CN109694237A - A kind of surface layer blank and its preparation method and application being used to prepare artificial granite water-permeable brick - Google Patents

A kind of surface layer blank and its preparation method and application being used to prepare artificial granite water-permeable brick Download PDF

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Publication number
CN109694237A
CN109694237A CN201811639067.4A CN201811639067A CN109694237A CN 109694237 A CN109694237 A CN 109694237A CN 201811639067 A CN201811639067 A CN 201811639067A CN 109694237 A CN109694237 A CN 109694237A
Authority
CN
China
Prior art keywords
surface layer
layer blank
permeable brick
water
artificial granite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811639067.4A
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Chinese (zh)
Inventor
胡启成
欧世湖
黄启明
范国雄
周伟军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Eco Sponge City Science And Technology Development Co Ltd
Original Assignee
Foshan Eco Sponge City Science And Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Eco Sponge City Science And Technology Development Co Ltd filed Critical Foshan Eco Sponge City Science And Technology Development Co Ltd
Priority to CN201811639067.4A priority Critical patent/CN109694237A/en
Publication of CN109694237A publication Critical patent/CN109694237A/en
Priority to CN201910823884.3A priority patent/CN110668793A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Abstract

The invention discloses a kind of surface layer blanks for being used to prepare artificial granite water-permeable brick, the addition of nickel soil slag in the surface layer blank formulation, keep the permeable effect of artificial granite water-permeable brick obtained more excellent compared with the water-permeable brick as made from ceramic tailing, although the main component in formula in natural crystal is identical as the main component of shraff, its hair color effect is more preferable compared with tailing.The present invention provides a kind of preparation method of surface layer blank for being used to prepare artificial granite water-permeable brick, preparation process carries out at normal temperature, without heating, greatly reduces every cost such as production and manpower.Meanwhile the physical property of artificial granite water-permeable brick obtained is identical as granite, and the decorative effect of granite can also be presented, and also while having excellent water permeability.Raw material sources of the invention are extensive, nickel soil slag turned waste into wealth, and preparation process is easy to operate, high-efficient, are suitble to large-scale production, and market application prospect is extensive.

