物将湿地土壤和植物与人工湿地阴极室内的填料分开;所选择的植物为挺水植物,如芦苇、菖蒲、香蒲或灯芯草等,种植密度10-20株/m2,所选择的分隔物为透水彩条布等。Further, the separator separates the wetland soil and plants from the filler in the cathode chamber of the constructed wetland; the selected plants are emergent plants, such as reeds, calamus, cattails or rushes, etc., and the planting density is 10-20 plants/m 2. The selected separator is water-permeable strip cloth, etc.
进一步地,所述的电阻的电阻值为500-2000Ω,所述的阳极电极和阴极电极所用材料为炭毡。Further, the resistance value of the resistor is 500-2000Ω, and the material used for the anode electrode and the cathode electrode is carbon felt.
进一步地,待处理污水进水COD浓度不高于1500mg/L,如果进水COD浓度高于1500mg/L,该装置前宜进行预处理或采取出水循环,与原水混合稀释后再进入装置,可避免由于浓度过高时厌氧产气量过大及湿地溶解氧不足;Furthermore, the COD concentration of the influent sewage to be treated is not higher than 1500mg/L. If the COD concentration of the influent water is higher than 1500mg/L, it is advisable to carry out pretreatment before the device or adopt the effluent circulation, and mix and dilute with the raw water before entering the device. Avoid excessive anaerobic gas production and insufficient dissolved oxygen in wetlands when the concentration is too high;
所述的污水处理装置的容积负荷率可达0.2-2.0kgCOD/m3.d,产电功率100-600mW/m2。The volume load rate of the sewage treatment device can reach 0.2-2.0kgCOD/m 3 .d, and the power generation power is 100-600mW/m 2 .
与现有技术相比,本发明具有以下优点:Compared with the prior art, the present invention has the following advantages:
(1)本发明区别于其它现有的微生物燃料电池污水处理装置,尤其是明显异于有质子交换膜的两室型微生物燃料电池反应器,本发明为无质子交换膜的,一体式连续流升流式湿地型微生物燃料电池反应器污水处理装置。(1) The present invention is different from other existing microbial fuel cell sewage treatment devices, especially obviously different from the two-chamber microbial fuel cell reactor with proton exchange membrane, the present invention is without proton exchange membrane, integrated continuous flow Upflow wetland type microbial fuel cell reactor sewage treatment device.
(2)进入微生物燃料电池前,先经过水解酸化池水解酸化,将污水中大分子成分分解为小分子成分,利于后续单元处理,可提高基质利用效率和缩短MFC启动周期,其它MFC装置未有该类设置。(2) Before entering the microbial fuel cell, it goes through the hydrolytic acidification tank to decompose the macromolecular components in the sewage into small molecular components, which is beneficial to the subsequent unit treatment, can improve the substrate utilization efficiency and shorten the MFC start-up period, which is not available in other MFC devices This class is set.
(3)阳极反应室水力停留时间为4-6h,小于常规污水处理厌氧反应池8-12h,采用微生物燃料电池技术提高污水处理系统效率和降低投资成本的效果较明显。(3) The hydraulic retention time of the anode reaction chamber is 4-6 hours, which is less than 8-12 hours in the conventional sewage treatment anaerobic reaction tank. The effect of using microbial fuel cell technology to improve the efficiency of the sewage treatment system and reduce the investment cost is more obvious.
(4)阳极室采用厌氧颗粒污泥和颗粒活性炭GAC等填料的混合物,可提高产电微生物含量和提高阳极反应效率,明显区别于其它微生物燃料电池反应器的阳极室。(4) The anode chamber adopts a mixture of anaerobic granular sludge and granular activated carbon GAC and other fillers, which can increase the content of electricity-producing microorganisms and improve the efficiency of the anode reaction, which is obviously different from the anode chamber of other microbial fuel cell reactors.
(5)用分隔物将湿地土壤和植物与阴极室GAC填料等分开,避免了常规人工湿地易堵塞的不足。穿孔管盘/管曝气安装在阴极室的中间高度位置,该设计避免了曝气后氧气对阳极室的影响。(5) The wetland soil and plants are separated from the GAC filler in the cathode chamber with a separator, which avoids the problem of easy blockage of conventional constructed wetlands. The perforated tube coil/tube aeration is installed at the middle height of the cathode chamber, this design avoids the influence of oxygen on the anode chamber after aeration.
