CN110023275B - 基于有机硫物质的电池 - Google Patents

基于有机硫物质的电池 Download PDF

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Publication number
CN110023275B
CN110023275B CN201780074924.8A CN201780074924A CN110023275B CN 110023275 B CN110023275 B CN 110023275B CN 201780074924 A CN201780074924 A CN 201780074924A CN 110023275 B CN110023275 B CN 110023275B
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organic
organic moiety
battery
lithium
organosulfur
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Chinese (zh)
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CN110023275A (zh
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G·S·史密斯
L·王
G·C·福特曼
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Arkema Inc
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Arkema Inc
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Priority claimed from US15/367,379 external-priority patent/US10243237B2/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
    • C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
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    • H—ELECTRICITY
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    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/446—Composite material consisting of a mixture of organic and inorganic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/30—Batteries in portable systems, e.g. mobile phone, laptop
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0085—Immobilising or gelification of electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Cell Separators (AREA)
CN201780074924.8A 2016-12-02 2017-12-01 基于有机硫物质的电池 Active CN110023275B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US15/367,379 2016-12-02
US15/367,379 US10243237B2 (en) 2012-04-13 2016-12-02 Battery based on organosulfur species
PCT/US2017/064185 WO2018102667A1 (en) 2016-12-02 2017-12-01 Battery based on organosulfur species

Publications (2)

Publication Number Publication Date
CN110023275A CN110023275A (zh) 2019-07-16
CN110023275B true CN110023275B (zh) 2022-11-29

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EP (1) EP3548459A4 (https=)
JP (1) JP2020501314A (https=)
KR (1) KR102600942B1 (https=)
CN (1) CN110023275B (https=)
BR (1) BR112019011107B1 (https=)
CA (1) CA3045463A1 (https=)
RU (1) RU2755479C2 (https=)
SG (1) SG10202006657SA (https=)
WO (1) WO2018102667A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109704302B (zh) * 2018-12-03 2020-12-04 江苏理工学院 一种磷掺杂多孔碳材料及其制备和在锂硫电池用涂层隔膜中的应用
CN109698331B (zh) * 2018-12-11 2021-04-23 温州大学 锂硫电池中亚硫酸盐/碳管载硫复合正极材料的制备方法
CN113054250B (zh) * 2019-12-27 2023-03-10 张家港市国泰华荣化工新材料有限公司 一种电解液及锂离子电池
KR102893454B1 (ko) * 2021-01-07 2025-12-02 주식회사 엘지에너지솔루션 리튬 이차전지용 전해액 및 이를 포함하는 리튬 이차전지
CN114597347A (zh) * 2022-03-15 2022-06-07 清华大学深圳国际研究生院 固态锂硫电池正极及制备方法、固态锂硫电池及制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1159253A (zh) * 1994-07-28 1997-09-10 波利普拉斯电池有限公司 采用有机硫/金属电荷转移材料作为正电极的二次电池
JP2003514356A (ja) * 1999-11-12 2003-04-15 モルテック・コーポレーション リチウムバッテリー
CN1595712A (zh) * 2003-09-05 2005-03-16 三星Sdi株式会社 有机电解质溶液和含有该溶液的锂－硫电池
JP2005108724A (ja) * 2003-09-30 2005-04-21 Sanyo Electric Co Ltd 非水電解質二次電池
CN104221196A (zh) * 2012-04-13 2014-12-17 阿科玛股份有限公司 基于有机硫物种的电池

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US4472489A (en) * 1983-11-30 1984-09-18 Allied Corporation Polymeric electrode coated with reaction product or organosulfur compound
US4833048A (en) * 1988-03-31 1989-05-23 The United States Of America As Represented By The United States Department Of Energy Metal-sulfur type cell having improved positive electrode
JP3102880B2 (ja) * 1989-10-13 2000-10-23 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 固体金属−硫黄セル
JPH0636797A (ja) * 1992-07-15 1994-02-10 Fuji Photo Film Co Ltd リチウム二次電池
JP4114259B2 (ja) * 1999-01-26 2008-07-09 宇部興産株式会社 リチウム二次電池用電解液およびそれを用いたリチウム二次電池
JP4304570B2 (ja) * 2002-06-28 2009-07-29 日本電気株式会社 非水電解液およびそれを用いた二次電池
KR100450208B1 (ko) * 2002-09-23 2004-09-24 삼성에스디아이 주식회사 리튬 전지용 음극 및 이를 포함하는 리튬 전지
KR100472513B1 (ko) * 2002-11-16 2005-03-11 삼성에스디아이 주식회사 리튬 설퍼 전지용 유기 전해액 및 이를 채용한 리튬 설퍼전지
KR100508923B1 (ko) * 2003-06-27 2005-08-17 삼성에스디아이 주식회사 비수성 전해질 및 이를 포함하는 리튬 이차 전지
WO2005092847A1 (en) * 2004-03-29 2005-10-06 Fuji Photo Film Co., Ltd. Dendron and dendrimer, method of producing the same, and method of producing a thioacetal compound

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1159253A (zh) * 1994-07-28 1997-09-10 波利普拉斯电池有限公司 采用有机硫/金属电荷转移材料作为正电极的二次电池
JP2003514356A (ja) * 1999-11-12 2003-04-15 モルテック・コーポレーション リチウムバッテリー
CN1595712A (zh) * 2003-09-05 2005-03-16 三星Sdi株式会社 有机电解质溶液和含有该溶液的锂－硫电池
JP2005108724A (ja) * 2003-09-30 2005-04-21 Sanyo Electric Co Ltd 非水電解質二次電池
CN104221196A (zh) * 2012-04-13 2014-12-17 阿科玛股份有限公司 基于有机硫物种的电池

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Publication number Publication date
EP3548459A1 (en) 2019-10-09
KR20190083672A (ko) 2019-07-12
KR102600942B1 (ko) 2023-11-14
WO2018102667A1 (en) 2018-06-07
RU2019120395A (ru) 2021-01-11
SG10202006657SA (en) 2020-08-28
EP3548459A4 (en) 2020-07-22
BR112019011107A2 (pt) 2019-10-08
BR112019011107B1 (pt) 2022-08-30
CA3045463A1 (en) 2018-06-07
JP2020501314A (ja) 2020-01-16
CN110023275A (zh) 2019-07-16
RU2755479C2 (ru) 2021-09-16
RU2019120395A3 (https=) 2021-07-22

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