Description

A kind of surface layer blank being used to prepare artificial granite water-permeable brick and preparation method thereof and Using
Technical field
The present invention relates to architectural pottery technical fields, and in particular to a kind of surface layer base for being used to prepare artificial granite water-permeable brick Material and its preparation method and application.
Background technique
Ceramic water-permeable brick refers to using the screened sorting of ceramic raw material, organizes reasonable grain composition, after adding bonding agent, warp Molding, drying, high temperature sintering and the high-quality permeable building materials formed, surface form the equally distributed honeycomb structure in hole, Connectivity hole of the inside containing significant proportion has the characteristics that ventilative, permeable and light-weight.Water-permeable brick can improve the micro- gas in city It waits, the formation of retardance city flood.The porosity of ceramic water-permeable brick itself has good water-holding capacity, in the summer in 20%-30% It, water, which is filled, after rain infiltrates through ground, nourishes ground vapour, water conservation, provides moisture to trees and flowers and plants;In strong sunlight, water Divide evaporation that can reduce surface temperature, improves micro climate.It such as forms large area to mat formation, can effectively block rainwater, reduce city flood The probability of formation.However existing water-permeable brick also while can not have while the decorative effect of artificial granite can be presented Excellent water permeability.
Summary of the invention
To overcome the above in the prior art insufficient or defect, the present invention provides one kind, to be used to prepare artificial granite permeable The physical property of surface layer blank of brick and its preparation method and application, artificial granite water-permeable brick obtained is identical as granite, energy The decorative effect of granite is presented, also while there is excellent water permeability.
The technical solution used in the present invention is: a kind of surface layer blank for being used to prepare artificial granite water-permeable brick, the face Layer blank includes following components by weight:
Wherein, the main component of natural crystal and the main component of shraff are identical, but the hair color effect of natural crystal More preferably.
As a further improvement of the foregoing solution, the nickel soil slag sources are in Hexi Corridor in Gansu area, specific position In Hexi Corridor in Gansu Yongchang County north of the city, the Dragon Head Mountain mineral deposit of there is the rare non-ferrous metal based on nickel in a world Mineral intergrowth, be richly stored with nickel sulfide and copper, cobalt, gold, silver and platinum group metal.After the Jinchang nickel minerals sixties is gone into operation, terminate China does not produce the history of nickel, and making China's jump is one of world's nickel ore resource most countries.Present Jinchang nickel minerals is completed one The large integrated enterprise of comprehensive management is adopted, selected, refining, more than ten products can be extracted directly from ore, wherein nickel and platinum group metal Yield accounts for 85% and 90% of national total amount or more respectively.Jinchang has become the maximum nickel production base in China, copper, cobalt, gold, silver With platinum group metal refinement center, and there is the title of " Chinese nickel is all ".The addition of the nickel soil slag makes the saturating of entire body water-permeable brick obtained Water effect is more excellent compared with the water-permeable brick as made from ceramic tailing.
A kind of preparation method for the surface layer blank being used to prepare artificial granite water-permeable brick, includes the following steps: by institute as above The formula for stating surface layer blank, takes natural crystal to be processed, and is sieved after crushing, and adding additives, water and colorant are stirred mixed After conjunction, nickel soil slag and shraff are added, is stirred to get the surface layer blank of artificial granite water-permeable brick is used to prepare.
As a further improvement of the foregoing solution, any one of the natural crystal, nickel soil slag and shraff Be it is wet, then carry out the preparation of surface layer blank after dry 24-48h again at 60-80 DEG C.
As a further improvement of the foregoing solution, the natural crystal after being sieved is 6-10 mesh.
A kind of application for the surface layer blank being used to prepare artificial granite water-permeable brick, surface layer blank as described above is applied In the preparation of artificial granite water-permeable brick, by bottom blank and above-mentioned surface layer blank through press-molding, imitated after being incorporated to kiln sintering Granite water-permeable brick finished product.
The beneficial effects of the present invention are: the present invention provides a kind of surface layer blank for being used to prepare artificial granite water-permeable brick, The addition of nickel soil slag in the surface layer blank formulation makes the permeable effect of artificial granite water-permeable brick obtained compared with by ceramic tailing Water-permeable brick obtained is more excellent, although the main component in formula in natural crystal is identical as the main component of shraff, its Hair color effect is more preferable compared with tailing.The present invention provides a kind of preparation sides of surface layer blank for being used to prepare artificial granite water-permeable brick Method, preparation process carry out at normal temperature, without heating, greatly reduce every cost such as production and manpower.Meanwhile it being made Artificial granite water-permeable brick physical property it is identical as granite, the decorative effect of granite can be presented, also and meanwhile have excellent Water permeability.Raw material sources of the invention are extensive, and nickel soil slag is turned waste into wealth, and preparation process is easy to operate, high-efficient, fit Large-scale production is closed, market application prospect is extensive.