附图说明Description of drawings
图1为实施例1中连续流湿地型生物阴极微生物燃料电池反应器污水处理装置的示意图,图中标号所示:Fig. 1 is the schematic diagram of continuous flow wetland type biocathode microbial fuel cell reactor sewage treatment device in embodiment 1, as shown in the label among the figure:
进水泵1,布水器2,水解酸化池3,填料承托层4,取样口5,厌氧颗粒污泥5,阳极室6,阳极电极7,三相分离器8,曝气机9,阴极电极10,分隔物11,植物12,电阻13,水封罐14,出水口15。Inlet pump 1, water distributor 2, hydrolytic acidification tank 3, packing support layer 4, sampling port 5, anaerobic granular sludge 5, anode chamber 6, anode electrode 7, three-phase separator 8, aerator 9, Cathode electrode 10, separator 11, plant 12, resistor 13, water seal tank 14, water outlet 15.
具体实施方式Detailed ways
下面结合附图和具体实施例对本发明进行详细说明。The present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments.
实施例1Example 1
如图1所示,一种连续流湿地型微生物燃料电池反应器污水处理装置,该装置包括由下至上依次设置的水解酸化池(3),阳极室(6)和人工湿地阴极室。As shown in Figure 1, a continuous flow wetland type microbial fuel cell reactor sewage treatment device includes a hydrolytic acidification tank (3), an anode chamber (6) and a constructed wetland cathode chamber arranged in sequence from bottom to top.
待处理污水通过进水系统输入水解酸化池(3),进水系统包括进水泵(1)和布水器(2);所述的布水器(2)由进水管和穿孔板组成,其中进水管连接进水泵(1),穿孔板设置在水解酸化池(3)底部,穿孔板上均匀分布有直径为10mm的孔,所述的水解酸化池(3)中含有弹性填料。污水通过进水泵(1)和进水管输入穿孔板下方,升流通过穿孔板分布后,进入水解酸化池(3)进行水解酸化,将污水中大分子成分分解为小分子成分,水解酸化后污水升流进入阳极室(6)。The sewage to be treated is input into the hydrolysis acidification tank (3) through the water inlet system, the water inlet system includes the water inlet pump (1) and the water distributor (2); the water distributor (2) is composed of the water inlet pipe and the perforated plate, wherein The water pipe is connected to the water inlet pump (1), the perforated plate is arranged at the bottom of the hydrolytic acidification tank (3), and holes with a diameter of 10mm are evenly distributed on the perforated plate, and the hydrolytic acidification tank (3) contains elastic fillers. Sewage enters the bottom of the perforated plate through the water inlet pump (1) and the water inlet pipe. After the upward flow is distributed through the perforated plate, it enters the hydrolysis acidification tank (3) for hydrolysis and acidification, and the macromolecular components in the sewage are decomposed into small molecular components. After hydrolysis and acidification, the sewage Upflow enters the anode chamber (6).
所述的阳极室(6)内填充有厌氧颗粒污泥和颗粒活性炭组成的填料,填料内设有阳极电极(7),阳极室内下部有填料承托层4,上部设有三相分离器8,厌氧颗粒污泥和颗粒活性炭置于填料承托层4上,三相分离器8连接水封罐14,水封罐14控制三相分离器8气室内的压力,水封水压为25cm,颗粒活性炭的粒径为3-4mm,厌氧颗粒污泥粒径为3-4mm,两者体积比为1:2,填料承托层4为孔径小于2mm的穿孔不锈钢板。The anode chamber (6) is filled with fillers composed of anaerobic granular sludge and granular activated carbon, the filler is provided with an anode electrode (7), the lower part of the anode chamber is provided with a filler support layer 4, and the upper part is provided with a three-phase separator 8 , anaerobic granular sludge and granular activated carbon are placed on the packing support layer 4, the three-phase separator 8 is connected to the water-sealed tank 14, and the water-sealed tank 14 controls the pressure in the air chamber of the three-phase separator 8, and the water-sealed water pressure is 25cm , the particle size of granular activated carbon is 3-4mm, the particle size of anaerobic granular sludge is 3-4mm, the volume ratio of the two is 1:2, and the filler support layer 4 is a perforated stainless steel plate with a hole diameter of less than 2mm.
