CN109881772B - A beam-column slab house structure system - Google Patents
A beam-column slab house structure system Download PDFInfo
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- CN109881772B CN109881772B CN201910225784.0A CN201910225784A CN109881772B CN 109881772 B CN109881772 B CN 109881772B CN 201910225784 A CN201910225784 A CN 201910225784A CN 109881772 B CN109881772 B CN 109881772B
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- 229940033123 tannic acid Drugs 0.000 claims description 22
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- 239000002356 single layer Substances 0.000 claims description 15
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- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 10
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- 229910052943 magnesium sulfate Inorganic materials 0.000 claims 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims 3
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- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B9/00—Magnesium cements or similar cements
- C04B9/04—Magnesium cements containing sulfates, nitrates, phosphates or fluorides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B9/00—Magnesium cements or similar cements
- C04B9/20—Manufacture, e.g. preparing the batches
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/38—Connections for building structures in general
- E04B1/61—Connections for building structures in general of slab-shaped building elements with each other
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/04—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Civil Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Finishing Walls (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开一种无梁柱板式房屋结构体系,包括内墙拼板、外墙拼板和楼板,所述内墙拼板、所述外墙拼板和所述楼板均为镁基水泥发泡板;在所述内墙拼板与所述外墙拼板的交接处,所述内墙拼板嵌入到所述外墙拼板内或所述外墙拼板嵌入到所述内墙拼板内或所述内墙拼板与所述外墙拼板一体成型;相邻所述楼板交接处的嵌缝内填充有镁基水泥纤维材料,所述镁基水泥纤维材料将相邻所述楼板粘结起来。本发明无需浇筑梁柱,不仅节省大量工时,缩短施工期,而且便于对建材的回收,减少建筑拆除过程中建筑垃圾产生量,有利于环保。
The invention discloses a beam-and-column-slab type house structure system, comprising an interior wall panel, an outer wall panel and a floor slab, wherein the inner wall panel, the outer wall panel and the floor slab are all magnesium-based cement foaming At the junction of the inner wall panel and the outer wall panel, the inner wall panel is embedded in the outer wall panel or the outer wall panel is embedded in the inner wall panel The inner or the inner wall panel and the outer wall panel are integrally formed; the caulking at the junction of the adjacent floor slabs is filled with magnesium-based cement fiber material, and the magnesium-based cement fiber material will be adjacent to the floor slab. stick together. The invention does not need to cast beams and columns, not only saves a lot of man-hours, shortens the construction period, but also facilitates the recovery of building materials, reduces the amount of construction waste generated in the process of building demolition, and is beneficial to environmental protection.
Description
本申请是发明创造名称为“一种无梁柱板式房屋结构体系”、申请日为2016年11月17日、申请号为201611052272.1的分案申请。This application is a divisional application with an invention-creation title of "a beam-column-free slab-type house structure system", an application date of November 17, 2016, and an application number of 201611052272.1.
技术领域technical field
本发明涉及建筑领域,更具体地,涉及一种无梁柱板式房屋结构体系。The invention relates to the field of construction, and more particularly, to a structural system of a beam-column-slab type house.
背景技术Background technique
现有房屋多采用梁柱式房屋结构,而梁柱均需要通过现场浇筑,需要消耗大量的工时,延长了施工期,而且也不便于对建材的回收利用,在对房屋进行拆除的时候会产生大量的建筑垃圾,不利于环保。而采用无梁柱的房屋结构,需要墙体具有良好的支撑性,而楼板需要在具备一定的抗弯强度和抗折强度的前提下具有较小的质量,但现有无梁柱的房屋结构由于墙板的支撑性较差以及楼板的质量较大而多为平房或二层楼房结构,无法构建三层或三层以上的楼房结构,不能提高土地的有效利用率。Existing houses mostly use beam-and-column structure, and the beams and columns need to be poured on site, which consumes a lot of man-hours, prolongs the construction period, and is inconvenient for the recycling of building materials. Construction waste is not conducive to environmental protection. However, the house structure without beams and columns requires the walls to have good support, while the floor slabs need to have a small mass under the premise of having a certain flexural strength and flexural strength, but the existing house structures without beams and columns Due to the poor supportability of the wall panels and the high quality of the floor slabs, most of them are bungalows or two-story building structures, it is impossible to build a building structure with three or more floors, and the effective utilization of land cannot be improved.
发明内容SUMMARY OF THE INVENTION
有鉴于此,本发明目的在于是提供一种无需浇筑梁柱的无梁柱板式房屋结构体系,不仅节省大量工时,缩短施工期,而且便于对建材的回收,减少建筑拆除过程中建筑垃圾产生量,有利于环保。In view of this, the purpose of the present invention is to provide a beam-column-free slab house structure system that does not need to cast beams and columns, which not only saves a lot of man-hours, shortens the construction period, but also facilitates the recovery of building materials and reduces the amount of construction waste generated in the process of building demolition. , is conducive to environmental protection.
为达到上述目的,本发明采用下述技术方案:To achieve the above object, the present invention adopts the following technical solutions:
一种无梁柱板式房屋结构体系,包括内墙拼板、外墙拼板和楼板,所述内墙拼板、所述外墙拼板和所述楼板均为镁基水泥发泡板;在所述内墙拼板与所述外墙拼板的交接处,所述内墙拼板嵌入到所述外墙拼板内或所述外墙拼板嵌入到所述内墙拼板内或所述内墙拼板与所述外墙拼板一体成型;相邻所述楼板交接处的嵌缝内填充有镁基水泥纤维材料,所述镁基水泥纤维材料将相邻所述楼板粘结起来。A beam-column slab-type house structure system, comprising an interior wall panel, an outer wall panel and a floor slab, wherein the inner wall panel, the outer wall panel and the floor slab are all magnesium-based cement foam boards; At the junction of the inner wall panel and the outer wall panel, the inner wall panel is embedded in the outer wall panel or the outer wall panel is embedded in the inner wall panel or any The inner wall panel and the outer wall panel are integrally formed; the caulking at the junction of the adjacent floor panels is filled with magnesium-based cement fiber material, and the magnesium-based cement fiber material bonds the adjacent floor panels together .