Specific embodiment
The present invention is specifically described below with reference to embodiment, in order to technical field personnel to of the invention Understand.It is necessary to it is emphasized that embodiment is only intended to, the present invention will be further described herein, should not be understood as to this The limitation of invention protection scope, fields person skilled in the art, according to foregoing invention content non-to made by the present invention The modifications and adaptations of matter should still fall within protection scope of the present invention.Mentioned raw materials following simultaneously are unspecified, For commercial product;The processing step or preparation method not referred in detail be processing step known to a person skilled in the art Or preparation method.
Embodiment 1
A kind of surface layer blank being used to prepare artificial granite water-permeable brick, the surface layer blank include with the following group by weight Point:
Wherein, the nickel soil slag sources are in Hexi Corridor in Gansu area.
A kind of preparation method for the surface layer blank being used to prepare artificial granite water-permeable brick, includes the following steps: by institute as above The formula for stating surface layer blank, takes natural crystal to be processed, after crushing cross 6-10 mesh sieve, adding additives, water and colorant into After row is stirred, nickel soil slag and shraff are added, is stirred to get the face of artificial granite water-permeable brick is used to prepare Layer blank;Wherein, the natural crystal, nickel soil slag and shraff need to be dried to 24-48h to carry out again at 60-80 DEG C The preparation of surface layer blank.
By bottom blank and above-mentioned surface layer blank through press-molding, artificial granite water-permeable brick finished product is obtained after being incorporated to kiln sintering 1。
Embodiment 2
A kind of surface layer blank being used to prepare artificial granite water-permeable brick, the surface layer blank include with the following group by weight Point:
Wherein, the nickel soil slag sources are in Hexi Corridor in Gansu area.
A kind of preparation method for the surface layer blank being used to prepare artificial granite water-permeable brick, includes the following steps: by institute as above The formula for stating surface layer blank, takes natural crystal to be processed, after crushing cross 6-10 mesh sieve, adding additives, water and colorant into After row is stirred, nickel soil slag and shraff are added, is stirred to get the face of artificial granite water-permeable brick is used to prepare Layer blank;Wherein, the natural crystal, nickel soil slag and shraff need to be dried to 24-48h to carry out again at 60-80 DEG C The preparation of surface layer blank.
By bottom blank and above-mentioned surface layer blank through press-molding, artificial granite water-permeable brick finished product is obtained after being incorporated to kiln sintering 2。
Embodiment 3
A kind of adhesive being used to prepare baking-free ceramic brick, the surface layer blank includes following components by weight:
Wherein, the nickel soil slag sources are in Hexi Corridor in Gansu area.
A kind of preparation method for the surface layer blank being used to prepare artificial granite water-permeable brick, includes the following steps: by institute as above The formula for stating surface layer blank, takes natural crystal to be processed, after crushing cross 6-10 mesh sieve, adding additives, water and colorant into After row is stirred, nickel soil slag and shraff are added, is stirred to get the face of artificial granite water-permeable brick is used to prepare Layer blank;Wherein, the natural crystal, nickel soil slag and shraff need to be dried to 24-48h to carry out again at 60-80 DEG C The preparation of surface layer blank.
By bottom blank and above-mentioned surface layer blank through press-molding, artificial granite water-permeable brick finished product is obtained after being incorporated to kiln sintering 3。
Comparative example 1
Ceramic water-permeable brick finished product purchased from the auspicious happy porcelain Co., Ltd production in Foshan City.
Embodiment 4
Ceramic water-permeable brick by above-described embodiment 1-3 and comparative example 1 purchased from the auspicious happy porcelain Co., Ltd production in Foshan City at Product carry out the performance detection of intensity, water penetration and artificial granite decorative effect etc. together, and result is as shown in table 1 below:
1 artificial granite water-permeable brick finished product 1-3 of table and the test of ceramic water-permeable brick end properties
Intensity (MPa) Water penetration (cm/s) Artificial granite decorative effect
Embodiment 1 6.0-8.0 4.9×10-2 Effect is obvious
Embodiment 2 6.0-8.0 5.5×10-2 Effect is obvious
Embodiment 3 8.0-9.0 5.8×10-2 Effect is obvious
Comparative example 1 3.5-5.0 0.5×10-2 It is unobvious
By table 1 it can be seen that, intensity, water penetration and the hilllock Fang Hua of the resulting artificial granite water-permeable brick finished product 1-3 of embodiment 1-3 Rock decorative effect is superior to the artificial granite ceramic water-permeable brick finished product of comparative example 1, especially water penetration, artificial granite water-permeable brick at The permeable effect of product 3 is substantially better than ceramic water-permeable brick finished product of the comparative example 1 purchased from the auspicious happy porcelain Co., Ltd production in Foshan City.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention, It should be equivalent substitute mode, be included within the scope of the present invention.