所述的人工湿地阴极室以活性炭为填料,采用填料承托层4支撑,活性炭填料中设有阴极电极(10),人工湿地阴极室上方设有分隔物11、植物12和出水口15,活性炭粒径为4-6mm,人工湿地阴极室还连接有曝气组件,曝气组件包括曝气机9和与其连接的穿孔盘,穿孔盘位于人工湿地阴极室中部,当植物12所产氧气不足时,采用曝气机9经穿孔盘曝气;分隔物11将湿地土壤和植物12与人工湿地阴极室内的填料分开;所选择的植物12为芦苇,种植密度10株/m2,所选择的分隔物为透水彩条布。The cathode chamber of the constructed wetland is filled with activated carbon, supported by a filler support layer 4, a cathode electrode (10) is arranged in the activated carbon filler, a partition 11, a plant 12 and a water outlet 15 are arranged above the cathode chamber of the constructed wetland, and the activated carbon The particle size is 4-6mm, and the cathode chamber of the constructed wetland is also connected with an aeration component, which includes an aerator 9 and a perforated disk connected thereto. The perforated disk is located in the middle of the cathode chamber of the constructed wetland. , the aerator 9 is used to aerate through the perforated plate; the partition 11 separates the wetland soil and the plants 12 from the filler in the cathode chamber of the constructed wetland; the selected plants 12 are reeds, and the planting density is 10 plants/m 2 , the selected partition The object is a transparent watercolor cloth.
所述的阳极电极(7)与阴极电极(10)通过电阻(13)连接;该装置的电阻13的电阻值为500Ω,阳极电极7和阴极电极10所用材料为炭毡。The anode electrode (7) is connected to the cathode electrode (10) through a resistor (13); the resistance value of the resistor 13 of the device is 500Ω, and the material used for the anode electrode 7 and the cathode electrode 10 is carbon felt.
采用上述连续流湿地型微生物燃料电池反应器污水处理装置,处理COD为450mg/L的模拟生活污水,包括以下工艺步骤:Using the above-mentioned continuous flow wetland type microbial fuel cell reactor sewage treatment device to treat simulated domestic sewage with a COD of 450 mg/L includes the following process steps:
1、所处理的污水进水COD浓度为450mg/L,低于1500mg/L,可直接由进水泵1泵入该装置,通过进水管和布水器2进行均匀布水。水温为室温,不需要调控。进入水解酸化池3水解酸化,后污水升流进入阳极室6,进行阳极反应,该室水力停留时间4h;1. The influent COD concentration of the treated sewage is 450mg/L, which is lower than 1500mg/L. It can be directly pumped into the device by the water inlet pump 1, and the water can be evenly distributed through the water inlet pipe and the water distributor 2. The water temperature is room temperature and does not need to be adjusted. After entering the hydrolytic acidification tank 3 for hydrolysis and acidification, the sewage rises and enters the anode chamber 6 for anodic reaction, and the hydraulic retention time of this chamber is 4h;
2、经阳极反应后经三相分离器8进行气液固分离后,水流升流进入人工湿地阴极室,当湿地植物所产氧气不足时,需要采用曝气机9经穿孔盘曝气,气水比为5:1,在曝气、水流及颗粒活性炭间互相搅拌等产生的水力剪切作用下,阴极反应充分;2. After the anode reaction, the gas-liquid-solid separation is carried out by the three-phase separator 8, and the water flow ascends into the cathode chamber of the constructed wetland. When the oxygen produced by the wetland plants is insufficient, it is necessary to use the aerator 9 to aerate through the perforated plate, and the gas The water ratio is 5:1, under the action of hydraulic shear generated by aeration, water flow and granular activated carbon, etc., the cathode reaction is sufficient;
3、由于反应器内生物膜量较高,稳定运行后容积负荷率可达1.2kgCOD/m3.d,比常规活性污泥法负荷高,电阻13为500欧姆的负载,产电功率100-200mW/m2,出水口15出水的COD可降至50mg/L以下。3. Due to the high amount of biofilm in the reactor, the volumetric loading rate can reach 1.2kgCOD/m 3 .d after stable operation, which is higher than the conventional activated sludge method. The resistance 13 is a load of 500 ohms, and the power generation power is 100-200mW /m 2 , the COD of water outlet 15 can be reduced to below 50mg/L.