上述无梁柱板式房屋结构体系,相邻所述外墙拼板的交接处的外表面上覆盖有纤维布。In the above-mentioned non-beam-column-panel type house structure system, the outer surface of the junction of the adjacent outer wall panels is covered with fiber cloth.
上述无梁柱板式房屋结构体系,所述内墙拼板和所述外墙拼板均为单层墙板;在所述楼板与所述外墙拼板的交接处,所述楼板伸入到所述外墙拼板内,并且所述楼板外侧端面的外侧设置有外墙补板,所述外墙补板嵌在所述外墙拼板内,并且所述外墙补板的外表面与所述外墙拼板的外立面平齐,所述外墙补板也为镁基水泥发泡板。In the above-mentioned non-beam-column panel house structure system, the inner wall panel and the outer wall panel are both single-layer wall panels; at the junction of the floor panel and the outer wall panel, the floor panel extends into the Inside the outer wall panel, and the outer side of the outer end face of the floor slab is provided with an outer wall patch panel, the outer wall patch panel is embedded in the outer wall panel, and the outer surface of the outer wall patch panel is connected to the outer wall panel. The outer facade of the outer wall panel is flush, and the outer wall patch panel is also a magnesium-based cement foam board.
上述无梁柱板式房屋结构体系,所述内墙拼板和所述外墙拼板均由单个镁基水泥发泡板粘结连接而成;In the above-mentioned non-beam-column-slab type house structure system, the inner wall panel and the outer wall panel are formed by bonding and connecting a single magnesium-based cement foam panel;
在所述内墙拼板与所述外墙拼板的交接处:所述内墙拼板嵌入到所述外墙拼板的相邻两个单个镁基水泥发泡板之间,并且所述内墙拼板的外侧端面与所述外墙拼板的外立面平齐;或者设置有T型节点、所述T型节点包括纵向板以及设置在所述纵向板外侧面上的横立板,所述横立板的板面与所述外墙拼板的外表面平齐,所述纵向板的板面与所述内墙拼板的板面平齐;或者设置有T型节点组,所述T型节点组由T型节点组成,所述T型节点包括纵向板以及设置在所述纵向板外侧面上的横立板,所述横立板的板面与所述外墙拼板的外表面平齐,所述纵向板的板面与所述内墙拼板的板面平齐,上下相邻的所述T型节点的横立板横向相错,使得相隔一个所述横立板的两个所述横立板之间形成容纳所述外墙拼板的凹槽,上下相邻的所述纵向板长度不同,使得相隔一个所述纵向板的两个所述纵向板之间形成容纳所述内墙拼板的凹槽;At the junction of the inner wall panel and the outer wall panel: the inner wall panel is embedded between two adjacent single magnesium-based cement foam panels of the outer wall panel, and the The outer end face of the inner wall panel is flush with the outer façade of the outer wall panel; or a T-shaped node is provided, and the T-shaped node includes a longitudinal plate and a horizontal vertical plate arranged on the outer side of the longitudinal panel. , the panel surface of the horizontal vertical panel is flush with the outer surface of the outer wall panel, and the panel surface of the longitudinal panel is flush with the panel surface of the inner wall panel; or a T-shaped node group is provided, The T-shaped node group is composed of T-shaped nodes, and the T-shaped nodes include a longitudinal plate and a horizontal vertical plate arranged on the outer side of the vertical plate, and the plate surface of the horizontal vertical plate is assembled with the outer wall. The outer surface of the vertical board is flush with the board surface of the inner wall panel, and the horizontal vertical boards of the T-shaped nodes adjacent to the top and bottom are horizontally staggered, so that one horizontal vertical board is separated from each other. A groove for accommodating the outer wall panels is formed between the two horizontal vertical panels of the panel, and the lengths of the longitudinal panels adjacent to the top and bottom are different, so that the two longitudinal panels are separated by one longitudinal panel. forming a groove for accommodating the interior wall panels;
在所述外墙拼板(200)的交接处:任意一个所述外墙拼板的端面与另一个所述外墙拼板(200)的墙面平齐,或者设置有L型节点单元。At the junction of the exterior wall panels (200): the end face of any one of the exterior wall panels is flush with the wall surface of the other exterior wall panel (200), or an L-shaped node unit is provided.
上述无梁柱板式房屋结构体系,所述镁基水泥发泡板是利用如下重量份数的原料经发泡工艺制成:镁质盐水泥40-65份、稳泡剂1-3份和发泡剂3-5份;The above-mentioned non-beam-column slab-type house structure system, the magnesium-based cement foam board is made by using the following raw materials in parts by weight through a foaming process: 40-65 parts of magnesia salt cement, 1-3 parts of foam stabilizer and foam. 3-5 parts of foaming agent;
所述镁质盐水泥的制备方法如下:将100-200目的MgO、100-200目的MgSO4和H2O三者按照物质的量之比为(7-12):1:(20-28)混合,然后加入诱导剂,诱导剂的加入量为MgO、MgSO4和H2O三者总质量的0.5-3wt%,搅拌24小时以上,干燥,研磨,过200目筛后即得镁质盐水泥。The preparation method of the magnesia salt cement is as follows: the ratio of 100-200 mesh MgO, 100-200 mesh MgSO 4 and H 2 O is (7-12):1:(20-28) according to the amount of matter Mix, then add inducer, the amount of inducer is 0.5-3wt% of the total mass of MgO, MgSO 4 and H 2 O, stir for more than 24 hours, dry, grind, pass through a 200-mesh sieve to obtain magnesium salt cement.