Claims (9)

1. a kind of surface layer blank for being used to prepare artificial granite water-permeable brick, which is characterized in that the surface layer blank is by weight Including following components:
2. surface layer blank according to claim 1, which is characterized in that the surface layer blank includes with the following group by weight Point:
3. surface layer blank according to claim 1, which is characterized in that the surface layer blank includes with the following group by weight Point:
4. surface layer blank according to claim 1, which is characterized in that the surface layer blank includes with the following group by weight Point:
5. surface layer blank according to claim 1-4, which is characterized in that the nickel soil slag sources are in Gansu Province Hexi Corridor Region.
6. a kind of preparation method for the surface layer blank for being used to prepare artificial granite water-permeable brick, which is characterized in that the preparation method Include the following steps: to take natural crystal to be processed by the formula of any one of the claim 1-4 surface layer blank, through broken After be sieved, after adding additives, water and colorant are stirred mixing, add nickel soil slag and shraff, be stirred to get It is used to prepare the surface layer blank of artificial granite water-permeable brick.
7. preparation method according to claim 6, which is characterized in that natural crystal, nickel soil slag and the waste ceramic Any one of material be it is wet, then carry out the preparation of surface layer blank after dry 24-48h again at 60-80 DEG C.
8. preparation method according to claim 6, which is characterized in that the natural crystal after being sieved is 6-10 mesh.
9. a kind of application for the surface layer blank for being used to prepare artificial granite water-permeable brick, which is characterized in that claim 1-4 is any Surface layer blank described in is applied in the preparation of artificial granite water-permeable brick.
CN201811639067.4A 2018-12-29 2018-12-29 A kind of surface layer blank and its preparation method and application being used to prepare artificial granite water-permeable brick Pending CN109694237A (en)

Priority Applications (2)

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CN201811639067.4A CN109694237A (en) 2018-12-29 2018-12-29 A kind of surface layer blank and its preparation method and application being used to prepare artificial granite water-permeable brick
CN201910823884.3A CN110668793A (en) 2018-12-29 2019-09-02 Granite ceramic water permeable brick and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981430A (en) * 2019-12-19 2020-04-10 佛山生态海绵城市科技发展有限公司 Nickel ore waste residue ceramic water permeable brick and preparation process thereof
CN112876212A (en) * 2021-03-15 2021-06-01 浙江寰龙环境科技有限公司 Granite-imitated water permeable brick made of stone waste and preparation process thereof
CN113716937A (en) * 2021-07-09 2021-11-30 景德镇市祎柏新材料研发有限公司 Granite-like ceramic tile taking domestic ceramic waste porcelain as raw material and preparation method thereof

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CN113336531A (en) * 2020-03-02 2021-09-03 广西净雨环保科技有限公司 Granite-like permeable plate and preparation method thereof
CN111875367A (en) * 2020-08-07 2020-11-03 广西净雨环保科技有限公司 Preparation method of waterproof granite-like plate
CN113003989A (en) * 2021-03-30 2021-06-22 广东四通建材股份有限公司 Stone-like ceramic water permeable brick and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1249858A (en) * 1968-01-05 1971-10-13 Certels Ltd Artificial stone tiles
US5264168A (en) * 1989-01-13 1993-11-23 Marcello Toncelli Plate product of ceramic material and process for the manufacturing thereof
CN105753504A (en) * 2016-01-28 2016-07-13 广东省建筑科学研究院集团股份有限公司 Ceramic water permeable brick produced by utilizing ceramic waste material and straw and preparation method for ceramic water permeable brick
CN108083769A (en) * 2017-12-22 2018-05-29 广东科达洁能股份有限公司 A kind of sintering brick permeable to water produced using ceramic particle and preparation method thereof
CN108083767B (en) * 2017-12-22 2020-05-22 广东科达洁能股份有限公司 Preparation method of water permeable brick

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981430A (en) * 2019-12-19 2020-04-10 佛山生态海绵城市科技发展有限公司 Nickel ore waste residue ceramic water permeable brick and preparation process thereof
CN112876212A (en) * 2021-03-15 2021-06-01 浙江寰龙环境科技有限公司 Granite-imitated water permeable brick made of stone waste and preparation process thereof
CN112876212B (en) * 2021-03-15 2021-09-28 浙江寰龙环境科技有限公司 Granite-imitated water permeable brick made of stone waste and preparation process thereof
CN113716937A (en) * 2021-07-09 2021-11-30 景德镇市祎柏新材料研发有限公司 Granite-like ceramic tile taking domestic ceramic waste porcelain as raw material and preparation method thereof
CN113716937B (en) * 2021-07-09 2023-02-28 景德镇市祎柏新材料研发有限公司 Granite-like ceramic tile taking domestic ceramic waste porcelain as raw material and preparation method thereof

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