实施例2Example 2
一种连续流湿地型微生物燃料电池反应器污水处理装置,采用的布水器2穿孔板上均匀分布的孔的直径为12mm,A continuous flow wetland type microbial fuel cell reactor sewage treatment device, the diameter of the uniformly distributed holes on the perforated plate of the water distributor 2 used is 12mm,
其结构同实施例1,阳极室内填充的颗粒活性炭的粒径为4-6mm,厌氧颗粒污泥粒径为4-6mm,两者体积比为1:1,填料承托层4为孔径小于2mm的穿孔HDPE板。水封罐14控制三相分离器8气室内的压力,水封水压为35cm。Its structure is the same as that of Example 1, the particle diameter of the granular activated carbon filled in the anode chamber is 4-6mm, the particle diameter of the anaerobic granular sludge is 4-6mm, the volume ratio of the two is 1:1, and the filler supporting layer 4 has a pore size smaller than 2mm perforated HDPE board. The water seal tank 14 controls the pressure in the air chamber of the three-phase separator 8, and the water seal water pressure is 35cm.
人工湿地阴极室内装填的活性炭粒径为6-8mm,人工湿地阴极室所选择的植物12为菖蒲,种植密度15株/m2。The particle size of the activated carbon filled in the cathode chamber of the constructed wetland is 6-8 mm. The plant 12 selected in the cathode chamber of the constructed wetland is calamus, and the planting density is 15 plants/m 2 .
电阻13的电阻值为1000Ω。其余结构同实施例1。The resistance value of the resistor 13 is 1000Ω. All the other structures are with embodiment 1.
采用上述连续流湿地型微生物燃料电池反应器污水处理装置,处理COD为1200mg/L的模拟工业污水,包括以下工艺步骤:Using the above-mentioned continuous flow wetland type microbial fuel cell reactor sewage treatment device to treat simulated industrial sewage with a COD of 1200mg/L, the following process steps are included:
1、所处理的污水进水COD浓度为1200mg/L,低于1500mg/L,可直接由进水泵1泵入该装置,通过进水管和布水器2进行均匀布水。水温为室温,不需要调控。进入水解酸化池3水解酸化,后污水升流进入阳极室6,进行阳极反应,该室水力停留时间6h;1. The influent COD concentration of the treated sewage is 1200mg/L, which is lower than 1500mg/L. It can be directly pumped into the device by the water inlet pump 1, and the water can be evenly distributed through the water inlet pipe and the water distributor 2. The water temperature is room temperature and does not need to be adjusted. Enter the hydrolytic acidification tank 3 for hydrolysis and acidification, and then the sewage rises and enters the anode chamber 6 for anodic reaction. The hydraulic retention time of this chamber is 6h;
2、经阳极反应后经三相分离器8进行气液固分离后,水流升流进入人工湿地阴极室,当湿地植物所产氧气不足时,需要采用曝气机9经穿孔盘曝气,气水比为15:1,在曝气、水流及颗粒活性炭间互相搅拌等产生的水力剪切作用下,阴极反应充分;2. After the anode reaction, the gas-liquid-solid separation is carried out by the three-phase separator 8, and the water flow ascends into the cathode chamber of the constructed wetland. When the oxygen produced by the wetland plants is insufficient, it is necessary to use the aerator 9 to aerate through the perforated plate, and the gas The water ratio is 15:1, under the action of hydraulic shear generated by aeration, water flow and granular activated carbon, etc., the cathode reaction is sufficient;
3、由于反应器内生物膜量较高,稳定运行后容积负荷率可达1.5kgCOD/m3.d,比常规活性污泥法负荷高,产电功率150-350mW/m2,出水口15出水的COD可降至500mg/L以下。3. Due to the high amount of biofilm in the reactor, the volumetric load rate can reach 1.5kgCOD/m 3 .d after stable operation, which is higher than the load of conventional activated sludge method, the power generation power is 150-350mW/m 2 , and the water outlet is 15 COD can be reduced to below 500mg/L.