上述无梁柱板式房屋结构体系,所述诱导剂的制备方法如下:将200-400目的滑石粉加入到醋丙乳液中,滑石粉与醋丙乳液的质量比为(8-15):(20-30),搅拌,加热至60-80℃并保持2-5小时,过滤烘干;在得到的固体产物中加入鞣酸水溶液,鞣酸水溶液中鞣酸的质量分数为5-10wt%,固体产物与鞣酸水溶液的质量比为1:(20-30),加热至90-100℃并保持5-10小时,过滤烘干并粉碎,过100目筛即得诱导剂。In the above-mentioned non-beam-column slab house structure system, the preparation method of the inducer is as follows: 200-400 mesh talcum powder is added to the acetic acid acrylic emulsion, and the mass ratio of the talc powder to the acetic acid acrylic emulsion is (8-15): (20 -30), stirred, heated to 60-80° C. and kept for 2-5 hours, filtered and dried; an aqueous tannic acid solution was added to the obtained solid product, and the mass fraction of tannic acid in the aqueous tannic acid solution was 5-10 wt %, and the solid The mass ratio of the product to the tannic acid aqueous solution is 1:(20-30), heated to 90-100° C. and kept for 5-10 hours, filtered, dried and pulverized, and passed through a 100-mesh sieve to obtain the inducer.
上述无梁柱板式房屋结构体系,所述诱导剂由A组分和B组分组成,A组分的制备方法如下:将200-400目的滑石粉加入到醋丙乳液中,滑石粉与醋丙乳液的质量比为(8-15):(20-30),搅拌,加热至60-80℃并保持2-5小时,过滤烘干;将得到的固体产物中加入到鞣酸水溶液中,鞣酸水溶液中鞣酸的质量分数为5-10wt%,固体产物与鞣酸水溶液的质量比为1:(20-30),加热至90-100℃并保持5-10小时,过滤烘干并粉碎,过100目筛即得A组分;B组分的制备方法如下:将200-400目粉煤灰的加入到三乙醇胺水溶液中,三乙醇胺水溶液中三乙醇胺的质量分数为3-5wt%,粉煤灰与三乙醇胺水溶液的质量比为1:(10-20),搅拌,加热至50-70℃并保持12-24小时,过滤烘干;将得到的固体产物加入到硅烷偶联剂溶液中,固体产物与硅烷偶联剂溶液的质量比为1:(5-20),硅烷偶联剂溶液中硅烷偶联剂的质量分数为10-15wt%,过滤烘干并粉碎,过100目筛即得B组分;In the above-mentioned non-beam-column slab house structure system, the inducer is composed of A component and B component, and the preparation method of A component is as follows: 200-400 mesh talcum powder is added to the acetone emulsion, and the talc powder and the acetonitrile The mass ratio of the emulsion is (8-15): (20-30), stirred, heated to 60-80 ° C and kept for 2-5 hours, filtered and dried; The mass fraction of tannic acid in the acid aqueous solution is 5-10wt%, the mass ratio of the solid product to the tannic acid aqueous solution is 1:(20-30), heated to 90-100 ° C and kept for 5-10 hours, filtered, dried and pulverized , and pass through a 100-mesh sieve to obtain component A; the preparation method of component B is as follows: adding 200-400 mesh fly ash to the triethanolamine aqueous solution, the mass fraction of triethanolamine in the triethanolamine aqueous solution is 3-5wt%, The mass ratio of fly ash to triethanolamine aqueous solution is 1:(10-20), stir, heat to 50-70 ° C and keep for 12-24 hours, filter and dry; add the obtained solid product to the silane coupling agent solution , the mass ratio of the solid product to the silane coupling agent solution is 1:(5-20), the mass fraction of the silane coupling agent in the silane coupling agent solution is 10-15 wt%, filter, dry and pulverize, pass 100 mesh Sieve to get B component;
先加入A组分,A组分的加入量为MgO、MgSO4和H2O三者总质量的0.5-1wt%,搅拌24小时以上;然后再加入B组分,B组分的加入量为MgO、MgSO4和H2O三者总质量的1-2wt%,搅拌24小时以上。First add component A, the amount of component A is 0.5-1wt% of the total mass of MgO, MgSO 4 and H 2 O, and stir for more than 24 hours; then add component B, and the amount of component B added is 1-2 wt% of the total mass of MgO, MgSO 4 and H 2 O, and stir for more than 24 hours.