实施例3Example 3
一种连续流湿地型微生物燃料电池反应器污水处理装置,采用的布水器2穿孔板上均匀分布的孔的直径为15mm。阳极室内填充的颗粒活性炭的粒径为3-6mm,厌氧颗粒污泥粒径为3-6mm,两者体积比为2:1,水封罐14控制三相分离器8气室内的水封水压为45cm,人工湿地阴极室内填充的活性炭粒径为5-7mm,人工湿地阴极室所选择的植物12为香蒲,种植密度20株/m2。电阻13的电阻值为2000Ω。A continuous flow wetland type microbial fuel cell reactor sewage treatment device, the diameter of the uniformly distributed holes on the perforated plate of the water distributor 2 used is 15mm. The particle size of the granular activated carbon filled in the anode chamber is 3-6mm, the particle size of the anaerobic granular sludge is 3-6mm, the volume ratio of the two is 2:1, and the water seal tank 14 controls the water seal in the air chamber of the three-phase separator 8 The water pressure is 45cm, the particle size of activated carbon filled in the cathode chamber of the constructed wetland is 5-7mm, and the plants 12 selected in the cathode chamber of the constructed wetland are cattails, and the planting density is 20 plants/m 2 . The resistance value of the resistor 13 is 2000Ω.
其余结构同实施例1。All the other structures are with embodiment 1.
采用上述连续流湿地型微生物燃料电池反应器污水处理装置,处理COD为2500mg/L的模拟工业污水,包括以下工艺步骤:Using the above-mentioned continuous flow wetland type microbial fuel cell reactor sewage treatment device to treat simulated industrial sewage with a COD of 2500mg/L, the following process steps are included:
1、所处理的污水进水COD浓度高于1500mg/L,采取出水循环,与原水按3:1混合稀释后用进水泵1泵入该装置进行处理,通过进水管和布水器2进行均匀布水。水温为室温,不需要调控。进入水解酸化池3水解酸化,后污水升流进入阳极室6,进行阳极反应,该室水力停留时间6h;1. The influent COD concentration of the treated sewage is higher than 1500mg/L, and the outlet water is circulated, mixed and diluted with raw water at 3:1, and then pumped into the device with the inlet pump 1 for treatment, and evenly distributed through the inlet pipe and water distributor 2 water. The water temperature is room temperature and does not need to be adjusted. Enter the hydrolytic acidification pool 3 for hydrolysis and acidification, and then the sewage rises and enters the anode chamber 6 for anodic reaction. The hydraulic retention time of this chamber is 6h;
2、经阳极反应后经三相分离器8进行气液固分离后,水流升流进入人工湿地阴极室,当湿地植物所产氧气不足时,需要采用曝气机9经穿孔盘曝气,气水比为20:1,在曝气、水流及颗粒活性炭间互相搅拌等产生的水力剪切作用下,阴极反应充分;2. After the anode reaction, the gas-liquid-solid separation is carried out by the three-phase separator 8, and the water flow ascends into the cathode chamber of the constructed wetland. When the oxygen produced by the wetland plants is insufficient, it is necessary to use the aerator 9 to aerate through the perforated plate, and the gas The water ratio is 20:1, under the action of hydraulic shear generated by aeration, water flow and granular activated carbon, etc., the cathode reaction is sufficient;
3、由于反应器内生物膜量较高,稳定运行后容积负荷率可达1.8kgCOD/m3.d,比常规活性污泥法负荷高,产电功率250-650mW/m2,出水口15出水的COD可降至500mg/L以下。3. Due to the high amount of biofilm in the reactor, the volumetric load rate can reach 1.8kgCOD/m 3 .d after stable operation, which is higher than the load of conventional activated sludge method, the power generation power is 250-650mW/m 2 , and the water outlet is 15 COD can be reduced to below 500mg/L.
实施例4Example 4
一种连续流湿地型微生物燃料电池反应器污水处理装置,采用的布水器2穿孔板上均匀分布的孔的直径为10mm。阳极室内填充的颗粒活性炭的粒径为3-5mm,厌氧颗粒污泥粒径为3-5mm,两者体积比为1:1.5,水封罐14控制三相分离器8气室内的水封水压为50cm,人工湿地阴极室内填充的活性炭粒径为4-6mm,人工湿地阴极室所选择的植物12为灯芯草,种植密度12株/m2。电阻13的电阻值为1500Ω。A continuous flow wetland type microbial fuel cell reactor sewage treatment device, the diameter of the uniformly distributed holes on the perforated plate of the water distributor 2 used is 10mm. The particle size of the granular activated carbon filled in the anode chamber is 3-5mm, the particle size of the anaerobic granular sludge is 3-5mm, the volume ratio of the two is 1:1.5, and the water seal tank 14 controls the water seal in the air chamber of the three-phase separator 8 The water pressure is 50cm, the particle size of the activated carbon filled in the cathode chamber of the constructed wetland is 4-6mm, the plant 12 selected in the cathode chamber of the constructed wetland is rush grass, and the planting density is 12 plants/m 2 . The resistance value of the resistor 13 is 1500Ω.
其余结构同实施例1。All the other structures are with embodiment 1.
采用上述连续流湿地型微生物燃料电池反应器污水处理装置,处理COD为450mg/L的模拟生活污水,包括以下工艺步骤:Using the above-mentioned continuous flow wetland type microbial fuel cell reactor sewage treatment device to treat simulated domestic sewage with a COD of 450 mg/L includes the following process steps:
1、所处理的污水进水COD浓度为450mg/L,低于1500mg/L,可直接由进水泵1泵入该装置,通过进水管和布水器2进行均匀布水。水温为室温,不需要调控。进入水解酸化池3水解酸化,后污水升流进入阳极室6,进行阳极反应,该室水力停留时间5h;1. The influent COD concentration of the treated sewage is 450mg/L, which is lower than 1500mg/L. It can be directly pumped into the device by the water inlet pump 1, and the water can be evenly distributed through the water inlet pipe and the water distributor 2. The water temperature is room temperature and does not need to be adjusted. Enter the hydrolytic acidification pool 3 for hydrolysis and acidification, and then the sewage rises and enters the anode chamber 6 for anodic reaction. The hydraulic retention time of this chamber is 5h;
2、经阳极反应后经三相分离器8进行气液固分离后,水流升流进入人工湿地阴极室,当湿地植物所产氧气不足时,需要采用曝气机9经穿孔管曝气,气水比为3:1,在曝气、水流及颗粒活性炭间互相搅拌等产生的水力剪切作用下,阴极反应充分;2. After the anode reaction, the gas-liquid-solid separation is carried out by the three-phase separator 8, and the water flow ascends into the cathode chamber of the artificial wetland. When the oxygen produced by the wetland plants is insufficient, it is necessary to use the aerator 9 to aerate the air through the perforated tube. The water ratio is 3:1, under the action of hydraulic shear generated by aeration, water flow and granular activated carbon, etc., the cathode reaction is sufficient;
3、由于反应器内生物膜量较高,稳定运行后容积负荷率可达2.0kgCOD/m3.d,比常规活性污泥法负荷高,产电功率400-600mW/m2,出水口15出水的COD可降至50mg/L以下。3. Due to the high amount of biofilm in the reactor, the volumetric load rate can reach 2.0kgCOD/m 3 .d after stable operation, which is higher than the load of conventional activated sludge method. The power generation power is 400-600mW/m 2 , and the water outlet is 15°C. COD can be reduced to below 50mg/L.
以上实施例仅用于说明本发明技术方案,并非是对本发明的限制,本技术领域的普通技术人员在本发明的实质范围内所做的改变、替代、修饰、简化均为等效的变换,都不脱离本发明的宗旨,也应属于本发明的权利要求保护范围。The above embodiments are only used to illustrate the technical solutions of the present invention, and are not intended to limit the present invention. Changes, substitutions, modifications, and simplifications made by those of ordinary skill in the art within the essential scope of the present invention are all equivalent transformations. All of them do not deviate from the gist of the present invention, and should also belong to the protection scope of the claims of the present invention.
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