上述无梁柱板式房屋结构体系,所述镁基水泥发泡板是利用如下重量份数的原料经发泡工艺制成:镁质盐水泥40-65份、前处理后的粉煤灰、稳泡剂1-3份和发泡剂3-5份,前处理后的粉煤灰的加入量为镁质盐水泥制备时所用MgO质量的10-50wt%;The above-mentioned non-beam-column slab-type house structure system, the magnesium-based cement foam board is made by using the following raw materials in parts by weight through a foaming process: 40-65 parts of magnesium salt cement, pre-treated fly ash, stable 1-3 parts of foaming agent and 3-5 parts of foaming agent, the added amount of fly ash after pretreatment is 10-50wt% of the mass of MgO used in the preparation of magnesia salt cement;
所述镁质盐水泥的制备方法如下:将100-200目的MgO、100-200目的MgSO4和H2O三者按照物质的量之比为(7-12):1:(20-28)混合,然后加入诱导剂,诱导剂的加入量为MgO、MgSO4和H2O三者总质量的0.5-3wt%,搅拌24小时以上,干燥,研磨,过200目筛后即得镁质盐水泥;所述诱导剂由A组分和B组分组成,A组分的制备方法如下:将200-400目的滑石粉加入到醋丙乳液中,滑石粉与醋丙乳液的质量比为(8-15):(20-30),搅拌,加热至60-80℃并保持2-5小时,过滤烘干;将得到的固体产物中加入到鞣酸水溶液中,鞣酸水溶液中鞣酸的质量分数为5-10wt%,固体产物与鞣酸水溶液的质量比为1:(20-30),加热至90-100℃并保持5-10小时,过滤烘干并粉碎,过100目筛即得A组分;B组分的制备方法如下:将200-400目粉煤灰的加入到三乙醇胺水溶液中,三乙醇胺水溶液中三乙醇胺的质量分数为3-5wt%,粉煤灰与三乙醇胺水溶液的质量比为1:(10-20),搅拌,加热至50-70℃并保持12-24小时,过滤烘干;将得到的固体产物加入到硅烷偶联剂溶液中,固体产物与硅烷偶联剂溶液的质量比为1:(5-15),硅烷偶联剂溶液中硅烷偶联剂的质量分数为10-15wt%,过滤烘干并粉碎,过100目筛即得B组分;诱导剂加入方法如下:先加入A组分,A组分的加入量为MgO、MgSO4和H2O三者总质量的0.5-1wt%,搅拌24小时以上;然后再加入B组分,B组分的加入量为MgO、MgSO4和H2O三者总质量的1-2wt%,搅拌24小时以上;The preparation method of the magnesia salt cement is as follows: the ratio of 100-200 mesh MgO, 100-200 mesh MgSO 4 and H 2 O is (7-12):1:(20-28) according to the amount of matter Mix, then add inducer, the amount of inducer is 0.5-3wt% of the total mass of MgO, MgSO 4 and H 2 O, stir for more than 24 hours, dry, grind, pass through a 200-mesh sieve to obtain magnesium salt Cement; Described inducer is made up of A component and B component, and the preparation method of A component is as follows: 200-400 purpose talc is added in vinegar-acrylic emulsion, and the mass ratio of talc and vinegar-acrylic emulsion is (8 -15): (20-30), stir, be heated to 60-80 ℃ and keep 2-5 hours, filter and dry; Join in the tannic acid aqueous solution in the solid product obtained, the quality of tannic acid in the tannic acid aqueous solution The fraction is 5-10wt%, the mass ratio of the solid product to the tannic acid aqueous solution is 1:(20-30), heated to 90-100 ° C and kept for 5-10 hours, filtered, dried and pulverized, and passed through a 100-mesh sieve to get The preparation method of component A; component B is as follows: adding 200-400 mesh fly ash into the triethanolamine aqueous solution, the mass fraction of triethanolamine in the triethanolamine aqueous solution is 3-5wt%, the fly ash and the triethanolamine aqueous solution The mass ratio is 1:(10-20), stirred, heated to 50-70 ° C and kept for 12-24 hours, filtered and dried; the obtained solid product was added to the silane coupling agent solution, and the solid product and the silane coupling agent The mass ratio of the coupling agent solution is 1:(5-15), the mass fraction of the silane coupling agent in the silane coupling agent solution is 10-15 wt%, filter, dry and pulverize, and pass through a 100-mesh sieve to obtain component B; The adding method of the inducer is as follows: first add component A, the amount of component A is 0.5-1wt% of the total mass of MgO, MgSO 4 and H 2 O, and stir for more than 24 hours; then add component B, B The added amount of the components is 1-2wt% of the total mass of MgO, MgSO 4 and H 2 O, and the mixture is stirred for more than 24 hours;
前处理后的粉煤灰的制备方法如下:将200-400目粉煤灰的加入到三乙醇胺水溶液中,三乙醇胺水溶液中三乙醇胺的质量分数为3-5wt%,粉煤灰与三乙醇胺水溶液的质量比为1:(10-20),搅拌,加热至50-70℃并保持12-24小时,过滤烘干;将得到的固体产物加入到硅烷偶联剂溶液中,固体产物与硅烷偶联剂溶液的质量比为1:(5-20),硅烷偶联剂溶液中硅烷偶联剂的质量分数为10-15wt%,过滤烘干并粉碎,过100目筛即得前处理后的粉煤灰。The preparation method of the pretreated fly ash is as follows: adding 200-400 mesh fly ash into the triethanolamine aqueous solution, the mass fraction of triethanolamine in the triethanolamine aqueous solution is 3-5 wt%, the fly ash and the triethanolamine aqueous solution The mass ratio is 1:(10-20), stirred, heated to 50-70 ° C and kept for 12-24 hours, filtered and dried; the obtained solid product was added to the silane coupling agent solution, and the solid product and the silane coupling agent The mass ratio of the coupling agent solution is 1: (5-20), the mass fraction of the silane coupling agent in the silane coupling agent solution is 10-15 wt%, filter, dry and pulverize, and pass through a 100-mesh sieve to obtain the pretreated fly ash.
本发明的有益效果如下:The beneficial effects of the present invention are as follows:
1.本发明中的无梁柱板式房屋结构体系所用镁基水泥发泡板的制备路线简单,利用工业废弃的硫酸生产镁质盐水泥,减少或完全不使用硅酸盐水泥,节能环保利废,所需原料廉价易得,产品具有较低的生产成本;1. The preparation route of the magnesium-based cement foam board used in the non-beam-column-slab-type house structure system in the present invention is simple, utilizes industrially discarded sulfuric acid to produce magnesium salt cement, reduces or does not use Portland cement at all, saves energy, protects the environment, and uses waste , the required raw materials are cheap and easy to obtain, and the product has a lower production cost;
2.本发明中的无梁柱板式房屋结构体系重量轻强度高,可以作为多层房屋内、外承重墙及隔墙,并且自重小,抗震性能好;2. The beam-column slab house structure system of the present invention is light in weight and high in strength, can be used as inner and outer load-bearing walls and partition walls of multi-storey houses, and has small self-weight and good seismic performance;
3.本发明中的无梁柱板式房屋结构体系的导热系数小,热容量大,抗冲击性能好,保温隔热隔音效果好;3. The beam-column-slab type house structure system of the present invention has small thermal conductivity, large heat capacity, good impact resistance, and good thermal insulation and sound insulation effects;
4.本发明中的无梁柱板式房屋结构体系强度高,抗冲击性和抗裂性高,可直接在表面做粉刷涂层或粘挂装饰板,装饰一体化程度高;4. The beam-column-slab type house structure system of the present invention has high strength, high impact resistance and crack resistance, and can be directly painted on the surface or adhered to decorative boards, and the degree of integration of decoration is high;
5.本发明的无梁柱板式房屋结构体系,工业化程度高,工程预制,现场组装,施工速度快,板材可加工性好,可锯、可钉;密度小,不需要大型吊装机械,施工现场排放少。5. The beam-column-slab plate house structure system of the present invention has a high degree of industrialization, engineering prefabrication, on-site assembly, fast construction speed, good plate machinability, can be sawed and nailed; low density, no need for large-scale lifting machinery, construction site Low emissions.
7.本发明采用无梁柱结构,节省了梁柱浇筑增加的工时,缩短了施工期,而且减少了建筑拆除时产生的建筑垃圾,同时便于对建筑材料(本发明中的外墙板、内墙板和楼板)的回收利用,有利于环保。7. The present invention adopts a beam-and-column structure, which saves the man-hours for beam-column pouring, shortens the construction period, and reduces the construction waste generated when the building is demolished. The recycling of wall panels and floor slabs) is conducive to environmental protection.
附图说明Description of drawings
图1为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的外部结构示意图;Fig. 1 is the exterior structure schematic diagram that the exterior wall panel and the interior wall panel of the non-beam-column panel house structure system of the present invention are single-layer wall panels;
图2为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的内部结构示意图;Fig. 2 is a schematic diagram of the internal structure of the single-layer wall panel that the exterior wall panel and the interior wall panel of the non-beam-column panel house structure system of the present invention are both;
图3为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的外部墙角处结构示意图;Fig. 3 is the structural schematic diagram at the outer corner of the single-layer wall panel that the outer wall panel and the inner wall panel of the beam-column panel house structure system of the present invention are both;
图4为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的楼板与外墙拼板的连接结构示意图;Fig. 4 is the connection structure schematic diagram of the floor slab and the outer wall assembling of the single-layer wall panel of the exterior wall panel and the interior wall panel of the beam-column panel house structure system of the present invention;
图5为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的楼板与楼板之间粘结连接结构示意图;5 is a schematic diagram of the bonding connection structure between the floor slabs and the floor slabs of the single-layer wall slabs of the exterior wall panel and the interior wall panel of the beam-column panel house structural system of the present invention;
图6为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的外墙拼板和内墙拼板交接处外侧的结构示意图;6 is a structural schematic diagram of the outside of the junction of the outer wall panel and the inner wall panel of the beam-column panel house structural system of the present invention, both of which are single-layer wall panels;
图7为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的外墙拼板和内墙拼板交接处内侧的结构示意图;7 is a structural schematic diagram of the inner side of the junction of the outer wall panel and the inner wall panel of the beam-column panel house structural system of the present invention, both of which are single-layer wall panels;
图8为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的T型节点组的结构示意图;8 is a schematic structural diagram of a T-shaped node group in which both the exterior wall panel and the interior wall panel of the beam-column panel house structural system of the present invention are single-layer wall panels;
图9为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的一种T型节点A的结构示意图;9 is a schematic structural diagram of a T-shaped node A in which the exterior wall panel and the interior wall panel of the beam-column panel house structural system of the present invention are both single-layer wall panels;
图10为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的另一种T型节点B的结构示意图;10 is a schematic structural diagram of another T-shaped node B in which the outer wall panel and the inner wall panel of the beam-column panel house structural system of the present invention are both single-layer wall panels;
图11为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的外墙拼板交接处的结构示意图;Fig. 11 is the structural schematic diagram of the junction of the outer wall panel and the inner wall panel of the beam-column panel house structure system of the present invention, both of which are single-layer wall panels;
图12为本发明无梁柱板式房屋结构体系的外墙拼板和内墙拼板均为单层墙板的L型节点单元C的结构示意图。12 is a schematic structural diagram of an L-shaped node unit C in which the exterior wall panel and the interior wall panel of the beam-column panel house structural system of the present invention are both single-layer wall panels.
图中:100-内墙拼板;200-外墙拼板;300-楼板;400-镁基水泥纤维材料;500-纤维布;600-单个镁基水泥发泡板;700-外墙补板;800-T型墙节点;801-纵向基板;802-横立条板一;803-横立条板二;900-T型节点;901-纵向板;902-横立板;903-凹槽;904-L型节点单元;1000-T型节点组。In the picture: 100-interior wall panel; 200-exterior wall panel; 300-floor slab; 400-magnesium-based cement fiber material; 500-fiber cloth; 600-single magnesium-based cement foam board; 700-exterior wall patch panel ;800-T-type wall joint; 801-longitudinal base plate; 802-horizontal vertical strip plate one; 803-horizontal vertical strip plate two; 900-T type joint; 901-longitudinal plate; 902-horizontal vertical plate; ; 904-L node unit; 1000-T node group.
具体实施方式Detailed ways
为了更清楚地说明本发明,下面结合优选实施例和附图对本发明做进一步的说明。附图中相似的部件以相同的附图标记进行表示。本领域技术人员应当理解,下面所具体描述的内容是说明性的而非限制性的,不应以此限制本发明的保护范围。In order to illustrate the present invention more clearly, the present invention will be further described below with reference to the preferred embodiments and accompanying drawings. Similar parts in the figures are denoted by the same reference numerals. Those skilled in the art should understand that the content specifically described below is illustrative rather than restrictive, and should not limit the protection scope of the present invention.
实施例6和实施例7中的镁基水泥发泡板制备方法如下:The preparation method of the magnesium-based cement foam board in Example 6 and Example 7 is as follows:
实施例1Example 1
(a)制备发泡水泥(a) Preparation of foamed cement
镁质盐水泥65千克、稳泡剂3千克和发泡剂5千克,按照水灰比0.45加水,搅拌制成发泡水泥浆液。所述稳泡剂为硅酮酰胺;所述发泡剂为十二烷基硫酸钠。65 kg of magnesia salt cement, 3 kg of foam stabilizer and 5 kg of foaming agent, add water according to the water-cement ratio of 0.45, and stir to make foamed cement slurry. The foam stabilizer is silicone amide; the foaming agent is sodium lauryl sulfate.
所述镁质盐水泥的制备方法如下:将100-200目的MgO、100-200目的MgSO4和H2O三者按照物质的量之比为9:1:25混合,然后加入诱导剂,诱导剂的加入量为MgO、MgSO4和H2O三者总质量的1wt%,搅拌24小时以上,干燥,研磨,过200目筛后即得镁质盐水泥。The preparation method of the magnesia salt cement is as follows: 100-200 mesh MgO, 100-200 mesh MgSO 4 and H 2 O are mixed according to the substance amount ratio of 9:1:25, and then an inducer is added to induce The added amount of the agent is 1 wt % of the total mass of MgO, MgSO 4 and H 2 O, stirred for more than 24 hours, dried, ground, and passed through a 200-mesh sieve to obtain magnesia salt cement.
所述诱导剂的制备方法如下:将200-400目的滑石粉加入到醋丙乳液中,滑石粉与醋丙乳液的质量比为15:22,搅拌,加热至80℃并保持5小时,过滤烘干;在得到的固体产物中加入鞣酸水溶液,鞣酸水溶液中鞣酸的质量分数为8wt%,固体产物与鞣酸水溶液的质量比为1:20,加热至90℃并保持10小时,过滤烘干并粉碎,过100目筛即得诱导剂。The preparation method of the inducer is as follows: adding 200-400 mesh talc powder into the vinegar-acrylic emulsion, the mass ratio of the talc powder and the vinegar-acrylic emulsion is 15:22, stirring, heating to 80° C. and maintaining for 5 hours, filtering and drying Dry; add tannic acid aqueous solution to the obtained solid product, the mass fraction of tannic acid in the tannic acid aqueous solution is 8wt%, and the mass ratio of the solid product to the tannic acid aqueous solution is 1:20, heated to 90 ° C and kept for 10 hours, filtered Dry and pulverize, and pass through a 100-mesh sieve to obtain the inducer.
(b)利用发泡水泥制成镁基水泥发泡板。(b) Using foamed cement to make magnesium-based cement foam board.
实施例2Example 2
本实施例与实施例1的区别在于:The difference between this embodiment and Embodiment 1 is:
所述诱导剂由A组分和B组分组成,A组分的制备方法如下:将200-400目的滑石粉加入到醋丙乳液中,滑石粉与醋丙乳液的质量比为8:27,搅拌,加热至60℃并保持4小时,过滤烘干;将得到的固体产物中加入到鞣酸水溶液中,鞣酸水溶液中鞣酸的质量分数为10wt%,固体产物与鞣酸水溶液的质量比为1:30,加热至100℃并保持5小时,过滤烘干并粉碎,过100目筛即得A组分;B组分的制备方法如下:将200-400目粉煤灰的加入到三乙醇胺水溶液中,三乙醇胺水溶液的质量分数为5wt%,粉煤灰与三乙醇胺水溶液的质量比为1:15,搅拌,加热至70℃并保持24小时,过滤烘干;将得到的固体产物加入到硅烷偶联剂溶液中,固体产物与硅烷偶联剂溶液的质量比为1:10,硅烷偶联剂溶液中硅烷偶联剂的质量分数为10wt%,过滤烘干并粉碎,过100目筛即得B组分。The inducer is composed of component A and component B, and the preparation method of component A is as follows: 200-400 mesh talcum powder is added to the acetic acid acrylic emulsion, and the mass ratio of the talc powder to the acetic acid acrylic emulsion is 8:27, Stir, heat to 60 ° C and keep for 4 hours, filter and dry; add the obtained solid product to the tannic acid aqueous solution, the mass fraction of tannic acid in the tannic acid aqueous solution is 10wt%, and the mass ratio of the solid product to the tannic acid aqueous solution It is 1:30, heated to 100 ° C and kept for 5 hours, filtered, dried and pulverized, and passed through a 100-mesh sieve to obtain component A; the preparation method of component B is as follows: add 200-400 mesh fly ash to three In the ethanolamine aqueous solution, the mass fraction of the triethanolamine aqueous solution is 5wt%, and the mass ratio of the fly ash to the triethanolamine aqueous solution is 1:15, stirring, heating to 70 ° C and maintaining for 24 hours, filtering and drying; adding the obtained solid product into In the silane coupling agent solution, the mass ratio of the solid product to the silane coupling agent solution is 1:10, and the mass fraction of the silane coupling agent in the silane coupling agent solution is 10 wt %, filter, dry and pulverize, pass 100 mesh Sieve to get B component.
诱导剂加入方法如下:先加入A组分,A组分的加入量为MgO、MgSO4和H2O三者总质量的0.5wt%,搅拌24小时以上;然后再加入B组分,B组分的加入量为MgO、MgSO4和H2O三者总质量的1wt%,搅拌24小时以上。The method of adding the inducer is as follows: first add component A, the amount of component A is 0.5wt% of the total mass of MgO, MgSO 4 and H 2 O, and stir for more than 24 hours; then add component B, group B The added amount of the powder is 1 wt% of the total mass of MgO, MgSO 4 and H 2 O, and the mixture is stirred for more than 24 hours.
实施例3Example 3
本实施例与实施例2的区别在于:The difference between this embodiment and Embodiment 2 is:
(a)制备发泡水泥(a) Preparation of foamed cement
镁质盐水泥65千克、前处理后的粉煤灰、稳泡剂3千克和发泡剂5千克,按照水灰比0.45加水,搅拌制成发泡水泥浆液。前处理后的粉煤灰的加入量为镁质盐水泥制备时所用MgO质量的10wt%。65 kg of magnesia salt cement, pre-treated fly ash, 3 kg of foam stabilizer and 5 kg of foaming agent, add water according to the water-cement ratio of 0.45, and stir to make foamed cement slurry. The added amount of the pretreated fly ash is 10 wt % of the mass of MgO used in the preparation of the magnesia salt cement.
前处理后的粉煤灰制备方法如下:将200-400目粉煤灰的加入到三乙醇胺水溶液中,三乙醇胺水溶液的质量分数为3wt%,粉煤灰与三乙醇胺水溶液的质量比为1:12,搅拌,加热至70℃并保持12小时,过滤烘干;将得到的固体产物加入到硅烷偶联剂溶液中,固体产物与硅烷偶联剂溶液的质量比为1:16,硅烷偶联剂溶液中硅烷偶联剂的质量分数为15wt%,过滤烘干并粉碎,过100目筛即得前处理后的粉煤灰。The fly ash preparation method after the pretreatment is as follows: 200-400 mesh fly ash is joined in the triethanolamine aqueous solution, the mass fraction of the triethanolamine aqueous solution is 3wt%, and the mass ratio of the fly ash and the triethanolamine aqueous solution is 1: 12. Stir, heat to 70°C for 12 hours, filter and dry; add the obtained solid product to the silane coupling agent solution, the mass ratio of the solid product to the silane coupling agent solution is 1:16, and the silane coupling The mass fraction of the silane coupling agent in the agent solution is 15 wt %, which is filtered, dried, pulverized, and passed through a 100-mesh sieve to obtain the pretreated fly ash.
实施例4Example 4
本实施例与实施例1的区别在于:制备镁质盐水泥的时候不加入诱导剂。The difference between this example and Example 1 is that no inducer is added when preparing the magnesia salt cement.
实施例5Example 5
本实施例与实施例4的区别在于:加入的粉煤灰是未经前处理的粉煤灰。The difference between this example and Example 4 is that the added fly ash is unpretreated fly ash.
对实施例1-5中得到的镁基水泥发泡板进行性能测试,结果如表1所示:The performance test is carried out to the magnesium-based cement foam board obtained in the embodiment 1-5, and the results are as shown in Table 1:
表1Table 1
由表1可以看出:加入诱导剂之后,能够明显地增强硫氧镁水泥的抗压强度,尤其是加入组分为A组分和B组分的诱导剂,能够进一步增强硫氧镁水泥的抗压强度;虽然加入诱导剂之后,硫氧镁水泥的初凝时间延长,但是初终凝时间差缩短,说明加入诱导剂的硫氧镁水泥的凝结作用一旦开始之后就能够加速凝结硬化,适合于要求快速凝固的现场施工。It can be seen from Table 1 that the compressive strength of magnesium oxysulfate cement can be significantly enhanced after adding the inducer, especially the addition of the inducers with components A and B can further enhance the compressive strength of magnesium oxysulfide cement. Compressive strength; although the initial setting time of magnesium oxysulfide cement is prolonged after adding the inducer, the difference between the initial and final setting time is shortened, indicating that the setting effect of magnesium oxysulfide cement with the addition of inducer can accelerate the setting and hardening once it starts, which is suitable for On-site construction requiring rapid solidification.
表1中抗压强度软化系数的测试方法如下:分别将实施例1-实施例5中制得的镁基水泥发泡板养护28天,浸泡于水中180天,然后分别测试抗压强度,计算抗压强度软化系数。抗压强度软化系数=浸泡后抗压强度/浸泡前抗压强度。The test method for the softening coefficient of compressive strength in Table 1 is as follows: respectively, the magnesium-based cement foam boards prepared in Example 1-Example 5 were cured for 28 days, soaked in water for 180 days, and then the compressive strength was tested respectively, calculating Compressive strength softening coefficient. Compressive strength softening coefficient = compressive strength after soaking/compressive strength before soaking.
表1中抗腐蚀系数的测试方法如下:分别将实施例1-实施例5中制得的镁基水泥发泡板养护28天,浸泡于氯化镁质量分数为31wt%的氯化镁溶液中180天,然后分别测试浸泡后抗压强度,计算抗腐蚀系数。抗腐蚀系数=浸泡后抗压强度/浸泡前抗压强度。The test method of the anti-corrosion coefficient in Table 1 is as follows: respectively, the magnesium-based cement foam boards prepared in Example 1-Example 5 were cured for 28 days, soaked in a magnesium chloride solution with a magnesium chloride mass fraction of 31 wt% for 180 days, and then The compressive strength after immersion was tested respectively, and the corrosion resistance coefficient was calculated. Corrosion resistance coefficient = compressive strength after immersion / compressive strength before immersion.
表1中钢筋锈蚀速率的测试方法如下:分别将实施例1-实施例5中的镁质盐水泥水化200小时,采用CHI660C电化学工作站,借助两电极线性极化法测定钢筋在镁质盐水泥中的腐蚀电流和腐蚀速率。The test method of the corrosion rate of steel bars in table 1 is as follows: respectively hydrate the magnesia salt cement in Example 1-Example 5 for 200 hours, adopt CHI660C electrochemical workstation, measure steel bars in magnesia salt by means of two-electrode linear polarization method Corrosion current and corrosion rate in cement.
实施例6Example 6
如图1至图5所示,本实施例无梁柱板式房屋结构体系包括内墙拼板100、外墙拼板200和楼板300,所述内墙拼板100、所述外墙拼板200和所述楼板300均为镁基水泥发泡板;在所述内墙拼板100与所述外墙拼板200的交接处,所述内墙拼板100嵌入到所述外墙拼板200内或所述外墙拼板200嵌入到所述内墙拼板100内或所述内墙拼板100与所述外墙拼板200一体成型;相邻所述楼板300交接处的嵌缝内填充有镁基水泥纤维材料400,所述镁基水泥纤维材料400将相邻所述楼板300粘结起来。相邻所述外墙拼板200的交接处的外表面上覆盖有纤维布500。As shown in FIG. 1 to FIG. 5 , the structural system of the non-beam-column panel house in this embodiment includes an
所述内墙拼板100和所述外墙拼板200均为单层墙板;在所述楼板300与所述外墙拼板200的交接处,所述楼板300伸入到所述外墙拼板200内,并且所述楼板300外侧端面的外侧设置有外墙补板700,所述外墙补板700嵌在所述外墙拼板200内,并且所述外墙补板700的外表面与所述外墙拼板200的外立面平齐,所述外墙补板700也为镁基水泥发泡板。The
所述内墙拼板100和所述外墙拼板200均由单个镁基水泥发泡板600粘结连接而成;如图6至图10所示,在所述内墙拼板100与所述外墙拼板200的交接处:所述内墙拼板100嵌入到所述外墙拼板200的相邻两个单个镁基水泥发泡板600之间,并且所述内墙拼板100的外侧端面与所述外墙拼板200的外立面平齐;或者设置有T型节点900、所述T型节点900包括纵向板901以及设置在所述纵向板901外侧面上的横立板902,所述横立板902的板面与所述外墙拼板200的外表面平齐,所述纵向板901的板面与所述内墙拼板100的板面平齐;或者设置有T型节点组1000,所述T型节点组1000由T型节点900组成,所述T型节点900包括纵向板901以及设置在所述纵向板901外侧面上的横立板902,所述横立板902的板面与所述外墙拼板200的外表面平齐,所述纵向板901的板面与所述内墙拼板100的板面平齐,上下相邻的所述T型节点900的横立板902横向相错,使得相隔一个所述横立板902的两个所述横立板902之间形成容纳所述外墙拼板200的凹槽903,上下相邻的所述纵向板901长度不同,使得相隔一个所述纵向板901的两个所述纵向板901之间形成容纳所述内墙拼板100的凹槽903;The
如图11和图12所示,在所述外墙拼板200的交接处:任意一个所述外墙拼板200的端面与另一个所述外墙拼板200的墙面平齐,或者设置有L型节点单元904。As shown in FIG. 11 and FIG. 12 , at the junction of the exterior wall panels 200 : the end face of any one of the
实施例6中的镁基水泥纤维材料制备方法如下:The preparation method of the magnesium-based cement fiber material in embodiment 6 is as follows:
镁质盐水泥65千克(可以使用实施例1至实施例5中的镁质盐水泥)、前处理后的粉煤灰和聚乙烯醇纤维5千克,按照水灰比0.45加水,搅拌制成镁基水泥纤维材料浆液。前处理后的粉煤灰的加入量为镁质盐水泥制备时所用MgO质量的10wt%。65 kg of magnesia salt cement (the magnesia salt cement in Example 1 to 5 can be used), 5 kg of pre-treated fly ash and polyvinyl alcohol fiber, add water according to the water-cement ratio of 0.45, and stir to make magnesium based cement fiber material slurry. The added amount of the pretreated fly ash is 10 wt % of the mass of MgO used in the preparation of the magnesia salt cement.
前处理后的粉煤灰制备方法如下:将200-400目粉煤灰的加入到三乙醇胺水溶液中,三乙醇胺水溶液的质量分数为3wt%,粉煤灰与三乙醇胺水溶液的质量比为1:12,搅拌,加热至70℃并保持12小时,过滤烘干;将得到的固体产物加入到硅烷偶联剂溶液中,固体产物与硅烷偶联剂溶液的质量比为1:16,硅烷偶联剂溶液中硅烷偶联剂的质量分数为15wt%,过滤烘干并粉碎,过100目筛即得前处理后的粉煤灰。The fly ash preparation method after the pretreatment is as follows: 200-400 mesh fly ash is joined in the triethanolamine aqueous solution, the mass fraction of the triethanolamine aqueous solution is 3wt%, and the mass ratio of the fly ash and the triethanolamine aqueous solution is 1: 12. Stir, heat to 70°C for 12 hours, filter and dry; add the obtained solid product to the silane coupling agent solution, the mass ratio of the solid product to the silane coupling agent solution is 1:16, and the silane coupling The mass fraction of the silane coupling agent in the agent solution is 15 wt %, which is filtered, dried, pulverized, and passed through a 100-mesh sieve to obtain the pretreated fly ash.
显然,本发明的上述实施例仅仅是为清楚地说明本发明所作的举例,而并非是对本发明的实施方式的限定,对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动,这里无法对所有的实施方式予以穷举,凡是属于本发明的技术方案所引伸出的显而易见的变化或变动仍处于本发明的保护范围之列。Obviously, the above-mentioned embodiments of the present invention are only examples for clearly illustrating the present invention, and are not intended to limit the embodiments of the present invention. Changes or changes in other different forms cannot be exhausted here, and all obvious changes or changes derived from the technical solutions of the present invention are still within the protection scope of the present invention.
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